CN104531384A - Tea saponin anti-bacterial detergent and preparing method thereof - Google Patents
Tea saponin anti-bacterial detergent and preparing method thereof Download PDFInfo
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- CN104531384A CN104531384A CN201510011494.8A CN201510011494A CN104531384A CN 104531384 A CN104531384 A CN 104531384A CN 201510011494 A CN201510011494 A CN 201510011494A CN 104531384 A CN104531384 A CN 104531384A
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Abstract
The invention discloses a tea saponin anti-bacterial detergent and a preparing method of the detergent, and relates to the technical field of detergent production in the daily-use chemical industry. The detergent is prepared through the following raw materials, by weight, 1-20 parts of a tea saponin concentrated solution, 1-10 parts of astragalus extract, 1-20 parts of AES, 1-10 parts of CAB, 1-5 parts of 6501, 0.1-5 parts of NaOH, 0.1-1 part of NaC1, 0.01-0.2 part of Kathan and the balance deionized water, and the raw materials amount to 100 parts in all. The preparing process includes (1) material preparation, (2) preparation of a solution A, (3) preparation of a solution B and (4) mixing. The tea saponin anti-bacterial detergent has a good cleaning effect and antibacterial effect, has the advantages of being easy to use for rinsing, low in stimulation, environmentally friendly and the like, and is suitable for being used for cleaning tableware for common families.
Description
Technical field
The present invention relates to the washing composition production technical field in daily-use chemical industry, particularly a kind of tea saponin Antibiotic liquid detergent and preparation method thereof.
Technical background
Detergents and cosmetic cleaning agent is a kind of daily chemical products of people's widespread use in daily life, and existing cleaning agent kind is more, mostly containing synthetic chemistry cleaning ingredients, not easily reduce, and certain pollution is caused to environment, simultaneously, in washing process, also residue problem can be produced.In addition, the antibacterial effect of existing liquid detergent also allows of no optimist.
Chinese patent (number of patent application is 201410432611.3) disclosed " a kind of sterilization antimicrobial form dish washing detergent ", be made up of the raw material of following weight percent: methyl sodiosul foaliphatate 11% ~ 16%, alcohol ether carboxylate 8% ~ 12%, alkyl glycoside 6% ~ 11%, bamboo vinegar liquid 4% ~ 8%, coconut oil fatty acid monoethanolamide 3% ~ 6%, Flower of Arabian Jasmine extracting solution 3% ~ 5%, tea saponin 1% ~ 3%, poly (sodium aspartate) 1% ~ 3%, Sunmorl N 60S 0.8% ~ 3.0%, salt 0.5% ~ 2.5%, distilled water surplus; The dish washing detergent of this invention, sterilization antibacterial effect is remarkable, and easily degrades, safety and environmental protection, gentle, has maintenance effect, can not injure skin to skin.Also has Chinese patent (number of patent application is 201010574177.4) disclosed " washing composition of a kind of manual dishwashing or vegetable and fruit ", the component of this washing composition is: tea saponin crystal 3 ~ 20, AES4 ~ 8,65011 ~ 7, sulfonic acid 1 ~ 3, sheet alkali 0.1 ~ 0.3, AOS1 ~ 3, EDTA-2Na0.1 ~ 0.3, KF88 0.1 ~ 0.4, essence 0.2 ~ 0.5, ethanol 1 ~ 3, deionized water 60 ~ 80; Use the present invention can effective wash dining set grease or remove fruit-vegetable pesticide residues, veterinary antibiotics can also be removed rapidly surperficial cured for fresh-keeping fruit, harmless to HUMAN HEALTH, environment is not polluted.
Technology contents
The object of the present invention is to provide one to have good cleaning effect, have good antibacterial effect again, and there is the cleaning supplies of the features such as easy rinsing, low stimulation and environmental friendliness.
For achieving the above object, the technical solution used in the present invention is a kind of tea saponin Antibiotic liquid detergent of invention, is be prepared from by following raw material by weight:
Surplus is deionized water, adds up to 100 parts.
Its technical scheme optimized is prepared from by following raw material by weight:
Described tea saponin concentrated solution is prepared from as follows: concentrated by the tea dregs of rice form through degreasing, hot water extraction, secondary hot water's lixiviate, flocculation sediment filtration, vacuum concentration, ethanol removal of impurities, a secondary vacuum;
Described Radix Astragali extractive solution is prepared from as follows: formed through soak at room temperature, once extraction, second extraction, once concentration, ethanol removal of impurities, secondary concentration by the Radix Astragali.
Its technical scheme optimized is prepared from by following raw material by weight:
The concrete preparation process of described tea saponin concentrated solution is as follows:
1., degreasing: getting the tea dregs of rice 100 parts by weight, be placed in Soxhlet extractor, take sherwood oil as solvent, and reflux at 60-70 DEG C 5-8h, obtains the degreasing tea dregs of rice, for subsequent use;
2., a hot water extraction: according to solid-liquid ratio 1:(4-6 in the degreasing tea dregs of rice for subsequent use) ratio add deionized water, extracting at constant temperature 2-4h at 80-95 DEG C, filter, obtain vat liquor and filter residue, for subsequent use;
3., secondary hot water's lixiviate: be 1:(1-3 according to solid-liquid ratio in filter residue for subsequent use) ratio add deionized water, extracting at constant temperature 1-2h at 80-95 DEG C, merge twice vat liquor, obtain mixing vat liquor, for subsequent use;
4., flocculation sediment filters: add the flocculation agent (can adopt Tai-Ace S 150 or other flocculation agents) accounting for its weight 1-5% to mixing vat liquor for subsequent use, standing 2-4h, filters, and collects filtered liquid, for subsequent use;
5., vacuum concentration: by filtered liquid for subsequent use through vacuum (0.08-0.1Mpa) be concentrated into filtrate be burgundy viscous liquid (that is: 1 standard atmospheric pressure, 20 DEG C time, kinematic viscosity≤1.2 × 10
-3m
2/ s), obtain concentrated solution, for subsequent use;
6., ethanol removal of impurities: add 100 parts of weight in concentrated solution for subsequent use, volumetric concentration is the ethanol of 80-90%, then, standing, layering, get supernatant liquor, again respectively with the washing with alcohol lower floor liquid 2 times that 50 parts of weight, volumetric concentration are 80-90%, merge three supernatant liquors, obtain removal of impurities liquid, for subsequent use;
7., secondary vacuum concentrates: half removal of impurities liquid for subsequent use being concentrated into original volume through vacuum (0.08-0.1Mpa), obtains tea saponin concentrated solution.
The concrete preparation process of described Radix Astragali extractive solution is as follows:
1., soak at room temperature: be 1:(4-6 by the Radix Astragali according to solid-liquid ratio) part by weight add in deionized water, soak at room temperature 0.5-2h, obtains the immersion Radix Astragali, for subsequent use;
2., once extract: the immersion Radix Astragali for subsequent use is heated to 90-110 DEG C with the speed of 3-6 DEG C/min, constant temperature extracts 1-3 hour, filters, and obtains an extracting solution and filter residue respectively, for subsequent use;
3., second extraction: be 1:(10-20 by solid-liquid ratio again) part by weight, in filter residue for subsequent use, add deionized water, boil and extract 0.5-1 hour, filter, obtain secondary raffinate, merge extracted twice liquid, obtain mixed extract, for subsequent use;
4., once concentration: mixed extract for subsequent use is concentrated into 1/3 of original volume through vacuum (0.08-0.1Mpa), obtains once concentration liquid, for subsequent use;
5., ethanol removal of impurities: the dehydrated alcohol adding equal volume in once concentration liquid for subsequent use, through 3000-5000r/min centrifugal treating 5-10min, obtains astragalus extraction supernatant liquor, for subsequent use;
6., secondary concentration: half astragalus extraction supernatant liquor for subsequent use being concentrated into original volume through vacuum (0.08-0.1Mpa), obtains Radix Astragali extractive solution.
Meanwhile, also provide a kind of preparation method of tea saponin Antibiotic liquid detergent, its preparation process is as follows:
(i), get the raw materials ready: according to above-mentioned weight, get each raw material respectively, for subsequent use;
(ii), solution A preparation: AES for subsequent use is joined in the deionized water accounting for deionized water total amount 20-50% for subsequent use, according to the ramp of 3-5 DEG C/min to 50-70 DEG C, and heat up in limit, limit is stirred, after AES dissolves completely under 20-50r/min, obtain solution A, for subsequent use;
(iii), solution B preparation: mixed with the deionized water of equivalent weight by CAB for subsequent use and 6501, according to the ramp of 3-5 DEG C/min to 50-70 DEG C, and limit intensification, limit are stirred under 20-50r/min, after CAB and 6501 dissolves completely, obtain solution B, for subsequent use;
(iv), mix: first NaCl for subsequent use is dissolved in and accounts in its weight 2-5 deionized water doubly, obtain NaCl solution, for subsequent use; Again tea saponin concentrated solution for subsequent use is mixed with solution A for subsequent use, solution B, stir under 20-50r/min, then, to 6.5-7.5 when being down to 35-45 DEG C according to the rate of temperature fall of 3-5 DEG C/min, by NaOH adjusted to ph for subsequent use, add Radix Astragali extractive solution again, and add NaCl solution for subsequent use, stir under 20-50r/min, add Kathon CG for subsequent use and remaining deionized water again, stir under 20-50r/min, degassed through vacuum (0.01-0.03Mpa), remove bubble, tea saponin Antibiotic liquid detergent.
The raw material that tea saponin Antibiotic liquid detergent of the present invention adopts be tea saponin concentrated solution, Radix Astragali extractive solution, AES, CAB, 6501, NaOH, NaCl, Kathon CG and deionized water, wherein:
Tea saponin concentrated solution: principle active component is tea saponin is a kind of natural surface active agent, is to extract from the tea dregs of rice extracted after tea oil with flocculation-precipitation method, concentrate gained;
Radix Astragali extractive solution: main containing astragalus polysaccharides and astragalin isoreactivity composition, has antibacterial effect;
AES: i.e. fatty alcohol-ether sodium sulfate is a kind of aniorfic surfactant, has the performances such as decontamination, emulsification and foaming, and character is gentle;
CAB: i.e. AMONYL 380LC, be a kind of zwitterionics, pungency is low, strong detergency;
6501: i.e. cocoanut fatty acid diethanolamide, be a kind of nonionogenic tenside, there is good foaming, detergency ability;
NaOH: i.e. sodium hydroxide, is a kind of highly basic, uses in the present invention as pH value regulator;
NaCl: i.e. sodium-chlor, has splendid thickening power to the surfactant system of AES and CAB composition;
Kathon CG: i.e. isothiazolinone is a kind of sanitas of efficient, nontoxic, restraining and sterilizing bacteria wide spectrum.
Thus, tea saponin Antibiotic liquid detergent of the present invention, can reach clean effect, has again easy rinsing, low stimulation and advantages of environment protection.
Tea saponin Antibiotic liquid detergent of the present invention, the Testing index of its product (with embodiment two for sample) is as follows:
One, sanitary index and sense organ physical and chemical index
Oranoleptic indicator of the present invention and physical and chemical index all meet the standard of GB 9985-2000 after testing, and wherein the mensuration of detersive power is with reference to GB 9985-2000 Appendix B.
Microbiological indicator of the present invention performs GB 14930.1 and specifies, meets its standard.
following table 1sense organ of the present invention, physical and chemical index.
table 1the sense organ of tea saponin liquid detergent and physical and chemical index
following table 2it is microbiological indicator of the present invention.
table 2the microbiological indicator of tea saponin liquid detergent
| Project | Index | Actual index |
| Total plate count, individual/g≤ | 1000 | 335 |
| Coliform, individual/100g≤ | 3 | Do not detect |
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.Explanation is below the mode exemplified, but protection scope of the present invention is not limited thereto.
Embodiment one
The tea saponin Antibiotic liquid detergent of the present embodiment, its preparation process comprises:
(i), get the raw materials ready: get respectively by weight tea saponin concentrated solution 20 parts, Radix Astragali extractive solution 1 part, AES 1 part, CAB 1 part, 6,501 1 parts, NaOH 0.1 part, NaCl 0.1 part, Kathon CG 0.01 part, deionized water 75.79 parts, add up to 100 parts, for subsequent use;
(ii), tea saponin concentrated solution preparation:
1., degreasing: getting the tea dregs of rice 100 parts by weight, be placed in Soxhlet extractor, take sherwood oil as solvent, and reflux at 65 DEG C 6h, obtains the degreasing tea dregs of rice, for subsequent use;
2. a, hot water extraction: add deionized water according to the ratio of solid-liquid ratio 1:5, extracting at constant temperature 3h at 90 DEG C in the degreasing tea dregs of rice for subsequent use, filtration, obtains vat liquor and filter residue, for subsequent use;
3., secondary hot water's lixiviate: the ratio being 1:2 according to solid-liquid ratio in filter residue for subsequent use adds deionized water, and extracting at constant temperature 1.5h at 90 DEG C merges twice vat liquor, obtains mixing vat liquor, for subsequent use;
4., flocculation sediment filters: add the Tai-Ace S 150 (flocculation agent) accounting for its weight 3% to mixing vat liquor for subsequent use, standing 3h, filters, and collects filtered liquid, for subsequent use;
5., vacuum concentration: by filtered liquid for subsequent use through vacuum (0.09Mpa) be concentrated into filtrate be burgundy viscous liquid (that is: 1 standard atmospheric pressure, 20 DEG C time, kinematic viscosity≤1.2 × 10
-3m
2/ s), obtain concentrated solution, for subsequent use;
6., ethanol removal of impurities: in concentrated solution for subsequent use, add 100 parts of weight, volumetric concentration be the ethanol of 85%, then, leave standstill, layering, get supernatant liquor, then be the washing with alcohol lower floor liquid 2 times of 85% by 50 parts of weight, volumetric concentration respectively, merge three supernatant liquors, obtain removal of impurities liquid, for subsequent use;
7., secondary vacuum concentrates: half removal of impurities liquid for subsequent use being concentrated into original volume through vacuum (0.09Mpa), obtains tea saponin concentrated solution.
(iii), Radix Astragali extractive solution preparation:
1., soak at room temperature: the Radix Astragali is added in deionized water according to the part by weight that solid-liquid ratio is 1:5, soak at room temperature 1h, obtains the immersion Radix Astragali, for subsequent use;
2., once extract: the immersion Radix Astragali for subsequent use is heated to 100 DEG C with the speed of 5 DEG C/min, and constant temperature extracts 2 hours, filter, obtain an extracting solution and filter residue respectively, for subsequent use;
3., second extraction: be the part by weight of 1:15 by solid-liquid ratio again, in filter residue for subsequent use, add deionized water, boil extraction 0.8 hour, filter, obtain secondary raffinate, merge extracted twice liquid, obtain mixed extract, for subsequent use;
4., once concentration: mixed extract for subsequent use is concentrated into 1/3 of original volume through vacuum (0.09Mpa), obtains once concentration liquid, for subsequent use;
5., ethanol removal of impurities: the dehydrated alcohol adding equal volume in once concentration liquid for subsequent use, through 4000r/min centrifugal treating 8min, obtains astragalus extraction supernatant liquor, for subsequent use;
6., secondary concentration: half astragalus extraction supernatant liquor for subsequent use being concentrated into original volume through vacuum (0.09Mpa), obtains Radix Astragali extractive solution.
(iv), solution A preparation: joined by AES for subsequent use and account in 20% of deionized water total amount for subsequent use, according to the ramp to 60 DEG C of 4 DEG C/min, and heat up in limit, limit is stirred under 35r/min, after AES dissolves completely, obtains solution A, for subsequent use;
(v), solution B preparation: mixed with the deionized water of equivalent weight by CAB for subsequent use and 6501, according to the ramp to 60 DEG C of 4 DEG C/min, and heat up in limit, limit is stirred under 35r/min, after CAB and 6501 dissolves completely, obtains solution B, for subsequent use;
(vi), mix: first NaCl for subsequent use is dissolved in the deionized water accounting for its weight 2 times, obtains NaCl solution, for subsequent use; Again tea saponin concentrated solution for subsequent use is mixed with solution A for subsequent use, solution B, stir under 35r/min, then, when being down to 40 DEG C according to the rate of temperature fall of 4 DEG C/min, by NaOH adjusted to ph to 7 for subsequent use, add Radix Astragali extractive solution again, and add NaCl solution for subsequent use, stir under 35r/min, then add Kathon CG for subsequent use and remaining deionized water, stir under 35r/min, through 0.02Mpa vacuum outgas, remove bubble, tea saponin Antibiotic liquid detergent.
Tea saponin Antibiotic liquid detergent of the present invention, using method is identical with common liquid detergent.
Embodiment two:
The tea saponin Antibiotic liquid detergent of the present embodiment, its preparation process comprises:
(i), get the raw materials ready: get respectively by weight tea saponin concentrated solution 1 part, Radix Astragali extractive solution 10 parts, AES 20 parts, CAB 10 parts, 6,501 5 parts, NaOH 3 parts, NaCl 1 part, Kathon CG 0.2 part, deionized water 49.8 parts, add up to 100 parts, for subsequent use;
Other is identical with embodiment one.
Embodiment three:
(i), get the raw materials ready: get respectively by weight tea saponin concentrated solution 10 parts, Radix Astragali extractive solution 5 parts, AES 10 parts, CAB 5 parts, 6,501 2.5 parts, NaOH 0.25 part, NaCl 0.5 part, Kathon CG 0.1 part, deionized water 66.65 parts, add up to 100 parts, for subsequent use;
Other is identical with embodiment one.
Embodiment four:
(i), get the raw materials ready: get respectively by weight tea saponin concentrated solution 20 parts, Radix Astragali extractive solution 10 parts, AES 20 parts, CAB 10 parts, 6,501 5 parts, NaOH 2 parts, NaCl 0.8 part, Kathon CG 0.2 part, deionized water 32 parts, add up to 100 parts, for subsequent use;
Other is identical with embodiment one.
Tea saponin Antibiotic liquid detergent of the present invention, uses when being suitable for general household cleaning tableware.
Claims (5)
1. a tea saponin Antibiotic liquid detergent, it is characterized in that being prepared from by following raw material by weight:
Surplus is deionized water, adds up to 100 parts;
Described tea saponin concentrated solution is prepared from as follows: concentrated by the tea dregs of rice form through degreasing, hot water extraction, secondary hot water's lixiviate, flocculation sediment filtration, vacuum concentration, ethanol removal of impurities, a secondary vacuum;
Described Radix Astragali extractive solution is prepared from as follows: formed through soak at room temperature, once extraction, second extraction, once concentration, ethanol removal of impurities, secondary concentration by the Radix Astragali.
2. tea saponin Antibiotic liquid detergent according to claim 1, it is characterized in that being prepared from by following raw material by weight:
3. tea saponin Antibiotic liquid detergent according to claim 1 and 2, is characterized in that, the concrete preparation process of described tea saponin concentrated solution is as follows:
1., degreasing: getting the tea dregs of rice 100 parts by weight, be placed in Soxhlet extractor, take sherwood oil as solvent, and reflux at 60-70 DEG C 5-8h, obtains the degreasing tea dregs of rice, for subsequent use;
2., a hot water extraction: according to solid-liquid ratio 1:(4-6 in the degreasing tea dregs of rice for subsequent use) ratio add deionized water, extracting at constant temperature 2-4h at 80-95 DEG C, filter, obtain vat liquor and filter residue, for subsequent use;
3., secondary hot water's lixiviate: be 1:(1-3 according to solid-liquid ratio in filter residue for subsequent use) ratio add deionized water, extracting at constant temperature 1-2h at 80-95 DEG C, merge twice vat liquor, obtain mixing vat liquor, for subsequent use;
4., flocculation sediment filters: add to mixing vat liquor for subsequent use the flocculation agent accounting for its weight 1-5%, standing 2-4h, filters, and collects filtered liquid, for subsequent use;
5., vacuum concentration: be burgundy viscous liquid by filtered liquid for subsequent use through vacuum concentration to filtrate, obtain concentrated solution, for subsequent use;
6., ethanol removal of impurities: add 100 parts of weight in concentrated solution for subsequent use, volumetric concentration is the ethanol of 80-90%, then, standing, layering, get supernatant liquor, again respectively with the washing with alcohol lower floor liquid 2 times that 50 parts of weight, volumetric concentration are 80-90%, merge three supernatant liquors, obtain removal of impurities liquid, for subsequent use;
7., secondary vacuum concentrates: by removal of impurities liquid for subsequent use through vacuum concentration to the half of original volume, obtain tea saponin concentrated solution.
4. tea saponin Antibiotic liquid detergent according to claim 3, is characterized in that, the concrete preparation process of described Radix Astragali extractive solution is as follows:
1., soak at room temperature: be 1:(4-6 by the Radix Astragali according to solid-liquid ratio) part by weight add in deionized water, soak at room temperature 0.5-2h, obtains the immersion Radix Astragali, for subsequent use;
2., once extract: the immersion Radix Astragali for subsequent use is heated to 90-110 DEG C with the speed of 3-6 DEG C/min, constant temperature extracts 1-3 hour, filters, and obtains an extracting solution and filter residue respectively, for subsequent use;
3., second extraction: be 1:(10-20 by solid-liquid ratio again) part by weight, in filter residue for subsequent use, add deionized water, boil and extract 0.5-1 hour, filter, obtain secondary raffinate, merge extracted twice liquid, obtain mixed extract, for subsequent use;
4., once concentration: by mixed extract for subsequent use through vacuum concentration to 1/3 of original volume, obtain once concentration liquid, for subsequent use;
5., ethanol removal of impurities: the dehydrated alcohol adding equal volume in once concentration liquid for subsequent use, through 3000-5000r/min centrifugal treating 5-10min, obtains astragalus extraction supernatant liquor, for subsequent use;
6., secondary concentration: by astragalus extraction supernatant liquor for subsequent use through vacuum concentration to the half of original volume, obtain Radix Astragali extractive solution.
5. the preparation method of tea saponin Antibiotic liquid detergent according to any one of claim 1-4, is characterized in that preparation process is as follows:
(i), get the raw materials ready: according to above-mentioned weight, get each raw material respectively, for subsequent use;
(ii), solution A preparation: AES for subsequent use is joined in the deionized water accounting for deionized water total amount 20-50% for subsequent use, according to the ramp of 3-5 DEG C/min to 50-70 DEG C, and heat up in limit, limit is stirred, after AES dissolves completely under 20-50r/min, obtain solution A, for subsequent use;
(iii), solution B preparation: mixed with the deionized water of equivalent weight by CAB for subsequent use and 6501, according to the ramp of 3-5 DEG C/min to 50-70 DEG C, and limit intensification, limit are stirred under 20-50r/min, after CAB and 6501 dissolves completely, obtain solution B, for subsequent use;
(iv), mix: first NaCl for subsequent use is dissolved in and accounts in its weight 2-5 deionized water doubly, obtain NaCl solution, for subsequent use; Again tea saponin concentrated solution for subsequent use is mixed with solution A for subsequent use, solution B, stir under 20-50r/min, then, to 6.5-7.5 when being down to 35-45 DEG C according to the rate of temperature fall of 3-5 DEG C/min, by NaOH adjusted to ph for subsequent use, add Radix Astragali extractive solution again, and add NaCl solution for subsequent use, stir under 20-50r/min, add Kathon CG for subsequent use and remaining deionized water again, stir under 20-50r/min, through vacuum outgas, remove bubble, tea saponin Antibiotic liquid detergent.
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| CN106434013A (en) * | 2016-09-19 | 2017-02-22 | 江苏田亮日用品有限公司 | Bacteriostatic and bactericidal kitchen stain remover and preparation method thereof |
| CN107418754A (en) * | 2017-05-22 | 2017-12-01 | 江西乔盛茶皂素科技有限公司 | A kind of plant dinnerware washing agent and preparation method thereof |
| CN109628209A (en) * | 2019-01-07 | 2019-04-16 | 蒋文昌 | A kind of tea seed essence production technology |
| CN111440673A (en) * | 2020-05-09 | 2020-07-24 | 佛山市南海区旭展洗涤用品厂 | Tea saponin detergent and preparation method thereof |
| CN111690474A (en) * | 2019-03-11 | 2020-09-22 | 中国科学院青岛生物能源与过程研究所 | Low-foaming tea saponin detergent and preparation method thereof |
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| CN112143581A (en) * | 2020-09-27 | 2020-12-29 | 枣庄学院 | Antibacterial and antiviral natural detergent and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106434013A (en) * | 2016-09-19 | 2017-02-22 | 江苏田亮日用品有限公司 | Bacteriostatic and bactericidal kitchen stain remover and preparation method thereof |
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| CN109628209A (en) * | 2019-01-07 | 2019-04-16 | 蒋文昌 | A kind of tea seed essence production technology |
| CN111690474A (en) * | 2019-03-11 | 2020-09-22 | 中国科学院青岛生物能源与过程研究所 | Low-foaming tea saponin detergent and preparation method thereof |
| CN111690473A (en) * | 2019-03-11 | 2020-09-22 | 中国科学院青岛生物能源与过程研究所 | Tea saponin detergent for infants and preparation method thereof |
| CN111440673A (en) * | 2020-05-09 | 2020-07-24 | 佛山市南海区旭展洗涤用品厂 | Tea saponin detergent and preparation method thereof |
| CN112143581A (en) * | 2020-09-27 | 2020-12-29 | 枣庄学院 | Antibacterial and antiviral natural detergent and preparation method thereof |
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Application publication date: 20150422 |