CN103205333A - Detergent and preparation method thereof - Google Patents
Detergent and preparation method thereof Download PDFInfo
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- CN103205333A CN103205333A CN2013101348934A CN201310134893A CN103205333A CN 103205333 A CN103205333 A CN 103205333A CN 2013101348934 A CN2013101348934 A CN 2013101348934A CN 201310134893 A CN201310134893 A CN 201310134893A CN 103205333 A CN103205333 A CN 103205333A
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Abstract
The invention discloses a detergent. The detergent comprises the following compositions in percentage by weight: 12-18% of a soap base, 6-10% of sodium alcohol ether sulphate, 1-4% of coconut diethanolamide, 5-10% of fatty alcohol-polyoxyethylene (9) ether, 0.01-0.5% of essence, 0.01-0.5% of pigment, and the balance of water. The preparation method of the detergent comprises the following steps of: a, mixing the compositions of the detergent in proportion; b, stirring and heating the obtained mixture to 80-85 DEG C; and c, cooling the obtained product so as to obtain a finished detergent product. According to the detergent and preparation method thereof disclosed by the invention, the obtained detergent is good in cleaning effect and moderate in performance, and can reduce the water consumption for cleaning.
Description
Technical field
The present invention relates to the articles for washing technical field, be specifically related to a kind of liquid detergent and preparation method thereof.
Background technology
Development along with the integrated and trade globalization of world economy, culture background, state of the art and environmental regulation become three large driving forces of articles for washing globalization development gradually, the articles for washing in the whole world will tend to variation, but energy-conservation, water saving, product efficient, gentle, easy to use and that meet safety and environmental requirement will be the main flow directions that current and following cleaning product develops.
Liquid detergent is family's cleaning dirt that arrives commonly used and the product of greasy dirt, and the performance impact of its product is to human beings'health.Therefore, require liquid detergent to have safety and environmental protection, clean gentle, soft and fine, the rapid characteristic of decomposing oil of foam, thereby reach fast decontaminating, degerming, effective thoroughly cleaning, not residual purpose.And in the prior art, use liquid detergent can produce a large amount of foams, and be easy to generate the residual problem of liquid detergent, thoroughly remove, need to consume a large amount of water, thereby increased the cost of cleaning dirt and greasy dirt.
Summary of the invention
The objective of the invention is to overcome above shortcoming, provide that a kind of cleaning effect is good, performance is gentle, and can reduce liquid detergent of cleaning water consumption and preparation method thereof.
Technical scheme of the present invention is:
A kind of liquid detergent, the component of described liquid detergent and the weight percent of each component are: soap base: 12-18%; Polyoxyethylenated alcohol sodium sulfate: 6-10%; Cocoanut fatty acid diethanolamide: 1-4%; Aliphatic alcohol polyethenoxy (9) ether: 5-10%; Essence: 0.01-0.5%; Pigment: 0.01-0.5%; Water: surplus.
Further, the weight percent of the component of described liquid detergent and each component is: soap base: 14-16%; Polyoxyethylenated alcohol sodium sulfate: 7.5-8.5%; Cocoanut fatty acid diethanolamide: 1.5-2.8%; Aliphatic alcohol polyethenoxy (9) ether: 7-8.5%; Essence: 0.01-0.5%; Pigment: 0.01-0.5%; Water: surplus.
Further, the weight percent of the component of described soap base and each component is: grease: 21-30%; Alkali: 10-15%; Dehydrated alcohol: 21-30%; Water: surplus.
Further, described grease is the product of discarded edible oil purification process technology.
Further, described discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; The vacuum tightness of described vacuum filtration step is 0.080～0.098MPa.
Further, the preparation method of described soap base is as follows:
A, grease, alkali, dehydrated alcohol and water are mixed in proportion;
B, stirring and heating 20-40min, heating and temperature control is at 70-90 ℃;
Obtain the soap base finished product after c, the cooling.
A kind of preparation method of liquid detergent, described preparation method's step is as follows:
A, the component of each described liquid detergent in the claim 1 to 4 is mixed in proportion;
B, stir and be heated to 80-85 ℃;
Obtain the liquid detergent finished product after c, the cooling.
Further, comprise the preparation method of soap base among the described preparation method, the preparation method of described soap base is as follows:
A, grease, alkali, dehydrated alcohol and water are mixed in proportion;
B, stirring and heating 20-40min, heating and temperature control is at 70-90 ℃;
Obtain the soap base finished product after c, the cooling.
Further, described stirring velocity is 270-320r/min.
Further, comprise the preparation method of grease among the described preparation method: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; The vacuum tightness of described vacuum filtration step is 0.080～0.098MPa.
Liquid detergent provided by the invention and preparation method thereof has following advantage:
1, liquid detergent provided by the invention, cleaning effect is eager to do well in everything.Liquid detergent provided by the invention, the weight percent of moiety and each composition is: the component of described liquid detergent and the weight percent of each component are: soap base: 12-18%; Polyoxyethylenated alcohol sodium sulfate: 6-10%; Cocoanut fatty acid diethanolamide: 1-4%; Aliphatic alcohol polyethenoxy (9) ether: 5-10%; Essence: 0.01-0.5%; Pigment: 0.01-0.5%; Water: surplus.Wherein, soap base is formed by grease, alkali, ethanol, water hybrid reaction as the main raw material of liquid detergent, and its cleaning capacity is strong; Polyoxyethylenated alcohol sodium sulfate is anion surfactant, and is soluble in water, has good decontamination, emulsification, foam performance, and has gentle washing character, can injured skin; Cocoanut fatty acid diethanolamide belongs to nonionogenic tenside, and is soluble in water, have functions such as good foaming, steady bubble, infiltration decontamination, anti-hard water; Aliphatic alcohol polyethenoxy (9) ether is to belong to nonionogenic tenside, and the ehter bond in the molecule is difficult for being destroyed by acid, alkali, so stability is higher, water-soluble better electrolyte-resistant is easy to biological degradation, and foam is little, and is good with the compatibleness of other tensio-active agents; Liquid detergent provided by the invention contains soap base, aniorfic surfactant and nonionic surface active agent, and compatibleness is good, and each component can be given full play to the advantage of oneself, and cleaning effect is good, and after testing, the gross activity thing in the liquid detergent is more than or equal to 20%.
2, liquid detergent provided by the invention, performance gentleness, pungency are little.After testing, under 25 ℃ of conditions, the liquid detergent provided by the invention of 0.1% concentration, pH value≤9, the pH value is moderate, skin irritation not, performance gentleness.
3, liquid detergent provided by the invention can reduce the cleaning water consumption, thereby reduces the use cost of liquid detergent article-cleaning.Liquid detergent provided by the invention mainly is made up of aniorfic surfactant and nonionic surface active agent, has increased the foam height of liquid detergent; And having increased the component of soap base in the liquid detergent, the adding of soap base can be played control bubble effect, reduces the height of foam, thereby can reduce the water consumption when article-cleaning, the conserve water resource.
4, liquid detergent provided by the invention and preparation method thereof has taken full advantage of discarded edible oil resource, has solved the problem of environmental pollution that brings because of discarded edible oil, can significantly reduce the manufacturing cost of liquid detergent simultaneously.Liquid detergent provided by the invention and preparation method thereof, the component of soap base and the weight percent of each component are: grease: 21-30%; Alkali: 10-15%; Dehydrated alcohol: 21-30%; Water: surplus.Wherein, grease in the preparation method of liquid detergent, at first will be discarded the edible oil purification process for the product of discarded edible oil purification process, and again with the grease production soap base behind the purifying, the grease after purified meets industrial requirement.Because adopting discarded edible oil as the raw material of producing liquid detergent, solved problems such as the present domestic environmental pollution that brings because of discarded edible oil, food safety, the utilization of discarded edible oil has simultaneously reduced the manufacturing cost of liquid detergent.
Embodiment
To the technical scheme in the embodiment of the invention be clearly and completely described below, obviously, described embodiment only is the present invention's part embodiment, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills belong to the scope of protection of the invention not making the every other embodiment that obtains under the creative work prerequisite.Embodiment 1
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 220 | 145 | 280 | 355 |
| Weight percent (%) | 22 | 14.5 | 28 | 35.5 |
Wherein, grease can be animal raw fat or vegetative grease; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.Soap base also can be the soap base of prior art in the market.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 82 ℃, wherein, stirring velocity is 275r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 28min, heating and temperature control is at 70 ℃; Stirring velocity is 290r/min;
Obtain the soap base finished product after c, the cooling.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 20.2%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 8.8, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 2
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 230 | 140 | 300 | 330 |
| Weight percent (%) | 23 | 14 | 30 | 33 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 80 ℃, wherein, stirring velocity is 295r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 35min, heating and temperature control is at 90 ℃; Stirring velocity is 295r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.089MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 21%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 8.6, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 3
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 250 | 125 | 250 | 375 |
| Weight percent (%) | 25 | 12.5 | 25 | 37.5 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 81 ℃, wherein, stirring velocity is 275r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 40min, heating and temperature control is at 88 ℃; Stirring velocity is 300r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.085MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 22.4%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 8.5, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 4
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 210 | 150 | 240 | 400 |
| Weight percent (%) | 21 | 15 | 24 | 40 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 84 ℃, wherein, stirring velocity is 320r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 20min, heating and temperature control is at 78 ℃; Stirring velocity is 275r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.09MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 20.5%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 9, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 5
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 280 | 100 | 260 | 360 |
| Weight percent (%) | 28 | 10 | 26 | 36 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 85 ℃, wherein, stirring velocity is 305r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 25min, heating and temperature control is at 75 ℃; Stirring velocity is 270r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.095MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 20.8%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 8.1, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 6
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 270 | 110 | 210 | 410 |
| Weight percent (%) | 27 | 11 | 21 | 41 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 83 ℃, wherein, stirring velocity is 285r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 37min, heating and temperature control is at 85 ℃; Stirring velocity is 320r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.092MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 20%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 8.2, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 7
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 240 | 115 | 220 | 425 |
| Weight percent (%) | 24 | 11.5 | 22 | 42.5 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 85 ℃, wherein, stirring velocity is 280r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 36min, heating and temperature control is at 82 ℃; Stirring velocity is 290r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.098MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 21.5%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 8.3, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 8
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 290 | 135 | 270 | 305 |
| Weight percent (%) | 29 | 13.5 | 27 | 30.5 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 81 ℃, wherein, stirring velocity is 275r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 28min, heating and temperature control is at 83 ℃; Stirring velocity is 310r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.082MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 21.3%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 8.6, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 9
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 260 | 120 | 290 | 330 |
| Weight percent (%) | 26 | 12 | 29 | 33 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 80 ℃, wherein, stirring velocity is 310r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 39min, heating and temperature control is at 88 ℃; Stirring velocity is 288r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.088MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 22%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is 8.5, the performance gentleness of liquid detergent, not skin irritation; The good stability of liquid detergent is placed 24h in the refrigerator of (5 ± 2) ℃, take out when returning to room temperature and observe, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Embodiment 10
The component of liquid detergent and the weight percent of each component are: (gross weight is: 1kg)
Wherein, the weight percent of the composition of soap base and a component is: (gross weight is: 1Kg)
| Component | Grease | Alkali | Dehydrated alcohol | Water |
| Weight (g) | 300 | 130 | 230 | 340 |
| Weight percent (%) | 30 | 13 | 23 | 34 |
Wherein, grease is the product of discarded edible oil purification process; Alkali can be common alkali such as sodium hydroxide, potassium hydroxide, yellow soda ash.
The preparation method of liquid detergent is:
A, the component of above-mentioned liquid detergent is mixed according to the above ratio;
B, stir and be heated to 85 ℃, wherein, stirring velocity is 293r/min;
Obtain the liquid detergent finished product after c, the cooling.
Wherein, the preparation method of soap base is:
A, grease, alkali, dehydrated alcohol and water are mixed according to the above ratio;
B, stirring and heating 30min, heating and temperature control is at 74 ℃; Stirring velocity is 275r/min;
Obtain the soap base finished product after c, the cooling.
Discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; Vacuum tightness is 0.080MPa.
By the liquid detergent that above-mentioned preparation method obtains, free from extraneous odour, no suspended substance or precipitation.Do not have after testing, active matter content is 20.5%, strong detergency; Under 25 ℃ of conditions, the liquid detergent pH value of 0.1% concentration is to place 24h in 8.7, takes out when returning to room temperature and observes, and is not stratified, do not have precipitation, and product is transparent not muddy; In the insulation can of (40 ± 2) ℃, place 24h, take out and observe, not stratified, there is not precipitation, product is transparent not muddy.
After testing, the methyl alcohol in every 1g liquid detergent, the content of formaldehyde are respectively less than 0.1mg, and the total number of bacterial colony in every 1g liquid detergent is less than 10; Heavy metal content all meets the Liquid soap standard-required; Do not detect white dyes and intestinal bacteria in this liquid detergent.
Liquid detergent provided by the invention, after testing, every index all meets the standard of GB9985-2000 " manual dishwashing washing composition ".
The above only is preferred embodiment of the present invention, not in order to limiting the present invention, all any modifications of doing, is equal to replacement etc. in protection scope of the present invention, all should be included within protection scope of the present invention.
Claims (10)
1. a liquid detergent is characterized in that, the component of described liquid detergent and the weight percent of each component are:
Soap base: 12-18%;
Polyoxyethylenated alcohol sodium sulfate: 6-10%;
Cocoanut fatty acid diethanolamide: 1-4%;
Aliphatic alcohol polyethenoxy (9) ether: 5-10%;
Essence: 0.01-0.5%;
Pigment: 0.01-0.5%;
Water: surplus.
2. liquid detergent according to claim 1 is characterized in that, the component of described liquid detergent and the weight percent of each component are:
Soap base: 14-16%;
Polyoxyethylenated alcohol sodium sulfate: 7.5-8.5%;
Cocoanut fatty acid diethanolamide: 1.5-2.8%;
Aliphatic alcohol polyethenoxy (9) ether: 7-8.5%;
Essence: 0.01-0.5%;
Pigment: 0.01-0.5%;
Water: surplus.
3. liquid detergent according to claim 1 is characterized in that, the component of described soap base and the weight percent of each component are:
Grease: 21-30%;
Alkali: 10-15%;
Dehydrated alcohol: 21-30%;
Water: surplus.
4. liquid detergent according to claim 3 is characterized in that, described grease is the product of discarded edible oil purification process technology.
5. liquid detergent according to claim 4 is characterized in that, described discarded edible oil purification process technology is: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; The vacuum tightness of described vacuum filtration step is 0.080～0.098MPa.
6. liquid detergent according to claim 3 is characterized in that, the preparation method of described soap base is as follows:
A, grease, alkali, dehydrated alcohol and water are mixed in proportion;
B, stirring and heating 20-40min, heating and temperature control is at 70-90 ℃;
Obtain the soap base finished product after c, the cooling.
7. the preparation method of a liquid detergent is characterized in that, described preparation method's step is as follows:
A, the component of each described liquid detergent in the claim 1 to 4 is mixed in proportion;
B, stir and be heated to 80-85 ℃;
Obtain the liquid detergent finished product after c, the cooling.
8. the preparation method of liquid detergent according to claim 7 is characterized in that, comprises the preparation method of soap base among the described preparation method, and the preparation method of described soap base is as follows:
A, grease, alkali, dehydrated alcohol and water are mixed in proportion;
B, stirring and heating 20-40min, heating and temperature control is at 70-90 ℃;
Obtain the soap base finished product after c, the cooling.
9. the preparation method of liquid detergent according to claim 8 is characterized in that, described stirring velocity is 270-320r/min.
10. the preparation method of liquid detergent according to claim 8 is characterized in that, comprises the preparation method of grease among the described preparation method: will discard edible oil and pour in the B that is equipped with 2-5 layer gauze, vacuum filtration obtains the grease after the purification process; The vacuum tightness of described vacuum filtration step is 0.080～0.098MPa.
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| CN2013101348934A CN103205333A (en) | 2013-04-17 | 2013-04-17 | Detergent and preparation method thereof |
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| CN2013101348934A CN103205333A (en) | 2013-04-17 | 2013-04-17 | Detergent and preparation method thereof |
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| CN106318739A (en) * | 2016-08-24 | 2017-01-11 | 祝家程 | Dishwashing liquid |
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| CN108485850A (en) * | 2018-04-09 | 2018-09-04 | 广州市浪奇实业股份有限公司 | A kind of kitchen greasy dirt cleaning agent and preparation method thereof |
| CN108559677A (en) * | 2018-06-01 | 2018-09-21 | 湖南中禹利晟环保科技有限公司 | A kind of concentrated type liquid detergent and preparation method thereof |
| CN112680298A (en) * | 2021-01-04 | 2021-04-20 | 广东药科大学 | Tableware detergent and laundry detergent taking soapstock as raw material and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318739A (en) * | 2016-08-24 | 2017-01-11 | 祝家程 | Dishwashing liquid |
| CN106350329A (en) * | 2016-08-24 | 2017-01-25 | 祝家程 | Oil-removing detergent |
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| CN108559677A (en) * | 2018-06-01 | 2018-09-21 | 湖南中禹利晟环保科技有限公司 | A kind of concentrated type liquid detergent and preparation method thereof |
| CN112680298A (en) * | 2021-01-04 | 2021-04-20 | 广东药科大学 | Tableware detergent and laundry detergent taking soapstock as raw material and preparation method thereof |
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Application publication date: 20130717 |