CN108559677A - A kind of concentrated type liquid detergent and preparation method thereof - Google Patents
A kind of concentrated type liquid detergent and preparation method thereof Download PDFInfo
- Publication number
- CN108559677A CN108559677A CN201810558647.4A CN201810558647A CN108559677A CN 108559677 A CN108559677 A CN 108559677A CN 201810558647 A CN201810558647 A CN 201810558647A CN 108559677 A CN108559677 A CN 108559677A
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- liquid detergent
- type liquid
- concentrated type
- soap base
- surfactant
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The present invention provides a kind of concentrated type liquid detergent, and raw material is calculated in mass percent comprising following components：Soap base 15 20%, anion surfactant 35 45%, amphoteric surfactant 7 15%, nonionic surfactant 8 13%, essence 0.2%, viscosity modifier 0.1 0.3%, emollient 0.5 2% and excess water；The soap base is made using kitchen garbage extraction；The viscosity modifier is modified polyurea compound.Concentrated type liquid detergent using the present invention, soap base are made by rubbish from cooking, and the dosage of viscosity modifier is small, at low cost；Rubbish from cooking is rationally utilized, it is environmental-friendly；Integral formula is at low cost, and washing effect is good.Invention additionally discloses a kind of production method of above-mentioned concentrated type liquid detergent, step is simplified, and technique is easy to control, and is suitable for industrialized production.
Description
Technical field
The present invention relates to detergents and cosmetic technical fields, particularly, are related to a kind of concentrated type liquid detergent and preparation method thereof.
Background technology
Contain a large amount of edible oil and fat, statistics display inside kitchen castoff, China's kitchen garbage accounts for domestic waste
Proportion approximate range be 37%-62%, Chinese main cities generate every year kitchen garbage be not less than 6000 tons, this kind of rubbish is not
Only become a kind of environmental contaminants, more impacts food security.
Liquid detergent is used for fine purifiation tableware, water fruits and vegetables etc., and the performance of product directly influences the health of the mankind.Commonly
A large amount of water is added in liquid detergent in process of production, and to ensure, liquid detergent has lower viscosity with easy to use in use,
Cause the effective ingredient of liquid detergent itself not high；In addition, liquid detergent, which is used for a long time, can lead to pachylosis, or even cracking；Contain
Family has the sewage of detergent to be just discharged into water body without processing, easily causes water body environment pollution.
There are many kinds of class liquid detergents in the prior art, but these liquid detergents cannot take into account cost and washing effect.Therefore,
A kind of liquid detergent at low cost, that washing effect is good is developed to be of great significance.
Invention content
The first object of the present invention is to provide a kind of liquid detergent at low cost, washing effect is good, and specific technical solution is such as
Under：
A kind of concentrated type liquid detergent, raw material are calculated in mass percent comprising following components：Soap base 15-20%, anion table
Face activating agent 35-45%, amphoteric surfactant 7-15%, nonionic surfactant 8-13%, essence 0.2%, viscosity tune
Save agent 0.1-0.3%, emollient 0.5-2% and excess water；
The soap base is made using kitchen garbage extraction；
The viscosity modifier is modified polyurea compound, and the relative molecular mass of the polyurea compound is not less than
4100, solid content is more than or equal to 50%, NH contents and is more than or equal to 3%.
Preferred in above technical scheme, the production method of the soap base includes the following steps：
Step A, grease, alkali, absolute ethyl alcohol and water are mixed to get mixture in proportion, in terms of weight fraction grease, alkali,
The proportioning of absolute ethyl alcohol and water is 200：110：250：440；The alkali is at least one of sodium hydroxide and potassium hydroxide；
Step B, 30min is stirred the mixture for and heats, heating temperature is 85 DEG C, mixing speed 300r/min；
Step C, soap base is obtained after cooling.
Preferred in above technical scheme, the preparation method of the grease in the step A is：Take a certain amount of kitchen rubbish
Rubbish, sonic oscillation 5min after it is beaten by mechanical agitation take upper layer edible oil and fat to be put into flask after standing 6h, are added one
Quantitative activated carbon is heated with stirring to 80 DEG C of holding 30min, is filtered under diminished pressure while hot with gauze, grease is obtained after filtering；The meal
The quality proportioning of kitchen rubbish and activated carbon is 50：1.
Preferred in above technical scheme, the anion surfactant is lauroyl sodium isethionate, hexadecane
At least one of base benzene sulfonic acid sodium salt and dodecyl alcohol polyoxyethylene ether sodium sulfate；The amphoteric surfactant is Zou oil
At least one of base imidazoline, Zou oleamide propyl-dimethyl glycine betaines and dodecyl dimethyl azochlorosulfonate propyl lycine；
The nonionic surfactant is：In alkyl glycosides, Zou fatty acid oils diglycollic amide and Zou fatty acid oil monoethanolamine
At least one；The essence is at least one of Flos Lonicerae extractive solution, gardenia extracting solution and sweet osmanthus extracting solution；It is described
Emollient is glycerine.
Preferred in above technical scheme, the preparation method of the modified polyurea compound is：Under stiring successively
Hydroxylated acrylic resin, solvent, hexa-methylene -1,6- diisocyanate is added, with water-bath cooling to 10 DEG C hereinafter, being stirred to react
3 hours up to modified polyurea compound, wherein：Stir speed (S.S.) is 100-300r/min.
Using the liquid detergent of the present invention, effect is：Soap base of the present invention be using kitchen garbage extract prepare and
, resource recycling；A kind of polyurea compound for modification that the present invention uses is as viscosity modifier, and dosage is few, effect
Obviously, the addition of viscosity modifier can significantly reduce liquid detergent concentrate viscosity (modified polyurea compound in system with wash
Clean essence main component forms the strong effect of hydrogen, there is good thixotropy under the action of shearing force：If shearing force disappears, hydrogen bond is very
Fast to be formed, viscosity ligament increases, and therefore, in the case of opposing stationary, can enhance the viscosity of system, that is, in the case of measuring less
Can play the role of regulation system viscosity), the effective component content of unit volume liquid detergent is improved, liquid detergent stoste is reduced
The content of middle water；The present invention is using quality-high and inexpensive and environmental-friendly raw material glycerine, at low cost, heat preservation soothing effect
It is good；The present invention is as a complete technical solution, with the good feature of at low cost, environmental-friendly and washing effect.
The invention also discloses a kind of preparation method of above-mentioned concentrated type liquid detergent, by soap base, anion surfactant,
Amphoteric surfactant, nonionic surfactant, essence, viscosity modifier, emollient and excess water mix in proportion；It stirs
It mixes and is heated to 75-80 DEG C；Concentrated type liquid detergent is obtained after cooling, wherein stir speed (S.S.) is 100-300r/min, heat temperature raising speed
Rate is 2-5 DEG C/min.Preparation method step of the present invention is simplified, and technique is easy to control, and is suitable for industrialized production.
Other than objects, features and advantages described above, the present invention also has other objects, features and advantages.
Below with reference to embodiment, the present invention is described in further detail.
Specific implementation mode
Technical scheme of the present invention is described in detail with reference to embodiments, but the present invention can be wanted according to right
The multitude of different ways of restriction and covering is asked to implement.
Embodiment 1：
A kind of concentrated type liquid detergent, raw material are calculated in mass percent comprising following components (total amount 1000g)：Soap base 150g,
Anion surfactant 400g, amphoteric surfactant 100g, nonionic surfactant 100g, essence 2g, viscosity-adjusting agent
Agent 2g, emollient 20g and water 226g.
The anion surfactant is lauroyl sodium isethionate, cetyl benzenesulfonic acid sodium and dodecyl
At least one of alcohol polyethenoxy ether sodium sulfate；The amphoteric surfactant is Zou oil-based imidazolines, Zou oleamide propyl
At least one of dimethyl betaine and dodecyl dimethyl azochlorosulfonate propyl lycine；The nonionic surfactant
For：At least one of alkyl glycosides, Zou fatty acid oils diglycollic amide and Zou fatty acid oil monoethanolamine；The essence is
At least one of Flos Lonicerae extractive solution, gardenia extracting solution and sweet osmanthus extracting solution；The emollient is glycerine.
The soap base is made using kitchen garbage extraction, specifically includes following steps：Step A, by grease, alkali, anhydrous second
Alcohol and water is mixed to get mixture in proportion, in terms of weight fraction grease, alkali, absolute ethyl alcohol and water proportioning be 200：110：
250：440；The alkali is sodium hydroxide；Step B, 30min is stirred the mixture for and heats, heating temperature is 85 DEG C, stirring speed
Degree is 300r/min；Step C, soap base is obtained after cooling.
The preparation method of grease in above-mentioned steps A is：A certain amount of kitchen garbage is taken, it is beaten by mechanical agitation
Sonic oscillation 5min afterwards takes upper layer edible oil and fat to be put into flask, a certain amount of activated carbon is added, is heated with stirring to after standing 6h
80 DEG C of holding 30min, are filtered under diminished pressure with gauze, grease are obtained after filtering while hot；The quality of the kitchen garbage and activated carbon is matched
Than being 50：1.
The viscosity modifier is modified polyurea compound, and the relative molecular mass of the polyurea compound is not less than
4100, solid content is more than or equal to 50%, NH contents and is more than or equal to 3%；The preparation method of the modified polyurea compound is：
Hydroxylated acrylic resin, solvent (Bian ammonia) and hexa-methylene -1,6- diisocyanate are sequentially added under stiring, use water-bath cooling
To 10 DEG C hereinafter, being stirred to react 3 hours up to modified polyurea compound, wherein：Stir speed (S.S.) is 100-300r/min.
The production method of concentrated type liquid detergent described in the present embodiment, specifically：By soap base, anion surfactant, two
Property surfactant, nonionic surfactant, essence, viscosity modifier, emollient and excess water mix in proportion；Stirring
It is heated to 75-80 DEG C；Concentrated type liquid detergent is obtained after cooling, wherein stir speed (S.S.) is 100-300r/min, heating ramp rate
For 2-5 DEG C/min.
The liquid detergent obtained by above-mentioned preparation method has pleasant fragrance, no suspended substance or precipitation.
After testing, active matter content 60%, dirt-removing power are strong；Under the conditions of 25 DEG C, the liquid detergent pH value of 0.1% concentration
It is 8.5, the performance for washing essence essence is mild, does not stimulate skin, and plays the role of protecting hand skin；Liquid detergent stability is good, at 5 DEG C
It is placed in refrigerator for 24 hours, taking-up is observed when being restored to room temperature, not stratified, no precipitation, and product is transparent limpid.Further detection, per 1g
The content of methanol, formaldehyde in liquid detergent is respectively less than 1mg, and content of beary metal, total plate count meet the requirement of hand cleanser standard.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, any made by repair
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of concentrated type liquid detergent, it is characterised in that：Raw material is calculated in mass percent comprising following components：Soap base 15-20%,
Anion surfactant 35-45%, amphoteric surfactant 7-15%, nonionic surfactant 8-13%, essence
0.2%, viscosity modifier 0.1-0.3%, emollient 0.5-2% and excess water；
The soap base is made using kitchen garbage extraction；
The viscosity modifier is modified polyurea compound, and the relative molecular mass of the polyurea compound is not less than
4100, solid content is more than or equal to 50%, NH contents and is more than or equal to 3%.
2. concentrated type liquid detergent according to claim 1, it is characterised in that：The production method of the soap base includes following step
Suddenly：
Step A, grease, alkali, absolute ethyl alcohol and water are mixed to get mixture in proportion, the grease, alkali, anhydrous in terms of weight fraction
The proportioning of second alcohol and water is 200：110：250：440；The alkali is at least one of sodium hydroxide and potassium hydroxide；
Step B, 30min is stirred the mixture for and heats, heating temperature is 85 DEG C, mixing speed 300r/min；
Step C, soap base is obtained after cooling.
3. concentrated type liquid detergent according to claim 2, it is characterised in that：The preparation method of grease in the step A
It is：A certain amount of kitchen garbage is taken, sonic oscillation 5min after it is beaten by mechanical agitation takes upper layer edible oil after standing 6h
Fat is put into flask, and a certain amount of activated carbon is added, and is heated with stirring to 80 DEG C of holding 30min, is filtered under diminished pressure while hot with gauze, mistake
Grease is obtained after filter；The quality proportioning of the kitchen garbage and activated carbon is 50：1.
4. concentrated type liquid detergent according to claim 1, it is characterised in that：The anion surfactant is lauroyl
At least one of sodium isethionate, cetyl benzenesulfonic acid sodium and dodecyl alcohol polyoxyethylene ether sodium sulfate；It is described
Amphoteric surfactant is Zou oil-based imidazolines, Zou oleamide propyl-dimethyl glycine betaines and dodecyl dimethyl sulfopropyl
At least one of glycine betaine；The nonionic surfactant is：Alkyl glycosides, Zou fatty acid oils diglycollic amide and Zou
At least one of fatty acid oil monoethanolamine；The essence is Flos Lonicerae extractive solution, gardenia extracting solution and sweet osmanthus extraction
At least one of liquid；The emollient is glycerine.
5. concentrated type liquid detergent according to any one of claims 1-4, it is characterised in that：The modified polyureas
Closing the preparation method of object is：Hydroxylated acrylic resin, solvent, hexa-methylene -1,6- diisocyanate are sequentially added under stiring,
With water-bath cooling to 10 DEG C hereinafter, be stirred to react 3 hours up to modified polyurea compound, wherein：Stir speed (S.S.) is 100-
300r/min。
6. a kind of production method of concentrated type liquid detergent as described in claim 1-5 any one, it is characterised in that：By soap
Base, anion surfactant, amphoteric surfactant, nonionic surfactant, essence, viscosity modifier, emollient with
And excess water mixes in proportion；It is heated with stirring to 75-80 DEG C；Concentrated type liquid detergent is obtained after cooling, wherein stir speed (S.S.) is
100-300r/min, heating ramp rate are 2-5 DEG C/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810558647.4A CN108559677A (en) | 2018-06-01 | 2018-06-01 | A kind of concentrated type liquid detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810558647.4A CN108559677A (en) | 2018-06-01 | 2018-06-01 | A kind of concentrated type liquid detergent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108559677A true CN108559677A (en) | 2018-09-21 |
Family
ID=63552843
Family Applications (1)
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| CN201810558647.4A Pending CN108559677A (en) | 2018-06-01 | 2018-06-01 | A kind of concentrated type liquid detergent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111286424A (en) * | 2018-12-06 | 2020-06-16 | 南风化工集团股份有限公司 | Super-concentrated detergent composition |
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| CN101815744A (en) * | 2007-08-14 | 2010-08-25 | 迈图高新材料有限责任公司 | Novel polyurea- and/or polyurethane-polyorganosiloxane compounds |
| CN103194338A (en) * | 2013-04-17 | 2013-07-10 | 武汉创新资源环保循环有限公司 | Hand sanitizer and preparation method thereof |
| CN103205333A (en) * | 2013-04-17 | 2013-07-17 | 武汉创新资源环保循环有限公司 | Detergent and preparation method thereof |
| CN103255010A (en) * | 2013-04-17 | 2013-08-21 | 武汉创新资源环保循环有限公司 | Dishwashing liquid and preparation method thereof |
| CN105400624A (en) * | 2015-12-11 | 2016-03-16 | 谭海涛 | High-efficiency oil-removing washing detergent |
| CN105886146A (en) * | 2016-06-01 | 2016-08-24 | 茗燕生物科技(上海)有限公司 | Environment-friendly hyper-concentrated liquid detergent tablets/particles and preparing method thereof |
| CN105878056A (en) * | 2014-12-05 | 2016-08-24 | 江南大学 | Mild and moist soap-based shower gel |
| CN106350329A (en) * | 2016-08-24 | 2017-01-25 | 祝家程 | Oil-removing detergent |
-
2018
- 2018-06-01 CN CN201810558647.4A patent/CN108559677A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101815744A (en) * | 2007-08-14 | 2010-08-25 | 迈图高新材料有限责任公司 | Novel polyurea- and/or polyurethane-polyorganosiloxane compounds |
| CN103194338A (en) * | 2013-04-17 | 2013-07-10 | 武汉创新资源环保循环有限公司 | Hand sanitizer and preparation method thereof |
| CN103205333A (en) * | 2013-04-17 | 2013-07-17 | 武汉创新资源环保循环有限公司 | Detergent and preparation method thereof |
| CN103255010A (en) * | 2013-04-17 | 2013-08-21 | 武汉创新资源环保循环有限公司 | Dishwashing liquid and preparation method thereof |
| CN105878056A (en) * | 2014-12-05 | 2016-08-24 | 江南大学 | Mild and moist soap-based shower gel |
| CN105400624A (en) * | 2015-12-11 | 2016-03-16 | 谭海涛 | High-efficiency oil-removing washing detergent |
| CN105886146A (en) * | 2016-06-01 | 2016-08-24 | 茗燕生物科技(上海)有限公司 | Environment-friendly hyper-concentrated liquid detergent tablets/particles and preparing method thereof |
| CN106350329A (en) * | 2016-08-24 | 2017-01-25 | 祝家程 | Oil-removing detergent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111286424A (en) * | 2018-12-06 | 2020-06-16 | 南风化工集团股份有限公司 | Super-concentrated detergent composition |
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Application publication date: 20180921 |