CN108559677A - A kind of concentrated type liquid detergent and preparation method thereof - Google Patents
A kind of concentrated type liquid detergent and preparation method thereof Download PDFInfo
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- CN108559677A CN108559677A CN201810558647.4A CN201810558647A CN108559677A CN 108559677 A CN108559677 A CN 108559677A CN 201810558647 A CN201810558647 A CN 201810558647A CN 108559677 A CN108559677 A CN 108559677A
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- Prior art keywords
- liquid detergent
- type liquid
- concentrated type
- soap base
- surfactant
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- 239000003599 detergent Substances 0.000 title claims abstract description 38
- 239000007788 liquid Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims description 12
- 239000000344 soap Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000010813 municipal solid waste Substances 0.000 claims abstract description 17
- 229920002396 Polyurea Polymers 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000004034 viscosity adjusting agent Substances 0.000 claims abstract description 13
- 239000003974 emollient agent Substances 0.000 claims abstract description 10
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 9
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 238000000605 extraction Methods 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000002585 base Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000004519 grease Substances 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- -1 dodecyl dimethyl sulfopropyl Chemical group 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- 239000008157 edible vegetable oil Substances 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 241000628997 Flos Species 0.000 claims description 3
- 240000001972 Gardenia jasminoides Species 0.000 claims description 3
- 244000242564 Osmanthus fragrans Species 0.000 claims description 3
- 235000019083 Osmanthus fragrans Nutrition 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 230000003292 diminished effect Effects 0.000 claims description 3
- 239000000686 essence Substances 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- 229930182470 glycoside Natural products 0.000 claims description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 3
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 3
- 230000010355 oscillation Effects 0.000 claims description 3
- 229940045998 sodium isethionate Drugs 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- JYTNGEWJAZCVAN-UHFFFAOYSA-N 2-hexadecylbenzenesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O JYTNGEWJAZCVAN-UHFFFAOYSA-N 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 2
- 150000002462 imidazolines Chemical class 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- LADXKQRVAFSPTR-UHFFFAOYSA-M sodium;2-hydroxyethanesulfonate Chemical compound [Na+].OCCS([O-])(=O)=O LADXKQRVAFSPTR-UHFFFAOYSA-M 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 238000005406 washing Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 3
- 238000010411 cooking Methods 0.000 abstract 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FXALIOUHXMVTMJ-UHFFFAOYSA-N CCCCCCCCCCCC([Na])=O Chemical group CCCCCCCCCCCC([Na])=O FXALIOUHXMVTMJ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000021393 food security Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 210000003041 ligament Anatomy 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of concentrated type liquid detergent, and raw material is calculated in mass percent comprising following components：Soap base 15 20%, anion surfactant 35 45%, amphoteric surfactant 7 15%, nonionic surfactant 8 13%, essence 0.2%, viscosity modifier 0.1 0.3%, emollient 0.5 2% and excess water；The soap base is made using kitchen garbage extraction；The viscosity modifier is modified polyurea compound.Concentrated type liquid detergent using the present invention, soap base are made by rubbish from cooking, and the dosage of viscosity modifier is small, at low cost；Rubbish from cooking is rationally utilized, it is environmental-friendly；Integral formula is at low cost, and washing effect is good.Invention additionally discloses a kind of production method of above-mentioned concentrated type liquid detergent, step is simplified, and technique is easy to control, and is suitable for industrialized production.
Description
Technical field
The present invention relates to detergents and cosmetic technical fields, particularly, are related to a kind of concentrated type liquid detergent and preparation method thereof.
Background technology
Contain a large amount of edible oil and fat, statistics display inside kitchen castoff, China's kitchen garbage accounts for domestic waste
Proportion approximate range be 37%-62%, Chinese main cities generate every year kitchen garbage be not less than 6000 tons, this kind of rubbish is not
Only become a kind of environmental contaminants, more impacts food security.
Liquid detergent is used for fine purifiation tableware, water fruits and vegetables etc., and the performance of product directly influences the health of the mankind.Commonly
A large amount of water is added in liquid detergent in process of production, and to ensure, liquid detergent has lower viscosity with easy to use in use,
Cause the effective ingredient of liquid detergent itself not high；In addition, liquid detergent, which is used for a long time, can lead to pachylosis, or even cracking；Contain
Family has the sewage of detergent to be just discharged into water body without processing, easily causes water body environment pollution.
There are many kinds of class liquid detergents in the prior art, but these liquid detergents cannot take into account cost and washing effect.Therefore,
A kind of liquid detergent at low cost, that washing effect is good is developed to be of great significance.
Invention content
The first object of the present invention is to provide a kind of liquid detergent at low cost, washing effect is good, and specific technical solution is such as
Under：
A kind of concentrated type liquid detergent, raw material are calculated in mass percent comprising following components：Soap base 15-20%, anion table
Face activating agent 35-45%, amphoteric surfactant 7-15%, nonionic surfactant 8-13%, essence 0.2%, viscosity tune
Save agent 0.1-0.3%, emollient 0.5-2% and excess water；
The soap base is made using kitchen garbage extraction；
The viscosity modifier is modified polyurea compound, and the relative molecular mass of the polyurea compound is not less than
4100, solid content is more than or equal to 50%, NH contents and is more than or equal to 3%.
Preferred in above technical scheme, the production method of the soap base includes the following steps：
Step A, grease, alkali, absolute ethyl alcohol and water are mixed to get mixture in proportion, in terms of weight fraction grease, alkali,
The proportioning of absolute ethyl alcohol and water is 200：110：250：440；The alkali is at least one of sodium hydroxide and potassium hydroxide；
Step B, 30min is stirred the mixture for and heats, heating temperature is 85 DEG C, mixing speed 300r/min；
Step C, soap base is obtained after cooling.
Preferred in above technical scheme, the preparation method of the grease in the step A is：Take a certain amount of kitchen rubbish
Rubbish, sonic oscillation 5min after it is beaten by mechanical agitation take upper layer edible oil and fat to be put into flask after standing 6h, are added one
Quantitative activated carbon is heated with stirring to 80 DEG C of holding 30min, is filtered under diminished pressure while hot with gauze, grease is obtained after filtering；The meal
The quality proportioning of kitchen rubbish and activated carbon is 50：1.
Preferred in above technical scheme, the anion surfactant is lauroyl sodium isethionate, hexadecane
At least one of base benzene sulfonic acid sodium salt and dodecyl alcohol polyoxyethylene ether sodium sulfate；The amphoteric surfactant is Zou oil
At least one of base imidazoline, Zou oleamide propyl-dimethyl glycine betaines and dodecyl dimethyl azochlorosulfonate propyl lycine；
The nonionic surfactant is：In alkyl glycosides, Zou fatty acid oils diglycollic amide and Zou fatty acid oil monoethanolamine
At least one；The essence is at least one of Flos Lonicerae extractive solution, gardenia extracting solution and sweet osmanthus extracting solution；It is described
Emollient is glycerine.
Preferred in above technical scheme, the preparation method of the modified polyurea compound is：Under stiring successively
Hydroxylated acrylic resin, solvent, hexa-methylene -1,6- diisocyanate is added, with water-bath cooling to 10 DEG C hereinafter, being stirred to react
3 hours up to modified polyurea compound, wherein：Stir speed (S.S.) is 100-300r/min.
Using the liquid detergent of the present invention, effect is：Soap base of the present invention be using kitchen garbage extract prepare and
, resource recycling；A kind of polyurea compound for modification that the present invention uses is as viscosity modifier, and dosage is few, effect
Obviously, the addition of viscosity modifier can significantly reduce liquid detergent concentrate viscosity (modified polyurea compound in system with wash
Clean essence main component forms the strong effect of hydrogen, there is good thixotropy under the action of shearing force：If shearing force disappears, hydrogen bond is very
Fast to be formed, viscosity ligament increases, and therefore, in the case of opposing stationary, can enhance the viscosity of system, that is, in the case of measuring less
Can play the role of regulation system viscosity), the effective component content of unit volume liquid detergent is improved, liquid detergent stoste is reduced
The content of middle water；The present invention is using quality-high and inexpensive and environmental-friendly raw material glycerine, at low cost, heat preservation soothing effect
It is good；The present invention is as a complete technical solution, with the good feature of at low cost, environmental-friendly and washing effect.
The invention also discloses a kind of preparation method of above-mentioned concentrated type liquid detergent, by soap base, anion surfactant,
Amphoteric surfactant, nonionic surfactant, essence, viscosity modifier, emollient and excess water mix in proportion；It stirs
It mixes and is heated to 75-80 DEG C；Concentrated type liquid detergent is obtained after cooling, wherein stir speed (S.S.) is 100-300r/min, heat temperature raising speed
Rate is 2-5 DEG C/min.Preparation method step of the present invention is simplified, and technique is easy to control, and is suitable for industrialized production.
Other than objects, features and advantages described above, the present invention also has other objects, features and advantages.
Below with reference to embodiment, the present invention is described in further detail.
Specific implementation mode
Technical scheme of the present invention is described in detail with reference to embodiments, but the present invention can be wanted according to right
The multitude of different ways of restriction and covering is asked to implement.
Embodiment 1：
A kind of concentrated type liquid detergent, raw material are calculated in mass percent comprising following components (total amount 1000g)：Soap base 150g,
Anion surfactant 400g, amphoteric surfactant 100g, nonionic surfactant 100g, essence 2g, viscosity-adjusting agent
Agent 2g, emollient 20g and water 226g.
The anion surfactant is lauroyl sodium isethionate, cetyl benzenesulfonic acid sodium and dodecyl
At least one of alcohol polyethenoxy ether sodium sulfate；The amphoteric surfactant is Zou oil-based imidazolines, Zou oleamide propyl
At least one of dimethyl betaine and dodecyl dimethyl azochlorosulfonate propyl lycine；The nonionic surfactant
For：At least one of alkyl glycosides, Zou fatty acid oils diglycollic amide and Zou fatty acid oil monoethanolamine；The essence is
At least one of Flos Lonicerae extractive solution, gardenia extracting solution and sweet osmanthus extracting solution；The emollient is glycerine.
The soap base is made using kitchen garbage extraction, specifically includes following steps：Step A, by grease, alkali, anhydrous second
Alcohol and water is mixed to get mixture in proportion, in terms of weight fraction grease, alkali, absolute ethyl alcohol and water proportioning be 200：110：
250：440；The alkali is sodium hydroxide；Step B, 30min is stirred the mixture for and heats, heating temperature is 85 DEG C, stirring speed
Degree is 300r/min；Step C, soap base is obtained after cooling.
The preparation method of grease in above-mentioned steps A is：A certain amount of kitchen garbage is taken, it is beaten by mechanical agitation
Sonic oscillation 5min afterwards takes upper layer edible oil and fat to be put into flask, a certain amount of activated carbon is added, is heated with stirring to after standing 6h
80 DEG C of holding 30min, are filtered under diminished pressure with gauze, grease are obtained after filtering while hot；The quality of the kitchen garbage and activated carbon is matched
Than being 50：1.
The viscosity modifier is modified polyurea compound, and the relative molecular mass of the polyurea compound is not less than
4100, solid content is more than or equal to 50%, NH contents and is more than or equal to 3%；The preparation method of the modified polyurea compound is：
Hydroxylated acrylic resin, solvent (Bian ammonia) and hexa-methylene -1,6- diisocyanate are sequentially added under stiring, use water-bath cooling
To 10 DEG C hereinafter, being stirred to react 3 hours up to modified polyurea compound, wherein：Stir speed (S.S.) is 100-300r/min.
The production method of concentrated type liquid detergent described in the present embodiment, specifically：By soap base, anion surfactant, two
Property surfactant, nonionic surfactant, essence, viscosity modifier, emollient and excess water mix in proportion；Stirring
It is heated to 75-80 DEG C；Concentrated type liquid detergent is obtained after cooling, wherein stir speed (S.S.) is 100-300r/min, heating ramp rate
For 2-5 DEG C/min.
The liquid detergent obtained by above-mentioned preparation method has pleasant fragrance, no suspended substance or precipitation.
After testing, active matter content 60%, dirt-removing power are strong；Under the conditions of 25 DEG C, the liquid detergent pH value of 0.1% concentration
It is 8.5, the performance for washing essence essence is mild, does not stimulate skin, and plays the role of protecting hand skin；Liquid detergent stability is good, at 5 DEG C
It is placed in refrigerator for 24 hours, taking-up is observed when being restored to room temperature, not stratified, no precipitation, and product is transparent limpid.Further detection, per 1g
The content of methanol, formaldehyde in liquid detergent is respectively less than 1mg, and content of beary metal, total plate count meet the requirement of hand cleanser standard.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, any made by repair
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of concentrated type liquid detergent, it is characterised in that：Raw material is calculated in mass percent comprising following components：Soap base 15-20%,
Anion surfactant 35-45%, amphoteric surfactant 7-15%, nonionic surfactant 8-13%, essence
0.2%, viscosity modifier 0.1-0.3%, emollient 0.5-2% and excess water；
The soap base is made using kitchen garbage extraction；
The viscosity modifier is modified polyurea compound, and the relative molecular mass of the polyurea compound is not less than
4100, solid content is more than or equal to 50%, NH contents and is more than or equal to 3%.
2. concentrated type liquid detergent according to claim 1, it is characterised in that：The production method of the soap base includes following step
Suddenly：
Step A, grease, alkali, absolute ethyl alcohol and water are mixed to get mixture in proportion, the grease, alkali, anhydrous in terms of weight fraction
The proportioning of second alcohol and water is 200：110：250：440；The alkali is at least one of sodium hydroxide and potassium hydroxide；
Step B, 30min is stirred the mixture for and heats, heating temperature is 85 DEG C, mixing speed 300r/min；
Step C, soap base is obtained after cooling.
3. concentrated type liquid detergent according to claim 2, it is characterised in that：The preparation method of grease in the step A
It is：A certain amount of kitchen garbage is taken, sonic oscillation 5min after it is beaten by mechanical agitation takes upper layer edible oil after standing 6h
Fat is put into flask, and a certain amount of activated carbon is added, and is heated with stirring to 80 DEG C of holding 30min, is filtered under diminished pressure while hot with gauze, mistake
Grease is obtained after filter；The quality proportioning of the kitchen garbage and activated carbon is 50：1.
4. concentrated type liquid detergent according to claim 1, it is characterised in that：The anion surfactant is lauroyl
At least one of sodium isethionate, cetyl benzenesulfonic acid sodium and dodecyl alcohol polyoxyethylene ether sodium sulfate；It is described
Amphoteric surfactant is Zou oil-based imidazolines, Zou oleamide propyl-dimethyl glycine betaines and dodecyl dimethyl sulfopropyl
At least one of glycine betaine；The nonionic surfactant is：Alkyl glycosides, Zou fatty acid oils diglycollic amide and Zou
At least one of fatty acid oil monoethanolamine；The essence is Flos Lonicerae extractive solution, gardenia extracting solution and sweet osmanthus extraction
At least one of liquid；The emollient is glycerine.
5. concentrated type liquid detergent according to any one of claims 1-4, it is characterised in that：The modified polyureas
Closing the preparation method of object is：Hydroxylated acrylic resin, solvent, hexa-methylene -1,6- diisocyanate are sequentially added under stiring,
With water-bath cooling to 10 DEG C hereinafter, be stirred to react 3 hours up to modified polyurea compound, wherein：Stir speed (S.S.) is 100-
300r/min。
6. a kind of production method of concentrated type liquid detergent as described in claim 1-5 any one, it is characterised in that：By soap
Base, anion surfactant, amphoteric surfactant, nonionic surfactant, essence, viscosity modifier, emollient with
And excess water mixes in proportion；It is heated with stirring to 75-80 DEG C；Concentrated type liquid detergent is obtained after cooling, wherein stir speed (S.S.) is
100-300r/min, heating ramp rate are 2-5 DEG C/min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111286424A (en) * | 2018-12-06 | 2020-06-16 | 南风化工集团股份有限公司 | Super-concentrated detergent composition |
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Application publication date: 20180921 |