CN101457184B - Environment friendly dishwashing granule and preparation method thereof - Google Patents
Environment friendly dishwashing granule and preparation method thereof Download PDFInfo
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- CN101457184B CN101457184B CN2008102418191A CN200810241819A CN101457184B CN 101457184 B CN101457184 B CN 101457184B CN 2008102418191 A CN2008102418191 A CN 2008102418191A CN 200810241819 A CN200810241819 A CN 200810241819A CN 101457184 B CN101457184 B CN 101457184B
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Abstract
The invention discloses an environment friendly bowl washing particle mixed by a powder material A component and a liquid material B component, wherein the A component is formed by the following materials by weight percentage: 1-19. 71f powdered soap, 0. 5-16. 1146113000f alpha-alkenyl sodium sulfonate, 0. 3-7. 6145755700f sodium carboxymethyl cellulose, 0. 5-6. 7146401270f sodium tetraborate, 0.05-3. 40f sodium ethylene diamine tetracetate, 1. 6-27. 40f sodium citrate, 3. 2-35. 21f sodium carbonate, 6. 3-60. 54563614f calcium carbonate, 1. 6-20. 14563720f sodium metasilicate pentahydrate; the B component is formed by the following materials by weight percentage: 1-16. 416764762631f ethoxylated lauryl alcohol sulfate, 4. 7-19. 716647331716f alkyl polysaccharide glycoside, 0. 1-2. 316647331703f defoamer, 3. 4-454565500f epoxy adhesive, and 3. 4-450f epoxy resin curing agent. The invention also discloses a method for preparing the environment friendly bowl washing particle. The environment friendly bowl washing particle of the invention can be safely used for multi-times without toxic and have advantages of good biodegradability for the activity constituent and good cleaning effectfor the dishware.
Description
Technical field
The present invention relates to sanitary washing article, relate in particular to a kind of environment friendly dishwashing granule of cleaning by bowl, plate, plate and similar tableware and preparation method thereof that is used to.
Background technology
Because the develop rapidly of society, healthy and requirement on environmental protection improves people gradually to self; The aggravation of social competition also impels people's concept of time more and more stronger.In order to save the time of wash dining set, people have invented automatic bowl washing machine, and people are freed from heavy wash dining set.Because need adding detergent for tableware, automatic bowl washing machine could effectively clean, what people used at present is liquid detergent or Powdered cleaning agent, and its main component is chemical substances such as sodium alkyl benzene sulfonate, Fatty Alcohol(C12-C14 and C12-C18) ether sodium sulfate, foaming agent, solubilizing agent, essence, water, pigment.For the residual harm of liquid detergent, scientists was done a lot of animal experiments, and residual the accumulating over a long period of liquid detergent stays in the body, can be very unfavorable to HUMAN HEALTH; And the waste water after washing the dishes is unfavorable to environment, causes environmental pollution.
But human lives's urbanization is inevasible, and city life also is inevitable to the dependence of liquid detergent.So, improve and to wash clean articles for use, develop not harmful to human, do not destroy living environment, the non-toxic and non-pollution articles for use that wash the dishes just become the task of top priority.For dishwasher, all need to add liquid detergent or Powdered cleaning agent, troublesome poeration before each the use simultaneously.In addition, the liquid detergent of the present tableware that washes the dishes or Powdered cleaning agent all are disposable, still do not make reusable product.
Summary of the invention
Purpose of the present invention to solve existing washing composition to HUMAN HEALTH produce unfavorable, cause environmental pollution, troublesome poeration easily, the technical problem that use cost is high proposes that a kind of clean effect is good, environment-protecting asepsis, can repeatedly circulate and reuse and have a durothermic environment friendly dishwashing granule.
Another object of the present invention is the preparation method who proposes a kind of environment friendly dishwashing granule.
For achieving the above object, the environment friendly dishwashing granule that the present invention proposes is mixed by powder material A component and liquid material B component.Described A component is formed by the raw material configuration of following weight percentage:
Soap powder-1～19.7%, α-sodium olefin sulfonate-0.5～16.1%, Xylo-Mucine-0.3～7.6%, sodium tetraborate-0.5～6.7%, sodium ethylene diamine tetracetate-0.05～3.4%, Trisodium Citrate-1.6～27.4% yellow soda ash-3.2～35.2%, lime carbonate-6.3～60.5%, metasilicate pentahydrate sodium-1.6～20.1%;
Described B component is formed by the raw material configuration of following weight percentage:
Polyoxyethylenated alcohol sodium sulfate-1～16.4%, APG-4.7～19.7%, defoamer-0.1～2.3%, epoxy resin binder-3.4～45%, epoxy curing agent-3.4～45%.
Preferred version of the present invention, described A component is formed by the raw material configuration of following weight percentage:
Soap powder 5%, α-sodium olefin sulfonate 2%, Xylo-Mucine 1%, sodium tetraborate 1.5%, sodium ethylene diamine tetracetate 0.5%, Trisodium Citrate 8%, yellow soda ash 10%, lime carbonate 33%, metasilicate pentahydrate sodium 3.5%;
The B component is formed by the raw material configuration of following weight percentage:
Polyoxyethylenated alcohol sodium sulfate 4%, APG 5%, defoamer 0.5%, epoxy resin binder 13%, epoxy curing agent 13%.
The preparation method of environment friendly dishwashing granule of the present invention comprises the steps:
(1) with the material of described A component according to weight accurately weighing successively, put in the stirred vessel of sealing, mix;
(2) with the material of described B component according to weight accurately weighing successively, put into the stainless steel stirred vessel, mix;
Above-mentioned two steps also can carry out in no particular order simultaneously;
(3) then the B component material that mixes is poured in the airtight stirred vessel of the A component that stirs, restir mixes;
(4) mixture of taking-up A, B two components drops into the particle pellet processing machine, makes the circular granular of 4～15 millimeters of diameters;
(5) with the circular granular for preparing, put into the baking oven baking, tackiness agent solidifies the back and takes out.
Wherein, the agitating vane rotating speed of the material of described A component is 60r/min, stirs 6～20 minutes; The mixing speed of described B component is 150r/min, stirs 4～8 minutes; The mixture mixing speed of described A, B two components is 40r/min, stirs 6～15 minutes; The temperature of described baking oven baking is 40～70 ℃, toasts 4～10 hours.
Advantage of the present invention: the environment friendly dishwashing granule manufacture craft of the present invention's preparation is simple; Soil removability is strong, can be good at cleaning tableware, is particularly suitable for dishwasher and uses; Used activeconstituents and tackiness agent all adopt environment-friendly materials, and biological degradability is good, and safety non-toxic does not have harm substantially to human body and environment; Repeatedly recirculation is used, and is that a kind of people's of satisfying decontamination is strong, the Novel tableware clean-out system of environmental protection, health demand.
Embodiment
The environment friendly dishwashing granule that the present invention proposes is mixed by powder material A component and liquid material B component.Wherein the A component is formed by the raw material configuration of following weight percentage:
Soap powder-1～19.7%, α-sodium olefin sulfonate-0.5～16.1%, Xylo-Mucine-0.3～7.6%, sodium tetraborate-0.5～6.7%, sodium ethylene diamine tetracetate-0.05～3.4%, Trisodium Citrate-1.6～27.4% yellow soda ash-3.2～35.2%, lime carbonate-6.3～60.5%, metasilicate pentahydrate sodium-1.6～20.1%;
The B component is formed by the raw material configuration of following weight percentage:
Polyoxyethylenated alcohol sodium sulfate-1～16.4%, APG-4.7～19.7%, defoamer-0.1～2.3%, epoxy resin binder-3.4～45%, epoxy curing agent-3.4～45%.
In preferred version of the present invention, described A component is formed by the raw material configuration of following weight percentage:
Soap powder 5%, α-sodium olefin sulfonate 2%, Xylo-Mucine 1%, sodium tetraborate 1.5%, sodium ethylene diamine tetracetate 0.5%, Trisodium Citrate 8%, yellow soda ash 10%, lime carbonate 33%, metasilicate pentahydrate sodium 3.5%;
The B component is formed by the raw material configuration of following weight percentage:
Polyoxyethylenated alcohol sodium sulfate 4%, APG 5%, defoamer 0.5%, epoxy resin binder 13%, epoxy curing agent 13%.
The present invention will be further described below in conjunction with specific embodiment.According to prescription of the present invention, the environment friendly dishwashing granule of configuration 200 grams.
Embodiment 1 (optimum embodiment): raw material weight prescription:
The A component:
Soap powder: 10 grams; α-sodium olefin sulfonate: 4 grams; Xylo-Mucine: 2 grams; Sodium tetraborate: 3 grams; Sodium ethylene diamine tetracetate: 1 gram; Trisodium Citrate: 16 grams; Yellow soda ash: 20 grams; Lime carbonate: 66 grams; Metasilicate pentahydrate sodium: 7 grams.
The B component:
Polyoxyethylenated alcohol sodium sulfate: 8 grams; APG: 10 grams; Defoamer: 1 gram; Epoxy resin binder: 26 grams; Epoxy curing agent: 26 grams.
Embodiment 2: the raw material weight prescription:
The A component:
Soap powder: 8 grams; α-sodium olefin sulfonate: 6 grams; Xylo-Mucine: 2 grams; Sodium tetraborate: 3 grams; Sodium ethylene diamine tetracetate: 2 grams; Trisodium Citrate: 16 grams; Yellow soda ash: 16 grams; Lime carbonate: 70 grams; Metasilicate pentahydrate sodium: 6 grams.
The B component:
Polyoxyethylenated alcohol sodium sulfate: 5 grams; APG: 14 grams; Defoamer: 1 gram; Epoxy resin binder: 34 grams; Epoxy curing agent: 17 grams.
Embodiment 3: the raw material weight prescription:
The A component:
Soap powder: 7 grams; α-sodium olefin sulfonate: 8 grams; Xylo-Mucine: 1 gram; Sodium tetraborate: 6 grams; Sodium ethylene diamine tetracetate: 1 gram; Trisodium Citrate: 13 grams; Yellow soda ash: 26 grams; Lime carbonate: 60 grams; Metasilicate pentahydrate sodium: 7 grams.
The B component:
Polyoxyethylenated alcohol sodium sulfate: 10 grams; APG: 8 grams; Defoamer: 1 gram; Epoxy resin binder: 39 grams; Epoxy curing agent: 13 grams.
Embodiment 4: the raw material weight prescription:
The A component:
Soap powder: 12 grams; α-sodium olefin sulfonate: 6 grams; Xylo-Mucine: 2 grams; Sodium tetraborate: 4 grams; Sodium ethylene diamine tetracetate: 2 grams; Trisodium Citrate: 16 grams; Yellow soda ash: 20 grams; Lime carbonate: 56 grams; Metasilicate pentahydrate sodium: 7 grams.
The B component:
Polyoxyethylenated alcohol sodium sulfate: 10 grams; APG: 12 grams; Defoamer: 1 gram; Epoxy resin binder: 41.5 grams; Epoxy curing agent: 10.5 grams.
Embodiment 5: the raw material weight prescription:
The A component:
Soap powder: 8 grams; α-sodium olefin sulfonate: 4 grams; Xylo-Mucine: 1 gram; Sodium tetraborate: 3 grams; Sodium ethylene diamine tetracetate: 1 gram; Trisodium Citrate: 16 grams; Yellow soda ash: 17 grams; Lime carbonate: 70 grams; Metasilicate pentahydrate sodium: 11 grams.
The B component:
Polyoxyethylenated alcohol sodium sulfate: 8 grams; APG: 8 grams; Defoamer: 1 gram; Epoxy resin binder: 43 grams; Epoxy curing agent: 9 grams.
Embodiment 6: the raw material weight prescription:
The A component:
Soap powder: 6 grams; α-sodium olefin sulfonate: 8 grams; Xylo-Mucine: 1 gram; Sodium tetraborate: 3 grams; Sodium ethylene diamine tetracetate: 1 gram; Trisodium Citrate: 13 grams; Yellow soda ash: 15 grams; Lime carbonate: 76 grams; Metasilicate pentahydrate sodium: 6 grams.
The B component:
Polyoxyethylenated alcohol sodium sulfate: 4 grams; APG: 14 grams; Defoamer: 1 gram; Epoxy resin binder: 26 grams; Epoxy curing agent: 26 grams.
Its granularity of A component powder raw material that the present invention prepares environment friendly dishwashing granule is 100 orders～2500 orders, wherein said polyoxyethylenated alcohol sodium sulfate is a liquid, its effective active thing content: 70 ± 2%, the weight percentage of polyoxyethylenated alcohol sodium sulfate is the net content of polyoxyethylenated alcohol sodium sulfate; APG light yellow liquid or lotion, it has active matter content: 〉=50%, the weight percentage of APG is the net content of APG.Epoxy resin binder is the amino acid derived Resins, epoxy of poisonless biological degradable: epoxy curing agent is a kind of in polyamide curing agent, polymeric amide affixture solidifying agent, amido amine solidifying agent, the modification amido amine solidifying agent.The bonding ratio range of described epoxy resin binder and epoxy curing agent is 1: 1～5: 1; At normal temperatures, Resins, epoxy surface drying set time was 2～16 hours after epoxy resin binder and epoxy curing agent were bonding.
Whole raw materials that the present invention prepares environment friendly dishwashing granule all adopt food grade materials.The main body activated feedstock all adopts the environment-protecting asepsis material, and the soap powder biological degradability is good, health environment-friendly; α-sodium olefin sulfonate biological degradability good (degradation rate＞97%), nontoxic (LD502.5g/kg); The APG biodegradability is good, nontoxic, non-stimulated.Polyoxyethylene alkyl ether sulfate salt biological degradability good (degradation rate 95%), nontoxic (LD50 1.7g/kg), little to skin irritation; Epoxy resin binder adopts the amino acid derived Resins, epoxy of novel poisonless biological degradable.Described APG is biodegradable APG, its actives component content 〉=50%; The active component content of described polyoxyethylenated alcohol sodium sulfate 〉=65%.
The used main actives composition of the present invention is biodegradable environmentfriendly products, and its relevant rerum natura is as follows:
1, APG be a kind of be raw material synthetic nonionic surface active agent by recyclability plants such as fatty alcohol and glucoses, it is to lose a part water and the product that obtains under the catalysis of acid by the hemiacetal hydroxyl of glucose and Fatty Alcohol(C12-C14 and C12-C18) hydroxyl.Its biological degradation rate 〉=99% belongs to natural, gentle, green product, compares with petrochemicals, has the new generation of green tensio-active agent of Sustainable development.Alkyl polyglucoside is except high wash dining set performance, and it not only itself can also reduce the stimulatory effect of anion surfactant to the human body skin gentleness.Usually and the product of skin highly compatible, can lose some washing performances usually, or the product of high wash dining set performance, then often be considered to relatively poor with the consistency of skin.But the existing high wash dining set performance of the product of APG again can be well compatible with skin.
2, AMONYL 380LC is a kind of amphoterics, and its chemical structure is: (RCO-NH-(CH2) 3-N+ (CH3) 2-CH2COONA) CL-is R=C12-14H24-28 wherein, to skin, non-stimulated, the no anaphylaxis of eye mucous membrane.Can cooperate with yin, yang, nonionogenic tenside and obtain transparent liquid or colloid, its foam stabilization, exquisiteness.Composite with anion surfactant, can improve material body viscosity, thickening effectiveness is obvious.Have low irritant and bactericidal properties, be used softness, conditioning and the low-temperature stability that can significantly improve the washing bowl product; Have good anti-hard water, static resistance and biological degradability.
3, α-sodium olefin sulfonate, molecular formula RCH=CH (CH2) n-SO3Na RCH (OH) is n-SO3Na n=C14-16 or C14-18 (CH2), has good surfactivity, in the finite concentration scope, α-sodium olefin sulfonate can be reduced to the surface tension of water about 30-40mN.m-1 from 72mN.m-1.So a kind of dishwasher detergent of excellent property, especially when having soap to exist, the hard water neutralization has good foaming power and good detersive power, its toxicity is low little and performance is gentle to skin irritation, the biodegradation rate of AOS and ultimate biodegradation degree are good, in physical environment, can degrade fully in 5-7 days and disappear, not pollute the environment.
4, polyoxyethylenated alcohol sodium sulfate, molecular formula: RO (CH2CH2O) n-SO3Na, anion surfactant, soluble in water, have good decontamination, emulsification, foam performance and anti-performance of hard water, the gentle character that washes the dishes can injured skin.Biological degradability good (degradation rate 95%), nontoxic (LD50 1.7g/kg), little to skin irritation.
5, soap powder is the product that washes the dishes that a kind of handle is washed, protective function combines, and has characteristics such as natural, strong decontamination, ultralow bubble, easy rinsing.Its active substance mainly is a lipid acid, and from reproducible Vegetable oil lipoprotein, biological degradability is good more than 90% for raw material, health environment-friendly, and does not contain poly-phosphate.
Above-mentioned material all can be bought on market.
According to said ratio, the preparation method of environment friendly dishwashing granule of the present invention, can carry out according to following steps:
Step 1: with lime carbonate, metasilicate pentahydrate sodium, yellow soda ash, Xylo-Mucine, soap powder, Trisodium Citrate, sodium ethylene diamine tetracetate, α-sodium olefin sulfonate, the sodium tetraborate of described A component, according to weight accurately weighing successively, put in the stirred vessel of sealing, start and stir.The rotating speed of agitating vane is 60r/min, stirs 6～20 minutes, so that each powder raw material component mixes;
Step 2: with APG, polyoxyethylenated alcohol sodium sulfate, defoamer, epoxy resin binder, the epoxy curing agent of described B component, according to weight weighing accurately successively, put into the stainless steel stirred vessel, start and stir, the rotating speed of agitating vane is 150r/min, stirred 4～8 minutes, so that each liquid starting material component mixes;
Above-mentioned two steps also can carry out in no particular order simultaneously;
Step 3: then the B component that mixes is poured in the airtight stirred vessel that stirs the A component, started and stir, the rotating speed of agitating vane is 40r/min, stirs 6～15 minutes, closes stirrer;
Step 4: take out the A that stirs, the mixture of B two components, drop into the circular granular that the particle pellet processing machine is made 4～15 millimeters of diameters;
Step 5: with the circular granular for preparing, put into baking oven, between 40～70 ℃ of temperature, toasted 4～10 hours, tackiness agent is thoroughly solidified, bonding firm, thus make circular environment friendly dishwashing granule of the present invention.
Carry out money in preparation, all machinery equipment all will be passed through strict disinfecting, and satisfies the making food hygienic requirements.
Environment friendly dishwashing granule with above specific embodiment preparation with the dishwasher special purpose detergent of selling on the market, carries out the mensuration of decontamination value.Its decontamination value such as following table:
By above data contrast, environment friendly dishwashing granule wash dining set cleanliness factor 〉=97% that the present invention is prepared, and commercially available dishwasher special purpose detergent=92%, the prepared environment friendly dishwashing granule washing effect of the present invention is higher than commercially available dishwasher special purpose detergent, can substitute the dishwasher special purpose detergent fully and clean tableware.Simultaneously the prepared environment friendly dishwashing granule of the present invention can satisfy washing times 〉=40 time, and repeatedly recirculation is used.
Claims (6)
1. an environment friendly dishwashing granule is mixed by powder material A component and liquid material B component, it is characterized in that, described A component is formed by the preparation of raw material of following weight percentage:
Soap powder-1～19.7%, α-sodium olefin sulfonate-0.5～16.1%, Xylo-Mucine-0.3～7.6%,
Sodium tetraborate-0.5～6.7%, sodium ethylene diamine tetracetate-0.05～3.4%, Trisodium Citrate-1.6～27.4%
Yellow soda ash-3.2～35.2%, lime carbonate-6.3～60.5%, metasilicate pentahydrate sodium-1.6～20.1%; Described B component is formed by the preparation of raw material of following weight percentage:
Polyoxyethylenated alcohol sodium sulfate-1～16.4%, APG-4.7～19.7%, defoamer-0.1～2.3%, epoxy resin binder-3.4～45%, epoxy curing agent-3.4～45%;
Described epoxy resin binder is the amino acid derived Resins, epoxy of poisonless biological degradable; Epoxy curing agent is a polyamide curing agent.
2. environment friendly dishwashing granule according to claim 1 is characterized in that described A component is formed by the preparation of raw material of following weight percentage:
Soap powder 5%, α-sodium olefin sulfonate 2%, Xylo-Mucine 1%, sodium tetraborate 1.5%,
Sodium ethylene diamine tetracetate 0.5%, Trisodium Citrate 8%, yellow soda ash 10%, lime carbonate 33%, metasilicate pentahydrate sodium 3.5%; The B component is formed by the preparation of raw material of following weight percentage:
Polyoxyethylenated alcohol sodium sulfate 4%, APG 5%, defoamer 0.5%, epoxy resin binder 13%, epoxy curing agent 13%.
3. as environment friendly dishwashing granule as described in the claim 2, it is characterized in that the raw-material powder granularity of the powder of described A component is 100～2000 orders.
4. as environment friendly dishwashing granule as described in the claim 3, it is characterized in that the bonding ratio range of described epoxy resin binder and epoxy curing agent is 1: 1～5: 1; At normal temperatures, Resins, epoxy surface drying set time was 2～16 hours after epoxy resin binder and epoxy curing agent were bonding.
5. the preparation method of environment friendly dishwashing granule according to claim 1 is characterized in that comprising the steps:
(1) elder generation according to weight accurately weighing successively, puts the material of described A component in the stirred vessel of sealing into, mixes;
(2) with the material of described B component according to weight accurately weighing successively, put into the stainless steel stirred vessel, mix;
Above-mentioned two steps perhaps carry out in no particular order simultaneously;
(3) then the B component material that mixes is poured in the airtight stirred vessel of the A component that stirs, restir mixes;
(4) mixture of taking-up A, B two components drops into the particle pellet processing machine, makes the circular granular of 4～15 millimeters of diameters;
(5) with the circular granular for preparing, put into the baking oven baking, take out after the adhering and solidifying.
6. as the preparation method of environment friendly dishwashing granule as described in the claim 5, it is characterized in that the agitating vane rotating speed of the material of described A component is 60r/min, stirred 6～20 minutes; The mixing speed of described B component is 150r/min, stirs 4～8 minutes; The mixture mixing speed of described A, B two components is 40r/min, stirs 6～15 minutes; The temperature of described baking oven baking is 40～70 ℃, toasts 4～10 hours.
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| CN2008102418191A CN101457184B (en) | 2008-12-23 | 2008-12-23 | Environment friendly dishwashing granule and preparation method thereof |
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| CN101457184A CN101457184A (en) | 2009-06-17 |
| CN101457184B true CN101457184B (en) | 2011-01-26 |
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| CN101885605B (en) * | 2010-06-28 | 2013-09-04 | 深圳市成为生物科技有限公司 | Ceramic particle with adsorption, ion exchange and negative ion generating functions and preparation method thereof |
| CN106381247A (en) * | 2015-12-07 | 2017-02-08 | 蒋宏凯 | Cleaning agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1219577A (en) * | 1997-08-04 | 1999-06-16 | 刘文庆 | Solid slow-releasing detergent and its preparation method |
| CN1222565A (en) * | 1997-11-28 | 1999-07-14 | 包头市红卫日用化工有限公司 | Soap base washing powder without benzene, phosphate, enzyme and fluorescent agent |
| JP2006124590A (en) * | 2004-10-29 | 2006-05-18 | Soft99 Corporation | Detergent for polishing coating face |
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2008
- 2008-12-23 CN CN2008102418191A patent/CN101457184B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1219577A (en) * | 1997-08-04 | 1999-06-16 | 刘文庆 | Solid slow-releasing detergent and its preparation method |
| CN1222565A (en) * | 1997-11-28 | 1999-07-14 | 包头市红卫日用化工有限公司 | Soap base washing powder without benzene, phosphate, enzyme and fluorescent agent |
| JP2006124590A (en) * | 2004-10-29 | 2006-05-18 | Soft99 Corporation | Detergent for polishing coating face |
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