CN110257186A - Dish washing liquid and its preparation method and application - Google Patents
Dish washing liquid and its preparation method and application Download PDFInfo
- Publication number
- CN110257186A CN110257186A CN201910587283.7A CN201910587283A CN110257186A CN 110257186 A CN110257186 A CN 110257186A CN 201910587283 A CN201910587283 A CN 201910587283A CN 110257186 A CN110257186 A CN 110257186A
- Authority
- CN
- China
- Prior art keywords
- dish washing
- washing liquid
- weight percentage
- cellulose
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000004851 dishwashing Methods 0.000 title claims abstract description 127
- 239000007788 liquid Substances 0.000 title claims abstract description 124
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 229920002678 cellulose Polymers 0.000 claims abstract description 80
- 239000001913 cellulose Substances 0.000 claims abstract description 80
- 239000000203 mixture Substances 0.000 claims abstract description 78
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 68
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 49
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 49
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 49
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 35
- 239000001632 sodium acetate Substances 0.000 claims abstract description 35
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 35
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 34
- 239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 34
- 239000000126 substance Substances 0.000 claims abstract description 11
- -1 Oxygroup alkyl sulfate Chemical class 0.000 claims description 50
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 44
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 36
- 239000002738 chelating agent Substances 0.000 claims description 34
- 239000003755 preservative agent Substances 0.000 claims description 34
- 230000002335 preservative effect Effects 0.000 claims description 34
- 229910052708 sodium Inorganic materials 0.000 claims description 29
- 239000011734 sodium Substances 0.000 claims description 29
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 28
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 28
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 25
- 229960003237 betaine Drugs 0.000 claims description 23
- 239000002736 nonionic surfactant Substances 0.000 claims description 22
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 16
- 150000002193 fatty amides Chemical class 0.000 claims description 15
- 239000004094 surface-active agent Substances 0.000 claims description 14
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 150000002191 fatty alcohols Chemical class 0.000 claims description 11
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 10
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 10
- 229930182478 glucoside Natural products 0.000 claims description 9
- 239000004711 α-olefin Substances 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 4
- 239000003205 fragrance Substances 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 235000016068 Berberis vulgaris Nutrition 0.000 claims description 2
- 241000335053 Beta vulgaris Species 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 9
- 238000005406 washing Methods 0.000 abstract description 8
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 239000012528 membrane Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 22
- 230000000694 effects Effects 0.000 description 16
- 239000003599 detergent Substances 0.000 description 13
- 238000004140 cleaning Methods 0.000 description 11
- 239000003292 glue Substances 0.000 description 9
- 239000002585 base Substances 0.000 description 8
- 238000013329 compounding Methods 0.000 description 8
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 206010054949 Metaplasia Diseases 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000015689 metaplastic ossification Effects 0.000 description 2
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- BHUGZIJOVAVBOQ-UHFFFAOYSA-N 2-(propylazaniumyl)acetate Chemical compound CCCNCC(O)=O BHUGZIJOVAVBOQ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000040710 Chela Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- HSHXDCVZWHOWCS-UHFFFAOYSA-N N'-hexadecylthiophene-2-carbohydrazide Chemical compound CCCCCCCCCCCCCCCCNNC(=O)c1cccs1 HSHXDCVZWHOWCS-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N lauric acid amide propyl betaine Natural products CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 238000004313 potentiometry Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C11D2111/14—
Abstract
The present invention provides a kind of dish washing liquids and its preparation method and application, are related to daily chemical product technical field.Dish washing liquid of the invention includes following component by weight percentage: anionic surfactant 5-40%, zwitterionic surfactant 0.5-15% and cellulose composition 0.05-1.0%；Wherein, the cellulose composition includes cationization hydroxyethyl cellulose, sodium acetate and isopropanol.The present invention passes through the hydroxyethyl cellulose and anionic surfactant of cationization and the coordinated of zwitterionic surfactant, so that the tableware surface after washing forms one layer of hydrophobic membrane, moisture is reduced in the residence time of tableware surface, it significantly improves and drains rate after tableware is washed, washmarking and spot are reduced in the generation of tableware surface, while can also reduce the growth risk of bacterium on tableware.
Description
Technical field
The invention belongs to daily chemical product technical fields, and in particular to a kind of dish washing liquid and its preparation method and application.
Background technique
Dish washing liquid is common daily necessity in daily life, can be used to clean tableware, vegetables, melon and fruit, cooking apparatus etc..
Since dish washing liquid and food and human skin etc. have more close contact, properties of product influence the health of the mankind, because
This, it is desirable that dish washing liquid has safety and environmental protection, as mild as possible to human skin, has the characteristics that preferable decontamination, degerming ability.
In recent years, with the development of society and the enhancing of people's environmental consciousness, requirement of the people to daily chemical products such as dish washing liquids is also more next
It is higher, in addition to that need to have effects that traditional safety and decontamination, it is also desirable to have the spies such as cleaning is thorough, does not remain, quickly drains
Point.
Currently, domestic washing habits, substantially manual dishwashing, washs and have drained naturally afterwards, or with clean bowl
Cloth wiped clean.However, most of tablewares after draining naturally, table after having washed tableware using dish washing liquid in the prior art
Face is also easy to produce washmarking, spot, and the rate drained is slower.Tableware can be made to wash it is therefore desired to provide one kind
It is quickly drained after complete, reduces the generation of washmarking, spot, while the good tableware dish washing liquid of cleaning effect, be able to solve above-mentioned
At least one of problem.
In consideration of it, the present invention is specifically proposed.
Summary of the invention
The first object of the present invention is to provide a kind of can be improved and drains rate after dishwashing detergent, reduces washmarking and spot
The generation of point, while cleaning effect is good, can reduce the dish washing liquid of the growth risk of bacterium on tableware, can overcome the above problem or
Person at least is partially solved above-mentioned technical problem.
The second object of the present invention is to provide a kind of preparation method of dish washing liquid, and method is simple, easy to operate, obtained
Dish washing liquid, which has, drains that rate is fast, the characteristics of can be reduced the generation of washmarking, spot, while can also reduce bacteria breed.
The third object of the present invention is to provide application of the dish washing liquid described in one kind in daily chemical product field, uses this
Dish washing liquid washs tableware, drains rate after capable of improving dishwashing detergent, reduces the generation of washmarking and spot, while cleaning effect
It is good, the growth risk of bacterium on tableware can be reduced.
To achieve the above object, the technical solution adopted by the present invention are as follows:
According to an aspect of the present invention, the present invention provides a kind of dish washing liquid, and the dish washing liquid includes by weight percentage
The following component of meter:
Anionic surfactant 5-40%, zwitterionic surfactant 0.5-15% and cellulose composition 0.05-
1.0%；
Wherein, the cellulose composition includes cationization hydroxyethyl cellulose, sodium acetate and isopropanol.
Further, the dish washing liquid includes following component by weight percentage: anionic surfactant 6-
30%, zwitterionic surfactant 1.0-10% and cellulose composition 0.1-0.8%；
Preferably, the dish washing liquid includes following component by weight percentage: anionic surfactant 9-15%,
Zwitterionic surfactant 1.5-5% and cellulose composition 0.4-0.6%.
Further, the cellulose composition mainly by forming following weight percentage components: cationization hydroxyl second
Base cellulose 90-99.8%, sodium acetate 0.1-5.0% and isopropanol 0.1-5.0%；
Preferably, the cellulose composition mainly by forming following weight percentage components: cationization ethoxy
Cellulose 91-98.5%, sodium acetate 0.1-2.5% and isopropanol 0.1-2.5%；
Preferably, the cellulose composition mainly by forming following weight percentage components: cationization ethoxy
Cellulose 91-97%, sodium acetate 0.1-1.5% and isopropanol 0.1-1.0%.
Further, the anionic surfactant include ethoxylated alkyl sulfates, linear alkylbenzene sulfonate (LAS),
At least one of alkyl sulfate, alpha-olefin sulfo group sodium sulfonate and fatty acid methyl ester sulfonate；
Preferably, the anionic surfactant includes ethoxylated alkyl sulfates and linear alkyl benzene sulfonic acid
Any one in salt, alpha-olefin sulfo group sodium sulfonate and fatty acid methyl ester sulfonate；
Preferably, the anionic surfactant includes ethoxylated alkyl sulfates and linear alkylbenzene sulfonate (LAS).
Further, the zwitterionic surfactant includes fatty amide propyl amine oxide, alkyl dimethylamine oxides
At least one of amine, alkyl dihydroxy ethyl amine oxide and fattyamidopropyl betaine；
Preferably, the zwitterionic surfactant includes fatty amide propyl amine oxide and/or fatty amide propyl
Glycine betaine；
Preferably, the zwitterionic surfactant is fatty amide propyl amine oxide.
It further, further include nonionic surfactant；
Preferably, the weight percentage of the nonionic surfactant be 0.1-2.5%, preferably 0.1-2.0%,
More preferably 0.5-1.5%；
Preferably, the nonionic surfactant include fatty alcohol polyoxyethylene ether, fatty acid methyl ester APEO,
At least one of alkylolamides polyoxyethylene ether, alkylolamides and alkyl poly glucoside；
Preferably, the nonionic surfactant includes fatty alcohol polyoxyethylene ether and/or alkyl poly glucoside；
Preferably, the nonionic surfactant is fatty alcohol polyoxyethylene ether.
It further, further include builder；
Preferably, the builder includes in chelating agent, preservative, viscosity modifier, stabilizer, structural agent or fragrance
It is at least one；
Preferably, the builder includes chelating agent, preservative and viscosity modifier.
Further, the weight percentage of the chelating agent be 0.01-0.1%, preferably 0.02-0.08%, it is more excellent
It is selected as 0.03-0.06%；
Preferably, the weight percentage of the preservative be 0.01-0.5%, preferably 0.02-0.4%, more preferably
0.03-0.1%；
Preferably, the weight percentage of the viscosity modifier be 0.01-5.0%, preferably 0.05-3.0%, it is more excellent
It is selected as 0.1-1.5%.
According to another aspect of the present invention, the present invention provides a kind of preparation method of dish washing liquid as described above, includes
Following steps:
The component of above-described dish washing liquid is uniformly mixed, the dish washing liquid is obtained.
According to another aspect of the present invention, the present invention provides a kind of dish washing liquid answering in daily chemical product field
With；
Preferably, the daily chemical product includes tableware.
Compared with prior art, the beneficial effects of the present invention are:
Dish washing liquid provided by the invention, including anionic surfactant, zwitterionic surfactant and cellulose group
Object is closed, cellulose composition therein includes cationization hydroxyethyl cellulose, sodium acetate and isopropanol, the hydroxyl second of cationization
Base cellulose combines the tableware surface after can to wash with anionic surfactant and zwitterionic surfactant
One layer of hydrophobic membrane is formed, moisture is reduced in the residence time of tableware surface, drains speed after tableware is washed to significantly improve
Rate reduces washmarking and spot in the generation of tableware surface, while can also reduce the growth risk of bacterium on tableware.
Dish washing liquid preparation process of the invention is simple, easy to operate, need to only be uniformly mixed each component, without multiple
Miscellaneous, expensive equipment, it is at low cost, it is conducive to realize that industrially scalable metaplasia produces.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiments and examples, but this field skill
Art personnel will be understood that following embodiments and embodiment are merely to illustrate the present invention, and are not construed as limiting model of the invention
It encloses.Based on the embodiments of the present invention, obtained by those of ordinary skill in the art without making creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.The person that is not specified actual conditions, according to normal conditions or manufacturer builds
The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase
Product.
Hydroxyethyl cellulose is a kind of important cellulose derivative, have it is resourceful, renewable, biodegradable,
The features such as good biocompatibility, is widely used in environmentally protective field.But the intermolecular hydrogen of hydroxyethyl cellulose
Key and a large amount of hydrogen bonds of intramolecular affect its application, and researchers utilize the hydroxyl on hydroxyethyl cellulose macromolecular chain thus
Base reactivity introduces cationic compound to improve its performance, to widen the application field of hydroxyethyl cellulose.The prior art
In have by the hydroxyethyl cellulose (alternatively referred to as cationic hydroxyethyl cellulose) of cationization apply oil exploitation, dye
Report in terms of material, filed of daily-use chemical industry.
Although there is the various relevant reports of addition cellulosic polymer in daily chemical product in the prior art such as detergent,
Its purpose for adding cellulosic polymer is viscosity for increasing detergent or enhances its cleaning capacity.For example, Publication No.
The patent of CN105008510A discloses a kind of viscous detergent agent composition, and it comprises the nonionic of 1~2.5 mass % fibres
Plain derivative is tieed up, increases the viscosity of detergent using the non-ionic cellulose element derivative.Publication No. CN101978038A's
Patent discloses a kind of detergent composition comprising cellulosic polymer, and it includes 70 weight % to the fiber of 100 weight %
Plain polymer is used to improve the water solubility of the solid laundry detergents composition comprising cellulosic polymer and silicate, i.e.,
For increasing the cleaning force of washing.The patent of Publication No. CN101415809A discloses a kind of comprising cationic hydroxyethyl fiber
The liquid laundry detergent of plain polymer, by cationic hydroxyethyl cellulose polymer and surfactant and fatty acid knot
It closes, nursing role etc. can be provided to fabric.But above-mentioned report does not refer to that hydroxyethyl cellulose can increase washing for dish washing liquid
After drain rate.
Therefore, before the applying date of the application, it has not been found that being washed about hydroxyethyl cellulose for improving dish washing liquid
Cationic hydroxyethyl cellulose is more applied in tableware detergent without discovery, is used for by the relevant report for draining rate afterwards
The relevant report for draining rate after improving tableware cleaning fine purifiation.And the present inventor has been found surprisingly that cationic hydroxyl second
This performance of base cellulose, and cationic hydroxyethyl cellulose has been put forward for the first time in dish washing liquid especially tableware dish washing liquid
Application, impart the tableware characteristic that can quickly drain after washing using the dish washing liquid, and the tableware after draining is not likely to produce spot
Point, washmarking.
In a first aspect, providing a kind of dish washing liquid at least one embodiment, the dish washing liquid includes by weight percentage
The following component of meter:
Anionic surfactant 5-40%, zwitterionic surfactant 0.5-15% and cellulose composition 0.05-
1.0%；
Wherein, the cellulose composition includes cationization hydroxyethyl cellulose, sodium acetate and isopropanol.
To overcome the not perfect of the prior art, the present invention provides a kind of dish washing liquid, by using the ethoxy of cationization
The cooperation of cellulose, anionic surfactant and zwitterionic surfactant, so that the tableware surface after washing forms one layer
Hydrophobic membrane reduces moisture in the residence time of tableware surface, drains faster so that the tableware after being washed using the dish washing liquid is had
Speed reduces the generation of washmarking, spot, while can also reduce the growth of bacterium, and cleaning effect is good.
Especially prominent, the present invention joined the hydroxyethyl cellulose of cationization in the dish washing liquid, improves and washes
Tableware after clean fine purifiation drains rate, has the effect quickly drained than common dish washing liquid after washing tableware using the dish washing liquid
Fruit, and the tableware after draining is not likely to produce spot.
In addition, above-mentioned cellulose composition is in addition to including cationization hydroxyethyl cellulose, it further include sodium acetate and different
Propyl alcohol can make the hydroxyethyl cellulose that is cationized by the cooperation of be cationized hydroxyethyl cellulose, sodium acetate and isopropanol
It preferably plays a role, facilitates the stability, uniformity for enhancing composition, be more conducive to drain speed after raising tableware is washed
Rate reduces moisture in the residence time of tableware surface.
Dish washing liquid of the invention mainly by suitable and suitable anionic surfactant, zwitterionic surfactant and
Cellulose composition comprising the hydroxyethyl cellulose that is cationized is made, and has good compatibility and collaboration effect between component
Fruit, each component can give full play to the advantage of oneself, green and pollution-free, safe and non-toxic, and performance is mild, irritation is small, be easy to
It rinses well, dirt-removing power is stronger, and cleaning effect is good.Gross activity object content >=15% through detecting, in the dish washing liquid；25
Under the conditions of DEG C, the dish washing liquid provided by the invention of 0.1% concentration, pH≤8.5, pH value is moderate, and performance is mild, does not stimulate skin,
Cleaning effect is good.
It should be understood that
In the present invention, if without particularly illustrating, all technical characteristics and preferred feature mentioned in this article can be with
Intercombination forms new technical solution.For example, related each component or its preferred ingredient can be combined with each other to be formed it is new
Technical solution.
"include", "comprise" of the present invention, it is intended that it can also include other components exceptionally except described group, these
Other components assign dish washing liquid different characteristics.In addition to this, "include", "comprise" of the present invention, " mainly by ... group
At " may be replaced by enclosed " for " or " by ... be prepared ".For example, it includes anionic surface that the dish washing liquid, which removes,
It can also include nonionic surfactant other than activating agent, zwitterionic surfactant and cellulose, it is commonly used in the art
Builder etc..For another example, cellulose composition includes cationization hydroxyethyl cellulose, sodium acetate and isopropanol, be could alternatively be
Cellulose composition is prepared by cationization hydroxyethyl cellulose, sodium acetate and isopropanol.
If be not specifically stated, the benchmark of percentage (including weight percent) of the present invention is all the combination
The total weight of object.That is, percentage (%) all refers to the weight percent relative to composition.
In the present invention, unless otherwise stated, related percentage, ratio or number are according to poidometer, such as 5-
40%, 5-40wt% or 5 weight %-40 weight % can be expressed as.
The value expressed using range format should it is flexible in a manner of be interpreted as not only including clearly enumerating as range limit
The numerical value of value, but also including covering all single numbers or subinterval in the range, like each numerical value and subinterval
It is expressly recited out.For example, the weight content of anionic surfactant is 5%-40%, it should be understood that not only include clear
Enumerate 5% and 40%, further include the single number in signified scope, such as 6%, 7%, 8%, 9%, 10%, 11%,
12%, 13%, 14%, 15%, 16%, 18%, 20%, 22%, 25%, 28%, 30%, 32%, 35% or 38%.Both sexes from
The weight content of sub- surfactant is 0.5%-15%, it is typical but non-limiting can enumerate 0.5%, 0.8%,
1.0%, 1.2%, 1.5%, 1.8%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 7%, 8%,
9%, 10%, 11%, 12%, 13%, 14% or 15%.The weight content of cellulose composition is 0.05%-1.0%, typical
But it is unrestricted can enumerate 0.05%, 0.08%, 0.1%, 0.15%, 0.2%, 0.25%, 0.3%, 0.35%,
0.4%, 0.45%, 0.5%, 0.55%, 0.6%, 0.7%, 0.75%, 0.8%, 0.85%, 0.9%, 0.95% or
1.0%.
Unless otherwise indicated, profession used herein and meaning phase known to scientific term and one skilled in the art
Together.
In some preferred embodiments, the dish washing liquid includes following component by weight percentage: anion
Surfactant 6-30%, zwitterionic surfactant 1.0-10% and cellulose composition 0.1-0.8%；
Preferably, the dish washing liquid includes following component by weight percentage: anionic surfactant 9-15%,
Zwitterionic surfactant 1.5-5% and cellulose composition 0.4-0.6%.
By reasonably adjusting and optimizing the dosage of each component in dish washing liquid, the mating reaction of each component is given full play to, into one
Step drains rate after improving the washing of dish washing liquid, and reduces the generation of washmarking, spot, while reducing the growth of bacterium, and cleaning effect is more
It is good, while the production cost of dish washing liquid is reduced, be conducive to the economic benefit for improving dish washing liquid.
In some preferred embodiments, the cellulose composition is mainly by group following weight percentage components
At: cationization hydroxyethyl cellulose 90-99.8%, sodium acetate 0.1-5.0% and isopropanol 0.1-5.0%；
Preferably, the cellulose composition mainly by forming following weight percentage components: cationization ethoxy
Cellulose 91-98.5%, sodium acetate 0.1-2.5% and isopropanol 0.1-2.5%；
Preferably, the cellulose composition mainly by forming following weight percentage components: cationization ethoxy
Cellulose 91-97%, sodium acetate 0.1-1.5% and isopropanol 0.1-1.0%.
According to the present invention, cellulose composition or cellulosic polymer are the combination comprising the hydroxyethyl cellulose that is cationized
Object, content >=90% for the hydroxyethyl cellulose that is cationized in composition, preferably >=91%；And sodium acetate and isopropanol always contain
Amount is preferably≤2.5%.In composition, cationization hydroxyethyl cellulose, sodium acetate and isopropanol and remaining optional auxiliary agent,
The sum of dosage of auxiliary material etc. is 100%.It is understood that not only including that cationization ethoxy is fine in the cellulose composition
Dimension element, sodium acetate and isopropanol can also include other acceptable auxiliary agent, auxiliary materials etc., these auxiliary agents, auxiliary material etc. do not made
Specifically limited, content is lower, as long as not generating limitation to the purpose of the present invention, not influencing the hydroxyethyl cellulose hair that is cationized
Wave effect.It is typical but non-limiting to enumerate, the content of the hydroxyethyl cellulose that is cationized is 90%, 91%,
92%, 93%, 94%, 95%, 95.5%, 96%, 96.5%, 97%, 97.5%, 98%, 98.5%, 99% or 99.8%,
The content of sodium acetate be 0.1%, 0.2%, 0.4%, 0.5%, 0.6%, 0.8%, 1.0%, 1.2%, 1.5%, 1.8%,
2%, 2.5%, 3%, 4% or 5%, the content of isopropanol is 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%,
0.7%, 0.8%, 0.9%, 1.0%, 1.5%, 2%, 2.5%, 3%, 4% or 5%.
Pass through the cellulose polymerization of suitable and suitable cationization hydroxyethyl cellulose, sodium acetate and isopropanol composition
Object, the quickening that can give full play to cationization hydroxyethyl cellulose drain the characteristic of rate, and energy and anion surface active
Agent and zwitterionic surfactant preferably cooperatively form hydrophobic membrane.Meanwhile raw material sources are extensive, are easy to get, at low cost, peace
Entirely, environmentally friendly, harmless.
It should be noted that the present invention is to involved cation in component included by above-mentioned cellulose composition
Change hydroxyethyl cellulose, sodium acetate and the source of isopropanol, concrete type not limit strictly, can choose known in the art normal
Type；Its commercial goods can be such as used, can also voluntarily be prepared using preparation method well known to those skilled in the art.
For example, above-mentioned cationization hydroxyethyl cellulose can use its commercial goods, routinizing by commercially available material can also be used
Learn modified be made.It can be used for the cationization hydroxyethyl cellulose of this paper or cellulose composition include commercially available by DOW Chemical
The cationization hydroxyethyl cellulose of supercare 212 of offer.
Any of cationization hydroxyethyl cellulose may each comprise in the present compositions.
In component included by above-mentioned dish washing liquid, the present invention is to involved anionic surfactant, amphoteric ion
Surfactant does not limit strictly, can choose this field known common type in preparing dish washing liquid, but in order to realize
Better cooperation/synergy between each component, the present invention to anionic surfactant, zwitterionic surfactant make as
Lower preferred restriction:
Preferably, the anionic surfactant includes ethoxylated alkyl sulfates, linear alkylbenzene sulfonate (LAS), alkane
At least one of base sulfate, alpha-olefin sulfo group sodium sulfonate and fatty acid methyl ester sulfonate.For example, the anion surface active
Agent can be ethoxylated alkyl sulfates, can be linear alkylbenzene sulfonate (LAS), can be alkyl sulfate, can be α-alkene
Hydrocarbon sulfo group sodium sulfonate can be fatty acid methyl ester sulfonate, can be ethoxylated alkyl sulfates and linear alkyl benzene sulfonic acid
The compounding of salt, or the compounding etc. of ethoxylated alkyl sulfates and alpha-olefin sulfo group sodium sulfonate.
It is highly preferred that the anionic surfactant includes ethoxylated alkyl sulfates and linear alkylbenzene (LAB) sulphur
Any one in hydrochlorate, alpha-olefin sulfo group sodium sulfonate and fatty acid methyl ester sulfonate.It is understood that the anionic surface
Activating agent includes at least ethoxylated alkyl sulfates；For example, the anionic surfactant can be ethoxylated alkyl sulphur
The compounding of hydrochlorate and linear alkylbenzene sulfonate (LAS), can answering for ethoxylated alkyl sulfates and alpha-olefin sulfo group sodium sulfonate
Match, or the compounding of ethoxylated alkyl sulfates and fatty acid methyl ester sulfonate.
Most preferably, the anionic surfactant includes ethoxylated alkyl sulfates and linear alkyl benzene sulfonic acid
Salt.
Further, above-mentioned ethoxylated alkyl sulfates include ethoxylated alkyl sulfate.It is applicable in second in this article
Oxygroup sodium alkyl sulfate includes the sulfate ethoxylated alkyl sulfate of the C12-C18 of 1-5 average degree of ethoxylation.
Above-mentioned linear alkylbenzene sulfonate (LAS) includes sodium n-alkylbenzenesulfonate, is applicable in linear alkyl benzene sulfonic acid in this article
Sodium includes the sodium n-alkylbenzenesulfonate of C10-C13, i.e., the sodium n-alkylbenzenesulfonate has carbon atom number 10-13.
Preferably, the zwitterionic surfactant include fatty amide propyl amine oxide, alkyl dimethyl amine oxide,
At least one of alkyl dihydroxy ethyl amine oxide and fattyamidopropyl betaine.For example, zwitterionic surfactant can
Think fatty amide propyl amine oxide, can be alkyl dimethyl amine oxide, can be alkyl dihydroxy ethyl amine oxide, Ke Yiwei
Fattyamidopropyl betaine can be the compounding of fatty amide propyl amine oxide and alkyl dimethyl amine oxide, can be alkane
The compounding of base dimethyl amine and alkyl dihydroxy ethyl amine oxide, or fatty amide propyl amine oxide and fatty acid amide
The compounding etc. of propyl betaine.
It is highly preferred that the zwitterionic surfactant includes fatty amide propyl amine oxide and/or fatty acid amide third
Base glycine betaine.
Most preferably, the zwitterionic surfactant is fatty amide propyl amine oxide.
It should be noted that herein, "and/or" is used to indicate that one of illustrated situation or both may hair
It is raw, such as A and/or B includes (A and B) and (A or B).
Further, above-mentioned fatty amide propyl amine oxide includes cocamidopropyl propyl amide amine oxide, dodecanamide propyl oxidation
Amine and palm-kernel oil amidopropyl amine oxide, preferably cocamidopropyl propyl amide amine oxide.It is applicable in fatty acid amide third in this article
Base amine oxide is preferably the fatty amide propyl amine oxide with the acyl group of carbon atom number 8-18.
As zwitterionic surfactant, glycine betaine series of surfactants, such as fatty acid amide can also be enumerated
The betaines surfactants such as propyl betaine.Fattyamidopropyl betaine, preferably with the acyl group of carbon atom number 8-18
Fattyamidopropyl betaine, specifically preferred lauroylamidopropyl betaine, palm kernel oil fatty amido propyl beet
Alkali, coconut oil fat amido propyl betaine etc..
In some preferred embodiments, dish washing liquid further includes nonionic surfactant；
Preferably, the weight percentage of the nonionic surfactant be 0.1-2.5%, preferably 0.1-2.0%,
More preferably 0.5-1.5%.
It should be understood that surfactant includes at least one anionic surfactant in dish washing liquid of the invention
In addition to this it may also include other surfaces activating agent at least one zwitterionic surfactant, such as non-ionic surface
Active.That is, nonionic surfactant optionally adds in sheet.The weight of nonionic surfactant
Content is typical but non-limiting can to enumerate 0.1%, 0.2%, 0.5%, 0.6%, 0.8%, 1.0%, 1.2%,
1.5%, 1.8%, 2.0%, 2.2% or 2.5%.
In component included by above-mentioned dish washing liquid, the present invention does not limit involved nonionic surfactant strictly
System, can choose this field known common type in preparing dish washing liquid, but in order to realize between each component preferably cooperation/association
Same effect, the present invention make following preferred restriction to nonionic surfactant:
Preferably, the nonionic surfactant include fatty alcohol polyoxyethylene ether, fatty acid methyl ester APEO,
At least one of alkylolamides polyoxyethylene ether, alkylolamides and alkyl poly glucoside.For example, non-ionic surface is living
Property agent can be fatty alcohol polyoxyethylene ether, can be fatty acid methyl ester polyoxyethylene ether, can be alkylolamides polyoxy second
Alkene ether can be alkylolamides, can be alkyl poly glucoside, can be fatty alcohol polyoxyethylene ether and the poly- grape of alkyl
The compounding of glucosides, or fatty acid methyl ester APEO, alkylolamides polyoxyethylene ether and alkylolamides are answered
With etc..
It is highly preferred that the nonionic surfactant includes fatty alcohol polyoxyethylene ether and/or alkyl poly glucoside；
Most preferably, the nonionic surfactant is fatty alcohol polyoxyethylene ether.
In some preferred embodiments, dish washing liquid further includes builder；
Preferably, the builder includes in chelating agent, preservative, viscosity modifier, stabilizer, structural agent or fragrance
It is at least one；For example, builder can be chelating agent, can be preservative, can be viscosity modifier, can for chelating agent,
Preservative and viscosity modifier can be chelating agent, viscosity modifier and structural agent, can be chelating agent, preservative, stabilizer
With fragrance etc..
It is highly preferred that the builder includes chelating agent, preservative and viscosity modifier.
It should be understood that above-mentioned builder be it is known in the art, be suitble to dish washing liquid this field commonly help
Agent, these auxiliary agents can assign dish washing liquid different characteristics；In practical application, selective according to the actual situation can add
Add.The builder being applicable in this article mainly includes chelating agent, preservative and viscosity modifier.
Any of chelating agent, preservative and viscosity modifier may each comprise in dish washing liquid of the invention.For institute
The source of the chelating agent, preservative and the viscosity modifier that are related to, concrete type do not limit strictly, can choose this field
Know common type；Its commercial goods can be such as used, it can also be using preparation method well known to those skilled in the art voluntarily
Preparation.For example, chelating agent can use edta and its sodium salt, glutamic acid diacetic acid and its sodium salt, glycine diethyl
Acid and its sodium salt etc.；Preservative can be using isothiazolinone, sodium benzoate, potassium sorbate etc.；Viscosity modifier can use
Carboxymethyl cellulose, hydroxypropyl methyl cellulose, chlorate etc..
In some preferred embodiments, the weight percentage of the chelating agent is 0.01-0.1%, preferably
0.02-0.08%, more preferably 0.03-0.06%；
Preferably, the weight percentage of the preservative be 0.01-0.5%, preferably 0.02-0.4%, more preferably
0.03-0.1%；
Preferably, the weight percentage of the viscosity modifier be 0.01-5.0%, preferably 0.05-3.0%, it is more excellent
It is selected as 0.1-1.5%.
As a kind of preferred embodiment of the invention, the dish washing liquid includes following component by weight percentage:
Anionic surfactant 5-40%, zwitterionic surfactant 0.5-15%, nonionic surfactant
0.1-2.0%, cellulose composition 0.05-1.0%, chelating agent 0.01-0.1%, preservative 0.01-0.5% and viscosity-adjusting agent
Agent 0.01-5.0%, surplus are water (water supplies 100%)；
Wherein, the cellulose composition mainly by forming following weight percentage components: cationization ethoxy is fine
Tie up element 90-99.8%, sodium acetate 0.1-5.0% and isopropanol 0.1-5.0%.
As another preferred embodiment of the invention, the dish washing liquid includes by weight percentage such as the following group
Point:
Anionic surfactant 5-40%, zwitterionic surfactant 0.5-15%, cellulose composition 0.05-
1.0%, chelating agent 0.01-0.1%, preservative 0.01-0.5% and viscosity modifier 0.01-5.0%, surplus are that water (supply by water
100%)；
Wherein, the cellulose composition mainly by forming following weight percentage components: cationization ethoxy is fine
Tie up element 90-99.8%, sodium acetate 0.1-5.0% and isopropanol 0.1-5.0%.
It should be understood that the sum of dosage of component included by dish washing liquid is 100%, i.e., several objects enumerated above
The sum of dosage of matter, along with the dosage of water is equal to 100%.
Second aspect provides a kind of preparation method of above-mentioned dish washing liquid in some embodiments, comprises the following steps:
The component of above-described dish washing liquid is uniformly mixed, the dish washing liquid is obtained.
According to the present invention, the preparation method includes: according to formula ratio, by anionic surfactant, amphoteric ion table
Face activating agent, cellulose composition, optional nonionic surfactant and builder are uniformly mixed, and obtain dish washing liquid.
Dish washing liquid of the invention is prepared at normal temperature, without heating equipment.For example, when preparation, first by straight chained alkyl
In benzene sulfonic acid and liquid alkaline and 10 minutes, the surfactants such as addition ethoxylated alkyl sulfate, cocamidopropyl propyl amide amine oxide,
After mixing evenly, the cellulose composition dissolved in advance is added, is eventually adding the auxiliary agent of auxiliary, entire process for preparation is about
40 minutes.
Dish washing liquid preparation process of the invention is simple, easy to operate, need to only be uniformly mixed each component, without multiple
Miscellaneous, expensive equipment, it is at low cost, it is high-efficient, it is conducive to realize that industrially scalable metaplasia produces.Meanwhile using cation of the invention
As raw material, the ratio of each component raw material is appropriate for surfactant, zwitterionic surfactant and cellulose composition, is made
Dish washing liquid improve and drain rate after tableware is washed, reduce washmarking and spot in the generation of tableware surface, while can also subtract
The growth risk of bacterium on few tableware.
The third aspect provides application of the dish washing liquid described in one kind in field of tableware in some embodiments.
It will be appreciated to those of skill in the art that the application and dish washing liquid above-mentioned and its preparation of third aspect present invention
Method is based on the same inventive concept, above for feature and advantage described in dish washing liquid and preparation method thereof, equally to fit
With the application of the dish washing liquid, details are not described herein.
It should be understood that the content being not described in detail in the explanation of above-mentioned dish washing liquid and its preparation method and application,
It is the Common Parameters or ordinary operation mode that those skilled in the art are readily apparent that, is referred to the prior art, or by this field
Technical staff regulates and controls according to the actual situation, therefore can be omitted detailed description thereof.
To facilitate the understanding of the present invention, combined with specific embodiments below, comparative example, the invention will be further described.
Embodiment 1
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 4.0%, ethoxylated alkyl sulfate 10.0%, cocamidopropyl propyl amide amine oxide
7.5%, fattyamidopropyl betaine 2.5%, cellulose composition 0.5%, chelating agent 0.05%, preservative 0.03%, glue
Spend regulator 0.5%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
95%, sodium acetate 1.5% and isopropanol 0.5%.
Embodiment 2
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 8.5%, ethoxylated alkyl sulfate 6.5%, coconut oleoyl amine alkyl amine oxide
1.5%, fattyamidopropyl betaine 0.5%, alkyl poly glucoside 1.0%, cellulose composition 0.5%, chelating agent
0.05%, preservative 0.03%, viscosity modifier 1.0%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
95%, sodium acetate 1.5% and isopropanol 0.5%.
Embodiment 3
A kind of dish washing liquid includes following component by weight percentage:
Ethoxylated alkyl sulfate 13.0%, cocamidopropyl propyl amide amine oxide 7.5%, fattyamidopropyl betaine
2.5%, cellulose composition 0.5%, chelating agent 0.03%, preservative 0.03%, viscosity modifier 2.0%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
95%, sodium acetate 1.5% and isopropanol 0.5%.
Embodiment 4
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 9.0%, ethoxylated alkyl sulfate 5.0%, coconut oleoyl amine alkyl amine oxide
1.5%, cellulose composition 0.5%, chelating agent 0.05%, preservative 0.03%, viscosity modifier 1.0%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
95%, sodium acetate 1.5% and isopropanol 0.5%.
Embodiment 5
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 12.0%, cocamidopropyl propyl amide amine oxide 7.5%, fattyamidopropyl betaine
2.5%, cellulose composition 0.5%, chelating agent 0.05%, preservative 0.03%, viscosity modifier 1.0%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
92.5%, sodium acetate 1.5% and isopropanol 0.5%.
Embodiment 6
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 7.0%, ethoxylated alkyl sulfate 6.0%, cocamidopropyl propyl amide amine oxide
3.5%, fattyamidopropyl betaine 1.5%, cellulose composition 0.5%, chelating agent 0.05%, preservative 0.03%, glue
Spend regulator 1.0%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
95%, sodium acetate 3.0% and isopropanol 2.0%.
Embodiment 7
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 4.0%, ethoxylated alkyl sulfate 10.0%, cocamidopropyl propyl amide amine oxide
7.5%, fattyamidopropyl betaine 2.5%, cellulose composition 0.1%, chelating agent 0.05%, preservative 0.03%, glue
Spend regulator 0.5%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
95%, sodium acetate 1.0% and isopropanol 1.0%.
Embodiment 8
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 4.0%, ethoxylated alkyl sulfate 10.0%, cocamidopropyl propyl amide amine oxide
7.5%, fattyamidopropyl betaine 2.5%, cellulose composition 0.3%, chelating agent 0.05%, preservative 0.03%, glue
Spend regulator 0.5%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
91%, sodium acetate 2.0% and isopropanol 1.0%.
Embodiment 9
A kind of dish washing liquid includes following component by weight percentage:
Alpha-olefin sulfo group sodium sulfonate 10.0%, ethoxylated alkyl sulfate 5.0%, coconut oleoyl amine alkyl amine oxide
1.5%, fattyamidopropyl betaine 0.5%, cellulose composition 0.5%, chelating agent 0.05%, preservative 0.03%, glue
Spend regulator 1.0%, water surplus.
Wherein, cellulose composition mainly by forming following weight percentage components: cationization hydroxyethyl cellulose
95%, sodium acetate 1.5% and isopropanol 0.5%.
Comparative example 1
A kind of dish washing liquid includes following component by weight percentage:
Cocamidopropyl propyl amide amine oxide 7.5%, fattyamidopropyl betaine 2.5%, cellulose composition 0.5%, chela
Mixture 0.05%, preservative 0.03%, viscosity modifier 0.5%, water surplus.
Remaining is same as Example 1.
This comparative example the difference from embodiment 1 is that, be omitted anionic surfactant sodium n-alkylbenzenesulfonate and
Ethoxylated alkyl sulfate.
Comparative example 2
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 4.0%, ethoxylated alkyl sulfate 10.0%, cellulose composition 0.5%, chelating
Agent 0.05%, preservative 0.03%, viscosity modifier 0.5%, water surplus.
Remaining is same as Example 1.
This comparative example the difference from embodiment 1 is that, be omitted zwitterionic surfactant cocamidopropyl propyl amide oxidation
Amine and fattyamidopropyl betaine.
Comparative example 3
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 4.0%, ethoxylated alkyl sulfate 10.0%, cocamidopropyl propyl amide amine oxide
7.5%, fattyamidopropyl betaine 2.5%, chelating agent 0.05%, preservative 0.03%, viscosity modifier 0.5%, more than water
Amount.
This comparative example the difference from embodiment 1 is that, cellulose composition is omitted.
Comparative example 4
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 4.0%, ethoxylated alkyl sulfate 10.0%, cocamidopropyl propyl amide amine oxide
7.5%, fattyamidopropyl betaine 2.5%, hydroxyethyl cellulose 0.5%, chelating agent 0.05%, preservative 0.03%, glue
Spend regulator 0.5%, water surplus.
This comparative example the difference from embodiment 1 is that, cellulose composition is replaced with into hydroxyethyl cellulose.
Comparative example 5
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 4.0%, ethoxylated alkyl sulfate 10.0%, cocamidopropyl propyl amide amine oxide
7.5%, fattyamidopropyl betaine 2.5%, carboxymethyl cellulose 0.5%, chelating agent 0.05%, preservative 0.03%, glue
Spend regulator 0.5%, water surplus.
This comparative example the difference from embodiment 1 is that, cellulose composition is replaced with into carboxymethyl cellulose.
Comparative example 6
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 4.0%, ethoxylated alkyl sulfate 10.0%, cocamidopropyl propyl amide amine oxide
7.5%, fattyamidopropyl betaine 2.5%, cellulose composition 0.02%, chelating agent 0.05%, preservative 0.03%, glue
Spend regulator 0.5%, water surplus.
This comparative example the difference from embodiment 1 is that, the content of cellulose composition is not within the scope of the present invention.
Comparative example 7
A kind of dish washing liquid includes following component by weight percentage:
Sodium n-alkylbenzenesulfonate 2.5%, ethoxylated alkyl sulfate 2.0%, cocamidopropyl propyl amide amine oxide
16.0%, fattyamidopropyl betaine 1.0%, cellulose composition 0.02%, chelating agent 0.15%, preservative 0.6%, glue
Spend regulator 0.01%, water surplus.
This comparative example the difference from embodiment 1 is that, each component content not within the scope of the present invention.
The preparation method of above-described embodiment and the dish washing liquid of comparative example include: according to formula ratio, by each component stirring and
Uniformly.
Comparative example 8
A kind of commercially available dish washing liquid, the clean dish washing liquid of tea.
Performance test
The dish washing liquid of the various embodiments described above and comparative example is tested for the property respectively, test result is as follows shown in table 1.
The various performance parameters of dish washing liquid are measured in accordance with the following methods:
(1) rate is drained
It takes a little sample of the dish washing liquid of each embodiment and comparative example on sponge or cotton, carrying out drenching blistering respectively, uses
The sponge or cotton for having speckled with dish washing liquid sample clean tableware, are then rinsed well, are drained with clear water, respectively record drip
The dry time.
(2) dirt-removing power
According to GB9985-200 " manual dishwashing detergent ", a certain amount of artificial greasy dirt is coated on plate, 2g/L's
It is washed in dish washing liquid solution, is disappeared using surfactant foam layer to half as the terminal washed, record the number of dishwashing, as
The evaluation of dirt-removing power.
(3) foam height
According to GB/T13173.6-91 " detergent foaming power measures (Ross-Miles method) " by detergent sample with centainly
Hardness water is configured to certain testing liquid.Under the conditions of certain temperature, 200mL test solution is flowed into measuring graduates bottom from 90cm height
Behind the surface of the identical test solution of portion mL, foaming power of the foam height measured as the sample.
(4) pH value
It is measured according to GB/T6368 " the measurement potentiometry of aqueous surfactant solution pH value ".
The performance test results of the dish washing liquid of each embodiment and comparative example of table 1
As can be seen from Table 1, the dish washing liquid that 1-9 of the embodiment of the present invention is obtained has preferable dirt-removing power, Draining time
Shorter, pH value is moderate, and performance is mild, illustrates that the dish washing liquid of inventive formulation has and drains rate faster, can reduce washmarking, spot
The generation of point, while dirt-removing power is strong, can reduce the growth risk of bacterium on tableware.
The dish washing liquid of embodiment 1-9 is in decontamination and drains in rate there are a degree of difference, illustrates component in formula
Dosage collocation is different or the concrete type of surfactant is different, the effect of dish washing liquid, can be impacted, wherein embodiment
The dish washing liquid comprehensive performance of 1-3 is preferable, therefore using it as optimization formula.
By comparing the effect of embodiment 1 and comparative example 1-7, illustrate in formula of the invention, anionic surfactant,
There is synergistic effect, and used time, or in suitable content range between zwitterionic surfactant and cellulose composition
It is interior in use, draining rate faster, dirt-removing power is stronger.
By comparing the effect of embodiment 1 and comparative example 8, illustrates that dish washing liquid of the invention greatly improves and drain speed
Rate, dish washing liquid of the invention drain the commercially available dish washing liquid of speed ratio fast 50% or so.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement；And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (10)
1. a kind of dish washing liquid, which is characterized in that the dish washing liquid includes following component by weight percentage:
Anionic surfactant 5-40%, zwitterionic surfactant 0.5-15% and cellulose composition 0.05-
1.0%；
Wherein, the cellulose composition includes cationization hydroxyethyl cellulose, sodium acetate and isopropanol.
2. dish washing liquid according to claim 1, which is characterized in that the dish washing liquid includes by weight percentage as follows
Component: anionic surfactant 6-30%, zwitterionic surfactant 1.0-10% and cellulose composition 0.1-
0.8%；
Preferably, the dish washing liquid includes following component by weight percentage: anionic surfactant 9-15%, both sexes
Ionic surface active agent 1.5-5% and cellulose composition 0.4-0.6%.
3. dish washing liquid according to claim 1, which is characterized in that the cellulose composition is mainly by following weight percent
The group of ratio is grouped as: cationization hydroxyethyl cellulose 90-99.8%, sodium acetate 0.1-5.0% and isopropanol 0.1-5.0%；
Preferably, the cellulose composition mainly by forming following weight percentage components: cationization hydroxy ethyl fiber
Plain 91-98.5%, sodium acetate 0.1-2.5% and isopropanol 0.1-2.5%；
Preferably, the cellulose composition mainly by forming following weight percentage components: cationization hydroxy ethyl fiber
Plain 91-97%, sodium acetate 0.1-1.5% and isopropanol 0.1-1.0%.
4. dish washing liquid according to claim 1-3, which is characterized in that the anionic surfactant includes second
Oxygroup alkyl sulfate, linear alkylbenzene sulfonate (LAS), alkyl sulfate, alpha-olefin sulfo group sodium sulfonate and fatty acid methyl ester sulfonic acid
At least one of salt；
Preferably, the anionic surfactant includes linear alkylbenzene sulfonate (LAS), alpha-olefin sulfo group sodium sulfonate and fatty acid
Any one in methyl ester sulfonate and ethoxylated alkyl sulfates；
Preferably, the anionic surfactant includes ethoxylated alkyl sulfates and linear alkylbenzene sulfonate (LAS).
5. dish washing liquid according to claim 1-3, which is characterized in that the zwitterionic surfactant includes
In fatty amide propyl amine oxide, alkyl dimethyl amine oxide, alkyl dihydroxy ethyl amine oxide and fattyamidopropyl betaine
At least one；
Preferably, the zwitterionic surfactant includes fatty amide propyl amine oxide and/or fatty amide propyl beet
Alkali；
Preferably, the zwitterionic surfactant is fatty amide propyl amine oxide.
6. dish washing liquid according to claim 1-3, which is characterized in that further include nonionic surfactant；
Preferably, the weight percentage of the nonionic surfactant be 0.1-2.5%, preferably 0.1-2.0%, it is more excellent
It is selected as 0.5-1.5%；
Preferably, the nonionic surfactant includes fatty alcohol polyoxyethylene ether, fatty acid methyl ester APEO, alkyl
At least one of alkylolamides polyoxyethylene ether, alkylolamides and alkyl poly glucoside；
Preferably, the nonionic surfactant includes fatty alcohol polyoxyethylene ether and/or alkyl poly glucoside；
Preferably, the nonionic surfactant is fatty alcohol polyoxyethylene ether.
7. dish washing liquid according to claim 1-3, which is characterized in that further include builder；
Preferably, the builder include in chelating agent, preservative, viscosity modifier, stabilizer, structural agent or fragrance at least
It is a kind of；
Preferably, the builder includes chelating agent, preservative and viscosity modifier.
8. dish washing liquid according to claim 7, which is characterized in that the weight percentage of the chelating agent is 0.01-
0.1%, preferably 0.02-0.08%, more preferably 0.03-0.06%；
Preferably, the weight percentage of the preservative be 0.01-0.5%, preferably 0.02-0.4%, more preferably
0.03-0.1%；
Preferably, the weight percentage of the viscosity modifier be 0.01-5.0%, preferably 0.05-3.0%, more preferably
0.1-1.5%.
9. the preparation method of the described in any item dish washing liquids of claim 1-8, which is characterized in that comprise the following steps:
The component of the described in any item dish washing liquids of claim 1-8 is uniformly mixed, the dish washing liquid is obtained.
10. application of the described in any item dish washing liquids of claim 1-8 in daily chemical product field；
Preferably, the daily chemical product includes tableware.
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| CN112812898A (en) * | 2020-12-31 | 2021-05-18 | 山东天和纸业有限公司 | Organic solvent method cellulose detergent and cellulose preparation method |
| CN115948205A (en) * | 2022-12-29 | 2023-04-11 | 广州立白企业集团有限公司 | Dish towel composition and preparation method thereof |
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| CN103261389A (en) * | 2010-10-01 | 2013-08-21 | 罗地亚管理公司 | Detergent composition with anti-potting and/or anti-filming effects |
| CN106118909A (en) * | 2016-06-29 | 2016-11-16 | 宋春燕 | Liquid detergent |
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