CN103301051B - Transparent beauty treatment soap composition - Google Patents
Transparent beauty treatment soap composition Download PDFInfo
- Publication number
- CN103301051B CN103301051B CN201210057880.7A CN201210057880A CN103301051B CN 103301051 B CN103301051 B CN 103301051B CN 201210057880 A CN201210057880 A CN 201210057880A CN 103301051 B CN103301051 B CN 103301051B
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- CN
- China
- Prior art keywords
- beauty treatment
- acid
- weight
- transparent beauty
- transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000344 soap Substances 0.000 title claims abstract description 130
- 239000000203 mixture Substances 0.000 title claims abstract description 125
- 230000003796 beauty Effects 0.000 title claims abstract description 69
- 238000002425 crystallisation Methods 0.000 claims abstract description 31
- 230000008025 crystallization Effects 0.000 claims abstract description 31
- 239000003513 alkali Substances 0.000 claims abstract description 29
- 150000001413 amino acids Chemical class 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 16
- 150000001298 alcohols Chemical class 0.000 claims abstract description 12
- 150000001720 carbohydrates Chemical class 0.000 claims abstract description 11
- 239000000194 fatty acid Substances 0.000 claims description 45
- 150000004665 fatty acids Chemical class 0.000 claims description 44
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 43
- 229930195729 fatty acid Natural products 0.000 claims description 43
- 229940024606 amino acid Drugs 0.000 claims description 25
- 235000001014 amino acid Nutrition 0.000 claims description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- 239000003921 oil Substances 0.000 claims description 23
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 18
- 244000060011 Cocos nucifera Species 0.000 claims description 13
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 10
- -1 acyl glycine potassium Chemical compound 0.000 claims description 10
- 239000005639 Lauric acid Substances 0.000 claims description 9
- 235000021355 Stearic acid Nutrition 0.000 claims description 7
- 239000004359 castor oil Substances 0.000 claims description 7
- 235000019438 castor oil Nutrition 0.000 claims description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 7
- 239000008117 stearic acid Substances 0.000 claims description 7
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 6
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 6
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 5
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 5
- 241001597008 Nomeidae Species 0.000 claims description 5
- 125000002252 acyl group Chemical group 0.000 claims description 5
- 229960002989 glutamic acid Drugs 0.000 claims description 5
- 235000013922 glutamic acid Nutrition 0.000 claims description 5
- 239000004220 glutamic acid Substances 0.000 claims description 5
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 5
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 claims description 4
- 235000021360 Myristic acid Nutrition 0.000 claims description 4
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 4
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 claims description 4
- 229920002690 Polyoxyl 40 HydrogenatedCastorOil Polymers 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 235000021551 crystal sugar Nutrition 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229940065859 sodium cocoyl glycinate Drugs 0.000 claims description 4
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 claims description 4
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 4
- 239000004471 Glycine Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 108010077895 Sarcosine Proteins 0.000 claims description 3
- 230000002421 anti-septic effect Effects 0.000 claims description 3
- 229960002449 glycine Drugs 0.000 claims description 3
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229940043230 sarcosine Drugs 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 3
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical group [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 3
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims description 2
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 claims description 2
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004473 Threonine Substances 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims description 2
- 239000002250 absorbent Substances 0.000 claims description 2
- 229960003767 alanine Drugs 0.000 claims description 2
- 235000004279 alanine Nutrition 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000000043 antiallergic agent Substances 0.000 claims description 2
- 229940070800 myristoyl glutamate Drugs 0.000 claims description 2
- 239000000419 plant extract Substances 0.000 claims description 2
- 108700004121 sarkosyl Proteins 0.000 claims description 2
- 229960003080 taurine Drugs 0.000 claims description 2
- 229960002898 threonine Drugs 0.000 claims description 2
- 235000013343 vitamin Nutrition 0.000 claims description 2
- 239000011782 vitamin Substances 0.000 claims description 2
- 229940088594 vitamin Drugs 0.000 claims description 2
- 229930003231 vitamin Natural products 0.000 claims description 2
- 150000003722 vitamin derivatives Chemical class 0.000 claims description 2
- 239000006260 foam Substances 0.000 abstract description 27
- 238000005406 washing Methods 0.000 abstract description 11
- 239000002253 acid Substances 0.000 abstract description 10
- 238000005187 foaming Methods 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 6
- 125000001931 aliphatic group Chemical group 0.000 abstract description 3
- 235000014633 carbohydrates Nutrition 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000002585 base Substances 0.000 description 26
- 239000013078 crystal Substances 0.000 description 21
- 235000019198 oils Nutrition 0.000 description 17
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 14
- 229920001223 polyethylene glycol Polymers 0.000 description 13
- 238000004140 cleaning Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000005238 degreasing Methods 0.000 description 9
- 238000005755 formation reaction Methods 0.000 description 8
- 239000003925 fat Substances 0.000 description 7
- 150000002885 octadecanoids Chemical class 0.000 description 7
- 235000021314 Palmitic acid Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000007127 saponification reaction Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000001815 facial effect Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000005713 safflower oil Nutrition 0.000 description 2
- 239000003813 safflower oil Substances 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 244000025272 Persea americana Species 0.000 description 1
- 235000008673 Persea americana Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000008365 aqueous carrier Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- TVQGDYNRXLTQAP-UHFFFAOYSA-N ethyl heptanoate Chemical compound CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0095—Solid transparent soaps or detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention belongs to the field of daily chemical goods, and discloses a transparent beauty treatment soap composition. The transparent beauty treatment soap composition includes 5.0-40.0% of aliphatic acid, 0.0-11.2% of an alkali, 1.0-15.0% of an amino acid surfactant, 40.0-70.0% of a crystallization aid, and the balance water; the pH value of the transparent beauty treatment soap composition is 8.0-11.0, and the neutralization of the aliphatic acid and the alkali is 90-100%; and the crystallization aid comprises at least one of alcohols, carbohydrates, and PEG hydrogenation oil and fat. The transparent beauty treatment soap composition which appropriately selects the amino acid surfactant has a very good foaming characteristic, a very good mildness and a very good moistening feeling, greatly improves the foam and the skin feeling and irradiation after washing of a transparent beauty treatment soap using the composition, and allows the transparent beauty treatment soap to have the advantages of very good foaming characteristic, very good mildness, and non-dry and non-tightening good skin feelings after washing.
Description
Technical field
The invention belongs to household chemicals field, relate to a kind of transparent beauty treatment soap composition.
Background technology
" soap base product " typically refers to those main body tables and lives as " RCOO
-" product of analog anion surfactants, its outward appearance can make flow-like (as soap base facial milk cleanser, soap base bath gel; soap base handwashing liquid, liquid soap etc.), paste (as Soap-base facial cleanser; soap base shower cream etc.); Powdered (the clean flour of soap base, soap base shower powder, laundry powdered soap etc.) and solid, shaped (as soap; fancy soap; transparent soap, beauty soap, bath soap etc.) etc.
Solid soap is the type that consumer is familiar the most, can be divided into by use object difference: " soap " that is 1. mainly used in clothes washing, 2. be mainly used in " fancy soap " of washing one's hands or taking a shower, 3. be mainly used in " bath soap " of taking a shower, 4. be mainly used in " beauty soap " of clean etc., above solid soap all can make transparent or opaque outward appearance.
Solid soap application is different, also different to the requirement of its serviceability.As clothes cleaning, what consumer mainly paid close attention to is its cleaning capacity, and the main feature of " soap base product " be exactly there is abundant foam, easily rinse well, degreasing power is strong, washing power is strong, therefore " soap " extraordinaryly can provide the cleaning force needed for clothes cleaning, is therefore widely used in clothes washing.But in skin clean, degreasing power easily brings zest too by force, make the skin after washing dry and astringent tight uncomfortable, therefore, in cleaning products, need in reservation " soap base " good foam performance with while easily rinsing performance, improve the dry and astringent tight shortcoming of not moistening of too strong the brought skin of its degreasing power.Washing one's hands, to take a shower and in clean three types cleaning products, clean product is the highest to the requirement of washing rear skinfeel and product appearance form, is secondly bath product.
" transparent bath soap " or " transparent beauty treatment soap " have sparkling and crystal-clear colourful outward appearance, are more and more subject to the welcome of consumer.But how to ensure product appearance transparency and by rear moist not tight good skinfeel, be the research emphasis of this series products when Formula Development and technological difficulties always.
Summary of the invention
The object of the invention is the above-mentioned deficiency for prior art, a kind of transparent beauty treatment soap composition is provided.
Object of the present invention realizes by following technical scheme:
A kind of transparent beauty treatment soap composition, said composition comprises:
Account for the fatty acid of composition weight 5.0% ~ 40.0%;
Account for the alkali of composition weight 0.0%-11.2%;
Account for the amino acid surfactant of composition weight 1.0% ~ 15.0%;
Account for the crystallization auxiliary of composition weight 40.0% ~ 70.0%;
Surplus is water;
The pH value of described transparent beauty treatment soap composition is 8.0-11.0, and wherein the degree of neutralization of fatty acid and alkali is 90%-100%;
Described crystallization auxiliary is alcohols, saccharide, Polyethylene Glycol, nonyl 2, 2-Oxydiphenol, at least one in alkyl ethoxylated or PEG hydrogenated oil and fat.
Described transparent beauty treatment soap composition, preferably comprises:
Account for the fatty acid of composition weight 10.0% ~ 30.0%;
Account for the alkali of composition weight 1.3%-8.4%;
Account for the amino acid surfactant of composition weight 4.0% ~ 12.0%;
Account for the crystallization auxiliary of composition weight 50.0% ~ 70.0%;
Surplus is water;
The pH value of described transparent beauty treatment soap composition is 9.0-11.0, and wherein the degree of neutralization of fatty acid and alkali is 95%-100%;
Described crystallization auxiliary is alcohols, saccharide, Polyethylene Glycol, nonyl 2, 2-Oxydiphenol, at least one in alkyl ethoxylated or PEG hydrogenated oil and fat.
Described transparent beauty treatment soap composition, preferably comprises further:
Account for the fatty acid of composition weight 12.0% ~ 20.0%;
Account for the alkali of composition weight 1.7%-5.6%;
Account for the amino acid surfactant of composition weight 5.0% ~ 10.0%;
Account for the crystallization auxiliary of composition weight 55.0% ~ 65.0%;
Surplus is water;
The pH value of described transparent beauty treatment soap composition is 9.0-10.0, and wherein the degree of neutralization of fatty acid and alkali is 100%;
Described crystallization auxiliary is alcohols, saccharide, Polyethylene Glycol, nonyl 2, 2-Oxydiphenol, at least one in alkyl ethoxylated or PEG hydrogenated oil and fat.
Detailed Description Of The Invention
The transparent beauty treatment soap composition that the present invention relates to provides foaming abundancy, gentle, washes the performance that rear skinfeel is moistened, and has good transparency.Such performance by compositions but not in compositions a certain component provide.Such compositions comprises solvent, the content limited in the present invention, and the feature of any additional or optional component or restriction, or is made up of them or is substantially made up of them.
Particularly, such compositions, comprise soap base, amino acid surfactant, crystallization auxiliary and water, the interpolation of amino acid surfactant, the degreasing power of formula can be reduced preferably, increase the mildness of formula, improve the foaming properties of formula and use sensation, it is very important for having good foam to formula, obtaining moist not tight rear skinfeel of washing.Adding of crystallization auxiliary, very important effect is played to the transparency of formula, also provide good moisture retention to formula simultaneously.
The solvent of the transparent beauty treatment soap composition that the present invention relates to, and additional or that can optionally add component, using method and production technology are described in detail all hereinafter.
1 solvent
The solvent of transparent beauty treatment soap composition of the present invention comprises soap base, amino acid surfactant, crystallization auxiliary and aqueous carrier, and each in these components is all hereafter being described in detail.
a soap base
Transparent beauty treatment soap composition of the present invention comprises the soap base component being suitable for being applied on skin accounting for composition weight 5.0% to 51.2%.Described soap base component is made up of with the alkali accounting for composition weight 0.0%-11.2% the fatty acid be applied on skin that is suitable for accounting for composition weight 5.0%-40.0%.The consumption of described alkali is determined by the degree of neutralization of fatty acid.This part content relates generally to the detailed description to fatty acid, alkali and degree of neutralization.
a1 fatty acid
Transparent beauty treatment soap composition of the present invention comprises and accounts for composition weight 5.0% to 40.0%, preferred 10.0%-30.0%, further the fatty acid being suitable for being applied on skin of preferred 12.0%-20.0%.Described fatty acid is the compositions of fatty acid, this aliphatic acid composition can give foam, hardness, outward appearance, cleaning force and skinfeel needed for transparent beauty treatment soap composition of the present invention, most importantly, its content of fatty acid preferably accounting for composition weight 12.0%-20.0% is further significantly less than the content of fatty acid (being usually greater than 70%) of normal transparent soap routine, while ensure that good cleaning force, reduce the degreasing power of transparent soap, contribute to reducing transparent beauty treatment soap and wash the tight use sensation of rear drying.
The example being suitable for the fatty acid of transparent beauty treatment soap composition of the present invention includes but not limited to: sad, capric acid, lauric acid, myristic acid, Palmic acid, stearic acid, hexadecanoic acid, octadecanoid acid or its two or more mixture.
The application performance that different fatty acids provides mainly in zest, cleaning force, degreasing power, foaming properties (comprising the size of foam, the uniformity, elasticity, foam stability etc.), formula hardness, outward appearance, wash in rear skinfeel etc. and show diversity.As, 1. the foam that produces of fatty acid is more and more tiny along with the increase of fatty acid molecule amount, foam is also more and more stable simultaneously, but the difficulty that foam generates is also increasing, zest also weakens with the increase of fatty acid molecule amount simultaneously, and the foam produced as lauric acid is maximum, also the most easily disappear, zest is comparatively large, and the foam that octadecanoid acid produces is tiny and lasting, simultaneously gentleer; 2. the fatty acid of high molecular can provide higher hardness to formula; 3. fatty acid soaps has polymorphism, mainly there is the crystal formations such as α, β, δ, ω in its micro structure, and alpha-crystal form and δ crystal formation are unstable, easily change beta crystal or ω crystal formation into, therefore the mixture of soap body in fact mainly β, ω two kinds of crystal formations.The crystal formation affecting transparency then mainly beta crystal, its content more soap bodies transparency is higher.In soap, the ratio of beta crystal increases with hydrophobic group chain length and increases, be in the soap of 8 ~ 12 at hydrophobic group chain carbon atom quantity, beta-crystalline form content is less than 30% (mass percent), when carbon number is 13 ~ 15, beta crystal reaches 50% (mass percent), and when carbon number is 16 ~ 19, beta-crystalline form content can reach 60% (mass percent).Therefore, C in satisfied fatty acid
12~ C
18alkyl fatty acid soap easily reaches transparent, and carbochain is more long more transparent.It is relation between soap crystal phase structure and chemical composition that table 1 lists.
Relation between table 1 soap crystal phase structure and chemical composition
Consider transparency, foam, zest, degreasing power, formula hardness, wash the factors such as rear skinfeel, the fatty acid be preferred in transparent beauty treatment soap composition of the present invention is lauric acid, myristic acid, Palmic acid, stearic acid, at least one in hexadecanoic acid, octadecanoid acid, preferred lauric acid, myristic acid, stearic mixture.The preferred weight ratio of described fatty acid mixt is lauric acid: myristic acid: stearic acid=0 ~ 1: 1 ~ 3: 1 ~ 6, more preferably 0.5 ~ 1: 1 ~ 2.5: 2 ~ 5, most preferably be 1: 1 ~ 2: 2 ~ 4.The preferred 80%-100% of described lauric purity, further preferred 90%-100%, most preferably 95%-100%.The preferred 80%-100% of purity of described myristic acid, more preferably 90%-100%, most preferably 95%-100%.Stearic acid described in the present invention, it is the mixture of hexadecanoic acid and octadecanoid acid, preferred hexadecanoic acid: the mass ratio of octadecanoid acid is the mixture of 10 ~ 80: 90 ~ 20, be more preferably hexadecanoic acid: the mass ratio of octadecanoid acid is the mixture of 40 ~ 80: 60 ~ 20, most preferably is hexadecanoic acid: the mass ratio of octadecanoid acid is the mixture of 60 ~ 80: 40 ~ 20.Described stearic acid, can be commercially available prod, as commodity are called Edernor ST05M (purchased from section's Ninghua work).
a2 alkali
Transparent beauty treatment soap composition of the present invention, its soap base component is obtained by fatty acid and alkali reaction, meets following reaction expression (I):
Wherein, MOH is alkali.
Different alkali, all has impact to the hardness of soap base, foam, outward appearance, skinfeel.The instantiation of preferred alkali, includes but not limited to: KOH, NaOH, NH
4oH, triethanolamine (TEA), or their mixture, more preferably NaOH, KOH, or their mixture, particularly preferably be NaOH.
The consumption of described alkali, outside the Pass having with degree of neutralization, also relevant with the purity of alkali.The preferred > 85% of purity of described alkali, more preferably > 90%, most preferably > 95%.Alkali is very easy to the moisture absorption, it is emphasized that wish each use, all can measure the purity of alkali preferably.
a3 degree of neutralization
Transparent beauty treatment soap composition of the present invention, its soap base component is obtained by fatty acid and alkali reaction.The consumption of described alkali, is determined by preferred degree of neutralization.Described degree of neutralization meets following general formula (II).Degree of neutralization defines the quantity that fatty acid participates in saponification.
When degree of neutralization is 100%, all fatty acids all participate in saponification, and soap base system is by sole component, and namely this anion surfactant of fatty acid soaps is formed.Degree of neutralization less than 100% time, fail for there being partial fatty acid to participate in saponification, soap base is made up of fatty acid soaps (belonging to anion surfactant) and the free fatty (belonging to oils and fats) that has neither part nor lot in saponification.The foam, skinfeel, system stability, production process, hardness, transparency etc. of free fatty to transparent beauty treatment soap all have an impact.
Take into account system stability, hardness, outward appearance, skinfeel, zest, degreasing power etc. factor, what be suitable for the degree of neutralization of fatty acid in transparent beauty treatment soap composition of the present invention ranges preferably from 90%-100%, is more preferably 95%-100%, is finally preferably 100%.
Especially, pH value is another key index of soap base component, with consumption and the degree of neutralization direct correlation of alkali.It is the main criterion of quality control during transparent beauty treatment soap production.The pH value being suitable for transparent beauty treatment soap composition of the present invention is preferably 8.0-11.0, is more preferably 9.0-11.0, is particularly preferably 9.0-10.0.
b amino acid surfactant
Transparent beauty treatment soap composition of the present invention comprises and accounts for composition weight 1.0% to 15.0%, preferably 4.0% to 12.0%, further preferably 5.0% to 10.0% the amino acid surfactant being suitable for being applied on skin.This amino acid surfactant brings abundant foaming properties, lower degreasing power and mildness can to transparent beauty treatment soap composition of the present invention, has very important effect to providing moist not tight rear skinfeel of washing of the present invention.The performance of its use amount on above-mentioned effect simultaneously has impact.This amino acid surfactant, uses in the pH value range that can use in transparent beauty treatment soap of the present invention, and compatible in physical property and chemical property with the soap base component of said composition in this pH value range.
Be applicable to amino acid surfactant described in transparent beauty treatment soap composition of the present invention, mainly refer to N-fatty acyl amino acid salts.Such surfactant is amino acid whose derivant, is obtained by fatty acid chloride.
Described amino acid whose non-limiting example comprises: sarcosine, glycine, glutamic acid, taurine, alanine, threonine, preferred sarcosine, glycine and glutamic acid.
Preferred N-fatty acyl glycine derivative, its structure meets following general formula (III)
Preferred N-fatty acyl sarcosines derivant, its structure meets following general formula (IV)
Preferred N-fatty acyl glutamate derivatives, its structure meets following logical formula V
Wherein, RCO-is fatty acid residue, and applicable fatty acid can be selected from natural origin, and as Oleum Cocois, Petiolus Trachycarpi oil, safflower oil, olive oil, or synthesis source, the carbochain be applicable to is C
8-C
22fatty acid, be preferably C
8-C
18fatty acid, its carbochain composition can be single carbochain, also can be mixing carbochain.Know from other published patents, carbochain has impact to the foam property of transparent beauty treatment soap and hardness.
M
+that hydrogen (sour form) or cationic (salt form) are as K
+, Na
+, NH
4 +, TEA
+.
The non-limiting example of N-fatty acyl amino acid salts comprises: sodium lauroyl sarcosine, potassium lauroyl sarcosine, Hamposyl L triethanolamine, sodium cocoyl glycinate, cocos nucifera oil acyl glycine potassium, cocos nucifera oil acyl glycine triethanolamine, sodium cocoyl glutamate, cocos nucifera oil acyl Kaglutam, cocos nucifera oil acyl glutamic acid triethanolamine, myristoyl-N-methylaminoacetic acid sodium, myristoyl glutamate triethanolamine, or its mixture, preferred sodium lauroyl sarcosine, sodium cocoyl glycinate, cocos nucifera oil acyl glycine potassium, sodium cocoyl glutamate, cocos nucifera oil acyl Kaglutam, more preferably sodium cocoyl glycinate, cocos nucifera oil acyl glycine potassium, finally be preferably cocos nucifera oil acyl glycine potassium (as the product from middle lion chemistry, commodity are called Eversoft
tMyCK-100K, Eversoft
tMyCK-30K, Eversoft
tMyCK etc.).Cocos nucifera oil acyl glycine potassium has the structure similar with fatty acid soaps.
c crystallization auxiliary
Transparent beauty treatment soap composition of the present invention comprises and accounts for composition weight 40% to 70%, preferably 50% to 70%, further preferably 55% to 65% the crystallization auxiliary being suitable for being applied on skin.Adding of crystallization auxiliary has very important effect to the outward appearance of transparent, the pure beauty of product acquisition, also can give product moisture-keeping efficacy simultaneously.This crystallization auxiliary, uses in the pH value range that can use in transparent beauty treatment soap of the present invention, and compatible in physical property and chemical property with other solvents of said composition in this pH value range.
Fatty acid and alkali generation saponification, more holding facile is sodium soap (or potassium) saponification compound, and this compound crystal granule is large, and crystal structure is complicated, and it is disadvantageous for obtaining good transparency to transparent soap.Suitable crystallization auxiliary must be selected, eliminate oarse-grained soap base compound molecule, promote the formation of beta crystal in soap base and suppress the formation of other crystal formations, stop beta crystal to increase simultaneously, maintain minimum crystal grain, crystal grain proper alignment is separated out, system just can be made to obtain good transparency.
Be applicable to the crystallization auxiliary described in transparent beauty treatment soap composition of the present invention, compound mainly containing one or more-OH or-O-group in structure, hydrogen bonded can be formed in aqueous medium with water or other materials (particularly water-insoluble), increase the dissolubility of other materials in water, change its adhesion in water.The non-limiting example of the crystallization auxiliary be applicable to comprises: alcohols, saccharide, Polyethylene Glycol, nonyl 2, 2-Oxydiphenol, alkyl ethoxylated, PEG hydrogenated oil and fat, or its mixture etc., preferred alcohols, saccharide, PEG hydrogenated oil and fat, or its mixture, more preferably alcohols, saccharide, the mixture of PEG hydrogenated oil and fat.
Described alcohols, refer to that carbon number is monohydric alcohol, dihydroxylic alcohols or the polyhydric alcohol of 1 ~ 10, applicable example includes but not limited to: ethanol, ethylene glycol, glycerol, isopropyl alcohol, 1,2-PD, 1,4-butanediol, hexanediol, sorbitol, one or more in citronellol; One or more in preferred alcohol, 1,2-PD, glycerol; Be more preferably the mixture of ethanol, 1,2-PD, glycerol.The weight ratio of preferred ethanol, 1,2-PD, glycerol mixture is ethanol: 1,2-PD: glycerol=0.5 ~ 1.0: 0.5 ~ 1.0: 0.5 ~ 1.0; The weight of this mixture preferred accounts for crystallization auxiliary weight 30% to 40%.
Described saccharide, the example be applicable to includes but not limited to: white sugar, crystal sugar, remelt sugar, one or more in brown sugar, glucose, Mel, xylitol, one or more in preferred crystal sugar, Mel, white sugar, are more preferably a kind of in crystal sugar, white sugar or both mixture.The weight of this mixture preferred accounts for crystallization auxiliary weight 30% to 40%.
Described PEG hydrogenated oil and fat, mainly refer to PEG castor oil hydrogenated, the example be applicable to includes but not limited to: one or more in Cremophor RH40, PEG-60 castor oil hydrogenated, PEG-80 castor oil hydrogenated, is preferably a kind of in Cremophor RH40, PEG-60 castor oil hydrogenated or both mixture.Described Cremophor RH40, commodity are called Cremopher
(available from BASF), described PEG-60 castor oil hydrogenated, commodity are called Cremopher
(available from BASF).The weight of this mixture preferred accounts for crystallization auxiliary weight 30% to 40%.
Be suitable for the crystallization auxiliary in transparent beauty treatment soap composition of the present invention, by said mixture, one or more form, preferably two kinds of mixture compositions, are more preferably three kinds of mixture compositions.
Described crystallization auxiliary, when the distribution between the soap base molecule of its consumption and proportioning and water, beta crystal reaches balance, just can present pellucidity, if but its distribution is uneven time, transparency can decline gradually and even disappear.The key factor of impact balance is the ratio of each component in the consumption of crystallization auxiliary and crystallization auxiliary, therefore strictly controls to be necessary to the consumption of preferred each component and ratio.
2 optional components
Transparent beauty treatment soap composition of the present invention in some embodiments, also comprises other additional optional components that are known or that be effectively adapted at skin uses.The weight of this optional components accounts for 0.0% to 15.0% of composition weight, and preferably about 0.01% to 10.0%, more preferably about 0.1% to 4.0%.This optional component, should be compatible in physical property and chemical property with the solvent of compositions of the present invention, should to the hardness of transparent beauty treatment soap, foam, stability, and outward appearance etc. produce harmful effect, and should meet the requirement of cosmetics health specification.
Non-limiting examples for the optional components in transparent beauty treatment soap composition of the present invention comprises: skinfeel improving agent, essence, antiseptic (as DMDM Hydantoin), pigment, active component is (as heat sensitizer, cool feeling agent, antibacterial, vitamin and derivant thereof), anti-allergic agent, UV absorbent, plant extract etc.
The non-limiting examples of described skinfeel improving agent comprises: the material of plant origin, as Oleum Camelliae, American Avocado Tree oil, Oleum Vitis viniferae, safflower oil, Bai Manghua seed wet goods.
In aminoacid beauty treatment soap composition of the present invention, except the above component, mend to aequum with water.
Beneficial effect of the present invention:
The amino acid surfactant that the present invention appropriately selects, there is extraordinary spumescence, mildness and moisture feeling, make the foam of transparent beauty treatment soap, wash rear skinfeel and zest is improved greatly, impart the extraordinary spumescence of transparent beauty treatment soap, mildness and wash rear moist not tight good skinfeel.
The crystallization auxiliary that the present invention appropriately selects, can make the distribution between water and beta crystal soap base molecule reach good poised state, thus make system present required transparency.
Therefore, transparent beauty treatment soap composition of the present invention has abundant foam, and what gentleness was moistened washes rear skin and good transparency.
3 usings method
Transparent beauty treatment soap composition of the present invention may be used for cleaning of face and cleaning of health, and use in the mode of the clean skin of routine, concrete steps are as follows:
Facial cleansing:
(A) with water by face and both hands moistening;
(B) transparent beauty treatment soap is got in wiping on hand repeatedly, to obtain the soap body of effective dose.Described wiping number of times, usually at 5 times to 30 times, preferably 10 times to 20 times; The scope of described effective dose usually at 0.1 gram to 3 grams, preferably 0.3 gram to 2 grams.
(C) drip a small amount of water (1.0g-5.0g) in the palm of the hand, both hands are rubbed to a large amount of foam of generation;
(D) both hands with a large amount of foam to be washed by rubbing with the hands gently on the face and massaged;
(E) finally foam is on the face rinsed well with clear water.
Clean body:
(A) by health moistening;
(B) directly by transparent beauty treatment soap on parts of body wiping repeatedly, to obtain the soap body of effective dose.Described wiping number of times, usually at 1 time to 10 times, preferably 2 times to 5 times.The scope of described effective dose normally about 0.1 gram to 15 grams, is preferably about 1.0 grams to 5.0 grams;
(C) directly with the hands or use bathing appliance (as wash towel, marine sponge, Fructus Luffae wipings, bath balls, bath flower, body friction brush, massage brush, towel for rubbing back, wash gloves, band bath flower wash gloves, band bath flower are given a rubdown with a damp towel to draw and carried on the back bar, rectangular towel for rubbing back etc.) to dab back and forth on parts of body, clean skin to produce foam simultaneously;
(D) finally foam is with it rinsed well with clear water.
Each clean face and health, as required, can carry out above-mentioned steps one or many, until reach clean requirement, is preferably once.
Above-mentioned steps can carry out one or many as required every day, to reach sought clean, moist effect.
4 preparation methoies
Transparent beauty treatment soap composition of the present invention can by any known or other be effectively applicable to provide the technology of transparent soap compositionv to prepare.The method preparing transparent beauty treatment soap composition of the present invention mainly adopts casting production technology.
Detailed description of the invention
Here is the non-limiting example of transparent beauty treatment soap of the present invention.Providing of these examples is only used to illustration purpose, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.
In these examples, unless stated otherwise, all concentration is all percentage by weight.Term used " a small amount of material " refers to those optional materials, and as antiseptic, essence, pigment etc., the selection of these a small amount of materials changes along with selected in order to prepare the physics and chemistry characteristic of special component of the present invention.
Preparation example I-VIII and Comparative Examples I-IV
The suitable method preparing example I-VIII and the transparent beauty treatment soap composition described in Comparative Examples I-IV is as follows:
1) A phase (being made up of fatty acid, amino acid surfactant and alcohols) is added in reactor, be heated to 65 DEG C-70 DEG C;
2) B phase (being made up of alkali and water) is added in reactor, insulated and stirred 30 minutes-40 minutes;
3) add C phase (being made up of saccharide, PEG castor oil hydrogenated), be warming up to 80 DEG C-85 DEG C, insulated and stirred 30 minutes-40 minutes;
4) when temperature is down to 40 DEG C ~ 50 DEG C, add D phase, after stirring, insulation leaves standstill;
5) blowing, is cast in mould;
6) demoulding after cooling forming, dries.
Table 2 example I-IV
Table 3 EXAMPLE V-VIII
Table 4 Comparative Examples I-IV
The stearic acid used in above-mentioned formula is commercially available prod, and commodity are called Edernor ST05M (purchased from section's Ninghua work).
Applicating evaluating
Applicating evaluating comprises ocular estimate and use sense evaluation.
Select 30 testers (each 15 people of men and women, age bracket 15 years old-55 years old), Blind Test is carried out to example I-VIII and Comparative Examples I-IV.Each embodiment and comparative example parallel assay 3 times.Tester feels to mark according to the application of oneself, and assessment item relates to foaming abundancy degree, washes rear skinfeel (gentle, moisten, moist not tight etc.) and transparency.Standards of grading adopt 5 points of systems, and 1 point the poorest, and 5 points best.Evaluation result is the average mark of all tester's marks, and the higher effect of average mark is better.
The method of described ocular estimate is: the transparency seeing No. 14 (4mm) boldface types when the soap blank thick by 6.35mm (1/4 inch) clearly is qualified; Otherwise, can not see clearly but have certain transparency for defective; Completely opaque, transparency is nothing; The soap transparency seeing No. 12 boldface types when the soap blank thick by 6.35mm (1/4 inch) clearly is medium; When the soap blank thick by 6.35mm (1/4 inch) can see the soap transparency of No. 10 boldface types clearly as well.
Described use sense evaluation methodology is: with water by face and both hands moistening; Get transparent beauty treatment soap wiping on hand 10 times, drip 2.0g water in the palm of the hand, both hands are rubbed to a large amount of foam of generation; Both hands with a large amount of foam to be washed by rubbing with the hands gently on the face and massaged; Finally rinse foam on the face well with clear water.
The application sense evaluation result of embodiment and comparative example lists in table 5.
Table 5 embodiment and comparative example application sense evaluation result
| Transparency | Foaming abundancy degree | Wash rear skinfeel | |
| Example I | 4.5 | 3.5 | 4.5 |
| Example II | 4.5 | 3.5 | 4.5 |
| EXAMPLE III | 4.0 | 4.5 | 4.0 |
| EXAMPLE IV | 4.5 | 4.5 | 4.0 |
| EXAMPLE V | 4.0 | 4.0 | 3.5 |
| Example VI | 4.2 | 4.5 | 4.8 |
| Example VII A | 4.0 | 4.5 | 4.6 |
| Example VII A I | 4.5 | 4.5 | 4.0 |
| Comparative Examples I | 1.0 | 4.5 | 1.0 |
| Comparative Example II | 1.0 | 4.5 | 1.0 |
| Comparative Example II I | 1.0 | 4.0 | 1.0 |
| Comparative Examples I V | 1.0 | 4.0 | 1.0 |
Claims (1)
1. a transparent beauty treatment soap composition, is characterized in that said composition comprises:
Account for the fatty acid of composition weight 12.0% ~ 20.0%;
Account for the alkali of composition weight 1.7%-5.6%;
Account for the amino acid surfactant of composition weight 5.0% ~ 10.0%;
Account for the crystallization auxiliary of composition weight 55.0% ~ 65.0%;
Account for the optional components of 0.0% to 15.0% of composition weight;
Surplus is water;
The pH value of described transparent beauty treatment soap composition is 9.0-10.0, and wherein the degree of neutralization of fatty acid and alkali is 100%;
Described crystallization auxiliary is alcohols, saccharide, the mixture of PEG hydrogenated oil and fat; Described alcohols is the mixture of ethanol, 1,2-PD, glycerol, and its weight accounts for crystallization auxiliary weight 30% to 40%; Described saccharide is the mixture of crystal sugar and white sugar, and its weight accounts for crystallization auxiliary weight 30% to 40%; Described PEG hydrogenated oil and fat is the mixture of Cremophor RH40 and PEG-60 castor oil hydrogenated, and its weight accounts for crystallization auxiliary weight 30% to 40%;
Described fatty acid is selected from lauric acid, myristic acid, stearic mixture, and weight ratio is lauric acid: myristic acid: stearic acid=0 ~ 1: 1 ~ 3: 1 ~ 6;
Described optional components comprises: essence, antiseptic, pigment, active component, anti-allergic agent, one or more in UV absorbent or plant extract; Described active component is selected from heat sensitizer, cool feeling agent, antibacterial, one or more in vitamin and derivant thereof.
2, transparent beauty treatment soap composition according to claim 1, is characterized in that lauric acid: myristic acid: stearic weight ratio is 0.5 ~ 1: 1 ~ 2.5: 2 ~ 5.
3, transparent beauty treatment soap composition according to claim 2, is characterized in that lauric acid: myristic acid: stearic weight ratio is 1: 1 ~ 2: 2 ~ 4.
4, transparent beauty treatment soap composition according to claim 1, is characterized in that described alkali is selected from KOH, NaOH, NH
4oH, triethanolamine, or their mixture.
5, transparent beauty treatment soap composition according to claim 1, is characterized in that described amino acid surfactant is selected from N-fatty acyl amino acid salts, and described N-fatty acyl amino acid salts is amino acid whose derivant, is obtained by fatty acid chloride; Described aminoacid is selected from sarcosine, glycine, glutamic acid, taurine, alanine or threonine.
6, transparent beauty treatment soap composition according to claim 1, is characterized in that described amino acid surfactant is selected from sodium lauroyl sarcosine, potassium lauroyl sarcosine, Hamposyl L triethanolamine, sodium cocoyl glycinate, cocos nucifera oil acyl glycine potassium, cocos nucifera oil acyl glycine triethanolamine, sodium cocoyl glutamate, cocos nucifera oil acyl Kaglutam, cocos nucifera oil acyl glutamic acid triethanolamine, myristoyl-N-methylaminoacetic acid sodium, myristoyl glutamate triethanolamine, or their mixture.
7, transparent beauty treatment soap composition according to claim 1, is characterized in that the weight ratio of three in the mixture of described ethanol, 1,2-PD, glycerol is ethanol: 1,2-PD: glycerol=0.5 ~ 1.0: 0.5 ~ 1.0: 0.5 ~ 1.0.
8, transparent beauty treatment soap composition according to claim 1, is characterized in that the consumption of described optional components accounts for 0.01% to 10.0% of composition weight.
9, transparent beauty treatment soap composition according to claim 8, is characterized in that the consumption of described optional components accounts for 0.1% to 4.0% of composition weight.
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| CN201210057880.7A CN103301051B (en) | 2012-03-07 | 2012-03-07 | Transparent beauty treatment soap composition |
| PCT/CN2012/074069 WO2013131307A1 (en) | 2012-03-07 | 2012-04-16 | Transparent beauty soap composition |
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|---|---|---|---|
| CN201210057880.7A CN103301051B (en) | 2012-03-07 | 2012-03-07 | Transparent beauty treatment soap composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115315244B (en) * | 2020-03-31 | 2024-07-30 | 联合利华知识产权控股有限公司 | Cleaning composition |
Also Published As
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| WO2013131307A1 (en) | 2013-09-12 |
| CN103301051A (en) | 2013-09-18 |
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