CN106497712B - A kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof - Google Patents
A kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof Download PDFInfo
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- CN106497712B CN106497712B CN201610785221.3A CN201610785221A CN106497712B CN 106497712 B CN106497712 B CN 106497712B CN 201610785221 A CN201610785221 A CN 201610785221A CN 106497712 B CN106497712 B CN 106497712B
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- acid
- amino acid
- liquid detergent
- containing amino
- underwear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention belongs to daily use chemicals technical field, do not washed clean to solve existing liquid detergent drift, dirt-removing power is poor, the shortcomings of hindering hand, and the present invention provides a kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof.Laundry liquid formulation of the present invention is ethoxylated alkyl sulfate, fatty alcohol polyoxyethylene ether, saturated fatty acid, unrighted acid, alkali, Citric Acid Mono, disodium ethylene diamine tetraacetate, lauroyl amido propyl betaine, amino acid surfactant, sodium chloride, styrene acrylic copolymer, essence, preservative and deionized water, liquid detergent each component of the present invention cooperates, strong detergency, easily rinsing, it is skin friendly, both hands are takeed good care of, without soapy feeling during hand washing.
Description
Technical field
The invention belongs to daily use chemicals technical field, and in particular to a kind of easy rinsing underwear liquid detergent and its system containing amino acid
Preparation Method.
Background technology
Liquid detergent, main component are nonionic surface active agent, its structure includes water-wet side and hydrophobic end, wherein oleophylic
End is combined with spot, then separates spot and fabric by physical motion (such as hand rubbing, machine movement)；Surfactant at the same time
The tension force of water is reduced, enables water to reach fabric face, active ingredient is played a role；The technology content higher of liquid detergent, just
In adding various active ingredients, clothing can be made fluffy, soft, smooth glossy after washing, and the work(with degerming and lasting lasting
Effect, it is low using comprehensive cost, just widely received by people.
Chinese patent application CN104212659A discloses a kind of ecology laundry liquid, and main component includes end group of amino acid
Methoxypolyethylene glycol-polylactide block copolymer, coconut oleoyl diethanol amine, methyl p-hydroxybenzoate and para hydroxybenzene first
Propyl propionate etc..Laundry using methoxypolyethylene glycol-polylactide block copolymer of end group of amino acid as principal surfactant
Liquid, its strong detergency, foam are low；There is a preferable Environmental compatibility at the same time, no biotoxicity and biodegradable, to environment friend
It is good, but amino acid type surfactant dosage has reached 22-30% in the invention, amino acid pattern activating agent dosage is not more
Better, compatibility is unreasonable, and the methyl p-hydroxybenzoate and propylparaben that use are discharged into water, are easily made
Into water pollution.
Chinese patent CN103451037B discloses a kind of bactericidal liquid detergent containing epsilon-polylysine, and the present invention relates to one kind
Bactericidal liquid detergent containing epsilon-polylysine.The bactericidal liquid detergent raw material includes surfactant, anti redeposition agent, chelating agent, increasing
Thick dose, epsilon-polylysine, essence.The invention is using epsilon-polylysine as fungicide, and restraining and sterilizing bacteria significant effect is safe,
Meet demand of the consumer to natural prodcuts.It is apt to deteriorate but amino acid composition is unstable, influence the soil release performance of liquid detergent
Energy.
The content of the invention
In order to solve decontamination force difference existing in the prior art, it is of high cost, be not easy to rinse the deficiencies of, the present invention provides one
The easy rinsing underwear liquid detergent of kind containing amino acid and preparation method thereof, is matched somebody with somebody using amino acid type surfactant and other components
5, the detergency of liquid detergent is improved, easily rinsing and nonirritant performance.
To achieve the above object, the present invention uses following technical scheme.
A kind of easy rinsing underwear liquid detergent containing amino acid, key component and its percentage by weight are：Ethoxylated alkyl
Sodium sulphate 2-10%, fatty alcohol polyoxyethylene ether 1-5%, saturated fatty acid 1-5%, unrighted acid 1-5%, alkali 1.0-
1.5%th, Citric Acid Mono 0.1-3%, disodium ethylene diamine tetraacetate 0.1-1.0%, lauroyl amido propyl betaine 0.2-
5%th, amino acid surfactant 0.2-5%, sodium chloride 0.2-3%, styrene acrylic copolymer 0.08-0.12%, essence
0.1-0.2%, preservative 0.08-0.12% and water 70-90%.
Styrene acrylic copolymer：Ou Nuo forensic chemistries (Shanghai) Co., Ltd., article No. TILAMARTMOP40
Preferably, key component and its percentage by weight are：Ethoxylated alkyl sulfate 3-7%, fatty alcohol polyoxy second
Alkene ether 1-3%, saturated fatty acid 3-5%, unrighted acid 1-3%, alkali 1.1-1.3%, Citric Acid Mono 0.1-0.5%,
Disodium ethylene diamine tetraacetate 0.1-0.2%, lauroyl amido propyl betaine 1-3%, amino acid surfactant 1.5-
2.5%th, sodium chloride 1-2%, styrene acrylic copolymer 0.08-0.12%, essence 0.1-0.15%, preservative 0.1-
0.12% and water 78-82%.
Preferably, the saturated fatty acid is a kind of in laurate, myristic acid, palmitic acid and stearic acid or two kinds
Combination of the above.
Preferably, the unrighted acid combines for oleic acid with one or two kinds of in linoleic acid.
Preferably, the alkali combines for sodium hydroxide with one or two kinds of in potassium hydroxide.
Preferably, the fatty alcohol polyoxyethylene ether combines for AEO-7 with one or two kinds of in AEO-9.
Preferably, the amino acid surfactant is cocoyl Sodium Glycinate, cocoyl glycine potassium, bay
Acyl glutamic acid sodium is combined with one or more kinds of in lauroyl glutamate potassium.
Preferably, the preservative is Kathon CG.
Further, present invention also offers the preparation method of the easy rinsing underwear liquid detergent containing amino acid, step to be,
S1：Temperature rise period, sodium chloride and alkali are added into deionized water, is heated while stirring, after being warming up to 55-65 DEG C,
Saturated fatty acid and unrighted acid are added, continues stirring and is warming up to 75-85 DEG C, and insulated and stirred reaction 25-40min, obtain
Uniform mixed liquor；
S2：Temperature-fall period, when the uniform mixed liquor that step S1 is obtained is cooled to 55-65 DEG C, adds ethoxylated alkyl
Sodium sulphate, fatty alcohol polyoxyethylene ether, amino acid type surfactant, lauroyl amido propyl betaine, Citric Acid Mono and
Disodium ethylene diamine tetraacetate, stirs evenly, and when continuing to be cooled to 35-45 DEG C, adds essence and preservative while stirring, stirring is equal
It is even to obtain mixed liquor；
S3：Styrene acrylic copolymer, deionized water and styrene acrylic copolymer volume are diluted with deionized water
Than for 12-18:1, stir evenly, then add in the mixed liquor obtained by step S2, stir evenly, to obtain the final product.
The present invention has the prior art to compare, and has the following advantages：
1st, dirt-removing power is strengthened：The present invention generates soap base when making using the reaction of the component such as alkali and aliphatic acid, oleic acid, its
The alkali metal salt of middle oleic acid is a kind of preferable emulsifying agent, is conducive to mutually merge between component in liquid detergent, and can be with it
His component compatibility reaches chelated metal ions, strengthens dirt-removing power；
2nd, do not stimulate gently：Since fatty acid soaps have irritation to skin, amino acid type surfactant can be therewith
Compatibility, reduces irritation, and oleic acid and soap base irritation that Citric Acid Mono generate are small in the present invention, and mutually compatibility reduction is pierced
Swash property；
3rd, easily rinsing：The present invention has drop bubble, subtracts sliding effect using soap base surfactant decontamination.
The clothing washed using the underwear liquid detergent of the present invention, all kinds of soap bases of introducing can be quick in the water of high rigidity
All kinds of heavy metal ion are chelated, make surfactant high-effective cleansing in formula system；It can play very well in the water of soft
Surface-active, other surfaces activating agent, which cooperates, in formula removes all kinds of spots.Component provided by the invention and proportion be through
Cross substantial amounts of experimental verification to obtain, interact, complement each other between component, there is good decontamination, do not stimulate, what is easily rinsed is good
Good performance.
Embodiment
The present invention is described in further detail below by embodiment, but the implementation of the present invention is not limited to this.(1)
Embodiment 1-4 and laundry liquid formulation made from comparative example 1-5 are as shown in table 1 below：
The formula of liquid detergent made from 1. embodiment 1-4 of table and comparative example 1-5
Comparative example 1 and the difference of embodiment 1 are：Do not add saturated fatty acid；
Comparative example 2 and the difference of embodiment 1 are：Do not add amino acid type surfactant；
Comparative example 3 and the difference of embodiment 1 are：Use more amino acid type surfactant；
Comparative example 4 and the difference of embodiment 1 are：Ethoxylated alkyl sulfate and lauroyl aminocarbonyl propyl beet are not added
Alkali；
Comparative example 5 and the difference of embodiment 1 are：Oily bronsted lowry acids and bases bronsted lowry is not added；
Embodiment 1-4 and comparative example 1-5 production methods are as follows：
S1：Temperature rise period, sodium chloride, alkali are added into deionized water, is heated while stirring, and after being warming up to 60 DEG C, are added
Saturated fatty acid and unrighted acid, continue stirring and are warming up to 80 DEG C, and insulated and stirred reaction 30min, obtain uniform mixed liquor；
S2：Temperature-fall period, when the uniform mixed liquor that step S1 is obtained is cooled to 60 DEG C, adds ethoxylated alkyl sulfates
Sodium, fatty alcohol polyoxyethylene ether, amino acid type surfactant, lauroyl amido propyl betaine, Citric Acid Mono and second two
Amine tetraacethyl disodium, stirs evenly, and when continuing to be cooled to 40 DEG C, adds essence and preservative while stirring, stirring evenly to mix
Close liquid；
S3：Styrene acrylic copolymer, deionized water and styrene acrylic copolymer volume are diluted with deionized water
Than for 15:1, stir evenly, then add in the mixed liquor obtained by step S2, stir evenly, to obtain the final product.
(2) detergency test is tested
Test object：Liquid detergent made from embodiment 1-4, comparative example 1-5 and two kinds of commercial laundry liquid.
Test method：According to GB/T13174-2008《Dress material detergent detergency and the measure of circulation scourability》In
Defined method is tested, and test detergency ratio result is as shown in table 2 below.
Liquid detergent made from 2. embodiment 1-4 of table and comparative example 1-5 and commercial laundry liquid detergency ratio
| Product | Carbon black soiled cotton | Sebum soiled cotton |
| Embodiment 1 | 1.35 | 1.39 |
| Embodiment 2 | 1.32 | 1.36 |
| Embodiment 3 | 1.30 | 1.35 |
| Embodiment 4 | 1.29 | 1.32 |
| Comparative example 1 | 0.98 | 1.12 |
| Comparative example 2 | 1.10 | 0.95 |
| Comparative example 3 | 1.05 | 1.01 |
| Comparative example 4 | 0.91 | 0.96 |
| Comparative example 5 | 1.06 | 1.10 |
| Commercial laundry liquid 1 | 1.12 | 1.10 |
| Commercial laundry liquid 2 | 1.09 | 1.05 |
| Standard liquid detergent | 1 | 1 |
Liquid detergent detergency is relatively good made from embodiment 1-4 as can be seen from Table 2, wherein the decontamination effect of embodiment 1
Fruit is best.In addition, from comparative example 1-5 compared with embodiment 1-4, the content of each component in laundry liquid formulation is to liquid detergent
Dirt-removing power have important influence, and the more detergencies of non-surface-active agent are stronger.
(3) the easy evaluating rinsing performance of liquid detergent
Subjects：Embodiment 1-4, liquid detergent made from comparative example 1-5, commercial laundry liquid 1-2.
Experiment material：Use GB/T13174-2008《Dress material detergent detergency and the measure of circulation scourability》In
Hard water, the cotton woven fabric of 10 × 10cm.
Experimental method：3ml liquid detergents are put into the beaker equipped with 500ml hard water, 1min is stirred, is put into one piece of woven fabric,
Continue after stirring 30min, stop stirring, wring out and (keep three times that wet cloth is dry cloth weight), aforesaid operations are repeated, until stopping
Bubble is wholly absent in 5 seconds after stirring, is stopped operation, and counts number of repetition, as shown in table 3 below.
Liquid detergent made from 3 embodiment 1-4 of table and comparative example 1-5 and commercial laundry liquid rinsing times
| Product | Number of repetition |
| Embodiment 1 | 2 |
| Embodiment 2 | 2 |
| Embodiment 3 | 3 |
| Embodiment 4 | 3 |
| Comparative example 1 | 5 |
| Comparative example 2 | 5 |
| Comparative example 3 | 5 |
| Comparative example 4 | 5 |
| Comparative example 5 | 6 |
| Commercial laundry liquid 1 | 5 |
| Commercial laundry liquid 2 | 6 |
| Standard liquid detergent | 6 |
From table 3 it is observed that embodiment 1-4 liquid detergents are more easy to rinse.In addition, by comparative example 1-5 and embodiment 1-4 ratios
Relatively understand, the content of each component in laundry liquid formulation has important influence to the easy rinsing performance of liquid detergent.
(4) liquid detergent irritation test
Test object：Liquid detergent and two kinds of commercial laundry liquid prepared by embodiment 1-4 and comparative example 1-5
Test method：Tester with the aqueous solution hand wash laundry 15 minutes for being mixed with 0.3% liquid detergent, collects test respectively
Person is to irritating assessment data.
Test result：Every group of 10 bit test persons, respectively using being mixed with washing prepared by embodiment 1-4 and comparative example 1-5
After the aqueous solution hand wash laundry of clothing liquid and two kinds of commercial laundry liquid, 10 bit test persons are calculated to liquid detergent irritation average ratings point
(10 without any irritation, 1 most strong and stimulating), as shown in table 4.
The nonirritant evaluation of 4 liquid detergent of table
| Product | Average nonirritant evaluation score value |
| Embodiment 1 | 10 |
| Embodiment 2 | 10 |
| Embodiment 3 | 9 |
| Embodiment 4 | 9 |
| Comparative example 1 | 4 |
| Comparative example 2 | 7 |
| Comparative example 3 | 6 |
| Comparative example 4 | 8 |
| Comparative example 5 | 7 |
| Commercial laundry liquid 1 | 7 |
| Commercial laundry liquid 2 | 7 |
| Standard liquid detergent | 6 |
From table 4, it can be seen that liquid detergent made from embodiment 1-4 is small to skin irritation, also, by comparative example 1-5 with
Embodiment 1-4 relatively understands, the content of each component in laundry liquid formulation to liquid detergent it is gentle, not stimulate performance to have important
Influence.
In conclusion liquid detergent each component disclosed in this invention cooperates, strong detergency, easily rinsing are skin friendly,
Both hands are takeed good care of, without soapy feeling during hand washing.
The technology contents described above that the present invention is only further illustrated with embodiment, in order to which reader is easier to understand,
But embodiments of the present invention are not represented and are only limitted to this, any technology done according to the present invention extends or recreation, is sent out by this
Bright protection.
Claims (4)
1. a kind of easy rinsing underwear liquid detergent containing amino acid, it is characterised in that be made of following components and its percentage by weight：
Ethoxylated alkyl sulfate 2-10%, fatty alcohol polyoxyethylene ether 1-5%, saturated fatty acid 1-5%, unrighted acid 1-5%,
Alkali 1.0-1.5%, Citric Acid Mono 0.1-3%, disodium ethylene diamine tetraacetate 0.1-1.0%, lauroyl amido propyl betaine 0.2-
5%th, amino acid surfactant 0.2-5%, sodium chloride 0.2-3%, styrene acrylic copolymer 0.08-0.12%, essence 0.1-
0.2%th, preservative 0.08-0.12% and deionized water 70-90%；The saturated fatty acid is laurate, myristic acid, palm
A kind of or two or more combinations in acid and stearic acid；The unrighted acid is oleic acid and one or two in linoleic acid
Combination；The alkali combines for sodium hydroxide with one or two kinds of in potassium hydroxide；The amino acid surfactant is coconut palm
One kind or two in oleoyl Sodium Glycinate, cocoyl glycine potassium, sodium lauroyl glutamate and lauroyl glutamate potassium
Kind combination of the above.
2. the easy rinsing underwear liquid detergent according to claim 1 containing amino acid, it is characterised in that by following components and its
Percentage by weight forms：Ethoxylated alkyl sulfate 3-7%, fatty alcohol polyoxyethylene ether 1-3%, saturated fatty acid 3-5%, no
Saturated fatty acid 1-3%, alkali 1.1-1.3%, Citric Acid Mono 0.1-0.5%, disodium ethylene diamine tetraacetate 0.1-0.2%, lauroyl
Aminocarbonyl propyl glycine betaine 1-3%, amino acid surfactant 1.5-2.5%, sodium chloride 1-2%, styrene acrylic copolymer
0.08-0.12%, essence 0.1-0.15%, preservative 0.1-0.12% and deionized water 78-82%.
3. the easy rinsing underwear liquid detergent according to claim 1 or 2 containing amino acid, it is characterised in that the fat
Alcohol polyoxyethylene ether combines for AEO-7 with one or two kinds of in AEO-9.
4. the easy rinsing underwear liquid detergent according to claim 1 or 2 containing amino acid, it is characterised in that the anti-corrosion
Agent is Kathon CG.
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| CN201610785221.3A CN106497712B (en) | 2016-08-31 | 2016-08-31 | A kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof |
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| CN107057888A (en) * | 2017-06-17 | 2017-08-18 | 安徽方翔羽绒制品有限公司 | A kind of preparation method of feather products cleaning agent |
| CN107418772A (en) * | 2017-06-17 | 2017-12-01 | 安徽方翔羽绒制品有限公司 | A kind of preparation method of the cleaning agent of down products |
| CN109294763A (en) * | 2018-11-22 | 2019-02-01 | 中山榄菊日化实业有限公司 | A kind of full effect muting sensitive surface activator composition and the liquid detergent containing it |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102492574A (en) * | 2011-12-13 | 2012-06-13 | 江南大学 | Tableware detergent containing N-acylglutamate |
| CN104540551A (en) * | 2012-05-30 | 2015-04-22 | 科莱恩金融(Bvi)有限公司 | Composition containing amino acid surfactants, betaines and N-methyl-N-acylglucamines and having improved foam quality and higher viscosity |
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2016
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102492574A (en) * | 2011-12-13 | 2012-06-13 | 江南大学 | Tableware detergent containing N-acylglutamate |
| CN104540551A (en) * | 2012-05-30 | 2015-04-22 | 科莱恩金融(Bvi)有限公司 | Composition containing amino acid surfactants, betaines and N-methyl-N-acylglucamines and having improved foam quality and higher viscosity |
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