CN102586039A - Clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt - Google Patents

Clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt Download PDF

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Publication number
CN102586039A
CN102586039A CN2012100095002A CN201210009500A CN102586039A CN 102586039 A CN102586039 A CN 102586039A CN 2012100095002 A CN2012100095002 A CN 2012100095002A CN 201210009500 A CN201210009500 A CN 201210009500A CN 102586039 A CN102586039 A CN 102586039A
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methyl
quaternary ammonium
sulfate
ammonium salt
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CN102586039B (en
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易行槐
黄文军
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JINGZHOU HUOLI 28 SHASHI DAILY CHEMICAL CO Ltd
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JINGZHOU HUOLI 28 SHASHI DAILY CHEMICAL CO Ltd
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Abstract

The invention provides a clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt. The clothes washing rinsing synergist containing the methyl sulfate-based quaternary ammonium salt consists of the following components in part by weight: 0.5-5 parts of polyethoxylated fatty alcohol, 0.5-4 parts of polyethoxylated heterogeneous fatty alcohol, 1-5 parts of citric acid, 5-15 parts of sodium citrate, 0.1-1 part of polydimethylsiloxane, 0.2-3 parts of distearate-ethoxyl-methyl-ammonium methyl sulfate, 0.1-3 parts of methyl-oleamide ethyl-oleic acid base-imidazoline ammonium methyl sulfate, 0.1-0.4 part of essence and 55-80 parts of neutral inorganic salt, wherein neutral inorganic salt is sodium sulfate, potassium sulfate, sodium chloride, potassium chloride, neutral sodium silicate and the like; and the clothes washing rinsing synergist containing the methyl sulfate-based quaternary ammonium salt is produced by the process for producing powdery washing powder.

Description

A kind of laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt
Technical field
The present invention relates to the daily chemical products field, specially refer to the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt.
Background technology
Use at ordinary times at us in the detergent washing clothings such as washing powder, washing liquid, often because of being eager the clothing wash clean, the amount ratio of washing composition is bigger.Usually, we use washing powder or washing liquid at home with laundry washer clothes, sheet, quilt cover, can find that foam is quite a lot of.Press the old process washing of washing machine, often wash, again rinse again after rinse repeatedly also has a lot of foams during dehydration.In the washing process of routine, eliminate foam, remove chemical residual, compliant fabric in the washing composition, all must adopt the washing post-processing technology of specialty.So,, can take the method for specialty to solve these problems in the laundry of specialty.
If the washing clothing do not clean up, also have a large amount of foams in the washings, prove that tensio-active agent and the washing assistant in the washing composition remains on the clothing in a large number, and have very strong basicity, clothing can become because of alkalescence is residual jaundice, harden.Moreover, the chemical residual of these tensio-active agents and washing assistant is gone back Diazolidinyl Urea, can let the people wear the back when serious and produce fash.
Induction-arrangement, there are following defective in existing washing composition and washing synergy product:
1, residual chemicals on fabric.
Foam is too many when 2, cleaning, and is difficult to quick rinse.
3, wash back clothing jaundice, hardening.
Summary of the invention
The object of the present invention is to provide a kind of laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt; To solve in daily life; Behind washing clothes such as washing powder, washing liquid, when cleaning, run into foam and be difficult to problems such as quick rinse, clothing harden after washing too much through regular meeting.
For realizing above-mentioned purpose, technical scheme of the present invention is:
A kind of laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt is characterized in that: each ingredients weight parts component is in the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt:
Polyethoxylated Fatty Alcohol(C12-C14 and C12-C18) 0.5-5 part
Polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18) 0.5-4 part
Hydrocerol A 1-5 part
Trisodium Citrate 5-15 part
YSR 3286 0.1-1 part
Two stearyl-hydroxyethyls-methyl-sulfate methyl ammonium 0.2-3 part
Methyl-oleylamide ethyl-oleic acid base-tetrahydroglyoxaline sulfate methyl ammonium 0.1-3 part
Essence 0.1-0.4 part
Neutral inorganic 55-80 part.
Described neutral inorganic is sodium sulfate, vitriolate of tartar, sodium-chlor, Repone K, neutral sodium silicate etc.
Positively effect of the present invention is:
1, just can eliminate foam, quick rinse in the rinsing first time, eliminate chemical residual, prevent that the hair-weaving xanthochromia is hard, make fabric recover soft and fluffy.In laundry processes, for the first time during rinse, synergistic agent at first reduces the surface tension of washing lotion, and demineralized water, and can remove foam fast makes that laundry processes more saves time, water-saving, reaches the effect of quick washing.
2, this synergistic agent can also infiltrate into the fabric depths, removes the washing composition residual surfactant, and neutralization helps the residual alkali in the washing composition, residual chlorine, the minimizing chemical residual.
3, the special novel environment friendly positively charged ion softener that adds in this synergistic agent can avoid clothing to harden, and makes clothing more fluffy, soft.
4, the effect through synergistic agent, the order laundry is more convenient, really realizes eliminating that foam, neutralization are residual, compliant fabric, flavouring lasting once accomplish, and Bai Yigeng is white, color dress is more gorgeous, and delicate fragrance is pleasant, lasting is lasting.
Embodiment
Further specify embodiment of the present invention below in conjunction with embodiment, each component is parts by weight of component among each embodiment.
Embodiment one
Get 0.5 part of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 2 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 1.5 parts of Hydrocerol As, 5 parts of Trisodium Citrates, 0.1 part of YSR 3286, two stearyl-hydroxyethyl-0.2 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-0.1 part of tetrahydroglyoxaline sulfate methyl ammonium, 0.1 part in essence, 70 parts in sodium sulfate; 10 parts in sodium-chlor is by producing the laundry rinse synergistic agent that powdery washing powder explained hereafter goes out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment two
Get 2.5 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 1 part of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 2.5 parts of Hydrocerol As, 7 parts of Trisodium Citrates, 0.3 part of YSR 3286, two stearyl-hydroxyethyl-0.4 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-0.2 part of tetrahydroglyoxaline sulfate methyl ammonium, 0.2 part in essence, 65 parts in sodium sulfate; 15 parts in Repone K is by producing the laundry rinse synergistic agent that powdery washing powder explained hereafter goes out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment three
Get 3 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 0.5 part of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 3.5 parts of Hydrocerol As, 8 parts of Trisodium Citrates, 0.15 part of YSR 3286, two stearyl-hydroxyethyl-1 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-0.6 part of tetrahydroglyoxaline sulfate methyl ammonium, 0.3 part in essence, 60 parts of vitriolate of tartar; 15 parts of vitriolate of tartar are by producing the laundry rinse synergistic agent that powdery washing powder explained hereafter goes out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment four
Get 2.5 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 2 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 3.5 parts of Hydrocerol As, 9 parts of Trisodium Citrates, 0.5 part of YSR 3286, two stearyl-hydroxyethyl-0.8 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-2 parts of tetrahydroglyoxaline sulfate methyl ammoniums, 0.3 part in essence, 65 parts of vitriolate of tartar; 10 parts of neutral sodium silicates are by producing the laundry rinse synergistic agent that powdery washing powder explained hereafter goes out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment five
Get 3 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 3 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 1 part of Hydrocerol A, 6 parts of Trisodium Citrates, 0.2 part of YSR 3286, two stearyl-hydroxyethyl-2 parts of methyl-sulfate methyl ammoniums, methyl-oleylamide ethyl-oleic acid base-1 part of tetrahydroglyoxaline sulfate methyl ammonium, 0.3 part in essence, 20 parts in sodium sulfate, 40 parts in sodium-chlor, by producing the laundry rinse synergistic agent that powdery washing powder explained hereafter goes out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment six
Get 3.5 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 1 part of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 3.5 parts of Hydrocerol As, 5 parts of Trisodium Citrates, 0.4 part of YSR 3286, two stearyl-hydroxyethyl-2.5 parts of methyl-sulfate methyl ammoniums, methyl-oleylamide ethyl-oleic acid base-2.5 parts of tetrahydroglyoxaline sulfate methyl ammoniums, 0.3 part in essence, 50 parts in sodium sulfate, 5 parts of neutral sodium silicates, by producing the laundry rinse synergistic agent that powdery washing powder explained hereafter goes out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment seven
Get 20 parts of 1 part of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 4 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 3 parts of Hydrocerol As, 10 parts of Trisodium Citrates, 0.5 part of YSR 3286, two stearyl-hydroxyethyl-0.8 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-2 parts of tetrahydroglyoxaline sulfate methyl ammoniums, 0.4 part in essence, sodium sulfate 60, Repone K, by producing the laundry rinse synergistic agent that powdery washing powder explained hereafter goes out sulfur acid methoxycarbonyl quaternary ammonium salt.
Embodiment eight
Get 5 parts of polyethoxylated Fatty Alcohol(C12-C14 and C12-C18), 2 parts of polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18), 5 parts of Hydrocerol As, 15 parts of Trisodium Citrates, 1 part of YSR 3286, two stearyl-hydroxyethyl-0.9 part of methyl-sulfate methyl ammonium, methyl-oleylamide ethyl-oleic acid base-3 parts of tetrahydroglyoxaline sulfate methyl ammoniums, 0.1 part in essence, 50 parts in sodium sulfate, 5 parts in Repone K, by producing the laundry rinse synergistic agent that powdery washing powder explained hereafter goes out sulfur acid methoxycarbonyl quaternary ammonium salt.
Example detection result
Figure DEST_PATH_IMAGE002AA
The above only is a non-limiting embodiment of the present invention; For the person of ordinary skill of the art; Do not breaking away from the invention design and do not making under the prerequisite of creative work, can also make some distortion and improvement, these all belong to protection scope of the present invention.

Claims (2)

1. the laundry rinse synergistic agent of a sulfur acid methoxycarbonyl quaternary ammonium salt, it is characterized in that: the parts by weight of component of each component is in the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt:
Polyethoxylated Fatty Alcohol(C12-C14 and C12-C18) 0.5-5 part
Polyethoxylated isomery Fatty Alcohol(C12-C14 and C12-C18) 0.5-4 part
Hydrocerol A 1-5 part
Trisodium Citrate 5-15 part
YSR 3286 0.1-1 part
Two stearyl-hydroxyethyls-methyl-sulfate methyl ammonium 0.2-3 part
Methyl-oleylamide ethyl-oleic acid base-tetrahydroglyoxaline sulfate methyl ammonium 0.1-3 part
Essence 0.1-0.4 part
Neutral inorganic 55-80 part.
2. the laundry rinse synergistic agent of sulfur acid methoxycarbonyl quaternary ammonium salt according to claim 1 is characterized in that: described neutral inorganic is sodium sulfate, vitriolate of tartar, sodium-chlor, Repone K, neutral sodium silicate.
CN 201210009500 2012-01-13 2012-01-13 Clothes washing rinsing synergist containing methyl sulfate-based quaternary ammonium salt Expired - Fee Related CN102586039B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017014497A (en) * 2015-06-30 2017-01-19 花王株式会社 Powder detergent composition for clothing
CN110467971A (en) * 2019-08-30 2019-11-19 广州市拓瑞科技有限公司 A kind of environmentally protective sterilizing waterless nano liquid detergent and preparation method thereof
CN111040889A (en) * 2018-10-15 2020-04-21 青岛海尔洗衣机有限公司 Cleaning composition, application thereof and cleaning agent

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1225670A (en) * 1996-05-17 1999-08-11 普罗格特-甘布尔公司 Detergent composition
CN101812381A (en) * 2009-06-08 2010-08-25 广州立白企业集团有限公司 Washing and softening laundry detergent composition
CN101935949A (en) * 2010-08-27 2011-01-05 上海制皂有限公司 Clothes softener
CN102002445A (en) * 2010-11-30 2011-04-06 广州星业科技股份有限公司 Washing powder and soap powder viscosity reduction synergist
CN102230278A (en) * 2011-06-07 2011-11-02 廊坊乐万家联合家化有限公司 Concentrated fabric softener and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1225670A (en) * 1996-05-17 1999-08-11 普罗格特-甘布尔公司 Detergent composition
CN101812381A (en) * 2009-06-08 2010-08-25 广州立白企业集团有限公司 Washing and softening laundry detergent composition
CN101935949A (en) * 2010-08-27 2011-01-05 上海制皂有限公司 Clothes softener
CN102002445A (en) * 2010-11-30 2011-04-06 广州星业科技股份有限公司 Washing powder and soap powder viscosity reduction synergist
CN102230278A (en) * 2011-06-07 2011-11-02 廊坊乐万家联合家化有限公司 Concentrated fabric softener and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017014497A (en) * 2015-06-30 2017-01-19 花王株式会社 Powder detergent composition for clothing
CN111040889A (en) * 2018-10-15 2020-04-21 青岛海尔洗衣机有限公司 Cleaning composition, application thereof and cleaning agent
CN111040889B (en) * 2018-10-15 2022-04-12 重庆海尔洗衣机有限公司 Cleaning composition, application thereof and cleaning agent
CN110467971A (en) * 2019-08-30 2019-11-19 广州市拓瑞科技有限公司 A kind of environmentally protective sterilizing waterless nano liquid detergent and preparation method thereof

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