CN104818168B - A kind of laundry soap lye and preparation method thereof - Google Patents
A kind of laundry soap lye and preparation method thereof Download PDFInfo
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Abstract
The present invention provides a kind of laundry soap lye, including following component and mass percent thereof: fatty acid mixed soap 2 ~ 15%, and Sodium Alcohol Ether Sulphate 2 ~ 10%, fatty alcohol-polyoxyethylene ether 1 ~ 5%, lauroyl amido CAB 0.2 ~ 5%, alkyl polyglucoside 0.2 ~ 5%, citrate 0.1 ~ 3%, chelating agen 0.1 ~ 1.0%, thickening agent 0.5 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 2%, preservative 0.1 ~ 2%, essence 0 ~ 1%, water 50 ~ 90%.The invention belongs to detergent technical field, laundry soap lye provided by the invention has excellent detergency and easily floats performance.
Description
Technical field
The invention belongs to detergent technical field, particularly relate to a kind of laundry soap lye and preparation method thereof.
Background technology
Laundry liquid agent is developed so far, from its ever-increasing market share it can be seen that consumer generally receives laundry liquid agent.Compared with solid laundry agent, laundry liquid agent has that production technology is simple, and product is easy to use, dissolves rapidly, to the action temperature of medicated clothing and etc. advantage.
As the one of laundry liquid agent, the active component of laundry soap lye includes fatty acid soaps and other surfactants.Owing to fatty acid soaps has good clean effect, it is possible to reduce the consumption of other surfactants, soap lye is increasingly becoming the new lover in laundry detergents.
Chinese patent 200780019337.5 discloses a kind of liquid handling components and fabrics, this liquid handling components and fabrics is while comprising fatty acid soaps, also comprise a certain amount of free fatty and fatty acid ester, soap and plasticizer is generated containing ester soap precursor and alkali reaction, this laundry product can realize SPE deposition preferably, it is possible to is made into superconcentrate.
Chinese patent 201210563439.6 discloses a kind of Liquid laundry composition, this Liquid laundry composition uses single coco-nut oil fatty acid potash soap as fatty acid soaps, use nonionic surfactant and anion surfactant as surfactant, there is when using dimethicone as defoamer preferably easily rinsing performance.But, silicone oil defoamer is more unstable in liquid detergent system, it is easy to the situation of oil-water separation occur, and its foam-inhibiting effect is more than froth breaking effect, easily produces, when main washing, the phenomenon that liquid detergent difficulty is bubbled.
It is not ideal enough to there is detergency in laundry soap lye of the prior art, and other dosage of surfactant beyond fatty acid soaps are bigger, it is necessary to use the shortcomings such as defoamer.Therefore, it is necessary to research and development are a kind of without defoamer, relatively strong and easily rinsing the laundry soap lye of detergency, to meet the higher demand of consumer.
Summary of the invention
For solving problems of the prior art, the composition of fatty acid soaps and other surfactants is carried out screening with composite by lot of experiments by inventor, unforeseeable discovery: the laundry soap lye obtained by special component combination is had excellent detergency and easily floats performance.Based on above-mentioned discovery, thus completing the present invention.
The purpose of the present invention will be further described in detail below reflect and description.
The present invention provides a kind of laundry soap lye, including following component and mass percent thereof: fatty acid mixed soap 2 ~ 15%, and Sodium Alcohol Ether Sulphate 2 ~ 10%, fatty alcohol-polyoxyethylene ether 1 ~ 5%, lauroyl amido CAB 0.2 ~ 5%, alkyl polyglucoside 0.2 ~ 5%, citrate 0.1 ~ 3%, chelating agen 0.1 ~ 1.0%, thickening agent 0.5 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 2%, preservative 0.1 ~ 2%, essence 0 ~ 1%, water 50 ~ 90%.
Generating fatty acid mixed soap, the introducing of multiple soap base, both scalable pH value by the reaction of satisfied fatty acid, unsaturated fatty acid and alkali, play effect of decontamination, it is also possible to chelate heavy metals ion, chelate products can do at washing process and drops infusion and subtract lubrication prescription；Soap base and the calcium salt in water, magnesium salt generate fatty acid calcium soap or magnesium soap through metathesis reaction, it is possible to accelerate the drain age velocity of foam, reduce Film strength, thus having promoted bubble burst, improve and easily floating performance.Sodium Alcohol Ether Sulphate has decontamination；Fatty alcohol-polyoxyethylene ether has infiltration and decontamination；Lauroyl amido CAB has decontamination and regulates the effect of viscosity；Alkyl polyglucoside has decontamination, softening, also can reduce the zest of other surfactants, have the performance of good thickening property and stabilising system.Synergism by above-mentioned 4 kinds of surfactants Yu fatty acid mixed soap, the consumption of other surfactants beyond fatty acid soaps can be reduced, while strengthening detergency, promote to cross lather collapse during water, without additionally adding defoamer, reach once rinsing and got final product the effect of basic rinse.Thickening agent is used for regulation system viscosity.Phenylethylene ethylene/propenoic acid ester copolymer is used for regulating pH and system rheologic behavio(u)r so that target product is stable in viscosity and phase globality.Chelating agen can chelate heavy metals ion, reduce hardness of water.
The combination of said components and the above-mentioned percentage range of each component, be that inventor is determined by lot of experiments, and combinations thereof and percentage range make laundry soap lye provided by the invention have excellent detergency and easily float performance.
Preferably, described fatty acid mixed soap is obtained through alkali neutralization by fatty acid mixed, and described fatty acid mixed is made up of with the mass ratio of 3 ~ 8:1 satisfied fatty acid and unsaturated fatty acid, and described alkali is selected from alkali-metal hydroxide.In order to ensure the complete of fatty acid mixed saponification, the addition of alkali is somewhat excessive, and therefore, in laundry soap lye provided by the invention, without free fatty, pH is between 7.5 ~ 8.5.
Preferably, described satisfied fatty acid by lauric acid and stearic acid with (1 ~ 2): the mass ratio of (2 ~ 1) forms, and described unsaturated fatty acid is oleic acid.
Preferably, described alkali metal is selected from sodium and/or potassium, and described chelating agen is selected from tetrasodium ethylenediamine tetraacetate and/or disodiumedetate, and described thickening agent is sodium chloride.
Preferably, laundry soap lye provided by the invention includes following component and mass percent thereof: potassium laurate 1 ~ 4%, potassium stearate 1 ~ 4%, potassium oleate 0.5 ~ 2%, Sodium Alcohol Ether Sulphate 3 ~ 6%, fatty alcohol-polyoxyethylene ether 1 ~ 3%, lauroyl amido CAB 1 ~ 3%, alkyl polyglucoside 1 ~ 3%, potassium citrate 0.2 ~ 1%, tetrasodium ethylenediamine tetraacetate 0.1 ~ 0.5%, sodium chloride 1 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 1%, preservative 0.1 ~ 1%, essence 0 ~ 0.5%, water 70 ~ 90%.
Preferably, laundry soap lye provided by the invention includes following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl polyglucoside 2%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, essence 0.15%, water 81.8%.
Preferably, the alkyl carbon chain lengths of described alkyl polyglucoside is C8~C12。
Preferably, described fatty alcohol-polyoxyethylene ether is selected from AEO7And/or AEO9。
Preferably, described preservative by Bronopol and Methylisothiazolinone with (6 ~ 9): the mass ratio of 1 forms.
Described essence, it is possible to adopt the conventional essence of the industry, it is also possible to select without essence.Whether the interpolation of essence, the major function of laundry soap lye provided by the invention will not be produced impact.Obviously, in addition to the above components, on the basis of the present invention, it is also possible to add other components such as applicable pigment.
Correspondingly, the preparation method that the present invention also provides for laundry soap lye, comprise the steps:, by soluble in water to thickening agent and alkali, to be warming up to 60 ~ 80 DEG C, under stirring condition, add lauric acid, stearic acid and oleic acid, after reaction 0.1 ~ 1h, cooling, under stirring condition, add Sodium Alcohol Ether Sulphate, fatty alcohol-polyoxyethylene ether, lauroyl amido CAB, alkyl polyglucoside, citric acid, tetrasodium ethylenediamine tetraacetate, preservative and essence, obtain mixed liquor；Under stirring condition, will add in described mixed liquor with the scattered phenylethylene ethylene/propenoic acid ester copolymer of water, preservative and essence, and stir and obtain laundry soap lye.Add citric acid and return acid, can suitably reduce pH, and the citrate obtained can offset polyvalent cation such as calcium and the magnesium negative effect to washing.Additionally, citrate can improve detersive efficiency and the effect of surfactant.
Compared with prior art, the invention has the beneficial effects as follows: laundry soap lye provided by the invention, easy to use, steady quality, preparation method is simple, and cost is low, without soapy feeling during hand washing, by the synergism of fatty acid mixed soap Yu other surfactants, while strengthening detergency, promote lather collapse during washed water, without additionally adding defoamer, having reached easy rinsing, once rinsing gets final product the effect of basic rinse, applied widely, it is adaptable to washing when high-hardness water.The preparation method of laundry soap lye provided by the invention is simple, and the laundry soap lye steady quality prepared, clean result is good, easily rinses.
Detailed description of the invention
Below by specific embodiment, the present invention is described in further detail.
Each component in the present invention is conventional commercial product, for instance, the alkyl polyglucoside in embodiment is purchased from Shanghai Fakai Chemical Co., Ltd., article No. APG0814；Phenylethylene ethylene/propenoic acid ester copolymer is purchased from Luomen Hars China Co., article No. Acusolop301.
Embodiment one is done washing soap lye
Laundry soap lye includes following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl polyglucoside 2%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, water 81.95%.
Preparation method: by weight, every part of 1kg, weigh 80 parts of water, add 1.5 parts of sodium chloride and 1.2 parts of potassium hydroxide, stirring, it is warming up to 70 DEG C, under stirring condition, add 2 parts of lauric acids, 2 parts of stearic acid and 1 part of oleic acid, after reaction 0.5h, it is cooled to 50 DEG C, under stirring condition, add 5 parts of Sodium Alcohol Ether Sulphate, 2 parts of fatty alcohol-polyoxyethylene ether, 2 parts of lauroyl amido CAB, 2 parts of alkyl polyglucoside, 0.25 part of citric acid and 0.1 part of tetrasodium ethylenediamine tetraacetate, it is cooled to 30 DEG C, under stirring condition, add 0.1 part of styrene acrylic copolymer (dissipating with 1.95 parts of moisture), 0.1 portion of preservative and 0 part of essence, stir and get final product.
Embodiment two is done washing soap lye
Laundry soap lye includes following component and mass percent thereof: potassium laurate 4%, potassium stearate 3%, potassium oleate 2%, Sodium Alcohol Ether Sulphate 3%, fatty alcohol-polyoxyethylene ether 1%, lauroyl amido CAB 1%, alkyl polyglucoside 2%, potassium citrate 0.5%, tetrasodium ethylenediamine tetraacetate 0.2%, sodium chloride 2%, phenylethylene ethylene/propenoic acid ester copolymer 0.5%, preservative 0.2%, essence 0.15%, water 80.45%.
Preparation method: similar with the preparation method in embodiment one.
Embodiment three is done washing soap lye
Laundry soap lye includes following component and mass percent thereof: potassium laurate 3%, potassium stearate 4%, potassium oleate 2%, Sodium Alcohol Ether Sulphate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 3%, alkyl polyglucoside 1%, potassium citrate 1%, tetrasodium ethylenediamine tetraacetate 0.4%, sodium chloride 2%, phenylethylene ethylene/propenoic acid ester copolymer 1%, Bronopol 0.18%, Methylisothiazolinone 0.02%, essence 0.5%, water 74.9%.
Preparation method: similar with the preparation method in embodiment one.
Comparative example 1
Laundry soap lye includes following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 5%, fatty alcohol-polyoxyethylene ether 4%, lauroyl amido CAB 2%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, water 81.95%.
The present embodiment and embodiment one are distinctive in that: from 2%, the mass percent of alkyl polyglucoside is become 0, from 2%, the mass percent of fatty alcohol-polyoxyethylene ether is become 4%.
Preparation method: similar with the preparation method in embodiment one.
Comparative example 2
Laundry soap lye includes following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 5%, lauroyl amido CAB 2%, alkyl polyglucoside 4%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, water 81.95%.
The present embodiment and embodiment one are distinctive in that: from 2%, the mass percent of alkyl polyglucoside is become 4%, from 2%, the mass percent of fatty alcohol-polyoxyethylene ether is become 0%.
Preparation method: similar with the preparation method in embodiment one.
Comparative example 3
Laundry soap lye includes following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 7%, lauroyl amido CAB 4%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, water 81.95%.
The present embodiment and embodiment one are distinctive in that: from 2%, the mass percent of alkyl polyglucoside is become 0, the mass percent of fatty alcohol-polyoxyethylene ether is become 0% from 2%, the mass percent of Sodium Alcohol Ether Sulphate is become 7% from 5%, and the mass percent of lauroyl amido CAB is become 4% from 2%.
Preparation method: similar with the preparation method in embodiment one.
Comparative example 4
Laundry soap lye includes following component and mass percent thereof: potassium laurate 4%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl polyglucoside 2%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, water 81.95%.
The present embodiment and embodiment one are distinctive in that: from 2%, the mass percent of potassium laurate is become 4%, and the mass percent of potassium stearate is become 0 from 2%.
Preparation method: similar with the preparation method in embodiment one.
Comparative example 5
Laundry soap lye includes following component and mass percent thereof: potassium stearate 4%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl polyglucoside 2%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, water 81.95%.
The present embodiment and embodiment one are distinctive in that: from 2%, the mass percent of potassium laurate is become 0, and the mass percent of potassium stearate is become 4% from 2%.
Preparation method: similar with the preparation method in embodiment one.
Comparative example 6
Laundry soap lye includes following component and mass percent thereof: potassium palmitate 2%, potassium stearate 2%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl polyglucoside 2%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, water 81.95%.
The present embodiment and embodiment one are distinctive in that: potassium laurate changes into potassium palmitate, and mass percent is 2%.
Preparation method: similar with the preparation method in embodiment one.
Detergency effect example
By the method for GB/T13174-2008, the laundry soap lye of different embodiments carrying out the test of detergency, result is as shown in table 1.As known from Table 1, embodiment one, embodiment two and embodiment three show stronger detergency, especially carbon black class and sebum class are shown very excellent clean effect, and it is significantly better than the clean effect of comparative example one, comparative example two and comparative example three, illustrate that Sodium Alcohol Ether Sulphate, fatty alcohol-polyoxyethylene ether, lauroyl amido CAB and the composite of alkyl polyglucoside serve obvious synergism.Although fatty alcohol-polyoxyethylene ether and alkyl polyglucoside are all conventional nonionic surfactants, but it is surprising that for laundry soap liquid system provided by the invention, fatty alcohol-polyoxyethylene ether and alkyl polyglucoside are all indispensable.
。
Wash effect embodiment
By the method for GB/T15818-2006, the test of foam height after the laundry soap lye of different embodiments is rinsed, result is as shown in table 2.As known from Table 2, embodiment one, embodiment two and embodiment three show stronger easily floats performance, namely rinse is can be considered through once rinsing, and it is significantly better than the wash effect of comparative example one, comparative example two and comparative example three, illustrate that the fatty acid mixed soap of the neutralized generation of lauric acid, stearic acid and oleic acid serves obvious synergism.Although lauric acid and stearic acid are all conventional satisfied fatty acid, but it is surprising that for laundry soap liquid system provided by the invention, lauric acid soap and stearate soap are all indispensable.
。
Above content is in conjunction with concrete preferred implementation further description made for the present invention, it is impossible to assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace, protection scope of the present invention all should be considered as belonging to.
Claims (7)
1. a laundry soap lye, it is characterised in that: it is made up of following component and mass percent thereof: fatty acid mixed soap 2 ~ 15%, Sodium Alcohol Ether Sulphate 2 ~ 10%, fatty alcohol-polyoxyethylene ether 1 ~ 5%, lauroyl amido CAB 0.2 ~ 5%, alkyl polyglucoside 0.2 ~ 5%, citrate 0.1 ~ 3%, chelating agen 0.1 ~ 1.0%, thickening agent 0.5 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 2%, preservative 0.1 ~ 2%, essence 0 ~ 1%, water 50 ~ 90%；Described fatty acid mixed soap is neutralized through alkali by fatty acid mixed and obtains, described fatty acid mixed by satisfied fatty acid and unsaturated fatty acid with (3 ~ 8): the mass ratio of 1 form, and described alkali is selected from alkali-metal hydroxide；Described satisfied fatty acid by lauric acid and stearic acid with (1 ~ 2): the mass ratio of (2 ~ 1) forms, and described unsaturated fatty acid is oleic acid.
2. laundry soap lye according to claim 1, it is characterised in that: described alkali metal is selected from sodium and/or potassium, and described chelating agen is selected from tetrasodium ethylenediamine tetraacetate and/or disodiumedetate, and described thickening agent is sodium chloride.
3. laundry soap lye according to claim 2, it is characterized in that: be made up of following component and mass percent thereof: potassium laurate 1 ~ 4%, potassium stearate 1 ~ 4%, potassium oleate 0.5 ~ 2%, Sodium Alcohol Ether Sulphate 3 ~ 6%, fatty alcohol-polyoxyethylene ether 1 ~ 3%, lauroyl amido CAB 1 ~ 3%, alkyl polyglucoside 1 ~ 3%, potassium citrate 0.2 ~ 1%, tetrasodium ethylenediamine tetraacetate 0.1 ~ 0.5%, sodium chloride 1 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 1%, preservative 0.1 ~ 1%, essence 0 ~ 0.5%, water 70 ~ 90%.
4. laundry soap lye according to claim 3, it is characterised in that: it is made up of following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, Sodium Alcohol Ether Sulphate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl polyglucoside 2%, potassium citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium chloride 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, preservative 0.1%, essence 0.15%, water 81.8%.
5. laundry soap lye according to any one of claim 1 to 3, it is characterised in that: the alkyl carbon chain lengths of described alkyl polyglucoside is C8~C12。
6. laundry soap lye according to any one of claim 1 to 3, it is characterised in that: described fatty alcohol-polyoxyethylene ether is selected from AEO7And/or AEO9。
7. laundry soap lye according to any one of claim 1 to 3, it is characterised in that: described preservative by Bronopol and Methylisothiazolinone with (6 ~ 9): the mass ratio of 1 forms.
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| US20060247151A1 (en) * | 2005-04-29 | 2006-11-02 | Kaaret Thomas W | Oxidizing compositions and methods thereof |
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| CN109181914A (en) * | 2018-08-04 | 2019-01-11 | 中山市妙洁精细化工有限公司 | A kind of long-acting bacteriostatic laundry soap lye and preparation method thereof |
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