CN109135954A - A kind of environment-friendly high-efficiency liquid detergent - Google Patents

A kind of environment-friendly high-efficiency liquid detergent Download PDF

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Publication number
CN109135954A
CN109135954A CN201811156222.7A CN201811156222A CN109135954A CN 109135954 A CN109135954 A CN 109135954A CN 201811156222 A CN201811156222 A CN 201811156222A CN 109135954 A CN109135954 A CN 109135954A
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China
Prior art keywords
ether
environment
polyethenoxy
aliphatic alcohol
alcohol
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CN201811156222.7A
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Chinese (zh)
Inventor
赵建利
郭剑
欧盛臣
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BEIJING LUOWA DAILY CHEMICAL Co Ltd
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BEIJING LUOWA DAILY CHEMICAL Co Ltd
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Priority to CN201811156222.7A priority Critical patent/CN109135954A/en
Publication of CN109135954A publication Critical patent/CN109135954A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides

Abstract

The present invention provides a kind of environment-friendly high-efficiency low foam laundry liquids, as follows comprising main component and mass fraction: anionic surfactant: 3-35 parts;Lauric acid/dodecanoic acid: 1-5 parts;Isomery ether surfactants: 6-25 parts;Nonionic surfactant: 8-18 parts;Alkyl glycosides: 1-10 parts;Zwitterionic surfactant: 3-12 parts;Thickener: 2-4 parts;Chelating agent: 0.1-3 parts;Sodium hydroxide: 0.1-10 parts;Biological enzyme: 0.1-2 parts;Preservative: 0.1-0.3 parts;Essence: 0.1-0.8 parts;Surplus: deionized water.Environment-friendly high-efficiency low foam laundry liquid washing effect of the invention is excellent, environmentally protective to human body and environmental-friendly.

Description

A kind of environment-friendly high-efficiency liquid detergent
Technical field
The present invention relates to the cleaning products of textile product, and in particular to a kind of environment-friendly high-efficiency low foam laundry liquid.
Background technique
With the development and improvement of living standard of society, people also gradually yearn for while meeting material life and enriching Thus the environmental demand of high-quality causes people's pay attention to day by day environmental issue.And in daily life, articles for washing becomes safe Change, environmental protection also becomes everybody widespread consensus.It, which is embodied in, is replaced or is reduced unnecessaryization using new raw material new material Work raw material uses, and it is even better to reach same effect.
In recent years, prospect of Chinese washing products market increases rapidly, and the liquid detergent market share is also increasing, wherein doing washing Liquid market accounts for about 30% or so of fabric washing product total amount.Environmental protection even avoids water body rich from the point of view of ecological environment, to reducing Nutrient laden plays the role of the ecological balance very positive.And efficiently then there is to liquid detergent usage amount the advantage of amount, low bubble is then There is water-saving to save time effect rinsing.
Summary of the invention
It, can be efficiently to environmental protection the purpose of the present invention is researching and developing a low foaming liquid detergent of environment-friendly high-efficiency Decontamination, detersive efficiency are significantly larger than commercially available ordinary liquid laundry detergent, and rinsing times are reduced in the case where defoaming agent is not added, and water-saving is time saving.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of environment-friendly high-efficiency low foam laundry liquid, which is characterized in that as follows comprising main component and mass fraction:
Preferably, the environment-friendly high-efficiency low foam laundry liquid includes that main component and mass fraction are as follows:
Preferably, the environment-friendly high-efficiency low foam laundry liquid includes that main component and mass fraction are as follows:
Preferably, the biological enzyme is protease
Preferably, the nonionic surfactant is aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether At least one of with aliphatic alcohol polyethenoxy (9) ether;
The thickener is at least one of hydroxyethyl cellulose, hydroxypropyl base cellulose, sodium chloride;
The isomery ether surfactants are ten alcohol alkoxide nonionic surfactant (HIC2109) of isomery, isomery At least one of tridecanol alkoxide nonionic surfactant (HIF4100);
The zwitterionic surfactant be in Cocoamidopropyl betaine and cocamidopropyl propyl amide amine oxide extremely Few one kind;
The alkyl glucoside surfactant is at least one of alkyl glycosides 0810 and alkyl glycosides 1214;
The chelating agent is at least one of EDTA-4Na and glutamic acid diacetic acid tetrasodium salt GLDA;
The anionic surfactant is selected from sodium sulfate of polyethenoxy ether of fatty alcohol, fatty acid methyl ester ethoxylate sulphur At least contain one kind in hydrochlorate, methyl sodiosul foaliphatate and sodium lauroyl glutamate.
Preferably, the anionic surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol and fatty acid methyl ester ethyoxyl Compound sulfonate, the mass parts ratio of the sodium sulfate of polyethenoxy ether of fatty alcohol, fatty acid methyl ester ethoxylate sulfonate For 6:4;The nonionic surfactant is aliphatic alcohol polyethenoxy (9) ether and aliphatic alcohol polyethenoxy (7) ether, the fat The mass parts ratio of alcohol polyoxyethylene (9) ether and aliphatic alcohol polyethenoxy (7) ether is 8:4.
Preferably, the nonionic surfactant is aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) The mass parts ratio of ether, aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether is 2:3.
Preferably, the nonionic surfactant is aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) The mass parts ratio of ether, aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether is 5:7;The isomery alcohol ether Surfactant is ten alcohol alkoxide nonionic surfactant (HIC 2109) of isomery and isomerous tridecanol alkoxide nonionic Surfactant (HIF 4100), the ten alcohol alkoxide nonionic surfactant (HIC 2109) of isomery, isomerous tridecanol The weight fraction ratio of alkoxide nonionic surfactant (HIF 4100) mixing is 3:7.
Preferably, the anionic surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol and fatty acid methyl ester ethyoxyl Compound sulfonate, the mass parts ratio of the sodium sulfate of polyethenoxy ether of fatty alcohol, fatty acid methyl ester ethoxylate sulfonate For 6:11;The nonionic surfactant is aliphatic alcohol polyethenoxy (9) ether and aliphatic alcohol polyethenoxy (7) ether, the rouge Fat alcohol polyoxyethylene (9) ether, aliphatic alcohol polyethenoxy (7) ether mass parts ratio be 4:7.
Preferably, the isomery ether surfactants are ten alcohol alkoxide nonionic surfactant of isomery (HIC2109) and isomerous tridecanol alkoxide nonionic surfactant (HIF4100), the ten alcohol alkoxide nonionic of isomery The mass parts ratio of surfactant (HIC2109) and isomerous tridecanol alkoxide nonionic surfactant (HIF4100) is 3:7;The zwitterionic surfactant is Cocoamidopropyl betaine and cocamidopropyl propyl amide amine oxide, the cocounut oil acyl Amine propyl betaine, the mass parts ratio of cocamidopropyl propyl amide amine oxide are 5:5.
Beneficial effects of the present invention: the present invention does not add solvent, defoaming agent in the feed, passes through environment-friendly type surfactant Between reasonable compounding, be subject to the high auxiliary agent of biological degradation rate, obtain the low foam system of a stable environment-friendly high-efficiency so that Reach the far super washing standard requirements even in terms of certain in the case that usage amount is very low, solves that environmental protection, foam is low, enzymatic activity is steady It is fixed.New raw material of the invention has been mass produced, quality assurance, while preparation process is easy, convenient for promoting the use of.
Specific embodiment
In order to better illustrate the present invention, below with reference to the embodiment of the present invention, technical solution in the embodiment of the present invention It is clearly and completely described.
The preparation method of herein described environment-friendly high-efficiency low foam laundry liquid, includes the following steps:
1. taking the deionized water half to be added in material kettle according to certain mass proportion, it is heated to 65 DEG C;
Piece alkali and lauric acid/dodecanoic acid stirring 10 minutes is added 2. matching according to certain mass;
3. sequentially adding anionic surfactant, isomery ether surfactants, nonionic according to certain mass proportion Surfactant, alkyl glycosides, zwitterionic surfactant are stirred to being completely dissolved, and obtain mixed liquor A;
4. matching the addition chelating agent, benzoisothiazolinone, essence, residue into the mixed liquor A according to certain mass Deionized water stirs evenly, and obtains mixed solution B;
5. being matched according to certain mass and biological enzyme being added into the mixed liquid B, stir evenly, obtains mixed solution C;
6. matching according to certain mass to the mixed liquor C and hydroxyethyl cellulose being added, stirs evenly, obtain mixed solution D;
7. mixed solution D is filtered processing, the high power concentration liquid detergent of the co-solvent is obtained.(filter screen: 300 mesh)
Unit of weight used in the present embodiment is gram, or kilogram;Essence described in the present embodiment is food-grade, His raw material is technical grade;Each raw material described in the present embodiment has been mass produced.
Embodiment 1
A kind of environment-friendly high-efficiency low foam laundry liquid, as follows comprising component and mass fraction:
The experimental condition of GB/T13174: standard liquid detergent concentration 2 ‰ is pressed in the detergency measurement of the detergent of the present embodiment, Sample concentration point 2 ‰, commercially available ordinary liquid laundry detergent concentration 2 ‰, wash result is as follows:
Extension rate JB-01 JB-02 JB-03
This formula 1.32 4.58 1.47
Commercial laundry liquid 1.13 2.89 1.26
The brbble test of the detergent of the present embodiment presses state specified standards method: Roche method;Instrument: Gai Shi Roche bubble Foam instrument;Standard liquid detergent concentration 2 ‰, sample concentration point 2 ‰, commercially available ordinary liquid laundry detergent concentration 2 ‰, foam data are as follows:
Embodiment 2
A kind of environment-friendly high-efficiency low foam laundry liquid, as follows comprising component and mass fraction:
The experimental condition of GB/T13174: standard liquid detergent concentration 2 ‰ is pressed in the detergency measurement of the detergent of the present embodiment, Sample concentration point 2 ‰, commercially available ordinary liquid laundry detergent concentration 2 ‰, wash result is as follows:
Extension rate JB-01 JB-02 JB-03
This formula 1.36 4.68 1.41
Commercial laundry liquid 1.13 2.89 1.26
The brbble test of the detergent of the present embodiment presses state specified standards method: Roche method;Instrument: Gai Shi Roche bubble Foam instrument;Standard liquid detergent concentration 2 ‰, sample concentration point 2 ‰, commercially available ordinary liquid laundry detergent concentration 2 ‰, foam data are as follows:
Embodiment 3
A kind of environment-friendly high-efficiency low foam laundry liquid, as follows comprising component and mass fraction:
The experimental condition of GB/T13174: standard liquid detergent concentration 2 ‰ is pressed in the detergency measurement of the detergent of the present embodiment, Sample concentration point 2 ‰, commercially available ordinary liquid laundry detergent concentration 2 ‰, wash result is as follows:
Extension rate JB-01 JB-02 JB-03
This formula 1.26 4.78 1.59
Commercial laundry liquid 1.13 2.89 1.26
The brbble test of the detergent of the present embodiment presses state specified standards method: Roche method;Instrument: Gai Shi Roche bubble Foam instrument;Standard liquid detergent concentration 2 ‰, sample concentration point 2 ‰, commercially available ordinary liquid laundry detergent concentration 2 ‰, foam data are as follows:
Embodiment 4
A kind of environment-friendly high-efficiency low foam laundry liquid, as follows comprising component and mass fraction:
The experimental condition of GB/T13174: standard liquid detergent concentration 2 ‰ is pressed in the detergency measurement of the detergent of the present embodiment, Sample concentration point 2 ‰, commercially available ordinary liquid laundry detergent concentration 2 ‰, wash result is as follows:
Extension rate JB-01 JB-02 JB-03
This formula 1.39 4.48 1.61
Commercial laundry liquid 1.13 2.89 1.26
The brbble test of the detergent of the present embodiment presses state specified standards method: Roche method;Instrument: Gai Shi Roche bubble Foam instrument;Standard liquid detergent concentration 2 ‰, sample concentration point 2 ‰, commercially available ordinary liquid laundry detergent concentration 2 ‰, foam data are as follows:
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Within the technical scope of the present disclosure, any changes or substitutions that can be easily thought of by anyone skilled in the art, It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims Subject to range.

Claims (10)

1. a kind of environment-friendly high-efficiency low foam laundry liquid, which is characterized in that as follows comprising main component and mass fraction:
2. environment-friendly high-efficiency low foam laundry liquid according to claim 1, which is characterized in that include main component and mass fraction It is as follows:
3. environment-friendly high-efficiency low foam laundry liquid according to claim 1, which is characterized in that include main component and mass fraction It is as follows:
4. environment-friendly high-efficiency low foam laundry liquid according to claim 1 to 3, which is characterized in that the biological enzyme is albumen Enzyme.
5. environment-friendly high-efficiency low foam laundry liquid according to claim 1 to 3, which is characterized in that the non-ionic surface is living Property agent be aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether at least one Kind;
The thickener is at least one of hydroxyethyl cellulose, hydroxypropyl base cellulose, sodium chloride;
The isomery ether surfactants are ten alcohol alkoxide nonionic surfactant (HIC2109) of isomery, isomery 13 At least one of alcohol alkoxide nonionic surfactant (HIF4100);
The zwitterionic surfactant is at least one in Cocoamidopropyl betaine and cocamidopropyl propyl amide amine oxide Kind;
The alkyl glucoside surfactant is at least one of alkyl glycosides 0810 and alkyl glycosides 1214;
The chelating agent is at least one of EDTA-4Na and glutamic acid diacetic acid tetrasodium salt GLDA;
The anionic surfactant is selected from sodium sulfate of polyethenoxy ether of fatty alcohol, fatty acid methyl ester ethoxylate sulfonic acid At least contain one kind in salt, methyl sodiosul foaliphatate and sodium lauroyl glutamate.
6. environment-friendly high-efficiency low foam laundry liquid according to claim 1 to 3, which is characterized in that the anionic surface is living Property agent be sodium sulfate of polyethenoxy ether of fatty alcohol and fatty acid methyl ester ethoxylate sulfonate, the fatty alcohol polyoxyethylene ether Sodium sulphate, fatty acid methyl ester ethoxylate sulfonate mass parts ratio be 6:4;The nonionic surfactant is fat Alcohol polyoxyethylene (9) ether and aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether and aliphatic alcohol polyethenoxy (7) mass parts ratio of ether is 8:4.
7. environment-friendly high-efficiency low foam laundry liquid according to claim 1 to 3, which is characterized in that the non-ionic surface is living Property agent be aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether and fat The mass parts ratio of alcohol polyoxyethylene (9) ether is 2:3.
8. environment-friendly high-efficiency low foam laundry liquid according to claim 1 to 3, which is characterized in that the non-ionic surface is living Property agent be aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether and fat The mass parts ratio of alcohol polyoxyethylene (9) ether is 5:7;The isomery ether surfactants are ten alcohol alkoxide nonionic of isomery Surfactant (HIC 2109) and isomerous tridecanol alkoxide nonionic surfactant (HIF 4100), ten alcohol of isomery Alkoxide nonionic surfactant (HIC 2109), isomerous tridecanol alkoxide nonionic surfactant (HIF4100) are mixed The weight fraction ratio of conjunction is 3:7.
9. environment-friendly high-efficiency low foam laundry liquid according to claim 1 to 3, which is characterized in that the anionic surface is living Property agent be sodium sulfate of polyethenoxy ether of fatty alcohol and fatty acid methyl ester ethoxylate sulfonate, the fatty alcohol polyoxyethylene ether Sodium sulphate, fatty acid methyl ester ethoxylate sulfonate mass parts ratio be 6:11;The nonionic surfactant is rouge Fat alcohol polyoxyethylene (9) ether and aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) mass parts ratio of ether is 4:7.
10. environment-friendly high-efficiency low foam laundry liquid according to claim 9, which is characterized in that the isomery alcohol ether surface active Agent is ten alcohol alkoxide nonionic surfactant (HIC2109) of isomery and isomerous tridecanol alkoxide nonionic surfactant (HIF4100), the ten alcohol alkoxide nonionic surfactant (HIC2109) of isomery and isomerous tridecanol alkoxide nonionic The mass parts ratio of surfactant (HIF4100) is 3:7;The zwitterionic surfactant is cocamidopropyl propyl amide beet Alkali and cocamidopropyl propyl amide amine oxide, the mass parts ratio of the Cocoamidopropyl betaine, cocamidopropyl propyl amide amine oxide For 5:5.
CN201811156222.7A 2018-09-30 2018-09-30 A kind of environment-friendly high-efficiency liquid detergent Pending CN109135954A (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN110817097A (en) * 2019-11-13 2020-02-21 陈繁 Environment-friendly laundry detergent
CN111269764A (en) * 2020-02-28 2020-06-12 山东丽波日化股份有限公司 Hand washing liquid detergent and preparation method thereof
CN111518630A (en) * 2020-05-13 2020-08-11 杭州炫墨生物科技有限公司 Laundry detergent with antibacterial function and preparation method thereof
CN111690475A (en) * 2020-05-15 2020-09-22 泉后(广州)生物科技研究院有限公司 Hard water-resistant high-efficiency active matter composition and application thereof
CN114836270A (en) * 2022-02-24 2022-08-02 青岛小鹿先生智能科技有限公司 Machine-washing shoe washing liquid and preparation method thereof
WO2023116310A1 (en) * 2021-12-23 2023-06-29 上海家化联合股份有限公司 Cleaning composition for removing protein stains

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CN102876483A (en) * 2012-10-11 2013-01-16 广州立白企业集团有限公司 Low-foam and easily bleachable laundry detergent composition and preparation method thereof
CN103060140A (en) * 2013-01-07 2013-04-24 北京洛娃日化有限公司 Neutral low-foam liquid laundry detergent containing natural grease
CN103194328A (en) * 2013-04-28 2013-07-10 北京绿伞化学股份有限公司 Cosolvent-free high-power concentrated detergent and preparation method thereof
CN104818168A (en) * 2015-04-28 2015-08-05 威莱(广州)日用品有限公司 Laundry soap solution and preparation method thereof
CN106318738A (en) * 2016-08-23 2017-01-11 浙江神英科技有限公司 Herbal ingredient laundry detergent and preparing method thereof
CN107603771A (en) * 2017-10-13 2018-01-19 北京洛娃日化有限公司 One kind concentration liquid detergent and preparation method

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CN110817097A (en) * 2019-11-13 2020-02-21 陈繁 Environment-friendly laundry detergent
CN110817097B (en) * 2019-11-13 2022-09-16 潮州市潮安区强盛彩印制版有限公司 Environment-friendly laundry detergent packaging bag
CN111269764A (en) * 2020-02-28 2020-06-12 山东丽波日化股份有限公司 Hand washing liquid detergent and preparation method thereof
CN111518630A (en) * 2020-05-13 2020-08-11 杭州炫墨生物科技有限公司 Laundry detergent with antibacterial function and preparation method thereof
CN111690475A (en) * 2020-05-15 2020-09-22 泉后(广州)生物科技研究院有限公司 Hard water-resistant high-efficiency active matter composition and application thereof
CN111690475B (en) * 2020-05-15 2021-08-31 泉后(广州)生物科技研究院有限公司 Hard water-resistant high-efficiency active matter composition and application thereof
WO2023116310A1 (en) * 2021-12-23 2023-06-29 上海家化联合股份有限公司 Cleaning composition for removing protein stains
CN114836270A (en) * 2022-02-24 2022-08-02 青岛小鹿先生智能科技有限公司 Machine-washing shoe washing liquid and preparation method thereof
CN114836270B (en) * 2022-02-24 2024-02-23 青岛小鹿先生智能科技有限公司 Machine-washing shoe-washing liquid and preparation method thereof

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Application publication date: 20190104