CN105886170A - Enzyme-containing concentrated low foam type laundry detergent and preparation method thereof - Google Patents
Enzyme-containing concentrated low foam type laundry detergent and preparation method thereof Download PDFInfo
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- CN105886170A CN105886170A CN201410764378.9A CN201410764378A CN105886170A CN 105886170 A CN105886170 A CN 105886170A CN 201410764378 A CN201410764378 A CN 201410764378A CN 105886170 A CN105886170 A CN 105886170A
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- nonionic surfactant
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Abstract
The invention relates to the field of detergent compositions of nonionic compounds and anionic compounds and in particular relates to an enzyme-containing concentrated low foam type laundry detergent and a preparation method thereof. The enzyme-containing concentrated low foam type laundry detergent comprises multiple surfactants, and is characterized by also comprising multiple bio-enzyme preparations, multiple solvents, a compound stabilizer, a chelating agent, a preservative, essence and water. The method for preparing the enzyme-containing concentrated low foam type laundry detergent is characterized by comprising the following steps: adding water and alkaline solution, heating, adding fatty acids and stirring, adding the chelating agent, stirring and dissolving; adding the anionic surfactant and multiple nonionic surfactants according to a sequence, and stirring until the surfactants are totally dissolved; adding the balance of water, cooling, sequentially adding the multiple solvents, compound stabilizer, multiple bio-enzyme preparations, essence and preservative, and stirring until the materials are completely dissolved. The laundry detergent disclosed by the invention is small in amount, good in effect, simple in preparation and low in cost.
Description
Technical field
The present invention relates to the composition of detergent field of nonionic compound and anionic compound, be specially
A kind of containing the enzyme low alveolitoid liquid detergent of concentration and manufacture method thereof.
Background technology
At present, fabric detergent mainly has the several prods such as laundry soap, detergent and liquid detergent, is that people live
In necessary.Along with progress and the development of science and technology in epoch, and people are to low-carbon (LC), the requirement of environmental protection,
Liquid detergent is with its exclusive advantage, such as: manufacturing process is simple, equipment investment is few, save the energy, easy to use,
Dissolution in low temperature is good, system is alkaline low etc., and the market segment share replacing detergent becomes the laundry of people
The newly selected.And at present the most on the market liquid detergent have that active matter is on the low side, washing time consumption is high, foam is higher, be difficult to
The phenomenon of rinse, is not particularly suitable for roller washing machine；Meanwhile, to there is also resource energy consumption high, unrestrained for ordinary liquid laundry detergent
Take packaging, increase storage and freight.It addition, ordinary liquid laundry detergent scarcely contains enzyme preparation, to bloodstain,
The decontamination of the special dirts such as milk stain, sweat stain is poor.
Summary of the invention
In order to overcome the defect of prior art, it is provided that a kind of consumption is few, effective, it is simple, with low cost to prepare
Articles for washing, the invention discloses and a kind of concentrate low alveolitoid liquid detergent and manufacture method thereof containing enzyme.
The present invention reaches goal of the invention by following technical solution:
A kind of containing the enzyme low alveolitoid liquid detergent of concentration, including polynary surfactant, it is characterized in that: also include polynary
Biological enzyme formulation, multicomponent solvent, complex stabilizer, chelating agen, preservative, essence and water, the matter of each component
Amount percent concentration is:
Wherein:
Polynary surfactant is by polynary nonionic surfactant, anion surfactant and fatty acid soaps group
Become:
The general structure of polynary nonionic surfactant is: R (OC2H4)nOH, in formula, R is C10～C15
Alkylol, n takes the positive integer in the range of [5,11], and in polynary nonionic surfactant, n takes the group of [5,9] scope
Sub-prime amount accounts for the 40%～50% of polynary nonionic surfactant gross mass；
The general structure of anion surfactant is R (OC2H4)nSO3Na, in formula, R is C10～C15 alkyl
Alcohol, n takes 2 or 3；
The quality of polynary nonionic surfactant: the quality of anion surfactant is 1: 1～2: 1；
The general structure of fatty acid soaps is RCOONa, in formula R select C8～C18, C12～C18 or C12,
C14, C16, C18, the quality of fatty acid soaps accounts for the 1%～5% of polynary surfactant gross mass；
Multi-element biologic enzyme preparation select in protease, lipase, cellulase and amylase any one or appoint
Anticipate several mixing；
Multicomponent solvent select in ethanol, ethylene glycol, butyl glycol ether and butyl any one or appoint
Anticipate several mixing；
Complex stabilizer select in propylene glycol, calcium chloride, Borax and water-soluble carboxylate any one or arbitrarily
Several mixing；Described water-soluble carboxylate selects the alkali metal salt of carboxylic acid (in sodium formate and sodium acetate
Any one or the most several mixing)；
Chelating agen selects sodium citrate.
Described concentrates low alveolitoid liquid detergent containing enzyme, it is characterized in that: fat selected by polynary nonionic surfactant
Polyoxyethylenated alcohol-9 and fatty alcohol-polyoxyethylene ether-7, wherein the quality of fatty alcohol-polyoxyethylene ether-7 accounts for polynary
The 40%～50% of nonionic surfactant gross mass.
Described concentrates low alveolitoid liquid detergent containing enzyme, it is characterized in that: poly alkyl alcohol selected by anion surfactant
Oxygen vinyl Ether sodium sulfate-70 type.
Described concentrates low foam laundry liquid containing enzyme, it is characterized in that: fatty acid soaps selects carbon chain lengths to be 8～18
Mixture, or carbon chain lengths is any one in 12～18, or the mixture that carbon chain lengths is 12～18 and
Sodium hydroxide solution product after saponification under uniform temperature and proportioning.
The described manufacture method concentrating low foam laundry liquid containing enzyme, is characterized in that: implement as follows:
In preparation tank, be initially charged part soften water and sodium hydroxide aqueous alkali, and temperature is risen to 55 DEG C～
65 DEG C, adding fatty acid, stirring is to fully transparent；Add chelating agen (such as sodium citrate), stirring and dissolving；Press
Order adds anion surfactant (such as polyoxyethylenated alcohol sodium sulfate-70 type), polynary nonionic table
Face activating agent (such as fatty alcohol-polyoxyethylene ether-9, fatty alcohol-polyoxyethylene ether-7), stirs to all dissolving；So
After, add surplus and soften water, and cool the temperature to less than 30 DEG C, be sequentially added into multicomponent solvent, complex stabilizer,
Multi-element biologic enzyme preparation, essence and preservative, stirring is to being completely dissolved；Sampling chemically examine, qualified after, mistake
Filter, filling bottle, pack.
Present invention employs polynary nonionic surfactant, anion surfactant and fatty acid soaps and carry out multiple
Joining, not only ensure washing detergency, the foam in washing process have also been obtained control simultaneously, it is easy to rinsing；
Have employed multi-element biologic enzyme preparation, can effectively remove the multiple special dirts such as the milk stain on medicated clothing, sweat stain, bloodstain；
Have employed polynary organic solvent and complex stabilizer technology makes enzyme preparation vigor stability be improved.
The present invention compares with ordinary liquid laundry detergent and has the advantage that
Due to for Concentrated formulations, when the formula that surface-active contents is 30%, washing consumption reduces half,
Have well performance at GB JB01, JB03 detergency, owing to adding enzyme preparation, to GB albumen dirt JB03,
The special soiled cotton of WFK10026, EMPA164 shows preferable decontamination ratio；During washing, foam is low, it is easy to drift
Wash.
Tables 1 and 2 is the contrast of the detergency of the present invention, foam volume and ordinary liquid laundry detergent respectively.
Table 1
The present invention is 1g consumption, and ordinary liquid laundry detergent is 2g consumption, compares with GB liquid detergent 2g consumption.
Table 2
Washing foam test is the dynamic survey of the foam carried out in different wash times based on Household drum washing machine
Examination, the full window of foam height observed by roller washing machine window is 230mm, and in washing process, foam height is at 230mm
For high foam laundry liquid, and foam height is low foam laundry liquid below window height half 110mm.
From Table 1 and Table 2, the present invention is in the case of consumption halves, and detergency still has than ordinary liquid laundry detergent
Well performance；On foam shows, the present invention is in whole roller washing machine washing process, and foam height is tieed up
Hold below window one half height, for Low-foam and easily bleaching washing liquid.
Detailed description of the invention
The present invention is further illustrated below by way of specific embodiment.
Embodiment 1～4,
During manufacture, implement as follows:
In preparation tank, be initially charged part soften water and sodium hydroxide aqueous alkali, and temperature is risen to 55 DEG C～
65 DEG C, adding fatty acid, stirring is to fully transparent；Add chelator acid citrate sodium, stirring and dissolving；In order
Add anion surfactant i.e. polyoxyethylenated alcohol sodium sulfate-70 type, polynary nonionic surfactant
I.e. fatty alcohol-polyoxyethylene ether-9 and fatty alcohol-polyoxyethylene ether-7, stir to all dissolving；Then, surplus is added
Soften water, and cool the temperature to less than 30 DEG C, be sequentially added into multicomponent solvent, complex stabilizer, multi-element biologic enzyme
Preparation, essence and preservative, stirring is to being completely dissolved；Sampling chemically examine, qualified after, filter, filling bottle,
Pack.
Claims (5)
1. concentrate a low alveolitoid liquid detergent containing enzyme, including polynary surfactant, it is characterized in that: also include many
Unit's biological enzyme formulation, multicomponent solvent, complex stabilizer, chelating agen, preservative, essence and water, each component
Mass percent concentration is:
Wherein:
Polynary surfactant is by polynary nonionic surfactant, anion surfactant and fatty acid soaps group
Become:
The general structure of polynary nonionic surfactant is: R (OC2H4)nOH, in formula, R is C10～C15
Alkylol, n takes the positive integer in the range of [5,11], and in polynary nonionic surfactant, n takes the group of [5,9] scope
Sub-prime amount accounts for the 40%～50% of polynary nonionic surfactant gross mass；
The general structure of anion surfactant is R (OC2H4)nSO3Na, in formula, R is C10～C15 alkyl
Alcohol, n takes 2 or 3；
The quality of polynary nonionic surfactant: the quality of anion surfactant is 1: 1～2: 1；
The general structure of fatty acid soaps is RCOONa, in formula R select C8～C18, C12～C18 or C12,
C14, C16, C18, the quality of fatty acid soaps accounts for the 1%～5% of polynary surfactant gross mass；
Multi-element biologic enzyme preparation select in protease, lipase, cellulase and amylase any one or appoint
Anticipate several mixing；
Multicomponent solvent select in ethanol, ethylene glycol, butyl glycol ether and butyl any one or appoint
Anticipate several mixing；
Complex stabilizer select in propylene glycol, calcium chloride, Borax and water-soluble carboxylate any one or arbitrarily
Several mixing；Described water-soluble carboxylate selects the alkali metal salt of carboxylic acid；
Chelating agen selects sodium citrate.
2. as claimed in claim 1 containing the enzyme low alveolitoid liquid detergent of concentration, it is characterized in that: polynary non-ionic surface
Activating agent selects fatty alcohol-polyoxyethylene ether-9 and fatty alcohol-polyoxyethylene ether-7, wherein fatty alcohol-polyoxyethylene ether-7
Quality account for the 40%～50% of polynary nonionic surfactant gross mass.
3. as claimed in claim 1 containing the enzyme low alveolitoid liquid detergent of concentration, it is characterized in that: anion surface active
Polyoxyethylenated alcohol sodium sulfate-70 type is selected in agent.
4. concentrate low foam laundry liquid containing enzyme as claimed in claim 1, it is characterized in that: fatty acid soaps selects carbon
Chain length is the mixture of 8～18, or carbon chain lengths is any one in 12～18, or carbon chain lengths be 12～
The mixture of 18 and sodium hydroxide solution product after saponification under uniform temperature and proportioning.
5. such as the manufacture method concentrating low foam laundry liquid containing enzyme as described in any one in claims 1 to 4,
It is characterized in that: implement as follows:
In preparation tank, be initially charged part soften water and sodium hydroxide aqueous alkali, and temperature is risen to 55 DEG C～
65 DEG C, adding fatty acid, stirring is to fully transparent；Add chelating agen, stirring and dissolving；Be sequentially added into cloudy from
Sub-surface activating agent, polynary nonionic surfactant, stir to all dissolving；Then, add surplus to soften
Water, and cool the temperature to less than 30 DEG C, be sequentially added into multicomponent solvent, complex stabilizer, multi-element biologic enzyme preparation,
Essence and preservative, stirring, to being completely dissolved, is filtered.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410764378.9A CN105886170A (en) | 2014-12-12 | 2014-12-12 | Enzyme-containing concentrated low foam type laundry detergent and preparation method thereof |
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| CN201410764378.9A CN105886170A (en) | 2014-12-12 | 2014-12-12 | Enzyme-containing concentrated low foam type laundry detergent and preparation method thereof |
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| CN105886170A true CN105886170A (en) | 2016-08-24 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106635467A (en) * | 2016-09-22 | 2017-05-10 | 长兴净安环保科技有限公司 | Collar cleaner and preparation method thereof |
| CN107488529A (en) * | 2017-07-22 | 2017-12-19 | 深圳诺漫斯生物科技有限公司 | The low foam laundry liquid and preparation method of a kind of antipathogenic composition containing American cockroach |
| CN108676629A (en) * | 2018-06-13 | 2018-10-19 | 北京日光旭升精细化工技术研究所 | Remove bloodstain cleaning agent and preparation method thereof |
| WO2019000350A1 (en) * | 2017-06-29 | 2019-01-03 | 黄玉倩 | Stabilizer for laundry detergent |
| CN109797054A (en) * | 2019-02-21 | 2019-05-24 | 党峰 | A kind of ferment High-concentration laundry detergent |
| CN113773918A (en) * | 2021-09-17 | 2021-12-10 | 广东优凯科技有限公司 | Premix with high content of surfactant and composition containing premix |
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| CN102071111A (en) * | 2011-01-12 | 2011-05-25 | 广州立白企业集团有限公司 | Laundry liquid and preparation method thereof |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102876483A (en) * | 2012-10-11 | 2013-01-16 | 广州立白企业集团有限公司 | Low-foam and easily bleachable laundry detergent composition and preparation method thereof |
| CN103013723A (en) * | 2012-12-21 | 2013-04-03 | 纳爱斯集团有限公司 | Low-foam laundry detergent composite facilitating rinsing |
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2014
- 2014-12-12 CN CN201410764378.9A patent/CN105886170A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102071111A (en) * | 2011-01-12 | 2011-05-25 | 广州立白企业集团有限公司 | Laundry liquid and preparation method thereof |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102876483A (en) * | 2012-10-11 | 2013-01-16 | 广州立白企业集团有限公司 | Low-foam and easily bleachable laundry detergent composition and preparation method thereof |
| CN103013723A (en) * | 2012-12-21 | 2013-04-03 | 纳爱斯集团有限公司 | Low-foam laundry detergent composite facilitating rinsing |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106635467A (en) * | 2016-09-22 | 2017-05-10 | 长兴净安环保科技有限公司 | Collar cleaner and preparation method thereof |
| WO2019000350A1 (en) * | 2017-06-29 | 2019-01-03 | 黄玉倩 | Stabilizer for laundry detergent |
| CN107488529A (en) * | 2017-07-22 | 2017-12-19 | 深圳诺漫斯生物科技有限公司 | The low foam laundry liquid and preparation method of a kind of antipathogenic composition containing American cockroach |
| CN108676629A (en) * | 2018-06-13 | 2018-10-19 | 北京日光旭升精细化工技术研究所 | Remove bloodstain cleaning agent and preparation method thereof |
| CN109797054A (en) * | 2019-02-21 | 2019-05-24 | 党峰 | A kind of ferment High-concentration laundry detergent |
| CN113773918A (en) * | 2021-09-17 | 2021-12-10 | 广东优凯科技有限公司 | Premix with high content of surfactant and composition containing premix |
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| C06 | Publication | ||
| PB01 | Publication | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Shi Rongying Inventor after: Wang Xiaochun Inventor after: Ye Cui Inventor before: Xu Qiumei Inventor before: Wang Xiaochun Inventor before: Zhang Lei |
|
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: Xuhui District Pingfu road 200231 Shanghai City No. 188 Caohejing Xin Park 3 Building second layer Applicant after: Shanghai Whitecat Shareholding Co., Ltd. Address before: 200231 No. 1800, Wu Long Road, Shanghai, Xuhui District Applicant before: Shanghai Whitecat Shareholding Co., Ltd. |
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160824 |