CN106318678A - Protease hyperconcentration laundry detergent with no water or corrosion remover or alcohol - Google Patents
Protease hyperconcentration laundry detergent with no water or corrosion remover or alcohol Download PDFInfo
- Publication number
- CN106318678A CN106318678A CN201610588044.XA CN201610588044A CN106318678A CN 106318678 A CN106318678 A CN 106318678A CN 201610588044 A CN201610588044 A CN 201610588044A CN 106318678 A CN106318678 A CN 106318678A
- Authority
- CN
- China
- Prior art keywords
- protease
- alcohol
- free
- laundry detergent
- washing liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a protease hyperconcentration laundry detergent with no water or corrosion remover or alcohol. The hyperconcentration laundry detergent is prepared from, by weight, 85-95% of total active matters, 4-14% of a solubilizer and 0.1-1.0% of protease, wherein the total active matters are composed of 20-85% of an anion surface active agent and 15-80% of a non-ionic surface active agent. The laundry detergent contains no water or corrosion remover, does not injure skin, is neutral in formula and has the ultra-strong detergency power, the concentration multiple is at least higher than 5.5 times or more that of a common laundry detergent. The protease hyperconcentration laundry detergent is superhigh in active matter concentration, large in cleaning range, dissolvable in water and abundant in bubble; the product is neutral and mild in character, has no stimulation and soft in touch, has no alkaline residues after being used for washing, will not cause symptoms such as skin allergy, will not damage a fabric, and is convenient to use, capable of conveniently controlling the consumption, and convenient to store and use.
Description
Technical field
The present invention relates to a kind of concentration liquid detergent, be specifically related to a kind of alive with anion surfactant and non-ionic surface
Property agent compounds the protease Superconcentrated washing liquid that the anhydrous preservative free of making is alcohol-free.
Background technology
Liquid detergent, uses nonionic surfactant more, and pH is close to neutral, gentle to skin, and enters nature
After, relatively detergent of degrading is fast, for the detergent of a new generation.The highest i.e. active matter content of liquid detergent concentration is the highest, and consumption more saves,
Therefore, the increasing laundry liquid product that concentrates is had to release on the market.But, along with progress and the development of science and technology, the ring of society
Protecting awareness of saving energy to be gradually rooted in the hearts of the people, the requirement concentrating environmental protection is the most increasingly valued by people, and most concentration on the market is washed
Clothing liquid is the most all added with preservative, and its active matter content is generally only about 2 times of ordinary liquid laundry detergent；Common concentration is washed
Clothing liquid contains certain moisture mostly, and cycles of concentration is generally 2-3 times, in use, the most really plays the actual meaning of concentration
Justice.
Summary of the invention
The technical problem to be solved is: for above-mentioned the deficiencies in the prior art, it is provided that a kind of moisture-free and
Preservative, not spirituosity, do not injure skin, and pH is neutral, has superstrong pollution-removing power, and cycles of concentration is at least above ordinary liquid laundry detergent
The protease Superconcentrated washing liquid that the anhydrous preservative free of more than 5.5 times is alcohol-free.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is: a kind of anhydrous preservative free is alcohol-free
Protease Superconcentrated washing liquid, this concentration liquid detergent is by weight percentage by gross activity thing 85-95%, solubilizing agent 4-14% and egg
White enzyme 0.1-1.0% composition；Wherein, this gross activity thing is by anion surfactant 20-85% and nonionic surfactant 15-
80% composition.
Present invention simultaneously provides another kind of technical scheme: the protease Superconcentrated washing that a kind of anhydrous preservative free is alcohol-free
Liquid, this concentration liquid detergent is by weight percentage by gross activity thing 85-95%, solubilizing agent 4-14%, proteinase-10 .1-1.0% and essence
0.05-0.7% forms；Wherein, this gross activity thing is by anion surfactant 20-85% and nonionic surfactant 15-80%
Composition.
Above-mentioned anion surfactant is in DBSA ethanolamine salt or pelopon A
One or both.
Above-mentioned nonionic surfactant is straight chain fatty polyoxyethylenated alcohol or Branched fatty polyoxyethylenated alcohol or alkane
One or both or three kinds in base glucosides.
Above-mentioned solubilizing agent is glycerol, propylene glycol, 1,3 propylene glycol or 1, one or more in 3 butanediols.
Above-mentioned protease includes bio protease or compound protease, for commercial products.
The Superconcentrated washing liquid of the present invention uses anion surfactant and nonionic surfactant to compound and forms, tool
Having good hydrophilic and lipophile, wherein pelopon A belongs to anion surfactant, has good
Decontamination, emulsifying, moistening and foam performance, little to skin and eye irritation, stable in hard water.Nonionic surfactant is
It is made up of fatty alcohol polyethenoxy ether class surface-active substance, there is good moistening, emulsifiability and stronger dirt-removing power, right
Acid, alkali and hard water are stable.
With overwhelming majority liquid detergent difference on the market, the concentration liquid detergent that the present invention provides is that moisture-free does not has
Having interpolation preservative, cycles of concentration is about more than 5.5 times of plain edition liquid detergent.
The protease Superconcentrated washing liquid of the present invention, formula is gentle, activity concentration superelevation, moisture-free, is not added with preventing
Rotten agent, alcohol-free, clean range is big, soluble in water, foaming abundancy.Product partial neutral character is gentle, non-stimulated, feel is soft,
Will not leave behind basic residual after washing, be not result in the symptoms such as skin allergy, fabric be there will not be damage, easy to use, consumption
It is easy to control, it is simple to store, easy to use.This concentration liquid detergent is not only greatly saved bottled, reduces the possibility of environmental pollution
Property, and gross activity thing content is high, reaches 85-95%, is the rarest a kind of Concentrated formulations liquid detergent.
Detailed description of the invention
Embodiment 1
Take gross activity thing 85%(gross activity thing by weight percentage by weight percentage by DBSA ethanolamine salt 20%
Form with straight chain fatty polyoxyethylenated alcohol 80%), glycerol 2%, 1,3 butylene glycol 12% and bio protease 1.0% mix, stirring
Uniformly i.e. obtain the Superconcentrated washing liquid of the present invention.
Embodiment 2
Take gross activity thing 90%(gross activity thing by weight percentage by weight percentage by pelopon A 10%, ten
Dialkyl benzene sulfonic acids ethanolamine salt 40%, straight chain fatty polyoxyethylenated alcohol 20% and alkyl polyglucoside 30% form), propylene glycol 9.9%
And compound protease 0.1% mixes, stir and i.e. obtain the Superconcentrated washing liquid of the present invention.
Embodiment 3
Take gross activity thing 95%(gross activity thing by weight percentage by weight percentage by pelopon A 30%, ten
Dialkyl benzene sulfonic acids ethanolamine salt 40%, Branched fatty polyoxyethylenated alcohol 20% and alkyl polyglucoside 10% form), 1,3 propylene glycol 4%
And bio protease 1.0% mixes, stir and i.e. obtain the Superconcentrated washing liquid of the present invention.
Embodiment 4
Take gross activity thing 88%(gross activity thing by weight percentage by weight percentage by DBSA ethanolamine salt 85%
Form with straight chain fatty polyoxyethylenated alcohol 10% and alkyl polyglucoside 5%), 1,3 butanediols 10.8%, compound protease 0.5% and perfume
Essence 0.7% mixing, stirs and i.e. obtains the Superconcentrated washing liquid of the present invention.
Embodiment 5
Take by weight percentage gross activity thing 85%(gross activity thing by weight percentage by pelopon A 40%,
Chain fatty alcohol polyoxyethylene ether 30% and alkyl polyglucoside 30% form), glycerol 7.2%, propylene glycol 6.75%, compound protease 1.0% and
Essence 0.05% mixes, and stirs and i.e. obtains the Superconcentrated washing liquid of the present invention.
Claims (6)
1. the protease Superconcentrated washing liquid that an anhydrous preservative free is alcohol-free, it is characterised in that this concentration liquid detergent is by weight
Amount percentage ratio is made up of gross activity thing 85-95%, solubilizing agent 4-14% and proteinase-10 .1-1.0%；Wherein, this gross activity thing is by the moon
Ionic surface active agent 20-85% and nonionic surfactant 15-80% composition.
2. the protease Superconcentrated washing liquid that an anhydrous preservative free is alcohol-free, it is characterised in that this concentration liquid detergent is by weight
Amount percentage ratio is made up of gross activity thing 85-95%, solubilizing agent 4-14%, proteinase-10 .1-1.0% and essence 0.05-0.7%；Wherein,
This gross activity thing is made up of anion surfactant 20-85% and nonionic surfactant 15-80%.
The protease Superconcentrated washing liquid that anhydrous preservative free the most as claimed in claim 1 or 2 is alcohol-free, it is characterised in that
Described anion surfactant is the one in DBSA ethanolamine salt or pelopon A or two
Kind.
The protease Superconcentrated washing liquid that anhydrous preservative free the most as claimed in claim 1 or 2 is alcohol-free, it is characterised in that
Described nonionic surfactant is in straight chain fatty polyoxyethylenated alcohol, Branched fatty polyoxyethylenated alcohol or alkyl polyglucoside
One or more mixing.
The protease Superconcentrated washing liquid that anhydrous preservative free the most as claimed in claim 1 or 2 is alcohol-free, it is characterised in that
Described solubilizing agent is glycerol, propylene glycol, 1,3 propylene glycol or 1, one or more mixing in 3 butanediols.
The protease Superconcentrated washing liquid that anhydrous preservative free the most as claimed in claim 1 or 2 is alcohol-free, it is characterised in that
Described protease is bio protease or compound protease.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610588044.XA CN106318678A (en) | 2016-07-25 | 2016-07-25 | Protease hyperconcentration laundry detergent with no water or corrosion remover or alcohol |
| PCT/CN2016/092666 WO2018018649A1 (en) | 2016-07-25 | 2016-08-01 | Anhydrous, preservative-free, alcohol-free, super-concentrated liquid laundry detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610588044.XA CN106318678A (en) | 2016-07-25 | 2016-07-25 | Protease hyperconcentration laundry detergent with no water or corrosion remover or alcohol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106318678A true CN106318678A (en) | 2017-01-11 |
Family
ID=57739217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610588044.XA Pending CN106318678A (en) | 2016-07-25 | 2016-07-25 | Protease hyperconcentration laundry detergent with no water or corrosion remover or alcohol |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN106318678A (en) |
| WO (1) | WO2018018649A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108192760A (en) * | 2018-01-17 | 2018-06-22 | 深圳市芭格美生物科技有限公司 | A kind of anhydrous liquid detergent and preparation method thereof |
| CN108359533A (en) * | 2018-02-24 | 2018-08-03 | 佛山市万善环保科技有限公司 | Liquid laundry composition and its application |
| CN108559655A (en) * | 2018-06-08 | 2018-09-21 | 康柏利科技（苏州）有限公司 | A kind of Superconcentrated washing liquid and preparation method thereof |
| CN108587811A (en) * | 2018-05-07 | 2018-09-28 | 安徽索亚装饰材料有限公司 | A kind of production method of skin carving cuticle removers |
| CN111690471A (en) * | 2020-07-08 | 2020-09-22 | 中山榄菊日化实业有限公司 | High-concentration laundry detergent without gel and precipitation and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113373006A (en) * | 2021-06-08 | 2021-09-10 | 四川海辰日用化工有限公司 | Super-concentrated laundry detergent and preparation method thereof |
| CN114736741A (en) * | 2022-02-28 | 2022-07-12 | 温柱 | Environment-friendly high-concentration laundry detergent and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3988265A (en) * | 1973-08-10 | 1976-10-26 | Kao Soap Co., Ltd. | Detergent compositions containing 1-hydroxyalkane-sulfate, surfactants, inorganic builder, having good rinsing characteristics |
| CN101514307A (en) * | 2008-12-31 | 2009-08-26 | 北京绿伞化学股份有限公司 | Transparent and high-concentration laundry detergent and preparation method thereof |
| CN101671605A (en) * | 2009-08-25 | 2010-03-17 | 西安开米股份有限公司 | Quintupling hyperconcentrated liquid detergent for garment |
| CN101979489A (en) * | 2010-11-03 | 2011-02-23 | 广州南顺清洁用品有限公司 | Moisture-less and preservative-less super-concentrated hand-washing detergent composition |
| CN104312754A (en) * | 2014-10-14 | 2015-01-28 | 南风化工集团股份有限公司 | Water-free laundry detergent and preparation method thereof |
| CN105062703A (en) * | 2015-07-27 | 2015-11-18 | 东莞市香与化工有限公司 | Protease super-concentrated laundry detergent and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TR200002723T2 (en) * | 1998-04-30 | 2000-12-21 | Henkel Kommanditgesellschaft Auf Aktien | Dishwashing liquid with an antibacterial effect |
-
2016
- 2016-07-25 CN CN201610588044.XA patent/CN106318678A/en active Pending
- 2016-08-01 WO PCT/CN2016/092666 patent/WO2018018649A1/en active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3988265A (en) * | 1973-08-10 | 1976-10-26 | Kao Soap Co., Ltd. | Detergent compositions containing 1-hydroxyalkane-sulfate, surfactants, inorganic builder, having good rinsing characteristics |
| CN101514307A (en) * | 2008-12-31 | 2009-08-26 | 北京绿伞化学股份有限公司 | Transparent and high-concentration laundry detergent and preparation method thereof |
| CN101671605A (en) * | 2009-08-25 | 2010-03-17 | 西安开米股份有限公司 | Quintupling hyperconcentrated liquid detergent for garment |
| CN101979489A (en) * | 2010-11-03 | 2011-02-23 | 广州南顺清洁用品有限公司 | Moisture-less and preservative-less super-concentrated hand-washing detergent composition |
| CN104312754A (en) * | 2014-10-14 | 2015-01-28 | 南风化工集团股份有限公司 | Water-free laundry detergent and preparation method thereof |
| CN105062703A (en) * | 2015-07-27 | 2015-11-18 | 东莞市香与化工有限公司 | Protease super-concentrated laundry detergent and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108192760A (en) * | 2018-01-17 | 2018-06-22 | 深圳市芭格美生物科技有限公司 | A kind of anhydrous liquid detergent and preparation method thereof |
| CN108359533A (en) * | 2018-02-24 | 2018-08-03 | 佛山市万善环保科技有限公司 | Liquid laundry composition and its application |
| CN108587811A (en) * | 2018-05-07 | 2018-09-28 | 安徽索亚装饰材料有限公司 | A kind of production method of skin carving cuticle removers |
| CN108559655A (en) * | 2018-06-08 | 2018-09-21 | 康柏利科技（苏州）有限公司 | A kind of Superconcentrated washing liquid and preparation method thereof |
| CN111690471A (en) * | 2020-07-08 | 2020-09-22 | 中山榄菊日化实业有限公司 | High-concentration laundry detergent without gel and precipitation and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018018649A1 (en) | 2018-02-01 |
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Application publication date: 20170111 |