CN108192760A - A kind of anhydrous liquid detergent and preparation method thereof - Google Patents
A kind of anhydrous liquid detergent and preparation method thereof Download PDFInfo
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- CN108192760A CN108192760A CN201810043795.2A CN201810043795A CN108192760A CN 108192760 A CN108192760 A CN 108192760A CN 201810043795 A CN201810043795 A CN 201810043795A CN 108192760 A CN108192760 A CN 108192760A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The present invention is suitable for daily chemical products technical field, provides a kind of anhydrous liquid detergent and preparation method thereof, anhydrous liquid detergent includes the component of following parts by weight：Nonionic surfactant：18~25 parts；Anion surfactant：21.2~27.5 parts；Alkylol ether surfactant：35.1~42 parts；Alcohol：1.5~2.5 parts；Liquid detergent enzyme：0.4~2.2 part.The anhydrous liquid detergent of the present invention is hyperconcetration formula, uses the vigor stability of a variety of complex enzymes and complex enzyme high in formula, under the synergistic effect of complex enzyme and surfactant, can fast and effeciently remove the various stains in clothing, washing effect is good；In addition, formula is neutral low foam formulations, it is easy to rinsing and noresidue, and mildly non-stimulated to skin, while not damaging laundry.
Description
Technical field
The invention belongs to daily chemical products technical fields more particularly to a kind of anhydrous liquid detergent and preparation method thereof.
Background technology
Due to the formula of liquid detergent is soft and in the residual of clothing it is less, so be well received by consumers, Qi Shi places
Position is also gradually established.And the activity substance content of concentrated type liquid detergent is high, usage amount is few, cleaning dirt-removing power is apparently higher than commonly
Liquid detergent, and specification is compact, is convenient for carrying and transports, it is easy to utilize, therefore with preferable market prospects.
However, commercially available concentrated type liquid detergent type and brand and few, domestic well-known brand such as blue moon is opened rice and is related to
The foot field, still, finds, the activity substance content of existing concentrated type liquid detergent is generally 26%~42% through market survey
Between, and the enzyme activity stability of some concentrated type liquid detergents containing enzyme is not high so that and under equal conditions, cleaning of washing etc.
Effect is unsatisfactory.
It can be seen that existing concentrated type liquid detergent activity substance content is not high, and enzyme activity stability is not high, equal
Under conditions of, the clean effect of washing is unsatisfactory.
Invention content
The embodiment of the present invention provides a kind of anhydrous liquid detergent, it is intended to solve existing concentrated type liquid detergent activity substance content
It is not high, and enzyme activity stability is not high, under comparable conditions, the problem of clean effect of washing is unsatisfactory.
The embodiment of the present invention is achieved in that a kind of anhydrous liquid detergent, includes the component of following parts by weight：Nonionic table
Face activating agent：18~25 parts；Anion surfactant：21.2~27.5 parts；Alkylol ether surfactant：35.1~42
Part；Alcohol：1.5~2.5 parts；Liquid detergent enzyme：0.4~2.2 part.
Preferably, the liquid detergent enzyme is protease, lipase, amylase, bromelain, mannonase cellulase
Or at least five kinds of mixture in lysozyme.
Preferably, the liquid detergent enzyme is the mixed of protease, lipase, cellulase, mannase and lysozyme
Close object.
Preferably, a kind of anhydrous liquid detergent includes the component of following parts by weight：Nonionic surfactant：20 parts；The moon from
Sub- surfactant：21.2 parts；Alkylol ether surfactant：42 parts；Alcohol：1.5 part；Liquid detergent enzyme：2.2 part.
Preferably, anhydrous liquid detergent includes the component of following parts by weight：Nonionic surfactant：18~25 parts；The moon from
Sub- surfactant：21.2~27.5 parts；Alcohol：1.5~2.5 parts；Liquid detergent enzyme：0.4~2.2 part；Alkylol ethers surface
Activating agent：35.1~42 parts；Polyethylene terephthalate：0.5~0.8 part；Anti redeposition agent：1.5~2.2 parts；Sterilization
Agent：8~10 parts；Essence：0.3~0.6 part.
Preferably, anhydrous liquid detergent includes the component of following parts by weight：Nonionic surfactant：20 parts；Anion table
Face activating agent：21.2 parts；Alcohol：1.5 part；Liquid detergent enzyme：2.2 part；Alkylol ether surfactant：42 parts；Gather to benzene two
Formic acid glycol ester：0.5 part；Anti redeposition agent：2.2 part；Fungicide：10 parts；Essence：0.4 part.
Preferably, the nonionic surfactant is nonylphenol polyoxyethylene ether, octyl phenol polyoxyethylene ether, fatty alcohol
Either a kind of in sucrose fatty ester or at least two mixing of polyoxyethylene ether, cocoanut fatty acid diethanolamide
Object；
The anion surfactant is dodecyl benzene sulfonic acid, sodium sulfate of polyethenoxy ether of fatty alcohol, poly alkyl alcohol
In ethylene oxide ether carboxylic acid sodium, ethoxylated fatty acid sulfonate, diisooctyl Disodium sulfosuccinate or sodium secondary alkyl sulfonate
It is a kind of or at least two mixture.
Preferably, the fungicide is dodecyl benzyl dimethyl ammonium chloride, to chloroxylenol, polyhexamethylene pair
At least two mixture in guanidine, tasteless L antiseptics, triclosan or didecyl Dimethy ammonium chloride.
Preferably, the nonionic surfactant includes the substance of following parts by weight：20 parts of fatty alcohol polyoxyethylene ether；
The anion surfactant includes the substance of following parts by weight：21.2 parts of AEO carboxylic acid sodium；Alkylol
42 parts of ether surfactant；Polyethylene terephthalate：0.5 part；2.2 parts of anti redeposition agent；Alcohol：1.5 part；It is described
Fungicide includes the substance of following parts by weight：7 parts of dodecyl benzyl dimethyl ammonium chloride and to 3 parts of chloroxylenol；It is described
Liquid detergent enzyme includes the substance of following parts by weight：.6 parts of proteinase-10,0.6 part of lipase, 0.3 part of cellulase, mannase
0.3 part and 0.4 part of lysozyme；And essence：0.4 part.
The embodiment of the present invention also provides the preparation method of anhydrous liquid detergent, includes the following steps：
Step 1：Formula according to above-mentioned anhydrous liquid detergent weighs each component, spare；
Step 2：The nonionic surfactant, anion surfactant and alcohol are put into ingredients pot, and
Stirring is to being completely dissolved；
Step 3：It puts into the alkylol ether surfactant into the ingredients pot, and stirs to being completely dissolved；
Step 4：The liquid detergent enzyme is put into the ingredients pot, and is stirred to being completely dissolved, obtains the no washing
Clothing liquid product.
Below to each raw material in above-mentioned anhydrous laundry liquid formulation the effect of and ingredient do specific description：
Protease：Protease can be used as skin conditioning agent.The ingredient is that decomposing protein is Amino acid, and hydrolysate is in skin
Surface layer forms one layer of amino acid and spreads out object film, make skin keep wetting with it is smooth.
Lipase：It can accelerate lipolysis, also with Oily conditioning is made, temperature and pH be required more.
Amylase：The effect of amylase is that resolve into the dirt of starch such as chocolate, mashed potatoes, noodles, congee etc. can
The dextrin of dissolubility, so as to remove the dirt of starch.Meanwhile amylase is cooperateed with between protease and lipase with good
Effect.Because the ingredient in practical dirt is extremely complex, using the compounding of several enzyme preparations, can greatly improve
Dirty effect.
Bromelain：Bromelain has the function of anti-inflammatory, and inflammation and oedema, spinach can be effectively treated in various tissues
Trailing plants protease has the potentiality of activation inflammatory reaction.Bromelain have effects that tender skin, whitening despeckle it is excellent.Bromelain
Enzyme may act on aging cutin layer on human skin, promote its degenerate, decompose, removal, promote skin metabolism, reduce because
Skin color depth phenomenon caused by solarization.Make skin care that good delicate state be presented.
Cellulase：The microtriche and small suede that main function object occurs when repeatedly washing for fabric surface on principal fiber
Ball.After being handled with cellulase, the microtriche and bobbles of fabric surface are just removed, can be with smooth fabric surface, and make to have
The color and luster of color clothing becomes more bright-coloured, and white garments is made to restore its true qualities.Cellulase also has soft function, but principal fiber
On microtriche and small bobbles be removed after, principal fiber becomes smooth, and decreases tangling and making fiber between microfibre
Become soft.
Mannase:Mannosan decomposes the manna oligosacchride generated, improves flora composition, reduces Escherichia coli, sramana
The infection of Salmonella.
Lysozyme：It is a kind of to hydrolyze the alkaline enzyme that polysaccharide is sticked in pathogenic bacteria.Mainly by destroying the N- acetyl in cell wall
β-Isosorbide-5-Nitrae glycosidic bond between muramic acid and n-acetylglucosamine makes the insoluble glutinous polysaccharide of cell wall resolve into soluble glycopeptide,
Cell wall rupture content is caused to escape and make bacterolysis.Lysozyme can also with negatively charged virus protein directly in conjunction with,
Double salt is formed with DNA, RNA, apoprotein, is made virally inactivated.Therefore, which has the effects that antibacterial, anti-inflammatory, antiviral,
It is and safe.
Nonylphenol polyoxyethylene ether：It is nonionic surfactant of good performance for light yellow soft paste, it is main to use
In various cleaning agents, textile industry auxiliary agent, lubricating oil, resin emulsifier etc..
Octyl phenol polyoxyethylene ether：It is a kind of multi-functional nonionic surface active agent, there is outstanding wetability, decontamination
The emulsifiability of power, hard surface and metal cleaning performance and brilliance.
Cocoanut fatty acid diethanolamide：Belong to nonionic surfactant, without cloud point.Character is faint yellow to amber
Amber color thick liquid, it is soluble easily in water, there is good foaming, is foam stabilizing, infiltration decontamination, hard water resistance etc..Belong to non-ionic surface
Activating agent, when anion surfactant is in acidity, compatibility thickening effect is particularly evident therewith, can be with a variety of surfactants
Compatibility.
Sucrose fatty ester：A kind of nonionic surfactant, the simple substance generated by sucrose and aliphatic acid through esterification
Or mixture.It is widely used in food, medicine, daily use chemicals, biological work with its nontoxic, easily biological-degradable and good surface property
The industries such as enzyme preparation, oil exploitation, weaving and the farming and animal husbandry of journey.
Fatty alcohol polyoxyethylene ether：From sustainable energy, extremely mildly, nonirritant and sensitization is healthy and safe,
Foam especially enriches stabilization and cleaning capacity is considerable, and biological degradability is good.
Dodecyl benzene sulfonic acid：For in all kinds of detergent, cosmetic formulations, there is good decontamination, moistening, foaming, breast
The performances such as change, dispersion.
AEO carboxylic acid sodium：It is a kind of novel multi-functional anion surfactant, structure and fertilizer
The characteristics of soap is quite similar, but embedded EO chains make it have both anion and nonionic surfactant, can be in extensive pH value
Under the conditions of use.With good detergency, emulsibility, dispersibility and calcium soap dispersion force, there is good foaming power and bubble
Foam stability；Acid and alkali-resistance, resistance to hard water ability are good, nontoxic, non-stimulated, easily biological-degradable.Preferably,
Sodium sulfate of polyethenoxy ether of fatty alcohol：It is good with the compatibility of other surfaces activating agent.It is insensitive to hard water, washing performance
Can be good, there is the effects that emulsification, foaming, decontamination, be hand cleanser, liquid detergent, shower cream, washing powder, liquid detergent, metal cleaning
The main active of agent.
Diisooctyl Disodium sulfosuccinate：Soluble easily in water, solution is milky, intolerant to strong acid, highly basic, heavy metallic salt and
Reducing agent, infiltration is quick, uniform, has good wetting, infiltration, emulsification, frothing capacity.Available for processing cotton, fiber crops, viscose glue and
Its blended product, treated, and fabric is directly bleached or is dyed without kiering, can improve and defect is contaminated caused by dead cotton, printing and dyeing
Fabric feeling afterwards is more soft, plentiful.
Ethoxylated fatty acid sulfonate：It is a kind of comprehensive anion surfactant of performance, low foam, alkaline-resisting, tool
There is good emulsion dispersion ability, having splendid prevents from instead staiing performance.In anion surfactant, ethoxylation fat
Fat acid sulfonate is the current highest product of washing ability, and washing ability is far above other anionic products.
Sodium secondary alkyl sulfonate：It is a kind of excellent anion surfactant, penetration is strong.In highly basic, high temperature, oxidant
In the presence of, still with superior infiltration, emulsification, degreasing, washing ability.
Dodecyl benzyl dimethyl ammonium chloride：Belong to non oxidizing bactericide, there is wide spectrum, efficient sterilization algae removal energy
Power can efficiently control bacterium algae breeding and foundry loam growth in water, and have good sludge stripping effect and certain dispersion, ooze
Effect thoroughly, at the same have it is certain deoil, deodorizing capability and corrosion inhibition.It is and soluble easily in water without accumulation property toxicity, not by water
Hardness influences.
To chloroxylenol：With unique bactericidal properties and anti-corrosive properties so that can efficient and nothing in many germicidal applications
Toxicity plays a role, and is widely used in some medicinal pulvis, soap, amenities and anti-dandruff shampoos.
Poly hexamethylene biguanide：It is widely used in the fields such as health care, household chemicals, papermaking, wet tissue, cultivation, uses
Make disinfectant, antiseptic, bactericidal agent, mould proof (corruption) agent, algicide.It is killed with wide spectrum and inhibits multiple-microorganism, bacterium effect
Persistently, bacterium is not likely to produce drug resistance；Practical nontoxic grade is detected as to human body and higher mammal, it is non-stimulated to skin and mucous membrane
Property.
Tasteless L antiseptics, didecyl Dimethy ammonium chloride：It is respectively provided with excellent bactericidal and bacteriostatic effect.
Triclosan：It is cloudy to Gram positive bacteria, Gram for the safe antibiosis and sterilization agent of external application broad-spectrum high efficacy of international popular
Property sclerotium mould and saccharomycete have stronger inhibitory or killing effect.
Alcohol：Colourless, transparent, the liquid of specific peat-reek, density ratio water is small, can be dissolved each other with water with arbitrary ratio, is one
The important solvent of kind, can dissolve gas chromatography and inorganic matter.
Alkylol ether surfactant：Preferably, alkylol ether surfactant can be used609.Alkyl
Alcohol ether surfactants609 be that the nonylphenol polyoxyethylene ether of new generation (NPEE) that Akzo Nobel releases is replaced
Dai Pin, detergency ability have surmounted the NPE substitutes of current main-stream.609 pour points and cloud point are lower, in cold water
Faster, not needing to solubilizer can be completely soluble, and easily biological-degradable is environmental-friendly, and TSCA and DSL are registered in for solution rate
Row.
Polyethylene terephthalate：A kind of dirt disengages polymer, by preventing grease from going deep into fabric come protective clothing
Object, while synergistic surfactant improves the cleaning performance of cleaning agent.SRN100 can also be combined with dirt, and in fabric surface shape
Into protective film, prevent dirt from redepositing on fabric surface in cleaning process；Fabric whiteness can be effectively repeatedly maintained during washing,
Improve the sense of touch of synthetic textiles；It is similary efficient under low temperature environment and low concentration, available for concentrated product and without phosphorus product.
Anti redeposition agent：Preferably, Tao Shi ACUSOLTM845 can be used.Tao Shi ACUSOLTM845, which are that one kind is novel, to be resisted again
Deposited polymer is hydrophobically modified acrylate copolymer, and polymolecularity, which can be sayed, adapts to the cleaning products enrichments such as liquid detergent
Concept；Sebum dirt detergency can be improved；Improve whiteness retention energy；It can keep formulation stable and promote dispensing viscosity.
Essence：The selection of essence can select to meet as needed《GB/T22731-2008》The requirement of daily essence standard, is fitted
The essence of amount can make clothing carry pleasant pure and fresh taste.
The anhydrous liquid detergent of the present invention is hyperconcetration formula, is stablized in formula using the vigor of a variety of complex enzymes and complex enzyme
Property it is high, under the synergistic effect of complex enzyme and surfactant, can fast and effeciently remove the various stains in clothing, wash
It is good to wash effect；In addition, formula is neutral low foam formulations, it is easy to rinsing and noresidue, and mildly non-stimulated to skin, while do not damage
Hinder clothing.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
The anhydrous liquid detergent of the present invention is hyperconcetration formula, is stablized in formula using the vigor of a variety of complex enzymes and complex enzyme
Property it is high, under the synergistic effect of complex enzyme and surfactant, can fast and effeciently remove the various stains in clothing, wash
It is good to wash effect；In addition, formula is neutral low foam formulations, it is easy to rinsing and noresidue, and mildly non-stimulated to skin, while do not damage
Hinder clothing.
Technical scheme of the present invention and technique effect are described further below by way of specific embodiment.
Embodiment 1：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(20 parts of fatty alcohol polyoxyethylene ether)；Anion surfactant (24.7 parts of AEO carboxylic acid sodium)；Alcohol 1.5
Part；Liquid detergent enzyme (.05 parts of proteinase-10,0.05 part of lipase, 0.1 part of mannase, 0.1 part of cellulase, lysozyme 0.1
Part), totally 0.4 part；Alkylol ether surfactant (alkylol ether surfactant609 41.1 parts)；Poly- pair
0.6 part of ethylene terephthalate (SRN100)；Anti redeposition agent (1.5 parts of Tao Shi ACUSOLTM845)；Fungicide (dodecane
6 parts of base dimethyl benzyl ammonium chloride, to 3 parts of chloroxylenol), totally 9 parts；0.4 part of essence.
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent includes the following steps：
Step 1：Formula according to above-mentioned anhydrous liquid detergent weighs each component, spare.
Step 2：Nonionic surfactant, anion surfactant and alcohol are put into ingredients pot, and is stirred
To being completely dissolved.
Step 3：Alkylol ether surfactant, polyethylene terephthalate are put into above-mentioned ingredients pot
(SRN100), anti redeposition agent and fungicide, and stir to being completely dissolved；
Step 4：Liquid detergent enzyme and essence are put into ingredients pot, and is stirred to being completely dissolved, obtains anhydrous liquid detergent production
Product.
Embodiment 2：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(25 parts of fatty alcohol polyoxyethylene ether)；Anion surfactant (25 parts of AEO carboxylic acid sodium)；Alcohol 2.5
Part；Liquid detergent enzyme (.2 parts of proteinase-10,0.2 part of lipase, 0.2 part of mannase, 0.2 part of cellulase, lysozyme 0.2
Part), totally 1 part；Alkylol ether surfactant (alkylol ether surfactant609 35.1 parts)；Gather to benzene
0.8 part of naphthalate (SRN100)；Anti redeposition agent (2 parts of Tao Shi ACUSOLTM845)；Fungicide (dodecyl two
6 parts of methylbenzyl ammonium chloride, to 2 parts of chloroxylenol), totally 8 parts；0.6 part of essence.
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 1 are identical.
Embodiment 3：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(18 parts of fatty alcohol polyoxyethylene ether)；Anion surfactant (24 parts of AEO carboxylic acid sodium)；2 parts of alcohol；
Liquid detergent enzyme (.4 parts of proteinase-10,0.2 part of lipase, 0.2 part of mannase, 0.4 part of cellulase, 0.4 part of lysozyme),
Totally 1.6 parts；Alkylol ether surfactant (alkylol ether surfactant609 42 parts)；Poly- terephthaldehyde
Sour 0.6 part of glycol ester (SRN100)；Anti redeposition agent (1.5 parts of Tao Shi ACUSOLTM845)；Fungicide (dimethyl
8 parts of base benzyl ammonium chloride, to 2 parts of chloroxylenol), totally 10 parts；0.3 part of essence.
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 1 are identical.
Embodiment 4：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(20 parts of fatty alcohol polyoxyethylene ether)；Anion surfactant (21.2 parts of AEO carboxylic acid sodium)；Alcohol 1.5
Part；Liquid detergent enzyme (.6 parts of proteinase-10,0.6 part of lipase, 0.3 part of mannase, 0.3 part of cellulase, lysozyme 0.4
Part), totally 2.2 parts；Alkylol ether surfactant (alkylol ether surfactant609 42 parts)；Gather to benzene
0.5 part of naphthalate (SRN100)；Anti redeposition agent (2.2 parts of Tao Shi ACUSOLTM845)；Fungicide (dodecyl
7 parts of dimethyl benzyl ammonium chloride, to 3 parts of chloroxylenol), totally 10 parts；0.4 part of essence.
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 1 are identical.
Embodiment 5：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(20 parts of fatty alcohol polyoxyethylene ether)；Anion surfactant (27.5 parts of AEO carboxylic acid sodium)；Alcohol 2
Part；Liquid detergent enzyme (.6 parts of proteinase-10,0.5 part of lipase, 0.3 part of mannase, 0.4 part of cellulase, lysozyme 0.4
Part), totally 2.2 parts；Alkylol ether surfactant (alkylol ether surfactant609 35.1 parts)；Poly- pair
0.8 part of ethylene terephthalate (SRN100)；Anti redeposition agent (2 parts of Tao Shi ACUSOLTM845)；Fungicide (dodecyl
8 parts of dimethyl benzyl ammonium chloride, to 2 parts of chloroxylenol), totally 10 parts；0.4 part of essence.
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 1 are identical.
Embodiment 6：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(12 parts of nonylphenol polyoxyethylene ether, 13 parts of fatty alcohol polyoxyethylene ether), totally 25 parts；Anion surfactant (dodecyl
15 parts of benzene sulfonic acid, 6.2 parts of AEO carboxylic acid sodium), totally 21.2 parts；1.5 parts of alcohol；Liquid detergent enzyme (proteinase-10 .5
Part, 0.3 part of lipase, 0.2 part of amylase, 0.2 part of bromelain, 0.3 part of lysozyme), totally 1.5 parts；It lives on alkylol ethers surface
Property agent (alkylol ether surfactant609 38 parts)；0.7 part of polyethylene terephthalate (SRN100)；
Anti redeposition agent (1.8 parts of Tao Shi ACUSOLTM845)；Fungicide (5 parts of dodecyl benzyl dimethyl ammonium chloride, poly- six methylene
4 parts of base biguanides, 1 part of triclosan), totally 10 parts；0.5 part of essence.
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 1 are identical.
Embodiment 7：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(15 parts of fatty alcohol polyoxyethylene ether, 5 parts of cocoanut fatty acid diethanolamide), totally 20 parts；Anion surfactant (fat
5 parts of alcohol polyethenoxy ether sodium sulfate, 15 parts of AEO carboxylic acid sodium, 1.2 parts of ethoxylated fatty acid sulfonate),
Totally 21.2 parts；2 parts of alcohol；Liquid detergent enzyme is (.4 parts of proteinase-10,0.1 part of lipase, 0.7 part of amylase, 0.2 part of bromelain, sweet
Reveal 0.2 part of dextranase, 0.2 part of cellulase, 0.4 part of lysozyme), totally 2.2 parts；Alkylol ether surfactant (alkylol
Ether surfactant609 42 parts).
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent includes the following steps：
Step 1：Formula according to above-mentioned anhydrous liquid detergent weighs each component, spare.
Step 2：Nonionic surfactant, anion surfactant and alcohol are put into ingredients pot, and is stirred
To being completely dissolved.
Step 3：It puts into the alkylol ether surfactant into the ingredients pot, and stirs to being completely dissolved.
Step 4：Liquid detergent enzyme is put into ingredients pot, and is stirred to being completely dissolved, obtains anhydrous laundry liquid product.
Embodiment 8：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
Totally 25 parts of (5 parts of nonylphenol polyoxyethylene ether, 8 parts of octyl phenol polyoxyethylene ether, 12 parts of fatty alcohol polyoxyethylene ether)；Anion table
Face activating agent (5 parts of dodecyl benzene sulfonic acid, 4 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, AEO carboxylic acid sodium 13
Part, 5.5 parts of diisooctyl Disodium sulfosuccinate), totally 27.5 parts；1.5 parts of alcohol；Liquid detergent enzyme (.1 parts of proteinase-10, fat
0.05 part of enzyme, 0.03 part of amylase, 0.02 part of mannase, 0.1 part of cellulase, 0.1 part of lysozyme), totally 0.4 part；Alkane
Base alcohol ether surfactants (alkylol ether surfactant609 35.1 parts).
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 7 is identical.
Embodiment 9：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(13 parts of fatty alcohol polyoxyethylene ether, 2 parts of cocoanut fatty acid diethanolamide, 3 parts of sucrose fatty ester), totally 18 parts；The moon from
Sub- surfactant (18 parts of AEO carboxylic acid sodium, 2 parts of ethoxylated fatty acid sulfonate, sodium secondary alkyl sulfonate 2
Part), totally 22 parts；2.5 parts of alcohol；Liquid detergent enzyme (.1 parts of proteinase-10,0.2 part of lipase, 0.1 part of amylase, mannase
0.2 part, 0.2 part of cellulase, 0.3 part of lysozyme), totally 1.1 parts；Alkylol ether surfactant (alkylol ethers surface
Activating agent609 40 parts).
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 7 is identical.
Embodiment 10：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(18 parts of fatty alcohol polyoxyethylene ether, 2 parts of sucrose fatty ester), totally 20 parts；Anion surfactant (aliphatic alcohol polyethenoxy
20 parts of ether carboxylic acid sodium, 1.2 parts of ethoxylated fatty acid sulfonate), totally 21.2 parts；1.5 parts of alcohol；Liquid detergent enzyme (proteinase-10 .6
Part, 0.5 part of lipase, 0.3 part of amylase, 0.3 part of mannase, 0.5 part of lysozyme), totally 2.2 parts；Alkylol ethers table
Face activating agent (alkylol ether surfactant609 42 parts).
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 7 is identical.
Embodiment 11：
A kind of formula of anhydrous liquid detergent is as follows：It counts in parts by weight, including following component：Nonionic surfactant
(2 parts of nonylphenol polyoxyethylene ether, 3 parts of octyl phenol polyoxyethylene ether, 13 parts of fatty alcohol polyoxyethylene ether, coco-nut oil fatty acid two
2 parts of glycollic amide), totally 20 parts；Anion surfactant (1.2 parts of dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether sulfuric acid
8 parts of sodium, 12 parts of AEO carboxylic acid sodium), totally 21.2 parts；1.5 parts of alcohol；Liquid detergent enzyme (.5 parts of proteinase-10, fat
0.3 part of fat enzyme, 0.2 part of amylase, 0.1 part of bromelain, 0.2 part of mannase, 0.1 part of cellulase, 0.7 part of lysozyme),
Totally 2.2 parts；Alkylol ether surfactant (alkylol ether surfactant609 42 parts)；Poly- terephthaldehyde
Sour 0.5 part of glycol ester (SRN100)；Anti redeposition agent (ACUSOLTM8452.2 parts of Tao Shi)；Fungicide (dimethyl
5 parts of base benzyl ammonium chloride, to 1 part of chloroxylenol, 3 parts of tasteless L antiseptics, 1 part of didecyl Dimethy ammonium chloride), totally 10
Part；0.4 part of essence.
In an embodiment of the present invention, the preparation method of anhydrous liquid detergent and embodiment 1 are identical.
It should be noted that in an embodiment of the present invention, liquid detergent enzyme is protease, lipase, amylase, pineapple
At least five kinds of mixture in enzyme, mannonase cellulase or lysozyme.For convenience of description, above-described embodiment
Several preferred combinations therein are illustrated only, in practical applications, can arbitrarily choose five kinds, six kinds or seven kinds objects therein
Matter is compounded, and forms complex enzyme, it is only necessary to and keeping the substance, shared parts by weight are 0.4~2.2 part in formula,
One of the various combinations are not just enumerated herein.
Based on it is above-mentioned identical the reasons why, the present embodiments relate to nonionic surfactant be Nonyl pheno
In ether, octyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide or sucrose fatty ester
It is a kind of or at least two mixture；Anion surfactant is dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether
Sodium sulphate, AEO carboxylic acid sodium, ethoxylated fatty acid sulfonate, diisooctyl Disodium sulfosuccinate or
A kind of in sodium secondary alkyl sulfonate or at least two mixture；Fungicide is dodecyl benzyl dimethyl ammonium chloride, right
In chloroxylenol, poly hexamethylene biguanide, tasteless L antiseptics, triclosan or didecyl Dimethy ammonium chloride at least
Two kinds of mixture.The various combinations of these above-mentioned components are not also enumerated herein one by one.
The performance for the anhydrous liquid detergent that embodiment provides in order to further illustrate the present invention, it is further below by way of test example
Illustrate the advantageous effect of anhydrous liquid detergent provided in an embodiment of the present invention：
Experiment one：Active matter content is tested
1st, test specimen：Anhydrous laundry liquid product provided in an embodiment of the present invention and reference product (blue moon machine-wash to
Honor liquid detergent and Kai meter three times wash king's neutral laundry liquid).
2nd, test method：With reference to the regulation of 5.3.1 methods one in QB1994-1994 " ethyl alcohol extraction ".
3rd, result of the test：Refer to the following table 1.
Table 1
| Test specimen | Implement 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Gross activity substance (%) | 91.8 | 91.1 | 91.9 | 90.2 | 90.6 | 89.2 |
| Test specimen | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Blue moon |
| Gross activity substance (%) | 83.2 | 87.6 | 83.2 | 80 | 88.2 | 47 |
| Test specimen | Open rice | / | / | / | / | / |
| Gross activity substance (%) | 40 | / | / | / | / | / |
Wash the regulation of agent standard by liquid according to QBT1224-2012 dress materials, it is desirable that for total in concentrated type liquid detergent
Active matter content should be greater than or equal to 25%.The height of gross activity object content is a weight for weighing liquid detergent quality good or not
Index is wanted, it is, in general, that the detergent that gross activity object content is high, the content of surfactant therein is also higher, dirt-removing power
By force, quality is relatively preferable.From the result of the test of upper table 1 it is found that the gross activity object of anhydrous liquid detergent provided in an embodiment of the present invention
More than 80%, the significantly larger than regulation and contrast product of standard.
In practical application, since the activity substance content of anhydrous liquid detergent provided in an embodiment of the present invention is high, pressing
The one drop product can wash 3~5 clothings, and be not easy in cleaning process the presence of cleaning agent residual.
Experiment two：Fluorescent whitening agent limitation test
1st, test specimen：Anhydrous laundry liquid product provided in an embodiment of the present invention and reference product (blue moon machine-wash to
Honor liquid detergent and Kai meter three times wash king's neutral laundry liquid).
2nd, test method：With reference to the limitation test method of GB9985-2000 appendix C fluorescent whitening agents.
3rd, result of the test：The following table 2 is referred to, wherein, expression is not detected less than detection limit.
Table 2
| Test specimen | Implement 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Gross activity substance (%) | It does not detect | It does not detect | It does not detect | It does not detect | It does not detect | It does not detect |
| Test specimen | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Blue moon |
| Gross activity substance (%) | It does not detect | It does not detect | It does not detect | It does not detect | It does not detect | Detection |
| Test specimen | Open rice | / | / | / | / | / |
| Gross activity substance (%) | It does not detect | / | / | / | / | / |
Fluorescent whitening agent, that is, stilbene biphenyl sodium disulfonate is a kind of fluorescent dye or for white dye and one
The complicated organic compound of kind, its characteristic are that incident ray can be excited to generate fluorescence, and contaminated substance is made to obtain similar fluorite
Sparkling effect makes the substance that naked eyes are seen very white.The fluorescent whitening agent that is added in liquid detergent, with clothing in itself
Yellow light is superimposed, sends out white light, reaches soft whitening effect.
It is found that anhydrous liquid detergent provided in an embodiment of the present invention does not detect fluorescent brightening from the result of the test of upper table 2
Agent, but make the whitening effect of the complex role promotion clothing using liquid detergent enzyme, it is more environmentally protective.
Experiment three：Enzyme activity stability test
1st, test specimen：Anhydrous laundry liquid product provided in an embodiment of the present invention.
2nd, test method：The anhydrous laundry liquid product that the embodiment of the present invention 1~11 is provided number 1~11 respectively, so
The test products that these have been numbered are placed under the conditions of room temperature (20 DEG C~30 DEG C) afterwards and are stored, and test is primary each at quarterly intervals
The enzyme activity of test products calculates and records corresponding enzyme activity, completes experiment within 12 months.
It is the enzyme activity test philosophy and method of various enzymes below：
(1) lipase activity power is tested：With reference to the detection method of GB/T 23535-2009 lipase preparations.
(2) the enzyme activity test of cellulase：With reference to QB 2583-2003 cellulase preparation detection methods.
(3) the enzyme activity test of lysozyme：Light is divided with reference to the measure of lysozyme in GB/T 25879-2010 egg whites
Photometry.
(4) the enzyme activity detection (referring to international standard) of mannase：Under conditions of 37 DEG C, pH value are 5.5, every point
Clock is degraded from mannosan (Sigma G0753) solution of a concentration of 3mg/mL discharges 1 μm of required enzyme amount of ol reduced sugars
For an enzyme activity unit U.
Mannosan can be degraded into oligosaccharides and monosaccharide by mannase.Oligosaccharides with reducing end under neutral and there is also former base
Under the conditions of boiling water bath with DNS reagents chromogenic reaction can occur for the monosaccharide of group.The intensity of reaction solution color is generated with enzymolysis
It is directly proportional to restore sugar amount, and the production quantity of reduced sugar is directly proportional to the vigor of mannase in reaction solution.
(5) the enzyme activity test of protease：With reference to GB/T 23527-2009 protease preparation detection methods.
(6) the enzyme activity test of amylase：With reference to GB/T 8275-2009 food additives alpha Amylase preparations detection side
Method.
(7) the enzyme activity test of bromelain：Bromelain can caseinhydrolysate, the tyrosine tool containing phenolic group in product
There is reproducibility, under alkaline condition, the Folin reagent of yellow can be made to restore the compound of au bleu, the depth and the junket ammonia of blue
The concentration of acid is directly proportional, and the production quantity of tyrosine can be measured by colorimetric method, its enzyme activity is represented with the production quantity of tyrosine.
3rd, result of the test refers to the following table 3, wherein, enzyme activity=(enzyme activity × 100%)/initial enzyme activity.
Table 3
As can be seen that anhydrous laundry liquid product provided in an embodiment of the present invention is in room temperature (20 from the result of the test of upper table 3
DEG C~30 DEG C) under the conditions of store 6 months, 12 months after, the enzyme activity of the various enzymes in formula is positively retained at more than 99%, institute
It can maintain the stability of various enzymes well with the formula system of anhydrous liquid detergent provided in an embodiment of the present invention, make its performance
Best washing functions.
Experiment four：Clean effect is tested
(1) clean effect contrast test
1st, test specimen：Anhydrous laundry liquid product provided in an embodiment of the present invention, standard liquid detergent and contrast product are (blue
The moon machine-washes most distinguished liquid detergent and Kai meter three times wash king's neutral laundry liquid).
2nd, test principle and method：GB/T 13174-2008 dress materials detergent detergency and the survey for recycling scourability
Determine method and QB/T 1224-2012 dress materials wash agent by liquid.
3rd, result of the test：Refer to the following table 4.Wherein, detergency experimental concentration is 0.1%, standard liquid detergent experimental concentration is
0.2%；JB-01 --- carbon black greasy dirt cloth；JB-02 --- albumen soiled cotton；JB-03 --- sebum soiled cotton.Collar detergency country
Standard parameter index request is as follows：Tri- kinds of experiment soiled cottons of JB-01, JB-02, JB-03 are all higher than or equal to standard liquid detergent.
Table 4
Detergency is a most important index of product quality, and general dirt-removing power is higher, and the quality of product is better.From
The result of the test of upper table 4 is it is found that the detergency effect of anhydrous laundry liquid product provided in an embodiment of the present invention is good, wherein JB-01
Soiled cotton detergency is up to 8.06%~10.50；JB-02 soiled cottons detergency is up to 7.71%~10.91%；JB-03 soiled cotton detergencies reach
8.28%~13.65%, it is above contrast product and standard liquid detergent.Therefore, anhydrous liquid detergent provided in an embodiment of the present invention
In a variety of complex enzymes and surfactant there is synergistic effect, the spot in clothing can be effectively removed, in equal item
Under part, clean effect is very good.
(2) clean effect endurance life test
1st, test specimen：Anhydrous laundry liquid product provided in an embodiment of the present invention, standard liquid detergent and contrast product
(blue moon machine-washes most distinguished liquid detergent and Kai meter three times wash king's neutral laundry liquid).
2nd, test method：Above-mentioned test products are placed under the conditions of room temperature (20 DEG C~30 DEG C) and are stored, were taken out every 6 months
Sample, and detergency measure of merit is carried out using the test method of above-mentioned experiment (one) and is recorded, off-test after 12 months.
3rd, result of the test：Refer to the following table 5, table 6 and table 7.
5 detergency comparison result of table (initial storage)
6 detergency comparison result of table (after storage 6 months)
7 detergency comparison result of table (after storage 12 months)
From the result of the test of upper table 5,6,7 it is found that anhydrous liquid detergent provided in an embodiment of the present invention at ambient temperature
After placing 6 months, 12 months, decontamination force value (JB-01, JB-02, JB-03) amplitude of variation is little, the persistence of clean effect
Good, therefore, anhydrous liquid detergent provided in an embodiment of the present invention builds decontamination system using a variety of complex enzymes and surfactant, no
But clean effect is good, and clean effect influenced by the resting period it is small.
Experiment five：Antiredeposition performance test
1st, test specimen：Anhydrous laundry liquid product standard liquid detergent and contrast product (Lan Yue provided in an embodiment of the present invention
Bright machine washing most distinguished liquid detergent and Kai meter three times wash king's neutral laundry liquid).
Cotton fabric and polyester textile (white fabrics)；Human society soil greasy dirt mixing soiling solution：+ 20% standard of 75% deionized water is red
+ 5% Oil stain mixture of dust (75% commercially available+No. 25%26 mineral oil of ready-mixed oil).
2nd, test method：Prepare 14 washing tanks, and number 1~14, weigh 10g human society soil greasy dirt mixing soiling solutions respectively
(being accurate to 0.01g) is put into washing tank, and the embodiment of the present invention 1~11 for adding in equivalent toward 1~No. 14 washing tank respectively provides
Anhydrous liquid detergent (2g/L), i.e. No. 1 washing tank adds in the anhydrous liquid detergent that the embodiment of the present invention 1 provides, and No. 2 washing tanks add in
The anhydrous liquid detergent ... that the embodiment of the present invention 2 provides and so on, No. 11 washing tanks add in what the embodiment of the present invention 11 provided
Anhydrous liquid detergent；No. 12 washing tanks add in standard liquid detergent (2g/L)；No. 13 washing tanks add in blue moons and machine-wash most distinguished liquid detergent
(2g/L)；No. 14 washing tank additions open a meter three times and wash king's neutral laundry liquid (2g/L).Respectively 1000mL is added in toward each washing tank
Hard water, be packed into spotter, stir evenly, and under stirring, respectively into washing tank add in 7cm × 7cm cotton fabric and
Each 3 of polyester textile, then washs 20min under conditions of 30 DEG C, 20min, 120r/min, after washing, takes out washing
Test fabric in cylinder after clear water rinsed clean, is placed on hang airing at room temperature, visually observes and soil layer is deposited in test fabric
Amount, and evaluated by the way of " ★ " quantity, " ★ " quantity is more, and it is weaker to represent antiredeposition performance.
3rd, result of the test：Refer to the following table 8.
Table 8
In washing process, the spot washed away on clothing is also possible to redeposited on clothing, these are remained can
It can cause clothing jaundice, wear.Antiredeposition is an important indicator for reflecting detergent performance.From the experiment knot of upper table 8
It can be seen that the blue moon that compares in fruit, open two contrast product of rice and standard liquid detergent, the embodiment of the present invention 1~11 provides
Anhydrous liquid detergent there is more preferably antiredeposition performance, be conducive to keep the pure and fresh cleaning of clothing.
Experiment six：Skin irritation is tested
1st, test specimen：Anhydrous laundry liquid product provided in an embodiment of the present invention.
2nd, test method：Randomly choosing 30 volunteers in a certain area, (for age level 18~55, health is non-
Constitution sensitive subjects) using the anhydrous liquid detergent of the present invention, daily using once, it is used continuously 3 months, observes and records will daily
Hope person use anhydrous liquid detergent hand wash laundry after skin irritation react (skin irritation reaction refers to during experiment, by
There is redness, itch, decortication symptom using the partial skin (such as hand skin) of this product in the contact of examination person.) and it is tested
After person's wearing has used the clothing of anhydrous liquid detergent cleaning of the present invention, the irritative response of skin.
3rd, result of the test：Using excitement percentage value come the effect of evaluation test, wherein excitement index percent value is got over
Greatly, illustrate that the product is big to the irritation of skin；Excitement percent value is smaller, illustrates that the product gets over the irritation of skin
It is small；Specific test result refers to the following table 9.
9 use feeling of table (irritation) evaluation result
As can be seen that in actual use, subject is using the embodiment of the present invention from the result of the test of upper table 9
During the anhydrous liquid detergent provided, the allergic stimulated of skin is 0, while dress the clothing after being cleaned using this product to skin
It is still non-stimulated.Therefore, anhydrous liquid detergent provided in an embodiment of the present invention is mildly non-stimulated to skin, safe.
The anhydrous liquid detergent of the present invention is hyperconcetration formula, is stablized in formula using the vigor of a variety of complex enzymes and complex enzyme
Property it is high, under the synergistic effect of complex enzyme and surfactant, can fast and effeciently remove the various stains in clothing, wash
It is good to wash effect；In addition, formula is neutral low foam formulations, it is easy to rinsing and noresidue, and mildly non-stimulated to skin, while do not damage
Hinder clothing.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
All any modification, equivalent and improvement made within refreshing and principle etc., should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of anhydrous liquid detergent, which is characterized in that include the component of following parts by weight：
Nonionic surfactant：18~25 parts；
Anion surfactant：21.2~27.5 parts；
Alkylol ether surfactant：35.1~42 parts；
Alcohol：1.5~2.5 parts；
Liquid detergent enzyme：0.4~2.2 part.
2. anhydrous liquid detergent as described in claim 1, which is characterized in that the liquid detergent enzyme is protease, lipase, starch
At least five kinds of mixture in enzyme, bromelain, mannonase cellulase or lysozyme.
3. anhydrous liquid detergent as claimed in claim 2, which is characterized in that the liquid detergent enzyme is protease, lipase, fiber
The mixture of plain enzyme, mannase and lysozyme.
4. anhydrous liquid detergent as described in claim 1, which is characterized in that include the component of following parts by weight：
Nonionic surfactant：20 parts；
Anion surfactant：21.2 parts；
Alkylol ether surfactant：42 parts；
Alcohol：1.5 part；
Liquid detergent enzyme：2.2 part.
5. anhydrous liquid detergent as described in claim 1, which is characterized in that include the component of following parts by weight：
Nonionic surfactant：18~25 parts；
Anion surfactant：21.2~27.5 parts；
Alcohol：1.5~2.5 parts；
Liquid detergent enzyme：0.4~2.2 part；
Alkylol ether surfactant：35.1~42 parts；
Polyethylene terephthalate：0.5~0.8 part；
Anti redeposition agent：1.5~2.2 parts；
Fungicide：8~10 parts；
Essence：0.3~0.6 part.
6. anhydrous liquid detergent as claimed in claim 5, which is characterized in that include the component of following parts by weight：
Nonionic surfactant：20 parts；
Anion surfactant：21.2 parts；
Alcohol：1.5 part；
Liquid detergent enzyme：2.2 part；
Alkylol ether surfactant：42 parts；
Polyethylene terephthalate：0.5 part；
Anti redeposition agent：2.2 part；
Fungicide：10 parts；
Essence：0.4 part.
7. anhydrous liquid detergent as described in claim 1, which is characterized in that the nonionic surfactant is polyoxyethylene nonyl phenyl
Vinethene, octyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide or sucrose-fatty
A kind of in ester or at least two mixture；
The anion surfactant is dodecyl benzene sulfonic acid, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxy second
One in alkene ether carboxylic acid sodium, ethoxylated fatty acid sulfonate, diisooctyl Disodium sulfosuccinate or sodium secondary alkyl sulfonate
Kind or at least two mixture.
8. anhydrous liquid detergent as claimed in claim 5, which is characterized in that the fungicide is dodecyl dimethyl benzyl chloride
Change ammonium, in chloroxylenol, poly hexamethylene biguanide, tasteless L antiseptics, triclosan or didecyl Dimethy ammonium chloride
At least two mixture.
9. anhydrous liquid detergent as claimed in claim 5, which is characterized in that the nonionic surfactant includes following weight
The substance of part：20 parts of fatty alcohol polyoxyethylene ether；
The anion surfactant includes the substance of following parts by weight：21.2 parts of AEO carboxylic acid sodium；
Alkylol ether surfactant：42 parts；
Polyethylene terephthalate：0.5 part；
Anti redeposition agent：2.2 part；
Alcohol：1.5 part；
The fungicide includes the substance of following parts by weight：7 parts of dodecyl benzyl dimethyl ammonium chloride and to chloroxylenol 3
Part；
The liquid detergent enzyme includes the substance of following parts by weight：It is .6 parts of proteinase-10,0.6 part of lipase, 0.3 part of cellulase, sweet
Reveal 0.4 part of 0.3 part of dextranase and lysozyme；And
Essence：0.4 part.
10. the preparation method of anhydrous liquid detergent as claimed in any one of claims 1 to 9 wherein, which is characterized in that including walking as follows
Suddenly：
Formula according to such as anhydrous liquid detergent of claim 1~9 any one of them weighs each component, spare；
The nonionic surfactant, anion surfactant and alcohol are put into ingredients pot, and is stirred to complete
Dissolving；
Alkylol ether surfactant is put into the ingredients pot, and is stirred to being completely dissolved；
The liquid detergent enzyme is put into the ingredients pot, and is stirred to being completely dissolved, obtains the anhydrous laundry liquid product.
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| EP3798289A1 (en) * | 2019-09-30 | 2021-03-31 | The Procter & Gamble Company | Fabric care compositions that include a copolymer and related methods |
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| CN114621829A (en) * | 2022-04-21 | 2022-06-14 | 浙江艾杰斯生物科技有限公司 | Bacteriostatic laundry detergent containing lysozyme |
| CN115449568A (en) * | 2022-09-16 | 2022-12-09 | 河南省科学院化学研究所有限公司 | Leather soaking agent and preparation method and application thereof |
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| EP3798289A1 (en) * | 2019-09-30 | 2021-03-31 | The Procter & Gamble Company | Fabric care compositions that include a copolymer and related methods |
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| CN115449568A (en) * | 2022-09-16 | 2022-12-09 | 河南省科学院化学研究所有限公司 | Leather soaking agent and preparation method and application thereof |
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