CN107287046A - Infantile clothes biology enzyme cleaning fluid and preparation method thereof - Google Patents
Infantile clothes biology enzyme cleaning fluid and preparation method thereof Download PDFInfo
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- CN107287046A CN107287046A CN201610202743.6A CN201610202743A CN107287046A CN 107287046 A CN107287046 A CN 107287046A CN 201610202743 A CN201610202743 A CN 201610202743A CN 107287046 A CN107287046 A CN 107287046A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3481—Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
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Abstract
The invention discloses a kind of infantile clothes biology enzyme cleaning fluid, by weight, it is made up of following composition：Nonionic surfactant 30 ~ 50%, chelating agent 0.1 ~ 0.3%, solubilizer 4.2 ~ 10.5%, preservative 0.3 ~ 0.7%, defoamer 1 ~ 3%, complex enzyme formulation 1 ~ 5%, surplus are deionized water.Using safe in the infantile clothes biology enzyme cleaning fluid of the present invention, degradable raw material, product is in neutral not injured skin and clothing, without essence pigment, sterilize antibacterial, complex enzyme formulation in component is played with nonionic surfactant to act synergistically, the protide on infantile clothes can not only quickly and efficiently be removed, fats, carbohydrate, sweat, the spots such as excreta, and milk taste or peculiar smell on infantile clothes can also be removed, easily floated after infantile clothes cleaning, chemical composition residual is few, the characteristics of being provided simultaneously with excellent cleaning performance and high security.
Description
Technical field
The present invention relates to cleaning fluid technical field, more particularly to a kind of biology enzyme cleaning of special cleaning infantile clothes
Liquid and preparation method thereof.
Background technology
Spot on infantile clothes is usually the dirts such as milk stain, all kinds of diatery supplement, saliva, the excreta of infant's everyday exposure
Stain, in terms of the cleaning of infantile clothes, because the skin of infant is very weak for the resistance of all kinds of chemical substances, so baby
The liquid detergent of child will be carefully chosen.Infant liquid laundry detergent is different from ordinary liquid laundry detergent, is tender and lovely fragile, easy for infant skin
The problems such as injured easily allergy and the special liquid detergent of baby researched and developed, its composition are more natural gentle, and excitant is small, can effectively clean
The clothing of infant and remained in without excessive harmful substance on clothing, so as to protect the skin health of infant, and common wash
Essence is generally added in clothing liquid, containing substantial amounts of chemical composition, pH is then unfavorable for guarantor in alkalescence for cleaning the clothing of infant
The skin health of infant is protected, and is difficult to effectively remove distinctive protide on infantile clothes, fats, carbohydrate spot
Deng, and truly remove the milk taste or peculiar smell on infantile clothes.Existing infant liquid laundry detergent can divide according to its function
For three classes：1st, degerming infant liquid laundry detergent：All kinds of bacteriums on clothing can be driven away；2nd, anti-mite infant liquid laundry detergent：Can not only
It is degerming to also have the effect for preventing that acarid from growing；3rd, hypo-allergenic infant liquid laundry detergent：May be to fractions in view of infant
Allergy and add special medical liquid detergent, allergic symptom, such as erythema, prickly heat can be prevented effectively from.But above-mentioned three classes infant
Liquid detergent function is excessively single, and because the country also lacks the national standard of infantile clothes tailored version liquid detergent, on the market
The usual fish mesh of product mixes, and consumer is difficult according to Brand and outward appearance, to judge and buy really suitable infant
Liquid detergent.Infant liquid laundry detergent is in order to ensure its skin-friendly, and raw material used is essentially all pure natural, and its acid-base value is also in
Neutrality, this will necessarily cause certain influence to its cleaning capacity.Traditional chemical formula is difficult the demand for taking into account each side, because
This, develop be provided simultaneously with excellent cleaning performance and safe infant liquid laundry detergent be this area researcher difficulty
Topic.
The content of the invention
The present invention solves the technical problem of a kind of infantile clothes biology enzyme cleaning fluid of offer and preparation method thereof,
Use safe, degradable raw material in the infantile clothes biology enzyme cleaning fluid, product in neutral not injured skin and
Clothing, without essence pigment, the complex enzyme formulation sterilized in antibacterial, component cooperates with work with nonionic surfactant performance
With, the spots such as protide, fats, carbohydrate, sweat, excreta on infantile clothes can not only be quickly and efficiently removed, and
And milk taste or peculiar smell on infantile clothes can also be removed, easily floated after infantile clothes cleaning, chemical composition residual is few, simultaneously
The characteristics of possessing excellent cleaning performance and high security.
In order to solve the above technical problems, one aspect of the present invention is：There is provided a kind of infantile clothes biological
Enzyme cleaning fluid, by weight, the infantile clothes biology enzyme cleaning fluid are made up of following component：
The % of nonionic surfactant 30% ~ 50；Chelating agent 0.1% ~ 0.3%；
Solubilizer 4.2% ~ 10.5%；Preservative 0.3% ~ 0.7%；
The % of defoamer 1% ~ 3；Complex enzyme formulation 1% ~ 5%；
Surplus is deionized water.
Preferably, the nonionic surfactant is by AEO, isomeric alcohol polyethenoxy ether, alkylol
Ether, alcohol ether glucoside, alkylol SYNPERONIC PE/F68 and Fatty alcohol polyoxyethylene polyoxypropylene ether composition.
It is highly preferred that the isomeric alcohol polyethenoxy ether is 13 carbon isomeric alcohol polyethenoxy ethers.
It is highly preferred that the alkyl alcohol ether is Aksu BEROL 609.
AEO（AEO）Ehter bond in molecule is difficult by acid, alkali destruction, so stability is higher, it is water-soluble
Property preferably, electrolyte-resistant, it is easy to biodegradable, foam is small.The compatibility of AEO and other surfaces activating agent
Good, cold washing performance is good, plays emulsification, foaming, decontamination.Meanwhile, AEO has excellent biological drop
Solution property and cryogenic property, are not influenceed by the water hardness.In embodiments of the invention, the AEO used is AEO7
（The polymerized unit number of oxygen vinethene is 7）.
Isomeric alcohol polyethenoxy ether has superpower permeability and emulsifying ability and excellent dirt-removing power, its great advantage
It is high surface and extremely low congealing point（Winter does not freeze）It is with anion, cation, nonionic surfactant and auxiliary agent
Compatibility is very good, and viscosity is low, is less prone to gelatin phenomenon, is applicable to highly enriched formula, with prominent stability.This
Outside, isomeric alcohol polyethenoxy ether and the compatibility of enzyme are very good, can keep and improve the infantile clothes life of the present invention well
The activity and stability of complex enzyme in thing enzyme cleaning fluid.In embodiments of the invention, the isomeric alcohol polyethenoxy ether used is ten
Three carbon isomeric alcohol polyethenoxy ethers（1309L）.
Alkyl alcohol ether has good permeability and emulsifying ability and excellent dirt-removing power, it is easy to biodegradable, environment friend
It is good.In embodiments of the invention, the alkyl alcohol ether used is Aksu BEROL 609.
Alcohol ether glucoside（AEG）It is nontoxic, non-stimulated, be readily biodegradable, with preserving moisture and protecting skin effect, can significantly reduce whole
The excitant of body formula, low-temperature water-soluble is good, and resistance to hard water has good thickening effect to formula system, can be with all kinds of work
Property thing compounding, chemical property is stable, to human body and Environmental security.
Alkylol SYNPERONIC PE/F68 and Fatty alcohol polyoxyethylene polyoxypropylene ether are that a kind of low alveolitoid is non-
Ionic surface active agent, it is adaptable to foam volume is as low as possible, quick humidification, be easy to rinsing and the good application environment of emulsifiability
In, with strong detergency, low pour point compatible with most of surfactants, inorganic assistant and chelating agent, low cloud point and it can be difficult
The characteristics of gel.In embodiments of the invention, the alkylol SYNPERONIC PE/F68 used is Skycore
HNS38, the Fatty alcohol polyoxyethylene polyoxypropylene ether used is NONIDET SF-5.
Above-mentioned nonionic surfactant source health and safety, are acted on cleaning, emulsification, infiltration, foaming etc., and energy
Help enzyme preparation quickly to reach the surface of spot, promote enzyme preparation to decompose spot, meanwhile, the nonionic surfactant can also
Enzyme preparation is decomposed to the product produced after spot quickly to remove.
Preferably, the complex enzyme formulation is made up of protease, lipase, amylase, mannase and lactase.Fat
Fat enzyme can effectively decompose vegetative grease and animal raw fat on infantile clothes etc..Amylase decomposable asymmetric choice net infant's clothing
Starch spot on thing, such as rice, noodles starch food products.Protease can effectively decompose the milk on infantile clothes
The protein stain of the food source such as juice, eggs, dairy products or gravy, vegetable juice.Mannase can effectively decompose infantile clothes
On mannanses spot, mannosan such as guar gum, konjac glucomannan etc., are the thickeners in food additives, in ice river in Henan Province
Generally used in pouring, mayonnaise, instant noodles.Lactase can effectively decompose the breast remained in the milk on infantile clothes
Sugar, removes milk taste.
Preferably, the solubilizer is made up of ethanol, sodium xylene sulfonate, glycerine and urea.The solubilizer can be carried
The solubility of each component in deionized water in the infantile clothes biology enzyme cleaning fluid of the high present invention.In addition, glycerine has guarantor
Wet function, and can as complex enzyme stabilizer, the enzyme activity of stable complex enzyme, while also having handguard to moisten the function of hand.
Preferably, the preservative is made up of sterilizing solution and triclosan.Sterilizing solution is broad spectrum type preservative of new generation, can be grown
Various bacteria, fungi are killed in effect ground, good with various emulsifying agents, surfactant and other composition compatibilities, can be with any ratio
The alcohol and water of example dissolves each other；Applicable pH scopes are wider compared with like product, and pH4.0 ~ 12.0 can be used；Stability is strong, effectively into
The tolerable 150 DEG C high temperature of part.Triclosan is a kind of broad spectrum antimicrobial agent, can be dissolved in a variety of organic solvents and surfactant, and
And to strong acid and strong base and heat have high stability, efficiently, safety, to no skin irritation, can decompose rapidly in the environment
Metabolism.The preservative makes the infantile clothes biology enzyme cleaning fluid of the present invention have the longer shelf-life.
Preferably, the defoamer is fatty acid potassium soap.Fatty acid potassium soap makees defoamer, with good defoaming effect,
The infantile clothes bio-enzyme cleaning agent of the present invention is set easily to be floated after cleaning infantile clothes, chemical composition residual is few.
Preferably, the chelating agent is disodium ethylene diamine tetraacetate.Disodium ethylene diamine tetraacetate can chelate calcium, magnesium in water
Ion；Calcium, magnesium ion especially in hard water, make calcium in water, magnesium ion will not Surfactant function produce it is unfavorable
Influence.
In order to solve the above technical problems, another technical solution used in the present invention is：A kind of infant's life is provided
The preparation method of thing enzyme cleaning fluid, comprises the following steps：
A, into ingredients pot add deionized water gross mass 60% ~ 70%；
B, input chelating agent, stirring is to being completely dissolved；
C, input nonionic surfactant, are heated to 50 DEG C ~ 60 DEG C, and stirring is to being completely dissolved；
D, the remaining deionized water of addition；
When temperature of charge is less than 40 DEG C in E, pot, input solubilizer and defoamer, stirring is to being completely dissolved；
F, input preservative, stirring is to being completely dissolved；
G, input complex enzyme formulation, stir, obtain the infantile clothes biology enzyme cleaning fluid.
The beneficial effects of the invention are as follows：It is different from that existing infant cleaning liquid function is single, traditional chemical formula is difficult to
Have a case that simultaneously in excellent cleaning performance and high security, infantile clothes biology enzyme cleaning fluid of the invention using safety
Property high, degradable raw material, product is in neutral not injured skin and clothing, without essence pigment, sterilizes in antibacterial, component
Complex enzyme formulation is played with nonionic surfactant and acted synergistically, and can not only quickly and efficiently remove the egg on infantile clothes
The spots such as white class, fats, carbohydrate, sweat, excreta, and milk taste or peculiar smell on infantile clothes, baby children can also be removed
Easily floated after youngster's clothes washing, chemical composition residual is few, the characteristics of being provided simultaneously with excellent cleaning performance and high security.
Embodiment
With reference to specific embodiment, the present invention is described further：
Embodiment 1
Infantile clothes biology enzyme cleaning formula of liquid is as follows：By weight, AEO（AEO7, oxygen vinethene
Polymerized unit number is 7）8%th, 13 carbon isomeric alcohol polyethenoxy ether（1309L）10%th, alkyl alcohol ether（Aksu BEROL 609）
2%th, alcohol ether glucoside 4%, alkylol SYNPERONIC PE/F68（Skycore HNS38）2%th, aliphatic alcohol polyethenoxy
Polyethenoxy ether（NONIDET SF-5）4%；Disodium ethylene diamine tetraacetate 0.1%, ethanol 1%, sodium xylene sulfonate 2%, glycerine
1%th, urea 0.2%, sterilizing solution 0.2%, triclosan 0.1%, the % of fatty acid potassium soap 1, protease 1.2%, lipase 1.2%, amylase
1%th, mannase 0.8%, lactase 0.8%, deionized water 59.4%.
The preparation method of infant's biology enzyme cleaning fluid：
Each component is weighed by above-mentioned formula, it is standby；Prepare according to the following steps：
A, into ingredients pot add deionized water gross mass 60% ~ 70%；
B, input chelating agent（Disodium ethylene diamine tetraacetate）, stirring is to being completely dissolved；
C, input nonionic surfactant（AEO, 13 carbon isomeric alcohol polyethenoxy ethers, alkyl alcohol ether,
Alcohol ether glucoside, alkylol SYNPERONIC PE/F68, Fatty alcohol polyoxyethylene polyoxypropylene ether）, be heated to 50 DEG C ~
60 DEG C, stirring is to being completely dissolved；
D, the remaining deionized water of addition；
When temperature of charge is less than 40 DEG C in E, pot, solubilizer is put into（Ethanol, sodium xylene sulfonate, glycerine, urea）And froth breaking
Agent（Fatty acid potassium soap）, stirring is to being completely dissolved；
F, input preservative（Sterilizing solution and triclosan）, stirring is to being completely dissolved；
G, input complex enzyme formulation（Protease, lipase, amylase, mannase and lactase）, stir, obtain institute
State infantile clothes biology enzyme cleaning fluid.
Embodiment 2
Infantile clothes biology enzyme cleaning formula of liquid is as follows：By weight, AEO（AEO7, oxygen vinethene
Polymerized unit number is 7）9%th, 13 carbon isomeric alcohol polyethenoxy ether（1309L）12%th, alkyl alcohol ether（Aksu BEROL 609）
3%th, alcohol ether glucoside 6%, alkylol SYNPERONIC PE/F68（Skycore HNS38）3.5%th, fatty alcohol polyoxy second
Alkene polyethenoxy ether（NONIDET SF-5）6%；Disodium ethylene diamine tetraacetate 0.2%, ethanol 2%, sodium xylene sulfonate 3%, the third three
Alcohol 2%, urea 0.35%, sterilizing solution 0.3%, triclosan 0.2%, fatty acid potassium soap 2%, proteinase-10 .8%, lipase 0.8%, starch
Enzyme 0.6%, mannase 0.4%, lactase 0.4%, deionized water 47.45%.The preparation of infantile clothes biology enzyme cleaning fluid
Method is same as Example 1.
Embodiment 3
Infantile clothes biology enzyme cleaning formula of liquid is as follows：By weight, AEO（AEO7, oxygen vinethene
Polymerized unit number is 7）10%th, 13 carbon isomeric alcohol polyethenoxy ether（1309L）14%th, alkyl alcohol ether（Aksu BEROL 609）
5%th, alcohol ether glucoside 8%, alkylol SYNPERONIC PE/F68（Skycore HNS38）5%th, aliphatic alcohol polyethenoxy
Polyethenoxy ether（NONIDET SF-5）8%；Disodium ethylene diamine tetraacetate 0.2%, ethanol 3%, sodium xylene sulfonate 4%, glycerine
3%th, urea 0.5%, sterilizing solution 0.4%, triclosan 0.3%, the % of fatty acid potassium soap 3, proteinase-10 .4%, lipase 0.2%, amylase
0.2%th, mannase 0.1%, lactase 0.1%, deionized water 34.6%.The preparation method of infantile clothes biology enzyme cleaning fluid
It is same as Example 1.
Embodiment 4
Infant liquid laundry detergent and standard liquid detergent that the performance of the infantile clothes biology enzyme cleaning fluid of the present invention has been sold with market
Performance comparision.
The infant cleaning liquid sold market is chosen to be respectively the special liquid detergent of blue moon baby, protect peaceful BB babies baby clothing
The close baby's multiple-effect liquid detergent of the special liquid detergent of thing, shellfish, Germany's NUK Infant laundry detergents, breathe out baby's draft liquid detergent.PH value is examined
Survey, gross activity analyte detection and detergency detection method are references：GB/T 13174-2008 dress material detergent detergencies and follow
The measure and QB/T 1224-2012 dress materials of ring scourability wash agent by liquid.
First, pH value is detected
Experimental method：Test temperature is 25 DEG C, and 1% sample solution concentration, testing result is shown in Table 1.
The pH value comparative result of table 1
| Liquid detergent | PH value |
| Standard liquid detergent | 7.8 |
| The special liquid detergent of blue moon baby | 7.7 |
| Protect the peaceful special liquid detergent of BB babies baby clothing | 7.1 |
| Shellfish parent's baby's multiple-effect liquid detergent | 7.3 |
| German NUK Infant laundry detergents | 7.3 |
| Breathe out baby's draft liquid detergent | 8.4 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 1 | 7.0 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 2 | 7.1 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 3 | 7.0 |
According to the regulation of national standard, it is desirable to which the pH value of the product for cleaning clothing should be less than or equal to 10.5.Reagent is molten
Liquid pH in neutrality, both will not damaging laundry, will not also damage the skin of human body；Reagent solution pH in alkalescence, both can damaging laundry,
Also the skin of human body can be damaged.As shown in Table 1, infant's biology enzyme cleaning fluid of the invention is gentle non-stimulated in neutrality, safety
Do not hinder clothing, do not hurt hands；Comparatively speaking, baby's draft liquid detergent pH value meta-alkalescence is breathed out, to the clothing and skin of infant
There is certain damage.
2nd, the detection of gross activity thing content
The comparative result of the gross activity thing content of table 2
| Liquid detergent | Gross activity thing content（%） |
| Standard liquid detergent | 16 |
| The special liquid detergent of blue moon baby | 19.7 |
| Protect the peaceful special liquid detergent of BB babies baby clothing | 14.0 |
| Shellfish parent's baby's multiple-effect liquid detergent | 26.2 |
| German NUK Infant laundry detergents | 17.7 |
| Breathe out baby's draft liquid detergent | 16.2 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 1 | 31.2 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 2 | 35.0 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 3 | 40.5 |
It is plain edition liquid detergent that gross activity thing content >=15% is provided in QB/T 1224-2012, and gross activity thing content >=25% is dense
Miniature liquid detergent, as shown in Table 2, the special liquid detergent of blue moon baby, the peaceful special liquid detergent of BB babies baby clothing of guarantor, Germany
NUK Infant laundry detergents are plain edition liquid detergent with baby's draft liquid detergent is breathed out, and shellfish parent's baby's multiple-effect liquid detergent is with the present invention's
Infantile clothes biology enzyme cleaning fluid is concentrated type liquid detergent.The height of gross activity thing content is to weigh liquid detergent Functionality, quality and appealing design
A bad important indicator, it is, in general, that the high detergent of gross activity thing content, the content of surfactant therein also compared with
Height, dirt-removing power is strong, and quality is relatively preferable；As shown in Table 2, the gross activity thing of infantile clothes biology enzyme cleaning fluid of the invention
Content highest, illustrates that the infantile clothes biology enzyme cleaning fluid dirt-removing power of the present invention is strong, quality is good.At the same time, high surface
But there is the drawbacks of difficulty is cleaned up, easily remained in activating agent, but in the infantile clothes biology enzyme cleaning fluid of the present invention it is non-from
Sub- Surfactant is all low foaming green surfactant, and has also been entered in formula after defoamer, therefore cleaning infantile clothes
Easily drift, chemical composition residual is few, safe.
3rd, detergency is detected
The decontamination force data measured is as shown in table 3：
The detergency comparative result of table 3
| Liquid detergent | Detergency（%）JB-01 | Detergency（%）JB-02 | Detergency（%）JB-03 |
| Standard liquid detergent | 4.1 | 0.9 | 3.1 |
| The special liquid detergent of blue moon baby | 5.4 | 9.3 | 5.9 |
| Protect the peaceful special liquid detergent of BB babies baby clothing | 4.7 | 1.4 | 5.5 |
| Shellfish parent's baby's multiple-effect liquid detergent | 4.1 | 2.3 | 4.0 |
| German NUK Infant laundry detergents | 5.1 | 1.6 | 5.9 |
| Breathe out baby's draft liquid detergent | 4.3 | 1.2 | 4.2 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 1 | 6.2 | 10.4 | 6.2 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 2 | 6.4 | 10.8 | 6.6 |
| The infantile clothes biology enzyme cleaning fluid of embodiment 3 | 7.0 | 11.1 | 7.2 |
Detergency experimental concentration：Plain edition liquid detergent（The special liquid detergent of blue moon baby, protect that peaceful BB babies baby clothing is special to be washed
Clothing liquid, Germany's NUK Infant laundry detergents and breathe out baby's draft liquid detergent）For 0.2%, concentrated type liquid detergent（Shellfish parent's baby's multiple-effect is washed
The infantile clothes biology enzyme cleaning fluid of clothing liquid and the present invention）For 0.1%；JB-01 --- carbon black greasy dirt cloth；JB-02 --- albumen
Soiled cotton；JB-03 --- sebum soiled cotton.Clothing detergency national standard parameter index requires as follows：JB-01, JB-02, JB-03 tri-
Experiment soiled cotton is planted to be all higher than or equal to standard liquid detergent.
Detergency is a most important index of product quality, as shown in Table 3, infantile clothes biology enzyme of the invention
Cleaning fluid is above the infant liquid laundry detergent that market has been sold to the detergency numerical value of tri- kinds of experiment soiled cottons of JB-01, JB-02, JB-03
And the detergency numerical value of standard liquid detergent, illustrating the infantile clothes biology enzyme cleaning fluid of the present invention has excellent cleaning effect
Really.
Although the embodiment of the present invention has obtained detailed description, it will be understood to those of skill in the art that root
According to disclosed all teachings, various modifications and replacement can be carried out to those details, these change the guarantor in the present invention
Within the scope of shield.The four corner of the present invention is provided by appended claims and its any equivalent.
Claims (10)
1. a kind of infantile clothes biology enzyme cleaning fluid, it is characterised in that by weight, the infantile clothes biology enzyme cleaning
Liquid is made up of following component：
The % of nonionic surfactant 30% ~ 50；Chelating agent 0.1% ~ 0.3%；
Solubilizer 4.2% ~ 10.5%；Preservative 0.3% ~ 0.7%；
The % of defoamer 1% ~ 3；Complex enzyme formulation 1% ~ 5%；
Surplus is deionized water.
2. infantile clothes biology enzyme cleaning fluid according to claim 1, it is characterised in that the non-ionic surface active
Agent is by AEO, isomeric alcohol polyethenoxy ether, alkyl alcohol ether, alcohol ether glucoside, alkylol oxirane epoxy
Propane copolymer and Fatty alcohol polyoxyethylene polyoxypropylene ether composition.
3. infantile clothes biology enzyme cleaning fluid according to claim 2, it is characterised in that the isomery alcohol polyoxyethylene
Ether is 13 carbon isomeric alcohol polyethenoxy ethers.
4. infantile clothes biology enzyme cleaning fluid according to claim 2, it is characterised in that the alkyl alcohol ether is Acker
Revive BEROL 609.
5. infantile clothes biology enzyme cleaning fluid according to claim 1, it is characterised in that the complex enzyme formulation is by egg
White enzyme, lipase, amylase, mannase and lactase composition.
6. infantile clothes biology enzyme cleaning fluid according to claim 1, it is characterised in that the solubilizer by ethanol,
Sodium xylene sulfonate, glycerine and urea composition.
7. infantile clothes biology enzyme cleaning fluid according to claim 1, it is characterised in that the preservative is by sterilizing solution
With triclosan composition.
8. infantile clothes biology enzyme cleaning fluid according to claim 1, it is characterised in that the defoamer is aliphatic acid
Potash soap.
9. infantile clothes biology enzyme cleaning fluid according to claim 1, it is characterised in that the chelating agent is ethylenediamine
Tetraacethyl disodium.
10. the preparation method of the infantile clothes biology enzyme cleaning fluid described in any one of claim 1 ~ 9, it is characterised in that bag
Include following steps：
A, into ingredients pot add deionized water gross mass 60% ~ 70%；
B, input chelating agent, stirring is to being completely dissolved；
C, input nonionic surfactant, are heated to 50 DEG C ~ 60 DEG C, and stirring is to being completely dissolved；
D, the remaining deionized water of addition；
When temperature of charge is less than 40 DEG C in E, pot, input solubilizer and defoamer, stirring is to being completely dissolved；
F, input preservative, stirring is to being completely dissolved；
G, input complex enzyme formulation, stir, obtain the infantile clothes biology enzyme cleaning fluid.
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| CN108192760A (en) * | 2018-01-17 | 2018-06-22 | 深圳市芭格美生物科技有限公司 | A kind of anhydrous liquid detergent and preparation method thereof |
| CN109762678A (en) * | 2019-03-21 | 2019-05-17 | 福建省纯杰绿色科技有限公司 | A kind of plant cleaning agent for animal origin cleaning |
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| CN109762678A (en) * | 2019-03-21 | 2019-05-17 | 福建省纯杰绿色科技有限公司 | A kind of plant cleaning agent for animal origin cleaning |
| CN109825377A (en) * | 2019-03-21 | 2019-05-31 | 福建省纯杰绿色科技有限公司 | A kind of plant cleaning agent using small molecule depth cleaning technique |
| CN109868191A (en) * | 2019-03-21 | 2019-06-11 | 福建省纯杰绿色科技有限公司 | A kind of plant cleaning agent for human secretion cleaning |
| CN110272783A (en) * | 2019-07-14 | 2019-09-24 | 衡阳市昌鑫化工有限公司 | A kind of multifuctional cleaning agent and preparation method thereof |
| CN110408481A (en) * | 2019-08-16 | 2019-11-05 | 浙江芬尼奇工贸有限公司 | A kind of clothing stain removal agent and its preparation process |
| CN110699190A (en) * | 2019-10-22 | 2020-01-17 | 山立欣业新材料(广东)有限公司 | Novel super-concentrated water-based cleaning agent for ground oil stains and preparation method thereof |
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| CN111893006B (en) * | 2020-07-15 | 2021-09-10 | 广州蓝月亮实业有限公司 | Detergent composition |
| CN112877150A (en) * | 2021-02-09 | 2021-06-01 | 浙江施维康生物医学材料有限公司 | Antibacterial and deodorant laundry detergent and preparation method thereof |
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