CN110272783A - A kind of multifuctional cleaning agent and preparation method thereof - Google Patents
A kind of multifuctional cleaning agent and preparation method thereof Download PDFInfo
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- CN110272783A CN110272783A CN201910632862.9A CN201910632862A CN110272783A CN 110272783 A CN110272783 A CN 110272783A CN 201910632862 A CN201910632862 A CN 201910632862A CN 110272783 A CN110272783 A CN 110272783A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/187—Hydrocarbons aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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Abstract
The present invention provides a kind of multifuctional cleaning agent, in terms of mass fraction, including following component: 6-9 parts of tripolyphosphate, 6-9 parts of sodium bicarbonate, 2-5 parts of vinegar, 4-5 parts of isomerous tridecanol, C12-18 branched fatty alcohol-β-glycol ether and 2-4 parts of propoxylate compound of C9-C11 fatty alcohol ethoxylate, ten 1-2 parts of carbon isomery carboxylate of dispersing agent dimethyl hydroxyethyl, 1-2 parts of glucoside, sugared sweet 3-5 parts of class compound with heptyl of polycarboxylic acid anhydride, pure and mild 3-6 parts of the ethoxylated propoxylated-C8-10- fatty alcohol compound of ethoxylation-C12-18-, 1-2 parts of aromatic hydrocarbons, 0.3-0.4 parts of lipase, 0.2-0.3 parts of cellulase, 0.3-0.4 parts of anti-corrosion raw material, 62.2-64.6 parts of water.The cleaning agent have decontamination, oil removing, derust, go it is cured and other effects, it is non-corrosive；Especially removal adhesive sticker has effect unique.
Description
Technical field
The invention belongs to chemical cleaning technique fields, and in particular to a kind of multifuctional cleaning agent and preparation method thereof.
Background technique
According to the principle of cleaning process and industrial application situation, cleaning technique can be greatly classified into three in the world today
Kind: chemical cleaning, physical cleaning, biology cleaning.Wherein at most, most species, application is most general for chemical cleaning technique history.
According to the water content of chemical cleaning Ji again can substantially organic cleaning solvent, aqueous cleaning agent and half it is water base clearly
Lotion three types.These three cleaning agents respectively have advantage and disadvantage, though some cleaning effects of organic cleaning solvent, there is certain poison
Property, and have pollution to environment and air；Although semi-aqueous cleaning agent cleaning effect is preferable, at high cost, raw material is taken in production
With not in place with technique, product layering is easily led to；Aqueous cleaning agent effect is obvious, but alkalinity is high, and use scope is limited to, and
Foam is more, is also easy to produce scale to metal material cleaning.Cleaning agent has alkalinity, acid, neutrality three categories in common people's meaning.Alkalinity
There is pungent taste with acidic cleaner, or even generates poison gas, not environmentally, and cleaning product object has significant limitation, therefore
It is nearly all the single scavenger specially of effect in the world today, without a kind of multifuctional cleaning agent truly.
Chinese patent CN201610438257.4 discloses a kind of street lamp cleaning agent and preparation method thereof, the street lamp cleaning agent
It is made of the component of following mass parts: 20-30 parts of sodium carbonate, 5-10 parts of sodium bicarbonate, 8-10 parts of acetone, 15-20 parts of acetic acid, boron
It is 5-8 parts sour, 10-15 parts of polyethylene frosted particle, 5-8 parts of chemical industry thickener, 8-10 parts of sodium citrate, 1-3 parts of sodium soap, sulphur
Sour copper 0.1-0.3 parts, 40-50 parts of water, the polyethylene frosted particle is 100-200 mesh, and the water is deionized water, institute
The chemical industry thickener stated is the mixture of Sodium Polyacrylate and polyvinyl alcohol.The street lamp cleaning agent can quickly and efficiently remove road
The stain on lamp surface is not needed only to be needed using brush using soft cotton or sponge, the poly- second contained in detergent
Alkene frosted particle can carry out soft polishing to lacquer painting, and either dust or organic matter, which can be removed, does not stay completely extremely
Angle, while the cleaning agent does not contain strong acid and strong base, is contacted not with lacquer painting and will cause lacquer painting discoloration.
Though the prior art, which has sodium bicarbonate to be used together with vinegar, prepares neutral cleaners, only match by both leading raw materials
Upper anion and nonionic isoreactivity agent are difficult to remove heavy oil dirt, in addition can just promote the energy after sodium tripolyphosphate
Power.Sodium bicarbonate category alkalescent is used together also with vinegar can only remove lighter greasy dirt, in addition sodium tripolyphosphate can increase alkalinity, mention
The ability gone compared with heavy oil stain is risen, while it being made to reach neutral products, here it is one of innovative points；Two, the application select table
Face activating agent is all the new product of manufacturer, environmentally protective, and respectively has each function, is many original surfactants
It is irreplaceable.Three, in order to which product neutrality purposes is wider, environment protection multifunctional in addition, the application formula is more scientific, but also uses
Biological enzyme and aromatic hydrocarbons such as propose at the technologies, all enhance innovative point, and solve neutral cleaners, high-cost industry is difficult
Topic.Four the application formulas in also added cationic synergist, greatly improve the ability of duplicate removal greasy dirt, in addition raw material
Secondary high-speed stirred, it is ensured that the uniformity of feed distribution has prevented this all innovative point of the layering of product.
Between the neutral multifunctional cleaning agent pH value 7-8 of the application production, the advantages of sufficiently combining three classes cleaning agent, return
Its shortcoming and defect is kept away, is set about from formula and technique, according to the basic principle of Green Chemistry, selects nontoxic, harmless raw material,
The multifuctional cleaning agent made of the organic complex of one nonionic surfactant of anion.Degreasing power is by force and after use
It can biodegrade.Good cleaning effect can be realized to the object of different types of oil foulant and unlike material.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art to provide a kind of multifuctional cleaning agent and preparation method thereof, should
Cleaning agent selects nontoxic, harmless raw material, and degreasing power by force and after use can biodegrade.
Multifuctional cleaning agent of the present invention is in terms of mass fraction, including following component:
Tripolyphosphate (Na5P3O10) 6-9 parts, sodium bicarbonate (NaHC03) 6-9 parts, 2-5 parts of vinegar, 4-5 parts of isomerous tridecanol, C12-
18 branched fatty alcohol-β-glycol ether and 2-4 parts of propoxylate compound of C9-C11 fatty alcohol ethoxylate, dispersing agent first
Ten 1-2 parts of carbon isomery carboxylate of base ethoxy, 1-2 parts of glucoside APG, polycarboxylic acid anhydride and the sweet class compound PH-E of heptyl sugar
3-5 parts, pure and mild 3-6 parts of the ethoxylated propoxylated-C8-10- fatty alcohol compound of ethoxylation-C12-18-, 1-2 parts of aromatic hydrocarbons,
0.3-0.4 parts of lipase, 0.2-0.3 parts of cellulase, 0.3-0.4 parts of anti-corrosion raw material, 62.2-64.6 parts of water.
0.1-0.3 parts of essence, preferably lemon extract can also be added in cleaning agent of the present invention.
Wherein the vinegar is edible white vinegar, quality of acetic acid content 3-5%.
Wherein the C12-18 branched fatty alcohol-β-glycol ether and C9-C11 fatty alcohol ethoxylate propoxylate
The mass ratio of C12-18 branched fatty alcohol-β-glycol ether and C9-C11 fatty alcohol ethoxylate propoxylate in compound
For 1:(2-4).
Wherein ethyoxyl in the pure and mild ethoxylated propoxylated-C8-10- fatty alcohol compound of the ethoxylation-C12-18-
The mass ratio of the pure and mild ethoxylated propoxylated-C8-10- fatty alcohol of change-C12-18- is 1:(2-5).
Wherein the isomerous tridecanol is the nonionic surfactant HF302B of Shenzhen Jiu Ning Science and Technology Ltd. production,
Ten carbon isomery carboxylate of dimethyl hydroxyethyl is the nonionic surfactant DS30 of Shenzhen Jiu Ning Science and Technology Ltd. production；
Wherein the polycarboxylic acid anhydride and the sweet class compound of heptyl sugar are the anionic surfaces of Shenzhen Rong Qiang Science and Technology Ltd. production
Activating agent.
The wherein aromatic hydrocarbons preferred aromatic hydrocarbons 6, the aromatic hydrocarbons and heteroside are the production of Guangzhou Gong Qing Chemical Co., Ltd..
Wherein the different thiophene raw material of methyl of the anti-corrosion raw material preferred Jinan De Lan company production (is also methylisothiozoline
Ketone).
Multifuctional cleaning agent of the present invention the preparation method is as follows:
(1) first by water and sodium tripolyphosphate Na5P3O10, sodium bicarbonate(edible) NaHCO3And vinegar puts into the pill tank that can be heated and stirs
It mixes, hot 80-90 DEG C of temperature tune of pill tank is allowed to raw material and sufficiently dissolves, and stirs evenly；Using upper and lower double mixing-blades mixer, turn
Velocity modulation is to 80-100 revs/min, and electricity heating is closed after stirring 5-9 minutes；
(2) then by the C12-18 branched fatty alcohol-β-glycol ether compounded and C9-C11 fatty alcohol ethoxylate propoxyl group
In compound compound and ten carbon isomery carboxylate of HF302B isomerous tridecanol and DS30 dimethyl hydroxyethyl investment pill tank, stirring
Machine revolving speed is adjusted to 120-140 revs/min of stirring 10-15 minutes；
(3) by the pure and mild ethoxylated propoxylated-C8-10- fatty alcohol compound of the ethoxylation-C12-18- of decontamination, lipase
(Lipase) it in cellulase (cellalase) raw material input cylinder, stirs 5-10 minutes；
(4) the raw material investment that dispersing agent PH-E polycarboxylic acid anhydride is compounded with the sweet class compound of heptyl sugar and glucose sweet (APG) is matched
In material cylinder, stir 5-10 minutes；
(5) aromatic hydrocarbons and anti-corrosion raw material are put into again and revolving speed is adjusted to 180-230 revs/min, stir 15-20 minutes to get finished product.
It finally puts into pill tank and stirs 5 minutes when needing to be added essence.
Cleaning agent of the present invention is nontoxic, and environmentally protective route is surrounded on material matching, makees by the performance for choosing raw material
With taking double raw material compounded technologies, and after every component raw material is by component compounding stirring, then the technique stream of comprehensive secondary agitation
Journey, it is ensured that raw material effect plays, and sequentially successively launches when feeding intake.
Of the invention mainly has the beneficial effect that:
(1) formula is filtered out using experiment of single factor, the optimum proportioning of multifuctional cleaning agent has been determined using orthogonal test, passed through
The theoretical calculation of screening repeatedly and HLB value has been carried out to more than 60 single and compounding surfactants and experiment is tested
Card finds the surfactant compounds such as non-ionic, anionic, and decontamination value significantly improves, there are also oil removing, derust, go it is cured
And other effects, it is almost non-corrosive.
(2) one nonionic of anion based on surfactant and APG and cationic surfactant is organic multiple
Match, not only between other components, there is fabulous compatibility, moreover it is possible to effectively improve the degreasing rate of nonionic surfactant.
(3) it using a variety of double raw materials and more raw material compounded technologies and prescription compatibility, deoils, strong detergency, moreover it is possible to improve film
The uniformity and corrosion resisting property, and improve surface cleanness and brightness, while product has both multifunctionality.Adaptability is wider.
(4) the third oxygen of isomerous tridecanol, C12-18 branched fatty alcohol-β-glycol ether and C9-C11 fatty alcohol ethoxylate
Glycolylate compound and the pure and mild ethoxylated propoxylated main work of-C8-10- fatty alcohol compound compounding of ethoxylation-C12-18-
With being to promote infiltration, wetting, disperses emulsification.
(5) HP-E and APG compounding major function is to speed up derusting, paraffin removal speed.
(6) the pure and mild ethoxylated propoxylated-C8-10- fatty alcohol compound of ethoxylation-C12-18-, Lipase and
Cellulase compounding major function is the gloss for removing heavy oil dirt Material-of-the-active and increasing cleaned material.
(7) major function of aromatic hydrocarbons is to extract infiltration after emulsion dispersion to body surface in the oil foulant of interior of articles,
The pH value of product is 7-8, and gross activity agent accounts for 13-17%, can be widely used for glassware, woodwork, plastic rubber product, and aluminium closes
Golden product, metal material, floor tile, ceramics, leatherware, design on fabric surface cleaning, through scene using detection, grease is aged decontamination for 24 hours
Power 100%；Dirt is aged for 24 hours, detergency 98%, and especially removal adhesive sticker (psoriasis) function has effect unique, Project Technical
It fills the domestic gaps.
(8) the different thiophene of methyl (being called methylisothiazolinone) has good anti-corrosion, the effect of guaranteeing the quality to neutral products.
(9) under the premise of sufficiently ensureing multifuctional cleaning agent product cleaning effect, cost is relatively low using basic materials and
The collocation of acid material science, it is final to realize product solves the problems, such as that neutral products are at high cost at neutrality, and realize product
Its is good for effect, widely used perfection.
(10) the fabulous feature of product of the present invention effect is: the main material for the dirt that deoils is all by tripolyphosphate, sodium bicarbonate, food
Adequately ensured and increased with three kinds of material combinations of vinegar the ability of dirt of deoiling, infiltration, emulsification, dispersion activating agent also use
HF302B, C12-18 branched fatty alcohol-β-glycol ether and C9-C11 fatty alcohol ethoxylate propoxylate compound and
The multiple actives such as DS30, it is ensured that infiltration, emulsion dispersion effect go the activating agent of dirt also to reach three kinds；Ethoxylation-
Pure and mild ethoxylated propoxylated-C8-10- fatty alcohol the compound of C12-18-, lipase cellulase, entire formula are substantially every
Kind function is compounded in two, three kind of raw material to realize, even dispersing agent has all reinstated double dispersing agents and ensured its effect.
(11) product instills in the goldfish jar of 5 milliliters of additions, one liter of water, still active travelling, product warp after small goldfish 8 hours
Business men quality supervision and inspection research institute, Hunan Province is according to GB/T9985-2000(manual dishwashing detergent) and GB14930.1-
2015 " inspections of national food safety standard detergent " are met the requirements of the standard.
Specific embodiment mode
Below with reference to embodiment, the present invention is further described, table 1-2 be embodiment 1-6, the group of comparative example 1-4 cleaning agent
At.
Vinegar described in embodiment, comparative example is edible white vinegar, quality of acetic acid content 4%.
Component A is that C12-18 branched fatty alcohol-β-glycol ether and C9-C11 fatty alcohol ethoxylate propoxylate are multiple
With object, compound proportion 1:3.
Component B is the pure and mild ethoxylated propoxylated-C8-10- fatty alcohol compound of ethoxylation-C12-18-, wherein ethoxy
The mass ratio of the pure and mild ethoxylated propoxylated-C8-10- fatty alcohol of base-C12-18- is 1:4；Aromatic hydrocarbons is aromatic hydrocarbons 6.
The composition of 1 embodiment 1-5 cleaning agent of table
。
The composition of 2 embodiment 6 of table, comparative example 1-4 cleaning agent
。
The component A of comparative example 1 is C12-18 branched fatty alcohol-β-glycol ether, other are same as Example 6；Comparative example 2
Component A be C9-C11 fatty alcohol ethoxylate propoxylate, other are same as Example 6；The component B of comparative example 3 is second
Oxygroup-C12-18- alcohol, other are same as Example 6；The component B of comparative example 4 is ethoxylated propoxylated-C8-10- fat
Alcohol, other are same as Example 6.
Above embodiments the preparation method is as follows:
Multifuctional cleaning agent of the present invention the preparation method is as follows:
(1) first by water and sodium tripolyphosphate Na5P3O10, sodium bicarbonate(edible) NaHCO3And vinegar puts into the pill tank that can be heated and stirs
It mixes, hot 85-90 DEG C of temperature tune of pill tank is allowed to raw material and sufficiently dissolves, and stirs evenly；Using upper and lower double mixing-blades mixer, turn
Velocity modulation is to 85 revs/min, and electricity heating is closed after five minutes for stirring；
(2) then by the C12-18 branched fatty alcohol-β-glycol ether compounded and C9-C11 fatty alcohol ethoxylate propoxyl group
In compound compound and ten carbon isomery carboxylate of HF302B isomerous tridecanol and DS30 dimethyl hydroxyethyl investment pill tank, stirring
Machine revolving speed is adjusted to 130 revs/min and stirs 10 minutes；
(3) by the pure and mild ethoxylated propoxylated-C8-10- fatty alcohol compound of the ethoxylation-C12-18- of decontamination, lipase
(Lipase) it in cellulase (cellalase) raw material input cylinder, stirs 5 minutes；
(4) the raw material investment that dispersing agent PH-E polycarboxylic acid anhydride is compounded with the sweet class compound of heptyl sugar and glucose sweet (APG) is matched
In material cylinder, stir 5 minutes；
(5) aromatic hydrocarbons and anti-corrosion raw material are put into again and revolving speed is adjusted to 200 revs/min, are stirred 15 minutes；When needing to be added essence most
After put into pill tank and stir 5 minutes to get finished product.
The using effect of embodiment 1-6 and comparative example 1-4 are shown in Table 3.
The using effect of table 3 embodiment 1-6 and comparative example 1-4
。
It can be seen that in the formula system of the application from the result of embodiment 6 in table 2 and comparative example 1-4 cleaning agent,
C12-18 branched fatty alcohol-β-glycol ether and C9-C11 fatty alcohol ethoxylate propoxylate have synergistic effect, ethoxy
Pure and mild ethoxylated propoxylated-C8-10- the fatty alcohol of base-C12-18- has synergistic effect.
Each embodiment of the application is hand-washed through business men quality supervision and inspection research institute, Hunan Province according to GB/T9985-2000(
Tableware detergent) and GB14930.1-2015 " inspection of national food safety standard detergent " meet the requirements of the standard；
The test method of the above test item is as follows:
1,6 samples have been done according to the embodiment 1-6 ratio that respectively formula material is launched, conclusion is in embodiment 1-6 and comparison
The using effect of example 1-4 shows to show.2, in order to which product use scope is without limitations, widely used truly to realize, product
It is multi-functional, each product sample pH value is detected, is optimal neutral products between pH value 7-8.3, product is through eating
Drink, hotel scene, which use, goes the heavy oil dirt effect on cooking-fume exhauster fine, it is evident that.Dirt is gone to detect, not to the several years
The outside Wall Cleaning effect of cleaning is very good, not only very clean to the ceramic tile cleaning of less gloss, and can also restore such as new light
Pool.4, the rusty stain on outdoor field spray bronzing metal surface, effect is it is also obvious that effect of derusting is favourable.5, External Wall and electric pole
On adhesive sticker small advertisement (psoriasis) directly sprayed with product of the present invention after, it can easily be wiped completely with towel.6,
In order to which neutral products realize multi-functional perfection, and low cost, continuous modification formula is originally prepared using single raw material, at
This is higher, and effect is also undesirable.Such as: additive amount, which is used alone, in main material sodium tripolyphosphate will reach 13% or more, can just go
It after heavy oil dirt is plus sodium bicarbonate and light-coloured vinegar, reduces costs, activating agent similarly so permeates, the C12-18 of emulsion dispersion effect
Branched fatty alcohol-β-glycol ether and C9-C11 fatty alcohol ethoxylate propoxylate compound, HF302B and DS30,
Compound not only adding proportion height with major ingredient with independent any raw material, but also ideal effect is not achieved, three kinds compound after at
This is low and effect is obvious, and raw material derust and decontamination is also in this way, it was verified that single raw material effect is not so good as two kinds or three kinds
The effect of raw material compounding is good.7, the processing support that good formula has also needed, it is also critically important according to dosing material sequentially.With regard to this hair
For bright formula, dispensing trimerization and sodium bicarbonate and temperature raising stirring first waits raw materials after completely dissolution, turns off electric temperature, then put light-coloured vinegar
And activating agent, i.e., the room temperature (being allowed to raw material composition not changed by high temperature) of raw material is not influenced and product is also not stratified, in turn
Activating agent is first put, then puts sodium tripolyphosphate, sodium bicarbonate, stirring at normal temperature, both pulvis raw materials cannot sufficiently dissolve, and product
It is also layered, pH value is also inaccurate.
Claims (8)
1. a kind of multifuctional cleaning agent, it is characterised in that in terms of mass fraction, including following component: it is 6-9 parts of tripolyphosphate, small
6-9 parts of soda, 2-5 parts of vinegar, 4-5 parts of isomerous tridecanol, C12-18 branched fatty alcohol-β-glycol ether and C9-C11 fatty alcohol
2-4 parts of ethoxylated propoxylated object compound, ten 1-2 parts of carbon isomery carboxylate of dispersing agent dimethyl hydroxyethyl, glucoside
1-2 parts, sugared sweet 3-5 parts of class compound with heptyl of polycarboxylic acid anhydride, the pure and mild ethoxylated propoxylated-C8- of ethoxylation-C12-18-
3-6 parts of 10- fatty alcohol compound, 1-2 parts of aromatic hydrocarbons, 0.3-0.4 parts of lipase, 0.2-0.3 parts of cellulase, anti-corrosion raw material
0.3-0.4 parts, 62.2-64.6 parts of water.
2. multifuctional cleaning agent according to claim 1, it is characterised in that be additionally added 0.1-0.3 parts of essence in cleaning agent.
3. multifuctional cleaning agent according to claim 1, it is characterised in that the vinegar is edible white vinegar, and quality of acetic acid contains
Measure 3-5%.
4. multifuctional cleaning agent according to claim 1, it is characterised in that the C12-18 branched fatty alcohol-β-second two
C12-18 branched fatty alcohol-β-glycol ether and C9- in alcohol ether and C9-C11 fatty alcohol ethoxylate propoxylate compound
The mass ratio of C11 fatty alcohol ethoxylate propoxylate is 1:(2-4).
5. multifuctional cleaning agent according to claim 1, it is characterised in that the pure and mild second of ethoxylation-C12-18-
Pure and mild ethoxylated propoxylated-C8-10- the rouge of ethoxylation-C12-18- in oxygroup propoxylation-C8-10- fatty alcohol compound
The mass ratio of fat alcohol is 1:(2-5).
6. multifuctional cleaning agent according to claim 1, it is characterised in that the aromatic hydrocarbons is aromatic hydrocarbons 6.
7. multifuctional cleaning agent according to claim 1, it is characterised in that the anti-corrosion raw material is the different thiophene of methyl.
8. the preparation method of multifuctional cleaning agent according to claim 1, it is characterised in that in turn include the following steps:
(1) first water and sodium tripolyphosphate, sodium bicarbonate and vinegar are put into the pill tank that can be heated and is stirred, the temperature tune of pill tank
80 DEG C -90 DEG C of heat dissolves raw material sufficiently, and stirs evenly；Using upper and lower double mixing-blades mixer, revolving speed be adjusted to 80-100 turn/
Point, electricity heating is closed after stirring 5-9 minutes；
(2) then by the C12-18 branched fatty alcohol-β-glycol ether compounded and C9-C11 fatty alcohol ethoxylate propoxyl group
In compound compound and ten carbon isomery carboxylate of isomerous tridecanol and dimethyl hydroxyethyl investment pill tank, blender revolving speed is adjusted to
120-140 revs/min stirring 10-15 minutes；
(3) by the pure and mild ethoxylated propoxylated-C8-10- fatty alcohol compound of the ethoxylation-C12-18- of decontamination, lipase
(Lipase) it in cellulase (cellalase) raw material investment pill tank, stirs 5-10 minutes；
(4) it in the raw material investment pill tank for compounding dispersing agent polycarboxylic acid anhydride with the sweet class compound of heptyl sugar and glucoside, stirs
It mixes 5-10 minutes；
(5) aromatic hydrocarbons and anti-corrosion raw material are put into again and revolving speed is adjusted to 180-230 revs/min, are stirred 15-20 minutes, are obtained finished product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110791391A (en) * | 2019-10-09 | 2020-02-14 | 上海柯灵展新化工有限公司 | Equipment pipeline deodorant and preparation method and application thereof |
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| CN110272783B (en) | 2021-03-26 |
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