CN1144533A - Aqueous cleaning compositions containing a 2-alkanol H202 an anionic and low hlb nonionic - Google Patents
Aqueous cleaning compositions containing a 2-alkanol H202 an anionic and low hlb nonionic Download PDFInfo
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- CN1144533A CN1144533A CN 95192224 CN95192224A CN1144533A CN 1144533 A CN1144533 A CN 1144533A CN 95192224 CN95192224 CN 95192224 CN 95192224 A CN95192224 A CN 95192224A CN 1144533 A CN1144533 A CN 1144533A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
- C11D3/202—Monohydric alcohols branched fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
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- Detergent Compositions (AREA)
Abstract
The present invention relates to multi-purpose aqueous cleaning compositions comprising hydrogen peroxide, a 2-alkyl alkanol, a hydrophobic surfactant having an HLB below 14 and an anionic surfactant. The present invention also encompasses the use of 2-alkyl alkanols together with hydrophobic surfactants, in aqueous cleaning compositions, so as to improve the greasy cleaning of said compositions. 2-alkyl alkanols in combination with hydrophobic surfactants can be used in any composition including laundry detergents or hard surface cleaners for bathrooms or kitchens or floors.
Description
Technical field
The present invention relates to the field of multi-usage cleaning combination.In fact, the present invention relates to the cleaning of different surfaces such as crust, carpet or relate to and comprise any laundry purposes of removing spot in advance.
Technical background
Various cleaning combinations have extensively been introduced in the prior art.Generally, cleaning combination can be divided into hard-surface cleaning composition and clothes washing composition.These two kinds of cleaning combinations have a great difference as usual on prescription, be to sell as the variant production of different selling concepts.These differences are forced at the human consumer and are made them be obliged to go to buy and use at least two kinds of different products.Therefore, above-mentioned two kinds of compositions, especially hard surface cleaners also can be divided into the accessory classification.In fact, can buy the hard surface cleaner of many different varietiess, for example bathroom clean-out system, cleaning agent for kitchen or floor cleaner.
According to from clothing with kitchen, floor and bathroom on the various surfaces detectable dirt character different, the prescription variation is necessary.For example, the kitchen dirt mainly contains edible oil, and the bathroom dirt mainly contains sebum and soap lather, also has calcium scale; The floor dirt mainly contains particulate dirt and clothing just may have various dirts and stain.
Yet the cleaning combination that development at present has better performance exists a kind of tendency from different aspects, promptly multiduty liquid cleaner, they can be used on the various surfaces satisfactorily and the laundry purposes on so that wash various dirts and stain.Such multipurpose composition for example has been described among European patent application EP-A-598973.In fact, the disclosed composition of this piece patent application comprises hydrogen peroxide and whole nonionic surfactant systems, that is to say at least a HLB at the nonionogenic tenside more than 15, and at least a HLB is at the nonionogenic tenside of 13-15.At least a HLB is lower than 9 nonionogenic tenside at nonionogenic tenside and at least a HLB of 9-13.This patent application further discloses use 2-alkyl chain triacontanol and has made to suppress infusion in described composition.
But, found thisly to contain hydrogen peroxide, 2-alkyl chain triacontanol and as the composition of surfactant system, wherein said surfactant system is a kind of specific nonionic surfactant system with different at least four kinds of nonionogenic tensides by former qualification HLB (hydrophile-lipophile balance value), described composition satisfy on human consumer's the needs unsatisfactory.In fact, find thisly based on whole nonionic surfactant systems and contain the composition of high density hydrophobic surfactant, the performance that has for some dirt under the laundry occasion is poor.Although this hydrophobicity nonionogenic tenside has the good oil stain performance of removing, and when being used for hard-surface cleaning composition, to the hydrophobicity greasy dirt, effective especially as mineral oil and soap lather, but still when finding that described hydrophobicity nonionogenic tenside is used to do washing, the stain bleaching that can bleach makes us dissatisfied.The wettability of fabric stain is subjected to seriously that the nonionic system is hydrophobic in the described composition influences, and has promptly hindered the excellent contact between the stain on hydrogen peroxide and the described fabric, thereby produces bad performance on the stain that can bleach.In addition, also find to exist a kind of with use described composition, i.e. hydrophobicity nonionogenic tenside and the related problem of 2-alkyl chain triacontanol, it is vaporific to be that they might cause that final product occurs, this shows separating of insoluble and phase.
The objective of the invention is to prepare multiduty liquid ceanser thus, it can be used for various surfaces and laundry occasion satisfactorily, removes various dirts and stain.Further aim of the present invention provides this under wide temperature range very, for example up to the limpid composition of 50 ℃ of uses.The present composition can also be under various conditions, promptly in hard water and soft water and with all using under pure or the diluting condition.The surface was safe when they can also provide gratifying gloss and be used as hard surface cleaner.
In other words, the purpose of this invention is to provide a kind of multi-usage waterborne compositions, it can discharge significant oil stain and reach when cleaning various surfaces and clothing, also can provide improved laundry usefulness on the stain that can bleach and other hydrophilic stain.
Have now found that these purposes can be met effectively by the cleaning combination that preparation comprises hydrogen peroxide, 2-alkyl chain triacontanol and special surfactant system, described system comprises at least a HLB (hydrophile-lipophile balance value) and is lower than 14 hydrophobic surfactant, preferred nonionic surfactants, with at least a anion surfactant, the preferred alkyl sulfuric acid.In fact, have been found that combination, can provide a kind of and can remove the multi-usage cleaning combination that shows very big handiness aspect the dirt by these four kinds of compositions.Find that also described composition can produce more strong clenaing effect, especially when laundry, promptly described composition can produce good usefulness when hydrophilic stain of bleaching and removal greasy dirt.
Also find the 2-alkyl chain triacontanol with regard to the oil stain clenaing effect, can strengthen the effect of given hydrophobic surfactant system.Especially, for any specified cleaning combination that contains hydrophobic surfactant and specified oil stain clenaing effect can be provided for the surface with its processing, add the 2-alkyl chain triacontanol and will improve the oil stain clenaing effect.In addition, be surprisingly found out that also the cleaning for oil stain when HLB is lower than 14 hydrophobicity nonionogenic tenside and uses of 2-alkyl chain triacontanol can produce synergistic effect.
The foam outward appearance that the advantage of the present composition is the present composition for suitable foam content the crust occasion when strict particularly suitable.In fact, the invention has the advantages that surperficial rinsing becomes more convenient.The further advantage of the present invention be the maximum cost effective multipurpose cleaning combination that provides the hard surface cleaning carpet clean and the laundry purposes in the usefulness excellence.
Introduced the cleaning combination that contains the 2-alkyl chain triacontanol in the prior art.The alcohol that DE4021265 discloses in 2-position top set is effective suds suppressor.This patent application discloses also that to contain the 2-alkyl chain triacontanol be the composition of the nonionic ethoxylated alcohol of 3-7 together with Fatty Alcohol(C12-C14 and C12-C18) chain length 13-17 and ethoxylation degree.Disclosed composition does not contain SYNTHETIC OPTICAL WHITNER.In addition, this patent application did not just use relevant oil stain clenaing effect to disclose its benefit with the 2-alkyl chain triacontanol together with hydrophobic surfactant.
The disclosed composition of EP-A-593841 contains tensio-active agent and as the branched-chain alcoho of suds suppressor system, for example mixture of 2-alkyl chain triacontanol and silicone oil.Disclosed dissimilar tensio-active agent comprises generalized negatively charged ion, nonionic, positively charged ion and zwitterionics.This patent application did not disclose described composition may further comprise SYNTHETIC OPTICAL WHITNER, says nothing of hydrogen peroxide.In addition, this patent application did not cooperate hydrophobic surfactant to use relevant oil stain to clean open beneficial effect with regard to the 2-alkyl chain triacontanol.
European Patent Application No. 93870215.6 discloses based on containing C
6-C
10Alkyl chain is made the concentrated cleaning combination of the short chain surfactants of its hydrophobic part.This patent application discloses 2-alkyl chain triacontanol may command foam.This patent application mention described short chain surfactants can be the composition that contains them provide stability but also mention the cleaning that they can improve the usefulness of whole cleaning, especially oil stain significantly.Yet this patent application record useless 2-alkyl chain triacontanol can strengthen hydrophobic surfactant and clean the smeary ability.In addition, the SYNTHETIC OPTICAL WHITNER as optional member has been mentioned in this patent application, but has not mentioned hydrogen peroxide.
EP-A-598973, above mentioned, disclosed composition contains hydrogen peroxide, 2-alkyl chain triacontanol and as whole nonionic system of tensio-active agent, be that at least a HLB is at the nonionogenic tenside more than 15, at least a HLB is at the nonionogenic tenside of 13-15, and at least a HLB is lower than 9 nonionogenic tenside at nonionogenic tenside and at least a HLB of 9-13.But,, mentioned wherein disclosed composition and do not required to use anionic surfactant system but also put down in writing described composition and preferably do not contain anion surfactant according to being documented in this patent application.In addition, this patent application was open with regard to the benefit with regard to the 2-alkyl chain triacontanol cooperates the relevant greasy dirt cleaning of hydrophobicity nonionogenic tenside use.
Summary of the invention
The present invention includes aqueous clean combination, said composition contains hydrogen peroxide, or its source thing, 2-alkyl chain triacontanol or its mixture, and HLB is lower than 14 hydrophobic surfactant, or its mixture, and anion surfactant.
The present invention includes the 2-alkyl chain triacontanol and be lower than 14 hydrophobic surfactant together with HLB, or the application in aqueous clean combination together of its mixture, to improve the greasy dirt clenaing effect of described composition.
Detailed Description Of The Invention
The present composition is the cleaning combination of water-based.Described composition comprises hydrogen peroxide, or its source thing, and 2-alkyl chain triacontanol, or its mixture, HLB are lower than 14 hydrophobic surfactant and anion surfactant.The present composition is effective especially in cleaning various dirt, and has observed significant cooperation relation (Cooperation) is arranged between four kinds of compositions.In fact, the present composition various dirts capable of washing, from particle to non-particulate dirt, from hydrophilic to hydrophobicity dirt and suitable especially for the clothing of washing hydrophobicity and hydrophilic fibre.
As first principal component, the present composition comprises hydrogen peroxide, or its water-soluble source thing.In an optimum implementation, the present composition comprises hydrogen peroxide.Generally, being suitable for that composition of the present invention contains by general composition weight meter is the hydrogen peroxide of 0.5%-20%, or its source thing.Preferred 2%-15% and be preferably 3%-10%.In fact, the existence of hydrogen peroxide can provide attractive firm cleaning benefit when particularly doing washing.In addition, be used for the combination of the present invention of cleaning combination, be tensio-active agent together with the 2-alkyl chain triacontanol together, significantly compatible with hydrogen peroxide, because hydrogen peroxide is for described composition, even under the situation of stabilizer of hydrogen peroxide useless, also can observe good preservation stability.
As Second principal component,, the present composition contains the 2-alkyl chain triacontanol, or its mixture.Being particularly suitable for of the present invention is to have the 6-16 of containing carbon atom, the alkyl chain of preferred 8-12 carbon atom and the 2-alkyl chain triacontanol that terminal is hydroxyl, described alkyl chain on alpha position by 1-10 carbon atom, preferred 2-8 and the alkyl chain that is more preferably 3-6 carbon atom replaces.Suitable compound can have been bought from the market like this.For example, with lsofol
Series as lsofol
12 (2-butyl octanol) or lsotol
16 (2-hexyl decyl alcohol).
Generally, be suitable for composition of the present invention and contain the 2-alkyl chain triacontanol of 0.05%-2%, or its mixture by general composition weight meter, preferred 0.1%-1.5% and best be 0.2%-0.8%.
As the 3rd principal constituent, the present composition contains HLB (hydrophile-lipophile balance value) and is lower than 14 hydrophobic surfactant, or its mixture.In composition of the present invention, described hydrophobic surfactant and described 2-alkyl chain triacontanol are brought into play effectiveness together, especially to greasy dirt such as kitchen oil dirt thing and bathtub dirt.So just might use the low described hydrophobic surfactant of total content, or its mixture.The present composition can contain the described hydrophobic surfactant of 0.1%-15% by general composition weight meter, or its mixture, preferred 0.3%-10% and be more preferably 0.4%-6%.
Being used for the present invention specially suitable is to have HLB to be lower than 14 hydrophobicity nonionogenic tenside, and preferred HLB is lower than 12 nonionogenic tenside, be more preferably to be lower than 11.5, and best be to be lower than 10.The HLB that has according to the better nonionogenic tenside of the present invention is lower than 9.Found that those hydrophobicity nonionogenic tensides can provide good degreasing performance.
Suitable hydrophobicity nonionogenic tenside is various Fatty Alcohol(C12-C14 and C12-C18) chain lengths and fatty alcohol ethoxylates various ethoxylation degrees and/or the propoxylated glycerine that can buy from the market to be used for the present invention.In fact, the HLB value of so oxyalkylated nonionogenic tenside depends on the chain length of Fatty Alcohol(C12-C14 and C12-C18) basically, alkoxylate character and oxyalkylated degree.Hydrophobic surfactant tends to have the Fatty Alcohol(C12-C14 and C12-C18) of lower alkoxylate of degree and long-chain.Can obtain many tensio-active agents from the market, comprise nonionogenic tenside, together with the table look-up of its corresponding HLB value.
The appropriate chemical method that preparation is used for hydrophobicity nonionogenic tenside of the present invention comprises the ratio condensation on request of corresponding alcohol and alkylene oxide.This method is understood thoroughly by those skilled in the art and extensively is described in the prior art.Thing as an alternative, being suitable for a large amount of alkoxylate alcohols of the present invention can many from the market suppliers buy there.
The preferred hydrophobicity nonionogenic tenside that is used for the present composition is that HLB is lower than 14 and general molecular formula RO-(C
2H
4O)
n(C
3H
6O)
mThe tensio-active agent of H, R is C in the formula
6-C
22Alkyl chain or C
6-C
28Alkylbenzene chain, and n+m is that 0-20 and n are that 0-15 and m are 0-20 in the formula, preferred n+m are that 1-15 and n and m are 0.5-15, and being more preferably n+m and being 1-10 and n and m is 0-10.For being used for preferably C of R chain of the present invention
8-C
22Alkyl chain.Therefore being used for suitable hydrophobicity nonionogenic tenside of the present invention is Dobanol
R91-2.5 (HLB=8.1; R is C
9And C
11The mixture of alkyl chain, n be 2.5 and m is 0), or Lutensol
RTO3 (HLB=8; R is C
13Alkyl chain, n be 3 and m is 0), or Lutensol
RAO3 (HLB=8; R is C
13And C
15The mixture of alkyl chain, n be 3 and m is 0), or Tergitol
R25L3 (HLB=7.7; R is at C
12-C
15In the scope of alkyl chain length, n be 3 and m is 0), or Dobanol
R23-3 (HLB=8.1; R is C
12And C
13The mixture of alkyl chain, n be 3 and m is 0), or Dobanol
R23-2 (HLB=6.2; R is C
12And C
13The mixture of alkyl chain, n be 2 and m is 0), or Dobanol
R23-6.5 (HLB=11.9; R is C
12And C
13The mixture of alkyl chain, n be 6.5 and m is 0), or Dobanol
R25-7 (HLB=12; R is C
12And C
15The mixture of alkyl chain, n be 7 and m is 0), or Dobanol
R91-5 (HLB=11.6; R is C
9And C
11The mixture of alkyl chain, n be 5 and m is 0), or Dobanol
R91-6 (HLB=12.5.; R is C
9And C
11The mixture of alkyl chain, n be 6 and m is 0), or Dobanol
R91-8 (HLB=13.7; R is C
9And C
11The mixture of alkyl chain, n be 8 and m is 0), or its mixture.Dobanol preferably in the present invention
R91-2.5, or Lutensol
RTO3, or Lutensol
RAO3, or Tergitol
R25L3, or Dobanol
R23-3, or Dobanol
R23-2, or its mixture.These Dobanol of available SHELL from the market
RTensio-active agent.These Lutensol of available BASF from the market
RTensio-active agent, and these Tergitol of also available UNION CARBIDE from the market
RTensio-active agent.
As the 4th principal constituent, the present composition contains anion surfactant, or its mixture.The anion surfactant of described hydrophilic compounds is brought into play effectiveness with hydrophobic surfactant, as offsetting the negative effect of hydrophobic surfactant.Described anion surfactant can play wetting agent, promptly when laundry they can be above the wetting fiber stain, especially the stain on the hydrophilic fibre, and therefore help hydrogen peroxide to go to carry out its bleaching action, help to improve the laundry usefulness in the time of can bleaching stain whereby.In addition, even anion surfactant of the present invention also can obtain limpid composition when described composition contains hydrophobicity composition such as 2-alkyl chain triacontanol and hydrophobic surfactant.The present composition contains the described anion surfactant of 0.1%-20% by general composition weight meter, or its mixture, preferred 0.2%-10%, more preferably 0.5%-8%.
Being used for the present invention specially suitable is sulfonate and sulfate surfactant.Similarly anion surfactant is that well-known technology and discovery are widely used in the commercially available washing composition.These anion surfactants comprise C
8-C
22Alkyl benzene sulphonate (ABS) (LAS), C
8-C
22Alkyl sulfuric ester salt (AS), unsaturated sulfuric acid such as oleoyl sulfuric acid (Oleyl Sulfate), C
10-C
18Alkyl alkoxy sulfuric acid (AES) and C
10-C
18The alkyl alkoxy carboxylate salt.In and the positively charged ion of negatively charged ion synthesising sulfonate and/or sulfuric acid can represent by the conventional positively charged ion such as sodium, potassium or the alkanol ammonium that are widely used in the washing composition technology.The present invention is alkyl sulfuric ester salt preferably, especially has 6-18 carbon atom in the alkyl chain, the coconut alkyl sulfuric ester salt of preferred 8-15 carbon atom, or its mixture.
The composition that is suitable among the present invention can further contain other nonionic and/or anion surfactant and other different classes of tensio-active agent such as positively charged ion, zwitter-ion or amphoterics except that described herein.
Be suitable for the liquid cleaning compositions that composition of the present invention is a water-based.The pH of described waterborne compositions is 1-9, preferred 3-6 and be more preferably 3-4.The pH of composition can pass through to use organic or inorganic acid, or alkalizing agent is regulated.
Be suitable for composition of the present invention and also can further contain various optional members such as auxiliary agent, stablizer, sequestrant, dirt suspension agent, dye-transfer, solvent, whitening agent, spices and dyestuff.
Use according to the household cleaners that the suitable composition that uses of the present invention can be used as in bathroom or the kitchen, and can be used as laundry detergent or laundry detergent secondary accelerator or the use of conduct laundry prewashing treatment compositions.When using as hard surface cleaner, this composition is easy to rinsing and good gloss can be provided on the surface of cleaning.This in addition composition is effective especially as carpet cleaner.If when using as carpet cleaner, the most handy spray dispenser of this composition distributes and it is stayed on the described carpet work.
Except providing the present invention the composition of preceding description, the present invention is with in aqueous clean combination, uses the 2-alkyl chain triacontanol to be lower than 14 hydrophobic surfactant together with HLB and can improve the oil stain of described composition and clean so a kind of basis that is found to be.
" improve oil stain clean " can be understood as in the present invention by using the 2-alkyl chain triacontanol to be lower than 14 the oil stain degree of cleaning that hydrophobic surfactant reached together with HLB in specified composition, compares and is improved with using or only contain a kind of in two kinds of additional compounds or do not contain its any oil stain degree of cleaning that same combination obtained.Found the synergistic effect of oil stain clenaing effect in addition and in aqueous clean combination, used the 2-alkyl chain triacontanol relevant with the hydrophobicity nonionogenic tenside.A kind of oil stain clenaing effect of composition can be estimated as used GSS (grease soap bubble foam dirt) test method among the embodiment hereinafter by different spot test for fat methods.
Be owing to used the 2-alkyl chain triacontanol with advantages associated of the present invention, thereby obtain good foam outward appearance.In fact, it is seemingly deleterious to gloss that the present invention can avoid, and the human consumer is caused the too much foaming of rinsing trouble.In other words, might under situation of the present invention, need not to add any other suds suppressor,, just can make foam profiles reach requirement as to all deleterious siloxanes suds suppressor of the aesthetics of stability of peroxide and composition.
To be further described the present invention by the following example.
A) experimental data of the benefit relevant with the present composition
Be mixed with following composition by following composition in the ratio (unless otherwise indicated being all weight %) of tabulating.
Composition I II III IV V VI
Dobanol
R?91-10 - - 1.6 1.6 1.6 1.6
Alkyl sulfuric ester salt-1.5-1.5 1.5 1.5
Dobanol
R?23-3 - - 1.1 1.1 1.1 -
H
2O
2 7.0 7.0 7.0 7.0 7.0 7.0
2-butyl octanol--0.4 0.4-1.1
Water and trace ingredients to 100%
Add H
2SO
4To pH4
Dobanol
R91-10 is that HLB is 14.7 nonionogenic tenside, Dobanol
R23-3 is that HLB is that 8.1 nonionogenic tenside and alkyl sulfuric ester salt are coconut alkyl sulfuric ester salt, and available from the market Marchon trade mark is the product of Empicol 0298F .
Composition I only contains hydrogen peroxide, gets its object of reference as bleaching usefulness in oil stain cleaning and the laundry applications in the crust application.Composition I I contains hydrogen peroxide and alkyl sulfuric ester salt.Composition I II is the representative of prior art compositions and contains nonionic system as tensio-active agent.Composition I V is representative of the present invention, and promptly it contains 2-butyl octanol together with hydrophobicity nonionogenic tenside, Dobanol
R23-3, hydrogen peroxide and alkyl sulfuric ester salt (coconut alkyl sulfuric ester salt).Composition V is different from composition I V and is that composition V does not contain 2-butyl octanol.Composition VI is different from composition I V and is that composition VI does not contain Dobanol
R23-3.In fact, except composition I V, all compositions are all got makes object of reference, all relevant with concuring of heterogeneity with the benefit that proof is relevant with the present composition.
Finish following test:
Finish GSS (grease soap bubble foam dirt) test method under the composition that the present invention in the above mentions.This GSS test method is that to adopt typical crust family expenses (bathroom) dirt be that the synthetic dirt of representative is finished.Test is to be the mixture of natural grease compound by mixing Virahol, stearic acid calcium powder, dirt mixture that comprises the inorganic and organic compound of representing the average family dirt and oil contamination with dirt (GSS dirt).This test is coated in oneself with dirt with paint roller and goes up on the metal sheet of enamel (earlier with cleaning with ethanol behind the washing composition), this plate is placed 130 ℃ of oven dry 30 minutes down again.After 24 hours they are used for testing.This test is estimated with Gardner straight line scrubber (straight-line scrub).
Getting composition I compares to estimate its oil stain clenaing effect with composition I I and VI as object of reference.Indicate+composition require significantly to be better than object of reference composition (I).Indicate ++ composition to significantly be better than indicate+composition and indicate +++composition to significantly be better than and indicate ++ composition.In the difference that indicates between the composition of identical point is inapparent statistically.These results obtain according to repeating eight tests.
Laundry test is to carry out on the white cotton of the tea mark fabric dying to have.Stain washs this piece fabric down in 25 ℃ again with the composition 4ml pre-treatment that front the present invention mentions.
Foam test is carried out in the cylinder foaming machine.Make 500ml contain the solution rotating 10 minutes of the aforementioned present compositions of 12.5 grams.Preparation respectively has this solution of the various compositions of above-mentioned the present invention.The water hardness is 18 gram/gallons.This numerical value is the standard of the rotating speed when considering the foam (use the cm surface) of correspondent composition and disappearance thereof.When cylinder stops operating, measure foam in the time of after 5 minutes and 30 minutes.The maximum value of group specified compound be 10 and this value cylinder of being equivalent to a kind of composition on three kinds of different Measuring Time, all be full of foam.
The result is as follows:
Composition I II III IV V VI
Laundry is used
Hydrophilic stain (tea) reference=-===
Crust is used
GSS test reference+++++++++ ++
Outward appearance is limpid vaporific limpid vaporific
Foam 072393
The above results clearly illustrates that the advantage of the present composition (composition I V).In fact, described result represents to contain HLB and is lower than the present composition that 14 hydrophobic surfactant and anion surfactant are made surfactant system, when as hard surface cleaner, with the composition contrast (seeing the correlated composition I V of composition I II) that does not contain described anion surfactant, far better with regard to laundry usefulness in the good oil stain clenaing effect of maintenance with the prior art representative.Described result further shows alkyl sulfuric ester salt pair final composition, and promptly alkyl sulfuric ester salt gives the as clear as crystal situation of composition with wholesome effect.
Described result represents that also 2-butyl octanol can not only be as the secondary accelerator of hydrophobic surfactant and in addition can be as the effect of suds suppressor (referring to for example composition V or II with respect to composition I V).
As for use 2-butyl octanol together with hydrophobicity nonionogenic tenside (DOBANOL23.3 ) in the cleaning detergent with regard to the oil stain clenaing effect relevant synergistic effect, although under composition I V and composition V or VI contrast, obtain, but still can further in following experimental data, be confirmed.
B) the synergistic experimental data of oil stain being cleaned about hydrophobicity nonionogenic tenside and 2-alkyl chain triacontanol
Following composition is to be mixed with by the ratio (unless otherwise indicated being weight %) of tabulation composition in tabulation.
Composition I II III
Lutensol
R?AO?30 0.75 0.75 0.75
Dobanol
R?91-10 2.60 2.60 2.60
Dobanol
R?23-6.5 0.90 0.90 0.90
Dobanol
R?23-3 1.00 1.75 -
H
2O
2 7.00 7.00 7.00
H
2SO
4The pH 4.00 4.00 4.00 that is up to
2-butyl octanol 0.75-1.75
Water and trace ingredients to 100%
Lutensol
RAO 30 is that to have HLB be 17 nonionogenic tenside, Dobanol
R91-10 is that to have HLB be 14.7 nonionogenic tenside, Dobanol
R23-6.5 be that to have HLB be 11.9 nonionogenic tenside and Dobanol
R23-3 is that to have HLB be 8.1 nonionogenic tenside.
Composition I is representative of the present invention, and promptly it contains 2-butyl octanol and is lower than 14 hydrophobic surfactant, Dobanol together with HLB
R23-3.The difference of composition I I and composition I is that composition I I does not contain 2-butyl octanol.The difference of composition I II and composition I is that composition I II does not contain Dobanol
R23-3.Getting composition I I and III is object of reference.
GSS (grease soap bubble foam dirt) test method is finished with composition mentioned above.
This GSS test method(s) is to adopt the synthetic dirt of representative typical crust family expenses (bathroom) dirt to carry out.Test is by mixing Virahol, stearic acid calcium powder, comprises inorganic and organic compound and represent the dirt mixture of common family's dirt and the mixture of the oil stain dirt of natural fats and oils compound with dirt (GSS dirt).This test is coated on the metal sheet of glass-lined (earlier with cleaning with ethanol behind the washing composition) with paint roller with dirt, and this plate is again in 130 ℃ of oven dry 30 minutes down.Use it for test after 24 hours.This test is estimated in Gardner straight line scrubber.
The result represents must the cleaning standard stain the used stroke number of (GSS dirt) plate for specified composition.The low more composition that is used for greasy filth on the washing test plate of required stroke number is effective more with regard to cleaning.
The result is as follows: as defined above, and the number of the numeric representation stroke of indicating.
Composition stroke number
Composition I 79.5
Composition I I 100.0
Composition I II 104.5
The above results clearly illustrates that and is existing and using 2-alkyl chain triacontanol (2-butyl octanol) to be lower than 14 hydrophobicity nonionogenic tenside (Dobanol together with its HLB in the cleaning detergent with regard to the oil stain clenaing effect
R23-3) relevant synergistic effect.
Embodiment
Following composition prepares in tabulation ratio (unless otherwise indicated being all weight %) by mixing the tabulation composition.
Composition I II III IV
H
2O
2 7.0 7.0 7.0 7.0
Alkyl sulfuric ester salt (1) 1.2-1.2-
Dobanol
R?91-8 - - 1.6 -
Dobanol
R?91-10 1.6 1.6 - 1.6
Lial alkyl sulfuric ester salt (2)-1.5-1.5
Dobanol
R?23-3 1.1 1.1 - 1.1
Lutensol
R?TO3 - - 1.1 -
2-butyl octanol 0.5 0.5 0.6 0.2
Water and trace ingredients (dyestuff) are to 100%
H
2SO
4To pH 4
(1) be that the coconut alkyl sulfuric ester salt of the commodity Empicol 0298F by name that bought from Marchon and (2) are the branched-chain alkyl sulfuric acids of commodity Empicol 8221 by name that bought from Marchon.Dobanol
R23-3 is that HLB is 8.1 nonionogenic tenside and Lutensol
RTO3 is that HLB is 8 nonionogenic tenside.
Composition among the embodiment conforms to the present invention, and promptly composition can show good degreasing usefulness to various dirts such as kitchen oil dirt thing, bathtub dirt, can also show good laundry usefulness simultaneously.In addition, stability of peroxide can obtain monitoring and prove gratifying in 50 ℃ of following two weeks.Also have, the composition among the embodiment all is as clear as crystal composition up to 50 ℃ for example in very wide temperature range.When described composition is used as hard surface cleaner, can further provide gratifying gloss characteristic and surperficial security.In addition, these compositions can promptly use in hard and soft water under various conditions.
Claims (10)
1, aqueous clean combination contains hydrogen peroxide, or its source thing, 2-alkyl chain triacontanol, or its mixture, and HLB is lower than 14 hydrophobic surfactant, or its mixture, and anion surfactant.
2,2-alkyl chain triacontanol, or its mixture are lower than 14 hydrophobic surfactant together with HLB, or its mixture together, and the application in aqueous clean combination is to improve the oil stain clenaing effect of described composition.
3, by the composition or the application of aforementioned each claim, wherein said hydrophobic surfactant is a nonionogenic tenside, and preferred HLB is lower than 12, better is lower than 11.5 and be preferably lower than 10 nonionogenic tenside.
4, by the composition or the application of aforementioned each claim, wherein said composition contains the described hydrophobic surfactant of 0.1%-15% by general composition weight meter, or its mixture, preferred 0.3%-10% and be more preferably 0.4%-6%.
5, press the composition or the application of aforementioned each claim, wherein said 2-alkyl chain triacontanol has the 6-16 of containing carbon atom, the alkyl chain and the end of preferred 8-12 carbon atom are hydroxyl, described alkyl chain is contained 1-10 carbon atom at alpha position, preferred 2-8 carbon atom, more preferably the alkyl chain of 3-6 carbon atom replaces.
6, by the composition or the application of aforementioned each claim, wherein said 2-alkyl chain triacontanol is 2-butyl octanol or 2-hexyl decyl alcohol, or its mixture.
7, by the composition or the application of aforementioned each claim, wherein said composition contains the described 2-alkyl chain triacontanol of 0.05%-2% by general composition weight meter, or its mixture, preferred 0.1%-1.5% and be more preferably 0.2%-0.8%.
8, by the composition or the application of aforementioned each claim, the pH of wherein said composition is 1-9, preferred 3-6, more preferably 3-4.
9, by the composition or the application of aforementioned each claim, wherein said composition contains the hydrogen peroxide of 0.5%-20% by weight, preferred 2%-1 5%.
10, press the composition or the application of aforementioned each claim, anion surfactant and wherein said anion surfactant that wherein said composition contains 0.1%-20% are to have 6-18 in its alkyl chain, the alkyl sulfuric ester salt of preferred 8-15 carbon atom.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP94870018.2 | 1994-02-03 | ||
| EP94870018 | 1994-02-03 | ||
| EP94201634A EP0666308B1 (en) | 1994-02-03 | 1994-06-08 | Multi-purpose liquid cleaning compositions |
| EP94201634.6 | 1994-06-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1144533A true CN1144533A (en) | 1997-03-05 |
Family
ID=26136317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95192224 Pending CN1144533A (en) | 1994-02-03 | 1995-01-31 | Aqueous cleaning compositions containing a 2-alkanol H202 an anionic and low hlb nonionic |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0666308B1 (en) |
| JP (1) | JPH09508655A (en) |
| CN (1) | CN1144533A (en) |
| AU (1) | AU701779B2 (en) |
| BR (1) | BR9506715A (en) |
| CA (1) | CA2182672A1 (en) |
| EG (1) | EG20508A (en) |
| FI (1) | FI963078A (en) |
| MX (1) | MX9603201A (en) |
| WO (1) | WO1995021233A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107849491A (en) * | 2015-06-05 | 2018-03-27 | 益克林实业有限责任公司 | Multifunction detergent without VOC |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0805200B1 (en) * | 1996-05-03 | 2003-07-16 | The Procter & Gamble Company | Hard surface cleaning compositions |
| DE69627847T2 (en) * | 1996-09-13 | 2004-03-11 | The Procter & Gamble Company, Cincinnati | Methods and compositions for bleaching laundry |
| US5922665A (en) * | 1997-05-28 | 1999-07-13 | Minnesota Mining And Manufacturing Company | Aqueous cleaning composition including a nonionic surfactant and a very slightly water-soluble organic solvent suitable for hydrophobic soil removal |
| EP0916721B1 (en) * | 1997-11-12 | 2004-09-15 | The Procter & Gamble Company | Laundry bleaching compositions |
| US5968888A (en) * | 1998-11-13 | 1999-10-19 | Colgate Palmolive Company | Liquid crystal compositions containing a 2 alkyl alkanol and abrasive |
| GB9917885D0 (en) * | 1999-07-29 | 1999-09-29 | Procter & Gamble | Method of removing plaque from a denture |
| US6849589B2 (en) | 2001-10-10 | 2005-02-01 | 3M Innovative Properties Company | Cleaning composition |
| US7781388B2 (en) | 2006-05-04 | 2010-08-24 | American Sterilizer Company | Cleaning compositions for hard to remove organic material |
| CN101392214B (en) * | 2008-10-17 | 2011-01-05 | 王宝玉 | Carpet dry-cleaning powder and preparation method thereof |
| JP5463026B2 (en) * | 2008-12-11 | 2014-04-09 | 花王株式会社 | Antibacterial composition |
| PL2978830T3 (en) | 2013-03-28 | 2019-08-30 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| CA2910881C (en) | 2013-05-24 | 2018-06-26 | The Procter & Gamble Company | Concentrated surfactant composition |
| CN105209587A (en) * | 2013-05-24 | 2015-12-30 | 宝洁公司 | Low PH detergent composition comprising nonionic surfactants |
| CA2910875C (en) | 2013-05-24 | 2018-11-06 | The Procter & Gamble Company | Low ph detergent composition |
| EP3122850A1 (en) | 2014-03-27 | 2017-02-01 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| US9719052B2 (en) | 2014-03-27 | 2017-08-01 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| US9926516B2 (en) * | 2014-06-05 | 2018-03-27 | The Procter & Gamble Company | Mono alcohols for low temperature stability of isotropic liquid detergent compositions |
| EP3152288A1 (en) | 2014-06-06 | 2017-04-12 | The Procter & Gamble Company | Detergent composition comprising polyalkyleneimine polymers |
| WO2016032992A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
| US9951297B2 (en) | 2014-08-27 | 2018-04-24 | The Procter & Gamble Company | Detergent composition compromising a cationic polymer containing a vinyl formamide nonionic structural unit |
| US9771546B2 (en) | 2014-08-27 | 2017-09-26 | The Procter & Gamble Company | Detergent composition comprising a cationic copolymer containing (meth)acrylamide and diallyl dimethyl ammonium chloride |
| US9617501B2 (en) | 2014-08-27 | 2017-04-11 | The Procter & Gamble Company | Method of treating a fabric by washing with a detergent comprising an acrylamide/DADMAC cationic polymer |
| US9850452B2 (en) | 2014-09-25 | 2017-12-26 | The Procter & Gamble Company | Fabric care compositions containing a polyetheramine |
| EP3170884A1 (en) * | 2015-11-20 | 2017-05-24 | The Procter and Gamble Company | Alcohols in liquid cleaning compositions to remove stains from surfaces |
| EP3747414A1 (en) | 2016-08-12 | 2020-12-09 | The Procter & Gamble Company | Method and apparatus for assembling absorbent articles |
| EP3399013B1 (en) | 2017-05-05 | 2022-08-03 | The Procter & Gamble Company | Laundry detergent compositions with improved grease removal |
| EP3399012A1 (en) | 2017-05-05 | 2018-11-07 | The Procter & Gamble Company | Liquid detergent compositions with improved rheology |
| US11944522B2 (en) | 2019-07-01 | 2024-04-02 | The Procter & Gamble Company | Absorbent article with ear portion |
| CA3228918A1 (en) | 2021-08-10 | 2023-02-16 | Nippon Shokubai Co., Ltd. | Polyalkylene-oxide-containing compound |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR241024A1 (en) * | 1981-09-30 | 1991-04-30 | Interox Chemicals Ltd | SUITABLE AQUEOUS HYDROGEN PEROXIDE COMPOSITION FOR DILUTION, TO FORM LIQUID DETERGENT COMPOSITIONS OR BLEACHING COMPOSITIONS, ESSENTIALLY CONSISTING OF (A) 20 TO 35% BY WEIGHT, BASED ON PEROXIDE COMPOSITION, PEROXIDE |
| DE4021265A1 (en) * | 1990-07-04 | 1992-01-09 | Kreussler Chem Fab | Use of satd. sec. branched alcohol - as additive in washing compsn. to reduce foaming |
| ES2062748T3 (en) * | 1991-06-14 | 1994-12-16 | Procter & Gamble | STABLE BLEACHING COMPOSITIONS CONTAINING HYDROGEN PEROXIDE. |
| EP0593841A1 (en) * | 1992-10-23 | 1994-04-27 | The Procter & Gamble Company | Detergent composition with suds suppressing system |
| EP0598973A1 (en) * | 1992-11-26 | 1994-06-01 | The Procter & Gamble Company | Multi-purpose liquid cleaning composition |
| EP0616027A1 (en) * | 1993-03-19 | 1994-09-21 | The Procter & Gamble Company | Concentrated cleaning compositions |
| EP0616026A1 (en) * | 1993-03-19 | 1994-09-21 | The Procter & Gamble Company | Concentrated cleaning compositions |
-
1994
- 1994-06-08 EP EP94201634A patent/EP0666308B1/en not_active Expired - Lifetime
-
1995
- 1995-01-31 JP JP7520693A patent/JPH09508655A/en active Pending
- 1995-01-31 MX MX9603201A patent/MX9603201A/en not_active Application Discontinuation
- 1995-01-31 BR BR9506715A patent/BR9506715A/en not_active Application Discontinuation
- 1995-01-31 CA CA 2182672 patent/CA2182672A1/en not_active Abandoned
- 1995-01-31 WO PCT/US1995/001257 patent/WO1995021233A1/en active Application Filing
- 1995-01-31 CN CN 95192224 patent/CN1144533A/en active Pending
- 1995-01-31 AU AU17378/95A patent/AU701779B2/en not_active Ceased
- 1995-02-01 EG EG9995A patent/EG20508A/en active
-
1996
- 1996-08-02 FI FI963078A patent/FI963078A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107849491A (en) * | 2015-06-05 | 2018-03-27 | 益克林实业有限责任公司 | Multifunction detergent without VOC |
Also Published As
| Publication number | Publication date |
|---|---|
| MX9603201A (en) | 1997-07-31 |
| FI963078A0 (en) | 1996-08-02 |
| JPH09508655A (en) | 1997-09-02 |
| EG20508A (en) | 1999-06-30 |
| FI963078A (en) | 1996-10-01 |
| EP0666308A3 (en) | 1996-06-05 |
| BR9506715A (en) | 1997-09-09 |
| AU1737895A (en) | 1995-08-21 |
| WO1995021233A1 (en) | 1995-08-10 |
| EP0666308B1 (en) | 2000-08-09 |
| EP0666308A2 (en) | 1995-08-09 |
| AU701779B2 (en) | 1999-02-04 |
| CA2182672A1 (en) | 1995-08-10 |
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