CN110272783B - Multifunctional cleaning agent and preparation method thereof - Google Patents
Multifunctional cleaning agent and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/187—Hydrocarbons aromatic
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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Abstract
The invention provides a multifunctional cleaning agent which comprises the following components in parts by weight: 6-9 parts of sodium tripolyphosphate, 6-9 parts of baking soda, 2-5 parts of vinegar, 4-5 parts of isomeric tridecanol, 2-4 parts of a C12-18 branched-chain fatty alcohol-beta-glycol ether and C9-C11 fatty alcohol ethoxylated propoxylate compound, 1-2 parts of dispersant methyl hydroxyethyl deca-carbon isomeric carboxylate, 1-2 parts of glucoside, 3-5 parts of polycarboxylic anhydride and heptylglyco compound, 3-6 parts of an ethoxylated-C12-18-alcohol and ethoxylated propoxylated-C8-10-fatty alcohol compound, 1-2 parts of aromatic hydrocarbon, 0.3-0.4 part of lipase, 0.2-0.3 part of cellulase, 0.3-0.4 part of an anticorrosive raw material and 62.2-64.6 parts of water. The cleaning agent has the effects of decontamination, oil removal, rust removal, wax removal and the like, and has no corrosiveness; especially has unique effect of removing the adhesive sticker.
Description
Technical Field
The invention belongs to the technical field of chemical cleaning, and particularly relates to a multifunctional cleaning agent and a preparation method thereof.
Background
In terms of the principle of the cleaning process and industrial applications, the cleaning technology in the world today can be roughly divided into three types: chemical cleaning, physical cleaning and biological cleaning. The chemical cleaning technology has the longest history, the most varieties and the most extensive application.
The chemical cleaning agent can be roughly three types of organic solvent cleaning agent, water-based cleaning agent and semi-water-based cleaning agent according to the water content of the chemical cleaning agent. The three cleaning agents have advantages and disadvantages, and although some cleaning effects of the organic solvent cleaning agent are achieved, the organic solvent cleaning agent has certain toxicity and pollutes the environment and the air; although the semi-water-based cleaning agent has a good cleaning effect, the cost is high, the raw material matching and the process are not in place during the manufacturing, and the product is easy to layer; the water-based cleaning agent has obvious effect, but high alkalinity, limited application range and more foams, and is easy to generate scaling when used for cleaning metal materials. The cleaning agent has three main categories of alkalinity, acidity and neutrality in common people meaning. Both alkaline and acidic cleaning agents have pungent smell, even generate toxic gas, are not environment-friendly, and have great limitation on cleaning products, so that the alkaline and acidic cleaning agents are almost special cleaning agents with single effect in the world at present and do not have a real multifunctional cleaning agent.
Chinese patent CN201610438257.4 discloses a street lamp cleaning agent and a preparation method thereof, wherein the street lamp cleaning agent comprises the following components in parts by mass: 20-30 parts of sodium carbonate, 5-10 parts of sodium bicarbonate, 8-10 parts of acetone, 15-20 parts of acetic acid, 5-8 parts of boric acid, 10-15 parts of polyethylene frosted particles, 5-8 parts of a chemical thickening agent, 8-10 parts of sodium citrate, 1-3 parts of sodium aliphatate, 0.1-0.3 part of copper sulfate and 40-50 parts of water, wherein the polyethylene frosted particles are 100-200 meshes, the water is deionized water, and the chemical thickening agent is a mixture of sodium polyacrylate and polyvinyl alcohol. This street lamp cleaner can clear away the stubborn spot on street lamp surface fast high-efficiently, need not use the brush only need use soft cotton or sponge, and the polyethylene dull polish granule that contains in the decontaminant can carry out soft polishing to the lacquer painting, and no matter dust or organic matter can all clear away totally and do not keep the dead angle, and this cleaner does not contain strong acid alkali simultaneously, can not cause the lacquer painting to discolour with the lacquer painting contact.
In the prior art, although sodium bicarbonate and vinegar are used together to prepare a neutral cleaning agent, the heavy oil dirt is difficult to remove only by matching the two main raw materials with an anion active agent, a nonionic active agent and the like, and the capacity can be improved after sodium tripolyphosphate is added. Sodium bicarbonate is alkalescent and can only remove light oil stains when used together with vinegar, and sodium tripolyphosphate can increase alkalinity, improve the capability of removing heavy oil stains and simultaneously enable the sodium bicarbonate to reach a neutral product, which is one of innovation points; secondly, the surfactant selected by the application is a new product of manufacturers, is green and environment-friendly, has various functions, and is irreplaceable by a plurality of original surfactants. Thirdly, in order to make the product have wider neutral use and environmental protection and multiple functions, the formula of the cleaning agent is scientific, and the technologies of biological enzyme, aromatic hydrocarbon extraction and the like are also used, so that innovation points are enhanced, and the industrial problems of neutral cleaning agent and high cost are solved. The cationic synergist is added in the formula of the paint, so that the heavy oil stain removal capability is greatly improved, and the secondary high-speed stirring of the raw materials ensures the uniformity of the distribution of the raw materials and avoids the innovation point of product layering.
The neutral multifunctional cleaning agent produced by the application has a pH value of 7-8, fully integrates the advantages of three types of cleaning agents, avoids the defects and shortcomings, starts from the aspects of formula and process, selects nontoxic and harmless raw materials according to the basic principle of green chemistry, and is prepared by organically compounding an anion and a nonionic surfactant. Has strong degreasing capability and can be biodegraded after being used. Can realize good cleaning effect on different types of oil dirt and objects made of different materials.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a multifunctional cleaning agent and a preparation method thereof.
The multifunctional cleaning agent comprises the following components in parts by weight:
sodium tripolyphosphate (Na)5P3O10) 6-9 parts of baking soda (NaHC 0)3) 6-9 parts of vinegar, 2-5 parts of isomeric tridecanol, 4-5 parts of C12-18 branched-chain fatty alcohol-beta-glycol ether and C9-C11 fatty alcohol ethoxylated propoxylate compound, 1-2 parts of dispersant methyl hydroxyethyl deca-isomeric carboxylate, 1-2 parts of glucoside APG, 3-5 parts of polycarboxylic anhydride and heptyl glycyl compound PH-E, 3-6 parts of ethoxylated-C12-18-alcohol and ethoxylated propoxylate-C8-10-fatty alcohol compound, 1-2 parts of aromatic hydrocarbon, 0.3-0.4 part of lipase, 0.2-0.3 part of cellulase, 0.3-0.4 part of preservative raw material and 62.2-64.6 parts of water.
0.1-0.3 part of essence, preferably lemon essence, can also be added into the cleaning agent.
Wherein the vinegar is edible white vinegar, and the mass content of acetic acid is 3-5%.
Wherein the mass ratio of the C12-18 branched chain fatty alcohol-beta-glycol ether to the C9-C11 fatty alcohol ethoxylation propoxylate in the C12-18 branched chain fatty alcohol-beta-glycol ether and C9-C11 fatty alcohol ethoxylation propoxylate compound is 1: (2-4).
Wherein the mass ratio of the ethoxylated-C12-18-alcohol to the ethoxylated propoxylated-C8-10-fatty alcohol in the ethoxylated-C12-18-alcohol and ethoxylated propoxylated-C8-10-fatty alcohol compound is 1: (2-5).
Wherein the isomeric tridecanol is a nonionic surfactant HF302B produced by Shenzhen Jiening science and technology Limited, and the methyl hydroxyethyl decacarbon isomeric carboxylate is a nonionic surfactant DS30 produced by Shenzhen Jiening science and technology Limited;
wherein the polycarboxylic anhydride and the heptylglycyl compound are anionic surfactants produced by Shenzhenlongqiang science and technology Limited.
The aromatic hydrocarbon is preferably aromatic hydrocarbon No. 6, and the aromatic hydrocarbon and the glucoside are produced by Guangzhou Chongqing chemical industry Co.
The antiseptic raw material is preferably methyl isothiazolinone (also called methyl isothiazolinone) produced by Jinan Delan company.
The preparation method of the multifunctional cleaning agent comprises the following steps:
(1) firstly, water and sodium tripolyphosphate Na5P3O10Edible sodium bicarbonate NaHCO3And adding vinegar into a heating mixing tank, stirring, heating to 80-90 deg.C to dissolve the materials, and stirring; adopting an upper and lower double-blade stirrer, regulating the rotating speed to 80-100 rpm, stirring for 5-9 minutes, and then electrically heating and closing;
(2) then putting the compounded C12-18 branched chain fatty alcohol-beta-glycol ether, C9-C11 fatty alcohol ethoxylation propoxylate compound, HF302B isomeric tridecanol and DS30 methyl hydroxyethyl decacarbon isomeric carboxylate into a batching cylinder, and adjusting the rotating speed of a stirrer to 120-140 revolutions per minute for stirring for 10-15 minutes;
(3) putting a compound of decontaminated ethoxylation-C12-18-alcohol and ethoxylation propoxylation-C8-10-fatty alcohol and a raw material of Lipase (Lipase) cellulase (cellalase) into a cylinder, and stirring for 5-10 minutes;
(4) putting the raw materials compounded by the dispersant PH-E polycarboxylic anhydride, the heptylglycylglycerol compound and the glucose glycylglycerol (APG) into a batching cylinder, and stirring for 5-10 minutes;
(5) then adding aromatic hydrocarbon and antiseptic raw materials, adjusting the rotating speed to 180-230 rpm, and stirring for 15-20 minutes to obtain the finished product.
When essence is required to be added, the mixture is finally put into a dosing cylinder to be stirred for 5 minutes.
The cleaning agent is non-toxic and harmless, the raw materials are matched around a green and environment-friendly route, a double-raw-material compounding technology is adopted according to the performance action of the selected raw materials, and after each component of the raw materials are compounded and stirred according to the components, the technological process of secondary stirring is integrated, so that the effect of the raw materials is ensured to be exerted, and the raw materials are sequentially added in sequence during feeding.
The invention has the following main beneficial effects:
(1) the formula is screened by adopting a single-factor experiment, the optimal proportion of the multifunctional cleaning agent is determined by adopting an orthogonal experiment, and more than sixty kinds of single and compound surfactants are repeatedly screened, and theoretical calculation and experimental verification of HLB (hydrophile-lipophile balance) values are carried out, so that the compound of the nonionic surfactant, the anionic surfactant and the like is found to obviously improve the decontamination value, have the effects of removing oil, rust, wax and the like and almost have no corrosiveness.
(2) The organic combination of the surfactant, the APG as main anion-nonionic surfactant and the cationic surfactant has excellent compatibility with other components, and can effectively improve the degreasing rate of the nonionic surfactant.
(3) By adopting multiple double-raw material and multi-raw material compounding technologies and formula compatibility, the oil removing and stain removing agent has strong oil removing and stain removing capabilities, can also improve the uniformity and corrosion resistance of a film, improves the surface cleanliness and brightness, and has multiple functions. The adaptability is wider.
(4) The compound of the isomeric tridecanol, the C12-18 branched chain fatty alcohol-beta-glycol ether, the C9-C11 fatty alcohol ethoxylation propoxylate compound and the compound of the ethoxylation-C12-18-alcohol and ethoxylation propoxylation-C8-10-fatty alcohol mainly have the functions of promoting penetration, wetting, emulsification and dispersion.
(5) The HP-E and APG are compounded to accelerate the speed of rust removal and wax removal.
(6) The main functions of the ethoxylated-C12-18-ol and ethoxylated propoxylated-C8-10-fatty alcohol combination, Lipase and Cellulase combination are the removal of the heavy grime and the increase in the gloss of the cleaned substrate.
(7) The aromatic hydrocarbon has the main functions of extracting oil dirt permeating into an object after emulsification and dispersion to the surface of the object, the pH value of a product is 7-8, the total active agent accounts for 13-17%, and the aromatic hydrocarbon can be widely used for cleaning the surfaces of glass products, wood products, plastic rubber products, aluminum alloy products, metal materials, floor tiles, ceramics, leather products and cloth materials, and the oil dirt is aged for 24 hours and the detergency is 100% after field use and detection; the dirt is aged for 24 hours, the detergency is 98 percent, and the cleaning agent has a unique effect especially on the function of removing self-adhesive sticker (psoriasis), and the project technology fills up the domestic blank.
(8) The methylisothiazole (also called methylisothiazolinone) has good antiseptic and quality-keeping effects on neutral products.
(9) On the premise of fully ensuring the cleaning effect of the multifunctional cleaning agent product, the product is finally neutral by utilizing the scientific collocation of the alkaline raw materials and the acidic raw materials, so that the problem of high cost of the neutral product is solved, the product has good efficacy and wide and perfect application.
(10) The product of the invention has the characteristics of excellent effect: the main raw materials of the degreasing agent are sodium tripolyphosphate, sodium bicarbonate and edible vinegar which are combined fully, the degreasing capability is improved, and the active agents for penetration, emulsification and dispersion are also a HF302B, C12-18 branched chain fatty alcohol-beta-glycol ether, C9-C11 fatty alcohol ethoxylation propoxylate compound, DS30 and the like, so that the penetration, emulsification and dispersion effects are ensured, and the three active agents for degreasing are also achieved; the whole formula of the ethoxylation-C12-18-alcohol and ethoxylation propoxylation-C8-10-fatty alcohol compound and lipase cellulase is basically realized by compounding two or three raw materials, and the double dispersant is used together with the dispersant to ensure the effect.
(11) The product is dropped into a goldfish tank with 5 ml of water, the goldfish still actively swims after 8 hours, and the product meets the standard requirements according to GB/T9985-2000 (detergent for washing tableware by hand) and GB14930.1-2015 national standard for food safety detergent inspection by the quality supervision and inspection research institute of manufacturers in Hunan province.
Detailed description of the preferred embodiments
The present invention will be further described with reference to examples, and tables 1 to 2 show compositions of cleaning agents of examples 1 to 6 and comparative examples 1 to 4.
The vinegar described in the examples and comparative examples is edible white vinegar, and the mass content of acetic acid is 4%.
The component A is a compound of C12-18 branched chain fatty alcohol-beta-glycol ether and C9-C11 fatty alcohol ethoxylation propoxylate, and the compounding ratio is 1: 3.
The component B is a compound of ethoxylated-C12-18-alcohol and ethoxylated propoxylated-C8-10-fatty alcohol, wherein the mass ratio of the ethoxylated-C12-18-alcohol to the ethoxylated propoxylated-C8-10-fatty alcohol is 1: 4; the aromatic hydrocarbon is aromatic hydrocarbon No. 6.
Table 1 examples 1-5 compositions of cleaning agents
TABLE 2 compositions of cleaning agents of example 6 and comparative examples 1 to 4
Component A of comparative example 1 is C12-18 branched fatty alcohol- β -glycol ether, the other is the same as in example 6; comparative example 2, component A, C9-C11 fatty alcohol ethoxylated propoxylate, was otherwise the same as in example 6; component B of comparative example 3 was ethoxylated-C12-18-ol, the other was the same as in example 6; component B of comparative example 4 was an ethoxylated propoxylated-C8-10-fatty alcohol, the other things being the same as in example 6.
The preparation method of the above example is as follows:
the preparation method of the multifunctional cleaning agent comprises the following steps:
(1) firstly, water and sodium tripolyphosphate Na5P3O10Edible sodium bicarbonate NaHCO3And adding vinegar into a heating mixing tank, heating to 85-90 deg.C to dissolve the materials, and stirring; adopting an upper and lower double-blade stirrer, adjusting the rotating speed to 85 rpm, stirring for 5 minutes, and then electrically heating and closing;
(2) then putting the compounded C12-18 branched chain fatty alcohol-beta-glycol ether, C9-C11 fatty alcohol ethoxylation propoxylate compound, HF302B isomeric tridecanol and DS30 methyl hydroxyethyl deca-isomeric carboxylate into a proportioning cylinder, and adjusting the rotating speed of a stirrer to 130 revolutions per minute for stirring for 10 minutes;
(3) putting a compound of decontaminated ethoxylation-C12-18-alcohol and ethoxylation propoxylation-C8-10-fatty alcohol and a raw material of Lipase (Lipase) cellulase (cellalase) into a cylinder, and stirring for 5 minutes;
(4) putting the raw materials compounded by the dispersant PH-E polycarboxylic anhydride, the heptylglycylglycerol compound and the glucoglycylglycerol (APG) into a batching cylinder, and stirring for 5 minutes;
(5) then adding aromatic hydrocarbon and anticorrosive raw materials, regulating the rotation speed to 200 revolutions per minute, and stirring for 15 minutes; when essence is required to be added, the mixture is finally put into a proportioning cylinder to be stirred for 5 minutes, and a finished product is obtained.
The effects of the use of examples 1 to 6 and comparative examples 1 to 4 are shown in Table 3.
TABLE 3 effects of Using examples 1 to 6 and comparative examples 1 to 4
As can be seen from the results of the cleaning agents of example 6 and comparative examples 1-4 in Table 2, in the formulation system of the present application, the C12-18 branched chain fatty alcohol- β -glycol ether and the C9-C11 fatty alcohol ethoxylated propoxylate have a synergistic effect, and the ethoxylated-C12-18-alcohol and the ethoxylated propoxylated-C8-10-fatty alcohol have a synergistic effect.
The embodiments of the application meet the standard requirements according to GB/T9985-2000 (detergent for washing tableware by hand) and GB14930.1-2015 national standard for food safety detergent inspection by the quality supervision and inspection research institute of manufacturers in Hunan province;
the test method of the above test items is as follows:
1. the results of 6 small samples of the ratio of the raw materials charged in the respective formulations of examples 1 to 6 are shown in the effects of examples 1 to 6 and comparative examples 1 to 4. 2. In order to realize the multifunction of the product in a real sense that the application range of the product is not limited and the application is wide, the pH value of a small sample of each product is detected, and the pH value between 7 and 8 is the most ideal neutral product. 3. The product has good and obvious effect of removing heavy oil dirt on the kitchen range hood after being used on the spot in restaurants and hotels. The dirt removal detection shows that the cleaning effect of the unwashed outer wall for years is very good, and the tile with low gloss can be cleaned completely and can also recover new gloss. 4. The rust on the surface of the metal is sprayed and wiped in an open-air field, the effect is obvious, and the rust removing effect is excellent. 5. After the adhesive sticker adlets (psoriasis) on the outer wall and the telegraph pole are directly sprayed with the product of the invention, the adhesive sticker adlets can be easily and completely wiped off by a towel. 6. In order to realize the perfection of multiple functions and low cost of a neutral product, the formula is continuously modified, the neutral product is originally prepared by adopting a single raw material, the cost is higher, and the effect is not ideal. Such as: the sodium tripolyphosphate serving as the main raw material is singly used, the addition amount of the sodium tripolyphosphate is more than 13 percent, the cost is reduced after the sodium bicarbonate and the white vinegar are added to the heavy oil dirt, the penetrating of the activator is carried out, the C12-18 branched-chain fatty alcohol-beta-glycol ether, the C9-C11 fatty alcohol ethoxylation propoxylate compound, HF302B and DS30, which have the emulsifying and dispersing functions, are compounded by any one independent raw material and the main material, the addition ratio is high, the ideal effect cannot be achieved, the cost is low and the effect is obvious after three kinds of compounding, and the rust removing and dirt removing raw materials are also the same, so the effect of the single raw material is proved to be not as good as the effect of compounding two or three kinds of raw materials by practice. 7. Good formulation also requires good process support, and it is also important to dose the ingredients in sequence. According to the formula of the invention, firstly, the trimerization and the baking soda are put in, heated and stirred, after the raw materials are fully dissolved, the electric heating is turned off, then the white vinegar and the active agent are put in, namely the normal temperature of the raw materials is not influenced (the components of the raw materials are not changed by high temperature), and the product is not layered, conversely, the active agent, the sodium tripolyphosphate and the baking soda are put in firstly, and the stirring is carried out at the normal temperature, so that the raw materials of the two powders can not be fully dissolved, the product is layered, and the pH value is not accurate.
Claims (2)
1. The multifunctional cleaning agent is characterized by being prepared from the following components in parts by mass: 7 parts of sodium tripolyphosphate, 6 parts of baking soda, 5 parts of vinegar, 4 parts of isomeric tridecanol, 3 parts of a C12-18 branched-chain fatty alcohol-beta-glycol ether and C9-C11 fatty alcohol ethoxylated propoxylate compound, 2 parts of a dispersant methyl hydroxyethyl deca-carbon isomeric carboxylate, 2 parts of glucoside, 4 parts of polycarboxylic anhydride and heptyl glucoside compounds, 4 parts of an ethoxylated-C12-18-alcohol and ethoxylated propoxylate-C8-10-fatty alcohol compound, 1 part of aromatic hydrocarbon No. 6, 0.3 part of lipase, 0.3 part of cellulase, 0.3 part of a preservative raw material methylisothiazolinone, 60.2 parts of water and 0.2 part of lemon essence;
wherein the mass ratio of the C12-18 branched chain fatty alcohol-beta-glycol ether to the C9-C11 fatty alcohol ethoxylated propoxylate is 1: 3;
wherein the mass ratio of the ethoxylated-C12-18-alcohol to the ethoxylated propoxylated-C8-10-fatty alcohol is 1: 4;
the vinegar is edible white vinegar, and the mass content of acetic acid is 4%;
the methyl hydroxyethyl decacarbon isomeric carboxylate is a surfactant DS30 produced by Shenzhen Jiening science and technology Limited.
2. The preparation method of the multifunctional cleaning agent as claimed in claim 1, which is characterized by comprising the following steps in sequence:
(1) firstly, adding water and sodium tripolyphosphate, baking soda and vinegar into a heating dosing cylinder for stirring, adjusting the temperature of the dosing cylinder to 80-90 ℃ to fully dissolve the raw materials, and uniformly stirring; adopting an upper and lower double-blade stirrer, regulating the rotating speed to 80-100 rpm, stirring for 5-9 minutes, and then electrically heating and closing;
(2) then putting the compounded C12-18 branched chain fatty alcohol-beta-glycol ether, C9-C11 fatty alcohol ethoxylation propoxylate compound, isomeric tridecanol and methyl hydroxyethyl deca-isomeric carboxylate into a proportioning cylinder, and adjusting the rotating speed of a stirrer to 120-140 revolutions per minute for stirring for 10-15 minutes;
(3) putting the decontaminated ethoxylation-C12-18-alcohol and ethoxylation propoxylation-C8-10-fatty alcohol compound, lipase and cellulose raw materials into a dosing cylinder, and stirring for 5-10 minutes;
(4) putting raw materials compounded by dispersant polycarboxylic anhydride, heptyl glycoside compounds and glucoside into a mixing cylinder, and stirring for 5-10 minutes;
(5) then adding aromatic hydrocarbon and antiseptic material methylisothiazolinone, adjusting the rotating speed to 180-230 r/min, and stirring for 15-20 min to obtain the finished product.
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| CN104130872A (en) * | 2014-07-16 | 2014-11-05 | 司徒建辉 | Special-purposed high-efficiency cleaning agent for automotive glass |
| CN107057888A (en) * | 2017-06-17 | 2017-08-18 | 安徽方翔羽绒制品有限公司 | A kind of preparation method of feather products cleaning agent |
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| CN102399642B (en) * | 2011-09-27 | 2014-07-09 | 英特沃斯(北京)科技有限公司 | Neutral cleaning agent and preparation method thereof |
| CN102517175B (en) * | 2011-11-23 | 2013-10-16 | 上海应用技术学院 | Neutral liquid cleaning agent for outside surface of bullet train and preparation method and applications thereof |
| CN102676317B (en) * | 2012-05-07 | 2013-06-05 | 安徽绿朋实业有限公司 | Multifunctional water-based oil-stain cleaning agent of automobile parts and preparation method thereof |
| CN103756798B (en) * | 2014-01-13 | 2017-02-15 | 沈阳追梦蓝环保科技有限公司 | Anion-cation exchange resin cleaning agent |
| CN107287046B (en) * | 2016-04-01 | 2020-04-17 | 深圳市芭格美生物科技有限公司 | Biological enzyme cleaning solution for infant clothes and preparation method thereof |
| CN107760459B (en) * | 2016-08-16 | 2020-08-04 | 蓝思科技股份有限公司 | Cleaning agent for cleaning glass after UV (ultraviolet) wire drawing |
| CN109536294B (en) * | 2018-03-16 | 2021-10-08 | 东莞市华启清洗剂科技有限公司 | Environment-friendly water-based cleaning agent |
| CN108865539A (en) * | 2018-07-06 | 2018-11-23 | 安徽腾奎智能科技有限公司 | Medical X-ray photo-electric display cleaning agent |
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| CN104130872A (en) * | 2014-07-16 | 2014-11-05 | 司徒建辉 | Special-purposed high-efficiency cleaning agent for automotive glass |
| CN107057888A (en) * | 2017-06-17 | 2017-08-18 | 安徽方翔羽绒制品有限公司 | A kind of preparation method of feather products cleaning agent |
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