CN110172378A - Antimicrobial form oil smoke detergent - Google Patents

Antimicrobial form oil smoke detergent Download PDF

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Publication number
CN110172378A
CN110172378A CN201910479303.9A CN201910479303A CN110172378A CN 110172378 A CN110172378 A CN 110172378A CN 201910479303 A CN201910479303 A CN 201910479303A CN 110172378 A CN110172378 A CN 110172378A
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CN
China
Prior art keywords
parts
form oil
oil smoke
antimicrobial form
detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910479303.9A
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Chinese (zh)
Inventor
高强
沈开成
吴耀举
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84 Ltd By Share Ltd Jiangsu
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84 Ltd By Share Ltd Jiangsu
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Publication date
Application filed by 84 Ltd By Share Ltd Jiangsu filed Critical 84 Ltd By Share Ltd Jiangsu
Priority to CN201910479303.9A priority Critical patent/CN110172378A/en
Publication of CN110172378A publication Critical patent/CN110172378A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/185Hydrocarbons cyclic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of antimicrobial form oil smoke detergents, it is mixed with by the raw material of following weight: 2 ~ 4 parts of isomeric alcohol polyethenoxy ether, 0.4 ~ 0.8 part of Nano silver solution, 3 ~ 6 parts of propylene glycol monomethyl ether, 0.5 ~ 3 part of alkyl benzene sulphonate, 0.1 ~ 1 part of EDTA-2Na, 0.1 ~ 0.3 part of xanthan gum, 1 ~ 3 part of D- limonene, 1 ~ 3 part of chitosan, 79 ~ 90 parts of deionized water.Two or more surfactants are used in formula of the invention, clean effect is more preferable, meanwhile, by the addition of Nano silver solution and chitosan, assign the good anti-microbial property of detergent.

Description

Antimicrobial form oil smoke detergent
Technical field
The invention belongs to field of fine chemical, are related to household chemicals, and in particular to a kind of antimicrobial form oil smoke detergent.
Background technique
Kitchen fume detergent belongs to heavy-dirty liquid-detergent, usually contains strong basicity auxiliary agent and propylene glycol alkyl ether solvent, Selected surfactant is from sodium alkyl benzene sulfonate to alkyl glycosides, nonylphenol polyoxyethylene ether has;Dosage form is usually liquid Body, when use, which generally places it in sprayer, is sprayed at smoke exhaust ventilator, kitchen range and kitchen tile surface, then with paper or smears Cloth is wiped;Kitchen easily pollutes bowls and chopsticks due to the oil smoke generated when cooking food and the food materials being scattered bacterium easy to breed, It causes damages to human body.Traditional kitchen fume detergent is typically only capable to removal in smoke exhaust ventilator, kitchen range and kitchen tile table The greasy dirt in face cannot inhibit bacterium.
Summary of the invention
In view of the deficiencies of the prior art, of the invention the purpose of the present invention is to provide a kind of antimicrobial form oil smoke detergent Two or more surfactants are used in formula, clean effect is more preferable, meanwhile, by the addition of Nano silver solution and chitosan, Assign the good anti-microbial property of detergent.
The present invention is achieved by the following technical solutions:
Antimicrobial form oil smoke detergent, is mixed with by the raw material of following weight: isomeric alcohol polyethenoxy ether 2 ~ 4 Part, it is 0.4 ~ 0.8 part of Nano silver solution, 3 ~ 6 parts of propylene glycol monomethyl ether, 0.5 ~ 3 part of alkyl benzene sulphonate, 0.1 ~ 1 part of EDTA-2Na, yellow 0.1 ~ 0.3 part of virgin rubber, 1 ~ 3 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, 1 ~ 3 part of chitosan, 79 ~ 90 parts of deionized water.
Further, the isomeric alcohol polyethenoxy ether is heterogeneous ten alcohol polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene One of ether or isomerous tridecanol polyoxyethylene ether.
Further, the isomeric alcohol polyethenoxy ether is isomerous tridecanol polyoxyethylene ether.
Further improvement of the present invention scheme are as follows:
The antimicrobial form oil smoke detergent, is mixed with by the raw material of following weight: isomerous tridecanol polyoxy second 3 parts of alkene ether, 0.8 part of Nano silver solution, 4 parts of propylene glycol monomethyl ether, 2 parts of alkyl benzene sulphonate, 1 part of EDTA-2Na, 0.2 part of xanthan gum, 1 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, 3 parts of chitosan, 85 parts of deionized water.
Further improvement project of the invention are as follows:
The antimicrobial form oil smoke detergent, is mixed with by the raw material of following weight: isomerous tridecanol polyoxy second 4 parts of alkene ether, 0.4 part of Nano silver solution, 6 parts of propylene glycol monomethyl ether, 1 part of alkyl benzene sulphonate, 0.2 part of EDTA-2Na, xanthan gum 0.3 Part, 3 parts of (R)-4-isopropenyl-1-methyl-1-cyclohexene, 2 parts of chitosan, 83.1 parts of deionized water.
Further, the step of preparing antimicrobial form oil smoke detergent is to weigh each raw material by above-mentioned weight, first After deionized water and EDTA-2Na are stirred and evenly mixed, alkyl benzene sulphonate and isomerous tridecanol polyoxyethylene are sequentially added under stiring Ether, propylene glycol monomethyl ether, chitosan and Nano silver solution, (R)-4-isopropenyl-1-methyl-1-cyclohexene and xanthan gum, by material after mixing to get antimicrobial form Oil smoke detergent during charging, often adds a kind of or one group of raw material, adds a kind of lower or next group of raw material after being sufficiently stirred again.
The invention has the benefit that
It is living using anion-nonionic surface using isomery alcohol ether and alkyl benzene sulphonate as bleeding agent and degreaser in formula of the invention Property agent synergistic effect, by the isomery alcohol ether in alkyl benzene sulphonate and formula, compatibility can be improved the dirt-removing power of detergent, changes The foaming properties of kind nonionic surfactant, the freeze-thaw stability for improving product also reduce the minimum film forming temperature of product simultaneously Degree;
Xanthan gum is used in formula of the invention, can be increased the wall built-up of product, be facilitated decontamination;
Isomerous tridecanol polyoxyethylene ether used in inventive formulation.It has emulsifying capacity strong, high surface activity, resists hard Water, chemical stability and Environmental compatibility are good in wider pH range, have degreasing effect;
Gluey grease cross-linking agent after propylene glycol monomethyl ether used in inventive formulation itself is especially crosslinked grease has preferably Dissolution and peptizaiton, also function to reduce minimum film formation temperature, improve water resistance and improve freeze-thaw stability effect, also have There is friendly smell;
(R)-4-isopropenyl-1-methyl-1-cyclohexene used in inventive formulation has fresh orange fragrance and lemon sample fragrance, while can remove viscose glue, no The macromolecules resinous matter such as dry glue, effect is fine, and environment-protecting industrial cleaning agent well, both enhances the ability of deoiling, together When can also assign product pleasant smell;
Antipathogenic composition Nano silver solution and chitosan used in inventive formulation, compatibility form chitosan nano silver solution, assign Give the good antimicrobial form of product.
To sum up, antimicrobial form oil smoke detergent provided by the invention, the effect of antibacterial can be increased while degreasing, Clean effect is more preferable, and smell faint scent.The detergent is of less demanding for wash temperature and water quality, under low temperature and hard water Also there is good detergency, dosage is few, and effect is good.
Specific embodiment
Embodiment 1
Following weight weight weighs each raw material: 3 parts of isomerous tridecanol polyoxyethylene ether, Nano silver solution 0.8 Part, 4 parts of propylene glycol monomethyl ether, 2 parts of alkyl benzene sulphonate, 1 part of EDTA-2Na, 0.2 part of xanthan gum, 1 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, chitosan 3 Part, 85 parts of deionized water.
After first stirring and evenly mixing deionized water and EDTA-2Na, alkyl benzene sulphonate and isomery ten are sequentially added under stiring Triol polyoxyethylene ether, propylene glycol monomethyl ether, chitosan and Nano silver solution, (R)-4-isopropenyl-1-methyl-1-cyclohexene and xanthan gum, material is uniformly mixed Afterwards to get antimicrobial form oil smoke detergent, during charging, a kind of or one group of raw material is often added, it is again plus lower a kind of after being sufficiently stirred Or next group of raw material.
Embodiment 2
Following weight weight weighs each raw material: 4 parts of isomerous tridecanol polyoxyethylene ether, Nano silver solution 0.4 Part, 6 parts of propylene glycol monomethyl ether, 1 part of alkyl benzene sulphonate, 0.2 part of EDTA-2Na, 0.3 part of xanthan gum, 3 parts of (R)-4-isopropenyl-1-methyl-1-cyclohexene, chitosan 2 Part, 83.1 parts of deionized water.
The preparation method is the same as that of Example 1.
Embodiment 3
Following weight weight weighs each raw material: 2 parts of isomerous tridecanol polyoxyethylene ether, Nano silver solution 0.6 Part, 5 parts of propylene glycol monomethyl ether, 3 parts of alkyl benzene sulphonate, 0.5 part of EDTA-2Na, 0.1 part of xanthan gum, 2 parts of (R)-4-isopropenyl-1-methyl-1-cyclohexene, chitosan 1 Part, 85.8 parts of deionized water.
The preparation method is the same as that of Example 1.
Embodiment 4: comparative experiments
Antibiotic property comparison
Respectively using antimicrobial form oil smoke detergent made from embodiment 1 to 3, and the general kitchen oil smoke cleaning to be sold on market Agent as a control group, carries out detecting its sterilizing rate, the results are shown in Table 1 according to WS/T650-2019 standard.
1 antibiotic property correlation data of table
Number Embodiment 1 Embodiment 2 Embodiment 3 It is commercially available
Sterilizing rate 99.3% 98.1% 96.5% 0
As shown in Table 1, the sterilizing rate of antimicrobial form oil smoke detergent made from embodiment 1 to 3 has reached 99.3%, has excellent Antibacterial effect.And general kitchen oil smoke detergent as a control group, sterilizing rate are essentially 0.
Detergency comparison
Respectively using antimicrobial form oil smoke detergent made from embodiment 1 to 3, and the general kitchen oil smoke cleaning to be sold on market Agent as a control group, detects its detergency, the results are shown in Table 2.
2 detergency correlation data of table
Grease is aged for 24 hours Grease is aged 168h
It is commercially available 92% 81%
Embodiment 1 100% 93%
Embodiment 2 99.6% 91.2%
Embodiment 3 99% 90%
As shown in Table 2, antimicrobial form oil smoke detergent clean effect provided by the invention is more preferable.

Claims (5)

1. antimicrobial form oil smoke detergent, which is characterized in that be mixed with by the raw material of following weight: isomery alcohol is poly- 2 ~ 4 parts of ethylene oxide ether, 0.4 ~ 0.8 part of Nano silver solution, 3 ~ 6 parts of propylene glycol monomethyl ether, 0.5 ~ 3 part of alkyl benzene sulphonate, EDTA-2Na 0.1 ~ 1 part, 0.1 ~ 0.3 part of xanthan gum, 1 ~ 3 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, 1 ~ 3 part of chitosan, 79 ~ 90 parts of deionized water.
2. antimicrobial form oil smoke detergent according to claim 1, it is characterised in that: the isomeric alcohol polyethenoxy ether is different One of ten alcohol polyoxyethylene ether of structure, isomery undecyl alcohol polyoxyethylene ether or isomerous tridecanol polyoxyethylene ether.
3. antimicrobial form oil smoke detergent according to claim 2, it is characterised in that: the isomeric alcohol polyethenoxy ether is different Structure tridecanol polyoxyethylene ether.
4. according to claim 1 or antimicrobial form oil smoke detergent described in 3 any one, it is characterised in that: the antimicrobial form oil Cigarette detergent is mixed with by the raw material of following weight: 3 parts of isomerous tridecanol polyoxyethylene ether, nano silver is molten 0.8 part of liquid, 4 parts of propylene glycol monomethyl ether, 2 parts of alkyl benzene sulphonate, 1 part of EDTA-2Na, 0.2 part of xanthan gum, 1 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, shell is poly- 3 parts, 85 parts of deionized water of sugar.
5. according to claim 1 or antimicrobial form oil smoke detergent described in 3 any one, it is characterised in that: the antimicrobial form oil Cigarette detergent is mixed with by the raw material of following weight: 4 parts of isomerous tridecanol polyoxyethylene ether, nano silver is molten 0.4 part of liquid, 6 parts of propylene glycol monomethyl ether, 1 part of alkyl benzene sulphonate, 0.2 part of EDTA-2Na, 0.3 part of xanthan gum, 3 parts of (R)-4-isopropenyl-1-methyl-1-cyclohexene, shell 2 parts of glycan, 83.1 parts of deionized water.
CN201910479303.9A 2019-06-04 2019-06-04 Antimicrobial form oil smoke detergent Pending CN110172378A (en)

Priority Applications (1)

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CN201910479303.9A CN110172378A (en) 2019-06-04 2019-06-04 Antimicrobial form oil smoke detergent

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Application Number Priority Date Filing Date Title
CN201910479303.9A CN110172378A (en) 2019-06-04 2019-06-04 Antimicrobial form oil smoke detergent

Publications (1)

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CN110172378A true CN110172378A (en) 2019-08-27

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112143583A (en) * 2020-10-10 2020-12-29 苏州特密达新材料有限公司 Semi-aqueous cleaning agent containing nano silver
CN115404133A (en) * 2021-05-28 2022-11-29 广州大白生物科技有限公司 Greasy dirt detergent without nose prick and its prepn

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725440A (en) * 2013-12-31 2014-04-16 中国船舶重工集团公司第七一八研究所 Cleaning agent for automobile
CN104419551A (en) * 2013-08-28 2015-03-18 青岛医防消毒专业技术中心 Chef working clothes dedicated sterilizing and oil stain-removing washing liquid
CN104498204A (en) * 2014-11-27 2015-04-08 江苏雪豹日化有限公司 Bio-enzyme bacteriostatic oil stain-emulsifying preparation
CN106995750A (en) * 2017-04-11 2017-08-01 冯恩芳 A kind of low alkaline Retrieve beer bottle special purpose detergent
CN109294754A (en) * 2018-10-23 2019-02-01 湖北天喜达生物科技有限公司 Antifouling environmentally friendly greasy dirt cleanser of a kind of antibacterial and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104419551A (en) * 2013-08-28 2015-03-18 青岛医防消毒专业技术中心 Chef working clothes dedicated sterilizing and oil stain-removing washing liquid
CN103725440A (en) * 2013-12-31 2014-04-16 中国船舶重工集团公司第七一八研究所 Cleaning agent for automobile
CN104498204A (en) * 2014-11-27 2015-04-08 江苏雪豹日化有限公司 Bio-enzyme bacteriostatic oil stain-emulsifying preparation
CN106995750A (en) * 2017-04-11 2017-08-01 冯恩芳 A kind of low alkaline Retrieve beer bottle special purpose detergent
CN109294754A (en) * 2018-10-23 2019-02-01 湖北天喜达生物科技有限公司 Antifouling environmentally friendly greasy dirt cleanser of a kind of antibacterial and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112143583A (en) * 2020-10-10 2020-12-29 苏州特密达新材料有限公司 Semi-aqueous cleaning agent containing nano silver
CN115404133A (en) * 2021-05-28 2022-11-29 广州大白生物科技有限公司 Greasy dirt detergent without nose prick and its prepn

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Application publication date: 20190827

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