CN106995750A - A kind of low alkaline Retrieve beer bottle special purpose detergent - Google Patents

A kind of low alkaline Retrieve beer bottle special purpose detergent Download PDF

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Publication number
CN106995750A
CN106995750A CN201710231785.7A CN201710231785A CN106995750A CN 106995750 A CN106995750 A CN 106995750A CN 201710231785 A CN201710231785 A CN 201710231785A CN 106995750 A CN106995750 A CN 106995750A
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China
Prior art keywords
beer bottle
special purpose
low alkaline
purpose detergent
sodium
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CN201710231785.7A
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Chinese (zh)
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冯恩芳
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Individual
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/34Derivatives of acids of phosphorus
    • C11D1/345Phosphates or phosphites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/042Acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/361Phosphonates, phosphinates or phosphonites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/364Organic compounds containing phosphorus containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds

Abstract

The present invention relates to detergent technical field, and in particular to a kind of low alkaline Retrieve beer bottle special purpose detergent.It is made up of the raw material of following percetage by weight:Surfactant 23% 28%, scale-dissolving agent 20% 30%, bactericide 2% 3%, pH buffer 3% 5%, defoamer 1% 2%, surplus are water.The present invention is water fluid, easy to use, time saving and energy saving, substantially reduces the toxicity that organic solvent is brought, and corrosion-free, consumption is few, strong detergency, clean beer bottle brightness height.

Description

A kind of low alkaline Retrieve beer bottle special purpose detergent
Technical field
The present invention relates to detergent technical field, and in particular to a kind of low alkaline Retrieve beer bottle special purpose detergent.
Background technology
China is Beer Brewage, consumption big country, and beer production reaches 45,000,000 kilolitres within 2016.The confession of current China beer Answer mode main based on bottled, it is filling that most of beer product all carries out cleaning using returnable bottle.Therefore beer bottle is special washes Wash agent and there is larger use market.
Retrieve beer bottle dirt composition it is considerably complicated, have vegetable and animals oils, dust, dirt, wine dirty and it is old mark etc..At present I The Detergent power that state uses is main based on the overbased materials such as Strong oxdiative sodium, sodium carbonate, sodium metasilicate.Such as Chinese patent CN104946437A discloses a kind of beer bottle scavenger specially and preparation method thereof, which uses substantial amounts of sodium hydroxide. The long-term use of high alkalinity cleaning agent can cause corrosion to beer bottle, and it is poor to wash rear reflecting effect, transparency decline, and brightness is not It is high.
The content of the invention
It is an object of the invention to provide a kind of low alkaline Retrieve beer bottle special purpose detergent, alkaline detergent is eliminated to beer The corrosion that bottle is caused.To reach above-mentioned purpose, the present invention uses following technical scheme, and a kind of low alkaline Retrieve beer bottle is special Detergent, is made up of the raw material of following percetage by weight:
Surfactant:23%-28%
Scale-dissolving agent:20%-30%
Bactericide:2%-3%
PH buffer:3%-5%
Defoamer:1%-2%
Surplus is water.
The surfactant is isomerous tridecanol polyoxyethylene ether, cetyl benzenesulfonic acid sodium, N, N- dimethyl-N -s ten It is one or more of in six alkyl ammonium group propane sulfonic acid salt, AEO phosphate monoester ammonium salt.
It is preferred that, the surfactant by isomerous tridecanol polyoxyethylene ether and cetyl benzenesulfonic acid sodium by weight 1:1 composition.
The scale-dissolving agent is made up of diethanol monoisopropanolamine and organic phosphonate.
It is preferred that, the organic phosphonate is the sodium of ATMP five, the sodium of hydroxy ethylene diphosphonic acid four, divinyl One kind in the sodium of five methylenephosphonic acid of triamine seven.
It is furthermore preferred that the scale-dissolving agent has diethanol monoisopropanolamine and the sodium of diethylene triamine pentamethylene phosphonic seven according to weight ratio 1:1 composition.
The bactericide is one kind in Phenoxyethanol, PZ and alum.
The pH buffer is boric acid or tartaric acid.
The defoamer is propane diols polyoxyethylene poly-oxygen propylene aether or triisopropanolamine polyoxyethylene polyoxypropylene ether.
Tridecanol polyoxyethylene ether has good washing performance in the present invention;Cetyl benzenesulfonic acid sodium alkalescence, in Property, have stable performance in weakly acidic solution, also there is good wetting, infiltration, scattered, generation foam in hard water and go Dirty ability;A variety of surfactants are used cooperatively, and can play mutual assistance effect, in washing with dirt formation liquid crystal so as to improve Dirty ability, and can permeate under wetting millimeter paper, the interface between reduction millimeter paper and beer bottle, the adhesion strength for making millimeter paper and bottle Drop;Diethanol monoisopropanolamine and organic phosphonate can produce chelation to cation, form the complex compound of easy-clear, dissolving With the dirt on scattered beer bottle, increase cleaning efficiency.
Beneficial effects of the present invention:
The present invention is water fluid, easy to use, time saving and energy saving, substantially reduces the toxicity that organic solvent is brought, and corrosion-free, use Amount less, strong detergency, clean beer bottle brightness it is high.
Embodiment
In order to further illustrate the present invention, the low alkaline Retrieve beer bottle provided with reference to embodiment the present invention is special Detergent is described in detail, but it is to be understood that these descriptions are simply to further illustrate the features and advantages of the present invention Rather than the limitation to patent requirements of the present invention.
Embodiment 1
A kind of low alkaline Retrieve beer bottle special purpose detergent, is made up of the raw material of following percetage by weight:Surfactant 23%, Scale-dissolving agent 20%, bactericide 2%, pH buffer 3%, defoamer 1%, surplus are water;
The surfactant is isomerous tridecanol polyoxyethylene ether;
The scale-dissolving agent is by diethanol monoisopropanolamine and the sodium of ATMP five according to weight ratio 2:1 composition;
The bactericide is Phenoxyethanol;
The pH buffer is boric acid;
The defoamer is propane diols polyoxyethylene poly-oxygen propylene aether.
Embodiment 2
A kind of low alkaline Retrieve beer bottle special purpose detergent, is made up of the raw material of following percetage by weight:Surfactant 28%, Scale-dissolving agent 30%, bactericide 3%, pH buffer 5%, defoamer 2%, surplus are water;
The surfactant is N, N- dimethyl-N-hexadecyl base ammonium propane sulfonic acid salt;
The scale-dissolving agent is by diethanol monoisopropanolamine and the sodium of hydroxy ethylene diphosphonic acid four according to weight ratio 1:2 compositions;
The bactericide is PZ;
The pH buffer is tartaric acid;
The defoamer is triisopropanolamine polyoxyethylene polyoxypropylene ether.
Embodiment 3
A kind of low alkaline Retrieve beer bottle special purpose detergent, is made up of the raw material of following percetage by weight:Surfactant 25%, Scale-dissolving agent 25%, bactericide 2.5%, pH buffer 4%, defoamer 1.5%, surplus are water;
The surfactant is by isomerous tridecanol polyoxyethylene ether and cetyl benzenesulfonic acid sodium by weight 1:1 composition;
The scale-dissolving agent is made up of diethanol monoisopropanolamine and organic phosphonate;
The scale-dissolving agent is by diethanol monoisopropanolamine and the sodium of diethylene triamine pentamethylene phosphonic seven according to weight ratio 1:1 composition;
The bactericide is alum;
The pH buffer is tartaric acid;
The defoamer is propane diols polyoxyethylene poly-oxygen propylene aether.
Embodiment 4
A kind of low alkaline Retrieve beer bottle special purpose detergent, is made up of the raw material of following percetage by weight:Surfactant 26%, Scale-dissolving agent 24%, bactericide 2.4%, pH buffer 4.2%, defoamer 1.2%, surplus are water;
The surfactant by isomerous tridecanol polyoxyethylene ether, N, N- dimethyl-N-hexadecyl base ammonium propane sulfonic acid salt and AEO phosphate monoester ammonium salt is by weight 2:1:1 composition;
The scale-dissolving agent is by diethanol monoisopropanolamine and the sodium of diethylene triamine pentamethylene phosphonic seven according to weight ratio 1:1 composition;
The bactericide is PZ;
The pH buffer tartaric acid;
The defoamer is propane diols polyoxyethylene poly-oxygen propylene aether.
Embodiment 5
A kind of low alkaline Retrieve beer bottle special purpose detergent, is made up of the raw material of following percetage by weight:Surfactant 24%, Scale-dissolving agent 28%, bactericide 2.6%, pH buffer 4.5%, defoamer 1.3%, surplus are water.
Comparative example 1
A kind of low alkaline Retrieve beer bottle special purpose detergent, is made up of the raw material of following percetage by weight:Surfactant 25%, Scale-dissolving agent 25%, bactericide 2.5%, pH buffer 4%, defoamer 1.5%, surplus are water;
The surfactant is by sodium alkyl benzene sulfonate and ethoxylation sodium sulphate by weight 14:1 composition;
The scale-dissolving agent is made up of diethanol monoisopropanolamine and organic phosphonate;
The scale-dissolving agent is by diethanol monoisopropanolamine and the sodium of diethylene triamine pentamethylene phosphonic seven according to weight ratio 1:1 composition;
The bactericide is alum;
The pH buffer is tartaric acid;
The defoamer is propane diols polyoxyethylene poly-oxygen propylene aether.
Comparative example 2
A kind of low alkaline Retrieve beer bottle special purpose detergent, is made up of the raw material of following percetage by weight:Surfactant 25%, Scale-dissolving agent 5%, bactericide 2.5%, pH buffer 4%, defoamer 1.5%, surplus are water;
The surfactant is by isomerous tridecanol polyoxyethylene ether and cetyl benzenesulfonic acid sodium by weight 1:1 composition;
The scale-dissolving agent is sodium hydroxide;
The scale-dissolving agent is by diethanol monoisopropanolamine and the sodium of diethylene triamine pentamethylene phosphonic seven according to weight ratio 1:1 composition;
The bactericide is alum;
The pH buffer is tartaric acid;
The defoamer is propane diols polyoxyethylene poly-oxygen propylene aether.
Performance test
With reference to GB 9985-2000《Manual dishwashing detergent》The foam level method of assay method 2 of Appendix B detergency carries out decontamination Power is determined.And with embodiment and comparative example clean and reuse beer bottle, the beer bottle after cleaning is described with bright, bright, matt Finish, effect is followed successively by light better than bright better than matt, as a result as follows:
Numbering Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Comparative example 1 Comparative example 2 National standard liquid detergent
Detergency(It is individual) 2.6 3.9 4.2 3.8 3.5 2.4 2.8 2.0
Finish It is bright Light Light Light Light It is bright Matt It is bright
Described above is only the preferred embodiment of the present invention, it is noted that come for those skilled in the art Say, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should be regarded as Protection scope of the present invention.

Claims (9)

1. a kind of low alkaline Retrieve beer bottle special purpose detergent, it is characterised in that be made up of the raw material of following percetage by weight:Table Face activating agent 23%-28%, scale-dissolving agent 20%-30%, bactericide 2%-3%, pH buffer 3%-5%, defoamer 1%-2%, surplus are water.
2. low alkaline Retrieve beer bottle special purpose detergent according to claim 1, it is characterised in that the surfactant For isomerous tridecanol polyoxyethylene ether, cetyl benzenesulfonic acid sodium, N, N- dimethyl-N-hexadecyl base ammonium propane sulfonic acid salt and fat It is one or more of in fat alcohol APEO phosphate monoester ammonium salt.
3. low alkaline Retrieve beer bottle special purpose detergent according to claim 2, it is characterised in that the surfactant By isomerous tridecanol polyoxyethylene ether and cetyl benzenesulfonic acid sodium by weight 1:1 composition.
4. low alkaline Retrieve beer bottle special purpose detergent according to claim 1, it is characterised in that the scale-dissolving agent is by two Ethanol monoisopropanolamine and organic phosphonate composition.
5. low alkaline Retrieve beer bottle special purpose detergent according to claim 4, it is characterised in that the organic phosphonate For one kind in the sodium of ATMP five, the sodium of hydroxy ethylene diphosphonic acid four, the sodium of diethylene triamine pentamethylene phosphonic seven.
6. low alkaline Retrieve beer bottle special purpose detergent according to claim 4, it is characterised in that the scale-dissolving agent is by two Ethanol monoisopropanolamine and the sodium of diethylene triamine pentamethylene phosphonic seven are according to weight ratio 1:1 composition.
7. low alkaline Retrieve beer bottle special purpose detergent according to claim 1, it is characterised in that the bactericide is benzene One kind in oxyethanol, PZ and alum.
8. low alkaline Retrieve beer bottle special purpose detergent according to claim 1, it is characterised in that the pH buffer is Boric acid or tartaric acid.
9. low alkaline Retrieve beer bottle special purpose detergent according to claim 1, it is characterised in that the defoamer is third Glycol polyoxyethylene poly-oxygen propylene aether or triisopropanolamine polyoxyethylene polyoxypropylene ether.
CN201710231785.7A 2017-04-11 2017-04-11 A kind of low alkaline Retrieve beer bottle special purpose detergent Pending CN106995750A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107699392A (en) * 2017-09-15 2018-02-16 安徽科技学院 Based on microcrystalline cellulose/silver composite material beer bottle Bactericidal cleaner preparation method
CN108728271A (en) * 2018-06-29 2018-11-02 安徽森米诺农业科技有限公司 Detergent for clearing up sieve
CN110172378A (en) * 2019-06-04 2019-08-27 江苏爱特福84股份有限公司 Antimicrobial form oil smoke detergent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103232901A (en) * 2013-04-18 2013-08-07 衡阳市天怡化工实业有限公司 Beverage bottle cleaning agent and preparation method thereof
CN104312807A (en) * 2014-10-23 2015-01-28 深圳市科玺化工有限公司 Acid washing bottle additive and application
CN104946437A (en) * 2015-05-18 2015-09-30 安徽省华凯轻工科技有限公司 Cleaning agent special for beer bottles and preparation method of cleaning agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103232901A (en) * 2013-04-18 2013-08-07 衡阳市天怡化工实业有限公司 Beverage bottle cleaning agent and preparation method thereof
CN104312807A (en) * 2014-10-23 2015-01-28 深圳市科玺化工有限公司 Acid washing bottle additive and application
CN104946437A (en) * 2015-05-18 2015-09-30 安徽省华凯轻工科技有限公司 Cleaning agent special for beer bottles and preparation method of cleaning agent

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107699392A (en) * 2017-09-15 2018-02-16 安徽科技学院 Based on microcrystalline cellulose/silver composite material beer bottle Bactericidal cleaner preparation method
CN107699392B (en) * 2017-09-15 2020-06-05 安徽科技学院 Preparation method of beer bottle sterilization cleaning agent based on microcrystalline cellulose/silver composite material
CN108728271A (en) * 2018-06-29 2018-11-02 安徽森米诺农业科技有限公司 Detergent for clearing up sieve
CN110172378A (en) * 2019-06-04 2019-08-27 江苏爱特福84股份有限公司 Antimicrobial form oil smoke detergent

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Application publication date: 20170801