CN103131546A - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
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- CN103131546A CN103131546A CN201310060331XA CN201310060331A CN103131546A CN 103131546 A CN103131546 A CN 103131546A CN 201310060331X A CN201310060331X A CN 201310060331XA CN 201310060331 A CN201310060331 A CN 201310060331A CN 103131546 A CN103131546 A CN 103131546A
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Abstract
The invention relates to a cleaning composition comprising a non-amine oxide nonionic surfactant, a water-soluble solvent, a pH buffering agent, and water. A mass ratio of the nonionic surfactant to the solvent to the pH buffering agent is 0.5-10:0.05-10:0.1-5. The non-amine oxide nonionic surfactant is one or a combination selected from alkyl glycoside and derivative thereof, fatty alcohol polyoxyethylene ether, and alcohol amide. The water-soluble solvent comprises at least one of alcohol ether solvent and organic amine solvent. With the cleaning composition provided by the invention, various different oil stains can be removed. The cleaning agent has high decontamination capacity, high cleaning efficiency, durable cleaning effect, stable pH value, and low irritation. The cleaning composition is especially suitable to be used in cleaning of areas such as kitchens with severe oil stain contamination.
Description
Technical field
The present invention relates to a kind of cleaning compositions.
Background technology
Along with improving constantly of people's health consciousness, attractive in appearance, clean and tidy, the health of individual living environment are also more and more paid attention to.The kitchen is the place that is easier to produce dirt.Usually the mixture that contains lipid acid, ester class, protein, hydrocarbon polymer and flue dust etc. in the dirt in kitchen, dirt is mainly from food oils and derivative thereof, and the organic and inorganic foulants that is also mixing other in greasy dirt, the dark greasy dirt that forms high viscosity adheres to kitchen appliance, along with the accumulative total of time, dirt is accumulation constantly, becomes more and more sticking, more and more dried, more increased the difficulty that cleans.
People adopt general household laundry powder usually, liquid detergent is first smeared or be sprayed at the surface that wish cleans, then carry out wiping to reach the purpose of cleaning with the instrument of cloth, paper or sponge and so on.But traditional washing powder, liquid detergent etc. are take anion surfactant as main sanitising agent, though comparatively effective to the dust and the light oil dirt that pollute on fabric, but its infiltration of kitchen oil stain and cleaning capacity for long-term accumulation are inadequate, need simultaneously with the auxiliary tool (as iron wire ball, brush etc.) of washing, greasy dirt to be carried out the physical property wiping again that rubs, could clean totally.And these auxiliary cleaning tools are selected not at that time can to cause to a certain degree destruction to cleaned surface.In addition, general cleaning liquor mostly is high alkalinity, though can accelerate the decomposition of kitchen dirt.But initial high alkalinity can because of in using with the kitchen dirt in the reaction of the acidic substance such as lipid acid continue reduction, the cleaning efficiency of the liquid that can't keep clean.Therefore for the abrasive efficient of the agent that continues to keep clean, most products all has higher Initial pH (11-12), and this class high alkalinity product has infringement to skin.
Summary of the invention
In view of this, be necessary to provide a kind of cleaning compositions that effectively addresses the above problem.
A kind of cleaning compositions, it contains the nonionogenic tenside of non-oxide amine type, water miscible solvent, pH buffer reagent and water, and wherein the mass ratio of nonionogenic tenside, solvent, pH buffer reagent is 0.5-10:0.05-10:0.1-5; The nonionogenic tenside of this non-oxide amine type is one or more the combination in alkyl glycoside and derivative thereof, fatty alcohol polyethenoxy ether class, alcohol amide class; This water miscible solvent comprises at least a in pure ether solvent, organic amine solvent.
Cleaning compositions of the present invention can be removed all kinds of different grease dirts, strong detergency, and cleaning efficiency is high, and cleaning is insisted on for a long time, pH value stabilization and stimulate low.The suitable especially cleaning as the dirty zone of the heavy oil such as kitchen of this cleaning compositions.
Embodiment
Cleaning compositions of the present invention is suitable as kitchen cleaning agent, this cleaning compositions contains the nonionogenic tenside of non-oxide amine type, water miscible solvent, pH buffer reagent and appropriate water, and wherein the mass ratio of nonionogenic tenside, solvent, pH buffer reagent is 0.5-10:0.05-10:0.1-5.
But this nonionogenic tenside emulsification is deoiled, and can avoid the Ca in itself and water
2+, Mg
2+Plasma precipitates, thereby avoids its emulsification effect of deoiling to lose efficacy.
The main function of this water miscible solvent is infiltration, cracking greasy dirt, being conducive to tensio-active agent better brings into play the effects such as deep layer is wetting, emulsification, solubilising with greasy dirt cracking and swelling and is scattered in cleaning liquor, dirt is taken away cleaned surface, no longer deposit, so nonionogenic tenside coordinates seepage force and the emulsification greasy dirt ability that can improve greasy dirt with solvent phase.
The quality optimization of this nonionogenic tenside be solvent quality 0.1-50 doubly, more preferably 5-25 is doubly.
This pH buffer reagent can reduce cleaning compositions in the process of decontamination, reduces because the impact that is subjected to the acidic substance such as lipid acid causes the pH value, and then affects the lasting soil removability of sanitising agent.This pH buffer reagent makes the pH value of this cleaning compositions be 6-10, is preferably 7.5-9.5.
The nonionogenic tenside of this non-oxide amine type can be one or more the combination in alkyl glycoside and derivative thereof, fatty alcohol polyethenoxy ether class, alcohol amide class.The nonionogenic tenside of this non-oxide amine type is preferably the compound surface reactive systems of alkyl glycoside and alcohol amide class composition, wherein alkyl glycoside accounts for the 50%-95% of compound surface reactive systems total mass, and the alcohol amide class accounts for the 5%-50% of compound surface reactive systems total mass.
This alkyl glycoside is specially the alkyl glycoside of 8-16 carbon, as AP G0810(carbon chain lengths 8-10), AP G1214(carbon chain lengths 12-14), AP G0814(carbon chain lengths 8-14), AP G0816(carbon chain lengths 8-16), AP G1216(carbon chain lengths 12-16) etc.Be more preferably the alkyl glycoside of 8-14 carbon, as GLUCOPON215CSUP, GLUCOPON225DK, GLUCOPON600CS UP, the GLUCOPON650EC etc. of cognis company.fatty alcohol polyethenoxy ether class specifically comprises laureth-4, laureth-23, C12-13 alkanol polyethers-3, C12-13 alkanol polyethers-4, C12-13 alkanol polyethers-23, hexadecanol polyethers-20, ceteareth-25, stearyl alcohol polyethers-2, stearyl alcohol polyethers-23, C12-C14 alkyl polyoxyethylene ether-3, C12-C14 Soxylat A 25-7-7, C12-C14 Soxylat A 25-7-9, C12-C14 Soxylat A 25-7-10, C12-C14 Soxylat A 25-7-13, C12-C14 Soxylat A 25-7-16, C12-C15 Soxylat A 25-7-7, C12-C15 Soxylat A 25-7-9, the alcohol amide class specifically comprises lauric monoethanolamide, lauric acid diethyl amide, cocounut oil acyl single ethanol amide, cocounut oil acyl diglycollic amide.
This water miscible solvent comprises at least a in pure ether solvent, organic amine solvent.For reduce solvent produce and use procedure in pollute production and environment for use because of solvent evaporates in a large number, the preferred boiling point of this water miscible solvent is greater than the solvent of 170 ℃.Boiling point specifically comprises dipropylene glycol butyl ether, diethylene glycol ether, propandiol butyl ether, Diethylene Glycol butyl ether, dipropylene glycol propyl ether, more preferably dipropylene glycol butyl ether greater than the pure ether solvent of 170 ℃; Boiling point specifically comprises monoethanolamine, diethanolamine, trolamine, more preferably trolamine greater than 170 ℃ of organic amine solvents.This water miscible solvent is preferably the double solvents system that dipropylene glycol butyl ether and trolamine form, and wherein the mass ratio of dipropylene glycol butyl ether and trolamine is 1:0.05-50.
Understandable, solvent of the present invention also can be selected the solvent of lower boiling (less than 170 ℃), or add appropriate lower boiling solvent in high boiling solvent, as ethanol, n-propyl alcohol, Virahol, butanols etc., the interpolation of this low boiling point solvent can improve the quick-drying performance after the cleaning compositions wiping, reduces its residue on crust.
In addition, also can add the solvent of appropriate low water solubility in this water miscible solvent, as tasteless kerosene, D-limonene etc., this kind solvent can be by making an addition in cleaning compositions after the emulsification solubilising, with the performance effect.
The pH system buffer of this pH system buffer for cushioning under the needed pH value of cleaning compositions (6-10) condition, the pH system buffer that more preferably can cushion under meta-alkalescence pH value (7.5-9.5) condition is as Sodium phosphate dibasic-SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate-sodium hydroxide, Veronal sodium-hydrochloric acid, Gan An Suan – sodium hydroxide, boric acid-borax, sodium carbonate-sodium bicarbonate, Sodium phosphate dibasic-citric acid, Sodium phosphate dibasic-potassium primary phosphate, potassium primary phosphate-dipotassium hydrogen phosphate.
Further, in order better to take good care of skin in decontamination, reduce the stimulation to skin, prevent from cleaning the rear problem dry, tight, the skin roughen that occurs, this cleaning compositions also can be added with skin conditioning agent, and this skin conditioning agent is at least a in wetting Agent for Printing Inks and softener.The quality percentage composition of this skin conditioning agent in cleaning compositions is 0.1%-10%.This wetting Agent for Printing Inks can be at least a in propylene glycol, butyleneglycol, glycerine, aloe, pentanediol.Softener can be at least a in Jojoba oil, Oleum Cocois, sweet oil, silicone oil and modified silicon oil, lanolin, iso-octyl palmitate, Isopropyl myristate (IPM) and Wickenol 111 (IPP).
Further, adhere in order to prevent soil redeposition, this cleaning compositions also can be added with anti redeposition agent.The quality percentage composition of this anti redeposition agent in cleaning compositions is 0.5%-2%.This anti redeposition agent can be any one in silicates and acrylic copolymer class, and the silicates anti redeposition agent includes water glass, Starso etc.Acrylic copolymer class anti redeposition agent includes Polyquart ampho149 and the Mirapol Surf-S210 of cognis company.This anti redeposition agent is preferably Mirapol Surf-S210, but the crusts such as its hydrophobically modified glass, pottery, stainless steel make it have hydrophilic layer, reduces the probability that dirt adheres to again, makes cleaning next time easier.
Further, other tensio-active agent that also comprises auxiliary nonionogenic tenside in this cleaning compositions.This other the quality percentage composition of tensio-active agent in cleaning compositions is 0.5%-5%.This other tensio-active agent is amphoterics, its main at least a in betanin derivative, both sexes Acetates, propionate compound, sulfo-succinic acid salt, oxidation amine.Betanin derivative has the AMONYL 380LC of comprising, octyl group/decyl amido propyl betaine, ricinoleic acid amide CAB, dodecyl oxyethyl group sultaine, dodecyl hydroxypropyl sultaine, dodecyl sulfobetaine.The both sexes Acetates specifically comprises cocounut oil both sexes sodium acetate, cocounut oil both sexes diacetic acid disodium.Propionic salt specifically comprises cocounut oil both sexes Sodium Propionate.The sulfo-succinic acid salt specifically comprises polyoxyethylene glycol-5 lauryl citric acid disodium sulfosuccinate, lauryl alcohol disodium sulfosuccinate, ricinoleic acid amide monoethanolamine disodium sulfosuccinate, lauryl disodium sulfosuccinate.The oxidation amine comprises stearylamide propyl group amine oxide, cocamidopropyl propyl amide amine oxide, dimethyl dodecyl amine oxide.This other tensio-active agent is preferably betanin derivative, oxidation amine and composition thereof.
Further, also be added with detergency enzymes in this cleaning compositions, it can accelerate the decomposition of greasy dirt, improves clean effect.This detergency enzymes can be at least a in lipase, amylase, proteolytic enzyme.
Further, this cleaning compositions also is added with ancillary component, as solubilizing agent, tinting material, sequestrant, sanitas, sterilant, defoamer, dispersion agent, thickening material, spices etc.
The present invention makes cleaning compositions by the nonionogenic tenside of non-oxide amine type, water-soluble and high boiling solvent, pH buffer reagent are mixed according to certain ratio, this cleaning compositions can effectively be removed the kitchen dirt, solved take anion surfactant as main common detergents and can not remove grease dirt of all kinds of different sourcess and composition thereof, the problem that cleaning efficiency is low, and the sanitising agent that contains lower boiling, lower molecular weight organic solvent is detrimental to health, the problem of contaminate environment.This cleaning compositions can be kept its Initial pH in cleaning course, and (6-10) keeps decontamination effect in certain pH scope, has solved the problem that existing over-based detergent is difficult for keeping continuing cleaning power.In a word, cleaning compositions of the present invention can be removed all kinds of different grease dirts, strong detergency, and cleaning efficiency is high, and cleaning is insisted on for a long time, pH value stabilization and stimulate low.The suitable especially cleaning as the dirty zone of the heavy oil such as kitchen of this cleaning compositions, this can make liquid spray products, also can add to and make all kinds of clean kitchen greasy dirt products on the wiping carrier in (as non-woven fabrics, wet-strength paper).
Below by embodiment, the present invention is specifically described.
Embodiment 1
Press the recipe configuration cleaning compositions shown in table one, in the present embodiment, the mass ratio of nonionogenic tenside, solvent, pH buffer reagent is 1.7:1.6:1.135.
Step of preparation process: water is added in the allotment bucket, add successively C12-C14 alkyl polyoxyethylene ether-3, cocounut oil acyl diglycollic amide and be stirred to fully dissolving, add successively to stir after dipropylene glycol butyl ether, trolamine, glycerine, Mirapol Surf-S210, Sodium phosphate dibasic, potassium primary phosphate, sanitas and namely make cleaning compositions again, the pH value of gained cleaning compositions stoste is about 8.
Table one
Embodiment 2
Press the recipe configuration cleaning compositions shown in table two, in the present embodiment, the mass ratio of nonionogenic tenside, solvent, pH buffer reagent is 5:3:1.45.
Step of preparation process: water is added in the allotment bucket, add successively GLUCOPON215CS UP, cocounut oil acyl diglycollic amide and be stirred to fully dissolving, add successively to stir after diethylene glycol ether, trolamine, aloe, Mirapol Surf-S210, sodium carbonate, sodium bicarbonate, essence, sanitas, sequestrant and namely make cleaning compositions again, the pH value of gained cleaning compositions stoste is about 9.5.
Table two
The result of use test: the cleaning compositions that embodiment 1-2 makes is through on probation, can be effective, remove fast the dirt that retains for a long time on the kitchen range top in the kitchen, wall, smoke exhaust ventilator, castor, and effect is better than the decontamination product such as the washing powder, liquid detergent of general family expenses, easy to use, free from extraneous odour.
In addition, those skilled in the art also can make various modifications, interpolation and the replacement on other form and details in claim of the present invention scope of disclosure and spirit.Certainly, the variations such as various modifications, interpolation and replacement that these are made according to spirit of the present invention are within all should being included in the present invention's scope required for protection.
Claims (17)
1. cleaning compositions, it is characterized in that: this cleaning compositions contains the nonionogenic tenside of non-oxide amine type, water miscible solvent, pH buffer reagent and water, and wherein the mass ratio of nonionogenic tenside, solvent, pH buffer reagent is 0.5-10:0.05-10:0.1-5; The nonionogenic tenside of this non-oxide amine type is one or more the combination in alkyl glycoside and derivative thereof, fatty alcohol polyethenoxy ether class, alcohol amide class; This water miscible solvent comprises at least a in pure ether solvent, organic amine solvent.
2. cleaning compositions as claimed in claim 1, it is characterized in that: the boiling point of this water miscible solvent is greater than 170 ℃.
3. cleaning compositions as claimed in claim 1 is characterized in that: the quality of this nonionogenic tenside be solvent quality 0.1-50 doubly.
4. cleaning compositions as claimed in claim 3 is characterized in that: the quality of this nonionogenic tenside be solvent quality 5-25 doubly.
5. cleaning compositions as claimed in claim 1 is characterized in that: this pH buffer reagent makes the pH value of this cleaning compositions be 6-10.
6. cleaning compositions as claimed in claim 5 is characterized in that: this pH buffer reagent makes the pH value of this cleaning compositions be 7.5-9.5.
7. cleaning compositions as claimed in claim 1, it is characterized in that: the nonionogenic tenside of this non-oxide amine type is the compound surface reactive systems that alkyl glycoside and alcohol amide class form, wherein alkyl glycoside accounts for the 50%-95% of compound surface reactive systems total mass, and the alcohol amide class accounts for the 5%-50% of compound surface reactive systems total mass.
8. cleaning compositions as claimed in claim 1, it is characterized in that: this alkyl glycoside is the alkyl glycoside with 8-16 carbon.
9. cleaning compositions as claimed in claim 1, it is characterized in that: this alcohol ether solvent includes dipropylene glycol butyl ether, diethylene glycol ether, propandiol butyl ether, Diethylene Glycol butyl ether, dipropylene glycol propyl ether; This organic amine solvent includes monoethanolamine, diethanolamine, trolamine.
10. cleaning compositions as claimed in claim 9, it is characterized in that: this water-soluble solvent is the double solvents system that dipropylene glycol butyl ether and trolamine form, and wherein the mass ratio of dipropylene glycol butyl ether and trolamine is 1:0.05-50.
11. cleaning compositions as claimed in claim 1 is characterized in that: this pH buffer reagent is Sodium phosphate dibasic-SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate-sodium hydroxide, Veronal sodium-hydrochloric acid, Gan An Suan – sodium hydroxide, boric acid-borax, sodium carbonate-sodium bicarbonate, Sodium phosphate dibasic-citric acid, Sodium phosphate dibasic-potassium primary phosphate or potassium primary phosphate-dipotassium hydrogen phosphate.
12. cleaning compositions as claimed in claim 1, it is characterized in that: also contain skin conditioning agent in this cleaning compositions, this skin conditioning agent is at least a in wetting Agent for Printing Inks and softener, and the quality percentage composition of this skin conditioning agent in cleaning compositions is 0.1%-10%; This wetting Agent for Printing Inks is at least a in propylene glycol, butyleneglycol, glycerine, aloe, pentanediol; This softener is at least a in Jojoba oil, Oleum Cocois, sweet oil, silicone oil and modified silicon oil, lanolin, iso-octyl palmitate, Isopropyl myristate and Wickenol 111.
13. cleaning compositions as claimed in claim 1 is characterized in that: also contain anti redeposition agent in this cleaning compositions, the quality percentage composition of this anti redeposition agent in cleaning compositions is 0.5%-2%; This anti redeposition agent is any one in silicates and acrylic copolymer class.
14. cleaning compositions as claimed in claim 1 is characterized in that: also contain other tensio-active agent of auxiliary nonionogenic tenside in this cleaning compositions, the quality percentage composition of other tensio-active agent in cleaning compositions is 0.5%-5%; Other tensio-active agent is amphoterics, its main at least a in betanin derivative, both sexes Acetates, propionate compound, sulfo-succinic acid salt, oxidation amine.
15. cleaning compositions as claimed in claim 1 is characterized in that: also contain detergency enzymes in this cleaning compositions, this detergency enzymes is at least a in lipase, amylase, proteolytic enzyme.
16. cleaning compositions as claimed in claim 1 is characterized in that: this cleaning compositions also is added with ancillary component, and this ancillary component includes solubilizing agent, tinting material, sequestrant, sanitas, sterilant, defoamer, dispersion agent, thickening material, spices.
17. cleaning compositions as claimed in claim 1 is characterized in that: also be added with at least a in tasteless kerosene, D-limonene in this cleaning compositions.
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| CN104017666A (en) * | 2014-05-27 | 2014-09-03 | 北京洛娃日化有限公司 | Kitchen cleaning agent for various surfaces |
| CN104245912A (en) * | 2012-06-29 | 2014-12-24 | 花王株式会社 | Method for producing alkali detergent composition for steel plate |
| CN104531402A (en) * | 2014-12-10 | 2015-04-22 | 广州市浪奇实业股份有限公司 | Neutral toilet cleaner |
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Application publication date: 20130605 |