CN103451037A - Sterilization laundry detergent containing epsilon-polylysine - Google Patents
Sterilization laundry detergent containing epsilon-polylysine Download PDFInfo
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- CN103451037A CN103451037A CN2013102426786A CN201310242678A CN103451037A CN 103451037 A CN103451037 A CN 103451037A CN 2013102426786 A CN2013102426786 A CN 2013102426786A CN 201310242678 A CN201310242678 A CN 201310242678A CN 103451037 A CN103451037 A CN 103451037A
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Abstract
The invention relates to a sterilization laundry detergent containing epsilon-polylysine. The sterilization laundry detergent comprises the following raw materials in percentage by weight: 10-50% of surfactant, 0-2% of anti-redeposition agent, 0.5-1% of chelating agent, 0-3% of thickening agent, 0.1-1% of epsilon-polylysine, 0.1-0.5% of essence and the balance of deionized water. According to the sterilization laundry detergent provided by the invention, by taking the epsilon-polylysine as a sterilization agent, the antibacterial sterilization effect is obvious, the safety is high, and the need of consumers for natural products is met.
Description
Technical field
The present invention relates to a kind of bactericidal liquid detergent containing epsilon-polylysine, belong to the washing composition technical field.
Background technology
In recent years, the washing liquid performance unique with it becomes the main flow of laundry product gradually, and particularly, in developed country and areas such as American-European and Japan, the washing liquid ascendant trend is very violent, and ratio improves constantly.Along with the raising of the level of consumption, people are also more and more higher to the demand of washing liquid, except the soil removability that requires, sterilization and disinfection ability, also more and more higher to security requirement.The sterilant that this patent adopts is epsilon-polylysine (ε-Polylysine, ε-PL), is the natural meta-bolites extracted from streptomycete fermentation liquid.It is polymerized by 25～30 lysine residues, and antimicrobial spectrum is wide, in acid and slightly acidic environment to various G ', G
-, yeast, mould all have good fungistatic effect.At present, in the U.S., Japan and other countries, be widely used in food antiseptic, safe.
Disclose antimicrobial laundry liquid of a kind of disinfecting and decontaminating simultaneously and preparation method thereof in Chinese patent application 20071079670.4, this patent adopts biguanides and diquaternary amine salt series bactericidal agent.Chinese patent application 200910259998.6 discloses a kind of Mouldproof liquid detergent, and the mould inhibitor of this patent is selected triclosan DP-300, parachlormetaxylenol (PCMX), mould inhibitor PlusFG, one or both in mould inhibitor LZ-25.A kind of multifunctional laundry liquid is disclosed in Chinese patent application 201010510824.5, the mixture of one or more that this patent is usingd in triclosan (DP300), triclocarban (TCC), Kathon CG, diazolones is chemostefilant as the disinfectant adopted in the above-mentioned patent of disinfection sanitizer, skin irritation, life-time service may be detrimental to health.It is sterilant that this patent adopts the biological preservative polylysine, and the restraining and sterilizing bacteria effect is remarkable, safe, meets the demand of human consumer to natural product.
Summary of the invention
Goal of the invention: aim to provide a kind of safe, efficiently containing bactericidal liquid detergent of epsilon-polylysine and preparation method thereof.
Technical scheme: a kind of bactericidal liquid detergent containing epsilon-polylysine comprises following component (with mass percent % note):
Described tensio-active agent comprises anion surfactant, nonionogenic tenside and both sexes table promoting agent, wherein:
One or more combination below anion surfactant is preferred: alkylbenzene sulfonate (LAS), alkenyl sulphonate (AOS), fatty alcohol polyoxyethylene ether sulfate (AES), fatty acid methyl ester sulfonate (MES), alkyl-sulphate (K12);
One or more combination below nonionogenic tenside is preferred: fatty alcohol-polyoxyethylene ether (AEO9, AEO7, AEO3), lauric acid amide of ethanol (6501), sorbitol anhydride alkyl acid esters (this dish), glutamic acid lauryl alcohol ester;
Amphoterics is one or more mixtures in amino acid pattern, betaine type, Imidazoline Surfactants.
One or more combination below described anti redeposition agent is preferred: Xylo-Mucine, Vltra tears sodium, hydroxy butyl methyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone.
Preferably following one or more mixtures of sequestrant: disodium edta, Trisodium Citrate.
The preparation method of this washing liquid comprises the following steps: (1) joins the anion surfactant of accurate-metering and deionized water in stirring tank, is warming up to 60 ℃, is stirred to fully and dissolves; (2) slowly add nonionogenic tenside and the epsilon-polylysine of accurate-metering, stir until its whole dissolvings are cooling, in the observing response still to the solution that is completed into transparent homogeneous; (3 add other auxiliary agents, and standing froth breaking after all dissolving, prepare the bactericidal liquid detergent containing epsilon-polylysine.
Characteristics of the present invention are to adopt the biological preservative epsilon-polylysine as fungicide active ingredient, the restraining and sterilizing bacteria effect is remarkable, gram-positive microorganism, negative bacterium, mould, yeast, virus are all had to deactivation, safe, to the skin nonirritant, strong detergency, fill a prescription without phosphorus, environmental protection.
Embodiment
Below by embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to this:
Embodiment 1:
A kind of bactericidal liquid detergent containing epsilon-polylysine comprises following component (with mass percent % note):
Prepare this washing liquid according to following steps: (1) joins the sodium alkyl benzene sulfonate of accurate-metering, fatty alcohol-polyoxyethylene ether and deionized water in stirring tank, is warming up to 60 ℃, is stirred to fully and dissolves; (2) slowly add cocoyl tetrahydroglyoxaline and the epsilon-polylysine of accurate-metering, stir until its whole dissolvings are cooling, in the observing response still to the solution that is completed into transparent homogeneous; (3) add other auxiliary agents, standing froth breaking after all dissolving, prepare the bactericidal liquid detergent containing epsilon-polylysine.Through with commercially available routine, containing parachlormetaxylenol bactericidal liquid detergent simultaneous test, embodiment 1 washing liquid strong detergency, can kill the microorganism more than 99.99%, washes rear clothing without the chemical bactericide taste, and smell is pure and fresh.
Table 1 washing effect
Embodiment 2:
A kind of bactericidal liquid detergent containing epsilon-polylysine comprises following component (with mass percent % note):
Prepare this washing liquid according to following steps: (1) joins the polyoxyethylenated alcohol sodium sulfate of accurate-metering and deionized water in stirring tank, be warming up to 60 ℃, be stirred to fully and dissolve: (2) slowly add sorbitol anhydride alkyl acid esters and the epsilon-polylysine of accurate-metering, stir until its whole dissolvings, cooling, in the observing response still to the solution that is completed into transparent homogeneous; (3) add other auxiliary agents, standing froth breaking after all dissolving, prepare the bactericidal liquid detergent containing epsilon-polylysine.This washing liquid strong detergency, can kill the microorganism more than 99.99%, washes rear clothing without the chemical bactericide taste, and smell is pure and fresh.
Table 2 washing effect
Embodiment 3:
A kind of bactericidal liquid detergent containing epsilon-polylysine comprises following component (with mass percent % note):
Prepare this washing liquid according to following steps: (1) joins the sodium alkyl benzene sulfonate of accurate-metering, lauric acid amide of ethanol, AMONYL 380LC and deionized water in stirring tank, is warming up to 60 ℃, is stirred to fully and dissolves; (2) slowly add the epsilon-polylysine of accurate-metering, stir until its whole dissolvings are cooling, in the observing response still to the solution that is completed into transparent homogeneous; (3) add other auxiliary agents, standing froth breaking after all dissolving, prepare the bactericidal liquid detergent containing epsilon-polylysine.This washing liquid strong detergency, can kill the microorganism more than 99.99%, washes rear clothing without the chemical bactericide taste, and smell is pure and fresh.
Table 3 washing effect
Embodiment 4:
A kind of bactericidal liquid detergent containing epsilon-polylysine comprises following component (with mass percent % note):
Prepare this washing liquid according to following steps: (1) joins the methyl sodiosul foaliphatate of accurate-metering and deionized water in stirring tank, is warming up to 60 ℃, is stirred to fully and dissolves; (2) slowly add glutamic acid lauryl alcohol ester and the epsilon-polylysine of accurate-metering, stir until its whole dissolvings are cooling, in the observing response still to the solution that is completed into transparent homogeneous; (3) add other auxiliary agents, standing froth breaking after all dissolving, prepare the bactericidal liquid detergent containing epsilon-polylysine.This washing liquid strong detergency, can kill the microorganism more than 99.99%, washes rear clothing without the chemical bactericide taste, and smell is pure and fresh.
Table 4 washing effect
Claims (6)
1. the bactericidal liquid detergent containing epsilon-polylysine, main component has tensio-active agent, anti redeposition agent, sequestrant, thickening material, pH adjusting agent, epsilon-polylysine, essence and deionized water, it is characterized in that usining that epsilon-polylysine is as sterilant.
2. the bactericidal liquid detergent containing epsilon-polylysine according to claim 1 is characterized in that each constituent mass per-cent of washing liquid % is as follows:
3. the bactericidal liquid detergent containing epsilon-polylysine according to claim 1, is characterized in that described tensio-active agent comprises anion surfactant, nonionogenic tenside and amphoterics, wherein:
Anion surfactant is alkylbenzene sulfonate (LAS), alkenyl sulphonate (AOS), fatty alcohol polyoxyethylene ether sulfate (AES), fatty acid methyl ester sulfonate (MES), one or more mixtures in alkyl-sulphate (K12);
Nonionogenic tenside is fatty alcohol-polyoxyethylene ether (AEO9, AEO7, AEO3), lauric acid amide of ethanol (6501), sorbitol anhydride alkyl acid esters (this dish), one or more mixtures in glutamic acid lauryl alcohol ester;
Amphoterics is one or more mixtures in amino acid pattern, betaine type, Imidazoline Surfactants.
4. the bactericidal liquid detergent containing epsilon-polylysine according to claim 1, is characterized in that described anti redeposition agent selects one or more mixtures in Xylo-Mucine, Vltra tears sodium, hydroxy butyl methyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone.
5. the bactericidal liquid detergent containing epsilon-polylysine according to claim 1, is characterized in that described sequestrant selects: one or more mixtures in disodium edta, Trisodium Citrate.
6. the bactericidal liquid detergent containing epsilon-polylysine according to claim 1, is characterized in that described thickening material selects one or more mixtures in sodium-chlor, dodecanamide propyl amine oxide, cellulose thickener.
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| CN201310242678.6A CN103451037B (en) | 2013-06-19 | 2013-06-19 | A kind of bactericidal liquid detergent containing epsilon-polylysine |
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| CN201310242678.6A CN103451037B (en) | 2013-06-19 | 2013-06-19 | A kind of bactericidal liquid detergent containing epsilon-polylysine |
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| CN103451037A true CN103451037A (en) | 2013-12-18 |
| CN103451037B CN103451037B (en) | 2015-12-23 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103805367A (en) * | 2014-02-28 | 2014-05-21 | 刘菊 | High-efficiency sterilization laundry detergent |
| CN103865670A (en) * | 2014-02-15 | 2014-06-18 | 上海方木精细化工有限公司 | Concentrated laundry powder |
| CN104804894A (en) * | 2015-04-14 | 2015-07-29 | 江南大学 | Environment-friendly compound laundry detergent with sterilizing and anti-fungus functions and preparation method of compound laundry detergent |
| CN105154249A (en) * | 2015-10-10 | 2015-12-16 | 中国日用化学工业研究院 | Bacteriostatic and bactericidal liquid detergent for fabrics and preparation method thereof |
| CN106047526A (en) * | 2016-05-25 | 2016-10-26 | 深圳市洁王精细化工科技有限公司 | Detergent sheet and preparation method thereof |
| CN106497690A (en) * | 2016-10-12 | 2017-03-15 | 易洁(北京)科技有限公司 | A kind of liquid detergent processing technology |
| CN106566685A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Efficient low-foam laundry detergent and preparation method thereof |
| CN106906053A (en) * | 2017-01-20 | 2017-06-30 | 北京德得创业科技有限公司 | A kind of liquid detergent containing polylysine and shitosan and preparation method and application |
| CN108300595A (en) * | 2018-02-12 | 2018-07-20 | 华南理工大学 | A kind of Chinese cassia tree clothes detergent and preparation method thereof |
| CN114989905A (en) * | 2022-07-01 | 2022-09-02 | 广东优凯科技有限公司 | Washing gel bead with sterilization and disinfection effects and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09176689A (en) * | 1995-12-27 | 1997-07-08 | T Paul Kk | Germicidal cleaner composition |
| JP2001348596A (en) * | 2000-06-09 | 2001-12-18 | Kao Corp | Detergent composition |
| CN1413248A (en) * | 1999-12-22 | 2003-04-23 | 宝洁公司 | Laundry and cleaning and/or fabric care compositions |
| CN103045400A (en) * | 2012-12-18 | 2013-04-17 | 广州立白企业集团有限公司 | Liquid tableware detergent composition containing natural antibacterial components |
| CN103131546A (en) * | 2013-02-26 | 2013-06-05 | 金红叶纸业集团有限公司 | Cleaning composition |
-
2013
- 2013-06-19 CN CN201310242678.6A patent/CN103451037B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09176689A (en) * | 1995-12-27 | 1997-07-08 | T Paul Kk | Germicidal cleaner composition |
| CN1413248A (en) * | 1999-12-22 | 2003-04-23 | 宝洁公司 | Laundry and cleaning and/or fabric care compositions |
| JP2001348596A (en) * | 2000-06-09 | 2001-12-18 | Kao Corp | Detergent composition |
| CN103045400A (en) * | 2012-12-18 | 2013-04-17 | 广州立白企业集团有限公司 | Liquid tableware detergent composition containing natural antibacterial components |
| CN103131546A (en) * | 2013-02-26 | 2013-06-05 | 金红叶纸业集团有限公司 | Cleaning composition |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865670A (en) * | 2014-02-15 | 2014-06-18 | 上海方木精细化工有限公司 | Concentrated laundry powder |
| CN103805367A (en) * | 2014-02-28 | 2014-05-21 | 刘菊 | High-efficiency sterilization laundry detergent |
| CN104804894A (en) * | 2015-04-14 | 2015-07-29 | 江南大学 | Environment-friendly compound laundry detergent with sterilizing and anti-fungus functions and preparation method of compound laundry detergent |
| CN105154249A (en) * | 2015-10-10 | 2015-12-16 | 中国日用化学工业研究院 | Bacteriostatic and bactericidal liquid detergent for fabrics and preparation method thereof |
| CN105154249B (en) * | 2015-10-10 | 2018-08-31 | 中国日用化学工业研究院 | A kind of restraining and sterilizing bacteria type fabric washes agent and preparation method thereof by liquid |
| CN106047526A (en) * | 2016-05-25 | 2016-10-26 | 深圳市洁王精细化工科技有限公司 | Detergent sheet and preparation method thereof |
| CN106497690A (en) * | 2016-10-12 | 2017-03-15 | 易洁(北京)科技有限公司 | A kind of liquid detergent processing technology |
| CN106566685A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Efficient low-foam laundry detergent and preparation method thereof |
| CN106906053A (en) * | 2017-01-20 | 2017-06-30 | 北京德得创业科技有限公司 | A kind of liquid detergent containing polylysine and shitosan and preparation method and application |
| CN108300595A (en) * | 2018-02-12 | 2018-07-20 | 华南理工大学 | A kind of Chinese cassia tree clothes detergent and preparation method thereof |
| CN114989905A (en) * | 2022-07-01 | 2022-09-02 | 广东优凯科技有限公司 | Washing gel bead with sterilization and disinfection effects and preparation method thereof |
| CN114989905B (en) * | 2022-07-01 | 2023-08-18 | 广东优凯科技有限公司 | Laundry gel bead with sterilization and disinfection effects and preparation method thereof |
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| CN103451037B (en) | 2015-12-23 |
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Effective date of registration: 20180514 Address after: 528478 one of seven buildings, 3 Fu Jie street, Heping Village, Zhongshan, Guangdong. Patentee after: Guangdong Hua Yong daily necessities Industry Co., Ltd. Address before: 300457 thirteenth Avenue, Taida Development Zone, Tianjin, 29 Patentee before: Tianjin University of Science & Technology |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20151223 Termination date: 20210619 |