CN101514305B - Fabric softener with bactericidal function and preparation method thereof - Google Patents

Fabric softener with bactericidal function and preparation method thereof Download PDF

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Publication number
CN101514305B
CN101514305B CN2008102474721A CN200810247472A CN101514305B CN 101514305 B CN101514305 B CN 101514305B CN 2008102474721 A CN2008102474721 A CN 2008102474721A CN 200810247472 A CN200810247472 A CN 200810247472A CN 101514305 B CN101514305 B CN 101514305B
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fabric softener
ether
aliphatic alcohol
sterilizing function
alcohol polyethenoxy
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CN101514305A (en
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李泉清
魏淑芬
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Beijing green umbrella Technology Co.,Ltd.
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BEIJING LUSAN CHEMICAL Co Ltd
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Abstract

The invention relates to a fabric softener with bactericidal function and a preparation method thereof. The fabric softener comprises the following components in portion by weight: 4.5 to 10 portions of quaternary amine ester (C18), 1 to 3 portions of dialkyl quaternary ammonium salt (C8-10), 1 to 2 portions of fatty alcohol polyoxyethylene ether (5), 0.5 to 1.5 portions of fatty alcohol polyoxyethylene ether (7), 0.1 to 0.5 portion of essence, 0.05 to 0.3 portion of citric acid, and 82.7 to 92.8 portions of deionized water. The fabric softener has good solubility and good softness, protects the fabric, has strong sterilizing power, and can reduce washing cost.

Description

A kind of fabric softener and preparation method thereof with sterilizing function
Technical field
The present invention relates to household chemicals, relate in particular to a kind of fabric softener and preparation method thereof with sterilizing function.
Background technology
In the daily life, when washing clothes, a lot of human consumers have formed in the clothing after washing and have added softening agent, make more soft, the more fragrant custom of clothing; Also the promising clothing disinfectant of some human consumer is accustomed to.The fabric especially frequent disinfection of underwear is prophylactic important means, generally is high-temperature sterilization at present both at home and abroad, or sterilizes with sterilant, but the human consumer often will carry out mellowing to underwear, if sterilization before soft may be infected with new germ after the softness; If soft back sterilization, softening agent itself is to fabric and bacterium formation protective layer, and sterilization effect is poor, the process complexity, wastes time and energy.
Softening agent generally can only be slightly soluble in water, poor permeability, sterilant adds the active obviously reduction in back, and prolonged storage is difficult for stable, yet there are no at present the product that has softness, sterilizing function simultaneously both at home and abroad, therefore be necessary to develop the needs that a kind of fabric softener with sterilizing function satisfies the human consumer, allow the human consumer saves working time, soft degerming is once finished.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, a kind of fabric softener with sterilizing function and preparation method thereof is provided, the present invention is based on cats product, and is composite with the cationic germicide that has hydrophilic radical, penetration enhancer.The present invention is environmentally friendly, and soft, sterilization is once finished, and nontoxic non-stimulated, helps HUMAN HEALTH, economizes on resources simultaneously, raises the efficiency.
The objective of the invention is to be achieved through the following technical solutions:
A kind of fabric softener with sterilizing function comprises following component by ratio of weight and the number of copies:
Quaternary amine ester (C 18) 4.5~10
Two alkyl quaternary amine salt (C 8-10) 1~3
Fatty alcohol-polyoxyethylene ether (5) 1~2
Fatty alcohol-polyoxyethylene ether (7) 0.5~1.5
Essence 0.1~0.5
Citric acid 0.05~0.3
Deionized water 82.7~92.8.
Its preparation method is: by ratio of weight and the number of copies, remove 82.7~92.8 parts of ionized waters, with wherein 70~85% be heated to 60~80 ℃, in the addingization material still, under agitation add quaternary amine ester (C then 18) (7) 0.5~1.5 parts of 4.5~10 parts, (5) 1~2 parts of fatty alcohol-polyoxyethylene ether, fatty alcohol-polyoxyethylene ether are to dissolving fully, add two alkyl quaternary amine salt (C when being cooled to 35 ℃~45 ℃ 8-10) 1~3 part, 0.1~0.5 part in essence, residue deionized water, stirring, pH is 4~5 with 0.05~0.3 part of adjustment of citric acid, stirs, leaves standstill, and must have the fabric softener of sterilizing function.
The invention has the beneficial effects as follows:
1, bactericide promoter of the present invention and softening agent molecule are rationally compound, have solved synergy and stability problem.Sterilizing rate height: the streptococcus aureus killing rate is reached 99.97%, the Candida albicans killing rate is reached 99.90%, the intestinal bacteria killing rate is reached 99.98%.
2, environmental protection of the present invention, safety: LD 50>5000mg/kg
Figure G2008102474721D00021
3, processable of the present invention is good, and flexibility is good, and protection fabric, sterilizing power is strong, can reduce the washing cost.
4, use fabric softener both can save time with sterilizing function, the water consumption in the time of can saving washing again, soft degerming is once finished, and can save the energy.
Below in conjunction with embodiment Ben Fanming is further described.
Embodiment
The present invention has the fabric softener of sterilizing function, comprises following component by ratio of weight and the number of copies:
Quaternary amine ester (C 18) 4.5~10
Two alkyl quaternary amine salt (C 8-10) 1~3
Fatty alcohol-polyoxyethylene ether (5) 1~2
Fatty alcohol-polyoxyethylene ether (7) 0.5~1.5
Essence 0.15~0.5
Citric acid 0.05~0.3
Deionized water 82.7~92.8.
In the component of the present invention, quaternary amine ester (C 18) have good flexibility, rewetting, can be antistatic, life-time service can not make the fabric yellowing.Two alkyl quaternary amine salt (C 8-10) have efficient, wide spectrum, low toxicity, characteristics that seepage force is strong, have sterilizing function.Fatty alcohol-polyoxyethylene ether (5), fatty alcohol-polyoxyethylene ether (7) play the penetration enhancer effect with the cation constituent compatibility, and synergy and stable soft, germicidal action are arranged.
Provide the embodiment that the present invention has the fabric softener and preparation method thereof of sterilizing function below.
Embodiment 1:
A kind of fabric softener with sterilizing function comprises following component by ratio of weight and the number of copies:
Quaternary amine ester (C 18) 4.5
Two alkyl quaternary amine salt (C 8-10) 1
Fatty alcohol-polyoxyethylene ether (5) 1
Fatty alcohol-polyoxyethylene ether (7) 1.5
Essence 0.15
Citric acid 0.05
Deionized water 91.8.
The fabric softener with sterilizing function with preparation 100kg present embodiment is an example, its preparation method is: by ratio of weight and the number of copies, remove ionized water 91.8kg, with wherein 70~85% be heated to 60~80 ℃, in the addingization material still, under agitation add quaternary amine ester (C then 18) 4.5kg, fatty alcohol-polyoxyethylene ether (5) 1kg, fatty alcohol-polyoxyethylene ether (7) 1kg be to dissolving fully, adds two alkyl quaternary amine salt (C when being cooled to 35 ℃~45 ℃ 8-10) 1kg, essence 0.15kg, residue deionized water, stir, be 4~5 with citric acid 0.05kg adjustment pH, stir, leave standstill, must have the fabric softener of sterilizing function.
Embodiment 2:
A kind of fabric softener with sterilizing function comprises following component by ratio of weight and the number of copies:
Quaternary amine ester (C 18) 8
Two alkyl quaternary amine salt (C 8-10) 3
Fatty alcohol-polyoxyethylene ether (5) 2
Fatty alcohol-polyoxyethylene ether (7) 1
Essence 0.2
Citric acid 0.2
Deionized water 85.6.
The fabric softener with sterilizing function with preparation 100kg present embodiment is an example, its preparation method is: by ratio of weight and the number of copies, remove ionized water 85.6kg, with wherein 70~85% be heated to 60~80 ℃, in the addingization material still, under agitation add quaternary amine ester (C then 18) 8kg, fatty alcohol-polyoxyethylene ether (5) 2kg, fatty alcohol-polyoxyethylene ether (7) 1kg add two alkyl quaternary amine salt (C when extremely dissolving, being cooled to 35 ℃~45 ℃ fully 8-10) 3kg, essence 0.2kg, residue deionized water, stir, be 4~5 with citric acid 0.2kg adjustment pH, stir, leave standstill, must have the fabric softener of sterilizing function.
Embodiment 3:
A kind of fabric softener with sterilizing function comprises following component by ratio of weight and the number of copies:
Quaternary amine ester (C 18) 10
Two alkyl quaternary amine salt (C 8-10) 2
Fatty alcohol-polyoxyethylene ether (5) 2
Fatty alcohol-polyoxyethylene ether (7) 0.5
Essence 0.5
Citric acid 0.3
Deionized water 84.7
Figure G2008102474721D00051
The fabric softener with sterilizing function with preparation 100kg present embodiment is an example, its preparation method is: by ratio of weight and the number of copies, remove ionized water 84.7kg, with wherein 70~85% be heated to 60~80 ℃, in the addingization material still, under agitation add quaternary amine ester (C then 18) 10 k, fatty alcohol-polyoxyethylene ether (5) 2kg, fatty alcohol-polyoxyethylene ether (7) 0.5kg be to dissolving fully, adds two alkyl quaternary amine salt (C when being cooled to 35 ℃~45 ℃ 8-10) 2kg, essence 0.5 kg, residue deionized water, stir, be 4~5 with citric acid 0.3kg adjustment pH, stir, leave standstill, must have the fabric softener of sterilizing function.

Claims (5)

1. the fabric softener with sterilizing function is characterized in that, is made up of by its ratio of weight and number following raw material:
Ester quat (C 18) 4.5~10
Dialkyl quaternary ammonium salt (C 8-10) 1~3
Aliphatic alcohol polyethenoxy (5) ether 1~2
Aliphatic alcohol polyethenoxy (7) ether 0.5~1.5
Essence 0.1~0.5
Citric acid 0.05~0.3
Deionized water 82.7~92.8.
2. the fabric softener with sterilizing function according to claim 1 is characterized in that, is made up of by its ratio of weight and number following raw material:
Ester quat (C 18) 4.5
Dialkyl quaternary ammonium salt (C 8-10) 1
Aliphatic alcohol polyethenoxy (5) ether 1
Aliphatic alcohol polyethenoxy (7) ether 1.5
Essence 0.15
Citric acid 0.05
Deionized water 91.8.
3. the fabric softener with sterilizing function according to claim 1 is characterized in that, is made up of by its ratio of weight and number following raw material:
Ester quat (C 18) 8
Dialkyl quaternary ammonium salt (C 8-10) 3
Aliphatic alcohol polyethenoxy (5) ether 2
Aliphatic alcohol polyethenoxy (7) ether 1
Essence 0.2
Citric acid 0.2
Deionized water 85.6.
4. the fabric softener with sterilizing function according to claim 1 is characterized in that, is made up of by its ratio of weight and number following raw material:
Ester quat (C 18) 10
Dialkyl quaternary ammonium salt (C 8-10) 2
Aliphatic alcohol polyethenoxy (5) ether 2
Aliphatic alcohol polyethenoxy (7) ether 0.5
Essence 0.5
Citric acid 0.3
Deionized water 84.7.
5. fabric softener preparation method with sterilizing function as claimed in claim 1, it is characterized in that: by ratio of weight and the number of copies, remove 82.7~92.8 parts of ionized waters, with wherein 70~85% be heated to 60~80 ℃, in the addingization material still, under agitation add ester quat (C then 18) 0.5~1.5 part of 4.5~10 part, 1~2 part in aliphatic alcohol polyethenoxy (5) ether, aliphatic alcohol polyethenoxy (7) ether are to dissolving fully, add dialkyl quaternary ammonium salt (C when being cooled to 35 ℃~45 ℃ 8-10) 1~3 part, 0.1~0.5 part in essence, residue deionized water, stirring, pH is 4~5 with 0.05~0.3 part of adjustment of citric acid, stirs, leaves standstill, and must have the fabric softener of sterilizing function.
CN2008102474721A 2008-12-31 2008-12-31 Fabric softener with bactericidal function and preparation method thereof Active CN101514305B (en)

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102493185A (en) * 2011-12-15 2012-06-13 青岛海芬海洋生物科技有限公司 Marine organism antibacterial fabric softener
CN102619087B (en) * 2012-03-02 2014-12-17 北京洛娃日化有限公司 Concentrated type fragrance clothing complaisant agent
CN103653407A (en) * 2013-12-17 2014-03-26 江苏波波熊纺织品有限公司 Anti-bacterium haze-proof mask and post-processing method thereof
CN103981713B (en) * 2014-05-21 2016-08-17 吴江市英力达塑料包装有限公司 A kind of fabric maintenance softener and preparation method thereof
CN104762812A (en) * 2015-03-11 2015-07-08 刘晓 Clothes softening agent
CN105040435A (en) * 2015-06-10 2015-11-11 南通赛晖科技发展有限公司 Production technology of antibacterial and deodorant eyelet fabric
CN105064021A (en) * 2015-09-11 2015-11-18 无锡市长安曙光手套厂 Destaticizer, preparation method and textile materials containing destaticizer
CN105421070A (en) * 2015-11-19 2016-03-23 天津天狮生物发展有限公司 Clothing care agent and preparing method thereof
CN110924154A (en) * 2019-10-23 2020-03-27 桐乡市易德纺织有限公司 Mulberry silk wool fiber blending moistening emulsion

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1128288A (en) * 1995-07-04 1996-08-07 郭玉琳 Synthetic detergent product with the functions of disinfection and sterilization and its preparation method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1128288A (en) * 1995-07-04 1996-08-07 郭玉琳 Synthetic detergent product with the functions of disinfection and sterilization and its preparation method

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Assignee: SHANGHAI LVSAN INVI-TECH DEVELOPMENT CO., LTD.

Assignor: Beijing Lusan Chemical Co., Ltd.

Contract record no.: 2012310000012

Denomination of invention: Fabric softener with bactericidal function and preparation method thereof

Granted publication date: 20110323

License type: Common License

Open date: 20090826

Record date: 20120119

CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing

Patentee after: Beijing green umbrella Technology Co.,Ltd.

Address before: 100094, Beijing Haidian District Zhongguancun Yongfeng industrial base, No. 3 North Wing Road, Czech Republic

Patentee before: Beijing Lvsan Chemistry Co.,Ltd.