CN105064021A - Destaticizer, preparation method and textile materials containing destaticizer - Google Patents
Destaticizer, preparation method and textile materials containing destaticizer Download PDFInfo
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- CN105064021A CN105064021A CN201510577829.2A CN201510577829A CN105064021A CN 105064021 A CN105064021 A CN 105064021A CN 201510577829 A CN201510577829 A CN 201510577829A CN 105064021 A CN105064021 A CN 105064021A
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Abstract
The invention provides a destaticizer for textile materials, a preparation method and the textile materials containing the destaticizer. The destaticizer is mainly prepared from the following raw materials in parts by weight: 12 to 18 parts of sodium alginate, 12 to 15 parts of polydimethylsiloxane divalent quaternary ammonium, 8 to 12 parts of polyvinyl alcohol, 4 to 7 parts of ethoxylation alkyl ammonium sulfate, 2 to 4 parts of polymethyl cyclotetrasiloxane, 3 to 5 parts of acetic acid and 120 to 130 parts of water. The destaticizer has excellent and permanent anti-static performance and can be used for static resistance of fabrics.
Description
Technical field
The invention belongs to textile material field, relate to a kind of destaticizer, preparation method and the textile material containing this destaticizer.
Background technology
Along with the increase of synthetic fiber and BLENDED FABRIC thereof, fabric after cyclic washing gradually hardening, feel is coarse, even produce electrostatic precipitation, sparkle phenomenon.Therefore the antistatic problem being textile industry always and paying close attention to.
Although there is certain progress in recent years, after arranging there is feel in textiles, hygroscopicity changes, antistatic effect affects greatly by ambient humidity, the not problem such as wash resistant.
" textile technology progress " magazine is the 2nd interim in 2006, disclose one section of name and be called in " processing method of antistatic spinning wool fabric " that disclose fabric adds the antistatic effect that appropriate nonionic surface active agent can reach certain in the soft process of Final finishing, but the hydrone that fabric absorbs when ambient humidity is less is less, the antistatic effect of non-ionic surface active agent declines very fast, and fabric is after repeatedly washing, antistatic additive and fabric are in conjunction with insecure, antistatic property declines significantly, not lastingly.
In existing softener, the representational product of most is cationic surfactant, wherein uses maximum are dioctadecyl dimethyl ammonium chloride or claim two hydrogenated-tallow group alkyl dimethyl ammonium chloride.Although its result of use is better, also there is biological degradability poor, the impact on environment may be caused.Therefore, for the textiles with skin contact and finishing agent must be safe, to people's totally nontoxic, non-stimulated, softener must be also non-sensitization.
CN104532572A provides a kind of novel destaticizer for textile material and preparation method thereof.This material is made up of the component comprising following weight portion: sodium alginate 10-20 part, dimethyl silicone polymer two quaternary amine 5-10 part, polyvinyl alcohol 3-6 part, ethoxylated alkyl ammonium sulfate 1.5-3 part, poly-methyl cyclotetrasiloxane 0.8-1.4 part, aqueous acetic acid 0.5-2 part and deionized water 100-150 part.Present invention also offers the preparation method of this destaticizer, comprise the following steps: in (1) deionized water 100-150 part, add sodium alginate 10-20 part, dimethyl silicone polymer two quaternary amine 5-10 part, polyvinyl alcohol 3-6 part, ethoxylated alkyl ammonium sulfate 1.5-3 part, at 55-70 DEG C, stir; (2) slowly add aqueous acetic acid 0.5-2 part, in a heated condition, add poly-methyl cyclotetrasiloxane 0.8-1.4 part, stir, obtain the destaticizer for textile material.But the electrostatic efficiency of this destaticizer is still very limited, poor durability.
Summary of the invention
For the problem of prior art, a kind of destaticizer for textile material, preparation method and the textile material containing this destaticizer are the object of this invention is to provide.
To achieve these goals, present invention employs following technical scheme:
For a destaticizer for textile material, it prepares primarily of following raw material by weight:
The content of described sodium alginate is such as 12.5 parts, 13 parts, 13.5 parts, 14 parts, 14.5 parts, 15 parts, 15.5 parts, 16 parts, 16.5 parts, 17 parts or 17.5 parts.
The content of described dimethyl silicone polymer two quaternary amine is such as 12.5 parts, 13 parts, 13.5 parts, 14 parts or 14.5 parts.
The content of described polyvinyl alcohol is such as 8.5 parts, 9 parts, 9.5 parts, 10 parts, 10.5 parts, 11 parts or 11.5 parts.
The content of described ethoxylated alkyl ammonium sulfate is such as 4.5 parts, 5 parts, 5.5 parts, 6 parts or 6.5 parts.
The content of described poly-methyl cyclotetrasiloxane is such as 2.5 parts, 3 parts or 3.5 parts.
Preferably, the number-average molecular weight of described polyvinyl alcohol is 3000 ~ 4000.
As above for a preparation method for the destaticizer of textile material, said method comprising the steps of:
By water, sodium alginate, dimethyl silicone polymer two quaternary amine, polyvinyl alcohol, ethoxylated alkyl ammonium sulfate mixing, at 55-70 DEG C, stir; Then, slowly add acetic acid, in a heated condition, add poly-methyl cyclotetrasiloxane, stir, obtain the destaticizer for textile material.
A kind of textile material, it contains destaticizer as above.
Compared with the prior art, the present invention has following beneficial effect:
(1) the destaticizer degradable for textile material of the present invention, environmentally friendly;
(2) destaticizer of the present invention is easier to dissolving and is dispersed in water, strong at water stability, and containing more hydrogen bond in structure, fully can contact with fabric surface, plays long-actingly to remove electrostatic interaction enduringly.
(3) destaticizer of the present invention is except having good antistatic property, also has good submissive and maintenance effect to clothing.
Detailed description of the invention
Technical scheme of the present invention is further illustrated below by detailed description of the invention.
Embodiment 1
For a destaticizer for textile material, it prepares primarily of following raw material by weight:
The number average molecular weight of described polyvinyl alcohol is 3000 ~ 4000.
As above for the preparation method of the destaticizer of textile material, said method comprising the steps of:
By water, sodium alginate, dimethyl silicone polymer two quaternary amine, polyvinyl alcohol, ethoxylated alkyl ammonium sulfate mixing, at 55-70 DEG C, stir; Then, slowly add acetic acid, in a heated condition, add poly-methyl cyclotetrasiloxane, stir, obtain the destaticizer for textile material.
Above-mentioned destaticizer is used for wool fibre, after oven dry, records the concrete condition of wool textile electrostatic half-life in table 1.
Embodiment 2
For a destaticizer for textile material, it prepares primarily of following raw material by weight:
The number average molecular weight of described polyvinyl alcohol is 3000 ~ 4000.
As above for the preparation method of the destaticizer of textile material, said method comprising the steps of:
By water, sodium alginate, dimethyl silicone polymer two quaternary amine, polyvinyl alcohol, ethoxylated alkyl ammonium sulfate mixing, at 55-70 DEG C, stir; Then, slowly add acetic acid, in a heated condition, add poly-methyl cyclotetrasiloxane, stir, obtain the destaticizer for textile material.
Above-mentioned destaticizer is used for wool fibre, after oven dry, records the concrete condition of wool textile electrostatic half-life in table 1.
Embodiment 3
For a destaticizer for textile material, it prepares primarily of following raw material by weight:
The number average molecular weight of described polyvinyl alcohol is 3000 ~ 4000.
As above for the preparation method of the destaticizer of textile material, said method comprising the steps of:
By water, sodium alginate, dimethyl silicone polymer two quaternary amine, polyvinyl alcohol, ethoxylated alkyl ammonium sulfate mixing, at 55-70 DEG C, stir; Then, slowly add acetic acid, in a heated condition, add poly-methyl cyclotetrasiloxane, stir, obtain the destaticizer for textile material.
Above-mentioned destaticizer is used for wool fibre, after oven dry, records the concrete condition of wool textile electrostatic half-life in table 1.
Embodiment 4
For a destaticizer for textile material, it prepares primarily of following raw material by weight:
The number average molecular weight of described polyvinyl alcohol is 3000 ~ 4000.
As above for the preparation method of the destaticizer of textile material, said method comprising the steps of:
By water, sodium alginate, dimethyl silicone polymer two quaternary amine, polyvinyl alcohol, ethoxylated alkyl ammonium sulfate mixing, at 55-70 DEG C, stir; Then, slowly add acetic acid, in a heated condition, add poly-methyl cyclotetrasiloxane, stir, obtain the destaticizer for textile material.
Comparative example 1
All the other are identical with embodiment 1, and the content except sodium alginate is 10 parts.
Comparative example 2
All the other are identical with embodiment 1, and the content except dimethyl silicone polymer two quaternary amine is 10 parts.
Comparative example 3
All the other are identical with embodiment 1, and the content except polyethylene glycol is 6 parts.
Comparative example 4
All the other are identical with embodiment 1, and the content except ethoxylated alkyl ammonium sulfate is 3 parts.
Comparative example 5
All the other are identical with embodiment 1, except the content of poly-methyl cyclotetrasiloxane is 1.4 parts.
Comparative example 6
All the other are identical with embodiment 1, and the content except acetic acid is 2 parts.
Comparative example 7
All the other are identical with embodiment 1, and the molecular weight except polyvinyl alcohol is 3000 ~ 4000.
Comparative example 8
Comparative example is embodiment 1 disclosed in CN104532572A.
Above-mentioned destaticizer is used for wool fibre, after oven dry, records the concrete condition of wool textile electrostatic half-life in table 1.
Applicant states, the present invention illustrates method detailed of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned method detailed, does not namely mean that the present invention must rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (4)
1., for a destaticizer for textile material, it prepares primarily of following raw material by weight:
2. destaticizer as claimed in claim 1, it is characterized in that, the number-average molecular weight of described polyvinyl alcohol is 3000 ~ 4000.
3., as claimed in claim 1 or 2 for a preparation method for the destaticizer of textile material, said method comprising the steps of:
By water, sodium alginate, dimethyl silicone polymer two quaternary amine, polyvinyl alcohol, ethoxylated alkyl ammonium sulfate mixing, at 55-70 DEG C, stir; Then, slowly add acetic acid, in a heated condition, add poly-methyl cyclotetrasiloxane, stir, obtain the destaticizer for textile material.
4. a textile material, it is containing, for example the destaticizer described in claim 1 or 2.
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| CN201510577829.2A CN105064021A (en) | 2015-09-11 | 2015-09-11 | Destaticizer, preparation method and textile materials containing destaticizer |
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| CN201510577829.2A CN105064021A (en) | 2015-09-11 | 2015-09-11 | Destaticizer, preparation method and textile materials containing destaticizer |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107190507A (en) * | 2017-06-29 | 2017-09-22 | 顾渊 | It is a kind of for destaticizer of textile material and preparation method thereof |
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| CN101619542A (en) * | 2008-07-01 | 2010-01-06 | 河南瑞贝卡发制品股份有限公司 | Preparation method of organosilicon emulsion straight fiber finishing additive and dipping process |
| CN101514305A (en) * | 2008-12-31 | 2009-08-26 | 北京绿伞化学股份有限公司 | Fabric softener with bactericidal function and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107190507A (en) * | 2017-06-29 | 2017-09-22 | 顾渊 | It is a kind of for destaticizer of textile material and preparation method thereof |
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Application publication date: 20151118 |