CN104088143A - Woolen clothes softening agent and preparation method thereof - Google Patents

Woolen clothes softening agent and preparation method thereof Download PDF

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Publication number
CN104088143A
CN104088143A CN201410338041.1A CN201410338041A CN104088143A CN 104088143 A CN104088143 A CN 104088143A CN 201410338041 A CN201410338041 A CN 201410338041A CN 104088143 A CN104088143 A CN 104088143A
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China
Prior art keywords
water
softener
ester group
wool clothing
polyethylene glycol
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Pending
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CN201410338041.1A
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Chinese (zh)
Inventor
张亚明
李旭峰
余成山
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SHANGHAI SOAP GROUP RUGAO CO Ltd
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SHANGHAI SOAP GROUP RUGAO CO Ltd
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Priority to CN201410338041.1A priority Critical patent/CN104088143A/en
Publication of CN104088143A publication Critical patent/CN104088143A/en
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Abstract

The invention discloses a woolen clothes softening agent and a preparation method thereof. The woolen clothes softening agent comprises the following components in percentage by weight: 6%-10% of ditallow carbethoxy hydroxyethyl methyl ammonium potassium sulfate ester, 0.3%-0.6% of polydimethylsiloxane di-quaternary ammonium salt, 2.5%-6% of water soluble wool fat, 4%-10% of sodium alginate, 0.2%-0.5% of essential oil, 2%-5% of polyethylene glycol and the balance being water. The preparation method comprises the following steps: dissolving ditallow carbethoxy hydroxyethyl methyl ammonium potassium sulfate ester and polydimethylsiloxane di-quaternary ammonium salt in water, adding the water soluble wool fat, and uniformly mixing to obtain a mixed solution; and adding sodium alginate and polyethylene glycol into the mixed solution, and finally adding the essential oil into the mixed solution for mixing. According to the woolen clothes softening agent provided by the invention, woolen clothes can be well softened in a use process, a layer of paper thin film is generated after the use process, the surface structure of the woolen clothes is improved, and the strength, flexibility and fluffy sense of the woolen clothes are enhanced; the raw materials are readily available, a production process is simple, the production is free of pollution, and a softening effect is remarkable.

Description

A kind of wool clothing softener and preparation method thereof
Technical field
The present invention relates to a kind of wool clothing softener, the invention still further relates to the preparation method of this wool clothing softener, belong to daily chemicals field.
Background technology
Along with social development, people's living standard is more and more higher, and the requirement of cleaning product is also more and more trended towards to functionalization, diversification, and consumer favors the cleaning product with special efficacy more.
The first exploitation later stage the 50's of 20th century of fabric softener, and successfully drop into American market, to the beginning of the sixties, on Japan and European market, also there is fabric softener, until today is still for people are widely used.
The effect of fabric softener just looks like to be the surface uniform ground floor diaphragm for fabric fibre; fiber surface is owing to having adsorbed softener; interfibrous coefficient of friction has reduced, mobility strengthens; intrinsic level and smooth, extension, the compression performance of fiber also obtained recovery, so that fabric becomes is more soft, fluffy, flexible.Same reason, because the effect of softener " diaphragm " has reduced interfibrous friction, has also just improved cotton, hair, silk, the particularly phenomenon of chemical & blended fabric static electrification to a certain extent.The function of softener product also gradually from single softener effect to multi-functional development, for example, makes clothing smoothing wrinkle, gives elasticity, is easy to flatiron, antibacterial bacteriostatic.
Softener is the chemical substance that a class can change quiet, the coefficient of kinetic friction of fiber.When changing confficient of static friction, feel touches level and smooth sense, is easy to move on fiber or fabric; When changing the coefficient of kinetic friction, the fine structure between fiber and fiber is easy to mutual movement, and namely fiber or fabric are easily deformable, and the comprehensive sensation of the two is exactly soft.
At present, on market, there are a variety of softeners, the simple softener for wool class is actually rare, at present a kind of to lack in the product having, can make wool clothing softness, quick-drying, anti-antistatic, good antimicrobial effect, and when wool clothing is collected without dehumidifying again, the product of mildew-resistant.
Summary of the invention
The object of the invention is to, for deficiency of the prior art, provides a kind of wool clothing softener and preparation method thereof, and product is submissive effective, and it is fluffy for a long time that wool clothing keeps.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of wool clothing softener, its innovative point is: described wool clothing softener comprises that 6~10% pairs of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums, 0.3~0.6% dimethyl silicone polymer two quaternary amines, 2.5~6% water-soluble lanolin, 4~10% sodium alginates, 0.2~0.5% essential oil, 2~5% polyethylene glycol and surpluses are water.
Further, described wool clothing softener comprises that 7~9% pairs of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums, 0.5~0.6% dimethyl silicone polymer two quaternary amines, 3~5% water-soluble lanolin, 6~8% sodium alginates, 0.2~0.5% essential oil, 2~5% polyethylene glycol and surpluses are water.
Further, described wool clothing softener comprises that 8% pair of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammonium, 0.6% dimethyl silicone polymer two quaternary amines, 4% water-soluble lanolin, 7% sodium alginate, 0.35% essential oil, 3% polyethylene glycol and surplus are water.
Further, in described wool clothing softener, also comprise ester quat class softener.
Further, described ester quat class softener addition is 9~18% of softener quality.
Another object of the present invention is to provide the preparation method of this wool clothing softener, comprises the following steps:
1) two ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums and dimethyl silicone polymer two quaternary amines are dissolved in the water of 70~80 ℃, then add water-soluble lanolin to mix and obtain mixed liquor;
2) sodium alginate and polyethylene glycol are added in the mixed liquor in step 1), be uniformly mixed, it is 0.2~0.5h that mixing time is set;
3) finally essential oil is added to step 2) in mixed liquor, mix 20~30min.
Beneficial effect of the present invention: wool clothing softener provided by the invention, can be so that wool clothing has the effect of fine softness in the process of using, after using, form one deck paper film, improved wool surfaces structure, strengthen intensity, flexibility and the fluffy sense of wool clothing; Preparation method of the present invention, raw material sources are extensive, and production technology is simply pollution-free, and soft effect is remarkable.
The specific embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is elaborated.
Embodiment 1
A wool clothing softener, its innovative point is: wool clothing softener comprises that 6~10% pairs of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums, 0.3~0.6% dimethyl silicone polymer two quaternary amines, 2.5~6% water-soluble lanolin, 4~10% sodium alginates, 0.2~0.5% essential oil, 2~5% polyethylene glycol and surpluses are water.
1) two ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums and dimethyl silicone polymer two quaternary amines are dissolved in the water of 70~80 ℃, then add water-soluble lanolin to mix and obtain mixed liquor;
2) sodium alginate and polyethylene glycol are added in the mixed liquor in step 1), be uniformly mixed, it is 0.2~0.5h that mixing time is set;
3) finally essential oil is added to step 2) in mixed liquor, mix 20~30min.
Embodiment 2
A wool clothing softener, its innovative point is: wool clothing softener comprises that 7~9% pairs of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums, 0.5~0.6% dimethyl silicone polymer two quaternary amines, 3~5% water-soluble lanolin, 6~8% sodium alginates, 0.2~0.5% essential oil, 2~5% polyethylene glycol and surpluses are water.
1) two ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums and dimethyl silicone polymer two quaternary amines are dissolved in the water of 70~80 ℃, then add water-soluble lanolin to mix and obtain mixed liquor;
2) sodium alginate and polyethylene glycol are added in the mixed liquor in step 1), be uniformly mixed, it is 0.2~0.5h that mixing time is set;
3) finally essential oil is added to step 2) in mixed liquor, mix 20~30min.
Embodiment 3
A wool clothing softener, its innovative point is: wool clothing softener comprises that 8% pair of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammonium, 0.6% dimethyl silicone polymer two quaternary amines, 4% water-soluble lanolin, 7% sodium alginate, 0.35% essential oil, 3% polyethylene glycol and surplus are water.
1) two ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums and dimethyl silicone polymer two quaternary amines are dissolved in the water of 70~80 ℃, then add water-soluble lanolin to mix and obtain mixed liquor;
2) sodium alginate and polyethylene glycol are added in the mixed liquor in step 1), be uniformly mixed, it is 0.2~0.5h that mixing time is set;
3) finally essential oil is added to step 2) in mixed liquor, mix 20~30min.
Softener recruitment evaluation:
Observation index Embodiment 1 Embodiment 2 Embodiment 3
Flexibility 95.0% 97.5% 99.9%
Bulkiness 96.1% 98.6% 99.9%

Claims (6)

1. a wool clothing softener, is characterized in that: described wool clothing softener comprises that 6~10% pairs of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums, 0.3~0.6% dimethyl silicone polymer two quaternary amines, 2.5~6% water-soluble lanolin, 4~10% sodium alginates, 0.2~0.5% essential oil, 2~5% polyethylene glycol and surpluses are water.
2. wool clothing softener according to claim 1, is characterized in that: described wool clothing softener comprises that 7~9% pairs of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums, 0.5~0.6% dimethyl silicone polymer two quaternary amines, 3~5% water-soluble lanolin, 6~8% sodium alginates, 0.2~0.5% essential oil, 2~5% polyethylene glycol and surpluses are water.
3. wool clothing softener according to claim 1, is characterized in that: described wool clothing softener comprises that 8% pair of ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammonium, 0.6% dimethyl silicone polymer two quaternary amines, 4% water-soluble lanolin, 7% sodium alginate, 0.35% essential oil, 3% polyethylene glycol and surplus are water.
4. wool clothing softener according to claim 1, is characterized in that: in described wool clothing softener, also comprise ester quat class softener.
5. wool clothing softener according to claim 1, is characterized in that: described ester quat class softener addition is 9~18% of softener quality.
6. a wool clothing softener preparation method claimed in claim 1, is characterized in that: comprise the following steps:
1) two ox ester group ethoxycarbonyl ethoxy potassium methyl sulfate ester group ammoniums and dimethyl silicone polymer two quaternary amines are dissolved in the water of 70~80 ℃, then add water-soluble lanolin to mix and obtain mixed liquor;
2) sodium alginate and polyethylene glycol are added in the mixed liquor in step 1), be uniformly mixed, it is 0.2~0.5h that mixing time is set;
3) finally essential oil is added to step 2) in mixed liquor, mix 20~30min.
CN201410338041.1A 2014-07-16 2014-07-16 Woolen clothes softening agent and preparation method thereof Pending CN104088143A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104480716A (en) * 2014-12-24 2015-04-01 湖州市菱湖重兆金辉丝织厂 Novel anti-pilling softener for fabrics and preparation method of softener
CN104532572A (en) * 2014-12-24 2015-04-22 湖州市菱湖重兆金辉丝织厂 Novel electrostatic removal agent for textile materials and preparation method of novel electrostatic removal agent
CN104762814A (en) * 2015-03-25 2015-07-08 苏州威尔德工贸有限公司 Linen softening agent and using method thereof
CN104893859A (en) * 2015-06-15 2015-09-09 湖州厉华妤婕联合纺织有限公司 Novel antistatic washing agent for textile fiber scarves and preparation method thereof
CN105064021A (en) * 2015-09-11 2015-11-18 无锡市长安曙光手套厂 Destaticizer, preparation method and textile materials containing destaticizer
CN105220497A (en) * 2015-10-20 2016-01-06 湖州博润实业有限公司 A kind of new type natural fiber softener and preparation method thereof
CN107237124A (en) * 2017-06-07 2017-10-10 常州建轩纺织品有限公司 A kind of fabric softening agent

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JPH06228874A (en) * 1993-01-30 1994-08-16 Lion Corp Softening agent composition
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CN102978914A (en) * 2011-12-14 2013-03-20 郑建光 Environment protection clothing softener
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CN103451922A (en) * 2013-08-21 2013-12-18 吴江市七都镇庙港雅迪针织制衣厂 Softening detergent for woolen clothes and preparation method thereof

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JPH06228874A (en) * 1993-01-30 1994-08-16 Lion Corp Softening agent composition
CN101935949A (en) * 2010-08-27 2011-01-05 上海制皂有限公司 Clothes softener
CN102978914A (en) * 2011-12-14 2013-03-20 郑建光 Environment protection clothing softener
CN103451922A (en) * 2013-08-21 2013-12-18 吴江市七都镇庙港雅迪针织制衣厂 Softening detergent for woolen clothes and preparation method thereof
CN103437170A (en) * 2013-09-14 2013-12-11 邢柯君 Multiple-effect softening and lubricating agent for textile fabrics as well as preparation method and use thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104480716A (en) * 2014-12-24 2015-04-01 湖州市菱湖重兆金辉丝织厂 Novel anti-pilling softener for fabrics and preparation method of softener
CN104532572A (en) * 2014-12-24 2015-04-22 湖州市菱湖重兆金辉丝织厂 Novel electrostatic removal agent for textile materials and preparation method of novel electrostatic removal agent
CN104762814A (en) * 2015-03-25 2015-07-08 苏州威尔德工贸有限公司 Linen softening agent and using method thereof
CN104893859A (en) * 2015-06-15 2015-09-09 湖州厉华妤婕联合纺织有限公司 Novel antistatic washing agent for textile fiber scarves and preparation method thereof
CN105064021A (en) * 2015-09-11 2015-11-18 无锡市长安曙光手套厂 Destaticizer, preparation method and textile materials containing destaticizer
CN105220497A (en) * 2015-10-20 2016-01-06 湖州博润实业有限公司 A kind of new type natural fiber softener and preparation method thereof
CN107237124A (en) * 2017-06-07 2017-10-10 常州建轩纺织品有限公司 A kind of fabric softening agent

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Application publication date: 20141008