CN103061147A - Composite antibacterial softening agent - Google Patents
Composite antibacterial softening agent Download PDFInfo
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- CN103061147A CN103061147A CN2011103217365A CN201110321736A CN103061147A CN 103061147 A CN103061147 A CN 103061147A CN 2011103217365 A CN2011103217365 A CN 2011103217365A CN 201110321736 A CN201110321736 A CN 201110321736A CN 103061147 A CN103061147 A CN 103061147A
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- silicon oil
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- composite antibiosis
- antibacterial
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Abstract
The invention discloses a composite antibacterial softening agent, and belongs to the technical field of an antibacterial finishing agent used for a textile fabric. The composite antibacterial softening agent comprises the following raw materials in parts by weight: 50-200 parts of low-yellowing amino silicone oil, 10-30 parts of acrylic emulsion, 1-3 parts of antibacterial components, 10-15 parts of emulsifier, 12-20 parts of solubilizer and 1000 parts of deionized water. The technical scheme provided by the invention is reasonable in formula, the antibacterial ratio of the composite antibacterial softening agent to staphylococcus aureus reaches more than 99%, and the antibacterial ratio of the composite antibacterial softening agent to escherichia coli reaches more than 99.2%, and fabric handfeel is softened by the composite antibacterial softening agent.
Description
Technical field
The invention belongs to the antibacterial finishing agent technical field that weaving face fabric is used, be specifically related to a kind of composite antibiosis softener
Background technology
In recent years, because the progressively raising of living standards of the people, people couple are also more and more higher with the requirement of the clothing that daily life is closely connected, and are embodied in: wear clothes and just develop towards the functionalization aspect.For feel and the comfort level that improves clothing, usually hydrophilic amino silicone oil is added behind the water emulsification as the finishing agent of fabric, use and give the better flexibility of fabric, slipping, hydrophily and yellowing resistance.Relate to the not linear amino-modified silicone oil of xanthochromia and microemulsion preparation method and application thereof such as China Patent Publication No. CN1546553A, China Patent Publication No. CN101565896A discloses a kind of quaternary amino cation modified polysiloxane softening agent and preparation method thereof; For health, the anti-microbial property of clothing also is concerned by people gradually.Utilize the anti-biotic material Nano Silver to prepare the fabric finishing agent with excellent antibacterial function, use the antibiotic fabric of this antibacterial finishing agent preparation have antibiotic fast, efficient, wide spectrum and lasting characteristics.Relate to a kind of preparation method of antibiotic soft finishing agent such as China Patent Publication No. CN102071577A, China Patent Publication No. CN101368331A relates to a kind of cotton fabric inorganic nanometer antibiotic finishing agent and preparation method thereof; But the composite fabric finishing agent that has above-mentioned several functions concurrently not yet is seen in report
Summary of the invention
Task of the present invention is to provide a kind of both had excellent antibacterial effect, the composite antibiosis softener that has again desirable anti-xanthochromia effect.
Task of the present invention is finished like this, a kind of composite antibiosis softener, and it is that raw material by following weight portion proportioning consists of:
Low-yellowing amido silicon oil 50-200 part;
Acrylic emulsion 10-30 part;
Antibacterial components 1-3 part;
Emulsifying agent 10-15 part;
Solubilizer 12-20 part;
1000 parts of deionized waters.
In a specific embodiment of the present invention, described low-yellowing amido silicon oil is a kind of or its combination in γ-Cyclohexyl Methyl Dimethoxysilane modified silicon oil, N-β aminoethyl-γ-aminopropyl methyl dimethoxysilane modified silicon oil, the N-β aminoethyl-γ-aminopropyltrimethoxysilane modified silicon oil.
In another specific embodiment of the present invention, described acrylic emulsion is butyl acrylate and acrylic acid amides copolymer emulsion or polymethylacrylic acid emulsion.
In another specific embodiment of the present invention, described antibacterial components is silver nitrate and reducing agent composition, and wherein: the weight ratio of silver nitrate and reductant is 1-4:1.
In another specific embodiment of the present invention, described reductant is tartaric acid, ascorbic acid, tannic acid or hydrazine hydrate.
Also have in the specific embodiment of the present invention, described emulsifying agent is a kind of or its combination in aliphatic acid polyethenoxy ether, anhydrous sorbitol aliphatic acid, the polyoxyethylene nonylphenol ether.
More of the present invention and in specific embodiment, described solubilizer is one or more the combination in xanthans, sodium cellulose glycolate, PVP, the diatomite.
Technical scheme prescription provided by the invention is reasonable, and the staphylococcus aureus antibiotic rate is reached more than 99%, colibacillary antibiotic rate is reached more than 99.2%, and can make fabrics feel soft.
The specific embodiment
The applicant need to prove: the following examples only are to reproduce the present invention program's preferred example, and do not mean that restriction to the present invention program, for example, although the applicant is γ-Cyclohexyl Methyl Dimethoxysilane modified silicon oil to the listed inventory of low-yellowing amido silicon oil, N-β aminoethyl-γ-aminopropyl methyl dimethoxysilane modified silicon oil, in these three kinds of N-β aminoethyl-γ-aminopropyltrimethoxysilane modified silicon oils any one, but do not show that other the similar low-yellowing amido silicon oil that excludes is left out emulsifying agent, antibacterial components and acrylic emulsion are with example.Therefore, any immaterial variation of form of having done according to the present invention program then all should be considered as technical scheme category disclosed in this invention.
Embodiment 1:
By weight:
200 parts of the silane-modified silicone oil of N-β aminoethyl-γ-aminopropyl dimethoxy;
30 parts of butyl acrylate and acrylate copolymer emulsions;
2 parts of silver nitrates;
0.6 part in ascorbic acid;
15 parts of aliphatic acid polyethenoxy ethers;
17 parts of PVP;
1000 parts of deionized waters.
Embodiment 2:
By weight:
50 parts of γ-Cyclohexyl Methyl Dimethoxysilane modified silicon oil;
26 parts of polymethylacrylic acid emulsions;
1.2 parts of silver nitrates;
1 part in tartaric acid;
12 parts in anhydrous sorbitol aliphatic acid;
10 parts of PVP;
2 parts of xanthans;
1000 parts of deionized waters.
Embodiment 3:
By weight:
100 parts of N-β aminoethyl-γ-aminopropyl methyl dimethoxysilane modified silicon oil;
72 parts of N-β aminoethyls-γ-aminopropyltrimethoxysilane modified silicon oil;
16 parts of butyl acrylate and acrylic acid amides copolymer emulsions;
1.6 parts of silver nitrates;
0.8 part of tannic acid;
10 parts of polyoxyethylene nonylphenol ether;
14 parts of sodium cellulose glycolates;
1000 parts of deionized waters.
Embodiment 4:
By weight:
50 parts of γ-Cyclohexyl Methyl Dimethoxysilane modified silicon oil;
30 parts of N-β aminoethyl-γ-aminopropyl methyl dimethoxysilane modified silicon oil;
20 parts of N-β aminoethyls-γ-aminopropyltrimethoxysilane modified silicon oil;
21 parts of polymethylacrylic acid emulsions;
1.8 parts of silver nitrates;
0.5 part of hydrazine hydrate;
6 parts of aliphatic acid polyethenoxy ethers;
8 parts in anhydrous sorbitol aliphatic acid;
10 parts of sodium cellulose glycolates;
10 parts of PVP;
1000 parts of deionized waters.
Embodiment 5:
By weight:
85 parts of N-β aminoethyls-γ-aminopropyltrimethoxysilane modified silicon oil;
12 parts of polymethylacrylic acid emulsions;
1.5 parts of silver nitrates;
1.5 parts in ascorbic acid;
11 parts of aliphatic acid polyethenoxy ethers;
18 parts of PVP;
2 parts in diatomite;
1000 parts of deionized waters.
The technique effect that has the excellence shown in the following table by the resulting composite antibiosis softener of above-described embodiment 1-5.
As can be seen from the above table, resulting fabric had both had good feel and yellowing resistance after using composite antibiosis softener of the present invention to process, and had again good antibacterial effect, had realized preferably purpose of the present invention
Claims (7)
1.
A kind of composite antibiosis softener is characterized in that it is that raw material by following weight portion proportioning consists of:
Low-yellowing amido silicon oil 50-200 part;
Acrylic emulsion 10-30 part;
Antibacterial components 1-3 part;
Emulsifying agent 10-15 part;
Solubilizer 12-20 part;
1000 parts of deionized waters.
2.
Composite antibiosis softener according to claim 1 is characterized in that described low-yellowing amido silicon oil is a kind of or its combination in γ-Cyclohexyl Methyl Dimethoxysilane modified silicon oil, N-β aminoethyl-γ-aminopropyl methyl dimethoxysilane modified silicon oil, the N-β aminoethyl-γ-aminopropyltrimethoxysilane modified silicon oil.
3.
Composite antibiosis softener according to claim 1 is characterized in that described acrylic emulsion is butyl acrylate and acrylic acid amides copolymer emulsion or polymethylacrylic acid emulsion.
4.
Composite antibiosis softener according to claim 1 is characterized in that described antibacterial components is silver nitrate and reducing agent composition, and wherein: the weight ratio of silver nitrate and reductant is 1-4:1.
5.
Composite antibiosis softener according to claim 4 is characterized in that described reductant is tartaric acid, ascorbic acid, tannic acid or hydrazine hydrate.
6.
Composite antibiosis softener according to claim 1 is characterized in that described emulsifying agent is a kind of or its combination in aliphatic acid polyethenoxy ether, anhydrous sorbitol aliphatic acid, the polyoxyethylene nonylphenol ether.
7.
Composite antibiosis softener according to claim 1 is characterized in that described solubilizer is one or more the combination in xanthans, sodium cellulose glycolate, PVP, the diatomite
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CN2011103217365A CN103061147A (en) | 2011-10-21 | 2011-10-21 | Composite antibacterial softening agent |
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CN2011103217365A CN103061147A (en) | 2011-10-21 | 2011-10-21 | Composite antibacterial softening agent |
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CN103061147A true CN103061147A (en) | 2013-04-24 |
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CN2011103217365A Pending CN103061147A (en) | 2011-10-21 | 2011-10-21 | Composite antibacterial softening agent |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103696270A (en) * | 2013-12-18 | 2014-04-02 | 江苏波波熊纺织品有限公司 | Mixed anti-bacteria cashmere softening agent |
CN103710993A (en) * | 2013-11-13 | 2014-04-09 | 皖西学院 | Preparation technology for silver-silicone composite antiseptic with permanent antibacterial effect |
CN105648752A (en) * | 2016-02-29 | 2016-06-08 | 苏州纺友新材料有限公司 | Environment-friendly fabric softener and preparation method thereof |
CN105970621A (en) * | 2016-05-31 | 2016-09-28 | 太仓协大申泰羊毛衫有限公司 | Softening agent special for wool fabric and preparation method of softening agent |
CN106085623A (en) * | 2016-06-06 | 2016-11-09 | 湖北新海鸿化工有限公司 | Self-curing function car washing liquid |
CN107675497A (en) * | 2017-11-14 | 2018-02-09 | 湖州南浔金吉宝纺织有限公司 | A kind of pure-cotton fabric increases soft method |
CN107815857A (en) * | 2017-11-10 | 2018-03-20 | 宾阳县东弘五金工艺品有限公司 | A kind of fabric softener |
CN108914570A (en) * | 2018-07-23 | 2018-11-30 | 海安润德服装有限公司 | A kind of cashmere softening agent and preparation method thereof with bacteria resistance function |
CN109162093A (en) * | 2018-07-18 | 2019-01-08 | 苏州市天翱特种织绣有限公司 | A kind of preparation method of skin care antibacterial cotton flax fabric |
WO2020019145A1 (en) * | 2018-07-24 | 2020-01-30 | 海安润德服装有限公司 | Cashmere softener having antibacterial function, and preparation method therefor |
CN111469244A (en) * | 2020-05-08 | 2020-07-31 | 中南林业科技大学 | Mildew preventive suitable for recombined bamboo and using method thereof |
CN113481732A (en) * | 2021-08-03 | 2021-10-08 | 恒天(江苏)化纤家纺科技有限公司 | Antibacterial and mildewproof fabric and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0193506A (en) * | 1987-10-06 | 1989-04-12 | Yuji Kato | Insecticidal and softener composition |
JPH0247371A (en) * | 1988-08-08 | 1990-02-16 | Kiyoueishiya Yushi Kagaku Kogyo Kk | Silicone-based softening agent composition for textile |
CN1948606A (en) * | 2006-10-20 | 2007-04-18 | 深圳清华大学研究院 | Textiles antibacterial finishing agent, its preparation method and application |
CN101368331A (en) * | 2008-09-25 | 2009-02-18 | 湖南多喜爱纺织科技有限公司 | Cotton fabric inorganic nanometer antibiotic finishing agent and preparation method thereof |
-
2011
- 2011-10-21 CN CN2011103217365A patent/CN103061147A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0193506A (en) * | 1987-10-06 | 1989-04-12 | Yuji Kato | Insecticidal and softener composition |
JPH0247371A (en) * | 1988-08-08 | 1990-02-16 | Kiyoueishiya Yushi Kagaku Kogyo Kk | Silicone-based softening agent composition for textile |
CN1948606A (en) * | 2006-10-20 | 2007-04-18 | 深圳清华大学研究院 | Textiles antibacterial finishing agent, its preparation method and application |
CN101368331A (en) * | 2008-09-25 | 2009-02-18 | 湖南多喜爱纺织科技有限公司 | Cotton fabric inorganic nanometer antibiotic finishing agent and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
刘瑞云: "亲水抗菌柔软整理剂的制备与应用", 《第六届全国印染后整理学术研讨会论文集》 * |
王清宏: "纳米银粉的制备及其在内墙抗菌涂料中的应用", 《粉末冶金工业》 * |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103710993A (en) * | 2013-11-13 | 2014-04-09 | 皖西学院 | Preparation technology for silver-silicone composite antiseptic with permanent antibacterial effect |
CN103710993B (en) * | 2013-11-13 | 2016-05-04 | 皖西学院 | A kind of preparation technology of the silver-colored silicon complex antimicrobials with permanent antibacterial action |
CN103696270A (en) * | 2013-12-18 | 2014-04-02 | 江苏波波熊纺织品有限公司 | Mixed anti-bacteria cashmere softening agent |
CN105648752A (en) * | 2016-02-29 | 2016-06-08 | 苏州纺友新材料有限公司 | Environment-friendly fabric softener and preparation method thereof |
CN105970621A (en) * | 2016-05-31 | 2016-09-28 | 太仓协大申泰羊毛衫有限公司 | Softening agent special for wool fabric and preparation method of softening agent |
CN106085623A (en) * | 2016-06-06 | 2016-11-09 | 湖北新海鸿化工有限公司 | Self-curing function car washing liquid |
CN107815857A (en) * | 2017-11-10 | 2018-03-20 | 宾阳县东弘五金工艺品有限公司 | A kind of fabric softener |
CN107675497A (en) * | 2017-11-14 | 2018-02-09 | 湖州南浔金吉宝纺织有限公司 | A kind of pure-cotton fabric increases soft method |
CN109162093A (en) * | 2018-07-18 | 2019-01-08 | 苏州市天翱特种织绣有限公司 | A kind of preparation method of skin care antibacterial cotton flax fabric |
CN108914570A (en) * | 2018-07-23 | 2018-11-30 | 海安润德服装有限公司 | A kind of cashmere softening agent and preparation method thereof with bacteria resistance function |
WO2020019145A1 (en) * | 2018-07-24 | 2020-01-30 | 海安润德服装有限公司 | Cashmere softener having antibacterial function, and preparation method therefor |
CN111469244A (en) * | 2020-05-08 | 2020-07-31 | 中南林业科技大学 | Mildew preventive suitable for recombined bamboo and using method thereof |
CN111469244B (en) * | 2020-05-08 | 2022-04-05 | 中南林业科技大学 | Mildew preventive suitable for recombined bamboo and using method thereof |
CN113481732A (en) * | 2021-08-03 | 2021-10-08 | 恒天(江苏)化纤家纺科技有限公司 | Antibacterial and mildewproof fabric and preparation method thereof |
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Application publication date: 20130424 |