CN106085623A - Self-curing function car washing liquid - Google Patents
Self-curing function car washing liquid Download PDFInfo
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- CN106085623A CN106085623A CN201610396531.6A CN201610396531A CN106085623A CN 106085623 A CN106085623 A CN 106085623A CN 201610396531 A CN201610396531 A CN 201610396531A CN 106085623 A CN106085623 A CN 106085623A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The present invention proposes a kind of Self-curing function car washing liquid, and this car washing liquid is suitable for the automobile of all appearance colors, including white car, and uses general unmodified amido silicon oil, is just only applicable to dark cars, such as redness, Lycoperdon polymorphum Vitt, black car;By being added with Quaternary Silicone Polymers and conducting modification of surface hydroxy group TiO2, the antibacterial ability of vehicle body can be carried, improve surface water repellency, reach the effect of long-term Self-curing;This car washing liquid is neutral, non-stimulated to skin, corrosion-free to vehicle body coating, and environmentally safe integrates carwash, waxing and care action, more laborsaving.
Description
Technical field
The present invention relates to automobile washing nursing materials field, particularly relate to a kind of Self-curing function car washing liquid.
Background technology
Traditional automobile carwash waxing technique includes cleaning, drying or dry up, waxing, drying or drying up, wipe light multiple tracks work
Sequence, uses different solvents, the longest, and consumes a large amount of labour, also wastes a lot of solvent, pollutes environment.
Chinese patent CN1195685A, discloses one and protects car automobile liquid, consisting of: Polyethylene Glycol, paraffin, silicone oil,
Emulsifying agent, Emulsification of Paraffin needs heating, cooling, and time-consuming power consumption, stability of emulsion is poor, after this content of wax car washing liquid carwash, without bright
Light, without water-proof function, clean effect is not got better.
Chinese patent CN102115638A, discloses a kind of environmentally friendly vehicle cleaning and lustering agent, uses Fructus Gleditsia extracting solution, methyl
Silicone oil, palm wax, emulsifying agent, propylene glycol and water make environmental-friendly car washing liquid, and using palm wax in formula is the Main Ingredients and Appearance of glazing,
It is high that palm wax comes from Brazil, shortage of resources, price, and fusing point, is difficult to emulsifying.This product is waxed for automobile washing, light
Degree is also the most inconspicuous because be solid wax, be solid suspension at normal temperatures, after spraying on vehicle body, after it must be waited again dry,
Again could be shinny with rag firmly friction, due to it is necessary to have wipe this one procedure of light, thus the most laborsaving.
Except problem above, current car washing liquid, after carwash, is parked for a long time under natural environment, easily grows thin
Bacterium, causes mouldy or even corrosion.
Summary of the invention
In view of this, the present invention proposes one and has that antibacterial effect, clean effect be good, labour-saving Self-curing function carwash
Liquid.
The technical scheme is that and be achieved in that: a kind of Self-curing function car washing liquid, including following components, methyl silicon
Oil, non yellowing amido silicon oil, conducting modification of surface hydroxy group TiO2, emulsifying agent, antifreezing agent and preservative.
On the basis of above technical scheme, it is preferred that each constituent mass number is as follows,
On the basis of above technical scheme, it is preferred that described methyl-silicone oil uses the viscosity of 0.5~5 part to be 50~300
The methyl-silicone oil that viscosity is 500~10000 of the methyl-silicone oil of centistoke and 0.5~5 part mixes.
On the basis of above technical scheme, it is preferred that described non yellowing amido silicon oil includes epoxy-modified amino silicone
Oil, carbonate-modified amido silicon oil, lactone-modified amido silicon oil, amide amido silicon oil or piperazine modified amino silicon oil.
On the basis of above technical scheme, it is preferred that described conducting modification of surface hydroxy group TiO2Preparation process is as follows, by salt
Acid, glacial acetic acid, positive four butyl esters of metatitanic acid, dehydrated alcohol, sodium ascorbyl phosphate aqueous solution, react 6-at being placed in 170-280 DEG C
12h, obtains modifying titanium dioxide;Wherein, positive four butyl esters of metatitanic acid of each molfraction, corresponding interpolation 0.8~1.2 molfractions
Hydrochloric acid, 1~3 glacial acetic acid of molfraction, and the sodium ascorbyl phosphate of 0.01~0.1 molfraction.
On the basis of above technical scheme, it is preferred that described emulsifying agent includes the non-ionic surface of 1~5 mass fractions
Activating agent and the anion surfactant of 1~10 mass fractions.Preferably, described nonionic surfactant includes alkylol
Polyoxyethylene ether series of surfactants, fatty acid ester polyvinyl ester series of surfactants, or alkyl polyglucoside class surface activity
Agent;Anion surfactant includes alkylol polyethers sulfuric acid.
On the basis of above technical scheme, it is preferred that described quaternary ammonium salt uses organosilicon quaternary ammonium salt, concrete, uses
DC-5700。
On the basis of above technical scheme, it is preferred that described preservative uses propylene glycol, ethylene glycol or Polyethylene Glycol.
On the basis of above technical scheme, it is preferred that also include essence.
The Self-curing function car washing liquid of the present invention has the advantages that relative to prior art
(1) amido silicon oil is the polysiloxanes of band amido, and emulsifying own is intended to acid adding becomes amine salt, carries weak positive charge, with
Electronegative vehicle body has electrostatic adsorption, after carwash, becomes monomolecular film to be closely adhered on body of a motor car surface, and has
There are water proofing property and brightness;When typically washing by water, dust greasy dirt is taken away by the water with cleaning mixture, and amino silicone oil film is difficult to by water
Wash away, and the modified amino silicon oil that the amido silicon oil used by the present invention is primary amine groups to be closed, it is difficult under action of ultraviolet light
Xanthochromia;This car washing liquid is suitable for the automobile of all appearance colors, including white car, and uses general unmodified amido silicon oil,
Just it is only applicable to dark cars, such as redness, Lycoperdon polymorphum Vitt, black car;
(2) by being added with Quaternary Silicone Polymers and conducting modification of surface hydroxy group TiO2, the antibacterial ability of vehicle body can be carried, improve surface
Water repellency, reaches the effect of long-term Self-curing;
(3) this car washing liquid is neutral, non-stimulated to skin, corrosion-free to vehicle body coating, environmentally safe, collection carwash,
Waxing and care action are in one, more laborsaving.
Detailed description of the invention
Below in conjunction with embodiment of the present invention, the technical scheme in embodiment of the present invention is carried out clearly and completely
Describe, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Base
Embodiment in the present invention, it is all that those of ordinary skill in the art are obtained under not making creative work premise
Other embodiments, broadly fall into the scope of protection of the invention.
Embodiment 1
First, conducting modification of surface hydroxy group TiO is prepared2。
By 0.8 mole hydrochloride, 1 mole of glacial acetic acid, 1 mole of positive four butyl ester of metatitanic acid, dehydrated alcohol, 0.01 mole of phosphoric acid sodium salt
Aqueous solution, is placed at 170 DEG C reacting 6h, obtains modifying titanium dioxide.
The Self-curing function car washing liquid of the present embodiment, each component formula is as follows:
In 500 milliliters of plastic cups, silicone oil, emulsifier for mixing are uniformly obtained oil phase material;Acetic acid, propylene glycol are added
Deionized water obtains aqueous phase material;In high speed homogenizing machine, open homogenizer, aqueous phase material is added in oil phase material by several times
Carrying out emulsifying, the rotating speed of homogenizer is 2000 4000rpm, and homogenizing, after 30 minutes, obtains Self-curing function car washing liquid.
The mean diameter recording emulsion is 1 micron, then carries out mechanically stable test, heat stabilization test, low-temperature stabilization examination
Test and use tap water dilution test, the most qualified.
Embodiment 2
First, conducting modification of surface hydroxy group TiO is prepared2。
By 0.8~1.2 mole hydrochlorides, 1~3 mole of glacial acetic acid, 1 mole of positive four butyl ester of metatitanic acid, dehydrated alcohol, 0.01~
0.1 mole of phosphoric acid sodium-salt aqueous solution mixing, reacts 6-12h, obtains modifying titanium dioxide at being placed in 170-280 DEG C.
The Self-curing function car washing liquid of the present embodiment, each component formula is as follows:
In 500 milliliters of plastic cups, silicone oil, emulsifier for mixing are uniformly obtained oil phase material;Acetic acid, propylene glycol are added
Deionized water obtains aqueous phase material;In high speed homogenizing machine, open homogenizer, aqueous phase material is added in oil phase material by several times
Carrying out emulsifying, the rotating speed of homogenizer is 2000 4000rpm, and homogenizing, after 30 minutes, obtains Self-curing function car washing liquid.
The mean diameter recording emulsion is 1 micron, then carries out mechanically stable test, heat stabilization test, low-temperature stabilization examination
Test and use tap water dilution test, the most qualified.
After above-mentioned car washing liquid 200 grams is watered 10 times, obtain 2 liters of carwash working solutions, drench washing working solution with cotton towel
The most standby, when body of a motor car earth is too many, after first rinsing well with tap water, then smear wiping car with the towel being stained with full carwash working solution
Body, can smear vehicle body time for the most about 20 minutes, and after then rinsing one time with tap water, vehicle body becomes cleaning light.Automobile used
Working solution also remains half, it was demonstrated that 100 grams of car washing liquids just can wash a car.
The car washing liquid of 200 grams is watered 10 times and becomes 2 liters of carwash working solutions, after filtered through gauze, draw above-mentioned mistake with spray gun
The working solution filtered, is sprayed on body of a motor car, and glass first hides with plastic paper, is then being jetted through carwash with mop or electric mop
Drag on the vehicle body of working solution one time, then with high pressure water washing one time, just obtain cleaning the body of a motor car of bright burn, whole process
It it is 15 minutes.
Embodiment 3
First, conducting modification of surface hydroxy group TiO is prepared2。
By 0.8~1.2 mole hydrochlorides, 1~3 mole of glacial acetic acid, 1 mole of positive four butyl ester of metatitanic acid, dehydrated alcohol, 0.01~
0.1 mole of phosphoric acid sodium-salt aqueous solution mixing, reacts 6-12h, obtains modifying titanium dioxide at being placed in 170-280 DEG C.
The Self-curing function car washing liquid of the present embodiment, each component formula is as follows:
The foregoing is only the better embodiment of the present invention, not in order to limit the present invention, all the present invention's
Within spirit and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
The foregoing is only the better embodiment of the present invention, not in order to limit the present invention, all spirit in the present invention and former
Within then, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (10)
1. a Self-curing function car washing liquid, it is characterised in that: include following components, methyl-silicone oil, non yellowing amido silicon oil, table
Face hydroxyl modification TiO2, emulsifying agent, quaternary ammonium salt and preservative.
2. Self-curing function car washing liquid as claimed in claim 1, it is characterised in that: each constituent mass number is as follows,
3. Self-curing function car washing liquid as claimed in claim 1, it is characterised in that: described methyl-silicone oil uses 0.5~5 part
Viscosity is the methyl-silicone oil of 50~300 centistokes and the methyl-silicone oil that viscosity is 500~10000 of 0.5~5 part mixes.
4. Self-curing function car washing liquid as claimed in claim 1, it is characterised in that: described non yellowing amido silicon oil includes epoxy
Base modified amino silicon oil, carbonate-modified amido silicon oil, lactone-modified amido silicon oil, amide amido silicon oil or piperazine modified amido
Silicone oil.
5. Self-curing function car washing liquid as claimed in claim 1, it is characterised in that: described conducting modification of surface hydroxy group TiO2Preparation step
Rapid as follows, by hydrochloric acid, glacial acetic acid, positive four butyl esters of metatitanic acid, dehydrated alcohol, sodium ascorbyl phosphate aqueous solution, it is placed in 170-280 DEG C
Lower reaction 6-12h, obtains modifying titanium dioxide;Wherein, positive four butyl esters of metatitanic acid of each molfraction, corresponding interpolation 0.8~1.2
The hydrochloric acid of molfraction, 1~3 glacial acetic acid of molfraction, and the sodium ascorbyl phosphate of 0.01~0.1 molfraction.
6. Self-curing function car washing liquid as claimed in claim 1, it is characterised in that: described emulsifying agent includes 1~5 mass fractions
Nonionic surfactant and the anion surfactant of 1~10 mass fractions.
7. Self-curing function car washing liquid as claimed in claim 6, it is characterised in that: described nonionic surfactant includes alkane
Base polyoxyethylenated alcohol series of surfactants, fatty acid ester polyvinyl ester series of surfactants, or alkyl polyglucoside class surface
Activating agent;Anion surfactant includes alkylol polyethers sulfuric acid.
8. Self-curing function car washing liquid as claimed in claim 1, it is characterised in that: described quaternary ammonium salt uses organosilicone quaternary ammonium
Salt.
9. Self-curing function car washing liquid as claimed in claim 1, it is characterised in that: described preservative uses propylene glycol, second two
Alcohol or Polyethylene Glycol.
10. Self-curing function car washing liquid as claimed in claim 1, it is characterised in that: also include essence.
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CN109810800A (en) * | 2019-02-02 | 2019-05-28 | 江苏云瀚股份有限公司 | Expelling water light self-emulsifying composition |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107987978A (en) * | 2017-12-14 | 2018-05-04 | 临沂大学 | Bath of glass, its preparation method and application |
CN107987978B (en) * | 2017-12-14 | 2020-04-03 | 临沂大学 | Glass water, preparation method and application thereof |
CN109810800A (en) * | 2019-02-02 | 2019-05-28 | 江苏云瀚股份有限公司 | Expelling water light self-emulsifying composition |
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Application publication date: 20161109 |