CN100497573C - Cleaning agent - Google Patents

Cleaning agent Download PDF

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Publication number
CN100497573C
CN100497573C CNB2005100905599A CN200510090559A CN100497573C CN 100497573 C CN100497573 C CN 100497573C CN B2005100905599 A CNB2005100905599 A CN B2005100905599A CN 200510090559 A CN200510090559 A CN 200510090559A CN 100497573 C CN100497573 C CN 100497573C
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weight parts
clean
out system
antioxidant
weight
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Expired - Fee Related
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CNB2005100905599A
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CN1730639A (en
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曲文涛
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Individual
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Abstract

The invention discloses a cleaning agent, which is a mixture that comprises buffering agent, chelating agent, anti-oxidizing agent, auxiliary solvent and surface active agent, which comprises at least alkyl alcohol ethoxy sodium sulfate (AES) and Cocanidoproryl Betaine alkali. The cleaning agent can be used for cleaning non-contact lens or automobile windscreen.

Description

A kind of clean-out system
Technical field
The present invention relates to a kind of clean-out system, relate in particular to a kind of clean-out system and using method thereof that is applied to contactless eyeglass or windshield cleaning field.
Background technology
Contactless eyeglass is very accurate optics, especially the coating processing of antireflection has been done on its surfaces such as Resins, epoxy eyeglass, quartzy eyeglass, directly can be stained with oil stain and fingerprint with the hand touch, very big to coating damage, influence the optical property and the image quality of glasses, can cause further injury user's eyesight.
After but glasses used, eyeglass more or less also can be stained with dust, and simple method is to blow off with blowing up a balloon, or brushes gently with banister brush.Blow and do not go also to brush if eyeglass is enclosed sweat mark, fruit juice, hair spray (agent), makeup etc., that will use special-purpose glasses clean-out system wiping gently, do not seem the softish paper and come eyeglass with paper handkerchief etc., these paper all include than the wood pulp that is easier to the scratch coating, accidentally can damage the rapid wear coating on the eyeglass.Before wiping, guarantee the no visible dust granule in surface, to avoid dust granule mill presbyopic glasses sheet.During wiping should according to from the center to around lightly along same direction wiping, do not wipe repeatedly back and forth, to avoid the eyeglass that frays.Be noted that when using clean-out system clean-out system is sticked in wiping camera lens on lens paper or the clean finger tripe, and clean-out system directly should not be dropped in eyeglass.
In addition, definitely can not at will use other chemical substance wiping eyeglasses, this is that such clean-out system still can have certain damage to eyeglass and coating thereof, and might bring some moisture issues because the chemical of other kind is not special in cleaning the eyeglass design.
The prescription of some clean-out system was to use ether and alcohol in the past.According to our test, clean the back eyeglass and will stay an oil membrane after the ether volatilization, must also to use lens paper again wiping use inconvenience once, and effect is not very desirable.
Summary of the invention
The present invention develops in order to solve above-mentioned problems of the prior art.
Clean-out system of the present invention is based on this clean-out systems of 100 weight parts liquid washing agent for the deionized water solution be made up of the water of the antifreeze membrane-forming agent of the tensio-active agent of the solubility promoter of the antioxidant of the sequestrant of the buffer reagent of 3~5 weight parts, 0.2~0.3 weight part, 0.02~0.8 weight part, 2~6 weight parts, 11~22 weight parts, 8~12 weight parts and its surplus.
The present invention is preferably based on this clean-out systems of 100 weight parts deionized water solution for being made up of the water of the antifreeze membrane-forming agent of the tensio-active agent of the solubility promoter of the antioxidant of the sequestrant of the buffer reagent of 4 weight parts, 0.25 weight part, 0.1 weight part, 4 weight parts, 19 weight parts, 10 weight parts and its surplus.
Tensio-active agent in the clean-out system of the present invention is for comprising in alkyl alcohol polyethenoxy ether sodium sulfate, the cocoamidopropyl betaine one or more at least.
Buffer reagent in the clean-out system of the present invention is a coconut oil diethanol amide.
The antioxidant of clean-out system of the present invention is this antioxidant based on 100 weight parts, comprises the 5-chloro-2-methyl-different azoles quinoline ketone of 0.8~1.2 weight part, the different azoles quinoline of the 2-methyl-4-ketone of 0.3~0.4 weight part, the MgCl of 21.0~24.5 weight parts 2Deionized water solution.Be preferably this antioxidant, comprise the 5-chloro-2-methyl-different azoles quinoline ketone of 1.15 weight parts, the different azoles quinoline of the 2-methyl-4-ketone of 0.35 weight part, the MgCl of 23.0 weight parts based on 100 weight parts 2Deionized water solution.
Sequestrant in the clean-out system of the present invention is the EDTA disodium salt.
Solubility promoter in the clean-out system of the present invention is that concentration is 95% industrial alcohol and sodium-chlor.
Antifreeze membrane-forming agent in the clean-out system of the present invention is one or both in ethylene glycol or the propylene glycol.
Certain material when even concentration is very little, can significantly reduce the surface tension of water with air after it is water-soluble, or water is with the interfacial tension of other materials, and then this material is called tensio-active agent.Water soluble surfactant active's molecule all has unsymmetrical structure and has the polar characteristics.
SURFACTANT ADSORPTION can change the interfacial tension of the physical properties, particularly each phase interface of system so greatly on the interface of the aqueous solution with other phases.
Hydrophilic radical is showed when water-soluble according to tensio-active agent electrically, can be divided into negatively charged ion, positively charged ion, neutrality and amphoterics to tensio-active agent.
Some metal ion such as Ca in sequestrant and the solution 2+, Mg 2+Deng forming the stable chelated body, thereby make washing composition have the function of anti-hard water, when cleaning, can contain Ca with some of lens surface again specific to eyeglass 2+, Mg 2+The material chelating and reach cleanup action.
The adding of some auxiliary agent can be played following effect: make the pH value of clean-out system can keep stable; Can increase the emulsifying capacity and the emulsifying stability of clean-out system; Can make solution have the ability of good suspending power and stable suspersion system, can prevent dirt sedimentation once more.
The selection principle of tensio-active agent, chelating, auxiliary agent is: the clean-out system that (1) is formed has stronger cleansing power; (2) chemical property is soft, does not damage eyeglass and coating; (3) chemical action does not take place between the component and component was lost efficacy; (4) has good rinsability.
The use temperature of preparation washings and concentration should be determined by concrete experiment.
Use clean-out system of the present invention to clean eyeglass scrubbing rate and reached more than 98%, and the cleaning efficiency of using organic solvent of the prior art to clean only is 60%-70%, and easily eyeglass and lens surface coating are caused damage.And the relative lens surface wettability of clean-out system of the present invention is low; only need gently get rid of several following behind the back clean-out system wiping eyeglass of the present invention of use; clean-out system and dissolve spot and can break away from eyeglass; clean-out system of the present invention is manipulated simple, quick and easy, has significant cleaning performance and has the functions such as antiultraviolet coating, sterilization of protection resin lens.
The clean-out system that has added antifreeze membrane-forming agent not only can use under-30~40 ℃ temperature condition, but also can form layer protecting film at contactless eyeglass or windshield surface, plays the effect that protection is cleaned article.
Prepare the method for clean-out system of the present invention, comprising:
A. take by weighing a certain amount of deionized water in proportion and add in the material-compound tank, stir and be heated to 40~50 ℃, keep temperature then;
B. take by weighing certain amount of surfactant in proportion and add in the jar, it is transparent to solution to stir;
C. take by weighing in proportion during a certain amount of sequestrant adds jar, stir 18~22 minutes transparent to solution;
D. take by weighing a certain amount of buffer reagent in proportion and add in the jar, continue to stir;
E. take by weighing a certain amount of solubility promoter in proportion and add in the jar, stir;
F. take by weighing certain amount of surfactant in proportion and add in the jar, stirred 15~25 minutes, transparent to solution;
G. take by weighing a certain amount of deionized water and scrub the equipment that takes up raw material, then washing lotion is poured in the retort, stir evenly to solution transparent;
H. take by weighing a certain amount of antifreeze membrane-forming agent in proportion and add in the jar, stir evenly to solution transparent;
I. take by weighing a certain amount of antioxidant in proportion and add in the jar, stir, being adjusted to viscosity of mixed liquid with sodium-chlor is that 0.1~0.6mPas obtains product.
Embodiment
Embodiment 1
Guarantee the clean and tidy drying of output zone and equipment, material-compound tank is cleaned decontamination, and whole valve closes.The production process of this product is simple mixing.
Take by weighing 60 kilograms of deionized waters, add in the material-compound tank, start stirring, speed setting is at 35~45 rev/mins.Open heating system, water is heated to 40~50 ℃, turn heating power down, temperature remains on this temperature;
Take by weighing 8 kilograms of tensio-active agent alkyl alcohol polyethenoxy ether sodium sulfates (AES) and add in the jar, it is transparent to solution to stir;
Take by weighing during 0.2 kilogram of sequestrant EDTA disodium salt adds jar, stir 20 minutes transparent to solution;
Take by weighing 3 kilograms of buffer reagent coconut oil diethanol amides and add in the jar, continue to stir;
Taking by weighing 4 kilograms of solubility promoter concentration is that 95% industrial alcohol adds in the jar, stirs evenly;
Take by weighing 8 kilograms of tensio-active agent cocoamidopropyl betaine and add in the jar, stirred 15~25 minutes, transparent to solution;
Take by weighing 10 kilograms of deionized waters and scrub the equipment that takes up raw material, then washing lotion is poured in the retort, stir evenly to solution transparent;
The antifreeze membrane-forming agent ethylene glycol that takes by weighing 8 kilograms adds in the jar, stirs evenly to solution transparent;
Taking by weighing 0.05 kilogram of antioxidant adds in the jar, stir, be adjusted to the suitable product that obtains of viscosity with sodium-chlor, wherein antioxidant consist of this antioxidant based on 100 weight parts, comprise the 5-chloro-2-methyl-different azoles quinoline ketone of 1.15 weight parts, the different azoles quinoline of the 2-methyl-4-ketone of 0.35 weight part, the MgCl of 23.0 weight parts 2Deionized water solution.
Embodiment 2
Guarantee the clean and tidy drying of output zone and equipment, material-compound tank is cleaned decontamination, and whole valve closes.The production process of this product is simple mixing, and temperature is up to 60 ℃
Prescription is: 60 kilograms of deionized waters, 9 kilograms of tensio-active agent alkyl alcohol polyethenoxy ether sodium sulfates (AES), 0.3 kilogram sequestrant EDTA disodium salt, 5 kilograms of buffer reagent coconut oil diethanol amides, 6 kilograms of Auxiliaries Industry ethanol, 12 kilograms of tensio-active agent cocoamidopropyl betaine, 13 kilograms of deionized waters (in order to scrub the equipment that takes up raw material), 10 kilograms of antifreeze membrane-forming agent ethylene glycol and 0.2 kilogram of antioxidant (composition of antioxidant is identical with the composition of the antioxidant described in the embodiment 1).
Then according to preparation method's step preparing product of embodiment 1.
Embodiment 3
Guarantee the clean and tidy drying of output zone and equipment, material-compound tank is cleaned decontamination, and whole valve closes.The production process of this product is simple mixing, and temperature is up to 60 ℃
Prescription is: 60 kilograms of deionized waters, 8.5 kilogram tensio-active agent alkyl alcohol polyethenoxy ether sodium sulfate (AES), 0.25 kilogram sequestrant EDTA disodium salt, 4 kilograms of buffer reagent coconut oil diethanol amides, 4 kilograms of assistant concentrations are 95% industrial alcohol, 10 kilograms of tensio-active agent cocoamidopropyl betaine, 11.5 kilogram deionized water (in order to scrub the equipment that takes up raw material), the ethylene glycol of 7 kilograms of antifreeze membrane-forming agents and 0.1 kilogram of antioxidant (composition of antioxidant is identical with the composition of the antioxidant described in the embodiment 1).
Then according to preparation method's step preparing product of embodiment 1.
Embodiment 4
Guarantee the clean and tidy drying of output zone and equipment, material-compound tank is cleaned decontamination, and whole valve closes.The production process of this product is simple mixing, and temperature is up to 60 ℃
Prescription is: 60 kilograms of deionized waters, 8.5 kilogram tensio-active agent alkyl alcohol polyethenoxy ether sodium sulfate (AES), 0.25 kilogram sequestrant EDTA disodium salt, 4 kilograms of buffer reagent coconut oil diethanol amides, 4 kilograms of assistant concentrations are 95% industrial alcohol, 10 kilograms of tensio-active agent cocoamidopropyl betaine, 11.5 kilogram deionized water (in order to scrub the equipment that takes up raw material), the propylene glycol of 7 kilograms of antifreeze membrane-forming agents and 0.1 kilogram of antioxidant (composition of antioxidant is identical with the composition of the antioxidant described in the embodiment 1).
Then according to preparation method's step preparing product of embodiment 1.
Embodiment 5
Guarantee the clean and tidy drying of output zone and equipment, material-compound tank is cleaned decontamination, and whole valve closes.The production process of this product is simple mixing, and temperature is up to 60 ℃
Prescription is: 60 kilograms of deionized waters, 8.5 kilogram tensio-active agent alkyl alcohol polyethenoxy ether sodium sulfate (AES), 0.25 kilogram sequestrant EDTA disodium salt, 4 kilograms of buffer reagent coconut oil diethanol amides, 4 kilograms of assistant concentrations are 95% industrial alcohol, 10 kilograms of tensio-active agent cocoamidopropyl betaine, 11.5 kilogram deionized water (in order to scrub the equipment that takes up raw material), 7 kilograms of antifreeze membrane-forming agents and 0.1 kilogram of antioxidant (composition of antioxidant is identical with the composition of the antioxidant described in the embodiment 1) with arbitrary proportion blended ethylene glycol and propylene glycol.
Then according to preparation method's step preparing product of embodiment 1.
Embodiment 6
Except changing into based on this antioxidant of 100 weight parts, the composition with antioxidant comprises the 5-chloro-2-methyl-different azoles quinoline ketone of 0.8 weight part, the different azoles quinoline of the 2-methyl-4-ketone of 0.3 weight part, the MgCl of 21.0 weight parts 2Deionized water solution outside, repeat the preparation process of embodiment 1.
Embodiment 7
Except changing into based on this antioxidant of 100 weight parts, the composition with antioxidant comprises the 5-chloro-2-methyl-different azoles quinoline ketone of 1.2 weight parts, the different azoles quinoline of the 2-methyl-4-ketone of 0.4 weight part, the MgCl of 24.5 weight parts 2Deionized water solution outside, repeat the preparation process of embodiment 1.

Claims (5)

1, a kind of clean-out system is characterized in that: based on this clean-out systems of 100 weight parts deionized water solution for being made up of the water of the antifreeze membrane-forming agent of the tensio-active agent of the solubility promoter of the antioxidant of the sequestrant of the buffer reagent of 3~5 weight parts, 0.2~0.3 weight part, 0.02~0.8 weight part, 2~6 weight parts, 11~22 weight parts, 8~12 weight parts and its surplus;
Wherein, buffer reagent is a coconut oil diethanol amide;
Antioxidant is this antioxidant based on 100 weight parts, comprises the 5-chloro-2-methyl-different azoles quinoline ketone of 0.8~1.2 weight part, 2-methyl-4-different azoles quinoline ketone of 0.3~0.4 weight part and the MgCl of 21.0~24.5 weight parts 2The deionized water solution of mixture;
Solubility promoter is the industrial alcohol and the sodium-chlor of 95% concentration;
Antifreeze membrane-forming agent is one or both in ethylene glycol or the propylene glycol.
2, according to the described clean-out system of claim 1, it is characterized in that: based on this clean-out systems of 100 weight parts deionized water solution for forming by the water of the antifreeze membrane-forming agent of the tensio-active agent of the solubility promoter of the antioxidant of the sequestrant of the buffer reagent of 4 weight parts, 0.25 weight part, 0.1 weight part, 4 weight parts, 19 weight parts, 10 weight parts and its surplus.
3, according to the described clean-out system of claim 1, it is characterized in that: the tensio-active agent of this clean-out system is for comprising in alkyl alcohol polyethenoxy ether sodium sulfate, the cocoamidopropyl betaine one or more at least.
4, according to the described clean-out system of claim 1, it is characterized in that: the antioxidant of this clean-out system comprises the 5-chloro-2-methyl-different azoles quinoline ketone of 1.15 weight parts, 2-methyl-4-different azoles quinoline ketone of 0.35 weight part and the MgCl of 23.0 weight parts for this antioxidant based on 100 weight parts 2The deionized water solution of mixture.
5, according to the described clean-out system of claim 1, it is characterized in that: the sequestrant of this clean-out system is the EDTA disodium salt.
CNB2005100905599A 2005-08-17 2005-08-17 Cleaning agent Expired - Fee Related CN100497573C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2005100905599A CN100497573C (en) 2005-08-17 2005-08-17 Cleaning agent

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Application Number Priority Date Filing Date Title
CNB2005100905599A CN100497573C (en) 2005-08-17 2005-08-17 Cleaning agent

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CN1730639A CN1730639A (en) 2006-02-08
CN100497573C true CN100497573C (en) 2009-06-10

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Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277241A (en) * 2011-07-20 2011-12-14 江苏爱特福84股份有限公司 Radiation-proof cleaning agent dedicated for clothes
CN103740481B (en) * 2013-11-27 2015-08-19 南通晶鑫光学玻璃有限公司 Glass mirror decontamination cleaning solvent and preparation method thereof
CN103981043A (en) * 2014-06-11 2014-08-13 陈建宝 Stain-removal antifogging detergent for glass
CN104403828A (en) * 2014-11-06 2015-03-11 无锡伊佩克科技有限公司 Automobile windshield cleaning agent and preparation method thereof
CN104479561A (en) * 2014-12-04 2015-04-01 常熟市金蝙蝠工艺家具有限公司 Lasting bright redwood furniture
CN107418801B (en) * 2017-04-12 2021-02-26 深圳宣顶实业有限公司 Concentrated car washing tablet and preparation method thereof
CN106883942A (en) * 2017-04-18 2017-06-23 湖北文理学院 A kind of automobile glass water
CN113088408A (en) * 2021-04-07 2021-07-09 四川兴望源商贸有限公司 Automobile glass water for cleaning and preparation method thereof

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Granted publication date: 20090610

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