CN102277241A - Radiation-proof cleaning agent dedicated for clothes - Google Patents

Radiation-proof cleaning agent dedicated for clothes Download PDF

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Publication number
CN102277241A
CN102277241A CN 201110203260 CN201110203260A CN102277241A CN 102277241 A CN102277241 A CN 102277241A CN 201110203260 CN201110203260 CN 201110203260 CN 201110203260 A CN201110203260 A CN 201110203260A CN 102277241 A CN102277241 A CN 102277241A
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China
Prior art keywords
clean
out system
total amount
system total
triclosan
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Pending
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CN 201110203260
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Chinese (zh)
Inventor
吴耀举
纪从林
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JIANGSU AITEFU 84 CO Ltd
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JIANGSU AITEFU 84 CO Ltd
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Priority to CN 201110203260 priority Critical patent/CN102277241A/en
Publication of CN102277241A publication Critical patent/CN102277241A/en
Pending legal-status Critical Current

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a radiation-proof cleaning agent dedicated for clothes, comprising 0.3% of chelating agent EDTA (Ethylene Diamine Tetraacetic Acid)-2Na, 8.0% of didoctyl ammonium chloride, 0.21% of triclosan, 7.0% of cocoamidopropyl betaine, 5.0% of coconut diethanolamide, 2.0% of aloe extract, 2.0% of glycerol, 0.3% of essence and 75.19% of deionized water. The preparation method comprises the following steps: filling the deionized water into a reaction kettle; stirring and rising the temperature to 35-40DEG C, and keeping the temperature; adding the chelating agent EDTA-2Na and the didoctyl ammonium chloride, and stirring till dissolving; successively adding the cocoamidopropyl betaine, the coconut diethanolamide, the triclosan, the aloe extract and the glycerol, and stirring till dissolving; after all materials are dissolved, cooling to 25-30DEG C; adding the essence, and stirring and carrying out backflow for 10-15 minutes; standing for 60 minutes, and storing qualified materials in a finished product storage tank; packaging the materials in the storage tank at fixed amount; and putting into a finished product storeroom. According to the radiation-proof cleaning agent, polluted radiant matters on clothes are chelated by radiant matter chelating agent, bactericide serves as a disinfection factor for synergy, and thus two aspects of radiation cleaning and clothes disinfection are perfectly combined.

Description

The special-purpose radioprotective clean-out system of clothing
Technical field
The present invention relates to clean-out system, be specifically related to the special-purpose radioprotective clean-out system of a kind of clothing.
Background technology
Along with the progress and the development of society, the further raising of living standards of the people, people's hygienic safety consciousness improves very fast, and is more and more deep for radiating harm understanding.Modern's life has be unable to do without household electrical appliance such as computer, TV, and these electrical equipment have also brought the problem that can't avoid: radiation when bringing the comfortable life of people; In addition, staff such as some special entities such as hospital contact radiant matter especially for a long time, must be subjected to the pollution of radiant matter on the clothing of dress.
People's outstanding to the harm understanding of communicable diseases such as tetter, venereal disease and the performance of preventive measure aspect simultaneously, for pet, environment and people be in contact with one another and the clothing virus brought, pathogen contamination especially to pay close attention to.Yet, currently marketed clothing sterilized product mainly adopts chlorophenols compound as the disinfection factor, synthetic and the applicating history of its compound is remote, in secular use, find bigger to people's skin irritation, simultaneously this compounds is also bigger to corrosion of metal, and metalware and environment are had in various degree influence; Find that by a large amount of research and investigation the fungicidal activity of above-mentioned clothes disinfector exists that fungicidal spectrum is narrow, the bigger problem of actual usage quantity of sterilization needs, so this compounds is the kind that is being eliminated.
Summary of the invention
The objective of the invention is to: provide a kind of clothing special-purpose radioprotective clean-out system, this clean-out system utilizes the radiant matter sequestrant that the radiant matter that pollutes on the clothing is carried out chelating, and the sterilant that utilizes high-efficiency broad spectrum is as disinfection factor, synergy perfectly combines radiation cleaning, clothing two aspects of sterilizing.
Technical solution of the present invention is that this radioprotective clean-out system is made up of following component percentages: sequestrant EDTA-2Na 0.3%, two decyl ammonium chlorides 8.0%, triclosan 0.21%, CAB 7.0%, coconut acid diethanolamide 5.0%, extract solution from aloe 2.0%, glycerol 2.0%, essence 0.3%, deionized water 75.19%.
Wherein, this radioprotective clean-out system is prepared by following steps:
A, elder generation put into reactor with the deionized water that accounts for clean-out system total amount 70% of accurate measurement, stir and are warming up to 35 ~ 40 ℃, and keep;
B, the sequestrant EDTA-2Na that adds clean-out system total amount 0.3%, two certain herbaceous plants with big flowers ammonium chlorides of clean-out system total amount 8.0% are stirred well to dissolving fully;
C, add the CAB of clean-out system total amount 7.0%, the coconut acid diethanolamide of clean-out system total amount 5.0%, the triclosan of clean-out system total amount 0.21%, the extract solution from aloe of clean-out system total amount 2.0%, the glycerol of clean-out system total amount 2.0% successively, be stirred well to dissolving fully;
D, treat all materials all dissolve good after, stop heating and begin cooling, be cooled to 25 ~ 30 ℃, add the essence of surplus deionized water, clean-out system total amount 0.3%, 10 ~ 15 min fully stir and reflux;
E, leave standstill 60min, sampling is tested, and qualified material changes the finished product basin of production plant over to;
F, the material in the basin is entered production line carry out quantitative package, require to test, go into stockyard after qualified according to product standard.
The present invention has the following advantages:
1, radioprotective clean-out system of the present invention meets related requests such as " People's Republic of China's Law on the Prevention and Control of Radioactive Pollution ", " People's Republic of China's Law on the Prevention and Control of Radioactive Pollution ", health ministry " Regulations of sterilization management ", " disinfection technology standard ", " evaluation method and the standard (GB15981-1995) of sterilization and sterilising effect ";
2, radioprotective clean-out system of the present invention adopts radiation sequestrant EDTA-2Na, triclosan, two decyl ammonium chloride as effective constituent, and adopt synergistic agent coconut acid diethanolamide, CAB, protective material glycerol, extract solution from aloe, be mixed in proportion, each component synergy, the radioprotective pollution effects is good, and the activity of killing microorganisms is strong, and good stability of products, the quality guaranteed period is 2 years;
3, the present invention adopts radiant matter sequestrant EDTA-2Na, it has stronger sequestering action to the radiation pollution thing, the radiation pollution thing can with its chelating after and fully soluble in water, adopting CAB, coconut acid diethanolamide tensio-active agent is synergistic agent, inner complex can be broken away from from clothing more abundant, more completely to be cleaned, the radiation cleaning performance is good, and the use of extract solution from aloe, glycerol makes clothing submissiveer, and it is comfortable and easy to wear to clean the back;
4, the main effective constituent of the disinfection factor of radioprotective clean-out system of the present invention is triclosan, two decyl ammonium chloride, and the germ-resistant point of application of triclosan is on cytoplasmic membrane, but the concentration difference, mechanism of action difference; The triclosan of high density can directly destroy bacterial cell membrane, causes the irreversible denaturation of albumen and nucleic acid in the kytoplasm, causes low-molecular-weight entocyte to ooze out, bacterium death; The triclosan of lower concentration acts on the cytolemma, hinders the absorption of bacterium to nutritive substances such as growth essential amino acid, uridylics, thereby suppresses the growth of bacterium; A large amount of evidences, triclosan and human body skin have good consistency, secular animal toxicology test has proved that also triclosan can reach the world today to the toxic international standard of chemical in advising use range and under the consumption, is the safe and efficient broad spectrum antimicrobicide of praising highly in the world at present;
5, two decyl ammonium chlorides in the radioprotective clean-out system of the present invention are as the good thing preparation of killing livestock, it is a kind of sterilization component of high-efficiency broad spectrum, to pathogenic bacterium such as intestinal bacteria, staphylococcus aureus, Candida albicanss etc. have killing action efficiently, each viroid and algae also had the good effect of killing livestock, this compound belongs to the safe environment protection type product, register at present in EPA (EPA), and obtained FDA approval, under the 150-400ppm active matter content, can be used as retention type food processor appliances disinfectant, the sterilization mechanism of this compounds mainly is positively charged in the aqueous solution, can be adsorbed in the microorganism surface, form micelle, and progressively infiltrate cytoplasmic lipoid layer and protein layer, thereby change the after birth permeability, entocyte is exosmosed, cause microbial death, simultaneously can solidifying egg white, make enzyme and structural protein sex change, the metabolism system of destroy microorganisms, cause its death, above-mentioned effective constituent and stablizer, the tensio-active agent compatibility uses, and it can strengthen the fungicidal activity of thimerosal.
Embodiment
Further specify technical solution of the present invention below in conjunction with specific embodiment, these embodiment can not be interpreted as it is restriction to technical solution.
Embodiment 1: according to the radioprotective clean-out system of 1000 kilograms of following steps preparations
A, elder generation put into reactor with 700 kilograms deionized water of accurate measurement, stir and are warming up to 35 ℃, and keep;
B, add 3 kilograms sequestrant EDTA-2Na, two certain herbaceous plants with big flowers ammonium chlorides of 80 kilograms, be stirred well to fully and dissolve;
C, add 70 kilograms CAB, 50 kilograms coconut acid diethanolamide, 2.1 kilograms triclosan, 20 kilograms extract solution from aloe, 20 kilograms glycerol successively, be stirred well to dissolving fully;
D, treat all materials all dissolve good after, stop heating and begin cooling, be cooled to 25 ℃, add 51.9 kilograms deionized water, 3 kilograms essence, 10 min fully stir and reflux;
E, leave standstill 60min, sampling is tested, and qualified material changes the finished product basin of production plant over to;
F, the material in the basin is entered production line carry out quantitative package, require to test, go into stockyard after qualified according to product standard.
Embodiment 2: according to the radioprotective clean-out system of 1000 kilograms of following steps preparations
A, elder generation put into reactor with 700 kilograms deionized water of accurate measurement, stir and are warming up to 38 ℃, and keep;
B, add 3 kilograms sequestrant EDTA-2Na, two certain herbaceous plants with big flowers ammonium chlorides of 80 kilograms, be stirred well to fully and dissolve;
C, add 70 kilograms CAB, 50 kilograms coconut acid diethanolamide, 2.1 kilograms triclosan, 20 kilograms extract solution from aloe, 20 kilograms glycerol successively, be stirred well to dissolving fully;
D, treat all materials all dissolve good after, stop heating and begin cooling, be cooled to 28 ℃, add 51.9 kilograms deionized water, 3 kilograms essence, 12 min fully stir and reflux;
E, leave standstill 60min, sampling is tested, and qualified material changes the finished product basin of production plant over to;
F, the material in the basin is entered production line carry out quantitative package, require to test, go into stockyard after qualified according to product standard.
Embodiment 3: according to the radioprotective clean-out system of 1000 kilograms of following steps preparations
A, elder generation put into reactor with 700 kilograms deionized water of accurate measurement, stir and are warming up to 40 ℃, and keep;
B, add 3 kilograms sequestrant EDTA-2Na, two certain herbaceous plants with big flowers ammonium chlorides of 80 kilograms, be stirred well to fully and dissolve;
C, add 70 kilograms CAB, 50 kilograms coconut acid diethanolamide, 2.1 kilograms triclosan, 20 kilograms extract solution from aloe, 20 kilograms glycerol successively, be stirred well to dissolving fully;
D, treat all materials all dissolve good after, stop heating and begin cooling, be cooled to 30 ℃, add 51.9 kilograms deionized water, 3 kilograms essence, 15 min fully stir and reflux;
E, leave standstill 60min, sampling is tested, and qualified material changes the finished product basin of production plant over to;
F, the material in the basin is entered production line carry out quantitative package, require to test, go into stockyard after qualified according to product standard.
Get the radioprotective clean-out system of embodiment 1, dilution in 1: 300 contains triclosan 6.90 mg/L, two decyl ammonium chloride 214 mg/L, and stainless steel substrates, copper sheet are not had corrosion substantially, to the aluminium flake mild corrosion, the carbon steel coupon moderate is corroded.
Get the radioprotective clean-out system of embodiment 1, dilution in 1: 300 stain to be handled the back to the clothing radiation and is cleaned 1 time, detects once more after crossing clearly with clear water, contrasts detected result twice, cotton fabric: cleans 0.02 μ Sv/h after preceding 1.19 μ Sv/h, the cleaning; Chemical fibre clothes lining: clean preceding 1.11 μ Sv/h, clean the back: 0.01 μ Sv/h; Blending clothing lining: clean preceding 1.02 μ Sv/h, clean back 0.01 μ Sv/h; The result shows: after the cleaning, radiation dose rate is lower than the threshold limit values level, can use safely.
Get the radioprotective clean-out system of embodiment 2, dilution in 1: 300 contains triclosan 6.70 mg/L, two decyl ammonium chloride 216 mg/L, acts on 2.5 minutes; The 1:500 dilution contains triclosan 4.02 mg/L, two decyl ammonium chloride 129.6 mg/L, acts on 5 minutes; To streptococcus aureus and colibacillary to kill logarithmic value equal 5.00.
Get the radioprotective clean-out system of embodiment 2, dilution in 1: 300 contains triclosan 6.70 mg/L, two decyl ammonium chloride 216 mg/L, acts on 2.5 minutes; The 1:500 dilution contains triclosan 4.02 mg/L, two decyl ammonium chloride 129.6 mg/L, acts on 5 minutes; To Candida albicans to kill logarithmic value equal 5.00.
Get the radioprotective clean-out system of embodiment 3, dilution in 1: 300 contains triclosan 6.70 mg/L, two decyl ammonium chloride 216 mg/L, to wooden painted surface wiping sterilization 5 minutes, its surperficial natural bacteria is on average killed logarithmic value〉1.00.
Get the radioprotective clean-out system of embodiment 3,1:500 dilution contains triclosan 4.02 mg/L, two decyl ammonium chloride 129.6 mg/L, to wooden painted surface wiping sterilization 10 minutes, its surperficial natural bacteria is on average killed logarithmic value〉1.00.
The radioprotective clean-out system of embodiment 1-3 is through 37 oC deposited 3 months, and effective constituent triclosan, two decyl ammonium chloride rate of descent are all less than 10%, and stability meets the requirement of Ministry of Health's " disinfection technology standard " version in 2002, and validity period is 1 year.
Get the radioprotective clean-out system of embodiment 3, through check, to male and female chmice acute per os LD 50Be worth all greater than 5000mg/kg b.wt the nontoxic level in the true border of this sample; To rabbit acute skin irritation reaction integrated value is 1.67, and this sample belongs to subexcite; Dosage reaches 1845 and 1165mg/kg b.wt, does not detect the marrow polychromatic erythrocyte is caused the micronucleus effect.
The research of the radiation cleaning by above system to the radioprotective scavenging solution, sterilization, toxicology character, a large amount of science, true and comprehensive data have been obtained, confirmed this reliability of products and actual effect, every physical and chemical index of this product and biological activity all meet national every standard.In a word: this product radiation cleaning performance is good, and sterilization effect is reliable, and good stability is easy to use.

Claims (1)

1. the special-purpose radioprotective clean-out system of clothing, it is characterized in that this radioprotective clean-out system is made up of following component percentages: sequestrant EDTA-2Na 0.3%, two decyl ammonium chlorides 8.0%, triclosan 0.21%, CAB 7.0%, coconut acid diethanolamide 5.0%, extract solution from aloe 2.0%, glycerol 2.0%, essence 0.3%, deionized water 75.19%; Described radioprotective clean-out system is prepared by following steps:
A, elder generation put into reactor with the deionized water that accounts for clean-out system total amount 70% of accurate measurement, stir and are warming up to 35 ~ 40 ℃, and keep;
B, the sequestrant EDTA-2Na that adds clean-out system total amount 0.3%, two certain herbaceous plants with big flowers ammonium chlorides of clean-out system total amount 8.0% are stirred well to dissolving fully;
C, add the CAB of clean-out system total amount 7.0%, the coconut acid diethanolamide of clean-out system total amount 5.0%, the triclosan of clean-out system total amount 0.21%, the extract solution from aloe of clean-out system total amount 2.0%, the glycerol of clean-out system total amount 2.0% successively, be stirred well to dissolving fully;
D, treat all materials all dissolve good after, stop heating and begin cooling, be cooled to 25 ~ 30 ℃, add the essence of surplus deionized water, clean-out system total amount 0.3%, 10 ~ 15 min fully stir and reflux;
E, leave standstill 60min, sampling is tested, and qualified material changes the finished product basin of production plant over to;
F, the material in the basin is entered production line carry out quantitative package, require to test, go into stockyard after qualified according to product standard.
CN 201110203260 2011-07-20 2011-07-20 Radiation-proof cleaning agent dedicated for clothes Pending CN102277241A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660397A (en) * 2012-03-31 2012-09-12 天津天狮生物发展有限公司 Detergent for cleaning underwear and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1696262A (en) * 2004-05-13 2005-11-16 崔生 Phosphorus free Nano Hyperconcentrated liquid detergent
CN1730639A (en) * 2005-08-17 2006-02-08 曲文涛 Cleaning agent
CN101906357A (en) * 2010-08-12 2010-12-08 江苏爱特福84股份有限公司 Textile disinfecting composition and preparation method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1696262A (en) * 2004-05-13 2005-11-16 崔生 Phosphorus free Nano Hyperconcentrated liquid detergent
CN1730639A (en) * 2005-08-17 2006-02-08 曲文涛 Cleaning agent
CN101906357A (en) * 2010-08-12 2010-12-08 江苏爱特福84股份有限公司 Textile disinfecting composition and preparation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660397A (en) * 2012-03-31 2012-09-12 天津天狮生物发展有限公司 Detergent for cleaning underwear and preparation method thereof
CN102660397B (en) * 2012-03-31 2015-10-28 天津天狮生物发展有限公司 A kind of for washing composition cleaning underwear and preparation method thereof

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Application publication date: 20111214