CN109825381A - A kind of automobile dry-cleaning cleaning curing agent composition and preparation method thereof - Google Patents
A kind of automobile dry-cleaning cleaning curing agent composition and preparation method thereof Download PDFInfo
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Abstract
The embodiment of the invention discloses a kind of automobiles to dry-clean cleaning curing agent composition, and the composition includes following ingredients based on parts by weight: 93-98 parts of deionized water, 0.01-0.1 parts of ethyl phthalate, 0.2-2.0 parts of silicone emulsion, 0.5-2.0 parts of wax emulsion, 0.05-0.15 parts of glycerol, 0.05-0.15 parts of long-chain polyunsaturated fatty acid, 0.01-0.3 parts of polyisobutene succinimide, 1.0-2.5 parts of solvent naphtha, 0.1-0.5 parts of surfactant, 0.05-1.5 parts of emulsifier and 0.1-0.15 parts of suspending agent.The composition materials environmental protection, can use, high-effective cleansing under the conditions of all kinds of, injure to automobile finish zero, have bactericidal effect and can form layer protecting film in surface of vehicle paint.Cleaning and one step of maintenance to lacquer painting outside automobile are completed, and are washed with water without additionally making.
Description
Technical field
The present invention relates to automobile clean product technical fields, and in particular to a kind of automobile dry-cleaning cleaning curing agent composition and
Preparation method.
Background technique
With the sharp increase of China's automobile guarantee-quantity, carwash demand is increasing.Traditional carwash mode is washing, no matter
Shop carwash is still arrived in family oneself cleaning, requires largely to use water, has not met " water conservation " theory of country's promotion at present.
And the type vehicle cleaning detergent used when tradition washing also has biggish pollution to environment, is not also inconsistent in addition to having certain corrosion to vehicle paint
Close the proposal of " protection environment " that country proposes.
Traditional carwash is needed using dedicated car wash site, car washing installation, a large amount of tap water and type vehicle cleaning detergent.In recent years, with
The rise of price, place rent, tap water, type vehicle cleaning detergent and car washing installation expense all improving, so as to cause carwash shop warp
The increase for seeking cost, also improves the spending of car owner's carwash.
With the strict demand of drinking water increasingly lacked with Environmental pollution, traditional carwash industry is anxious to be risen wait make the transition
Grade, it is desirable that reduce water consumption as far as possible and reduce the pollution level to environment, in the hope of reducing the waste and raising pair to water resource
The protection of ecological environment.
In addition, also needing to make improvements in the methods of carwash, to improve carwash efficiency, saves car-cleaning time and improve
Carwash maintenance effect.
Summary of the invention
The embodiment of the present invention is designed to provide a kind of automobile dry-cleaning cleaning curing agent composition, to solve existing water
Wash mode and type vehicle cleaning detergent there are the problem of.Automobile dry-cleaning cleaning curing agent composition materials environmental protection, can be under the conditions of all kinds of
It uses, high-effective cleansing, automobile finish zero is injured, there is bactericidal effect and layer protecting film can be formed in surface of vehicle paint.To vapour
The cleaning of the outer lacquer painting of vehicle and one step of maintenance are completed, and are washed with water without additionally making.
To achieve the above object, the embodiment of the present invention provides a kind of automobile dry-cleaning cleaning curing agent composition, the combination
Object includes following ingredients based on parts by weight: 93-98 parts of deionized water, 0.01-0.1 parts of ethyl phthalate, silicone emulsion 0.2-
2.0 parts, 0.5-2.0 parts of wax emulsion, 0.05-0.15 parts of glycerol, 0.05-0.15 parts of long-chain polyunsaturated fatty acid, polyisobutene
0.01-0.3 parts of succimide, 1.0-2.5 parts of solvent naphtha, 0.1-0.5 parts of surfactant, 0.05-1.5 parts of emulsifier and
0.1-0.15 parts of suspending agent.
Further, the composition includes following ingredients based on parts by weight: 94-97 parts of deionized water, phthalandione diethyl
0.03-0.08 parts of ester, 0.5-1.5 parts of silicone emulsion, 0.8-1.5 parts of wax emulsion, 0.08-0.12 parts of glycerol, long-chain how unsaturated
0.08-0.12 parts of fatty acid, 0.05-0.2 parts of polyisobutene succinimide, 1.5-2.2 parts of solvent naphtha, surfactant 0.2-
0.4 part, 0.2-1.2 parts of emulsifier and 0.11-0.13 parts of suspending agent.
Wherein, ethyl phthalate is also known as diethyl phthalate, colourless transparent oil liquid, micro- tool fragranced.With second
Alcohol, ether are miscible, are dissolved in the organic solvents such as acetone, benzene.It is important solvent, also acts as plasticizer and lubricant etc..
Silicone emulsion is also known as the sliding element of silk.White viscous liquid, chemical property stablize, it is non-volatile, it is nonflammable, to metal without
Corrosivity is long placed in air and is also not easy gelatinization.Silicone emulsion have excellent chemical stability, heat-resisting cold resistance, weatherability,
Lubricity, hydrophobicity and low surface tension, it is non-toxic to humans.
Wax emulsion is a kind of heterogeneous system that the materials such as native paraffin and synthetic wax are dispersed in water under the action of emulsifier
Lotion, be a kind of important addition auxiliary agent in coating material.Wax emulsion used in the embodiment of the present invention can assign lacquer painting height
Gloss can polish, and transparency is good.
Glycerol, that is, glycerine, thick liquid is sweet, has hygroscopicity.In any proportion with water and alcohols, amine, phenols
Miscible, aqueous solution is neutrality.It is non-corrosive to metal, make solvent using when can be oxidized to methacrylaldehyde.It serves many purposes, example
Such as it is used as solvent, lubricant, plasticiser.
Long-chain polyunsaturated fatty acid (LC-PUFA) refers to containing two or more carbon-carbon double bonds and carbon chain lengths are 18
The straight chain fatty acid of~22 carbon atoms.It preferably comprises 4 or more carbon-carbon double bonds and carbon chain lengths is 18~22 carbon atoms
Straight chain fatty acid.This kind of fatty acid usually makes an addition in food.A small amount of long-chain is added in the product of the embodiment of the present invention mostly not
The plasticizing capacity and thermal stability of product can be improved in saturated fatty acid.
Polyisobutene succinimide is using high-activity polyisobutene as raw material, using the preparation of hot adduction technique without ash content
Powder.Without chlorine, good dispersion, for modulating all types of machine oil.
Solvent naphtha, that is, paint solvent oil, also known as paint naphtha, is commonly used for solvent in coating preparation.
Further, the boiling point of solvent naphtha used in the embodiment of the present invention is 200-300 DEG C.It is molten to belong to higher boiling
Agent oil, boiling point of 140-200 DEG C compared to usual paint naphtha are higher.The boiling point is used in the product of the embodiment of the present invention
The solvent naphtha of section can provide better dissolubility, volatilization stability and product safety in utilization.
The surfactant can be used for improving product quality, improve execution conditions, can be antistatic, improve product levelling
Property.
It further, include the amino acid type amphoteric surface of 20-30% by percentage to the quality in the surfactant
Activating agent.It is generated by amino acid and hydrophobic substance, mainly there is glycine class, alanine class and taurine class amophoteric surface active
Agent, commonly used in the production of cosmetics and amenities.It is living using a part of amino acid type amphoteric surface in the embodiment of the present invention
Property agent further can provide flatness and antistatic property to product other than having good emulsibility and dispersibility, and have
Certain bactericidal properties and suppression mouldiness.
Emulsifier is can to improve the various surface tension constituted between phase in emulsion, is allowed to form uniform and stable point
The substance of granular media system or emulsion, while there is hydrophilic group and lipophilic group.It is emulsified used in technical solution of the embodiment of the present invention
Agent can be the common emulsifier being currently used in coating and cleaning agent, such as Tween-80, Tween-60, EKS-300 solvent cream
Agent etc..
Suspending agent is also known as suspension stabilizer, refers to solid component is uniform with certain size such as 4 microns of particles below
It is scattered in medium, makes the preparation of its stable suspersion in the medium.Suspending agent used in technical solution of the embodiment of the present invention can
Think the common suspending agent being currently used in coating and cleaning agent, such as acrylate copolymer emulsion, card wave 940 etc..
In one embodiment, the composition includes following ingredients based on parts by weight: 96 parts of deionized water, phthalandione
0.05 part of diethylester, 1.0 parts of silicone emulsion, 1.2 parts of wax emulsion, 0.1 part of glycerol, 0.1 part of long-chain polyunsaturated fatty acid, gather it is different
0.12 part of butylene succimide, 1.8 parts of solvent naphtha, 0.3 part of surfactant, 0.7 part of emulsifier and 0.12 part of suspending agent.
In another embodiment, the composition includes following ingredients based on parts by weight: 94 parts of deionized water, phthalein
0.03 part of diethyl phthalate, 0.5 part of silicone emulsion, 0.8 part of wax emulsion, 0.08 part of glycerol, 0.08 part of long-chain polyunsaturated fatty acid,
0.05 part of polyisobutene succinimide, 1.5 parts of solvent naphtha, 0.2 part of surfactant, 0.2 part of emulsifier and suspending agent
0.11 part.
In another embodiment, the composition includes following ingredients based on parts by weight: 97 parts of deionized water, phthalein
0.08 part of diethyl phthalate, 1.5 parts of silicone emulsion, 1.5 parts of wax emulsion, 0.12 part of glycerol, 0.12 part of long-chain polyunsaturated fatty acid,
0.2 part of polyisobutene succinimide, 2.2 parts of solvent naphtha, 0.4 part of surfactant, 1.2 parts of emulsifier and suspending agent 0.13
Part.
It further, further include 0.01-0.25 parts of essence, preferably 0.05-0.15 parts in the composition.The essence can
Think the common essence type being currently used in coating and cleaning agent, including natural and/or artificial synthesized fragrance.The washing is clear
The selection and addition of essence are known to those skilled in the art in clean product.
The other side of the embodiment of the present invention additionally provides the preparation side of the automobile dry-cleaning cleaning curing agent composition
Method, the method includes the following steps:
(1) merging of ethyl phthalate, silicone emulsion, wax emulsion, glycerol and oil miscible solvent is heated to 60~70 DEG C, homogeneous
2-4 minutes；
(2) 40 DEG C are cooled to, long-chain polyunsaturated fatty acid and polyisobutene succinimide are added one by one, stirring is equal
It is even, obtain precast body mixture；
(3) will the precast body mixture be added deionized water in, then one by one be added surfactant, emulsifier and
Suspending agent, one component of every addition, adds next component after mixing evenly；
(4) charging finishes, and discharges after stirring to room temperature.
Further, the method also includes: after polyisobutene succinimide is added in the step (2), be additionally added
0.01-0.25 parts of essence.The essence is 0.05-0.15 parts preferred.
The embodiment of the invention also provides the application methods that the automobile dry-cleans cleaning curing agent composition, comprising: uses
It is preceding to shake up the composition, uniformly it is sprayed onto surface of vehicle paint；It is gently wiped with one piece of clean cleaning cloth；Naturally dry 3-5 points
Zhong Hou dips the composition with another piece of clean cleaning cloth and carries out second time wiping.
Wherein, first pass wiping primarily serves cleaning action；Second time wiping is also acted as and is beaten vehicle paint in addition to supplementing cleaning
Wax, glazing make up the effect of scratch.Car owner voluntarily can clean vehicle by above method operation.Existing carwash shop can also make
With this product come for client operating carwash.
Car washing liquid of the invention mainly by water, solvent naphtha, the silicone oil of emulsification, wax emulsion, surfactant and other help
Agent composition, the content of water reach 90% or more, and materials environmental protection, can use under the conditions of all kinds of, decontamination efficiently, to automobile
Zero scratch of lacquer painting has bactericidal effect and forms layer protecting film in surface of vehicle paint.By it is experimentally confirmed that vapour provided by the invention
Vehicle dry-cleaning cleaning curing agent just uses definite effect.
The embodiment of the present invention has the advantages that
1, when stating cleaning curing agent composition in use, without using additional water, without the use of Large Electric equipment, no
Need using dedicated place (general park position), by simple wiping can be completed cleaning to automobile, glazing, waxing,
Sterilization and care action；
2, it can reach water conservation using above-mentioned preparation, protection environment, reduce cost of running a shop, reduce car owner car-cleaning cost
Purpose；
3, above-mentioned preparation carries and conveniently, and does not need using large scale equipment, cleans vehicle at any time convenient for car owner, and hold
It easily provides carwash shop to make house calls.
Specific embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book is understood other advantages and efficacy of the present invention easily, it is clear that described embodiment is the present invention one
Section Example, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not doing
Every other embodiment obtained under the premise of creative work out, shall fall within the protection scope of the present invention.
Embodiment 1
The automobile dry-cleaning cleaning curing agent composition of the embodiment of the present invention includes following component based on parts by weight: deionization
96 parts of water, 0.05 part of ethyl phthalate, 1.0 parts of silicone emulsion, 1.2 parts of wax emulsion, 0.1 part of glycerol, long-chain polyunsaturated fat
Acid 0.1 part, 0.12 part of polyisobutene succinimide, 1.8 parts of solvent naphtha, 0.3 part of surfactant, 0.7 part of emulsifier and
0.12 part of suspending agent.
Preparation method includes the following steps:
(1) merging of ethyl phthalate, silicone emulsion, wax emulsion, glycerol and oil miscible solvent is heated to 66 DEG C, homogeneous 3 divides
Clock；
(2) 40 DEG C are cooled to, long-chain polyunsaturated fatty acid and polyisobutene succinimide are added one by one, stirring is equal
It is even, obtain precast body mixture；
(3) will the precast body mixture be added deionized water in, then one by one be added surfactant, emulsifier and
Suspending agent, one component of every addition, adds next component after mixing evenly；
(4) charging finishes, and stirring is to discharging after 25 DEG C of room temperature.
Embodiment 2
The automobile dry-cleaning cleaning curing agent composition of the embodiment of the present invention includes following component based on parts by weight: deionization
94 parts of water, 0.03 part of ethyl phthalate, 0.5 part of silicone emulsion, 0.8 part of wax emulsion, 0.08 part of glycerol, long-chain polyunsaturated fat
Acid 0.08 part, 0.05 part of polyisobutene succinimide, 1.5 parts of solvent naphtha, 0.2 part of surfactant, 0.2 part of emulsifier and
0.11 part of suspending agent.
Preparation method is the same as embodiment 1.
Embodiment 3
The automobile dry-cleaning cleaning curing agent composition of the embodiment of the present invention includes following component based on parts by weight: deionization
97 parts of water, 0.08 part of ethyl phthalate, 1.5 parts of silicone emulsion, 1.5 parts of wax emulsion, 0.12 part of glycerol, long-chain polyunsaturated fat
Acid 0.12 part, 0.2 part of polyisobutene succinimide, 2.2 parts of solvent naphtha, 0.4 part of surfactant, 1.2 parts of emulsifier and
0.13 part of suspending agent.
Preparation method is the same as embodiment 1.
Embodiment 4
The automobile dry-cleaning cleaning curing agent composition of the embodiment of the present invention includes following component based on parts by weight: deionization
94 parts of water, 0.03 part of ethyl phthalate, 0.3 part of silicone emulsion, 0.6 part of wax emulsion, 0.06 part of glycerol, long-chain polyunsaturated fat
0.05 part of acid, 1.5 parts of solvent naphtha, 0.1 part of surfactant, 0.1 part of emulsifier, hangs 0.05 part of polyisobutene succinimide
Floating 0.11 part and 0.05 part of essence of agent.
Preparation method includes the following steps:
(1) merging of ethyl phthalate, silicone emulsion, wax emulsion, glycerol and oil miscible solvent is heated to 62 DEG C, homogeneous 4 divides
Clock；
(2) 40 DEG C are cooled to, long-chain polyunsaturated fatty acid, polyisobutene succinimide and essence are added one by one, stirs
It mixes uniformly, obtains precast body mixture；
(3) will the precast body mixture be added deionized water in, then one by one be added surfactant, emulsifier and
Suspending agent, one component of every addition, adds next component after mixing evenly；
(4) charging finishes, and stirring is to discharging after 25 DEG C of room temperature.
Embodiment 5
The automobile dry-cleaning cleaning curing agent composition of the embodiment of the present invention includes following component based on parts by weight: deionization
97 parts of water, 0.06 part of ethyl phthalate, 1.8 parts of silicone emulsion, 1.7 parts of wax emulsion, 0.13 part sweet, long-chain polyunsaturated fatty acid
0.14 part, 0.25 part of polyisobutene succinimide, 2.5 parts of solvent naphtha, 0.5 part of surfactant, 1.3 parts of emulsifier, suspension
0.14 part of agent and 0.05 part of essence.
Preparation method is the same as embodiment 4.
The automobile dry-cleaning cleaning curing agent composition that the above embodiment of the present invention obtains is easy to use, and cleaning effect is good；?
While cleaning, can also simple scratch be carried out to vehicle paint and made up, and there is certain sterilization and care action.For personal user and
Businessman businessman is a kind of convenience and effective product.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (10)
1. a kind of automobile dry-cleaning cleaning curing agent composition, which is characterized in that the composition includes following based on parts by weight
Ingredient: 93-98 parts of deionized water, 0.01-0.1 parts of ethyl phthalate, 0.2-2.0 parts of silicone emulsion, 0.5-2.0 parts of wax emulsion,
It is 0.05-0.15 parts of glycerol, 0.05-0.15 parts of long-chain polyunsaturated fatty acid, 0.01-0.3 parts of polyisobutene succinimide, molten
1.0-2.5 parts of agent oil, 0.1-0.5 parts of surfactant, 0.05-1.5 parts of emulsifier and 0.1-0.15 parts of suspending agent.
2. composition according to claim 1, which is characterized in that the composition include based on parts by weight it is following at
Point: it is 94-97 parts of deionized water, 0.03-0.08 parts of ethyl phthalate, 0.5-1.5 parts of silicone emulsion, 0.8-1.5 parts of wax emulsion, sweet
0.08-0.12 parts oily, 0.08-0.12 parts of long-chain polyunsaturated fatty acid, 0.05-0.2 parts of polyisobutene succinimide, solvent
1.5-2.2 parts oily, 0.2-0.4 parts of surfactant, 0.2-1.2 parts of emulsifier and 0.11-0.13 parts of suspending agent.
3. composition according to claim 1, which is characterized in that the composition include based on parts by weight it is following at
Point: 96 parts of deionized water, 0.05 part of ethyl phthalate, 1.0 parts of silicone emulsion, 1.2 parts of wax emulsion, 0.1 part of glycerol, long-chain are mostly not
0.1 part of saturated fatty acid, 0.12 part of polyisobutene succinimide, 1.8 parts of solvent naphtha, 0.3 part of surfactant, emulsifier
0.7 part and 0.12 part of suspending agent.
4. composition according to claim 1, which is characterized in that the composition include based on parts by weight it is following at
Point: 94 parts of deionized water, 0.03 part of ethyl phthalate, 0.5 part of silicone emulsion, 0.8 part of wax emulsion, 0.08 part of glycerol, long-chain are more
0.08 part of unsaturated fatty acid, 0.05 part of polyisobutene succinimide, 1.5 parts of solvent naphtha, 0.2 part of surfactant, emulsification
0.2 part of agent and 0.11 part of suspending agent.
5. composition according to claim 1, which is characterized in that the composition include based on parts by weight it is following at
Point: 97 parts of deionized water, 0.08 part of ethyl phthalate, 1.5 parts of silicone emulsion, 1.5 parts of wax emulsion, 0.12 part of glycerol, long-chain are more
0.12 part of unsaturated fatty acid, 0.2 part of polyisobutene succinimide, 2.2 parts of solvent naphtha, 0.4 part of surfactant, emulsifier
1.2 parts and 0.13 part of suspending agent.
6. composition according to any one of claims 1-5, which is characterized in that the boiling point of the solvent naphtha is 200-
300℃。
7. composition according to any one of claims 1-5, which is characterized in that include with matter in the surfactant
Measure the amino acid type amphoteric surfactant of percentages 20-30%.
8. composition according to any one of claims 1-5, which is characterized in that further include essence in the composition
0.01-0.25 parts.
9. the preparation method of automobile dry-cleaning cleaning curing agent composition according to any one of claims 1-5, feature
It is, the method includes the following steps:
(1) merging of ethyl phthalate, silicone emulsion, wax emulsion, glycerol and oil miscible solvent is heated to 60~70 DEG C, homogeneous 2-4
Minute；
(2) 40 DEG C are cooled to, long-chain polyunsaturated fatty acid and polyisobutene succinimide are added one by one, stirs evenly, obtains
Obtain precast body mixture；
(3) the precast body mixture is added in deionized water, surfactant, emulsifier and suspension is then added one by one
Agent, one component of every addition, adds next component after mixing evenly；
(4) charging finishes, and discharges after stirring to room temperature.
10. according to the method described in claim 9, it is characterized in that, the method also includes: be added in the step (2) gather it is different
After butylene succimide, it is additionally added 0.01-0.25 parts of essence.
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| CN201910199726.5A CN109825381A (en) | 2019-03-15 | 2019-03-15 | A kind of automobile dry-cleaning cleaning curing agent composition and preparation method thereof |
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Application publication date: 20190531 |