CN106929242B - The method of carwash under high temperature car washing liquid and preparation method thereof, high temperature - Google Patents
The method of carwash under high temperature car washing liquid and preparation method thereof, high temperature Download PDFInfo
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- CN106929242B CN106929242B CN201710215313.2A CN201710215313A CN106929242B CN 106929242 B CN106929242 B CN 106929242B CN 201710215313 A CN201710215313 A CN 201710215313A CN 106929242 B CN106929242 B CN 106929242B
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
- C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
- C09G1/12—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin mixtures of wax and silicon-containing polycondensates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
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- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of high temperature car washing liquid of the present invention, the high temperature car washing liquid includes the deionized water of 93 96 parts by weight, the triethanolamine of the silicone emulsion of 0.5 2.5 parts by weight, the wax emulsion of 0.5 1.5 parts by weight, 0.2 0.5 parts by weight include the surfactant of amino acid type amphoteric surfactant, 1.0 2.0 parts by weight boiling points are 250 350 DEG C solvent naphtha, the long-chain unsaturated acids of 0.1 0.2 parts by weight, the polyisobutene succinimide of 0.01 0.25 parts by weight and 0.02 0.06 parts by weight.The high temperature car washing liquid of the present invention is mainly made of silicone oil, wax emulsion, solvent naphtha, surfactant and other auxiliary agents of water, emulsification, the content of water reaches more than 93%, and it materials environmental protection, can use again under conditions of high temperature burning sun, cut can be significantly reduced, decontamination efficiently, on automobile finish glossiness influences low.
Description
Technical field
The present invention relates to a kind of car washing liquid, more particularly to a kind of car washing liquid for being suitble to use under the high temperature conditions.
Background technology
At present, conventional carwash flow is：Vehicle body is drenched first or preliminary flushing is to remove substantial amounts of dirt, then
The car washing liquid prepared is uniformly sprayed and/or wiped in bodywork surface, then is rinsed with water the foam and sewage of bodywork surface, finally with hair
Towel, chamois leather etc. dry vehicle body.In this process, in order to remove the remaining car washing liquid of vehicle body, need to be rinsed with substantial amounts of water, pole
Spend waste water resource.And many private car owners like the carwash under burning sun, it is believed that will soon will be on vehicle body after so washing
Water dries, and it is local that the convex lens effect that common car washing liquid water droplet is formed under tangible burning sun can generate the top layer of vehicle paint
High temperataure phenomena easily makes vehicle paint tarnish, and largely effects on vehicle body appearance.
For this purpose, people are explored in car washing operation method and car washing liquid species.For example, disclosed in CN1704293A
A kind of water-saving type carwash method, by 5 steps, mainly repetitious wiping reaches water-saving and clean mesh
's.The method that CN105505642A discloses another water-saving vehicle washing reaches section by the use of the car washing liquid of special component
Water purpose.But above-mentioned car washing liquid in high temperature burning sun condition but is attached to the particulate matter of bodywork surface in rag or bulk sponge
Firmly and wiping repeatedly under, be also easy to surface of vehicle paint generate cut.Down in use, being difficult to keep preferable carwash, shield
Vehicle effect.
The content of the invention
In order to solve the above technical problem, the present invention provides a kind of high temperature car washing liquid, the high temperature car washing liquid includes 93-
The deionized water of 96 parts by weight, the silicone oil of the emulsification of 0.5-2.5 parts by weight, the wax emulsion of 0.5-1.5 parts by weight, 0.2-0.5 weights
Amount part includes the surfactant of amino acid type amphoteric surfactant, 1.0-2.0 parts by weight boiling point is 250-350 DEG C molten
Agent oil, the long-chain unsaturated acids of 0.1-0.2 parts by weight, the polyisobutene succinimide and 0.02- of 0.01-0.25 parts by weight
The triethanolamine of 0.06 parts by weight.
As a preferred embodiment, the silicone oil of the emulsification is selected from methyl silicone emulsion, ethyl silicone emulsion, first
The hydrogeneous silicone emulsion of base, methyl ethoxy silicone emulsion, methyl trifluoro propyl silicone emulsion, methyl ethylene silicone emulsion, first
One or more of base hydroxyl silicone emulsion, the hydrogeneous silicone emulsion of ethyl, amino silicone emulsion, the hydrogeneous silicone emulsion of hydroxyl.
As a preferred embodiment, it is characterized in that, the silicone oil of the emulsification includes solid content in 40%-65%
Methyl trifluoro propyl silicone emulsion and solid content the amino silicone emulsion of 30%-40% mixture.
As a preferred embodiment, it is characterized in that, the high temperature car washing liquid further includes 10000-15000cst
Viscous silicone fluid, the mass ratio of the viscous silicone fluid and surfactant is 1：20-40.
As a preferred embodiment, the surfactant includes the alkyl phenol polyoxy of 0.07-0.09 parts by weight
Vinethene, the isomeric alcohol polyethenoxy ether of 0.05-0.07 parts by weight, 0.02-0.03 parts by weight phosphate ester surfactants and
The amino acid type amphoteric surfactant of 0.005-0.05 parts by weight.
As a preferred embodiment, the amino acid type amphoteric surfactant is obtained through following steps：First
Sodium chloroacetate is added in into the lauryl amine aqueous solution containing 5-10% mass percents, 0.5h is stirred to react at 60-70 DEG C,
PH is adjusted to neutrality using dilute hydrochloric acid；Sodium hydroxide is added, the reaction was continued under the conditions of 60-70 DEG C 0.5h obtains amino acid
Type amphoteric surfactant；The mass ratio of lauryl amine, sodium chloroacetate and sodium hydroxide in wherein described lauryl amine aqueous solution is
1：0.5-1.5：0.1-0.2.
As a preferred embodiment, the long-chain unsaturated acids is selected from erucic acid, selacholeic acid, nutmeg oleic acid, 2-
The combination of one or more of gaidic acid, palmitoleic acid, oleic acid, leukotrienes, 9- eicosenoic acids；The wax emulsion choosing
From babassu wax emulsion, lignite wax emulsion, beeswax lotion, wool wax emulsion, paraffin wax emulsions, red bayberry wax emulsion, haze tallow lotion
One or more of combination.
As a preferred embodiment, high temperature car washing liquid further include 0.01-0.1 parts by weight antistatic agent and
Pigment, essence, the preservative of 0.01-0.5 parts by weight.
The present invention provides a kind of preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 93-96 parts by weight is added in the first container, stirring is treated that temperature is increased to 40-50 DEG C, added in
The alkylphenol polyoxyethylene ether of 0.07-0.09 parts by weight, the isomeric alcohol polyethenoxy ether and 0.02- of 0.05-0.07 parts by weight
The phosphate ester surfactants of 0.03 parts by weight, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in 0.02-0.06
The triethanolamine of parts by weight, the long-chain unsaturated acids of 0.1-0.2 parts by weight, the polyisobutene succinyl of 0.01-0.25 parts by weight
Imines stirs evenly, and obtains the first mixed liquor；
The wax emulsion of 0.5-1.5 parts by weight is added in second container, stirring when temperature is increased to 50-60 DEG C, adds in
1.0-2 parts by weight boiling point is 250-350 DEG C of solvent naphtha, is uniformly mixing to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds in 0.5-2.5 weight
The silicone oil of the emulsification of part, stirs evenly；Add the amino acid type amphoteric surfactant of 0.005-0.05 parts by weight, 0.01-
The antistatic agent of 0.1 parts by weight stirs 15min at 75-85 DEG C, adds in the pigment, essence, anti-corrosion of 0.01-0.5 parts by weight
Agent stirs evenly, and obtains high temperature car washing liquid.
The present invention also provides the car-washing methods under a kind of hot conditions, comprise the following steps：
The high temperature car washing liquid is sprayed to surface of vehicle paint, stands 30-60 seconds；It is wiped away using towel or sponge brush except vehicle
Paint the dirt on surface and the liquid of remnants；The towel is bamboo fibre or superfine fibre towel.
The present invention high temperature car washing liquid mainly by water, emulsification silicone oil, wax emulsion, solvent naphtha, surfactant and its
His auxiliary agent composition, the content of water reach more than 93%, and materials environmental protection, can use again under conditions of high temperature burning sun, and decontamination is high
It imitates, is low on the influence of automobile finish glossiness.
Due to car surface dirt species complexity it is necessary to have fabulous scourability surfactant.The present invention's
Organic silicone oil can not only improve the brightness of car surface after washing, additionally it is possible to synergistic effect is played with surfactant,
Improve the scourability of car washing liquid.In addition, surfactant, organic solvent and wax that the present invention uses are environment-friendly degradables
Material.
Specific embodiment
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of fields of the present invention
The normally understood identical meaning of art personnel.When there is a conflict, the definition in this specification shall prevail.
The high temperature car washing liquid of the present invention includes the deionized water of 93-96 parts by weight, the silicon of the emulsification of 0.5-2.5 parts by weight
Oil, the wax emulsion of 0.5-1.5 parts by weight, 0.2-0.5 parts by weight include the surface-active of amino acid type amphoteric surfactant
Agent, the solvent naphtha that 1.0-2.0 parts by weight boiling point is 250-350 DEG C, long-chain unsaturated acids, the 0.01-0.25 of 0.1-0.2 parts by weight
The polyisobutene succinimide of parts by weight and the triethanolamine of 0.02-0.06 parts by weight.
Wherein the boiling point of solvent naphtha is 250-350 DEG C, and inventor has found preferably improve under high temperature car washing liquid high temperature
Performance, obtain preferably scratch repair.
As a kind of perferred technical scheme, the silicone oil of the emulsification is selected from silicone emulsion, methyl silicone emulsion, ethyl breast
SiClx oil, methyl hydrogen silicone emulsion, methyl ethoxy silicone emulsion, methyl trifluoro propyl silicone emulsion, methyl ethylene breast
One in SiClx oil, methylhydroxy silicone emulsion, the hydrogeneous silicone emulsion of ethyl, amino silicone emulsion, the hydrogeneous silicone emulsion of hydroxyl
Kind is several.
As a kind of perferred technical scheme, the silicone oil of the emulsification includes methyl trifluoro of the solid content in 40%-65%
Propyl silicone emulsion and solid content are in the mixture of the amino silicone emulsion of 30%-40%.
As a kind of perferred technical scheme, the silicone oil of the emulsification by solid content 40%-65% methyl trifluoro propyl
The amino silicone emulsion of silicone emulsion and solid content in 30%-40% forms.
As a kind of perferred technical scheme, the silicone oil of the emulsification by solid content 40%-65% methyl trifluoro propyl
Silicone emulsion and solid content more than 30%-40% amino silicone emulsion according to weight ratio 1：15-20 is formed.
The silicone oil solid content of above-described emulsification contains admittedly for quality.
As a kind of perferred technical scheme, high temperature car washing liquid of the invention further includes the high viscosity of 10000-15000cst
Silicone oil, the silicone oil of 10000-15000cst and the mass ratio of surfactant are 1：20-40, using highly viscous methyl-silicone oil
Although being unfavorable for the brightness of surface of vehicle paint, surface-active can be improved using the silicone oil of a small amount of 10000-15000cst
Agent Fouling Cleaning effect, it may be possible to because highly viscous methyl-silicone oil can promote surfactant formed lamellar phase.
As a kind of perferred technical scheme, the surfactant includes the alkyl phenol polyoxy of 0.07-0.09 parts by weight
Vinethene, the isomeric alcohol polyethenoxy ether of 0.05-0.07 parts by weight, 0.02-0.03 parts by weight phosphate ester surfactants and
The amino acid type amphoteric surfactant of 0.005-0.05 parts by weight.
As a kind of perferred technical scheme, the alkylphenol polyoxyethylene ether includes nonylphenol polyoxyethylene ether, octyl group
Phenol polyethenoxy ether, dodecyl polyoxyethylene ether (DPEO) and Dinonylphenol Polyoxyethylene Ether (DNPEO), and then preferred nonyl
Phenol polyethenoxy ether.
As a kind of perferred technical scheme, the isomeric alcohol polyethenoxy ether includes heterogeneous ten alcohol polyoxyethylene ether, different
Structure undecyl alcohol polyoxyethylene ether, isomerous tridecanol polyoxyethylene ether.
As a kind of perferred technical scheme, the phosphate ester surfactants include fatty alcohol polyoxyethylene ether phosphoric acid
It is ester/salt, Phosphate of Polyoxyethylene Isooctyl Ether, thermally coupled distillation columns/salt, isomerous tridecanol ether phosphate, different
Decyl alcohol ether phosphate.
As a kind of perferred technical scheme, the amino acid type amphoteric surfactant is obtained through following steps：First
Sodium chloroacetate is added in into the lauryl amine aqueous solution containing 5-10% mass percents, 0.5h is stirred to react at 60-70 DEG C,
PH is adjusted to neutrality using dilute hydrochloric acid；Sodium hydroxide is added, the reaction was continued under the conditions of 60-70 DEG C 0.5h obtains amino acid
Type amphoteric surfactant；The mass ratio of lauryl amine, sodium chloroacetate and sodium hydroxide in wherein described lauryl amine aqueous solution is
1：0.5-1.5：0.1-0.2.
Lauryl amine by being first substantially dissolved in water by currently preferred amino acid type amphoteric surfactant, Ran Houxiang
Successively add in sodium chloroacetate in lauryl amine solution and sodium hydroxide reacted after obtain, the inventors discovered that in high temperature car washing liquid
In plus a small amount of above-mentioned amphoteric surfactant, then compatibility specific wax emulsion, solvent naphtha in right amount, can not only greatly improve and wash
Vehicle liquid cleaning performance under high temperature burning sun, and vehicle paint brightness does not weaken, and conjecture may be because this amino acid pattern two
Property the special charged characteristic of surfactant, promote cured scattered in car washing liquid, car washing liquid water droplet made to become more flat, is reduced
The convex lens effect of high temperature burning sun.The polyisobutene succinimide and long-chain unsaturated acids of the present invention can be reduced and repaired
Scuffing in wiping process, the possible reason is polyisobutene succinimide has substantial amounts of hydrogen bond, long-chain unsaturated acids energy
Enough and plane of crystal, abraded area generate strong absorption.
As a kind of perferred technical scheme, lauryl amine, sodium chloroacetate and the sodium hydroxide in the lauryl amine aqueous solution
Mass ratio be 1：0.8：0.1.
As a kind of perferred technical scheme, the long-chain unsaturated acids is selected from erucic acid, selacholeic acid, nutmeg oleic acid, 2-
The combination of one or more of gaidic acid, palmitoleic acid, oleic acid, leukotrienes, 9- eicosenoic acids；The wax emulsion is selected from
In babassu wax emulsion, lignite wax emulsion, beeswax lotion, wool wax emulsion, paraffin wax emulsions, red bayberry wax emulsion, haze tallow lotion
One or more of combinations.
As a kind of perferred technical scheme, the high temperature car washing liquid further includes the antistatic agent of 0.01-0.1 parts by weight,
And pigment, essence, the preservative of 0.01-0.5 parts by weight.
As a kind of perferred technical scheme, the high temperature car washing liquid further includes the antistatic agent ox of 0.01-0.1 parts by weight
The pigment of fat amine polyoxyethylene ether and 0.01-0.5 parts by weight, essence, preservative methyl hydroxybenzoate.
The present invention also provides a kind of preparation methods of high temperature car washing liquid, comprise the following steps：
The deionized water of 93-96 parts by weight is added in the first container, stirring is treated that temperature is increased to 40-50 DEG C, added in
The alkylphenol polyoxyethylene ether of 0.07-0.09 parts by weight, the isomeric alcohol polyethenoxy ether and 0.02- of 0.05-0.07 parts by weight
The phosphate ester surfactants of 0.03 parts by weight, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in 0.02-0.06
The triethanolamine of parts by weight, the long-chain unsaturated acids of 0.1-0.2 parts by weight, the polyisobutene succinyl of 0.01-0.25 parts by weight
Imines stirs evenly, and obtains the first mixed liquor；
The wax emulsion of 0.5-1.5 parts by weight is added in second container, stirring when temperature is increased to 50-60 DEG C, adds in
1.0-2 parts by weight boiling point is 250-350 DEG C of solvent naphtha, is uniformly mixing to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds in 0.5-2.5 weight
The silicone emulsion of part, stirs evenly；Add the amino acid type amphoteric surfactant of 0.005-0.05 parts by weight, 0.01-0.1
The antistatic agent of parts by weight stirs 15min at 75-85 DEG C, adds in pigment, essence, the preservative of 0.01-0.5 parts by weight, stirs
It mixes uniformly, obtains high temperature car washing liquid.
The present invention also provides the car-washing methods under a kind of hot conditions, comprise the following steps：
Any one high temperature car washing liquid recited above is sprayed to surface of vehicle paint, stands 30-60 seconds；Use towel or sea
The dirt of silk floss wiping removal surface of vehicle paint and the liquid of remnants.
As a kind of perferred technical scheme, the towel is bamboo fibre or superfine fibre towel.
Using bamboo fibre or superfine fibre towel can under the premise of keeping compared with high definition spot effect, be further reduced cut and
Brightness is improved, it is presumed that being that amino acid surfactant in high temperature car washing liquid of the present invention enhances fiber on fiber towel
Between repulsive interaction, reduce the frictional force between fiber, it made to become more soft and smooth, be more easy to play carwash
The cleaning function of liquid.And the effect of bamboo fiber towel is compared with superfine fibre towel more preferably.
The present invention high temperature car washing liquid mainly by water, emulsification silicone oil, wax emulsion, solvent naphtha, surfactant and its
His auxiliary agent composition, the content of water reach more than 93%, and materials environmental protection, can use again under conditions of high temperature burning sun, and decontamination is high
It imitates, is low on the influence of automobile finish glossiness.
Due to car surface dirt species complexity it is necessary to have fabulous scourability surfactant.Present invention choosing
The compatible uses such as amino acid type amphoteric surfactant and wax emulsion, solvent naphtha can not only improve automobile table after washing
The brightness in face, additionally it is possible to improve scourability of the car washing liquid under high temperature burning sun.
In addition, surfactant, organic solvent and wax that the present invention uses are the materials of environment-friendly degradable.
Hereinafter, the present invention is explained in more detail by embodiment, it should be appreciated that these embodiments are only
Illustrate and not restrictive.It is if raw materials used to be all commercially available without other explanations.
The present invention is described in detail referring to several examples.
The amino acid type amphoteric surfactant preparation method that following embodiment uses is as follows：
（1）Amino acid type amphoteric surfactant A：Sodium chloroacetate is added in 12 containing 5% mass percent first
In amine aqueous solution, 0.5h is stirred to react at 60-70 DEG C, pH is adjusted to neutrality using dilute hydrochloric acid；Sodium hydroxide is added,
The reaction was continued under the conditions of 60-70 DEG C 0.5h, acquisition amino acid type amphoteric surfactant A；In wherein described lauryl amine aqueous solution
Lauryl amine, the mass ratio of sodium chloroacetate and sodium hydroxide be 1：0.8：0.1.
（2）Amino acid type amphoteric surfactant B：Sodium chloroacetate is added in 12 containing 8% mass percent first
In amine aqueous solution, 0.5h is stirred to react at 60-70 DEG C, pH is adjusted to neutrality using dilute hydrochloric acid；Sodium hydroxide is added,
The reaction was continued under the conditions of 60-70 DEG C 0.5h, acquisition amino acid type amphoteric surfactant B；In wherein described lauryl amine aqueous solution
Lauryl amine, the mass ratio of sodium chloroacetate and sodium hydroxide be 1：1.5：0.1.
Embodiment 1
The component of high temperature car washing liquid includes：The deionized water of 95 parts by weight, the solid content of 2 parts by weight are 50% methyl three
Fluoropropyl silicone emulsion, 0.1 parts by weight solid content be 30% amino silicone emulsion, 0.09 parts by weight lignite wax emulsion,
The solid content of 1.0 parts by weight is 30% babassu wax emulsion, the amino acid type amphoteric surfactant A of 0.03 parts by weight, 0.09
The nonylphenol polyoxyethylene ether of parts by weight, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight, the isooctanol of 0.03 parts by weight
The solvent naphtha, the oleic acid of 0.15 parts by weight, 0.03 weight that polyoxyethylene ether phosphate, the boiling point of 1.8 parts by weight are 250-350 DEG C
The polyisobutene succinimide, the triethanolamine of 0.05 parts by weight, the pigment of 0.02 parts by weight, essence, methyl hydroxybenzoate of part.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 parts by weight is added in the first container, is stirred, treats that temperature is increased to 40-50 DEG C, adds in 0.09
The isooctanol of the nonylphenol polyoxyethylene ether of parts by weight, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight and 0.03 parts by weight
Polyoxyethylene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in the triethanolamine of 0.05 parts by weight,
The polyisobutene succinimide of the oleic acid of 0.15 parts by weight, 0.03 parts by weight, stirs evenly, and obtains the first mixed liquor；
The lignite wax emulsion of 0.09 parts by weight is added in second container, the solid content of 1.0 parts by weight is 30% babassu
Wax emulsion, stirring when temperature is increased to 50-60 DEG C, add in the solvent naphtha that 1.8 parts by weight boiling points are 250-350 DEG C, and stirring is equal
It is even to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds in 0.1 parts by weight
The amino silicone emulsion that methyl trifluoro propyl silicone emulsion that solid content is 50%, the solid content of 2.0 parts by weight are 30%, stirring are equal
It is even；Add the amino acid type amphoteric surfactant A of 0.03 parts by weight, the antistatic agent tallow amine polyoxy second of 0.05 parts by weight
Alkene ether stirs 15min at 75-85 DEG C, adds in pigment, essence, the methyl hydroxybenzoate of 0.02 parts by weight, stirs evenly, obtain
High temperature car washing liquid.
Embodiment 2
The component of high temperature car washing liquid includes：The deionized water of 95 parts by weight, the solid content of 0.1 parts by weight are 50% methyl
Trifluoro propyl silicone emulsion, 2 parts by weight solid content be 30% amino silicone emulsion, 0.09 parts by weight lignite wax emulsion,
The solid content of 1.0 parts by weight is 30% babassu wax emulsion, the amino acid type amphoteric surfactant A of 0.03 parts by weight, 0.09
The nonylphenol polyoxyethylene ether of parts by weight, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight, the isooctanol of 0.03 parts by weight
The solvent naphtha, the oleic acid of 0.15 parts by weight, 0.08 weight that polyoxyethylene ether phosphate, the boiling point of 1.8 parts by weight are 250-350 DEG C
The polyisobutene succinimide, the triethanolamine of 0.05 parts by weight, the pigment of 0.02 parts by weight, essence, methyl hydroxybenzoate of part.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 parts by weight is added in the first container, is stirred, treats that temperature is increased to 40-50 DEG C, adds in 0.09
The isooctanol of the nonylphenol polyoxyethylene ether of parts by weight, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight and 0.03 parts by weight
Polyoxyethylene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in the triethanolamine of 0.05 parts by weight,
The polyisobutene succinimide of the oleic acid of 0.15 parts by weight, 0.08 parts by weight, stirs evenly, and obtains the first mixed liquor；
The lignite wax emulsion of 0.09 parts by weight is added in second container, the solid content of 1.0 parts by weight is 30% babassu
Wax emulsion, stirring when temperature is increased to 50-60 DEG C, add in the solvent naphtha that 1.8 parts by weight boiling points are 250-350 DEG C, and stirring is equal
It is even to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds in consolidating for 2 parts by weight
The amino silicone emulsion that methyl trifluoro propyl silicone emulsion that content is 50%, the solid content of 0.1 parts by weight are 30%, stirring are equal
It is even；Add the amino acid type amphoteric surfactant A of 0.03 parts by weight, the antistatic agent tallow amine polyoxy second of 0.05 parts by weight
Alkene ether stirs 15min at 75-85 DEG C, adds in pigment, essence, the methyl hydroxybenzoate of 0.02 parts by weight, stirs evenly, obtain
High temperature car washing liquid.
Embodiment 3
The component of high temperature car washing liquid includes：The deionized water of 95 parts by weight, the solid content of 1 parts by weight are 50% methyl three
Fluoropropyl silicone emulsion, the amino silicone emulsion that the solid content of 1 parts by weight is 30%, the lignite wax emulsion of 0.09 parts by weight, 1.0
The solid content of parts by weight is 30% babassu wax emulsion, the amino acid type amphoteric surfactant A of 0.03 parts by weight, 0.09 weight
The amount nonylphenol polyoxyethylene ether of part, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight, the isooctanol of 0.03 parts by weight gather
The solvent naphtha, the oleic acid of 0.15 parts by weight, 0.2 parts by weight that ethylene oxide ether phosphate, the boiling point of 1.8 parts by weight are 250-350 DEG C
Polyisobutene succinimide, the triethanolamine of 0.05 parts by weight, the pigment of 0.02 parts by weight, essence, methyl hydroxybenzoate.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 parts by weight is added in the first container, is stirred, treats that temperature is increased to 40-50 DEG C, adds in 0.09
The isooctanol of the nonylphenol polyoxyethylene ether of parts by weight, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight and 0.03 parts by weight
Polyoxyethylene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in the triethanolamine of 0.05 parts by weight,
The polyisobutene succinimide of the oleic acid of 0.15 parts by weight, 0.2 parts by weight, stirs evenly, and obtains the first mixed liquor；
The lignite wax emulsion of 0.09 parts by weight is added in second container, the solid content of 1.0 parts by weight is 30% babassu
Wax emulsion, stirring when temperature is increased to 50-60 DEG C, add in the solvent naphtha that 1.8 parts by weight boiling points are 250-350 DEG C, and stirring is equal
It is even to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds in consolidating for 1 parts by weight
The amino silicone emulsion that methyl trifluoro propyl silicone emulsion that content is 50%, the solid content of 1 parts by weight are 30%, stirs evenly；
Add the amino acid type amphoteric surfactant A of 0.03 parts by weight, the antistatic agent tallow amine polyoxyethylene of 0.05 parts by weight
Ether stirs 15min at 75-85 DEG C, adds in pigment, essence, the methyl hydroxybenzoate of 0.02 parts by weight, stirs evenly, obtain height
Warm car washing liquid.
Embodiment 4
The component of high temperature car washing liquid includes：The deionized water of 95 parts by weight, the solid content of 0.1 parts by weight are 50% methyl
Amino silicone emulsion, the 12000cst methyl of 0.015 parts by weight that trifluoro propyl silicone emulsion, the solid content of 2 parts by weight are 30%
Silicone oil, the lignite wax emulsion of 0.09 parts by weight, the solid content of 1.0 parts by weight are 30% babassu wax emulsion, 0.03 parts by weight
Amino acid type amphoteric surfactant A, the nonylphenol polyoxyethylene ether of 0.09 parts by weight, the isomerous tridecanol of 0.06 parts by weight gather
The solvent that ethylene oxide ether, the Phosphate of Polyoxyethylene Isooctyl Ether of 0.03 parts by weight, the boiling point of 1.8 parts by weight are 250-350 DEG C
Oil, the oleic acid of 0.15 parts by weight, the polyisobutene succinimide of 0.1 parts by weight, the triethanolamine of 0.05 parts by weight, 0.02 weight
Measure the pigment, essence, methyl hydroxybenzoate of part.
The preparation method of high temperature car washing liquid is same as Example 1, and difference lies in add in after amino silicone emulsion is added in
The 12000cst methyl-silicone oils of 0.015 parts by weight.
Embodiment 5
The component of high temperature car washing liquid includes：The deionized water of 95 parts by weight, the solid content of 0.1 parts by weight are 50% methyl
Amino silicone emulsion, the 12000cst methyl of 0.015 parts by weight that trifluoro propyl silicone emulsion, the solid content of 2 parts by weight are 30%
Silicone oil, the lignite wax emulsion of 0.09 parts by weight, the solid content of 1.0 parts by weight are 30% babassu wax emulsion, 0.03 parts by weight
Amino acid type amphoteric surfactant A, the nonylphenol polyoxyethylene ether of 0.09 parts by weight, the isomerous tridecanol of 0.06 parts by weight gather
The solvent that ethylene oxide ether, the Phosphate of Polyoxyethylene Isooctyl Ether of 0.03 parts by weight, the boiling point of 1.8 parts by weight are 250-350 DEG C
Oil, the oleic acid of 0.15 parts by weight, the polyisobutene succinimide of 0.1 parts by weight, the triethanolamine of 0.05 parts by weight, 0.02 weight
Measure the pigment, essence, methyl hydroxybenzoate of part.The preparation method of high temperature car washing liquid is same as Example 1.
Embodiment 6
Same as Example 1, difference lies in amino acid type amphoteric surfactant uses amino acid type amphoteric surface
Activating agent B.
Comparative example 1
The component of high temperature car washing liquid includes：The deionized water of 95 parts by weight, the solid content of 0.1 parts by weight are 50% methyl
Amino silicone emulsion, lignite wax emulsion, 1.0 parts by weight of 0.09 parts by weight that silicone emulsion, the solid content of 2 parts by weight are 30%
Solid content for 30%-40% babassus wax emulsion, the nonylphenol polyoxyethylene ether of 0.09 parts by weight, the isomery of 0.06 parts by weight
Tridecanol polyoxyethylene ether, the Phosphate of Polyoxyethylene Isooctyl Ether of 0.03 parts by weight, the boiling point of 1.8 parts by weight are 250-350
DEG C solvent naphtha, oleic acid, the triethanolamine of 0.05 parts by weight, the pigment of 0.02 parts by weight, essence, the nipalgin of 0.15 parts by weight
Methyl esters.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 parts by weight is added in the first container, is stirred, treats that temperature is increased to 40-50 DEG C, adds in 0.09
The isooctanol of the nonylphenol polyoxyethylene ether of parts by weight, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight and 0.03 parts by weight
Polyoxyethylene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in the triethanolamine of 0.05 parts by weight,
The oleic acid of 0.15 parts by weight, stirs evenly, and obtains the first mixed liquor；
The lignite wax emulsion of 0.09 parts by weight is added in second container, the solid content of 1.0 parts by weight is 30% babassu
Wax emulsion, stirring when temperature is increased to 50-60 DEG C, add in the solvent naphtha that 1.8 parts by weight boiling points are 250-350 DEG C, and stirring is equal
It is even to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds in 0.1 parts by weight
The amino silicone emulsion that silicone emulsion that solid content is 50%, the solid content of 2.0 parts by weight are 30%, stirs evenly；It adds
The antistatic agent tallow amine polyoxyethylene ether of 0.05 parts by weight stirs 15min at 75-85 DEG C, adds in the color of 0.02 parts by weight
Element, essence, methyl hydroxybenzoate, stir evenly, and obtain high temperature car washing liquid.
Comparative example 2：
The component of high temperature car washing liquid includes：The deionized water of 95 parts by weight, the solid content of 0.1 parts by weight are 50% methyl
Amino silicone emulsion, lignite wax emulsion, 1.0 parts by weight of 0.09 parts by weight that silicone emulsion, the solid content of 2 parts by weight are 30%
Solid content be 30% babassu wax emulsion, the amino acid type amphoteric surfactant As of 0.03 parts by weight, 0.09 parts by weight
Nonylphenol polyoxyethylene ether, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight, the isooctanol polyoxyethylene of 0.03 parts by weight
Ether phosphate, the oleic acid of 0.15 parts by weight, the triethanolamine of 0.05 parts by weight, the pigment of 0.02 parts by weight, essence, Metagin
Ester.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 parts by weight is added in the first container, is stirred, treats that temperature is increased to 40-50 DEG C, adds in 0.09
The isooctanol of the nonylphenol polyoxyethylene ether of parts by weight, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight and 0.03 parts by weight
Polyoxyethylene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in the triethanolamine of 0.05 parts by weight,
The oleic acid of 0.15 parts by weight, stirs evenly, and obtains the first mixed liquor；
The lignite wax emulsion of 0.09 parts by weight, the solid content of 1.0 parts by weight are added in second container as 30%-40% Brazil
Palm wax emulsion, stirring, is uniformly mixing to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds in 0.1 parts by weight
The amino silicone emulsion that methyl silicone emulsion that solid content is 50%, the solid content of 2.0 parts by weight are 30%, stirs evenly；Again plus
Enter the amino acid type amphoteric surfactant A of 0.03 parts by weight, the antistatic agent tallow amine polyoxyethylene ether of 0.05 parts by weight,
15min is stirred at 75-85 DEG C, pigment, essence, the methyl hydroxybenzoate of 0.02 parts by weight is added in, stirs evenly, obtain high temperature carwash
Liquid.
Comparative example 3
The component of car washing liquid includes：The deionized water of 95 parts by weight, the methyl that the solid content of 0.1 parts by weight is 50% emulsify
Amino silicone emulsion, nonylphenol polyoxyethylene ether, 0.06 weight of 0.09 parts by weight that silicone oil, the solid content of 2 parts by weight are 30%
Part isomerous tridecanol polyoxyethylene ether, the Phosphate of Polyoxyethylene Isooctyl Ether of 0.03 parts by weight, the boiling point of 1.8 parts by weight be
250-350 DEG C of solvent naphtha, the oleic acid of 0.15 parts by weight, the triethanolamine of 0.05 parts by weight, the pigment of 0.02 parts by weight, perfume (or spice)
Essence, methyl hydroxybenzoate.
The preparation method of car washing liquid, comprises the following steps：
The deionized water of 95 parts by weight is added in a reservoir, is stirred, and is treated that temperature is increased to 40-50 DEG C, is added in 0.09 weight
The nonylphenol polyoxyethylene ether, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight and the isooctanol polyoxy of 0.03 parts by weight of part
Ethylene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in the triethanolamine of 0.05 parts by weight, 0.15
The oleic acid of parts by weight, stirs evenly, and obtains the first mixed liquor；Add in the solvent naphtha that 1.8 parts by weight boiling points are 250-350 DEG C；Again
The amino silicone emulsion that methyl silicone emulsion that the solid content for adding in 2 parts by weight is 50%, the solid content of 0.1 parts by weight are 30%,
It stirs evenly；The antistatic agent tallow amine polyoxyethylene ether of 0.05 parts by weight is added, 15min is stirred at 75-85 DEG C, is added in
Pigment, essence, the methyl hydroxybenzoate of 0.02 parts by weight, stir evenly, obtain car washing liquid.
Comparative example 4：
The component of car washing liquid includes：The deionized water of 95 parts by weight, the methyl that the solid content of 0.1 parts by weight is 50% emulsify
Silicone oil, 2 parts by weight solid content be 30% amino silicone emulsion, 0.03 parts by weight amino acid type amphoteric surfactant A,
The nonylphenol polyoxyethylene ether of 0.09 parts by weight, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight, 0.03 parts by weight it is different
Octanol polyoxyethylene ether phosphate, the solvent naphtha that the boiling point of 1.8 parts by weight is 250-350 DEG C, the oleic acid of 0.15 parts by weight, 0.05
The triethanolamine of parts by weight, the pigment of 0.02 parts by weight, essence, methyl hydroxybenzoate.
The preparation method of car washing liquid, comprises the following steps：
The deionized water of 95 parts by weight is added in a reservoir, is stirred, and is treated that temperature is increased to 40-50 DEG C, is added in 0.09 weight
The nonylphenol polyoxyethylene ether, the isomerous tridecanol polyoxyethylene ether of 0.06 parts by weight and the isooctanol polyoxy of 0.03 parts by weight of part
Ethylene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, adds in the triethanolamine of 0.05 parts by weight, 0.15
The oleic acid of parts by weight, it stirs evenly, obtains the first mixed liquor；Add in the solvent naphtha that 1.8 parts by weight boiling points are 250-350 DEG C；Again
The amino silicone emulsion that methyl silicone emulsion that the solid content for adding in 2 parts by weight is 50%, the solid content of 0.1 parts by weight are 30%,
It stirs evenly；Add the amino acid type amphoteric surfactant A of 0.03 parts by weight, the antistatic agent tallow amine of 0.05 parts by weight
Polyoxyethylene ether stirs 15min at 75-85 DEG C, adds in pigment, essence, the methyl hydroxybenzoate of 0.02 parts by weight, and stirring is equal
It is even, obtain car washing liquid.
Evaluation：
Certain amount is taken to have the metallic plate of automobile coating（330mm×100mm）, brightness is essentially identical and surface tear number
It measures essentially identical, is placed on the outdoor of a small amount of airborne dust 14 days, then in 40 DEG C of temperature and the item of light source analogy solar irradiation is set
Under part, each 15 of metallic plate is cleaned using the car washing liquid of embodiment and comparative example.Car washing liquid is sprayed into metal sheet surface, until
Metal sheet surface covers car washing liquid substantially, stands 45 seconds, removes dirt using towel wiping, then is removed using a clean towel
The liquid of surface residual：The towel that wherein embodiment 1-4,6 and comparative example 1-3 are used is bamboo fiber towel, embodiment 5 and comparison
Example 4 uses common cotton towels.
Metal sheet surface brightness and scuffing item number after observation cleaning, and compared.By substantially brighter after cleaning
It is substantially deteriorated to brightness and is denoted as+6 to -6, cut quantity is significantly reduced to cut quantity, and substantially increase is denoted as+6 to -6, uses
Surface observation dirt after paper handkerchief wiping cleaning, spot substantially arrive no spot and are denoted as 6 to 0, take the average value of 15 metallic plates
As a result it is as follows.
As can be seen that cut can be significantly reduced using car washing liquid of the present invention.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention.It is every
The equivalent changes and modifications that content is done according to the present invention are encompassed by the scope of the claims of the present invention.
Claims (4)
1. a kind of high temperature car washing liquid, which is characterized in that the high temperature car washing liquid includes the deionized water of 93-96 parts by weight, 0.5-
The silicone oil of the emulsification of 2.5 parts by weight, the wax emulsion of 0.5-1.5 parts by weight, the alkylphenol-polyethenoxy of 0.07-0.09 parts by weight
Ether, the isomeric alcohol polyethenoxy ether of 0.05-0.07 parts by weight, the phosphate ester surfactants of 0.02-0.03 parts by weight, 0.005-
The amino acid type amphoteric surfactant of 0.05 parts by weight, the solvent naphtha that 1.0-2.0 parts by weight boiling point is 250-350 DEG C, 0.1-
The long-chain unsaturated acids of 0.2 parts by weight, the polyisobutene succinimide of 0.01-0.25 parts by weight and 0.02-0.06 parts by weight
Triethanolamine,
The silicone oil of the emulsification is selected from methyl silicone emulsion, ethyl silicone emulsion, methyl hydrogen silicone emulsion, methyl ethoxy breast
SiClx oil, methyl trifluoro propyl silicone emulsion, methyl ethylene silicone emulsion, methylhydroxy silicone emulsion, the hydrogeneous emulsification of ethyl
One or more of silicone oil, amino silicone emulsion, the hydrogeneous silicone emulsion of hydroxyl,
The silicone oil of the emulsification includes methyl trifluoro propyl silicone emulsion and solid content of the solid content in 40%-65% in 30%-
The mixture of 40% amino silicone emulsion,
The amino acid type amphoteric surfactant is obtained through following steps：Sodium chloroacetate is added in containing 5-10% matter first
In the lauryl amine aqueous solution for measuring percentage, 0.5h is stirred to react at 60-70 DEG C, pH is adjusted to neutrality using dilute hydrochloric acid；Again plus
Enter sodium hydroxide, the reaction was continued under the conditions of 60-70 DEG C 0.5h obtains amino acid type amphoteric surfactant；Wherein described ten
The mass ratio of lauryl amine, sodium chloroacetate and sodium hydroxide in two amine aqueous solutions is 1：0.5-1.5：0.1-0.2,
The long-chain unsaturated acids is selected from erucic acid, selacholeic acid, nutmeg oleic acid, 2- gaidic acids, palmitoleic acid, oleic acid, Asia
The combination of one or more of numb acid, 9- eicosenoic acids；
The wax emulsion is selected from babassu wax emulsion, lignite wax emulsion, beeswax lotion, wool wax emulsion, paraffin wax emulsions, red bayberry
The combination of one or more of wax emulsion, haze tallow lotion.
2. high temperature car washing liquid according to claim 1, which is characterized in that the high temperature car washing liquid further includes 10000-
The mass ratio of the viscous silicone fluid of 15000cst, the viscous silicone fluid and surfactant is 1：20-40, the surface-active
The quality of agent is alkylphenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether, phosphate ester surfactants, amino acid type amphoteric surface
The quality summation of activating agent.
3. high temperature car washing liquid according to claim 1, which is characterized in that high temperature car washing liquid further includes 0.01-0.1 parts by weight
Antistatic agent and 0.01-0.5 parts by weight pigment, essence, preservative.
4. the car-washing method under a kind of hot conditions, which is characterized in that comprise the following steps：
High temperature car washing liquid described in any one claim in claim 1-3 is sprayed to surface of vehicle paint, stands 30-60
Second；Wipe the liquid of the dirt and remnants except surface of vehicle paint away using towel or sponge brush；The towel is bamboo fibre or ultra-fine
Fiber towel.
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| CN1563236A (en) * | 2004-04-22 | 2005-01-12 | 王金环 | Brightening agent for vehicle without water washing, and preparation method |
| CN103614083A (en) * | 2013-12-03 | 2014-03-05 | 沈阳化工大学 | Automobile cleaning water wax and preparation method thereof |
| CN105368596A (en) * | 2015-12-11 | 2016-03-02 | 天津璞誉环保科技开发有限公司 | Vehicle cleaning agent with strong antirust capability |
| EP3091066A1 (en) * | 2015-05-06 | 2016-11-09 | Latvijas Universitate | Vehicles anhydrous care products |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1563236A (en) * | 2004-04-22 | 2005-01-12 | 王金环 | Brightening agent for vehicle without water washing, and preparation method |
| CN103614083A (en) * | 2013-12-03 | 2014-03-05 | 沈阳化工大学 | Automobile cleaning water wax and preparation method thereof |
| EP3091066A1 (en) * | 2015-05-06 | 2016-11-09 | Latvijas Universitate | Vehicles anhydrous care products |
| CN105368596A (en) * | 2015-12-11 | 2016-03-02 | 天津璞誉环保科技开发有限公司 | Vehicle cleaning agent with strong antirust capability |
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