The content of the invention
It is an object of the invention to disposable high-efficiency environment friendly carwash is provided to solve above the deficiencies in the prior art
Towel, high-efficiency environment friendly waterless carwash wet tissue and preparation method, vehicle cleaning towel can be with Wet-dry.Environmental protection is drawn without washing using vehicle cleaning towel
After car liquid, it is sealed in polybag, is directly used in carwash.A piece of vehicle cleaning towel, which can also be taken out, and directly drawn after car washing liquid makes
With without additionally using water.Carwash wet tissue is not nitrogenous, phosphorus, ammonia, benzene plasma or group, harmless, environment friendly and pollution-free.
Technical scheme is as follows:
Disposable high-efficiency environment friendly vehicle cleaning towel, the vehicle cleaning towel is made up of fiber, and it includes three-decker, wherein above and below be for two layers
Alveolate texture layer, intermediate layer is water accepting layer.
Further, the preparation method of described disposable high-efficiency environment friendly vehicle cleaning towel, comprises the following steps:
Step one, top fiber, intermediate layer fiber and lowermost fibre are mixed respectively;
Step 2, by mixed top fiber, intermediate layer fiber and lowermost fibre according to the suitable of upper strata, middle level and lower floor
Sequence is placed and combs lapping simultaneously;
Step 3, obtains the entirety that top fiber, intermediate layer fiber and lowermost fibre are laminated naturally, then after combing lapping
Carry out entering baking oven after the two-sided glue spraying in top and bottom, heating fuses low-melting fiber, and top layer drying adhesive is simultaneously shaped, cold after sizing
But and cut, obtain vehicle cleaning towel.
Further, the preparation method of described disposable high-efficiency environment friendly vehicle cleaning towel, step one fiber and lower floor at the middle and upper levels
The composition of fiber is Regenerated Polyester Staple Fiber and the mass ratio of the low-melting fiber of Saehan 4080 is 8:2;Intermediate layer is fine in step 2
The composition of dimension is that the mass ratio of bamboo fibre and the low-melting fiber of Saehan 4080 is 8:2.
Further, the preparation method of described disposable high-efficiency environment friendly vehicle cleaning towel, fiber, lower floor are fine at the middle and upper levels for vehicle cleaning towel
Dimension, the mass ratio of intermediate layer fiber are 1:1:2.
Disposable high-efficiency environment friendly waterless carwash wet tissue, including the above-described vehicle cleaning towel of car washing liquid has been infiltrated, wherein washing
Car liquid includes following components:Sodium Polyacrylate, surfactant, odium stearate, glycol distearate and deionized water;Its
Middle surfactant is in alkyl-polyoxyethylene ether acetate, plant polyenoid phenol polyethenoxy ether or ethoxylated dodecyl alcohol
Any two or three.
Further, described disposable high-efficiency environment friendly waterless carwash wet tissue, car washing liquid also include sodium carboxymethylcellulose,
Any one or a few in soy broth lecithin or Kathon CG.
Further, described disposable high-efficiency environment friendly waterless carwash wet tissue, car washing liquid include in parts by weight as
Lower component:
0.2-0.4 parts of Sodium Polyacrylate, 0.02-0.03 parts of glycol distearate, 0.1-0.5 parts of odium stearate, go
97.8-99.18 parts of ionized water and surfactant, wherein surfactant are selected from alkyl-polyoxyethylene ether acetate 0.3-0.6
Any two kinds or three in 0.3-0.6 parts of part, 0.2-0.5 parts of plant polyenoid phenol polyethenoxy ether or ethoxylated dodecyl alcohol
Kind.
Further, described disposable high-efficiency environment friendly waterless carwash wet tissue, car washing liquid is also included in parts by weight
In 0.1-0.2 parts of 0.3-0.5 parts of carboxymethyl cellulose sodium, 0.05-0.08 parts of soy broth lecithin or Kathon CG any one or
It is several.
The preparation method of car washing liquid, comprises the following steps in above-described disposable high-efficiency environment friendly waterless carwash wet tissue:
Step one, each component is weighed according to parts by weight;
Step 2, takes Sodium Polyacrylate to be added in 10-20 parts of deionized waters, stirs to being completely dissolved, adjusts at room temperature
System pH is 7.0-7.2, obtains mixed liquor one;
Step 3, surfactant is added in 5-10 parts of deionized waters, 70-80 DEG C is warming up to, adds ethylene glycol
Room temperature is down to after distearate, stirring and dissolving, and regulation system pH is 7.0-7.2, obtains mixed liquor two;
Step 4, mixed liquor two is added in mixed liquor one, then adds odium stearate and surplus water, regulation system pH
For 7.0-7.2, it is uniformly mixed, obtains disposable high-efficiency environment friendly waterless carwash towel.
Further, in described disposable high-efficiency environment friendly waterless carwash wet tissue car washing liquid preparation method, in step 2
Add the soybean added in 0.3-0.5 parts of sodium carboxymethylcellulose and/or step 3 in parts by weight in parts by weight
0.1-0.2 parts of Kathon CG in parts by weight is added in 0.05-0.08 parts of liquid lecithin and/or step 4;Regulation system pH
Conditioning agent used is acetic acid or citric acid.
Sodium Polyacrylate is to manufacture the ideal material of nontoxic, Pollution-free detergent as builder.Sodium Polyacrylate
It is a kind of new and effective environment friendly washing auxiliary agent, the tripolyphosphate and other aluminium generally used in current detergent can be replaced
Salt, so as to eliminate the pollution because of the waste water discharged using sodium tripolyphosphate and aluminium salt to environment.Helping for Sodium Polyacrylate is washed
Performance is far superior to traditional sodium tripolyphosphate, and clean result is only three equivalent to 5 times of sodium tripolyphosphates with weight, i.e. consumption
The 1/5 of polyphosphate sodium, it is possible to decrease the cost of detergent.Sodium Polyacrylate is as the mechanism of action of builder:Sodium Polyacrylate
There is chelation to metal ion, play alkaline buffer, there is good cohesion to soliquid, come from its surface
The neutralization characteristic of electric charge, i.e. it and positively charged suspended particles constitute quasi- ionic bond, at this moment due to electrostatic repulsion, polyacrylic acid
The carboxyl of sodium makes flexible polymer suitably stretch, and makes the absorption of suspended particles, condenses, and the crosslinking between particle is easily entered
OK.If there is Na around polymer+Ion and Ca2+In the presence of ion, then Ca2+Ion is easier to adsorb and fixed.With polymolecular
It is absorption surface charge reversal, with hydrophily increase, display Protection glue effect makes particle dispersion system stable.Polyacrylic acid
Sodium is a kind of efficient washing assisant, dirt is departed from car body surface and prevents that attachment is deposited dirt again to car body surface.
Sodium Polyacrylate emulsion dispersion stability is good and heat-resisting, and good mechanical stability can close trace metal ion, again
It is nontoxic.The lubricity and stability of car washing liquid can be improved.
Sodium carboxymethylcellulose:The stable homogeneous emulsion of forming properties.Because its is safe and reliable, therefore, its consumption not by
National food hygienic standard ADI is limited, and is recognized as safe food additives.Play a part of flocculation, chelating, emulsification,
Car washing liquid lubricity is added, car washing liquid is wiped and more facilitates, it is time saving and energy saving.
The present invention uses nonionic surface active agent completely:Alkyl-polyoxyethylene ether acetate, plant polyenoid phenol polyoxy
Vinethene, ethoxylated dodecyl alcohol, are compounded from two or more, can make carwash using the compatibility of above-mentioned surface-active
The surfactant concentration of liquid drops to 0.8-1.4%, reduces cost, reduces the surface tension of solution, adds wettability
And dirt-removing power.And solve excitant and sensitization of the ionic surfactant mainly to tissues such as skin, eyes, it is ensured that
Security and mildness in car washing liquid use, body of not hurting sb.'s feelings protect skin.Alkyl-polyoxyethylene ether acetate biological degradability
It is good, to skin action temperature and, the obstruction to enzyme is few, there is good stability in hard water and detergency.Ethoxylated dodecyl alcohol has
There are the functions such as excellent washing, emulsification, scattered, wetting, solubilising, and foaming power is strong, easily rinsing, detergency is excellent;It is that surface is lived
One of kind minimum to skin irritation in property agent.It can reduce their excitant, change with various surfactant compounds
The performance of kind product.Wherein, described plant polyenoid phenol polyethenoxy ether preferably uses biological by the resistance to element in Jiangsu Province, China Changshu
The production of material Science and Technology Ltd., and the plant in the model NSF 10E of market sale before the application proposition is more
Alkene phenol polyethenoxy ether, key component comes from natural plants, and biological degradability is very good.It is right with efficient washing performance
Animal and plant fat removal ability is strong, and good to machinery oil, mineral oil washability, water emulsification performance, foam is low, is lived with other surfaces
Property agent has good compatibility.
Ethylene glycol distearyl acid:The surfactant intermiscibility provided with the present invention is good, compound in above-mentioned surfactant
Heating is configured to pearlite slurry in thing, and can embody its stable pearl effect, and the pearly-lustre relatively fruit of generation is fine and smooth so that after cleaning
Car body lacquer painting optical effect more preferably., skin care non-stimulated to skin.Also there is antistatic property, prevent dust from sticking.
Odium stearate:Due to odium stearate good water solubility, relative to traditional silicone oil, palm wax, wiped more in use
It is convenient, it can be painted after use in car and quickly form protective film uniform and smooth, that light is durable, while odium stearate has moisturizing work
With.
Soy broth lecithin:There is good emulsibility, play protection skin effect.
Kathon CG:It is that generally acknowledged in the world safe efficient, broad spectrum activity chemical product limit the use of preservative, plays bactericidal effect,
Increase car washing liquid stability and the term of validity.
The disposable high-efficiency environment friendly waterless carwash wet tissue that the present invention is provided is in cleaning process, and vehicle cleaning towel top layer is using high-elastic
Hollow polyester fibre, a small amount of ultra-fine bamboo fibre, by the low-melting fiber molding bonded of Saehan 4080, forms alveolate texture, fiber
Between have larger hole, can be combined with car washing liquid preferably remove vehicle body bulky grain silt;Middle ultra-fine bamboo fibre water accepting layer is few
Hollow polyester fibre is measured, is laminated structure, has super-strong moisture absorbing performance, car washing liquid can be slowly discharged, extension is cleaned effective time, and
Adsorbable fine dust.Chelation and the alkali of offer that car washing liquid passes through metal ion in Sodium Polyacrylate and automobile dirt
Property buffer condition and cohesion so that automobile dirt is easier to be combined with the surfactant that the present invention is provided, and accelerates clearly
Efficiency is washed, while the dirt for making it difficult to cleaning is easier to be combined with the surfactant in the present invention, degree of cleaning is improved;
Odium stearate can coordinate stearic acid in car surface one layer of uniform diaphragm of formation, ethylene glycol distearyl acid in cleaning process
Sodium forms the brightness enhancement layer with pearly-lustre in diaphragm, car surface brightness is improved, while enhancing the stabilization of diaphragm
Property.The surfactant used in the present invention can play humidification to the upper photosensitiveness of ethylene glycol distearyl acid, further carry
Polishing effect is risen.Ethylene glycol distearyl acid is used in the present invention as glazing agent, in use can not only be with tristearin
Sour sodium, which is mutually cooperateed with, collectively forms diaphragm, and in use relative to the glazing such as conventional paraffin composition have be easy to
The advantage being easily dispersed is cleaned, conventional paraffin is easy to passivation, causes scouring to be difficult, to use larger power in use
Gas could uniformly wipe it in car surface formation glazing layer.Sodium carboxymethylcellulose and polyacrylic acid in car washing liquid of the present invention
Sodium cooperates, and enhances lubricity so that carwash process is more easily carried out.
The disposable high-efficiency environment friendly waterless carwash wet tissue that the present invention is provided, it is easy to use, directly used during carwash,
Water need not be added to be diluted, substantial amounts of water resource has been saved.
The vehicle cleaning towel and carwash wet tissue that the present invention is provided can directly be used during carwash, can use vehicle cleaning towel
Infiltration draws car washing liquid or directly uniformly wipes outer surface of automobile and automotive interior using carwash wet tissue, and outer surface of automobile includes
Vehicle glass, car body, wheel hub, automotive interior include seat, bridge, steering wheel, glass, in-car bottom plate, pad blanket.Again with hydrophilic
Property towel, spend artificial about one people 20 minutes, it is possible to complete the overall cleaning of one 53 railway carriage or compartment cars.Energy after use
Enough mixed dirts to automobile interior exterior surface carry out rapid cleaning, glazing, plated film and once completed, and noresidue vestige shows light
Clean car body, and vehicle body electrostatic is effectively removed, prevent dust from sticking.Automobile finish will not be damaged after carwash, will not produce simultaneously
Cut, any injury is not resulted in outer surface of automobile and inside.Environmentally friendly waterless carwash liquid is not nitrogenous, phosphorus, benzene, ammonia etc. harmful
Composition, pH value is neutral, tasteless non-stimulated, harmless, environmentally safe.Skin, skin care are protected during use.
The vehicle cleaning towel uses regenerated fiber, and Environment-friendlyglue glue is manufactured, and degradable, sealed plastic bag is degradable.It is environmentally safe.
Car washing liquid improves the mildness of car washing liquid using nonionic surfactant in the carwash wet tissue that the present invention is provided,
Significantly reduce excitant.The surface tension of solution is reduced, wettability is added.Usage amount is few simultaneously, and cost is low.
Ethylene glycol distearyl acid and non-ionic surface active are used cooperatively in car washing liquid in the carwash wet tissue that the present invention is provided,
Obvious pearl effect can be produced, protective film uniform and smooth, that light is durable can be quickly formed after use in surface of vehicle paint, make
With rear paint film without discoloration, foaming, obscission, no loss of gloss, no color differnece prevent lacquer painting from aoxidizing.Also there is antistatic property, can have
Effect removes vehicle body electrostatic, prevents dust from sticking.Automobile finish will not be damaged, cut will not be produced, to outer surface of automobile and inside
Any injury is not resulted in.
Car washing liquid stability is good in the carwash wet tissue that the present invention is provided, and the situation that storage at normal temperature does not expand with heat and contract with cold occurs.
The vehicle cleaning towel that the present invention is provided can be easy to use with dry and wet functions.
Embodiment 2-8
The vehicle cleaning towel that above example 1 is provided coordinates with car washing liquid, prepares disposable high-efficiency environment friendly waterless carwash
Wet tissue, the vehicle cleaning towel infiltration specially obtained using embodiment 1 is drawn car washing liquid and then smoothed out with the fingers to liquid to be obtained without dripping, wherein washing
The preparation of car liquid is carried out according to following:
The carwash formula of liquid composition of example 2 below-embodiment 8 is as follows:
1. formula composition
Raw material proportioning (mass ratio) configuration is by 1000 grams of calculating
The preparation method of the car washing liquid of above example 2- embodiments 8 is as follows:
Step one, each component is weighed according to parts by weight;
Step 2, takes Sodium Polyacrylate to be added in 10-20 parts of deionized waters, stirs to being completely dissolved, adjusts at room temperature
System pH is 7.0-7.2, obtains mixed liquor one;
Step 3, by alkyl-polyoxyethylene ether acetate, plant polyenoid phenol polyethenoxy ether and ethoxylated dodecyl alcohol
It is added in 5-10 parts of deionized waters, is warming up to 70-80 DEG C, room is down to after adding glycol distearate, stirring and dissolving
Temperature, and regulation system pH is 7.0-7.2, obtains mixed liquor two;
Step 4, mixed liquor two is added in mixed liquor one, then adds odium stearate and surplus water, regulation system pH
For 7.0-7.2, it is uniformly mixed, obtains disposable high-efficiency environment friendly waterless carwash towel.
In above example 2- embodiments 8, sodium carboxymethylcellulose, soy broth lecithin and Kathon CG are related in formula
, in specific preparation process, sodium carboxymethylcellulose is added in step 2, and soy broth lecithin is added in step 3,
Kathon CG is added in step 4.The conditioning agent that regulation system pH is used in method made above is acetic acid or citric acid.
The disposable high-efficiency environment friendly waterless carwash towel prepared for above example 2-8, through country processed food and
Food additives Quality Supervision and Inspection Center (Nanjing) Nanjing Quality Supervision and Examination Institute is detected, with reference to GB 9985-2000
《Manual dishwashing detergent》Standard, test result:Gross activity thing content > 16%, pH (25 DEG C, 1% solution) 7.0-7.2, first
Aldehyde is not detected, and detergency is all higher than standard dish washing detergent.
According to HJ636-2012, GB11893-89 standard testing, ammonia-nitrogen content HJ636-2012 standard detections are 0, and phosphorus contains
It is 0 to measure GB11893-89 standard detections.
Take acrylic acid paint film test plate (panel) to be put into car washing liquid, soak 2 days, test result is:Paint film bubbles, come off without discoloration
Phenomenon, no loss of gloss, no color differnece.
The product that the domestic applications invention of car washing liquid in the present invention and Application No. 2008101948364 is obtained is carried out
Performance comparison, it is specific as follows:
As can be seen from the above results, the car washing liquid in the disposable high-efficiency environment friendly waterless carwash towel that the present invention is provided is integrated
Performance is substantially better than the performance of above prior art, and wherein cleannes have reached 96%, is remained after cleaning without vestige, that is, shows light
Clean car body, feel clearly lubricates, odorless non-stimulated, safe and reliable using food-grade bactericide, to automobile finish, tire, glass
Glass, wheel hub and automotive interior device etc. are without any corrosion and damaging action, and environmental protection is environmentally safe.
Further investigation revealed that, the disposable high-efficiency environment friendly waterless carwash wet tissue that the present invention is provided is in cleaning process
In, vehicle cleaning towel top layer is due to using high-elastic hollow polyester fibre, and a small amount of ultra-fine bamboo fibre is bonded by the low-melting fiber of Saehan 4080
Shaping, being formed between alveolate texture, fiber has larger hole, can be combined with car washing liquid and preferably remove vehicle body bulky grain mud
It is husky;Middle ultra-fine bamboo fibre water accepting layer, a small amount of hollow polyester fibre is laminated structure, has super-strong moisture absorbing performance, can slowly discharge
Car washing liquid, extends effective scavenging period, while adsorbable fine dust, further lifts cleaning performance.Car washing liquid passes through poly- third
The chelation and the alkaline buffer condition and cohesion of offer of olefin(e) acid sodium and metal ion in automobile dirt so that automobile
Dirt is easier to be combined with the surfactant that the present invention is provided, and cleaning efficiency is accelerated, while making it difficult to the dirt of cleaning
Easily combined with the surfactant in the present invention, improve degree of cleaning;Odium stearate can be in automobile in cleaning process
Surface forms one layer of uniform diaphragm, and ethylene glycol distearyl acid coordinates odium stearate to form the increasing with pearly-lustre in diaphragm
Bright layers, improve car surface brightness, while enhancing the stability of diaphragm.The surfactant energy used in the present invention
Enough upper photosensitiveness to ethylene glycol distearyl acid play humidification, further improve polishing effect.Second two is used in the present invention
Alcohol distearyl acid can not only mutually cooperate with odium stearate collectively form diaphragm in use as glazing agent, and
And there is the advantage for being easy to clean and being easily dispersed relative to the glazing such as conventional paraffin composition in use, conventional paraffin exists
Passivation is easy to during use, causes scouring to be difficult, to use larger strength uniformly to wipe it in car surface shape
Into glazing layer.Sodium carboxymethylcellulose in car washing liquid of the present invention cooperates with Sodium Polyacrylate, enhances lubricity so that
Carwash process is more easily carried out.Vehicle cleaning towel efficiently completes carwash mistake jointly with car washing liquid coordinated during carwash
Journey.