CN104120052A - Concentrated pasty/ semisolid detergent composition containing fatty acid alkali metal salt and preparation method thereof - Google Patents
Concentrated pasty/ semisolid detergent composition containing fatty acid alkali metal salt and preparation method thereof Download PDFInfo
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- CN104120052A CN104120052A CN201410293530.XA CN201410293530A CN104120052A CN 104120052 A CN104120052 A CN 104120052A CN 201410293530 A CN201410293530 A CN 201410293530A CN 104120052 A CN104120052 A CN 104120052A
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Abstract
The invention discloses a concentrated pasty/ semisolid detergent composition containing a fatty acid alkali metal salt. The composition contains the following components in percentage by weight: 5-40% of fatty acid alkali metal salt, 1-30% of high boiling point organic solvent, 1-35% of surfactant, 0-25% of liquid alcohol, 0-5% of aid and 0-20% of hard water softening additive. The composition can provide multiple high-concentration active ingredients, and has excellent capability of removing dirt such as grease, protein, fruit juice, tea trace, coffee and ink. After the composition is applied at the heavy dirt, the heavy dirt is cleaned with a common detergent in a washing machine, so that the composition is not limited by retention time at the heavy dirt. Moreover, the composition can be stored in a paste hose, so that the composition can be conveniently carried and can be used for timely cleaning local dirt in water-lacking environments such as a journey and the way to work.
Description
Technical field
The present invention relates to a kind of detergent composition, especially relate to the ointment/semi-solid detergent composition that contains fatty acid alkali metal salt, the invention still further relates to the preparation method of this washing composition combination.
Background technology
Fatty acid alkali metal salt, if sodium stearate (being commonly called as soap) and sodium palmitate (being commonly called as soft soap) are that a class is with a long history, washing composition cheaply, well known and be widely used in fabric and clean.Along with the development of detergent industry, various tensio-active agents, clean as sodium alkyl benzene sulfonate (washing powder) and other liquid washing agents are also widely used in fabric, especially for washing machine.Soap and washing powder are as common scouring agent, and to the light dirt of clothing effectively, counterweight is dirty as dirts such as the fat at collar place or albumen, fruit juice, and tea mark, coffee, the effect of ink etc. is undesirable.People are finding more effective heavy-dirty liquid-detergent always, as various liquid sprays, wherein mostly contain liquid surfactant, or the water soluble surfactant active of dilute with water.This class I liquid I spray exists and is difficult to provide high density activated detergent problem, compatible problem between different surfaces promoting agent, to meet the problem of the viscosity of product and the needs of stability, make it to be difficult to freely to add the not bery compatible effective constituent of certain density various and water or a certain tensio-active agent, thereby limited the ability of its duplicate removal dirt.
Heavy-filth liquid spray is usually used in clothing Local Gravity And dirt place, as collar etc.And then put the common scouring agent of use in washing machine into and wash.For the clean effect having reached, need treat that liquid spray is fully penetrated into fabric fibre inside, and stop certain hour, and then put the common scouring agent of use in washing machine into and clean.As spraying heavy-filth liquid spray after just putting long afterwards laundry machine washing into, heavy-filth liquid spray can become dry, and can lose part activity, does not reach expected effect.This type of heavy-filth liquid spray need stop certain hour at heavy dirt place and also daily laundry be made troubles.
Summary of the invention
The object of the present invention is to provide a kind of ointment/semi-solid detergent composition that contains fatty acid alkali metal salt, it can provide the multiple effective active composition of high density, has the soil removal capabilities such as superior greasy and albumen, fruit juice, tea mark, coffee and ink.
First object of the present invention is to be achieved through the following technical solutions: the ointment/semi-solid detergent composition that contains fatty acid alkali metal salt, and the component that comprises following weight percent:
Fatty acid alkali metal salt 5-40%, high boiling organic solvent 1-30%, tensio-active agent 1-35%, liquid alcohols 0-25%, auxiliary agent 0-5%, softening of water additive 0 ~ 20%.
Main active ingredient of the present invention is fatty acid alkali metal salt, and wherein lipid acid is advisable with saturated fatty acid.Lipid acid acid alkali metal salt is a kind of anion surfactant, is widely used in washing, and cost is low, and energy is any and negatively charged ion, nonionic and superpolymer cats product are composite.Saturated fatty acid is advisable with C16-18 saturated fatty acid again.Wherein basic metal can be sodium or potassium, and sodium is advisable.The soap of the C16-18 saturated fatty acid sodium that contains 5-40% of take in the present invention is raw material, as soap flakes, and translucent soap, or common opaque soap (main component is sodium stearate) is advisable.These higher unsaturated fatty acid soda soaps start to soften at about 45 ℃ ~ 50 ℃.Fatty acid content is higher, more softening.Common opaque soap is generally higher than the fatty acid content of translucent soap and soap flakes, more softening.These higher unsaturated fatty acid soda soaps are suitable as the matrix of paste composition of the present invention.By the adjusting to these higher unsaturated fatty acid soda soap content, can and flow to the soft or hard of composition and in very large range regulate, reach required soft or hard degree.In the making processes of the present composition, the saturated fatty acid soda soap adding is advisable with soap powder or broken soap flakes form.
Organic solvent of the present invention requires low the irritating property of high boiling point, with propylene glycol or its acetic ester, is advisable.Propylene glycol or its acetic ester be to ink, pigment, and greasy dirt, color spots etc. have good solubility.Because general tensio-active agent is to ink, pigment, the cleansing power of greasy dirt etc. is limited, adds propylene glycol or its acetic ester can greatly improve composition degreasing, heavy dirty ability.Described propylene glycol and acetic ester thereof comprise propandiol butyl ether, dipropylene glycol butyl ether, and dipropylene glycol methyl ether acetate, tripropylene glycol methyl ether, propylene glycol monomethyl ether, 1-Methoxy-2-propyl acetate, dipropylene glycol methyl ether, as the DOWANOL series solvent of Dow Chemical Company's production.The physico-chemical property of these propylene glycols and acetic ester thereof is as shown in table 1.In the present invention, with the propylene glycol that contains 1-30% or wherein one or more mixtures of propylene-glycol ether acetate, be advisable.Conventional propylene glycol shown in table 1 and the boiling point of acetic ester thereof, all substantially exceed the boiling point of water, and have high flash point, and the feature of high spontaneous ignition temperature, and low irritating property and hypotoxic characteristic, can be used safely in to produce articles for washing.
Tensio-active agent described in the present invention can be cationic surfactant, aniorfic surfactant, amphoterics or nonionic surface active agent, or the mixture of these tensio-active agents.In a preferred embodiment, tensio-active agent is advisable with aniorfic surfactant or nonionic surface active agent or their mixture.Wherein, described nonionic surface active agent is fatty alcohol-polyoxyethylene ether (AEO-3, AEO-4, AEO-5, AEO-7, AEO-9), or 13 carbon isomery alcohol ether TO series or lauryl alcohol phosphoric acid ester.Described aniorfic surfactant is one or more mixtures in alcohol sulfate (AS), sulfuric acid ether (ES), polyoxyethylenated alcohol sodium sulfate (AES), Oleum Cocois diethanolamine of fat acyl, fatty acid methyl ester ethoxylate sulfonated salts, lauryl alcohol phosphoric acid ester, lauryl alcohol phosphoric acid ester potassium and lauryl sulfosuccinate monoesters disodium.Add different tensio-active agents can help being uniformly distributed of the organic solvents such as propylene glycol or its acetic ester and other compositions, make effective constituent more easily disperse, soak, be penetrated in long-pending fibres, the various soil removabilitys of enhancing composition, also can play soft and anlistatig effect to long-pending fibres.
Described tensio-active agent is non-ionic type, anionic, the mixture of cationic and amphoterics.Aniorfic surfactant and nonionic surface active agent as mentioned above, generally account for the most of of mixture and play main cleaning function.And cationic surfactant plays sterilization, antistatic and as softening agent.Conventional cationic surfactant has fatty amine salt, ethanolamine salt, polyethylene polyamines salt etc.As add a small amount of quaternary cationics can play germicidal action; Add a small amount of diethanolamine (rope Luo Ming A) to play softening agent effect etc. to fabric.Amphoterics shows with non-ionic type similar under neutral environment; Under sour environment, performance is with cationic similar; And performance is similar with anionic under alkaline environment.Conventional amphoterics has amine oxide type and betaine type.This type of amphoterics is usually used in personal-care supplies, replaces part or all of nonionic surface active agent or the aniorfic surfactant except lipid acid acid alkali metal salt in the present invention, makes high-grade washing composition.Advantage of the present invention, is by regulating the viscosity of (raisings) detergent composition, make the different surfaces promoting agent of not blend of script or blend after unsettled different surfaces promoting agent can in composition, stablize and coexist.
Add in the present invention appropriate water can improve the mutual solubility of tensio-active agent and organic solvent.Add water to be improved organic solvent flash-point simultaneously, and reduce the effect of its vapour pressure.
In the present invention, described liquid alcohols is one or more the mixture in ethanol, Virahol and propylene glycol.Appropriate liquid alcohols can increase the mutual solubility of tensio-active agent and organic solvent, also can be used to regulate the mobility of composition.Also washing effect that can enhancing composition.
Due to the large multiplex cold wash clothing in China various places, add in the present invention the washing effect that softening of water additive can enhancing composition.Softening of water additive can be a kind of or both mixtures in Trisodium Citrate and sodium carbonate.
In the present composition, described auxiliary agent is one or more the mixing in sequestrant, tinting material, dyestuff, spices, bactericide, mycocide, sanitas, pH adjusting agent, pH buffer reagent and opalizer.Add the shelf lives that above-mentioned auxiliary agent can improve composition, smell, color and luster and outward appearance etc.
Second object of the present invention is by the following technical programs: the above-mentioned ointment/semi-solid detergent composition that contains fatty acid alkali metal salt, get in proportion fragment, organic solvent, tensio-active agent, liquid alcohols and the auxiliary agent of saturated fatty acid soda soap, organic solvent and liquid alcohols mix, add water and mix post-heating to 70-90 degree Celsius, then the fragment and the auxiliary agent that add tensio-active agent, saturated fatty acid soda soap, mix, be cooled to below 60 degrees Celsius, add softening of water additive to mix.
Or, first by the fragment thermoplastic of saturated fatty acid soda soap, then add in proportion organic solvent, tensio-active agent, liquid alcohols, auxiliary agent and water, be uniformly mixed, be cooled to after room temperature, add softening of water additive to mix.
Described Heating temperature is generally at 70-90 degree Celsius.Mixed process needs to stir, and large capacity is made and can in the stirring tank with heating jacket, be carried out.
the present invention compares in prior art, has advantages of following:
Paste of the present invention or half is consolidated the multiple effective active composition that shape detergent composition provides high density, has superior greasy and albumen, fruit juice, tea mark, coffee, the soil removal capabilities such as ink.Behind heavy dirt place, then put the common scouring agent of use in washing machine into and clean, be not subject to limit in heavy dirt place's residence time.And it can be stored in Paste hose, be easy to carry, can be under the environment of few water, as journey, the occasions such as working, remove local dirt in time.General using method of the present invention: this paste or half is consolidated to shape composition and be applied to heavy dirt or ink, pigment, greasy dirt, color spots etc. are located, and then put washing machine into, roughly the same common cleaning.Also can counterweight dirt place with paste of the present invention or half, consolidate shape composition and carry out pre-washing, as with scrubbing etc.
Embodiment
In following embodiment, ointment or half weight of consolidating shape detergent composition are from being approximately 100 grams-2500 grams.Gross weight is on the not impact of the per-cent of each component.First essential activeconstituents of the present composition is fatty acid alkali metal salt, and wherein lipid acid is advisable with saturated fatty acid.Fatty acid alkali metal salt is a kind of anion surfactant, is widely used in washing composition, and cost is low, and energy is any and negatively charged ion, nonionic and superpolymer cats product are composite.Saturated fatty acid is advisable with C16-18 saturated fatty acid again.Wherein basic metal can be sodium or potassium, with sodium, is advisable.The soap of the C16-18 saturated fatty acid sodium that contains 5-40% of take in the present invention is raw material, as soap flakes, and translucent soap, or common opaque soap (main component is sodium stearate) is advisable.These higher unsaturated fatty acid soda soaps start to soften at about 45 ℃ ~ 50 ℃.Fatty acid content is higher, more softening.Common opaque soap is generally higher than the fatty acid content of translucent soap and soap flakes, more softening.These higher unsaturated fatty acid soda soaps are suitable as the matrix of paste composition of the present invention.By the adjusting to these higher unsaturated fatty acid soda soap content, can and flow to the soft or hard of composition and in very large range regulate, reach required soft or hard degree.In the making processes of the present composition, saturated fatty acid soda soap is incorporated as suitable with soap powder or broken soap flakes form, but calculates by sodium stearate quantity.
In following examples, also can add 0 ~ 5% auxiliary agent, auxiliary agent is one or more the mixing in sequestrant, tinting material, dyestuff, spices, bactericide, mycocide, sanitas, pH adjusting agent, pH buffer reagent and opalizer, to improve the shelf lives of composition, smell, color and luster and outward appearance etc.
embodiment 1:
The propandiol butyl ether (PnB), 1% distilled water and 22% the propylene glycol that in container, add 20% (weight), mix, then mixture is heated with stirring to 80 degrees Celsius, surfactant A EO-9 and 5% (weight) sodium stearate that adds 33% (weight), stir the mixture until component is uniformly distributed, cooling mixture is to room temperature.Mixture is high viscosity paste.Stearic acid sodium wherein adds with the soap flakes form containing sodium stearate, but calculates by sodium stearate quantity.
embodiment 2:
The dipropylene glycol butyl ether (DPnB), 5% distilled water and 5% the propylene glycol that in container, add 30% (weight), mix, then mixture is heated with stirring to 85 degrees Celsius, surfactant A EO-9 and 40% (weight) sodium stearate that adds 20% (weight), stir the mixture until component is uniformly distributed, cooling mixture is to room temperature.Mixture is than the high paste of embodiment 1 viscosity.Stearic acid sodium wherein adds with the soap flakes form containing sodium stearate, but calculates by sodium stearate quantity.
embodiment 3:
The tripropylene glycol methyl ether (TPM), 35% distilled water and 15% the propylene glycol that in container, add about 15% (weight), mix, then mixture is heated with stirring to 90 degrees Celsius, surfactant A EO-9 and 20% (weight) sodium stearate that adds 15% (weight), stir the mixture until component is uniformly distributed, cooling mixture is to room temperature.Mixture is than the low paste of embodiment 1 viscosity.Stearic acid sodium wherein adds with the soap flakes form containing sodium stearate, but calculates by sodium stearate quantity.
embodiment 4:
The dipropylene glycol butyl ether (DPnB), 5% distilled water and 15% the propylene glycol that in container, add 30% (weight), mix, then mixture is heated with stirring to 80 degrees Celsius, tensio-active agent polyoxyethylenated alcohol sodium sulfate (AES) and 20% (weight) sodium stearate of adding the surfactant A EO-9,20% (weight) of 10% (weight), stir the mixture until component is uniformly distributed, cooling mixture is to room temperature.Mixture is lower than embodiment 1 viscosity, than the high paste of embodiment 3 viscosity.Stearic acid sodium wherein adds with the soap flakes form containing sodium stearate, but calculates by sodium stearate quantity.
embodiment 5:
The propandiol butyl ether (PnB), 5% distilled water and 15% the propylene glycol that in container, add 15% (weight), mix, then mixture is heated with stirring to 85 degrees Celsius, surfactant A EO-3 and 20% (weight) sodium stearate that adds 35% (weight), stir the mixture until component is uniformly distributed, cooling mixture to 60 degree Celsius, the sodium carbonate that adds 15% (weight), stir the mixture until component after being uniformly distributed rapidly cooling mixture to room temperature.Mixture is than the high paste of embodiment 1 viscosity.Stearic acid sodium wherein adds with the soap flakes form containing sodium stearate, but calculates by sodium stearate quantity.
embodiment 6:
The propandiol butyl ether (PnB), 45% distilled water and 25% the propylene glycol that in device, add 5% (weight), mix, then mixture is heated with stirring to 85 degrees Celsius, surfactant A EO-3 and 10% (weight) sodium stearate that adds 10% (weight), stir the mixture until component is uniformly distributed, stir the mixture until component is even, be cooled to room temperature, the Trisodium Citrate that adds 5% (weight), mixture is the thick liquid lower than other embodiment viscosity.Stearic acid sodium wherein adds with the soap flakes form containing sodium stearate, but calculates by sodium stearate quantity.
washing test:
test 1:
On two calicos that scribble ball pen ink, spray respectively/coat the paste mixture of the common collar sanitising agent in a market and the embodiment of the present invention 1.Then respectively add a small amount of water, with hairbrush is light, brush 10 times, then rinse with clear water.Be sprayed with on the calico of the common collar sanitising agent in market, ink traces is still known clearly visible.With the calico of the embodiment of the present invention 1, there is no visible ink traces.
test 2:
On two calicos that scribble ball pen ink and fruit juice, spray respectively/coat the paste mixture of the common collar sanitising agent in a market and the embodiment of the present invention 6.Then put these two calicos into washing machine, by normal cycles of washing, wash 15 minutes.Be sprayed with on the calico of the common collar sanitising agent in market, ink and fruit juice are just slightly thin out.With the calico of the invention process 6, substantially lose ink and fruit juice vestige.
test 3:
On two calicos that scribble ball pen ink, in the time, be 0 respectively, and after 6 hours, coat the paste mixture of the embodiment of the present invention 5.Then put these two calicos into washing machine, by normal cycles of washing, wash 10 minutes two calicos and substantially lose ink traces, there is no obvious difference.The paste mixture of the embodiment of the present invention 6, is not subject to the impact in the dirt place residence time substantially.
Embodiments of the present invention are not limited to this; according to foregoing of the present invention; according to ordinary skill knowledge and the customary means of this area; do not departing under the above-mentioned basic fundamental thought of the present invention prerequisite; can also make modification, replacement or the change of other various ways, within all dropping on rights protection scope of the present invention.
Claims (9)
1. ointment/semi-solid the detergent composition that contains fatty acid alkali metal salt, is characterized in that the component that comprises following weight percent:
Fatty acid alkali metal salt 5-40%, high boiling organic solvent 1-30%, tensio-active agent 1-35%, liquid alcohols 0-25%, auxiliary agent 0-5%, softening of water additive 0 ~ 20%.
2. ointment/semi-solid the detergent composition that contains fatty acid alkali metal salt according to claim 1, is characterized in that, described lipid acid acid alkali metal salt is C16-18 saturated fatty acid alkali metal salt.
3. ointment/semi-solid the detergent composition that contains fatty acid alkali metal salt according to claim 1, is characterized in that, described 16-18 saturated fatty acid alkali metal salt is C16-18 saturated fatty acid sodium or C16-18 saturated fatty acid potassium.
4. ointment/semi-solid the detergent composition that contains fatty acid alkali metal salt according to claim 3, is characterized in that, described C16-18 saturated fatty acid alkali metal salt is added in composition with soap powder or broken soap flakes form.
5. ointment/semi-solid the detergent composition that contains fatty acid alkali metal salt according to claim 1, is characterized in that, described organic solvent is wherein one or more mixtures of propylene glycol or its acetic ester; Described liquid alcohols is one or more the mixture in ethanol, Virahol and propylene glycol; Described tensio-active agent is cationic surfactant, aniorfic surfactant, amphoterics or nonionic surface active agent, or the mixture of these tensio-active agents.
6. ointment/semi-solid the detergent composition that contains fatty acid alkali metal salt according to claim 5, it is characterized in that, described propylene glycol is propandiol butyl ether, dipropylene glycol butyl ether, tripropylene glycol methyl ether, propylene glycol monomethyl ether or dipropylene glycol methyl ether; Described propylene-glycol ether acetate is dipropylene glycol methyl ether acetate or 1-Methoxy-2-propyl acetate; Described nonionic surface active agent is fatty alcohol-polyoxyethylene ether or 13 carbon isomery alcohol ether TO series or lauryl alcohol phosphoric acid ester; Described aniorfic surfactant is one or more mixtures in alcohol sulfate, sulfuric acid ether, polyoxyethylenated alcohol sodium sulfate, Oleum Cocois diethanolamine of fat acyl, fatty acid methyl ester ethoxylate sulfonated salts, lauryl alcohol phosphoric acid ester, lauryl alcohol phosphoric acid ester potassium and lauryl sulfosuccinate monoesters disodium; It is amine oxide type or betaine type that described cationic surfactant has amphoterics described in fatty amine salt, ethanolamine salt or polyethylene polyamines salt; Described auxiliary agent is one or more the mixing in sequestrant, tinting material, dyestuff, spices, bactericide, mycocide, sanitas, pH adjusting agent, pH buffer reagent and opalizer.
7. ointment/semi-solid the detergent composition that contains fatty acid alkali metal salt according to claim 1, is characterized in that, described softening of water additive is a kind of or both mixtures in Trisodium Citrate and sodium carbonate.
8. ointment/semi-solid the detergent composition that contains fatty acid alkali metal salt according to claim 1, is characterized in that, also comprises water.
9. the preparation method of the ointment/semi-solid detergent composition that contains fatty acid alkali metal salt described in claim 1 to 8 any one, it is characterized in that, get in proportion fragment, organic solvent, tensio-active agent, liquid alcohols and the auxiliary agent of saturated fatty acid soda soap, organic solvent and liquid alcohols mix, add water and mix post-heating to 70-90 degree Celsius, then the fragment and the auxiliary agent that add tensio-active agent, saturated fatty acid soda soap, mix, be cooled to below 60 degrees Celsius, add softening of water additive to mix; Or, first by the fragment thermoplastic of saturated fatty acid soda soap, then add in proportion organic solvent, tensio-active agent, alcohols, auxiliary agent and water, be uniformly mixed.
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| CN201410293530.XA CN104120052A (en) | 2014-06-27 | 2014-06-27 | Concentrated pasty/ semisolid detergent composition containing fatty acid alkali metal salt and preparation method thereof |
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Cited By (2)
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| CN109957479A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | One kind being suitable for fire-entry suit high grease soil detergent and preparation method thereof |
| WO2023178580A1 (en) * | 2022-03-24 | 2023-09-28 | Ecolab Usa Inc. | Laundry emulsifier with surfactant and solvent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109957479A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | One kind being suitable for fire-entry suit high grease soil detergent and preparation method thereof |
| WO2023178580A1 (en) * | 2022-03-24 | 2023-09-28 | Ecolab Usa Inc. | Laundry emulsifier with surfactant and solvent |
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Effective date of registration: 20160713 Address after: 515500 west side of 206 National Road, Jiedong Economic Development Zone, Jieyang, Guangdong Applicant after: Guangdong Pangkam Industrial Co., Ltd. Address before: 515500 west side of 206 National Road, Jiedong Economic Development Zone, Jieyang, Guangdong Applicant before: Guangdong Pangkam Industrial Co., Ltd. Applicant before: Wei Huailiang |
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Application publication date: 20141029 |