CN104862112A - Clothes oil removal agent and preparation method thereof - Google Patents
Clothes oil removal agent and preparation method thereof Download PDFInfo
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- CN104862112A CN104862112A CN201510227738.6A CN201510227738A CN104862112A CN 104862112 A CN104862112 A CN 104862112A CN 201510227738 A CN201510227738 A CN 201510227738A CN 104862112 A CN104862112 A CN 104862112A
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Abstract
The invention belongs to daily chemical products, and relates to a clothes oil removal agent. The clothes oil removal agent comprises hydroxymethyl butyl ether acetate, butyl acetate, octylphenol polyoxyethylene ether, dodecanol amide, oleic acid, dimethicone, alkyl sulfonate, sodium silicate, sodium perborate, 2-5 parts of essence, brightening agents, detergent and composite surfactants. A formula of the clothes oil removal agent is unique, lubricating grease, carbon agents and mildew stains on the surfaces of various materials can be easily removed, use is safe, the detergency is high, the technology is simple, the economic effect is remarkable, other stains besides oil stains can be removed, clothes have good luster and the good hand feeling after the clothes are washed, and fluff of woolen fabric cannot contract.
Description
Technical field
The invention belongs to daily-use chemical industry series products, relate to a kind of clothes degreasing agent and preparation method thereof.
Background technology
People often can be stained with oil stain at daily clothes of having a meal, and the clothes being stained with oil stain is difficult to cleaning, and people usually select to send drycleaner's to clean, and dry cleaning price is more expensive and bother.Some dry-cleaning class organic agents are not suitable for using in the family; And the washing composition that market is sold is various in style, but some contains a large amount of organic solvents, has serious infringement or corrosive nature to human body, can cause a large amount of pollutions, be exclusively used in also not having of family type washing clothes animal and plant oils spot to environment.
Chinese invention patent, application number 200910247922.1 discloses " a kind of Novel clothing deoiling agent ", the clothes degreasing agent formula that this degreaser is made up of sodium hydroxide, Sodium Benzoate, salt, fatty acid ethylene oxide affixture permeate agent, polyoxyethylene nonylphenol ether and polyoxyethylene nonylphenol ether sulfonate surfactants.
Chinese invention patent, application number 200910112365.2, name is called the application of " a kind of fabric one-bath deoiling agent ", disclose the degreaser formula be made up of aliphatic amine polyoxyethylene ether, alkylsulfonate, vitriol and phosphate ester salt tensio-active agent, can be used for the fabrics such as terylene, polyamide fibre, cotton and carry out the process of oil removing one-pass bath method for dyeing., there is the problems such as range of application is little, deoiling effect is poor, biological degradability is poor in the degreaser of current use, silicone oil residual on fabric easily forms color dot in dyeing course, and degreaser is easily caused environmental pollution by sludge absorption in sewage disposal mostly.
Clothes degreasing agent ubiquity oil removing is in the market slow, oil removing not thoroughly, effect is single, and Fabric Physical index after oil removing is good not, and biological degradability is poor, degreaser not easily washes removing, cause clothing variable color, gloss and the feel of the rear clothing of washing are deteriorated, woolen fulling milling.
Summary of the invention
(1) technical problem solved
For the deficiencies in the prior art, the invention provides a kind of clothes degreasing agent and preparation method thereof, formula for a product of the present invention is unique, the various grease of clothing surface, carbon agent, mildew etc. can be removed easily, use safety, soil removability are strong, technique is simple, economy, Be very effective, energy other spots except degreasing, have good gloss and feel after washing, wool fabric is fulling milling not.
(2) technical scheme
Technical problem to be solved by this invention can be achieved through the following technical solutions:
A kind of clothes degreasing agent, the raw material weight number of described degreaser is: methylol monobutyl ether acetate 20-30 part, butylacetate 20-30 part, polyoxyethylene octylphenol ether 20-30 part, lauryl alcohol acid amides 10-15 part, oleic acid 10-15 part, dimethyl silicone oil 5-10 part, alkylsulfonate 10-15 part, sodium silicate 10-15 part, excessively friend's acid sodium 15-20 part, essence 2-5 part, whitening agent 5-8 part, stain remover 5-8 part, complexed surfactant 10-15 part.
A kind of clothes degreasing agent, described complexed surfactant is polyoxyethylene nonylphenol ether HA-10055-60%, polyoxyethylene nonylphenol ether sulfonic acid ES-2040-45%, and both directly mix.
A kind of preparation method of clothes degreasing agent, comprise the following steps: by methylol monobutyl ether acetate, butylacetate, polyoxyethylene octylphenol ether, lauryl alcohol acid amides starting material weigh, join in reactor, 20-30 minute is stirred after mixing, evenly to be mixed, be warming up to 80-100 DEG C, add oleic acid while stirring, dimethyl silicone oil, alkylsulfonate, sodium silicate and excessively friend's acid sodium, when temperature drops to 35-50 DEG C, add stain remover, reheat to 100-110 DEG C, essence is added when temperature drops to 50-60 DEG C, whitening agent and complexed surfactant, 10-20 minute is stirred under the condition of 50-60 DEG C of insulation, to be delivered in mulser after emulsification again, obtain degreaser product of the present invention.
Preferably, a kind of clothes degreasing agent, is characterized in that described alkylsulfonate is one or both in alkylbenzene sulfonate, secondary paraffin sulfonate and alkene sulfonate.
Preferred a kind of clothes degreasing agent, is characterized in that described alkylsulfonate selects alpha-olefin sodium sulfonate or Sodium dodecylbenzene sulfonate.
(3) beneficial effect
The invention provides a kind of clothes degreasing agent and preparation method thereof, the present invention has following beneficial effect: (1) easily forms emulsion in water, and can stablize at various concentrations; (2) easily wash removing, the Fabric Physical index of oil removing rapidly, thoroughly, after oil removing is excellent, and biological degradability is strong, can not cause environmental pollution, belong to environment-friendly type clothes degreasing agent; (3) do not make clothing variable color smelly, after washing, clothing has good gloss and feel, and wool fabric is fulling milling not; (4) applied range, deoiling effect are obvious.
Embodiment
For making the object of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1:
In the present embodiment clothes degreasing agent raw material and be constructed as follows: methylol monobutyl ether acetate 20 parts, butylacetate 20 parts, polyoxyethylene octylphenol ether 25 parts, lauryl alcohol acid amides 12 parts, oleic acid 10 parts, dimethyl silicone oil 8 parts, alkylsulfonate 12 parts, sodium silicate 12 parts, cross friend acid 15 parts, sodium, 3 parts, essence, 6 parts, whitening agent, stain remover 5 parts, complexed surfactant 10 parts.
Preparation method: by methylol monobutyl ether acetate, butylacetate, polyoxyethylene octylphenol ether, lauryl alcohol acid amides weighs according to the present embodiment raw material weight number, join in reactor, 20-30 minute is stirred after mixing, evenly to be mixed, be warming up to 80-100 DEG C, add the oleic acid of weight part while stirring, dimethyl silicone oil, alkylsulfonate, sodium silicate and excessively friend's acid sodium, when temperature drops to 35-50 DEG C, add stain remover, reheat to 100-110 DEG C, essence is added when temperature drops to 50-60 DEG C, whitening agent and complexed surfactant, 10-20 minute is stirred under the condition of 50-60 DEG C of insulation, to be delivered in mulser after emulsification again, obtain degreaser product of the present invention.
Embodiment 2:
In the present embodiment clothes degreasing agent raw material and be constructed as follows: methylol monobutyl ether acetate 25 parts, butylacetate 20 parts, polyoxyethylene octylphenol ether 25 parts, lauryl alcohol acid amides 15 parts, oleic acid 12 parts, dimethyl silicone oil 8 parts, alkylsulfonate 15 parts, sodium silicate 13 parts, cross friend acid 18 parts, sodium, 3 parts, essence, 7 parts, whitening agent, stain remover 8 parts, complexed surfactant 15 parts.
By the present embodiment weight part, preparation method is with embodiment 1.
Embodiment 3:
In the present embodiment clothes degreasing agent raw material and be constructed as follows: methylol monobutyl ether acetate 30 parts, butylacetate 30 parts, polyoxyethylene octylphenol ether 25 parts, lauryl alcohol acid amides 15 parts, oleic acid 12 parts, dimethyl silicone oil 10 parts, alkylsulfonate 15 parts, sodium silicate 15 parts, cross friend acid 15 parts, sodium, 5 parts, essence, 8 parts, whitening agent, stain remover 8 parts, complexed surfactant 15 parts.
By the present embodiment weight part, preparation method is with embodiment 1.
Embodiment 4:
By clothes degreasing agent obtained for embodiment 1 to embodiment 3, carry out the clean experiment of soiled cotton.
Soiled cotton prepares: draw the machine oil of equivalent weight 30ml, salad oil, vegetables oil and animal oil with syringe, be applied in calico surface respectively, and with the oven dry of 80 DEG C, baking oven, for subsequent use.
Test: constant 40 DEG C of water temperature, standard washing of washing machine is washed, per minute 30 turns, positive and negative each 15 turns, and bath raio is according to 1: 20, and wash 5 minutes, fast dewatering is also dried, and experimental result is as shown in table 1.
Deoiling effect, pass judgment on cloth cover greasy residues amount:
1 grade: cloth cover greasy dirt is not removed completely;
2 grades: cloth cover greasy dirt is removed on a small quantity;
3 grades: cloth cover greasy dirt half amount is removed;
4 grades: cloth cover greasy dirt great majority are removed;
5 grades: cloth cover greasy dirt is removed substantially.
Experimental result is as shown in the table
By above contrast, degreaser of the present invention has excellent performance, all has cleaning effect to various grease contamination, applied widely.
It should be noted that, in this article, such as term " comprises ", " comprising " or its any other variant are intended to contain comprising of nonexcludability, thus make to comprise the process of a series of key element, method, article or equipment and not only comprise those key elements, but also comprise other key elements clearly do not listed, or also comprise by the intrinsic key element of this process, method, article or equipment.When not more restrictions, the key element limited by statement " comprising ... ", and be not precluded within process, method, article or the equipment comprising described key element and also there is other identical element.
Above embodiment only in order to technical scheme of the present invention to be described, is not intended to limit; Although with reference to previous embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that: it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. a clothes degreasing agent, is characterized in that: the raw material weight number of described degreaser is: methylol monobutyl ether acetate 20-30 part, butylacetate 20-30 part, polyoxyethylene octylphenol ether 20-30 part, lauryl alcohol acid amides 10-15 part, oleic acid 10-15 part, dimethyl silicone oil 5-10 part, alkylsulfonate 10-15 part, sodium silicate 10-15 part, excessively friend's acid sodium 15-20 part, essence 2-5 part, whitening agent 5-8 part, stain remover 5-8 part, complexed surfactant 10-15 part.
2. clothes degreasing agent according to claim 1, is characterized in that, described complexed surfactant is polyoxyethylene nonylphenol ether HA-100 55-60, polyoxyethylene nonylphenol ether sulfonic acid ES-20 40-45, and both directly mix.
3. clothes degreasing agent according to claim 2, is characterized in that, in described complexed surfactant, the per-cent of two kinds of components is: polyoxyethylene nonylphenol ether HA-100 is 55-60%, and polyoxyethylene nonylphenol ether sulfonic acid ES-20 is 40-45%.
4. as the clothes degreasing agent of claim 1-3 as described in one of them, it is characterized in that, described alkylsulfonate is one or both in alkylbenzene sulfonate, secondary paraffin sulfonate and alkene sulfonate.
5. clothes degreasing agent according to claim 4, is characterized in that, described alkylsulfonate selects alpha-olefin sodium sulfonate or Sodium dodecylbenzene sulfonate.
6. the preparation method as the clothes degreasing agent of claim 1-5 as described in one of them, it is characterized in that, comprise the following steps: by methylol monobutyl ether acetate, butylacetate, polyoxyethylene octylphenol ether, lauryl alcohol acid amides starting material weigh, join in reactor, 20-30 minute is stirred after mixing, evenly to be mixed, be warming up to 80-100 DEG C, add oleic acid while stirring, dimethyl silicone oil, alkylsulfonate, sodium silicate and excessively friend's acid sodium, when temperature drops to 35-50 DEG C, add stain remover, reheat to 100-110 DEG C, essence is added when temperature drops to 50-60 DEG C, whitening agent and complexed surfactant, 10-20 minute is stirred under the condition of 50-60 DEG C of insulation, to be delivered in mulser after emulsification again, obtain degreaser product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510227738.6A CN104862112A (en) | 2015-05-06 | 2015-05-06 | Clothes oil removal agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510227738.6A CN104862112A (en) | 2015-05-06 | 2015-05-06 | Clothes oil removal agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104862112A true CN104862112A (en) | 2015-08-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510227738.6A Withdrawn CN104862112A (en) | 2015-05-06 | 2015-05-06 | Clothes oil removal agent and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106350275A (en) * | 2016-08-26 | 2017-01-25 | 曹平 | Laundry brightening agent |
| CN113403151A (en) * | 2021-06-17 | 2021-09-17 | 浙江新益印染有限公司 | Method for removing colloid on dyed cloth surface of cotton fabric |
| CN115161133A (en) * | 2022-08-02 | 2022-10-11 | 晋江市盛星新材料科技有限公司 | Whitening and degreasing agent for cotton fabric and preparation method and use method thereof |
-
2015
- 2015-05-06 CN CN201510227738.6A patent/CN104862112A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106350275A (en) * | 2016-08-26 | 2017-01-25 | 曹平 | Laundry brightening agent |
| CN113403151A (en) * | 2021-06-17 | 2021-09-17 | 浙江新益印染有限公司 | Method for removing colloid on dyed cloth surface of cotton fabric |
| CN115161133A (en) * | 2022-08-02 | 2022-10-11 | 晋江市盛星新材料科技有限公司 | Whitening and degreasing agent for cotton fabric and preparation method and use method thereof |
| CN115161133B (en) * | 2022-08-02 | 2023-12-01 | 晋江市盛星新材料科技有限公司 | Whitening and degreasing agent for cotton fabric, and preparation method and application method thereof |
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Application publication date: 20150826 |
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