CN106929242A - The method of carwash under high temperature car washing liquid and preparation method thereof, high temperature - Google Patents
The method of carwash under high temperature car washing liquid and preparation method thereof, high temperature Download PDFInfo
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- CN106929242A CN106929242A CN201710215313.2A CN201710215313A CN106929242A CN 106929242 A CN106929242 A CN 106929242A CN 201710215313 A CN201710215313 A CN 201710215313A CN 106929242 A CN106929242 A CN 106929242A
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- high temperature
- washing liquid
- car washing
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
- C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
- C09G1/12—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin mixtures of wax and silicon-containing polycondensates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
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- Emergency Medicine (AREA)
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- Detergent Compositions (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of high temperature car washing liquid of the present invention, the high temperature car washing liquid includes the deionized water of 93 96 weight portions, the silicone emulsion of 0.5 2.5 weight portions, the wax emulsion of 0.5 1.5 weight portions, 0.2 0.5 weight portions include the surfactant of amino acid type amphoteric surfactant, 1.0 2.0 weight portion boiling points are 250 350 DEG C solvent naphtha, the triethanolamine of the long-chain unsaturated acids, the polyisobutene succinimide of 0.01 0.25 weight portions and 0.02 0.06 weight portions of 0.1 0.2 weight portions.High temperature car washing liquid of the invention is main to be made up of water, the silicone oil of emulsification, wax emulsion, solvent naphtha, surfactant and other auxiliary agents, the content of water reaches more than 93%, and materials environmental protection, can use under conditions of high temperature burning sun again, cut can be significantly reduced, decontamination efficiently, on automobile finish glossiness influences low.
Description
Technical field
The present invention relates to a kind of car washing liquid, more particularly to a kind of car washing liquid for being adapted to and using under the high temperature conditions.
Background technology
At present, conventional carwash flow is：Vehicle body is drenched first or preliminary flushing is to remove substantial amounts of dirt, then
The car washing liquid for preparing uniformly is sprayed and/or wipes in bodywork surface, then the foam and sewage of bodywork surface are rinsed with water, finally with hair
Towel, chamois leather etc. dry vehicle body.In this process, in order to remove the car washing liquid that vehicle body is remained, need to be rinsed with substantial amounts of water, pole
Degree waste water resource.And many private car owners like the carwash under burning sun, it is believed that will soon be by vehicle body after so washing
Water is dried, and it is local that the convex lens effect that common car washing liquid water droplet is formed under its tangible burning sun can produce the superiors of car paint
High temperataure phenomena, easily makes car paint tarnish, and largely effects on vehicle body outward appearance.
Therefore, people are explored in car washing operation method and car washing liquid species.For example, disclosed in CN1704293A
A kind of water-saving type carwash method, it passes through 5 steps, and mainly repetitious wiping reaches the mesh of water saving and cleaning
's.The method that CN105505642A discloses another water-saving vehicle washing, the use of its car washing liquid for passing through special component reaches section
Water purpose.But above-mentioned car washing liquid is in high temperature burning sun condition but is attached to the particulate matter of bodywork surface in rag or bulk sponge
Firmly and wiping repeatedly under, be also easy to surface of vehicle paint produce cut.Under when using, it is difficult to keep preferable carwash, shield
Car effect.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of high temperature car washing liquid, the high temperature car washing liquid includes 93-
The deionized water of 96 weight portions, the silicone oil of the emulsification of 0.5-2.5 weight portions, the wax emulsion of 0.5-1.5 weight portions, 0.2-0.5 weights
It is molten for 250-350 DEG C that amount part includes the surfactant of amino acid type amphoteric surfactant, 1.0-2.0 weight portions boiling point
Agent oil, the long-chain unsaturated acids of 0.1-0.2 weight portions, the polyisobutene succinimide and 0.02- of 0.01-0.25 weight portions
The triethanolamine of 0.06 weight portion.
As one kind preferred embodiment, the silicone oil of the emulsification is selected from methyl silicone emulsion, ethyl silicone emulsion, first
The hydrogeneous silicone emulsion of base, methyl ethoxy silicone emulsion, methyl trifluoro propyl silicone emulsion, methyl ethylene silicone emulsion, first
One or more in base hydroxyl silicone emulsion, the hydrogeneous silicone emulsion of ethyl, amino silicone emulsion, the hydrogeneous silicone emulsion of hydroxyl.
As one kind preferred embodiment, it is characterised in that the silicone oil of the emulsification includes solid content in 40%-65%
Methyl trifluoro propyl silicone emulsion and solid content the amino silicone emulsion of 30%-40% mixture.
As one kind preferred embodiment, it is characterised in that the high temperature car washing liquid also includes 10000-15000cst
Viscous silicone fluid, the mass ratio of the viscous silicone fluid and surfactant is 1：20-40.
As one kind preferred embodiment, the surfactant includes the alkyl phenol polyoxy of 0.07-0.09 weight portions
Vinethene, the isomeric alcohol polyethenoxy ether of 0.05-0.07 weight portions, the phosphate ester surfactants of 0.02-0.03 weight portions and
The amino acid type amphoteric surfactant of 0.005-0.05 weight portions.
As one kind preferred embodiment, the amino acid type amphoteric surfactant is obtained through following steps：First
Sodium chloroacetate is added into the lauryl amine aqueous solution containing 5-10% mass percents, the stirring reaction 0.5h at 60-70 DEG C,
PH to neutrality is adjusted using watery hydrochloric acid；NaOH is added, continues to react 0.5h under the conditions of 60-70 DEG C, obtain amino acid
Type amphoteric surfactant；The mass ratio of lauryl amine, sodium chloroacetate and NaOH in the wherein described lauryl amine aqueous solution is
1：0.5-1.5：0.1-0.2.
As one kind preferred embodiment, the long-chain unsaturated acids is selected from erucic acid, selacholeic acid, nutmeg oleic acid, 2-
The combination of one or more in gaidic acid, palmitoleic acid, oleic acid, leukotrienes, 9- eicosenoic acids；The wax emulsion choosing
From babassu wax emulsion, lignite wax emulsion, beeswax emulsion, wool wax emulsion, paraffin wax emulsions, red bayberry wax emulsion, haze tallow emulsion
In the combination of one or more.
As one kind preferred embodiment, the high temperature car washing liquid also antistatic additive including 0.01-0.1 weight portions, and
The pigment of 0.01-0.5 weight portions, essence, preservative.
The present invention provides a kind of preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 93-96 weight portions is added in the first container, stirring treats that temperature is increased to 40-50 DEG C, adds 0.07-
The APES of 0.09 weight portion, the isomeric alcohol polyethenoxy ether of 0.05-0.07 weight portions and 0.02-0.03 weight
Part phosphate ester surfactants, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, 0.02-0.06 weight portions are added
Triethanolamine, the long-chain unsaturated acids of 0.1-0.2 weight portions, the polyisobutene succinimide of 0.01-0.25 weight portions, stirring
Uniformly, the first mixed liquor is obtained；
The wax emulsion of 0.5-1.5 weight portions is added in second container, stirring when temperature is increased to 50-60 DEG C, adds 1.0-
2 weight portion boiling points are 250-350 DEG C of solvent naphtha, are uniformly mixing to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, 0.5-2.5 weight portions are added
The silicone oil of emulsification, stirs；Add the amino acid type amphoteric surfactant of 0.005-0.05 weight portions, 0.01-0.1 weights
The antistatic additive of part is measured, 15min is stirred at 75-85 DEG C, add pigment, essence, the preservative of 0.01-0.5 weight portions, stirring
Uniformly, high temperature car washing liquid is obtained.
Present invention also offers the car-washing method under a kind of hot conditions, comprise the following steps：
Described high temperature car washing liquid is sprayed to surface of vehicle paint, 30-60 seconds is stood；Wiped away except car paint table using towel or sponge brush
The dirt in face and the liquid of remnants；The towel is bamboo fibre or superfine fibre towel.
High temperature car washing liquid of the invention it is main by water, the silicone oil of emulsification, wax emulsion, solvent naphtha, surfactant and its
His auxiliary agent composition, the content of water reaches more than 93%, and materials environmental protection, can use under conditions of high temperature burning sun again, and decontamination is high
Imitate, low is influenceed on automobile finish glossiness.
Because the dirt species complexity of car surface is, it is necessary to have the surfactant of fabulous scourability.It is of the invention
Organic silicone oil can not only improve the brightness of car surface after washing, additionally it is possible to play synergy with surfactant,
Improve the scourability of car washing liquid.Additionally, surfactant, organic solvent and wax that the present invention is used are environment-friendly degradables
Material.
Specific embodiment
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of art of the present invention
The identical implication that art personnel are generally understood that.When there is contradiction, the definition in this specification is defined.
High temperature car washing liquid of the invention includes the deionized water of 93-96 weight portions, the silicon of the emulsification of 0.5-2.5 weight portions
Oil, the wax emulsion of 0.5-1.5 weight portions, 0.2-0.5 weight portions include the surface-active of amino acid type amphoteric surfactant
Agent, solvent naphtha, the long-chain unsaturated acids of 0.1-0.2 weight portions, the 0.01-0.25 that 1.0-2.0 weight portions boiling point is 250-350 DEG C
The polyisobutene succinimide of weight portion and the triethanolamine of 0.02-0.06 weight portions.
Wherein the boiling point of solvent naphtha is 250-350 DEG C, and inventor has found preferably improve under high temperature car washing liquid high temperature
Performance, obtain preferably scratch repair.
As a kind of perferred technical scheme, the silicone oil of the emulsification is selected from silicone emulsion, methyl silicone emulsion, ethyl breast
SiClx oil, methyl hydrogen silicone emulsion, methyl ethoxy silicone emulsion, methyl trifluoro propyl silicone emulsion, methyl ethylene breast
In SiClx oil, methylhydroxy silicone emulsion, the hydrogeneous silicone emulsion of ethyl, amino silicone emulsion, the hydrogeneous silicone emulsion of hydroxyl one
Plant or several.
As a kind of perferred technical scheme, the silicone oil of the emulsification includes methyl trifluoro of the solid content in 40%-65%
The mixture of propyl group silicone emulsion and solid content in the amino silicone emulsion of 30%-40%.
As a kind of perferred technical scheme, the silicone oil of the emulsification by solid content 40%-65% methyl trifluoro propyl
Silicone emulsion and solid content are constituted in the amino silicone emulsion of 30%-40%.
As a kind of perferred technical scheme, the silicone oil of the emulsification by solid content 40%-65% methyl trifluoro propyl
Silicone emulsion and solid content compare 1 in the amino silicone emulsion of more than 30%-40% according to weight：15-20 is constituted.
The silicone oil solid content of above-described emulsification contains admittedly for quality.
As a kind of perferred technical scheme, the high temperature car washing liquid of the invention also high viscosity including 10000-15000cst
Silicone oil, the silicone oil of 10000-15000cst is 1 with the mass ratio of surfactant：20-40, using high-viscosity methyl-silicone oil
Although being unfavorable for the brightness of surface of vehicle paint, surface-active can be improved using the silicone oil of a small amount of 10000-15000cst
Agent Fouling Cleaning effect, it may be possible to because high-viscosity methyl-silicone oil can promote surfactant formed lamellar phase.
As a kind of perferred technical scheme, the surfactant includes the alkyl phenol polyoxy of 0.07-0.09 weight portions
Vinethene, the isomeric alcohol polyethenoxy ether of 0.05-0.07 weight portions, the phosphate ester surfactants of 0.02-0.03 weight portions and
The amino acid type amphoteric surfactant of 0.005-0.05 weight portions.
As a kind of perferred technical scheme, the APES includes NPE, octyl group
Phenol polyethenoxy ether, alkylpolyoxyethylene (DPEO) and Dinonylphenol Polyoxyethylene Ether (DNPEO), and then preferably nonyl
Phenol polyethenoxy ether.
As a kind of perferred technical scheme, the isomeric alcohol polyethenoxy ether includes heterogeneous ten alcohol polyoxyethylene ether, different
Structure undecyl alcohol APEO, isomerous tridecanol polyoxyethylene ether.
As a kind of perferred technical scheme, the phosphate ester surfactants include AEO phosphoric acid
It is ester/salt, Phosphate of Polyoxyethylene Isooctyl Ether, thermally coupled distillation columns/salt, isomerous tridecanol ether phosphate, different
Decyl alcohol ether phosphate.
As a kind of perferred technical scheme, the amino acid type amphoteric surfactant is obtained through following steps：First
Sodium chloroacetate is added into the lauryl amine aqueous solution containing 5-10% mass percents, the stirring reaction 0.5h at 60-70 DEG C,
PH to neutrality is adjusted using watery hydrochloric acid；NaOH is added, continues to react 0.5h under the conditions of 60-70 DEG C, obtain amino acid
Type amphoteric surfactant；The mass ratio of lauryl amine, sodium chloroacetate and NaOH in the wherein described lauryl amine aqueous solution is
1：0.5-1.5：0.1-0.2.
Currently preferred amino acid type amphoteric surfactant by the way that first lauryl amine is substantially dissolved in water, Ran Houxiang
Obtained after successively adding sodium chloroacetate and NaOH to be reacted in lauryl amine solution, the inventors discovered that in high temperature car washing liquid
In plus a small amount of above-mentioned amphoteric surfactant, then compatibility appropriate specific wax emulsion, solvent naphtha, can not only greatly improve and wash
Car liquid cleaning performance under high temperature burning sun, and car paint brightness do not weaken, and conjecture is probably because this amino acid pattern two
Property the special charged characteristic of surfactant, promote the cured dispersion in car washing liquid, car washing liquid water droplet is become more flat, reduce
The convex lens effect of high temperature burning sun.Polyisobutene succinimide of the invention and long-chain unsaturated acids can be reduced and repaired
Scuffing in wiping process, is that polyisobutene succinimide has substantial amounts of hydrogen bond, long-chain unsaturated acids energy the reason for possible
Enough and plane of crystal, abraded area produce strong absorption.
As a kind of perferred technical scheme, in the lauryl amine aqueous solution lauryl amine, sodium chloroacetate and NaOH
Mass ratio be 1：0.8：0.1.
As a kind of perferred technical scheme, the long-chain unsaturated acids is selected from erucic acid, selacholeic acid, nutmeg oleic acid, 2-
The combination of one or more in gaidic acid, palmitoleic acid, oleic acid, leukotrienes, 9- eicosenoic acids；The wax emulsion is selected from
In babassu wax emulsion, lignite wax emulsion, beeswax emulsion, wool wax emulsion, paraffin wax emulsions, red bayberry wax emulsion, haze tallow emulsion
The combination of one or more.
As a kind of perferred technical scheme, the high temperature car washing liquid also antistatic additive including 0.01-0.1 weight portions,
And pigment, essence, the preservative of 0.01-0.5 weight portions.
As a kind of perferred technical scheme, the high temperature car washing liquid also antistatic additive ox including 0.01-0.1 weight portions
Fat amine APEO, and 0.01-0.5 weight portions pigment, essence, preservative methyl hydroxybenzoate.
Present invention also offers a kind of preparation method of high temperature car washing liquid, comprise the following steps：
The deionized water of 93-96 weight portions is added in the first container, stirring treats that temperature is increased to 40-50 DEG C, adds 0.07-
The APES of 0.09 weight portion, the isomeric alcohol polyethenoxy ether of 0.05-0.07 weight portions and 0.02-0.03 weight
Part phosphate ester surfactants, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, 0.02-0.06 weight portions are added
Triethanolamine, the long-chain unsaturated acids of 0.1-0.2 weight portions, the polyisobutene succinimide of 0.01-0.25 weight portions, stirring
Uniformly, the first mixed liquor is obtained；
The wax emulsion of 0.5-1.5 weight portions is added in second container, stirring when temperature is increased to 50-60 DEG C, adds 1.0-
2 weight portion boiling points are 250-350 DEG C of solvent naphtha, are uniformly mixing to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, 0.5-2.5 weight portions are added
Silicone emulsion, stirs；Add the amino acid type amphoteric surfactant of 0.005-0.05 weight portions, 0.01-0.1 weight
The antistatic additive of part, stirs 15min at 75-85 DEG C, adds pigment, essence, the preservative of 0.01-0.5 weight portions, and stirring is equal
It is even, obtain high temperature car washing liquid.
Present invention also offers the car-washing method under a kind of hot conditions, comprise the following steps：
Any one high temperature car washing liquid recited above is sprayed to surface of vehicle paint, 30-60 seconds is stood；Use towel or sponge brush
Wipe the liquid of the dirt and remnants except surface of vehicle paint away.
As a kind of perferred technical scheme, the towel is bamboo fibre or superfine fibre towel.
Using bamboo fibre or superfine fibre towel can under the premise of keeping compared with high definition spot effect, further reduce cut and
Brightness is improved, it is presumed that being that amino acid surfactant in high temperature car washing liquid of the present invention enhances fiber on fiber towel
Between repulsive interaction, reduce the frictional force between fiber, it is become more soft and smooth, be more easy to play carwash
The cleaning function of liquid.And the effect of bamboo fiber towel is than superfine fibre towel more preferably.
High temperature car washing liquid of the invention it is main by water, the silicone oil of emulsification, wax emulsion, solvent naphtha, surfactant and its
His auxiliary agent composition, the content of water reaches more than 93%, and materials environmental protection, can use under conditions of high temperature burning sun again, and decontamination is high
Imitate, low is influenceed on automobile finish glossiness.
Because the dirt species complexity of car surface is, it is necessary to have the surfactant of fabulous scourability.Present invention choosing
The compatibilities such as amino acid type amphoteric surfactant and wax emulsion, solvent naphtha are using can not only improve automobile table after washing
The brightness in face, additionally it is possible to improve scourability of the car washing liquid under high temperature burning sun.
Additionally, surfactant, organic solvent and wax that the present invention is used are the materials of environment-friendly degradable.
Hereinafter, the present invention is explained in more detail by embodiment, it should be appreciated that these embodiments are only
Illustrate and it is nonrestrictive.If without other explanations, raw materials used is all commercially available.
The present invention is described in detail referring to several examples.
The amino acid type amphoteric surfactant preparation method that following examples are used is as follows：
（1）Amino acid type amphoteric surfactant A：Sodium chloroacetate is added to the lauryl amine water containing 5% mass percent first
In solution, the stirring reaction 0.5h at 60-70 DEG C adjusts pH to neutrality using watery hydrochloric acid；NaOH is added, in 60-70
Continue to react 0.5h under the conditions of DEG C, obtain amino acid type amphoteric surfactant A；In the wherein described lauryl amine aqueous solution 12
The mass ratio of amine, sodium chloroacetate and NaOH is 1：0.8：0.1.
（2）Amino acid type amphoteric surfactant B：Sodium chloroacetate is added to containing 8% mass percent 12 first
In amine aqueous solution, the stirring reaction 0.5h at 60-70 DEG C adjusts pH to neutrality using watery hydrochloric acid；NaOH is added,
Continue to react 0.5h under the conditions of 60-70 DEG C, obtain amino acid type amphoteric surfactant B；In the wherein described lauryl amine aqueous solution
Lauryl amine, sodium chloroacetate and NaOH mass ratio be 1：1.5：0.1.
Embodiment 1
The component of high temperature car washing liquid includes：The deionized water of 95 weight portions, the solid content of 2 weight portions is 50% methyl trifluoro third
Base silicone emulsion, the amino silicone emulsion that the solid content of 0.1 weight portion is 30%, the lignite wax emulsion of 0.09 weight portion, 1.0 weights
The solid content for measuring part is 30% babassu wax emulsion, the amino acid type amphoteric surfactant A of 0.03 weight portion, 0.09 weight
The NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion, the isooctanol polyoxy of 0.03 weight portion of part
Ethene ether phosphate, the solvent naphtha that the boiling point of 1.8 weight portions is 250-350 DEG C, the oleic acid of 0.15 weight portion, 0.03 weight portion
Polyisobutene succinimide, the triethanolamine of 0.05 weight portion, the pigment of 0.02 weight portion, essence, methyl hydroxybenzoate.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 weight portions is added in the first container, is stirred, treat that temperature is increased to 40-50 DEG C, add 0.09 weight
The isooctanol polyoxy of the NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion and 0.03 weight portion of part
Ethene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, the triethanolamine of 0.05 weight portion, 0.15 is added
The polyisobutene succinimide of the oleic acid of weight portion, 0.03 weight portion, stirs, and obtains the first mixed liquor；
It is 30% Brazil wax breast that the lignite wax emulsion of 0.09 weight portion, the solid content of 1.0 weight portions are added in second container
Liquid, stirring, when temperature is increased to 50-60 DEG C, it is 250-350 DEG C of solvent naphtha to add 1.8 weight portion boiling points, is stirred
To the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds the solid of 0.1 weight portion to contain
It is 50% methyl trifluoro propyl silicone emulsion, the amino silicone emulsion that the solid content of 2.0 weight portions is 30% to measure, and is stirred；
Add the amino acid type amphoteric surfactant A of 0.03 weight portion, the antistatic additive tallow amine polyoxyethylene of 0.05 weight portion
Ether, stirs 15min at 75-85 DEG C, adds pigment, essence, the methyl hydroxybenzoate of 0.02 weight portion, stirs, and obtains height
Warm car washing liquid.
Embodiment 2
The component of high temperature car washing liquid includes：The deionized water of 95 weight portions, the solid content of 0.1 weight portion is 50% methyl trifluoro
Propyl group silicone emulsion, the amino silicone emulsion that the solid content of 2 weight portions is 30%, the lignite wax emulsion of 0.09 weight portion, 1.0 weights
The solid content for measuring part is 30% babassu wax emulsion, the amino acid type amphoteric surfactant A of 0.03 weight portion, 0.09 weight
The NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion, the isooctanol polyoxy of 0.03 weight portion of part
Ethene ether phosphate, the solvent naphtha that the boiling point of 1.8 weight portions is 250-350 DEG C, the oleic acid of 0.15 weight portion, 0.08 weight portion
Polyisobutene succinimide, the triethanolamine of 0.05 weight portion, the pigment of 0.02 weight portion, essence, methyl hydroxybenzoate.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 weight portions is added in the first container, is stirred, treat that temperature is increased to 40-50 DEG C, add 0.09 weight
The isooctanol polyoxy of the NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion and 0.03 weight portion of part
Ethene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, the triethanolamine of 0.05 weight portion, 0.15 is added
The polyisobutene succinimide of the oleic acid of weight portion, 0.08 weight portion, stirs, and obtains the first mixed liquor；
It is 30% Brazil wax breast that the lignite wax emulsion of 0.09 weight portion, the solid content of 1.0 weight portions are added in second container
Liquid, stirring, when temperature is increased to 50-60 DEG C, it is 250-350 DEG C of solvent naphtha to add 1.8 weight portion boiling points, is stirred
To the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, the solid content of 2 weight portions is added
It is 50% methyl trifluoro propyl silicone emulsion, the amino silicone emulsion that the solid content of 0.1 weight portion is 30%, stirs；Again
Add the amino acid type amphoteric surfactant A of 0.03 weight portion, the antistatic additive tallow amine APEO of 0.05 weight portion,
15min is stirred at 75-85 DEG C, pigment, essence, the methyl hydroxybenzoate of 0.02 weight portion is added, stirred, obtained high temperature and wash
Car liquid.
Embodiment 3
The component of high temperature car washing liquid includes：The deionized water of 95 weight portions, the solid content of 1 weight portion is 50% methyl trifluoro third
Base silicone emulsion, the amino silicone emulsion that the solid content of 1 weight portion is 30%, the lignite wax emulsion of 0.09 weight portion, 1.0 weight
The solid content of part is 30% babassu wax emulsion, the amino acid type amphoteric surfactant A of 0.03 weight portion, 0.09 weight portion
NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion, the isooctanol polyoxy second of 0.03 weight portion
Alkene ether phosphate, 1.8 weight portions boiling point for 250-350 DEG C solvent naphtha, the oleic acid of 0.15 weight portion, 0.2 weight portion it is poly-
Isobutene succimide, the triethanolamine of 0.05 weight portion, the pigment of 0.02 weight portion, essence, methyl hydroxybenzoate.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 weight portions is added in the first container, is stirred, treat that temperature is increased to 40-50 DEG C, add 0.09 weight
The isooctanol polyoxy of the NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion and 0.03 weight portion of part
Ethene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, the triethanolamine of 0.05 weight portion, 0.15 is added
The polyisobutene succinimide of the oleic acid of weight portion, 0.2 weight portion, stirs, and obtains the first mixed liquor；
It is 30% Brazil wax breast that the lignite wax emulsion of 0.09 weight portion, the solid content of 1.0 weight portions are added in second container
Liquid, stirring, when temperature is increased to 50-60 DEG C, it is 250-350 DEG C of solvent naphtha to add 1.8 weight portion boiling points, is stirred
To the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, the solid content of 1 weight portion is added
It is 50% methyl trifluoro propyl silicone emulsion, the amino silicone emulsion that the solid content of 1 weight portion is 30%, stirs；Again plus
Enter the amino acid type amphoteric surfactant A of 0.03 weight portion, the antistatic additive tallow amine APEO of 0.05 weight portion,
15min is stirred at 75-85 DEG C, pigment, essence, the methyl hydroxybenzoate of 0.02 weight portion is added, stirred, obtain high temperature carwash
Liquid.
Embodiment 4
The component of high temperature car washing liquid includes：The deionized water of 95 weight portions, the solid content of 0.1 weight portion is 50% methyl trifluoro
Propyl group silicone emulsion, the amino silicone emulsion that the solid content of 2 weight portions is 30%, the 12000cst methyl silicon of 0.015 weight portion
Oil, the lignite wax emulsion of 0.09 weight portion, the solid content of 1.0 weight portions are 30% babassu wax emulsion, the ammonia of 0.03 weight portion
Base acid type amphoteric surfactant A, the NPE of 0.09 weight portion, the isomerous tridecanol polyoxy of 0.06 weight portion
Vinethene, the Phosphate of Polyoxyethylene Isooctyl Ether of 0.03 weight portion, 1.8 weight portions boiling point for 250-350 DEG C solvent naphtha,
The oleic acid of 0.15 weight portion, the polyisobutene succinimide of 0.1 weight portion, the triethanolamine of 0.05 weight portion, 0.02 weight
The pigment, essence, methyl hydroxybenzoate of part.
The preparation method of high temperature car washing liquid is same as Example 1, and difference is to be added after amino silicone emulsion is added
The 12000cst methyl-silicone oils of 0.015 weight portion.
Embodiment 5
The component of high temperature car washing liquid includes：The deionized water of 95 weight portions, the solid content of 0.1 weight portion is 50% methyl trifluoro
Propyl group silicone emulsion, the amino silicone emulsion that the solid content of 2 weight portions is 30%, the 12000cst methyl silicon of 0.015 weight portion
Oil, the lignite wax emulsion of 0.09 weight portion, the solid content of 1.0 weight portions are 30% babassu wax emulsion, the ammonia of 0.03 weight portion
Base acid type amphoteric surfactant A, the NPE of 0.09 weight portion, the isomerous tridecanol polyoxy of 0.06 weight portion
Vinethene, the Phosphate of Polyoxyethylene Isooctyl Ether of 0.03 weight portion, 1.8 weight portions boiling point for 250-350 DEG C solvent naphtha,
The oleic acid of 0.15 weight portion, the polyisobutene succinimide of 0.1 weight portion, the triethanolamine of 0.05 weight portion, 0.02 weight
The pigment, essence, methyl hydroxybenzoate of part.The preparation method of high temperature car washing liquid is same as Example 1.
Embodiment 6
Same as Example 1, difference is that amino acid type amphoteric surfactant uses amino acid type amphoteric surface-active
Agent B.
Comparative example 1
The component of high temperature car washing liquid includes：The deionized water of 95 weight portions, the solid content of 0.1 weight portion is 50% methyl emulsification
Silicone oil, amino silicone emulsion that the solid content of 2 weight portions is 30%, the lignite wax emulsion of 0.09 weight portion, 1.0 weight portions are consolidated
Content is 30%-40% babassus wax emulsion, the NPE of 0.09 weight portion, the isomery 13 of 0.06 weight portion
Alcohol APEO, the Phosphate of Polyoxyethylene Isooctyl Ether of 0.03 weight portion, the boiling point of 1.8 weight portions are 250-350 DEG C
Solvent naphtha, the oleic acid of 0.15 weight portion, the triethanolamine of 0.05 weight portion, the pigment of 0.02 weight portion, essence, Metagin
Ester.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 weight portions is added in the first container, is stirred, treat that temperature is increased to 40-50 DEG C, add 0.09 weight
The isooctanol polyoxy of the NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion and 0.03 weight portion of part
Ethene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, the triethanolamine of 0.05 weight portion, 0.15 is added
The oleic acid of weight portion, stirs, and obtains the first mixed liquor；
It is 30% Brazil wax breast that the lignite wax emulsion of 0.09 weight portion, the solid content of 1.0 weight portions are added in second container
Liquid, stirring, when temperature is increased to 50-60 DEG C, it is 250-350 DEG C of solvent naphtha to add 1.8 weight portion boiling points, is stirred
To the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds the solid of 0.1 weight portion to contain
Measure the silicone emulsion for 50%, the amino silicone emulsion that the solid content of 2.0 weight portions is 30%, stir；Add 0.05 weight
The antistatic additive tallow amine APEO of part is measured, 15min is stirred at 75-85 DEG C, add pigment, the perfume (or spice) of 0.02 weight portion
Essence, methyl hydroxybenzoate, stir, and obtain high temperature car washing liquid.
Comparative example 2：
The component of high temperature car washing liquid includes：The deionized water of 95 weight portions, the solid content of 0.1 weight portion is 50% methyl emulsification
Silicone oil, amino silicone emulsion that the solid content of 2 weight portions is 30%, the lignite wax emulsion of 0.09 weight portion, 1.0 weight portions are consolidated
Content is 30% babassu wax emulsion, the amino acid type amphoteric surfactant A of 0.03 weight portion, the nonyl of 0.09 weight portion
Phenol polyethenoxy ether, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion, the isooctanol polyethoxylate phosphorus of 0.03 weight portion
Acid esters, the oleic acid of 0.15 weight portion, the triethanolamine of 0.05 weight portion, the pigment of 0.02 weight portion, essence, methyl hydroxybenzoate.
The preparation method of high temperature car washing liquid, comprises the following steps：
The deionized water of 95 weight portions is added in the first container, is stirred, treat that temperature is increased to 40-50 DEG C, add 0.09 weight
The isooctanol polyoxy of the NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion and 0.03 weight portion of part
Ethene ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, the triethanolamine of 0.05 weight portion, 0.15 is added
The oleic acid of weight portion, stirs, and obtains the first mixed liquor；
It is 30%-40% babassus that the lignite wax emulsion of 0.09 weight portion, the solid content of 1.0 weight portions are added in second container
Wax emulsion, stirring, is uniformly mixing to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, adds the solid of 0.1 weight portion to contain
It is 50% methyl silicone emulsion, the amino silicone emulsion that the solid content of 2.0 weight portions is 30% to measure, and is stirred；Add
The amino acid type amphoteric surfactant A of 0.03 weight portion, the antistatic additive tallow amine APEO of 0.05 weight portion,
15min is stirred at 75-85 DEG C, pigment, essence, the methyl hydroxybenzoate of 0.02 weight portion is added, stirred, obtain high temperature carwash
Liquid.
Comparative example 3
The component of car washing liquid includes：The deionized water of 95 weight portions, the solid content of 0.1 weight portion be 50% methyl silicone emulsion,
The solid content of 2 weight portions is 30% amino silicone emulsion, the NPE of 0.09 weight portion, 0.06 weight portion
Isomerous tridecanol polyoxyethylene ether, the Phosphate of Polyoxyethylene Isooctyl Ether of 0.03 weight portion, the boiling point of 1.8 weight portions are 250-
350 DEG C of solvent naphtha, the oleic acid of 0.15 weight portion, the triethanolamine of 0.05 weight portion, the pigment of 0.02 weight portion, essence, Buddhist nun
Pool tortoise beetle ester.
The preparation method of car washing liquid, comprises the following steps：
The deionized water of 95 weight portions is added in a reservoir, is stirred, treat that temperature is increased to 40-50 DEG C, add 0.09 weight portion
The isooctanol polyoxyethylene of NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion and 0.03 weight portion
Ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, the triethanolamine of 0.05 weight portion, 0.15 weight is added
The oleic acid of part, stirs, and obtains the first mixed liquor；Add the solvent naphtha that 1.8 weight portion boiling points are 250-350 DEG C；Add 2
The solid content of weight portion is 50% methyl silicone emulsion, the amino silicone emulsion that the solid content of 0.1 weight portion is 30%, and stirring is equal
It is even；The antistatic additive tallow amine APEO of 0.05 weight portion is added, 15min is stirred at 75-85 DEG C, add 0.02 weight
The pigment, essence, methyl hydroxybenzoate of part are measured, is stirred, obtain car washing liquid.
Comparative example 4：
The component of car washing liquid includes：The deionized water of 95 weight portions, the solid content of 0.1 weight portion be 50% methyl silicone emulsion,
The solid content of 2 weight portions is 30% amino silicone emulsion, the amino acid type amphoteric surfactant A of 0.03 weight portion, 0.09 weight
The NPE of amount part, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion, the isooctanol of 0.03 weight portion gather
Oxygen ethene ether phosphate, solvent naphtha, the oleic acid of 0.15 weight portion, 0.05 weight portion that the boiling point of 1.8 weight portions is 250-350 DEG C
Triethanolamine, the pigment of 0.02 weight portion, essence, methyl hydroxybenzoate.
The preparation method of car washing liquid, comprises the following steps：
The deionized water of 95 weight portions is added in a reservoir, is stirred, treat that temperature is increased to 40-50 DEG C, add 0.09 weight portion
The isooctanol polyoxyethylene of NPE, the isomerous tridecanol polyoxyethylene ether of 0.06 weight portion and 0.03 weight portion
Ether phosphate, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, the triethanolamine of 0.05 weight portion, 0.15 weight is added
The oleic acid of part, stir, obtain the first mixed liquor；Add the solvent naphtha that 1.8 weight portion boiling points are 250-350 DEG C；Add
The solid content of 2 weight portions is 50% methyl silicone emulsion, the amino silicone emulsion that the solid content of 0.1 weight portion is 30%, stirring
Uniformly；Add the amino acid type amphoteric surfactant A of 0.03 weight portion, the antistatic additive tallow amine polyoxy of 0.05 weight portion
Vinethene, stirs 15min at 75-85 DEG C, adds pigment, essence, the methyl hydroxybenzoate of 0.02 weight portion, stirs, and obtains
To car washing liquid.
Evaluate：
Taking certain amount has the metallic plate of automobile coating（330mm×100mm）, its brightness is essentially identical and surface tear quantity base
This is identical, is placed on the outdoor 14 days of a small amount of airborne dust, then in 40 DEG C of temperature and under conditions of setting light source analogy solar irradiation,
Each 15 of metallic plate is cleaned using the car washing liquid of embodiment and comparative example.Will car washing liquid be sprayed into metal sheet surface, to metal
Plate surface covers car washing liquid substantially, stands 45 seconds, is wiped using towel and removes dirt, then using a clean towel removal surface
Remaining liquid：The towel that wherein embodiment 1-4,6 and comparative example 1-3 are used is bamboo fiber towel, embodiment 5 and comparative example 4
Use common cotton towels.
Metal sheet surface brightness and scuffing bar number after observation cleaning, and contrasted.By substantially brighter after cleaning
Substantially it is deteriorated to brightness and is designated as+6 to -6, cut quantity is significantly reduced to cut quantity, and substantially increase is designated as+6 to -6, uses
Paper handkerchief wipes the surface observation dirt after cleaning, and spot substantially arrives no spot and is designated as 6 to 0, takes 15 average values of metallic plate
Result is as follows.
As can be seen that cut can be significantly reduced using car washing liquid of the present invention.
The above, only presently preferred embodiments of the present invention is not intended to limit the scope of the present invention.It is every
The impartial change done according to present invention and modification, are encompassed by the scope of the claims of the invention.
Claims (10)
1. a kind of high temperature car washing liquid, it is characterised in that the high temperature car washing liquid includes the deionized water of 93-96 weight portions, 0.5-
The silicone oil of the emulsification of 2.5 weight portions, the wax emulsion of 0.5-1.5 weight portions, 0.2-0.5 weight portions include amino acid type amphoteric table
The surfactant of face activating agent, solvent naphtha, the long-chain of 0.1-0.2 weight portions that 1.0-2.0 weight portions boiling point is 250-350 DEG C
The triethanolamine of unsaturated acids, the polyisobutene succinimide of 0.01-0.25 weight portions and 0.02-0.06 weight portions.
2. high temperature car washing liquid according to claim 1, it is characterised in that the silicone oil of the emulsification is selected from methyl and emulsifies silicon
Oil, ethyl silicone emulsion, methyl hydrogen silicone emulsion, methyl ethoxy silicone emulsion, methyl trifluoro propyl silicone emulsion, methyl
Vinyl silicone emulsion, methylhydroxy silicone emulsion, the hydrogeneous silicone emulsion of ethyl, amino silicone emulsion, the hydrogeneous emulsification silicon of hydroxyl
One or more in oil.
3. high temperature car washing liquid according to claim 1, it is characterised in that the silicone oil of the emulsification includes solid content and exists
Mixture of the methyl trifluoro propyl silicone emulsion and solid content of 40%-65% in the amino silicone emulsion of 30%-40%.
4. high temperature car washing liquid according to claim 1, it is characterised in that the high temperature car washing liquid also includes 10000-
The viscous silicone fluid of 15000cst, the viscous silicone fluid is 1 with the mass ratio of surfactant：20-40.
5. high temperature car washing liquid according to claim 1, it is characterised in that the surfactant includes 0.07-0.09 weights
Measure the APES, the isomeric alcohol polyethenoxy ether of 0.05-0.07 weight portions, the phosphorus of 0.02-0.03 weight portions of part
The amino acid type amphoteric surfactant of acid ester surface active agent and 0.005-0.05 weight portions.
6. the high temperature car washing liquid according to claim 1-5 any one, it is characterised in that the amino acid type amphoteric surface
Activating agent is obtained through following steps：Sodium chloroacetate is added into the lauryl amine aqueous solution containing 5-10% mass percents first,
The stirring reaction 0.5h at 60-70 DEG C, pH to neutrality is adjusted using watery hydrochloric acid；NaOH is added, under the conditions of 60-70 DEG C
Continue to react 0.5h, obtain amino acid type amphoteric surfactant；Lauryl amine, monoxone in the wherein described lauryl amine aqueous solution
The mass ratio of sodium and NaOH is 1：0.5-1.5：0.1-0.2.
7. high temperature car washing liquid according to claim 1, it is characterised in that the long-chain unsaturated acids is selected from erucic acid, oil of dogfish
The group of one or more in acid, nutmeg oleic acid, 2- gaidic acids, palmitoleic acid, oleic acid, leukotrienes, 9- eicosenoic acids
Close；The wax emulsion is selected from babassu wax emulsion, lignite wax emulsion, beeswax emulsion, wool wax emulsion, paraffin wax emulsions, red bayberry
The combination of one or more in wax emulsion, haze tallow emulsion.
8. high temperature car washing liquid according to claim 1, it is characterised in that high temperature car washing liquid also includes 0.01-0.1 weight portions
Antistatic additive, and 0.01-0.5 weight portions pigment, essence, preservative.
9. a kind of preparation method of high temperature car washing liquid, it is characterised in that comprise the following steps：
The deionized water of 93-96 weight portions is added in the first container, stirring treats that temperature is increased to 40-50 DEG C, adds 0.07-
The APES of 0.09 weight portion, the isomeric alcohol polyethenoxy ether of 0.05-0.07 weight portions and 0.02-0.03 weight
Part phosphate ester surfactants, stirring is to being completely dissolved；Temperature is warming up to 80-90 DEG C, 0.02-0.06 weight portions are added
Triethanolamine, the long-chain unsaturated acids of 0.1-0.2 weight portions, the polyisobutene succinimide of 0.01-0.25 weight portions, stirring
Uniformly, the first mixed liquor is obtained；
The wax emulsion of 0.5-1.5 weight portions is added in second container, stirring when temperature is increased to 50-60 DEG C, adds 1.0-
2 weight portion boiling points are 250-350 DEG C of solvent naphtha, are uniformly mixing to obtain the second mixed liquor；
First mixed liquor of the first container is poured into the second container equipped with the second mixed liquor, 0.5-2.5 weight portions are added
The silicone oil of emulsification, stirs；Add the amino acid type amphoteric surfactant of 0.005-0.05 weight portions, 0.01-0.1 weights
The antistatic additive of part is measured, 15min is stirred at 75-85 DEG C, add pigment, essence, the preservative of 0.01-0.5 weight portions, stirring
Uniformly, high temperature car washing liquid is obtained.
10. the car-washing method under a kind of hot conditions, it is characterised in that comprise the following steps：
High temperature car washing liquid described in any one claim in claim 1-8 is sprayed to surface of vehicle paint, 30-60 is stood
Second；Wipe the liquid of the dirt and remnants except surface of vehicle paint away using towel or sponge brush；The towel is bamboo fibre or ultra-fine
Fiber towel.
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| CN109825381A (en) * | 2019-03-15 | 2019-05-31 | 浙江钰兔汽车科技有限公司 | A kind of automobile dry-cleaning cleaning curing agent composition and preparation method thereof |
| CN111100764A (en) * | 2019-12-06 | 2020-05-05 | 李斌 | Automobile glazing cleaning wet tissue for waterless car washing |
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| CN1563236A (en) * | 2004-04-22 | 2005-01-12 | 王金环 | Brightening agent for vehicle without water washing, and preparation method |
| CN103614083A (en) * | 2013-12-03 | 2014-03-05 | 沈阳化工大学 | Automobile cleaning water wax and preparation method thereof |
| EP3091066A1 (en) * | 2015-05-06 | 2016-11-09 | Latvijas Universitate | Vehicles anhydrous care products |
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