CN103666797A - Antimicrobial cleaning agent for washing machine tank and preparation method for antimicrobial cleaning agent - Google Patents

Antimicrobial cleaning agent for washing machine tank and preparation method for antimicrobial cleaning agent Download PDF

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Publication number
CN103666797A
CN103666797A CN201310723436.9A CN201310723436A CN103666797A CN 103666797 A CN103666797 A CN 103666797A CN 201310723436 A CN201310723436 A CN 201310723436A CN 103666797 A CN103666797 A CN 103666797A
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China
Prior art keywords
ether
washing machine
aliphatic alcohol
alcohol polyethenoxy
sodium
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Application number
CN201310723436.9A
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Chinese (zh)
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CN103666797B (en
Inventor
冯秀节
王晓跃
袁琦
魏淑芬
王建
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SHANGHAI LVSAN INVI-TECH DEVELOPMENT Co Ltd
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SHANGHAI LVSAN INVI-TECH DEVELOPMENT Co Ltd
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Priority to CN201310723436.9A priority Critical patent/CN103666797B/en
Publication of CN103666797A publication Critical patent/CN103666797A/en
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Abstract

The invention provides an antimicrobial cleaning agent for a washing machine tank and a preparation method for the antimicrobial cleaning agent. The antimicrobial cleaning agent for the washing machine tank comprises sodium sulfate, sodium chloride, sodium carboxymethylcellulose, EDTA (ethylene diamine tetraacetic acid)-2Na, a nonionic surfactant, didoctyl dimethyl ammonium chloride and essence. The cleaning agent does not contain an oxidative bleaching agent; the raw materials are substances which are high in biological degradability and environment-friendly; the cleaning agent integrates multiple functions of cleaning, descaling, antimicrobial performance, scale resedimentation prevention and the like; the production method provided by the invention is simple, feasible and suitable for industrial production.

Description

A kind of washing machine tank antibacterial cleanser and preparation method thereof
Technical field
The invention belongs to detergent composition field, particularly a kind of washing machine tank antibacterial cleanser and preparation method thereof.
Background technology
With the quickening pace of modern life, washing machine has become requisite burnisher in people's daily life.But washing machine internal is moist, if life-time service and not cleaning not only can accumulate dirt in a large number, and easy breed bacteria.The washing powder using in daily life in addition, particularly soap or liquid soap contain lubricant component, and these greases also can be attached on interior bucket interlayer wall, so the time that washing machine uses is longer, and the grease of absorption is more, easily causes the secondary pollution of clothing.
The investigation discovery of relevant authoritative health organ, family expenses sleeve washer bacterium exceeding standard rate is up to 81.3%; The germ detecting is of a great variety: comprise other multiple germs such as intestinal bacteria, streptococcus aureus, Candida albicans, nail cryptococcus, Pseudomonas aeruginosa.Visible, washing machine tank pollutes the stealthy killer who has become harm household health.It is stricken that the harm that clothing secondary pollution causes household's health is also made us.To the cleaning of washing machine tank, be not only to clean the observable dirt of energy, more will kill the germ of the inside.
At present, the Washine-machine chute detergent of selling on the market has a variety of, all has sterilizing function.These products are all used oxidative bleaching agent, utilize active oxygen to carry out sterilization.But active oxygen is strong oxidizer, and various article is had to damage effect, can make that rubber product becomes fragile, hardening, accelerated deterioration; Make copper sheet occur green rust staining; Make fabric bleaching, fade etc.Therefore, be badly in need of a kind of effectively stain removal bactericidal, again the Washine-machine chute detergent of safety and environmental protection.
Summary of the invention
The object of this invention is to provide a kind of washing machine tank antibacterial cleanser and preparation method thereof.Oxygen-freeization SYNTHETIC OPTICAL WHITNER in described sanitising agent, selected raw material is good, the environment amenable material of biological degradability, the several functions such as integrate cleaning, scale removal, antibacterial, anti-dirt deposits again, and the production method providing, simple, be suitable for suitability for industrialized production.
The object of the invention is to be achieved through the following technical solutions:
A washing machine tank antibacterial cleanser, the raw material of described sanitising agent comprises sodium sulfate, sodium-chlor, Xylo-Mucine, EDTA-2Na, nonionogenic tenside, two decyl alkyl dimethyl ammonium chloride and essence, the ratio of weight and number of described each raw material is:
Sodium sulfate 30 ~ 50
Sodium-chlor 10 ~ 40
Xylo-Mucine 0.5 ~ 1
EDTA-2Na 0.5~2
Nonionogenic tenside 2 ~ 10
Two decyl alkyl dimethyl ammonium chlorides 5 ~ 10
Essence 0.2 ~ 0.4.
Further, described nonionogenic tenside is one or more the mixture in aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
Further, described essence is lavender oil.
Another object of the present invention is realized by following another technical scheme:
A kind of preparation method of washing machine tank antibacterial cleanser, the raw material of described sanitising agent comprises sodium sulfate, sodium-chlor, Xylo-Mucine, EDTA-2Na, nonionogenic tenside, two decyl alkyl dimethyl ammonium chloride and essence, and the ratio of weight and number of described each raw material is:
Sodium sulfate 30 ~ 50
Sodium-chlor 10 ~ 40
Xylo-Mucine 0.5 ~ 1
EDTA-2Na 0.5~2
Nonionogenic tenside 2 ~ 10
Two decyl alkyl dimethyl ammonium chlorides 5 ~ 10
Essence 0.2 ~ 0.4;
Described preparation method comprises the following steps:
1) after above-mentioned sodium sulfate and sodium-chlor are mixed, add described pair of decyl alkyl dimethyl ammonium chloride, mixing and stirring, obtains mixture A;
2) in said mixture A, add successively described Xylo-Mucine and EDTA-2Na, mixing and stirring, obtains mixture B;
3) in said mixture B, add described nonionogenic tenside and essence, stir, obtain described washing machine tank antibacterial cleanser.
the present invention compared with prior art has following beneficial effect:
1, washing machine tank antibacterial cleanser of the present invention is by cats product and nonionogenic tenside compounding technology, reached the effect of decontamination to washing machine tank, sterilization, removal peculiar smell, while oxygen-freeization SYNTHETIC OPTICAL WHITNER, use safety and environmental protection, can reduce the damage to washing machine tank itself;
2, washing machine tank antibacterial cleanser of the present invention is powder preparation, and convenient transportation is used more convenient;
3, to be biological degradability good for the raw material of washing machine tank antibacterial cleanser of the present invention, and environment amenable material, belongs to environmentally friendly product;
4, in washing machine tank antibacterial cleanser of the present invention, select Xylo-Mucine, there is the ability of antiredeposition, can prevent the secondary pollution of dirt; EDTA-2Na is sequestrant, can strengthen the resistance to hard water of described sanitising agent; Two decyl alkyl dimethyl ammonium chlorides are fungicidal preservative, and the killing rate of intestinal bacteria, streptococcus aureus and Candida albicans is all greater than to 99.9%; In sanitising agent, also contain sodium-chlor, can increase the perviousness of product water solution, kill bacteria that can be more quickly and effectively;
5, preparation method's technique of washing machine tank antibacterial cleanser of the present invention is simple, easily suitability for industrialized production;
6, washing machine tank antibacterial cleanser of the present invention is solid powder preparation, and convenient transportation is used more convenient.
Embodiment
embodiment 1
A kind of preparation method of washing machine tank antibacterial cleanser, the raw material of described sanitising agent comprises sodium sulfate, sodium-chlor, Xylo-Mucine, EDTA-2Na, nonionogenic tenside, two decyl alkyl dimethyl ammonium chloride and essence, and the ratio of weight and number of described each raw material is:
Sodium sulfate 30 ~ 50
Sodium-chlor 10 ~ 40
Xylo-Mucine 0.5 ~ 1
EDTA-2Na 0.5~2
Nonionogenic tenside 2 ~ 10
Two decyl alkyl dimethyl ammonium chlorides 5 ~ 10
Essence 0.2 ~ 0.4;
Further, described nonionogenic tenside is one or more the mixture in aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
Further, described essence is lavender oil.
The preparation method of described washing machine tank antibacterial cleanser comprises the following steps:
1) after above-mentioned sodium sulfate and sodium-chlor are mixed, add described pair of decyl alkyl dimethyl ammonium chloride, mixing and stirring, obtains mixture A;
2) in said mixture A, add successively described Xylo-Mucine and EDTA-2Na, mixing and stirring, obtains mixture B;
3) in said mixture B, add described nonionogenic tenside and essence, stir, obtain described washing machine tank antibacterial cleanser.
The present embodiment weight unit used is kilogram, also can for gram;
Essence described in the present embodiment is food grade, and other each raw materials are technical grade;
Each component described in the present embodiment is the conventional products of selling on market.
In the present embodiment, each raw material in described washing machine tank antibacterial cleanser can be in the ratio range providing flexible combination, at this, do not enumerate one by one.
embodiment 2
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of described each raw material is:
Sodium sulfate 42
Sodium-chlor 40
Xylo-Mucine 0.7
EDTA-2Na 1
Aliphatic alcohol polyethenoxy (3) ether 7
Aliphatic alcohol polyethenoxy (7) ether 2
Aliphatic alcohol polyethenoxy (9) ether 1
Two decyl alkyl dimethyl ammonium chlorides 6
Lavender oil 0.3.
The present embodiment weight unit used is kilogram, also can for gram.
The preparation method of the present embodiment refers to embodiment 1.
According to the < < disinfection technology standard > > in 2002 of the Ministry of Health, the sterilizing power of the washing machine tank antibacterial cleanser of the present embodiment is detected, to colibacillary killing rate be 99.99%, streptococcus aureus killing rate is 99.95%, the killing rate of Candida albicans is 95.6%.
embodiment 3
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of described each raw material is:
Sodium sulfate 48
Sodium-chlor 30
Xylo-Mucine 1
EDTA-2Na 0.6
Aliphatic alcohol polyethenoxy (3) ether 5
Aliphatic alcohol polyethenoxy (7) ether 4
Aliphatic alcohol polyethenoxy (9) ether 1
Two decyl alkyl dimethyl ammonium chlorides 10
Lavender oil 0.4.
The present embodiment weight unit used is kilogram, also can for gram.
The preparation method of the present embodiment refers to embodiment 1.
According to the < < disinfection technology standard > > in 2002 of the Ministry of Health, the sterilizing power of the washing machine tank antibacterial cleanser of the present embodiment is detected, to colibacillary killing rate be 99.99%, streptococcus aureus killing rate is 99.95%, the killing rate of Candida albicans is 95.6%.
embodiment 4
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of described each raw material is:
Sodium sulfate 40
Sodium-chlor 38
Xylo-Mucine 1
EDTA-2Na 1.7
Aliphatic alcohol polyethenoxy (7) ether 6
Aliphatic alcohol polyethenoxy (9) ether 4
Two decyl alkyl dimethyl ammonium chlorides 9
Lavender oil 0.3.
The present embodiment weight unit used is kilogram, also can for gram.
The preparation method of the present embodiment refers to embodiment 1.
According to the < < disinfection technology standard > > in 2002 of the Ministry of Health, the sterilizing power of the washing machine tank antibacterial cleanser of the present embodiment is detected, to colibacillary killing rate be 99.99%, streptococcus aureus killing rate is 99.95%, the killing rate of Candida albicans is 95.6%.
embodiment 5
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of described each raw material is:
Sodium sulfate 49
Sodium-chlor 28
Xylo-Mucine 1
EDTA-2Na 1.6
Aliphatic alcohol polyethenoxy (3) ether 5
Aliphatic alcohol polyethenoxy (7) ether 5
Two decyl alkyl dimethyl ammonium chlorides 10
Lavender oil 0.4.
The present embodiment weight unit used is kilogram, also can for gram.
The preparation method of the present embodiment refers to embodiment 1.
According to the < < disinfection technology standard > > in 2002 of the Ministry of Health, the sterilizing power of the washing machine tank antibacterial cleanser of the present embodiment is detected, to colibacillary killing rate be 99.99%, streptococcus aureus killing rate is 99.95%, the killing rate of Candida albicans is 95.6%.
embodiment 6
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of described each raw material is:
Sodium sulfate 44
Sodium-chlor 35
Xylo-Mucine 1
EDTA-2Na 1.6
Aliphatic alcohol polyethenoxy (7) ether 8
Aliphatic alcohol polyethenoxy (9) ether 2
Two decyl alkyl dimethyl ammonium chlorides 8
Lavender oil 0.4.
The present embodiment weight unit used is kilogram, also can for gram.
The preparation method of the present embodiment refers to embodiment 1.
According to the < < disinfection technology standard > > in 2002 of the Ministry of Health, the sterilizing power of the washing machine tank antibacterial cleanser of the present embodiment is detected, to colibacillary killing rate be 99.99%, streptococcus aureus killing rate is 99.95%, the killing rate of Candida albicans is 95.6%.
embodiment 7
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of described each raw material is:
Sodium sulfate 41
Sodium-chlor 40
Xylo-Mucine 0.6
EDTA-2Na 2
Aliphatic alcohol polyethenoxy (3) ether 7
Aliphatic alcohol polyethenoxy (9) ether 3
Two decyl alkyl dimethyl ammonium chlorides 6
Lavender oil 0.4.
The present embodiment weight unit used is kilogram, also can for gram.
The preparation method of the present embodiment refers to embodiment 1.
According to the < < disinfection technology standard > > in 2002 of the Ministry of Health, the sterilizing power of the washing machine tank antibacterial cleanser of the present embodiment is detected, to colibacillary killing rate be 99.99%, streptococcus aureus killing rate is 99.95%, the killing rate of Candida albicans is 95.6%.

Claims (10)

1. a washing machine tank antibacterial cleanser, it is characterized in that, the raw material of described sanitising agent comprises sodium sulfate, sodium-chlor, Xylo-Mucine, EDTA-2Na, nonionogenic tenside, two decyl alkyl dimethyl ammonium chloride and essence, and the ratio of weight and number of described each raw material is:
Sodium sulfate 30 ~ 50
Sodium-chlor 10 ~ 40
Xylo-Mucine 0.5 ~ 1
EDTA-2Na 0.5~2
Nonionogenic tenside 2 ~ 10
Two decyl alkyl dimethyl ammonium chlorides 5 ~ 10
Essence 0.2 ~ 0.4.
2. washing machine tank antibacterial cleanser according to claim 1, it is characterized in that, described nonionogenic tenside is one or more the mixture in aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
3. washing machine tank antibacterial cleanser according to claim 1, is characterized in that, described essence is lavender oil.
4. according to the washing machine tank antibacterial cleanser described in claim 1 ~ 3 any one, it is characterized in that, the ratio of weight and number of described each raw material is:
Sodium sulfate 42
Sodium-chlor 40
Xylo-Mucine 0.7
EDTA-2Na 1
Aliphatic alcohol polyethenoxy (3) ether 7
Aliphatic alcohol polyethenoxy (7) ether 2
Aliphatic alcohol polyethenoxy (9) ether 1
Two decyl alkyl dimethyl ammonium chlorides 6
Essence 0.3.
5. according to the washing machine tank antibacterial cleanser described in claim 1 ~ 3 any one, it is characterized in that, the ratio of weight and number of described each raw material is:
Sodium sulfate 48
Sodium-chlor 30
Xylo-Mucine 1
EDTA-2Na 0.6
Aliphatic alcohol polyethenoxy (3) ether 5
Aliphatic alcohol polyethenoxy (7) ether 4
Aliphatic alcohol polyethenoxy (9) ether 1
Two decyl alkyl dimethyl ammonium chlorides 10
Essence 0.4.
6. according to the washing machine tank antibacterial cleanser described in claim 1 ~ 3 any one, it is characterized in that, the ratio of weight and number of described each raw material is:
Sodium sulfate 40
Sodium-chlor 38
Xylo-Mucine 1
EDTA-2Na 1.7
Aliphatic alcohol polyethenoxy (7) ether 6
Aliphatic alcohol polyethenoxy (9) ether 4
Two decyl alkyl dimethyl ammonium chlorides 9
Essence 0.3.
7. according to the washing machine tank antibacterial cleanser described in claim 1 ~ 3 any one, it is characterized in that, the ratio of weight and number of described each raw material is:
Sodium sulfate 49
Sodium-chlor 28
Xylo-Mucine 1
EDTA-2Na 1.6
Aliphatic alcohol polyethenoxy (3) ether 5
Aliphatic alcohol polyethenoxy (7) ether 5
Two decyl alkyl dimethyl ammonium chlorides 10
Essence 0.4.
8. according to the washing machine tank antibacterial cleanser described in claim 1 ~ 3 any one, it is characterized in that, the ratio of weight and number of described each raw material is:
Sodium sulfate 44
Sodium-chlor 35
Xylo-Mucine 1
EDTA-2Na 1.6
Aliphatic alcohol polyethenoxy (7) ether 8
Aliphatic alcohol polyethenoxy (9) ether 2
Two decyl alkyl dimethyl ammonium chlorides 8
Essence 0.4.
9. according to the washing machine tank antibacterial cleanser described in claim 1 ~ 3 any one, it is characterized in that, the ratio of weight and number of described each raw material is:
Sodium sulfate 41
Sodium-chlor 40
Xylo-Mucine 0.6
EDTA-2Na 2
Aliphatic alcohol polyethenoxy (3) ether 7
Aliphatic alcohol polyethenoxy (9) ether 3
Two decyl alkyl dimethyl ammonium chlorides 6
Essence 0.4.
10. the preparation method of a washing machine tank antibacterial cleanser, it is characterized in that, the raw material of described sanitising agent comprises sodium sulfate, sodium-chlor, Xylo-Mucine, EDTA-2Na, nonionogenic tenside, two decyl alkyl dimethyl ammonium chloride and essence, and the ratio of weight and number of described each raw material is:
Sodium sulfate 30 ~ 50
Sodium-chlor 10 ~ 40
Xylo-Mucine 0.5 ~ 1
EDTA-2Na 0.5~2
Nonionogenic tenside 2 ~ 10
Two decyl alkyl dimethyl ammonium chlorides 5 ~ 10
Essence 0.2 ~ 0.4;
Described preparation method comprises the following steps:
1) after above-mentioned sodium sulfate and sodium-chlor are mixed, add described pair of decyl alkyl dimethyl ammonium chloride, mixing and stirring, obtains mixture A;
2) in said mixture A, add successively described Xylo-Mucine and EDTA-2Na, mixing and stirring, obtains mixture B;
3) in said mixture B, add described nonionogenic tenside and essence, stir, obtain described washing machine tank antibacterial cleanser.
CN201310723436.9A 2013-12-25 2013-12-25 A kind of washing machine tank antibacterial cleanser and preparation method thereof Active CN103666797B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105713744A (en) * 2016-01-26 2016-06-29 孟根森 Cleaning and treating agent for textile fabrics
CN106350253A (en) * 2016-08-23 2017-01-25 余姚市德派日用品有限公司 Washing machine cleaning tablet and preparation method thereof
CN106497687A (en) * 2016-11-01 2017-03-15 青岛海澄知识产权事务有限公司 A kind of cleaning agent
CN106544158A (en) * 2016-11-01 2017-03-29 青岛净世家环保技术有限公司 A kind of mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing
CN106675827A (en) * 2016-12-24 2017-05-17 叶宗瑞 Washing machine tank cleaning agent and preparation method thereof

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Publication number Priority date Publication date Assignee Title
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CN101070512A (en) * 2006-05-12 2007-11-14 上海家化联合股份有限公司 Washine-machine chute detergent
CN101210212A (en) * 2006-12-29 2008-07-02 上海和黄白猫有限公司 Special-purpose cleaning agent for washing machine
CN103131542A (en) * 2013-03-20 2013-06-05 广州立白企业集团有限公司 Active oxygen washing machine tank cleaning agent and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1524941A (en) * 2003-02-28 2004-09-01 薛舜明 Cleaning agent of washing machine interlayer
CN1796520A (en) * 2004-12-20 2006-07-05 张捷 Purificant dedicated to washing machine
CN1796521A (en) * 2004-12-28 2006-07-05 海尔科化工程塑料国家工程研究中心股份有限公司 Purificant dedicated to barrel type washing machine
CN101070512A (en) * 2006-05-12 2007-11-14 上海家化联合股份有限公司 Washine-machine chute detergent
CN101210212A (en) * 2006-12-29 2008-07-02 上海和黄白猫有限公司 Special-purpose cleaning agent for washing machine
CN103131542A (en) * 2013-03-20 2013-06-05 广州立白企业集团有限公司 Active oxygen washing machine tank cleaning agent and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105713744A (en) * 2016-01-26 2016-06-29 孟根森 Cleaning and treating agent for textile fabrics
CN106350253A (en) * 2016-08-23 2017-01-25 余姚市德派日用品有限公司 Washing machine cleaning tablet and preparation method thereof
CN106497687A (en) * 2016-11-01 2017-03-15 青岛海澄知识产权事务有限公司 A kind of cleaning agent
CN106544158A (en) * 2016-11-01 2017-03-29 青岛净世家环保技术有限公司 A kind of mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing
CN106675827A (en) * 2016-12-24 2017-05-17 叶宗瑞 Washing machine tank cleaning agent and preparation method thereof

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Denomination of invention: A washing machine slot antibacterial cleaning agent and its preparation method

Effective date of registration: 20230323

Granted publication date: 20150930

Pledgee: Shanghai Rural Commercial Bank Co.,Ltd. Qingpu sub branch

Pledgor: SHANGHAI LVSAN INVI-TECH DEVELOPMENT Co.,Ltd.

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