CN109234062A - A kind of environmentally-friendly water-based hard surface antibacterial cleanser and its preparation method and application - Google Patents
A kind of environmentally-friendly water-based hard surface antibacterial cleanser and its preparation method and application Download PDFInfo
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- CN109234062A CN109234062A CN201810959655.XA CN201810959655A CN109234062A CN 109234062 A CN109234062 A CN 109234062A CN 201810959655 A CN201810959655 A CN 201810959655A CN 109234062 A CN109234062 A CN 109234062A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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Abstract
The invention discloses a kind of environmentally-friendly water-based hard surface antibacterial cleansers and its preparation method and application, belong to detergent technical field.It is made of raw material from the following weight: 2-5 parts of antibacterial agent；5-15 parts of cosolvent；10-20 parts of amphoteric surfactant；10-20 parts of anionic surfactant；1-10 parts of chelating agent；40-70 parts of deionized water；Antibacterial agent is selected from one of zinc Isoocatanoate, zinc undecylenate and undecenoic acid single ethanol amide or several；Anionic surfactant is selected from one or more of sodium lauroyl glutamate, lauroyl glutamate potassium, sodium cocoyl glutamate, cocounut oil acyl potassium glutamate, cocoyl sarcosine sodium, cocoyl sarcosine potassium and Hamposyl L triethanolamine salt.Antibacterial cleanser provided by the invention is green safe, asepsis environment-protecting, no pollution to the environment, there is cleaning and antibiotic and sterilizing double effects, all has preferable killing to Conventional bacteria and mould and inhibitory effect, persistent have wide range of applications.
Description
Technical field
The invention belongs to detergent technical field, specifically disclose a kind of environmentally-friendly water-based hard surface antibacterial cleanser and
Preparation method and application, the detergent are mainly used for the cleaning and disinfection of floor, toilet and household plastic articles etc..
Background technique
With the development of the times, various aqueous detergent comes into being in the market, but dosage is most in detergent at present
More surfactants is sodium alkyl sulfonate, and sodium alkyl benzene sulfonate, degradability is poor, and residual quantity is big, and with other pollutants
Dispersion colloid particle easy to form together, phosphate builder are easy to make water eutrophication, cause environmental pollution.
Meanwhile sterilizing this concept and having goed deep into each consumer at heart, thimerosal ingredient currently on the market is containing chlorine
Thimerosal, zephiran, Dialkyl dimethyl ammonium chloride etc..
Such as application No. is the patents of CN201210053059.8 to disclose a kind of hard surface cleaner with biocidal efficacies,
Its main component and its mass fraction are as follows: 1-15 parts of nonionic surfactant, 1-10 parts of zwitterionic surfactant, sterilization
1-4 parts of agent, 0.1-1 parts of chelating agent.Fungicide is preferably dimercaptodimethyl ammonium chloride and zephiran two
Kind compound quaternary ammonium salt.
Such as application No. is the patents of CN201480065499.2 to disclose a kind of hard surface Bactericidal cleaner composition,
Wherein, containing 0.5 mass % of following compositions (a) or more and 3 mass % or less, 0 .5 mass % of ingredient (b) or more and 10 mass % with
Under, 1 mass % of ingredient (c) or more and 8 mass % or less and ingredient (d), ratio of the ingredient (a) in all surfaces activating agent
For 65 mass % or more, and pH value of the composition at 25 DEG C is 2 or more and 6 hereinafter, ingredient (a): betaine type amphoteric surface
Ingredient (b): activating agent is preferably selected from the compound of benzyl alcohol and benzyl carbinol, ingredient (c): chelating agent, ingredient (d): water.
Ingredient (a) is preferably anionic surfactant, such as alkylbenzene sulfonate, alkyl or alkenyl sulfuric acid, polyoxy alkylidene alkane
Base or alkene ether sulfuric acid, alkene sulfonate, alkyl sulfonate, fatty acid salt, polyoxyalkylene alkyl or alkenyl ether carboxylate,
Alpha-olefin fatty acid salt and its ester etc..
These thimerosals not only itself have niff, stronger corrosivity, and it is to most of moulds, fungi
Bactericidal effect it is poor and water-soluble antiseptic agent is lost with the loss of dampening and makes bactericidal effect not lasting, itself is also right
Environment has pollution.Therefore, it is badly in need of a kind of long-term antibacterial detergent of green safe environmental protection in the market.
Summary of the invention
To solve the above-mentioned problems, an object of the present invention is to provide a kind of environmentally-friendly water-based hard surface antibiotic cleaning
Agent, the cleaning agent have environmentally protective, no pollution to the environment non-stimulated to human body, clean effect is good and disinfection effect is held
It waits so long advantage；The second object of the present invention is to provide the preparation method of the antibacterial cleanser, and this method is simple；The purpose of the present invention
Three be that the application of the antibacterial cleanser is provided.The scheme is as follows:
On the one hand, the embodiment of the invention provides a kind of environmentally-friendly water-based hard surface antibacterial cleansers, by following parts by weight
Raw material is made:
2-5 parts of antibacterial agent；
5-15 parts of cosolvent；
8-20 parts of amphoteric surfactant；
10-20 parts of anionic surfactant；
1-10 parts of chelating agent；
40-70 parts of deionized water；
Wherein, antibacterial agent is selected from one of zinc Isoocatanoate, zinc undecylenate and undecenoic acid single ethanol amide etc. or several；
The antibacterial agent all has good antibacterium, fungi effect, and is insoluble in water, this antibacterial cleaning agent developed for us
Lasting bactericidal effect have special effect instead.
Wherein, anionic surfactant is selected from sodium lauroyl glutamate, lauroyl glutamate potassium, cocounut oil acyl glutamic acid
In sodium, cocounut oil acyl potassium glutamate, cocoyl sarcosine sodium, cocoyl sarcosine potassium and Hamposyl L triethanolamine salt etc.
It is one or more of.The anionic surfactant that the present invention uses is a kind of novel amino acid surfactant, can be complete
Biodegrade, no pollution to the environment have mild decontamination, while having antibiotic and sterilizing, mildew resistance；We send out simultaneously
Existing its has good emulsification to our antibacterial agent (especially zinc undecylenate), need to only add on a small quantity, can make
Remaining a small amount of undissolved antibacterial agent whole solubilization is become colorless aqueous solution when standby.
Preferably, the antibacterial agent in the embodiment of the present invention is zinc undecylenate.
Wherein, the cosolvent in the embodiment of the present invention is selected from ethyl alcohol, isopropanol, butanol, ethylene glycol, propylene glycol and benzene oxygen second
One of alcohol etc. is a variety of.Aforementioned cosolvent has preferable solubilization to antibacterial agent of the invention.
Preferably, the cosolvent in the embodiment of the present invention is selected from one of butanol, ethylene glycol, propylene glycol and Phenoxyethanol
Or it is a variety of.
Wherein, the amphoteric surfactant in the embodiment of the present invention is selected from Cocoamidopropyl betaine, coconut oleoyl amine third
One of base hydroxyl sulfo betaine and lauroyl both sexes base diethyl acid disodium etc. are a variety of.The amphoteric surface that the present invention uses
Activating agent is mild amphoteric surfactant, and this kind of amphoteric surfactant all has excellent under acid and alkaline condition
Stability, irritation is small, to ph stability, strong detergency, has good cleaning action；And itself has good kill
Bacterium effect, can kill most of bacterium, act synergistically with the antibacterial agent in this patent, have preferably sterilization synergistic effect, greatly
Its bactericidal range is expanded greatly.
Preferably, the amphoteric surfactant in the embodiment of the present invention is selected from Cocoamidopropyl betaine and coconut oleoyl amine
One of hydroxysultaine is a variety of.
Preferably, the anionic surfactant in the embodiment of the present invention is selected from sodium lauroyl glutamate, cocounut oil acyl paddy ammonia
One of sour sodium, cocoyl sarcosine sodium and Hamposyl L triethanolamine salt are a variety of.
Wherein, the chelating agent in the embodiment of the present invention is selected from disodium ethylene diamine tetraacetate, sodium citrate and sodium gluconate
Deng one of or it is a variety of.
Preferably, the environmentally-friendly water-based hard surface antibacterial cleanser in the embodiment of the present invention by following parts by weight raw material
It is made:
2-4 parts of antibacterial agent；
8-12.5 parts of cosolvent；
8-15 parts of amphoteric surfactant；
10-20 parts of anionic surfactant；
2-3 parts of chelating agent；
54-70 parts of deionized water；
Wherein, antibacterial agent is selected from one of zinc Isoocatanoate, zinc undecylenate and undecenoic acid single ethanol amide or several；It helps
Solvent is selected from one of butanol, ethylene glycol, propylene glycol and Phenoxyethanol or a variety of；Anionic surfactant is selected from lauroyl
One of sodium glutamate, cocoyl sarcosine sodium and Hamposyl L triethanolamine salt are a variety of；Amphoteric surfactant
Selected from one of Cocoamidopropyl betaine and cocamidopropyl propyl amide hydroxyl sulfo betaine or a variety of；Chelating agent is selected from second
One of edetate disodium, sodium citrate and sodium gluconate are a variety of.
Aforementioned each component is all made of ep-type material, and the overwhelming majority is degradable, frees from extraneous odour, nonirritant.
On the other hand, the embodiment of the invention also provides the preparation sides of the environmentally-friendly water-based hard surface antibacterial cleanser
Method makes most of powder (main this method comprises: antibacterial agent, cosolvent and amphoteric surfactant are added according to the ratio under stirring
It is antibacterial agent) dissolution, then anionic surfactant and deionized water are added according to the ratio, continue stirring to powder and be completely dissolved,
Chelating agent is finally added according to the ratio, stirs evenly up to product.Preparation method provided by the invention is simple, and obtained product can be through
Water dilution, Direct spraying uses, low in cost.
Another aspect, the embodiment of the invention also provides the applications of the environmentally-friendly water-based hard surface antibacterial cleanser, use
It in the cleaning and disinfection of floor, toilet and household plastic articles etc., has wide range of applications, will not corrode or damage hard surface
Or the coating of hard surface, and antibacterial agent not soluble in water is attached to hard surface to guarantee its long-acting, especially can be with
Guarantee that the hard surfaces such as floor are not mouldy for a long time.
In short, detergent provided by the invention is green safe, asepsis environment-protecting, no pollution to the environment has cleaning to disappear with antibacterial
Malicious double effects all have preferable killing to Conventional bacteria and mould and inhibitory effect, persistent have wide range of applications,
It can be applied to Domestic floor, toilet, the cleaning and disinfection of household plastic articles etc..
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, embodiment of the present invention is made below further
Ground detailed description.
1 sample of embodiment
Embodiment 1 provides a kind of environmentally-friendly water-based hard surface antibacterial cleanser, is made of the raw material of following parts by weight:
2.5 parts of zinc undecylenate
12.5 parts of Phenoxyethanol
12.5 parts of cocamidopropyl betaine
10 parts of sodium lauroyl glutamate
2 parts of EDETATE SODIUM
60.5 parts of deionized water.
The present embodiment into reaction kettle the preparation method is as follows: sequentially add antibacterial agent (zinc undecylenate), cosolvent first
(Phenoxyethanol) and amphoteric surfactant (cocamidopropyl betaine), stirring down toward most of powder dissolve, in addition plus
Enter anionic surfactant (sodium lauroyl glutamate) and deionized water, continues stirring and completely disappeared to powder, finally added
A small amount of chelating agent (EDETATE SODIUM) stirs evenly up to product, and product is transparent and homogeneous solution, and long time without deposit generates.
2 sample of embodiment
Embodiment 2 provides a kind of environmentally-friendly water-based hard surface antibacterial cleanser, is made of the raw material of following parts by weight:
2 parts of zinc undecylenate
8 parts of butanol
8 parts of cocamidopropyl betaine
10 parts of sodium lauroyl glutamate
2 parts of EDETATE SODIUM
70 parts of deionized water.
Preparation method is same as Example 1, and product is transparent and homogeneous solution, and long time without deposit generates.
3 sample of embodiment
Embodiment 3 provides a kind of environmentally-friendly water-based hard surface antibacterial cleanser, is made of the raw material of following parts by weight:
2 parts of zinc Isoocatanoate
8 parts of butanol
8 parts of cocamidopropyl betaine
15 parts of cocoyl sarcosine sodium
2 parts of sodium gluconate
65 parts of deionized water.
Preparation method is same as Example 1, and product is transparent and homogeneous solution, and long time without deposit generates.
4 sample of embodiment
Embodiment 4 provides a kind of environmentally-friendly water-based hard surface antibacterial cleanser, is made of the raw material of following parts by weight:
4 parts of zinc undecylenate
8 parts of Phenoxyethanol
8 parts of cocamidopropyl propyl amide hydroxyl sulfo betaine
20 parts of sodium lauroyl glutamate
3 parts of sodium citrate
57 parts of deionized water.
Preparation method is same as Example 1, and product is transparent and homogeneous solution, and long time without deposit generates.
5 sample of embodiment is 5.
Embodiment 5 provides a kind of environmentally-friendly water-based hard surface antibacterial cleanser, is made of the raw material of following parts by weight:
4 parts of undecenoic acid single ethanol amide
12 parts of Phenoxyethanol
10 parts of cocamidopropyl propyl amide hydroxyl sulfo betaine
10 parts of sodium lauroyl glutamate
3 parts of sodium gluconate
61 parts of deionized water.
Preparation method is same as Example 1.
6 sample of embodiment is 6.
Embodiment 6 provides a kind of environmentally-friendly water-based hard surface antibacterial cleanser, is made of the raw material of following parts by weight:
4 parts of zinc undecylenate
12 parts of ethylene glycol
10 parts of Cocoamidopropyl betaine
10 parts of cocoyl sarcosine sodium
3 parts of sodium gluconate
61 parts of deionized water.
Preparation method is same as Example 1, and product is transparent and homogeneous solution, and long time without deposit generates.
7 sample of embodiment is 7.
Implement 7 and provide a kind of environmentally-friendly water-based hard surface antibacterial cleanser, is made of the raw material of following parts by weight:
3 parts of isoolefine acid zinc
10 parts of propylene glycol
15 parts of Cocoamidopropyl betaine
15 parts of Hamposyl L triethanolamine salt
3 parts of EDETATE SODIUM
54 parts of deionized water.
Preparation method is same as Example 1.
Verify example
The test of 1.1 antibiotic properties
Experimental method is executed according to GB/T15979-2012, test multiple samples its to the minimum of common bacteria, fungi and mould
Bacteriocidal concentration, table 1 are the minimum bactericidal concentrations (ppm) of sterilizing detergent for cleaning of the invention:
Table 1
| Sample number into spectrum | ① | ② | ③ | ④ | ⑤ | ⑥ | ⑦ |
| Staphylococcus aureus | 64 | 80 | 120 | 80 | 80 | 74 | 83 |
| Escherichia coli | 32 | 40 | 40 | 80 | 80 | 56 | 75 |
| Pseudomonas aeruginosa | 24 | 32 | 32 | 40 | 40 | 32 | 36 |
| Candida albicans | 8 | 16 | 16 | 8 | 10 | 15 | 12 |
| Aspergillus flavus | 3.2 | 8 | 8 | 16 | 16 | 11 | 8.5 |
Table 1 the result shows that, antibacterial cleaning agent provided by the invention have extensive bacteriostasis property, to Gram-positive and gram
Negative bacterium has certain inhibiting effect, especially makees to moulds such as Aspergillus flavus and Candida albicans with extremely strong inhibition
With.
The bacteriostasis property test of 1.2 pairs of common moulds
2 sample of table(10% dilution) to the bacteriostasis property of common mould, the results are shown in Table 2:
Table 2
By the content of above-mentioned table 2 it is found that bacteriostasis property is excellent after the antibacterial cleanser that this patent provides is diluted 10: 1.
The test of 1.3 detergency abilities
Antibacterial cleanser provided by the invention (10 times of spray clean floor tests of dilution) is tested with the current product in market in decontamination
Performance comparison in terms of power, test method are executed according to GB/T4532-2013,15cm × 15cm ceramic coated steel plate, check weighing
W1, the dirt of one layer about 20 grams of coating, roast 1 hour, check weighing W2 at 200 DEG C on steel plate, 5 grams of detergents are uniformly sprayed shine in
On steel plate, places 2 hours, then rinsed in the case where 60 DEG C of hot water are flowed with sponge at room temperature, baking oven drying, check weighing W3.By weight
Method obtains soil removal efficiency.Above-mentioned dirt is by 50wt% chicken fat, 20wt% vegetable oil, 20wt% stearic acid, 5wt% catsup and 5wt%
Grain sugar composition；Soil removal efficiency=[(W2-W3)/(W2-W1)] × 100%, the results are shown in Table 3:
Table 3
| Sample number into spectrum | ① | ② | ③ | ⑤ | ⑦ | Commercially available product 1 | Commercially available product 2 |
| Soil removal efficiency (%) | 95.22 | 91.36 | 93.24 | 94.33 | 92.51 | 82.86 | 84.57 |
From the point of view of appearance, floor spot can be effectively removed, does not damage the original protective layer in floor；From the decontamination data in table 3 also table
Its bright product clean effect more current than market is more preferable.
The test of 1.4 permanences
The antibacterial cleanser that Example 1-5 is provided respectively is diluted 5-10 times, is put into vacuum after sample plank is impregnated 2 days
60 DEG C of drying box vacuum drying use undecenoic acid Zn content on titration test plank, again will be wooden after 120 days for A
Plate is put into clear water immersion, and it is B that 11 sad Zn contents are surveyed after same vacuum drying, the loss late of zinc undecylenate be S loss late=
(1-B/A) * 100, the results are shown in Table 4:
Table 4
| Sample number into spectrum | ① | ② | ③ | ④ | ⑤ | ⑥ | ⑦ |
| Fungicide loss late (%) | 2 | 2.4 | 1.8 | 2.6 | 2.8 | 2.2 | 2.5 |
Can be seen that antibacterial cleaning agent provided by the invention from the data of table 4, its sterilization component loss late is smaller after three months,
Below 5%.The loss late of fungicide is small, and resistance leachability is strong, its long-term antibacterial is mould proof to provide guarantee to play, and shows its tool
There is antibacterial permanence.
1.5 irritation test
Using sensory evaluation method, 49 testers are equally divided into 7 groups, give test group sample at random by " double blind " experiment
Product, it is desirable that tester, by smell and peculiar smell and irritation, feeling of the tester according to oneself are evaluated in directly contact respectively
It scores, removes best result and minimum point, calculate dividing equally for one group of remaining 5 tester；Wherein, 1 point is best, and 5
It is divided into worst, Analyses Methods for Sensory Evaluation Results is as follows:
Table 5
| Sample number into spectrum | ① | ② | ③ | ④ | ⑤ | ⑥ | ⑦ | Commercially available product 1 | Commercially available product 2 |
| Peculiar smell | 1.4 | 1.6 | 1.4 | 1.5 | 1.4 | 1.5 | 1.5 | 2.1 | 2.4 |
| Irritation | 1.2 | 1.3 | 1.3 | 1.3 | 1.2 | 1.3 | 1.2 | 1.6 | 1.7 |
As can be seen from Table 5, the peculiar smell of antibacterial cleanser provided by the invention and irritation are low compared with conventional products.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of environmentally-friendly water-based hard surface antibacterial cleanser, which is characterized in that be made of raw material from the following weight:
2-5 parts of antibacterial agent；
5-15 parts of cosolvent；
8-20 parts of amphoteric surfactant；
10-20 parts of anionic surfactant；
1-10 parts of chelating agent；
40-70 parts of deionized water；
The antibacterial agent is selected from one of zinc Isoocatanoate, zinc undecylenate and undecenoic acid single ethanol amide or several；
The anionic surfactant is selected from sodium lauroyl glutamate, lauroyl glutamate potassium, sodium cocoyl glutamate, cocounut oil
One of acyl potassium glutamate, cocoyl sarcosine sodium, cocoyl sarcosine potassium and Hamposyl L triethanolamine salt are several
Kind.
2. environmentally-friendly water-based hard surface antibacterial cleanser according to claim 1, which is characterized in that the cosolvent choosing
From one of ethyl alcohol, isopropanol, butanol, ethylene glycol, propylene glycol and Phenoxyethanol or a variety of.
3. environmentally-friendly water-based hard surface antibacterial cleanser according to claim 1, which is characterized in that the cosolvent choosing
From one of butanol, ethylene glycol, propylene glycol and Phenoxyethanol or a variety of.
4. environmentally-friendly water-based hard surface antibacterial cleanser according to claim 1, which is characterized in that the amphoteric surface
Activating agent is selected from Cocoamidopropyl betaine, cocamidopropyl propyl amide hydroxyl sulfo betaine and lauroyl both sexes base oxalic acid two
One of sodium is a variety of.
5. environmentally-friendly water-based hard surface antibacterial cleanser according to claim 1, which is characterized in that the amphoteric surface
Activating agent is selected from one of Cocoamidopropyl betaine and cocamidopropyl propyl amide hydroxyl sulfo betaine or a variety of.
6. environmentally-friendly water-based hard surface antibacterial cleanser according to claim 1, which is characterized in that the anion table
Face activating agent is selected from sodium lauroyl glutamate, three ethyl alcohol of sodium cocoyl glutamate, cocoyl sarcosine sodium and Hamposyl L
One of amine salt is a variety of.
7. environmentally-friendly water-based hard surface antibacterial cleanser according to claim 1, which is characterized in that the chelating agent choosing
From one of disodium ethylene diamine tetraacetate, sodium citrate and sodium gluconate or a variety of.
8. environmentally-friendly water-based hard surface antibacterial cleanser according to claim 1, which is characterized in that by following parts by weight
Raw material be made:
2-4 parts of antibacterial agent；
8-12.5 parts of cosolvent；
8-15 parts of amphoteric surfactant；
10-20 parts of anionic surfactant；
2-3 parts of chelating agent；
54-70 parts of deionized water；
The antibacterial agent is selected from one of zinc Isoocatanoate, zinc undecylenate and undecenoic acid single ethanol amide or several；
The cosolvent is selected from one of butanol, ethylene glycol, propylene glycol and Phenoxyethanol or a variety of；
The anionic surfactant is selected from sodium lauroyl glutamate, sodium cocoyl glutamate, cocoyl sarcosine sodium and the moon
One of osmanthus acylsarcosine triethanolamine salt is a variety of；
The amphoteric surfactant is in Cocoamidopropyl betaine and cocamidopropyl propyl amide hydroxyl sulfo betaine
It is one or more；
The chelating agent is selected from one of disodium ethylene diamine tetraacetate, sodium citrate and sodium gluconate or a variety of.
9. such as the preparation method of the described in any item environmentally-friendly water-based hard surface antibacterial cleansers of claim 1-8, feature
It is, which comprises
Antibacterial agent, cosolvent and amphoteric surfactant are added according to the ratio, dissolves most of powder under stirring, then adds according to the ratio
Enter anionic surfactant and deionized water, continues stirring and be completely dissolved to powder, chelating agent is finally added according to the ratio, stir
Uniformly up to product.
10. such as the application of the described in any item environmentally-friendly water-based hard surface antibacterial cleansers of claim 1-8, feature exists
In cleaning and disinfection for floor, toilet and household plastic articles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810959655.XA CN109234062A (en) | 2018-08-22 | 2018-08-22 | A kind of environmentally-friendly water-based hard surface antibacterial cleanser and its preparation method and application |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111019778A (en) * | 2019-12-06 | 2020-04-17 | 铜陵麟安生物科技有限公司 | Greasy dirt removing wet tissue for kitchen |
| CN115746680A (en) * | 2022-11-29 | 2023-03-07 | 江苏扬瑞新材料有限公司 | Silicon-free gloss oil coating and preparation method thereof |
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| CN102051273A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Carpet cleaner |
| CN102618400A (en) * | 2012-03-02 | 2012-08-01 | 北京洛娃日化有限公司 | Hard surface cleaning agent with sterilizing effect |
| CN102660394A (en) * | 2012-05-09 | 2012-09-12 | 中航材航空新材料有限公司 | Water-based all-natural environment-friendly cleaning agent and preparation method thereof |
| CN106753894A (en) * | 2016-11-22 | 2017-05-31 | 青岛净世家环保技术有限公司 | A kind of degerming, sterilization, the preparation method of the floor cleaner of glazing maintenance |
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| CN102051273A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Carpet cleaner |
| CN102618400A (en) * | 2012-03-02 | 2012-08-01 | 北京洛娃日化有限公司 | Hard surface cleaning agent with sterilizing effect |
| CN102660394A (en) * | 2012-05-09 | 2012-09-12 | 中航材航空新材料有限公司 | Water-based all-natural environment-friendly cleaning agent and preparation method thereof |
| CN106753894A (en) * | 2016-11-22 | 2017-05-31 | 青岛净世家环保技术有限公司 | A kind of degerming, sterilization, the preparation method of the floor cleaner of glazing maintenance |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111019778A (en) * | 2019-12-06 | 2020-04-17 | 铜陵麟安生物科技有限公司 | Greasy dirt removing wet tissue for kitchen |
| CN111019778B (en) * | 2019-12-06 | 2021-12-14 | 铜陵麟安生物科技有限公司 | Kitchen degreasing method |
| CN115746680A (en) * | 2022-11-29 | 2023-03-07 | 江苏扬瑞新材料有限公司 | Silicon-free gloss oil coating and preparation method thereof |
| CN115746680B (en) * | 2022-11-29 | 2023-12-26 | 江苏扬瑞新材料有限公司 | Silicon-free gloss oil paint and preparation method thereof |
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