CN106544158A - A kind of mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing - Google Patents
A kind of mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing Download PDFInfo
- Publication number
- CN106544158A CN106544158A CN201610936447.9A CN201610936447A CN106544158A CN 106544158 A CN106544158 A CN 106544158A CN 201610936447 A CN201610936447 A CN 201610936447A CN 106544158 A CN106544158 A CN 106544158A
- Authority
- CN
- China
- Prior art keywords
- parts
- extract
- water
- aqueous solution
- washing machine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Abstract
The invention belongs to chemical preparing technical field，It is related to a kind of preparation method of washing machine cleaning agent，A kind of especially preparation method of the mould proof washing machine cleaning agent of antibiotic and sterilizing，For washing machine cleaning agent occasions that manufacture，Solve a difficult problem of the product without mould proof effect that preparation method is complicated and prepares，Concrete technology step is first by constituent part、During the water-soluble chilli extract of preparation and deionized water add reactor，30 minutes are stirred under normal temperature to being completely dissolved,Take in the obtained plant ash aqueous solution and purple perilla extract addition reactor，It is stirred until homogeneous,Continuously add constituent part,Stir,The achene of Siberian cocklebur aqueous solution for preparing and mint extract are added in remaining deionized water，It is stirred until homogeneous,Finally mixed solution is added in reactor，30 45 minutes are stirred when 40 DEG C，It is cooled to room temperature，Its overall preparation process is simple，Applied environment is friendly，With good economic benefit and market prospects.
Description
Technical field：
The invention belongs to chemical preparing technical field, is related to a kind of preparation method of washing machine cleaning agent, especially
It is a kind of preparation method of the mould proof washing machine cleaning agent of antibiotic and sterilizing, for washing machine cleaning agent occasions that manufacture.
Background technology：
Washing machine can adhere to one layer solid yellow or black on its inner tank theca (also referred to as interlayer) through prolonged use
Color dirt, or even mildew, which is mainly by five kinds into being grouped into：1st, in running water calcium ion and the incrustation scale of calcium carbonate composition；
2nd, the educt of detergent；3rd, the cellulose of clothing；4th, the organic substance of human body；5th, clothing is brought into dust and bacterium and other
Material；These dirts will pollute the secondary health for being broadcast to human body, threatening people, washing machine use time when cleaning washed
It is longer, the dirt of accumulation and germ it is more, the threat to human health is bigger, so periodically resisting to washing machine interlayer
The process of bacterium disinfection mould-proof is very necessary.
In the prior art, Chinese patent CN102517176B discloses a kind of Special tub lotion for washing machine, by component A,
B, C, D are mixed；Wherein component A is selected from one or more in hypochlorite, percarbonate, perborate；Component B is selected from
One or more in calcium oxide, NaOH, potassium oxide, sodium oxide molybdena；Component C selected from Nonionic surfactant OP series,
One or more during TX series, AEO are serial；Component D is a kind of or several in sodium metasilicate, stearic acid, dextrin, pregelatinized starch
Kind, although can be sterilized and clean effect is good, but without mould proof effect and bactericidal effect is poor；Chinese patent CN179652A is announced
A kind of purificant dedicated to barrel type washing machine, is obtained by the following raw material：Oxygen system cleaning agent, antiseptic 50-99 weight portions, basic mineral
Salts substances 0-50 weight portions, nonionic surfactant 0.1-25 weight portions, its 1% solution ph are more than 8, its scale removal effect
It is not good and do not possess mould proof effect；Chinese patent CN101591589A discloses a kind of interlayer of inner tank of washing machine of removing and cleans
Agent, with following formula (component and its percentage by weight %)：Higher alcohols sulfuric acid 10-12%, glycerol fatty acid ester 10-
15%th, alkyl-dimethyl benzyl group ammonium chloride 5-10%, excessively sodium hypochlorite 2-3%, carbon alkyd sodium 10-15%, sodium metasilicate 8-10%；It is raw
Thing enzyme preparation 2-3%, water softener 2-3%, soil suspender 2-3%, international essence is appropriate and purified water is to 100%, although
The formula has antibacterial, a decontamination, but formula constituent and preparation method are more complicated and without mould proof effect.
The content of the invention：
It is an object of the invention to overcome the shortcomings of that prior art is present, propose that a kind of mould proof washing machine of antibiotic and sterilizing is clear
Lotion preparation, solves a difficult problem of the product without mould proof effect that preparation method is complicated and prepares, and obtained product can be same
Shi Shixian cleanings, scale removal, antibacterial, sterilization, mould proof multiple efficacies, effectively remove the inside and outside cylinder attachment of current laundry machine, the dirt of accumulation
Stain and bacterium, eliminate the root of washing machine cross-infection, and Kathon CG, the sodium Diacetate and potassium sorbate compounding in raw material is than being 0.5:
3:1, PH less than 4 when anti-mold effect it is notable.
To achieve these goals, it is according to the present invention can be with each raw material of the mould proof washing machine cleaning agent of antibiotic and sterilizing
Components by weight percent is：2.5 parts of mould inhibitor, antiseptic 2-5.5 parts, disinfectant 4-4.5 parts, surfactant 5.5-10 parts, water solubility
Cosolvent 5-9 parts and deionized water 68.5-81 part, mixture of the mould inhibitor for Kathon CG, sodium Diacetate and potassium sorbate, institute
The mixture that antiseptic is the achene of Siberian cocklebur aqueous solution that mass ratio is 12.5% and peppermint extract is stated, the disinfectant is mass ratio
The mixture of the plant ash aqueous solution and purple perilla extract for 3%, the surfactant are DTAC,
The water-soluble co-solvents are the mixtures of the ethanol water that volume ratio is 95% and water-soluble chilli extract.
The concrete step of preparation process of the mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing according to the present invention is：
(1) prepare water-soluble chilli extract：Weigh that color is red, taste is peppery, moisture is low, without the chilli that goes mouldy, decontamination uses distilled water
Cleaning 3-5 time, is ground into graininess chilli powder, takes size and be put into container for less than 74 μm solid particulate matters after drying naturally
In, the ethanol water that volume ratio is 70% is added, feed liquid mass volume ratio is 1g:35ml, heat backflow 1 hour, takes supernatant,
Extract three times altogether, Jing distilled water concentration and recovery ethanol, obtain the aqueous solution of the thing to be extracted of muddiness, volume ratio is at 15 DEG C
8.5% ethyl acetate is extracted respectively to three parts of extracts, feed liquid mass volume ratio 1g:50ml, is washed after lipid layer with distillation,
By lipid layer distillating recovering solvent, red thick water-soluble chilli extract liquid is obtained, water-soluble chilli extract 1-4 parts are standby；
(2) mixed dissolution：First component by weight weighs commercially available DTAC 5.5-10 parts, volume ratio
95% ethanol water 3-6 parts, deionized water 68.5-81 part, Kathon CG 0.2-0.7 parts, sodium Diacetate 1.2-1.5 parts and sorb
Sour potassium 0.3-0.8 parts are standby；Again by DTAC 5.5-10 parts, the ethanol water 3-6 of volume ratio 95%
During the half of part, mixture 1-4 parts of water-soluble chilli extract and deionized water total amount adds reactor, setting temperature is normal temperature
Under, rotating speed is 1000 revs/min, and stirring 30 minutes is to being completely dissolved；
(3) prepare the plant ash aqueous solution：Taking 3 parts of fresh plant ash adds 7 parts of water to boil 1 hour, and natural cooling takes supernatant
It is standby, the plant ash aqueous solution that mass ratio is 3% is obtained final product, plant ash aqueous solution 2-4.5 parts that mass ratio is 3% is taken standby；Its
In, plant ash is the ash of agricultural crop straw or weeds after burning completely；
(4) prepare purple perilla extract：Fresh purple perilla stem and leaf are taken, decontamination, with distillation washing 3-5 time, dries in the shade, is put into
Soak 60 minutes in 60 DEG C of distilled water, with ethanol as Extraction solvent, solid-liquid ratio is 1g:40ml, circumfluence distillation three times, every time
2 hours, merge extract, the concentrated recovery ethanol of extract evaporates moisture, using spray drying, obtains extractive of perilla powder
End, the size-reduced machine of powder are crushed, and are sieved with rocking vibration sieve, take less than 74 μm particles, after blended device mixing 1 is little, take purple perilla
Extract 2-3 parts are standby；
(5) mix：Take step (3) and plant ash aqueous solution 2-4.5 parts that mass ratio obtained in step (4) is 3%
With purple perilla extract 2-3 parts, in adding reactor, continue to be stirred until homogeneous；Wherein, mass ratio is the 3% plant ash aqueous solution
Common 4-4.5 parts with the mixture of purple perilla extract；
(6) mix：Kathon CG 0.2-0.7 parts, sodium Diacetate 1.2-1.5 parts and sorbic acid are continuously added in a kettle.
Temperature of reaction kettle is set to 55 DEG C -60 DEG C by potassium 0.3-0.8 parts, and the reaction time is set to 10 minutes, stirs；Wherein, block
The mass ratio of active component CMIO and MIO in pine is 3: 1；Totally 2.5 parts of the mixture of Kathon CG, sodium Diacetate and potassium sorbate,
The compounding of Kathon CG, sodium Diacetate and potassium sorbate compares for 0.5:3:1；
(7) prepare xanthium sibiricum：Annual herb plant Siberian cocklebur bronzing fruit is taken, fruit side is with beak minister 12-
15mm, wide 4-7mm, decontamination, with distillation washing 3-5 time, dry naturally, are ground into graininess, take 2 parts of Siberian Cocklebur Fruits and be put into
In heating container, plus 7 parts of distilled water, after immersion 0.5 hour, is first boiled by fire, after be cooked by slow fire 0.5 hour, be cooled to room temperature, use
0.3mm screen filtrations；Residue adds 7 parts of distilled water, decocting method ibid, to be cooled to room temperature, uses 0.3mm screen filtrations；Residue is again
5 parts of distilled water, decocting method are added ibid, to be cooled to room temperature, use 0.3mm screen filtrations；Three filtrate mixing are concentrated by evaporation
To 8 parts, water decoction mass ratio is obtained for 25%, then by volume 1:1 adds distilled water, and prepared mass ratio is 12.5% achene of Siberian cocklebur
The aqueous solution, takes achene of Siberian cocklebur aqueous solution 0.8-3 parts standby；
(8) prepare mint extract：The cauline leaf of fresh mint is taken, impurity is removed, with distillation washing 2-3 time, is dried naturally,
Crushed after being dried, takes some peppermint powder and loads extraction kettle, and in extracting pressure position 9Mpa, extraction temperature is 50 DEG C, carbon dioxide
Under conditions of flow is 25L/h, extract 1.5 hours, peppermint extract is obtained, peppermint extract 0.8-3 parts is taken standby；
(9) mixed configuration：Achene of Siberian cocklebur aqueous solution 0.8-3 parts prepared by step (7) and step (8), mint extract
0.8-3 parts, in adding remaining deionized water, continue to be stirred until homogeneous；
(10) complete to prepare：Finally the mixed solution of step (9) is added in reactor, it is 40 DEG C to arrange temperature, is continued
30-45 minutes are sufficiently stirred for, room temperature is cooled to, the preparation of the mould proof washing machine cleaning agent of antibiotic and sterilizing is completed.
Kathon CG according to the present invention, English name is Isothiazolinones, abbreviation OIT, and chemical name is
(complete entitled 5-Chloro-2-Methyl-4-Isothiazolin-3-One, CIT are change to chloro- -3 ketone of -4 isothiazoline of 2 methyl of 5-
The abbreviation for studying point) and MIT (complete entitled 2-METHYL-4-ISOTHIAZOLIN-3-ONE, MI
For the abbreviation of chemical composition), be a kind of wide spectrum, efficiently, low toxicity, non-oxidizable mould inhibitor, can effectively kill algae, bacterium and true
Bacterium, effective dose are few, nontoxic pollution-free, are easily blended in all kinds of formulas, and PH use ranges are wide, after dilution use, can be by
It is biodegradable to kill the bacterium algae in glutinous mud through glutinous mud top layer for nontoxic pollution-free material, prevent the glutinous mud of cooling water system
Generate；Achene of Siberian cocklebur decoction has some bacteriostasis in vitro to staphylococcus aureus, and its acetone or alcohol extract is in vitro
Also there is bacteriostasis to Trichophyton rubrum；Mass ratio is that the 3% plant ash aqueous solution has disinfection efficacy to virus, bacterium；12
Alkyl trimethyl ammonium chloride is cationic surfactant, molecular formula:C15H34NCl, molecular weight:263.89, it is colourless or light
Yellow transparent colloid, water soluble and ethanol, have good compatibility, chemically stable with cation, nonionic surfactant
Good, the strong alkali-acid resistance of property, its strong detergency, chemical stability are good, sufficient raw, low production cost.
The mechanism of action of the mould proof washing machine cleaning agent of antibiotic and sterilizing according to the present invention is：Surfactant and cosolvent
Synergy takes out stains；Shitosan not only plays bactericidal action and can also prevent metal excessive erosion, with radiation-resisting functional, has
Certain sagging effect, is attached to the surface of cleaning of objects in cleaning showers, when extending relatively contact of the cleaning agent with dirt
Between, improve the efficiency of cleaning agent.
It is according to the present invention with the using method of the mould proof washing machine cleaning agent of antibiotic and sterilizing to be：Under normal temperature, by stoste
10 times of dilution, after cleaning showers 1-3 minutes, is cleaned with clear water.
Involved in the present invention can be with the main physical and chemical index of the mould proof washing machine cleaning agent of antibiotic and sterilizing：Outward appearance is colourless
Transparency liquid；Proportion is 1.03-1.08g/ml, and in terms of hydrochloric acid, acidity is 4-9%；Normal temperature stoste immersion 2h, rate of corrosion≤
0.1g/m2.h。
Compared with prior art, its raw material sources extensively, is suitable to industrialized production to the present invention；Can decontamination, scale removal, kill
Bacterium, sterilization are once completed, and scavenging period is short, and effect is good, and water-saving saves time, corrosion-free to equipment, is rinsed using rear Low-foam and easily, can give birth to
Thing degraded surfactant, safety and environmental protection, its overall preparation process is simple, preparation cost are low, and applied environment is friendly, with good
Economic benefit and market prospects.
Specific embodiment：
With reference to embodiment, the present invention will be further described.
Embodiment 1：
What the present embodiment was related to the components by weight percent of each raw material of the mould proof washing machine cleaning agent of antibiotic and sterilizing can be：It is mould proof
2.5 parts of agent, antiseptic 2-5.5 parts, disinfectant 4-4.5 parts, surfactant 5.5-10 parts, water-soluble co-solvents 5-9 parts and go
Ionized water 68.5-81 parts, mixture of the mould inhibitor for Kathon CG, sodium Diacetate and potassium sorbate, the antiseptic is quality
Than the mixture of the achene of Siberian cocklebur aqueous solution and peppermint extract for 12.5%, the disinfectant is the plant ash that mass ratio is 3%
The mixture of the aqueous solution and purple perilla extract, the surfactant are DTAC, and the water solubility helps
Solvent is the mixture of the ethanol water that volume ratio is 95% and water-soluble chilli extract；
The concrete step of preparation process of the mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing that the present embodiment is related to is：
(1) prepare water-soluble chilli extract：Weigh that color is red, taste is peppery, moisture is low, without the chilli that goes mouldy, decontamination uses distilled water
Cleaning 3-5 time, is ground into graininess chilli powder, takes size and be put into container for less than 74 μm solid particulate matters after drying naturally
In, the ethanol water that volume ratio is 70% is added, feed liquid mass volume ratio is 1g:35ml, heat backflow 1 hour, takes supernatant,
Extract three times altogether, Jing distilled water concentration and recovery ethanol, obtain the aqueous solution of the thing to be extracted of muddiness, volume ratio is at 15 DEG C
8.5% ethyl acetate is extracted respectively to three parts of extracts, feed liquid mass volume ratio 1g:50ml, is washed after lipid layer with distillation,
By lipid layer distillating recovering solvent, red thick water-soluble chilli extract liquid is obtained, water-soluble chilli extract 1-4 parts are standby；
(2) mixed dissolution：First component by weight weighs commercially available DTAC 5.5-10 parts, volume ratio
95% ethanol water 3-6 parts, deionized water 68.5-81 part, Kathon CG 0.2-0.7 parts, sodium Diacetate 1.2-1.5 parts and sorb
Sour potassium 0.3-0.8 parts are standby；Again by DTAC 5.5-10 parts, the ethanol water 3-6 of volume ratio 95%
During the half of part, mixture 1-4 parts of water-soluble chilli extract and deionized water total amount adds reactor, setting temperature is normal temperature
Under, rotating speed is 1000 revs/min, and stirring 30 minutes is to being completely dissolved；
(3) prepare the plant ash aqueous solution：Taking 3 parts of fresh plant ash adds 7 parts of water to boil 1 hour, and natural cooling takes supernatant
It is standby, the plant ash aqueous solution that mass ratio is 3% is obtained final product, plant ash aqueous solution 2-4.5 parts that mass ratio is 3% is taken standby；Its
In, plant ash is the ash of agricultural crop straw or weeds after burning completely；
(4) prepare purple perilla extract：Fresh purple perilla stem and leaf are taken, decontamination, with distillation washing 3-5 time, dries in the shade, is put into
Soak 60 minutes in 60 DEG C of distilled water, with ethanol as Extraction solvent, solid-liquid ratio is 1g:40ml, circumfluence distillation three times, every time
2 hours, merge extract, the concentrated recovery ethanol of extract evaporates moisture, using spray drying, obtains extractive of perilla powder
End, the size-reduced machine of powder are crushed, and are sieved with rocking vibration sieve, take less than 74 μm particles, after blended device mixing 1 is little, take purple perilla
Extract 2-3 parts are standby；
(5) mix：Take step (3) and plant ash aqueous solution 2-4.5 parts that mass ratio obtained in step (4) is 3%
With purple perilla extract 2-3 parts, in adding reactor, continue to be stirred until homogeneous；Wherein, mass ratio is the 3% plant ash aqueous solution
Common 4-4.5 parts with the mixture of purple perilla extract；
(6) mix：Kathon CG 0.2-0.7 parts, sodium Diacetate 1.2-1.5 parts and sorbic acid are continuously added in a kettle.
Temperature of reaction kettle is set to 55 DEG C -60 DEG C by potassium 0.3-0.8 parts, and the reaction time is set to 10 minutes, stirs；Wherein, block
The mass ratio of active component CMIO and MIO in pine is 3: 1；Totally 2.5 parts of the mixture of Kathon CG, sodium Diacetate and potassium sorbate,
The compounding of Kathon CG, sodium Diacetate and potassium sorbate compares for 0.5:3:1；
(7) prepare xanthium sibiricum：Annual herb plant Siberian cocklebur bronzing fruit is taken, fruit side is with beak minister 12-
15mm, wide 4-7mm, decontamination, with distillation washing 3-5 time, dry naturally, are ground into graininess, take 2 parts of Siberian Cocklebur Fruits and be put into
In heating container, plus 7 parts of distilled water, after immersion 0.5 hour, is first boiled by fire, after be cooked by slow fire 0.5 hour, be cooled to room temperature, use
0.3mm screen filtrations；Residue adds 7 parts of distilled water, decocting method ibid, to be cooled to room temperature, uses 0.3mm screen filtrations；Residue is again
5 parts of distilled water, decocting method are added ibid, to be cooled to room temperature, use 0.3mm screen filtrations；Three filtrate mixing are concentrated by evaporation
To 8 parts, water decoction mass ratio is obtained for 25%, then by volume 1:1 adds distilled water, and prepared mass ratio is 12.5% achene of Siberian cocklebur
The aqueous solution, takes achene of Siberian cocklebur aqueous solution 0.8-3 parts standby；
(8) prepare mint extract：The cauline leaf of fresh mint is taken, impurity is removed, with distillation washing 2-3 time, is dried naturally,
Crushed after being dried, takes some peppermint powder and loads extraction kettle, and in extracting pressure position 9Mpa, extraction temperature is 50 DEG C, carbon dioxide
Under conditions of flow is 25L/h, extract 1.5 hours, peppermint extract is obtained, peppermint extract 0.8-3 parts is taken standby；
(9) mixed configuration：Achene of Siberian cocklebur aqueous solution 0.8-3 parts prepared by step (7) and step (8), mint extract
0.8-3 parts, in adding remaining deionized water, continue to be stirred until homogeneous；
(10) complete to prepare：Finally the mixed solution of step (9) is added in reactor, it is 40 DEG C to arrange temperature, is continued
30-45 minutes are sufficiently stirred for, room temperature is cooled to, the preparation of the mould proof washing machine cleaning agent of antibiotic and sterilizing is completed.
Claims (1)
1. the mould proof washing machine cleaning agent preparation method of a kind of antibiotic and sterilizing, it is characterised in that concrete technology step is：
(1) prepare water-soluble chilli extract：Weigh that color is red, taste is peppery, moisture is low, without the chilli that goes mouldy, decontamination is cleaned with distilled water
3-5 time, graininess chilli powder after drying naturally, is ground into, takes size and be put in container for less than 74 μm solid particulate matters,
The ethanol water that volume ratio is 70% is added, feed liquid mass volume ratio is 1g:35ml, heat backflow 1 hour, takes supernatant, altogether
Extract three times, Jing distilled water concentration and recovery ethanol, obtain the aqueous solution of the thing to be extracted of muddiness, volume ratio is at 15 DEG C
8.5% ethyl acetate is extracted respectively to three parts of extracts, feed liquid mass volume ratio 1g:50ml, is washed after lipid layer with distillation,
By lipid layer distillating recovering solvent, red thick water-soluble chilli extract liquid is obtained, water-soluble chilli extract 1-4 parts are standby；
(2) mixed dissolution：First component by weight weighs DTAC 5.5-10 parts, the ethanol of volume ratio 95%
Aqueous solution 3-6 parts, deionized water 68.5-81 part, Kathon CG 0.2-0.7 parts, sodium Diacetate 1.2-1.5 parts and potassium sorbate 0.3-
0.8 part standby；Again by DTAC 5.5-10 parts, ethanol water 3-6 parts of volume ratio 95%, water solubility
During mixture 1-4 parts of chilli extract and the half of deionized water total amount add reactor, it is that rotating speed is under normal temperature to arrange temperature
1000 revs/min, stirring 30 minutes is to being completely dissolved；
(3) prepare the plant ash aqueous solution：Taking 3 parts of fresh plant ash adds 7 parts of water to boil 1 hour, and it is standby that natural cooling takes supernatant,
The plant ash aqueous solution that mass ratio is 3% is obtained final product, plant ash aqueous solution 2-4.5 parts that mass ratio is 3% is taken standby；Wherein, grass
Wood ash is the ash of agricultural crop straw or weeds after burning completely；
(4) prepare purple perilla extract：Fresh purple perilla stem and leaf are taken, decontamination, with distillation washing 3-5 time, dries in the shade, is put into 60 DEG C
Distilled water in soak 60 minutes, with ethanol as Extraction solvent, solid-liquid ratio is 1g:40ml, circumfluence distillation three times, 2 is little every time
When, merging extract, the concentrated recovery ethanol of extract evaporates moisture, using spray drying, obtains extractive of perilla powder,
The size-reduced machine of powder is crushed, and is sieved with rocking vibration sieve, is taken less than 74 μm particles, after blended device mixing 1 is little, is taken purple perilla extraction
Liquid 2-3 parts are standby；
(5) mix：Take step (3) and plant ash aqueous solution 2-4.5 parts that mass ratio obtained in step (4) is 3% and purple
Soviet Union's extract 2-3 parts, in adding reactor, continue to be stirred until homogeneous；Wherein, mass ratio is the 3% plant ash aqueous solution and purple
Common 4-4.5 parts of mixture of Soviet Union's extract；
(6) mix：Kathon CG 0.2-0.7 parts, sodium Diacetate 1.2-1.5 parts and potassium sorbate are continuously added in a kettle.
Temperature of reaction kettle is set to 55 DEG C -60 DEG C by 0.3-0.8 parts, and the reaction time is set to 10 minutes, stirs；Wherein, Kathon CG
In active component CMIO and MIO mass ratio be 3: 1；Totally 2.5 parts of the mixture of Kathon CG, sodium Diacetate and potassium sorbate, card
The compounding of pine, sodium Diacetate and potassium sorbate compares for 0.5:3:1；
(7) prepare xanthium sibiricum：Take annual herb plant Siberian cocklebur bronzing fruit, decontamination, with distillation washing 3-5
Time, dry naturally, be ground into graininess, take 2 parts of Siberian Cocklebur Fruits and be put in heating container, plus 7 parts of distilled water, soak 0.5 little
Shi Hou, is first boiled by fire, after be cooked by slow fire 0.5 hour, be cooled to room temperature, use 0.3mm screen filtrations；Residue adds 7 parts of distilled water, decocts
Boil method ibid, be cooled to room temperature, use 0.3mm screen filtrations；Residue adds 5 parts of distilled water, and decocting method ibid, is cooled to
Room temperature, uses 0.3mm screen filtrations；Three filtrate mixing are concentrated by evaporation to 8 parts, it is 25% to obtain water decoction mass ratio, then is pressed
Volume ratio 1:1 adds distilled water, and prepared mass ratio is 12.5% achene of Siberian cocklebur aqueous solution, takes achene of Siberian cocklebur aqueous solution 0.8-3 parts standby；
(8) prepare mint extract：The cauline leaf of fresh mint is taken, impurity is removed, with distillation washing 2-3 time, is dried naturally, is dried
After crush, take some peppermint powder and load extraction kettles, in extracting pressure position 9Mpa, extraction temperature is 50 DEG C, carbon dioxide flow
Under conditions of 25L/h, extract 1.5 hours, peppermint extract is obtained, peppermint extract 0.8-3 parts is taken standby；
(9) mixed configuration：Achene of Siberian cocklebur aqueous solution 0.8-3 parts prepared by step (7) and step (8), mint extract 0.8-3
Part, in adding remaining deionized water, continue to be stirred until homogeneous；
(10) complete to prepare：Finally the mixed solution of step (9) is added in reactor, it is 40 DEG C to arrange temperature, continues abundant
Stirring 30-45 minutes, room temperature is cooled to, the preparation of the mould proof washing machine cleaning agent of antibiotic and sterilizing is completed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610936447.9A CN106544158A (en) | 2016-11-01 | 2016-11-01 | A kind of mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610936447.9A CN106544158A (en) | 2016-11-01 | 2016-11-01 | A kind of mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106544158A true CN106544158A (en) | 2017-03-29 |
Family
ID=58392821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610936447.9A Pending CN106544158A (en) | 2016-11-01 | 2016-11-01 | A kind of mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106544158A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2299926A1 (en) * | 1999-03-03 | 2000-09-03 | Henkel Kommanditgesellschaft Auf Aktien | A process for the production of multiphase detergent tablets |
| CN1796521A (en) * | 2004-12-28 | 2006-07-05 | 海尔科化工程塑料国家工程研究中心股份有限公司 | Purificant dedicated to barrel type washing machine |
| CN1861773A (en) * | 2006-06-09 | 2006-11-15 | 上海制皂有限公司 | Cleaning agent for washing machine tank |
| CN101744207A (en) * | 2010-02-25 | 2010-06-23 | 周顺 | Method for preparing high-pungency chilli extract |
| CN102198059A (en) * | 2011-04-29 | 2011-09-28 | 安徽师范大学 | Novel cleaning material |
| CN103666797A (en) * | 2013-12-25 | 2014-03-26 | 上海绿伞环保科技发展有限公司 | Antimicrobial cleaning agent for washing machine tank and preparation method for antimicrobial cleaning agent |
| CN103805367A (en) * | 2014-02-28 | 2014-05-21 | 刘菊 | High-efficiency sterilization laundry detergent |
| CN105132197A (en) * | 2015-08-27 | 2015-12-09 | 建华建材（蚌埠）有限公司 | Herbal cleaning agent with sterilization and odor removing functions and preparation method thereof |
| CN105861169A (en) * | 2016-04-18 | 2016-08-17 | 袁玉珍 | Washing machine tank cleaning agent and preparation method thereof |
-
2016
- 2016-11-01 CN CN201610936447.9A patent/CN106544158A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2299926A1 (en) * | 1999-03-03 | 2000-09-03 | Henkel Kommanditgesellschaft Auf Aktien | A process for the production of multiphase detergent tablets |
| CN1796521A (en) * | 2004-12-28 | 2006-07-05 | 海尔科化工程塑料国家工程研究中心股份有限公司 | Purificant dedicated to barrel type washing machine |
| CN1861773A (en) * | 2006-06-09 | 2006-11-15 | 上海制皂有限公司 | Cleaning agent for washing machine tank |
| CN101744207A (en) * | 2010-02-25 | 2010-06-23 | 周顺 | Method for preparing high-pungency chilli extract |
| CN102198059A (en) * | 2011-04-29 | 2011-09-28 | 安徽师范大学 | Novel cleaning material |
| CN103666797A (en) * | 2013-12-25 | 2014-03-26 | 上海绿伞环保科技发展有限公司 | Antimicrobial cleaning agent for washing machine tank and preparation method for antimicrobial cleaning agent |
| CN103805367A (en) * | 2014-02-28 | 2014-05-21 | 刘菊 | High-efficiency sterilization laundry detergent |
| CN105132197A (en) * | 2015-08-27 | 2015-12-09 | 建华建材（蚌埠）有限公司 | Herbal cleaning agent with sterilization and odor removing functions and preparation method thereof |
| CN105861169A (en) * | 2016-04-18 | 2016-08-17 | 袁玉珍 | Washing machine tank cleaning agent and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 南京中医药大学: "《中药大辞典》", 31 March 2006, 上海科学技术出版社 * |
| 彭明丽等: "《精选小化工产品配方与工艺》", 31 January 2010, 化学工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106497683A (en) | A kind of abluent | |
| CN101979490B (en) | Cleaning agent for removing pesticides and microorganisms from surfaces of fruits and vegetables | |
| CN102198059B (en) | Novel cleaning material | |
| CN103332970A (en) | Method for producing functional fertilizers by comprehensive utilization of shrimp and crab shells | |
| CN106906084A (en) | Infant's Antibacterial laundry detergent and its production method | |
| CN106434028A (en) | Fruit and vegetable washing salt for removing pesticide residues and preparation method thereof | |
| CN106309285A (en) | Pure-natural bacterium-removing hand sanitizer for children | |
| KR101875190B1 (en) | Detergent composition composition comprising tengcha | |
| CN106497687A (en) | A kind of cleaning agent | |
| CN106544156A (en) | A kind of degerming air conditioner cleaning agent preparation method of antibiotic and sterilizing | |
| CN106497684A (en) | A kind of cleaning agent | |
| CN104450305A (en) | Pesticide scavenger and application method thereof | |
| CN108559656A (en) | A kind of plant type antibacterial bacteriostatic liquid detergent with pomelo fragrant smell | |
| KR20090120648A (en) | Natural product composition comprising anthraquinone- based compounds for enhansing control of harmful algae | |
| CN106544158A (en) | A kind of mould proof washing machine cleaning agent preparation method of antibiotic and sterilizing | |
| JP2006282896A (en) | Detergent and method for producing the same | |
| CN106955583A (en) | The preparation method of biology enzyme/plant extraction liquid degradation of formaldehyde composite | |
| CN107318894A (en) | Inhibitor administered for microcystic aeruginosa and preparation method thereof and application method | |
| CN102067887B (en) | Preparation for preventing and controlling aphid | |
| CN102100237A (en) | Composite disinfectant and preparation method | |
| CN108261355A (en) | A kind of hand cleanser of containing gingko extract | |
| CN103255002A (en) | Antibacterial floor cleaner and preparation method thereof | |
| CN103122280A (en) | Pesticide residue scavenger | |
| CN102899199A (en) | Sterilization particle and preparation method thereof | |
| KR101013946B1 (en) | Composition comprising menadione based compound for enhansing control of harmful algae, and method for controlling harmful algae using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170329 |
|
| RJ01 | Rejection of invention patent application after publication |