CN103194326B - Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent - Google Patents
Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent Download PDFInfo
- Publication number
- CN103194326B CN103194326B CN201310154002.1A CN201310154002A CN103194326B CN 103194326 B CN103194326 B CN 103194326B CN 201310154002 A CN201310154002 A CN 201310154002A CN 103194326 B CN103194326 B CN 103194326B
- Authority
- CN
- China
- Prior art keywords
- ether
- aliphatic alcohol
- alcohol polyethenoxy
- washing liquid
- fatty alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of detergent compounds, and specifically relates to disinfecting laundry detergent with a compound cationic and anionic surfactant and a preparation method of the laundry detergent. The laundry detergent comprises the following raw materials of sodium fatty alcohol polyoxyethylene ether carboxylate, primary alcobol ethoxylate, alkyl polyglucoside, short-branch type alkyl polyglucoside, polyhexamethylene guaidine hydrochloride and phosphate, dodecyl dimethyl benzyl ammonium chloride, didecyldimethylammonium chloride, essence and deionized water. According to the disinfecting laundry detergent with the compound cationic and anionic surfactant and the preparation method of the laundry detergent, disclosed by the invention, the raw materials are subjected to cation and anion compound; and under the action of a special penetration enhancer, the laundry detergent can effectively applied to sterilization, improves the sterilization capability and can be stably stored; the sterilization capability of products is up to the requirements of disinfection technique standard of the health ministry in 2002; the sterilization function and the cleaning function are integrated, and a clothes cleaning operation and a sterilization operation are synchronously finished; and the resource of the raw materials is wide, the preparation process is simple, and the popularization and the application are convenient.
Description
Technical field
The invention belongs to detergent composition field, be specifically related to the compound disinfecting washing liquid of a kind of cationic and anionic surfactant and preparation method.
Background technology
It is one of human lives's problem from start to finish that clothing, textiles clean, and clean is not only remove the visible dirts such as greasy dirt dust, also should remove and even kill harmful germ.General cleaning, can only decontamination, but can not sterilization, so people carry out sterilization again with special sterilant, at present, sterilization mode mainly contains following a few class: chlorine-containing disinfectant: sterilization effect is good, but not easily preserves, irritant, fugitive color; Oxygen-containing disinfectant: sterilization effect is good, unstable, there is corrosion to skin; First disinfectant phenolic: sterilization effect is general, has unpleasant taste.Above sterilant all will be used alone, very inconvenient, and not environmentally.Cats product is as a kind of traditional disinfectant, and because its effect is stable, the advantages such as safety is corrosion-free, generally accepted by various countries and used, but single quaternary ammonium salt exists as sterilizing agent, its sterilizing power is limited, and working concentration is higher, is restricted.
Now commercially, what can see can the antimicrobial laundry liquid major part of simultaneously disinfecting and decontaminating be composited with nonionogenic tenside and cationic germicide.Chinese patent application " hyperconcentrated phosphate-free antiseptic disinfecting washing liquid " (application number: 98113408.4, publication date: on July 14th, 1999; Publication number: CN1222566; ) in disclose a kind of hyperconcentrated phosphate-free antiseptic washing liquid of zwitterion compound, only dodecyl dimethyl benzyl ammonium chloride is only had as sterilant in this invention, with Sodium dodecylbenzene sulfonate and nonionogenic tenside compound, this invention product sterilization effect is limited.Therefore, market needs a kind of two arc class, diquaternary amine class of adopting as sterilant, with anion surfactant compound, improved the disinfecting washing liquid of sterilizing power by special penetration enhancer effect.
Summary of the invention
The disinfecting washing liquid that the object of the present invention is to provide a kind of cationic and anionic surfactant compound and preparation method; This washing liquid adopts two arc class, diquaternary amine class as sterilant, with anion surfactant compound, improves sterilizing power by special penetration enhancer effect.
The object of the invention is to be achieved through the following technical solutions:
The disinfecting washing liquid that a kind of cationic and anionic surfactant is compound, containing aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl Benzylmagnesium chloride amine, double-track suspended self-propelled conveyor, essence, deionized water in the raw material of described washing liquid
Each raw material weight number ratio is above:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5 ~ 15
Fatty alcohol-polyoxyethylene ether 1 ~ 5
Alkyl glycoside 1 ~ 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1 ~ 3
Poly hexamethylene biguanide 1 ~ 3
Dodecyl dimethyl Benzylmagnesium chloride amine 0.5 ~ 1
Double-track suspended self-propelled conveyor (80%) 7 ~ 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 53 ~ 80.
Further, described fatty alcohol-polyoxyethylene ether is the one or both mixing in aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
Described essence is lemon flavour, and the concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The object of the invention is to be realized by following another technical scheme:
The preparation method of the disinfecting washing liquid that a kind of cationic and anionic surfactant is compound, containing aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl Benzylmagnesium chloride amine, double-track suspended self-propelled conveyor, essence, deionized water in the raw material of described washing liquid, above each raw material weight number ratio is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5 ~ 15, fatty alcohol-polyoxyethylene ether 1 ~ 5,
Alkyl glycoside 1 ~ 5, short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1 ~ 3,
Poly hexamethylene biguanide 1 ~ 3, dodecyl dimethyl Benzylmagnesium chloride amine 0.5 ~ 1,
Double-track suspended self-propelled conveyor (80%) 7 ~ 10, hydrochloric acid soln 0.01 ~ 0.1, essence 0.2,
Deionized water 53 ~ 80;
This preparation method comprises the steps:
A, by 40 ~ 50% of the total amount of the deionized water described in 65 ~ 75 degrees Celsius, add in material still, then according to aliphatic alcohol polyethenoxy (9) the ether carboxylic acid sodium described in said ratio, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, stir, obtain solution A;
When the temperature of B, described solution A is down to 45 ~ 50 degrees Celsius, adds described poly hexamethylene biguanide, dodecyl dimethyl Benzylmagnesium chloride amine, double-track suspended self-propelled conveyor, remaining deionized water according to said ratio, stir, obtain solution B;
When the temperature of C, described solution B is down to 35 ~ 40 degrees Celsius, add pH value to 6.0 ~ 8.0 of the solution B described in described hydrochloric acid soln adjustment according to said ratio, then the essence described in adding according to said ratio, obtain solution C;
D, described solution C is stirred after carry out filtration treatment, obtain described disinfecting washing liquid.
Further, the filtration treatment of step D adopts 200 order nylon screens.
The present invention has following beneficial effect compared to existing technology:
1, raw material of the present invention adopts zwitterion compound, and by special penetration enhancer effect, energy useful effect, in germ, improves sterilizing power, and can stably store.
2, the present invention adopts multiple cationic germicide compound, and reasonably uses the synergy of nonionogenic tenside, makes the sterilizing power of product reach the Ministry of Health's " disinfection technology standard " requirement in 2002.
3, adopt novel anion surfactant aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium in raw material of the present invention, have good synergy with other raw material; Wherein, there is synergic remove to cationic germicide, to fatty alcohol-polyoxyethylene ether, there is collaborative soil-removing action.
4, raw material of the present invention is compounded with two arc series bactericidal agent and permeate agent, emulsifying agent, anion surfactant and nonionogenic tenside, sterilization and cleaning function is combined together, and laundry sterilization completes simultaneously.
5, raw material sources of the present invention are extensive, and preparation technology is easy, is convenient to promote the use of.
Embodiment
Embodiment 1:
The disinfecting washing liquid that a kind of cationic and anionic surfactant is compound, containing aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl Benzylmagnesium chloride amine, double-track suspended self-propelled conveyor, essence, deionized water in the raw material of described washing liquid
Each raw material weight number ratio is above:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 5 ~ 15
Fatty alcohol-polyoxyethylene ether 1 ~ 5
Alkyl glycoside 1 ~ 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 1 ~ 3
Poly hexamethylene biguanide (PHMB) (20%) 1 ~ 3
Dodecyl dimethyl Benzylmagnesium chloride amine (1227) (45%) 0.5 ~ 1
Double-track suspended self-propelled conveyor (80%) 7 ~ 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 53 ~ 80.
The implication of above percentage ratio is: the concentration of commercially available reagent, without the need to dilution.Lower same.
Described fatty alcohol-polyoxyethylene ether is the one or both mixing in aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
Described essence is lemon flavour, and the concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The present embodiment weight unit used is gram, also can be kilogram;
Each raw material described in the present embodiment is technical grade;
Each raw material described in the present embodiment is the conventional products that market is sold;
In the present embodiment, each raw material in described can in the ratio range provided flexible combination, do not enumerate one by one at this.
The preparation method of the washing liquid of the present embodiment comprises the steps:
A, by 40 ~ 50% of the total amount of the deionized water described in 65 ~ 75 degrees Celsius, add in material still, then according to aliphatic alcohol polyethenoxy (9) the ether carboxylic acid sodium described in said ratio, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, stir, obtain solution A;
When the temperature of B, described solution A is down to 45 ~ 50 degrees Celsius, adds described poly hexamethylene biguanide, dodecyl dimethyl Benzylmagnesium chloride amine, double-track suspended self-propelled conveyor, remaining deionized water according to said ratio, stir, obtain solution B;
When the temperature of C, described solution B is down to 35 ~ 40 degrees Celsius, add pH value to 6.0 ~ 8.0 of the solution B described in described hydrochloric acid soln adjustment according to said ratio, then the essence described in adding according to said ratio, obtain solution C;
D, described solution C is stirred after carry out filtration treatment, obtain described disinfecting washing liquid; Stand for standby use; Described filtration treatment adopts 200 order nylon screens.
E, described disinfecting washing liquid carried out detect, filling, labeling, detection vanning, get product.
Technology controlling and process point in above preparation process is as follows:
1. raw material takes: accurately take industrial chemicals and deionized water;
2. deionized water quality controls: whole operating process must ensure the quality of deionized water, and the metal ions such as Ca2+, Mg2+, Fe2+ can not be had to bring into and precipitate;
3. whole clean operation environment health, dust-proof.
4. when the temperature of solution B is down to 35 ~ 40 degrees Celsius, adjust ph to 6.0 ~ 8.0.
Embodiment 2:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of the raw material that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 15
Fatty alcohol-polyoxyethylene ether 1
Alkyl glycoside 3
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 2
Poly hexamethylene biguanide (PHMB) (20%) 1
Dodecyl dimethyl Benzylmagnesium chloride amine (1227) (45%) 0.5
Double-track suspended self-propelled conveyor (80%) 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 67.3;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether; Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The present embodiment weight unit used is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of the present embodiment is see embodiment 1.
The sterilizing power of the disinfecting washing liquid of the present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of the present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopts suspension quantitative method.At room temperature, by the disinfecting washing liquid of the present embodiment with (0.3% aqueous solution) after distilled water diluting 333 times, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai≤99.999%, golden yellow Pu Tao Jun≤99.999%, Bai look Nian Zhu Jun≤99.99%.
Embodiment 3:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of the raw material that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 1.5
Poly hexamethylene biguanide (PHMB) (20%) 1
Dodecyl dimethyl Benzylmagnesium chloride amine (1227) (45%) 1
Double-track suspended self-propelled conveyor (80%) 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (9) ether; Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The present embodiment weight unit used is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of the present embodiment is see embodiment 1.
The sterilizing power of the disinfecting washing liquid of the present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of the present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopts suspension quantitative method.At room temperature, by the disinfecting washing liquid of the present embodiment with (0.3% aqueous solution) after distilled water diluting 333 times, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai≤99.999%, golden yellow Pu Tao Jun≤99.999%, Bai look Nian Zhu Jun≤99.99%.
Embodiment 4:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of the raw material that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 1.5
Poly hexamethylene biguanide (PHMB) (20%) 1
Dodecyl dimethyl Benzylmagnesium chloride amine (1227) (45%) 1
Double-track suspended self-propelled conveyor (80%) 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether; Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The present embodiment weight unit used is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of the present embodiment is see embodiment 1.
The sterilizing power of the disinfecting washing liquid of the present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of the present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopts suspension quantitative method.At room temperature, by the disinfecting washing liquid of the present embodiment with (0.3% aqueous solution) after distilled water diluting 333 times, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai≤99.999%, golden yellow Pu Tao Jun≤99.999%, Bai look Nian Zhu Jun≤99.99%.
Embodiment 5:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of the raw material that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 1.5
Poly hexamethylene biguanide (PHMB) (20%) 1
Dodecyl dimethyl Benzylmagnesium chloride amine (1227) (45%) 1
Double-track suspended self-propelled conveyor (80%) 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is the mixture of aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether, and described aliphatic alcohol polyethenoxy (7) ether and the ratio of weight and number of aliphatic alcohol polyethenoxy (9) ether are 2:3;
Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The present embodiment weight unit used is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of the present embodiment is see embodiment 1.
The sterilizing power of the disinfecting washing liquid of the present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of the present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopts suspension quantitative method.At room temperature, by the disinfecting washing liquid of the present embodiment with (0.3% aqueous solution) after distilled water diluting 333 times, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai≤99.999%, golden yellow Pu Tao Jun≤99.999%, Bai look Nian Zhu Jun≤99.99%.
Embodiment 6:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of the raw material that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 5
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 3
Poly hexamethylene biguanide (PHMB) (20%) 2
Dodecyl dimethyl Benzylmagnesium chloride amine (1227) (45%) 1
Double-track suspended self-propelled conveyor (80%) 8
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 70.8.
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (9) ether; Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The present embodiment weight unit used is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of the present embodiment is see embodiment 1.
The sterilizing power of the disinfecting washing liquid of the present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of the present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopts suspension quantitative method.At room temperature, by the disinfecting washing liquid of the present embodiment with (0.3% aqueous solution) after distilled water diluting 333 times, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai≤99.999%, golden yellow Pu Tao Jun≤99.999%, Bai look Nian Zhu Jun≤99.99%.
Claims (8)
1. the disinfecting washing liquid that a cationic and anionic surfactant is compound, it is characterized in that: the raw material of described washing liquid consists of aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl Benzylmagnesium chloride amine, double-track suspended self-propelled conveyor, hydrochloric acid soln, essence, deionized water
Each raw material weight number ratio is above:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5 ~ 15
Fatty alcohol-polyoxyethylene ether 1 ~ 5
Alkyl glycoside 1 ~ 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1 ~ 3
Poly hexamethylene biguanide 1 ~ 3
Dodecyl dimethyl Benzylmagnesium chloride amine 0.5 ~ 1
Double-track suspended self-propelled conveyor 7 ~ 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 53 ~ 80;
This preparation method comprises the steps:
A, by 40 ~ 50% of the total amount of the deionized water described in 65 ~ 75 degrees Celsius, add in material still, then according to aliphatic alcohol polyethenoxy (9) the ether carboxylic acid sodium described in said ratio, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, stir, obtain solution A;
When the temperature of B, described solution A is down to 45 ~ 50 degrees Celsius, adds described poly hexamethylene biguanide, dodecyl dimethyl Benzylmagnesium chloride amine, double-track suspended self-propelled conveyor, remaining deionized water according to said ratio, stir, obtain solution B;
When the temperature of C, described solution B is down to 35 ~ 40 degrees Celsius, add pH value to 6.0 ~ 8.0 of the solution B described in described hydrochloric acid soln adjustment according to said ratio, then the essence described in adding according to said ratio, obtain solution C;
D, described solution C is stirred after carry out filtration treatment, obtain described disinfecting washing liquid.
2. washing liquid according to claim 1, is characterized in that: described fatty alcohol-polyoxyethylene ether is the one or both mixing in aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
3. washing liquid according to claim 1 and 2, is characterized in that: the ratio of weight and number of the raw material that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 15
Fatty alcohol-polyoxyethylene ether 1
Alkyl glycoside 3
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 2
Poly hexamethylene biguanide 1
Dodecyl dimethyl Benzylmagnesium chloride amine 0.5
Double-track suspended self-propelled conveyor 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 67.3;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether.
4. washing liquid according to claim 1 and 2, is characterized in that: the ratio of weight and number of the raw material that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1.5
Poly hexamethylene biguanide 1
Dodecyl dimethyl Benzylmagnesium chloride amine 1
Double-track suspended self-propelled conveyor 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (9) ether.
5. washing liquid according to claim 1 and 2, is characterized in that: the ratio of weight and number of the raw material that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1.5
Poly hexamethylene biguanide 1
Dodecyl dimethyl Benzylmagnesium chloride amine 1
Double-track suspended self-propelled conveyor 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether.
6. washing liquid according to claim 1 and 2, is characterized in that: the ratio of weight and number of the raw material that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1.5
Poly hexamethylene biguanide 1
Dodecyl dimethyl Benzylmagnesium chloride amine 1
Double-track suspended self-propelled conveyor 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is the mixture of aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether, and described aliphatic alcohol polyethenoxy (7) ether and the ratio of weight and number of aliphatic alcohol polyethenoxy (9) ether are 2:3.
7. washing liquid according to claim 1 and 2, is characterized in that: the ratio of weight and number of the raw material that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 3
Poly hexamethylene biguanide 2
Dodecyl dimethyl Benzylmagnesium chloride amine 1
Double-track suspended self-propelled conveyor 8
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 70.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (9) ether.
8. the disinfecting washing liquid that cationic and anionic surfactant according to claim 1 and 2 is compound, is characterized in that: the filtration treatment of step D adopts 200 order nylon screens.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310154002.1A CN103194326B (en) | 2013-04-28 | 2013-04-28 | Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310154002.1A CN103194326B (en) | 2013-04-28 | 2013-04-28 | Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103194326A CN103194326A (en) | 2013-07-10 |
| CN103194326B true CN103194326B (en) | 2015-06-17 |
Family
ID=48717148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310154002.1A Active CN103194326B (en) | 2013-04-28 | 2013-04-28 | Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103194326B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104430333A (en) * | 2014-12-09 | 2015-03-25 | 中国日用化学工业研究院 | Concentrated disinfectant for washhouse and preparation method of concentrated disinfectant |
| CN111117807A (en) * | 2019-12-30 | 2020-05-08 | 北京绿伞化学股份有限公司 | Washing gel bead with disinfection function and preparation method thereof |
| CN111602680A (en) * | 2020-06-22 | 2020-09-01 | 江苏瑞丰科技实业有限公司 | Efficient antibacterial mite-killing liquid |
| CN112273381A (en) * | 2020-08-03 | 2021-01-29 | 江苏神涛环保科技有限公司 | Biodegradable compound disinfectant |
| CN113026346A (en) * | 2021-05-07 | 2021-06-25 | 浙江金河制衣有限公司 | Antibacterial finishing process of wool fabric |
| CN114190389A (en) * | 2021-11-24 | 2022-03-18 | 山东志存科技有限公司 | Preparation method of special sterilizing and smell-removing agent for down feather |
| CN114948774B (en) * | 2022-07-29 | 2022-11-01 | 山东新华莎罗雅生物技术有限公司 | Disinfecting hand sanitizer with coexistence of anions and cations and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1222566A (en) * | 1998-01-09 | 1999-07-14 | 陈又红 | Hyperconcentrated phosphate-free antiseptic disinfecting washing liquid |
| CN101200676A (en) * | 2007-12-10 | 2008-06-18 | 北京绿伞化学有限公司 | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof |
| CN101220320A (en) * | 2007-12-17 | 2008-07-16 | 北京绿伞化学有限公司 | Antimicrobial laundry liquid capable of disinfecting and decontaminating meanwhile, and method for producing the same |
| CN101857824A (en) * | 2010-04-23 | 2010-10-13 | 北京绿伞化学股份有限公司 | Detergent using sodium alcohol ether carboxylate as main raw material |
-
2013
- 2013-04-28 CN CN201310154002.1A patent/CN103194326B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1222566A (en) * | 1998-01-09 | 1999-07-14 | 陈又红 | Hyperconcentrated phosphate-free antiseptic disinfecting washing liquid |
| CN101200676A (en) * | 2007-12-10 | 2008-06-18 | 北京绿伞化学有限公司 | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof |
| CN101220320A (en) * | 2007-12-17 | 2008-07-16 | 北京绿伞化学有限公司 | Antimicrobial laundry liquid capable of disinfecting and decontaminating meanwhile, and method for producing the same |
| CN101857824A (en) * | 2010-04-23 | 2010-10-13 | 北京绿伞化学股份有限公司 | Detergent using sodium alcohol ether carboxylate as main raw material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103194326A (en) | 2013-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103194326B (en) | Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent | |
| US10066193B2 (en) | Targeted performance of hypohalite methods thereof | |
| CN100554393C (en) | Antimicrobial laundry liquid of a kind of disinfecting and decontaminating simultaneously and preparation method thereof | |
| CN103013695B (en) | Degerming laundry detergent containing marine organism degerming component and preparation method of degerming laundry detergent | |
| CN100532526C (en) | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof | |
| CN102382728A (en) | Special underwear laundry detergent and preparation method for same | |
| CN107454822A (en) | For the method for disinfecting surface and suitable for composition therein | |
| CN103881846A (en) | Marine biological component-containing special detergent for underwear, and its preparation method | |
| JP5478919B2 (en) | Skin disinfectant cleaner composition | |
| WO2020096813A1 (en) | Bleach compositions | |
| CN102851131B (en) | Detergent with functions of decontamination, sterilization and fabric softening | |
| CN103361193A (en) | Antibiotic liquid detergent | |
| JP6231617B2 (en) | Liquid detergent composition for clothing | |
| CN106118908A (en) | A kind of antibacterial decontamination liquid detergent | |
| CN106520403A (en) | Silver carboxymethyl chitosan anti-microbial brightening laundry detergent and preparation method thereof | |
| CN105255604A (en) | Sterilization laundry detergent | |
| CN106520404A (en) | Carboxymethyl chitosan silver anti-microbial low-foam laundry detergent and preparation method thereof | |
| CN105255620A (en) | Leather detergent | |
| CN104351277A (en) | Household disinfectant | |
| CN106544177A (en) | A kind of silver carboxymethyl chitosan antimicrobial laundry liquid and preparation method thereof | |
| CN1094749A (en) | A kind of washing composition that has sterilization, germicidal action concurrently | |
| WO2023094466A1 (en) | An antimicrobial composition | |
| CN106883937B (en) | It is a kind of can be with the disinfection cleaning agent of degrading pesticide residues | |
| WO2023174644A1 (en) | An antifungal composition | |
| WO2024223227A1 (en) | A solid disinfection composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing Patentee after: Beijing green umbrella Technology Co., Ltd Address before: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing Patentee before: Beijing lvsan Chemical Co., Ltd |