CN103194326A - Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent - Google Patents
Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent Download PDFInfo
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Abstract
The invention belongs to the field of detergent compounds, and specifically relates to disinfecting laundry detergent with a compound cationic and anionic surfactant and a preparation method of the laundry detergent. The laundry detergent comprises the following raw materials of sodium fatty alcohol polyoxyethylene ether carboxylate, primary alcobol ethoxylate, alkyl polyglucoside, short-branch type alkyl polyglucoside, polyhexamethylene guaidine hydrochloride and phosphate, dodecyl dimethyl benzyl ammonium chloride, didecyldimethylammonium chloride, essence and deionized water. According to the disinfecting laundry detergent with the compound cationic and anionic surfactant and the preparation method of the laundry detergent, disclosed by the invention, the raw materials are subjected to cation and anion compound; and under the action of a special penetration enhancer, the laundry detergent can effectively applied to sterilization, improves the sterilization capability and can be stably stored; the sterilization capability of products is up to the requirements of disinfection technique standard of the health ministry in 2002; the sterilization function and the cleaning function are integrated, and a clothes cleaning operation and a sterilization operation are synchronously finished; and the resource of the raw materials is wide, the preparation process is simple, and the popularization and the application are convenient.
Description
Technical field
The invention belongs to the detergent composition field, be specifically related to the compound disinfecting washing liquid of a kind of cationic and anionic surfactant and preparation method.
Background technology
Clothing, textiles cleaning is one of human lives's problem from start to finish, and cleaning is not only to remove visible dirt such as greasy dirt dust, also should remove even kill harmful germ.General cleaning can only decontamination, but can not sterilization, so people will carry out sterilization again with special sterilant, at present, sterilization mode mainly contains following a few class: chlorine-containing disinfectant: sterilization effect is good, but is difficult for preserving, and pungency is arranged, fugitive color; Oxygen-containing disinfectant: sterilization effect is good, and instability has corrosion to skin; Cresols class sterilizing agent: sterilization effect is general, and unpleasant flavor is arranged.Above sterilant all will use separately, and is very inconvenient, and not environmental protection.Cats product is as a kind of traditional disinfectant, and stable because of its effect, safety does not have advantages such as corrosion, generally accepted by various countries and use, but single quaternary ammonium salt exists as sterilizing agent, and its sterilizing power is limited, and working concentration is higher, is restricted.
On the market, the antimicrobial laundry liquid major part of disinfecting and decontaminating simultaneously that can see is to be composited with nonionogenic tenside and cationic germicide now.Chinese patent application " hyperconcentrated phosphate-free antiseptic disinfecting washing liquid " (application number: 98113408.4, open day: on July 14th, 1999; Publication number: CN1222566; ) in the compound hyperconcentrated phosphate-free antiseptic washing liquid of a kind of zwitterion is disclosed, only dodecyl dimethyl benzyl ammonium chloride is only arranged as sterilant in this invention, compound with Sodium dodecylbenzene sulfonate and nonionogenic tenside, this invention product sterilization effect is limited.Therefore, need the two arc classes of a kind of employing, diquaternary amine class as sterilant on the market, compound with anion surfactant, by the disinfecting washing liquid of special penetration enhancer effect raising sterilizing power.
Summary of the invention
The object of the present invention is to provide the compound disinfecting washing liquid of a kind of cationic and anionic surfactant and preparation method; This washing liquid adopts two arc classes, diquaternary amine class as sterilant, and is compound with anion surfactant, improves sterilizing power by special penetration enhancer effect.
The objective of the invention is to be achieved through the following technical solutions:
The disinfecting washing liquid that a kind of cationic and anionic surfactant is compound, contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl benzyl ammonia chloride, two decyl alkyl dimethyl ammonium chloride, essence, deionized water in the raw material of described washing liquid
More than each raw material weight umber ratio be:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5 ~ 15
Fatty alcohol-polyoxyethylene ether 1～5
Alkyl glycoside 1 ~ 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1 ~ 3
Poly hexamethylene biguanide 1 ~ 3
Dodecyl dimethyl benzyl ammonia chloride 0.5 ~ 1
Two decyl alkyl dimethyl ammonium chlorides (80%) 7 ~ 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 53 ~ 80.
Further, described fatty alcohol-polyoxyethylene ether is a kind of or the two mixing in aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
Described essence is lemon flavour, and the concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The objective of the invention is to realize by following another technical scheme:
The preparation method of the disinfecting washing liquid that a kind of cationic and anionic surfactant is compound, contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl benzyl ammonia chloride, two decyl alkyl dimethyl ammonium chloride, essence, deionized water in the raw material of described washing liquid, more than each raw material weight umber ratio be:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5 ~ 15, fatty alcohol-polyoxyethylene ether 1～5,
Alkyl glycoside 1 ~ 5, short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1 ~ 3,
Poly hexamethylene biguanide 1 ~ 3, dodecyl dimethyl benzyl ammonia chloride 0.5 ~ 1,
Two decyl alkyl dimethyl ammonium chlorides (80%) 7 ~ 10, hydrochloric acid soln 0.01 ~ 0.1, essence 0.2,
Deionized water 53 ~ 80;
This preparation method comprises the steps:
A, with 40～50% of the total amount of 65～75 degrees centigrade described deionized waters, in the addingization material still, then according to the described aliphatic alcohol polyethenoxy of said ratio (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, stir, obtain solution A;
When the temperature of B, described solution A is down to 45～50 degrees centigrade, add described poly hexamethylene biguanide, dodecyl dimethyl benzyl ammonia chloride, two decyl alkyl dimethyl ammonium chloride, remaining deionized water according to said ratio, stir, obtain solution B;
When the temperature of C, described solution B is down to 35～40 degrees centigrade, add pH value to 6.0～8.0 that described hydrochloric acid soln is regulated described solution B according to said ratio, the essence described in adding according to said ratio again obtains solution C;
D, carry out filtration treatment after described solution C stirred, obtain described disinfecting washing liquid.
Further, the filtration treatment of step D adopts 200 order nylon screens.
The present invention has following beneficial effect compared to existing technology:
1, it is compound that raw material of the present invention adopts zwitterion, and by special penetration enhancer effect, the energy useful effect improves sterilizing power, and can stably store in germ.
2, it is compound that the present invention adopts multiple cationic germicide, and reasonably use the synergy of nonionogenic tenside, makes the sterilizing power of product reach the Ministry of Health's " disinfection technology standard " requirement in 2002.
3, adopt novel anion surfactant aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium in the raw material of the present invention, with other raw material good synergy is arranged; Wherein, cationic germicide there is the Synergistic biocidal effect, fatty alcohol-polyoxyethylene ether is had collaborative soil-removing action.
4, raw material of the present invention is compound two arc series bactericidal agents and permeate agent, emulsifying agent, anion surfactant and nonionogenic tenside combines sterilization and cleaning function together, and the laundry sterilization is finished simultaneously.
5, raw material sources of the present invention are extensive, and preparation technology is easy, are convenient to promote the use of.
Embodiment
Embodiment 1:
The disinfecting washing liquid that a kind of cationic and anionic surfactant is compound, contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl benzyl ammonia chloride, two decyl alkyl dimethyl ammonium chloride, essence, deionized water in the raw material of described washing liquid
More than each raw material weight umber ratio be:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 5 ~ 15
Fatty alcohol-polyoxyethylene ether 1～5
Alkyl glycoside 1 ~ 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 1 ~ 3
Poly hexamethylene biguanide (PHMB) (20%) 1 ~ 3
Dodecyl dimethyl benzyl ammonia chloride (1227) (45%) 0.5 ~ 1
Two decyl alkyl dimethyl ammonium chlorides (80%) 7 ~ 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 53 ~ 80.
The implication of above percentage ratio is: the concentration of commercially available reagent need not dilution.Down together.
Described fatty alcohol-polyoxyethylene ether is a kind of or the two mixing in aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
Described essence is lemon flavour, and the concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The used weight unit of present embodiment also can be kilogram for gram;
Each raw material described in the present embodiment is technical grade;
Each raw material described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, each raw material in described can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
The preparation method of the washing liquid of present embodiment comprises the steps:
A, with 40～50% of the total amount of 65～75 degrees centigrade described deionized waters, in the addingization material still, then according to the described aliphatic alcohol polyethenoxy of said ratio (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, stir, obtain solution A;
When the temperature of B, described solution A is down to 45～50 degrees centigrade, add described poly hexamethylene biguanide, dodecyl dimethyl benzyl ammonia chloride, two decyl alkyl dimethyl ammonium chloride, remaining deionized water according to said ratio, stir, obtain solution B;
When the temperature of C, described solution B is down to 35～40 degrees centigrade, add pH value to 6.0～8.0 that described hydrochloric acid soln is regulated described solution B according to said ratio, the essence described in adding according to said ratio again obtains solution C;
D, carry out filtration treatment after described solution C stirred, obtain described disinfecting washing liquid; Stand for standby use; Described filtration treatment adopts 200 order nylon screens.
E, with described disinfecting washing liquid detect, can, decals, detection vanning, get product.
Technology controlling and process point in the above preparation process is as follows:
1. raw material takes by weighing: accurately take by weighing industrial chemicals and deionized water;
2. deionized water quality control: the entire operation process must guarantee the quality of deionized water, can not have metal ions such as Ca2+, Mg2+, Fe2+ to bring into and precipitate;
3. entire operation clean environment health, dustproof.
4. when the temperature of solution B is down to 35～40 degrees centigrade, regulate pH value to 6.0～8.0.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the raw materials in part by weight ratio that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 15
Fatty alcohol-polyoxyethylene ether 1
Alkyl glycoside 3
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 2
Poly hexamethylene biguanide (PHMB) (20%) 1
Dodecyl dimethyl benzyl ammonia chloride (1227) (45%) 0.5
Two decyl alkyl dimethyl ammonium chlorides (80%) 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 67.3;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether; Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of present embodiment is referring to embodiment 1.
The sterilizing power of the disinfecting washing liquid of present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopt the suspension quantitative method.At room temperature, with (0.3% aqueous solution) behind 333 times of the distilled water dilutings, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai ≧ 99.999% with the disinfecting washing liquid of present embodiment, golden yellow Pu Tao Jun ≧ 99.999%, Bai look Nian Zhu Jun ≧ 99.99%.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the raw materials in part by weight ratio that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 1.5
Poly hexamethylene biguanide (PHMB) (20%) 1
Dodecyl dimethyl benzyl ammonia chloride (1227) (45%) 1
Two decyl alkyl dimethyl ammonium chlorides (80%) 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (9) ether; Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of present embodiment is referring to embodiment 1.
The sterilizing power of the disinfecting washing liquid of present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopt the suspension quantitative method.At room temperature, with (0.3% aqueous solution) behind 333 times of the distilled water dilutings, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai ≧ 99.999% with the disinfecting washing liquid of present embodiment, golden yellow Pu Tao Jun ≧ 99.999%, Bai look Nian Zhu Jun ≧ 99.99%.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the raw materials in part by weight ratio that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 1.5
Poly hexamethylene biguanide (PHMB) (20%) 1
Dodecyl dimethyl benzyl ammonia chloride (1227) (45%) 1
Two decyl alkyl dimethyl ammonium chlorides (80%) 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether; Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of present embodiment is referring to embodiment 1.
The sterilizing power of the disinfecting washing liquid of present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopt the suspension quantitative method.At room temperature, with (0.3% aqueous solution) behind 333 times of the distilled water dilutings, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai ≧ 99.999% with the disinfecting washing liquid of present embodiment, golden yellow Pu Tao Jun ≧ 99.999%, Bai look Nian Zhu Jun ≧ 99.99%.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the raw materials in part by weight ratio that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 1.5
Poly hexamethylene biguanide (PHMB) (20%) 1
Dodecyl dimethyl benzyl ammonia chloride (1227) (45%) 1
Two decyl alkyl dimethyl ammonium chlorides (80%) 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is the mixture of aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether, and the ratio of weight and number of described aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether is 2:3;
Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of present embodiment is referring to embodiment 1.
The sterilizing power of the disinfecting washing liquid of present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopt the suspension quantitative method.At room temperature, with (0.3% aqueous solution) behind 333 times of the distilled water dilutings, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai ≧ 99.999% with the disinfecting washing liquid of present embodiment, golden yellow Pu Tao Jun ≧ 99.999%, Bai look Nian Zhu Jun ≧ 99.99%.
Embodiment 6:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the raw materials in part by weight ratio that this disinfecting washing liquid comprises is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium (AEC-9) 5
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether (XL-80) 3
Poly hexamethylene biguanide (PHMB) (20%) 2
Dodecyl dimethyl benzyl ammonia chloride (1227) (45%) 1
Two decyl alkyl dimethyl ammonium chlorides (80%) 8
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 70.8.
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (9) ether; Described essence is lemon flavour; The concentration of described hydrochloric acid soln is 10%, and this hydrochloric acid is technical hydrochloric acid.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of the disinfecting washing liquid of present embodiment is referring to embodiment 1.
The sterilizing power of the disinfecting washing liquid of present embodiment reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The detected result of present embodiment is as follows: according to the Ministry of Health's " disinfection technology standard " requirement in 2002, adopt the suspension quantitative method.At room temperature, with (0.3% aqueous solution) behind 333 times of the distilled water dilutings, sterilizing time is 20min, its sterilizing power result: intestinal bacteria sterilization Shuai ≧ 99.999% with the disinfecting washing liquid of present embodiment, golden yellow Pu Tao Jun ≧ 99.999%, Bai look Nian Zhu Jun ≧ 99.99%.
Claims (9)
1. disinfecting washing liquid that cationic and anionic surfactant is compound, it is characterized in that: contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl benzyl ammonia chloride, two decyl alkyl dimethyl ammonium chloride, hydrochloric acid soln, essence, deionized water in the raw material of described washing liquid
More than each raw material weight umber ratio be:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5 ~ 15
Fatty alcohol-polyoxyethylene ether 1～5
Alkyl glycoside 1 ~ 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1 ~ 3
Poly hexamethylene biguanide 1 ~ 3
Dodecyl dimethyl benzyl ammonia chloride 0.5 ~ 1
Two decyl alkyl dimethyl ammonium chlorides 7 ~ 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 53 ~ 80.
2. washing liquid according to claim 1, it is characterized in that: described fatty alcohol-polyoxyethylene ether is a kind of or the two mixing in aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether.
3. washing liquid according to claim 1 and 2, it is characterized in that: the raw materials in part by weight ratio that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 15
Fatty alcohol-polyoxyethylene ether 1
Alkyl glycoside 3
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 2
Poly hexamethylene biguanide 1
Dodecyl dimethyl benzyl ammonia chloride 0.5
Two decyl alkyl dimethyl ammonium chlorides 10
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 67.3;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether.
4. washing liquid according to claim 1 and 2, it is characterized in that: the raw materials in part by weight ratio that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1.5
Poly hexamethylene biguanide 1
Dodecyl dimethyl benzyl ammonia chloride 1
Two decyl alkyl dimethyl ammonium chlorides 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (9) ether.
5. washing liquid according to claim 1 and 2, it is characterized in that: the raw materials in part by weight ratio that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1.5
Poly hexamethylene biguanide 1
Dodecyl dimethyl benzyl ammonia chloride 1
Two decyl alkyl dimethyl ammonium chlorides 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether.
6. washing liquid according to claim 1, it is characterized in that: the raw materials in part by weight ratio that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 10
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 1.5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1.5
Poly hexamethylene biguanide 1
Dodecyl dimethyl benzyl ammonia chloride 1
Two decyl alkyl dimethyl ammonium chlorides 7
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 72.8;
Described fatty alcohol-polyoxyethylene ether is the mixture of aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether, and the ratio of weight and number of described aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether is 2:3.
7. washing liquid according to claim 1, it is characterized in that: the raw materials in part by weight ratio that described washing liquid contains is:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5
Fatty alcohol-polyoxyethylene ether 5
Alkyl glycoside 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 3
Poly hexamethylene biguanide 2
Dodecyl dimethyl benzyl ammonia chloride 1
Two decyl alkyl dimethyl ammonium chlorides 8
Hydrochloric acid soln 0.01 ~ 0.1
Essence 0.2
Deionized water 70.8;
Described fatty alcohol-polyoxyethylene ether is aliphatic alcohol polyethenoxy (9) ether.
8. the preparation method of the compound disinfecting washing liquid of a cationic and anionic surfactant, it is characterized in that: contain aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, poly hexamethylene biguanide, dodecyl dimethyl benzyl ammonia chloride, two decyl alkyl dimethyl ammonium chloride, essence, deionized water in the raw material of described washing liquid
More than each raw material weight umber ratio be:
Aliphatic alcohol polyethenoxy (9) ether carboxylic acid sodium 5 ~ 15, fatty alcohol-polyoxyethylene ether 1～5,
Alkyl glycoside 1 ~ 5, short-chain branch type aliphatic alcohol polyethenoxy (8) ether 1 ~ 3,
Poly hexamethylene biguanide 1 ~ 3, dodecyl dimethyl benzyl ammonia chloride 0.5 ~ 1,
Two decyl alkyl dimethyl ammonium chlorides 7 ~ 10, hydrochloric acid soln 0.01 ~ 0.1, essence 0.2,
Deionized water 53 ~ 80;
This preparation method comprises the steps:
A, with 40～50% of the total amount of 65～75 degrees centigrade described deionized waters, in the addingization material still, then according to the described aliphatic alcohol polyethenoxy of said ratio (9) ether carboxylic acid sodium, fatty alcohol-polyoxyethylene ether, alkyl glycoside, short-chain branch type aliphatic alcohol polyethenoxy (8) ether, stir, obtain solution A;
When the temperature of B, described solution A is down to 45～50 degrees centigrade, add described poly hexamethylene biguanide, dodecyl dimethyl benzyl ammonia chloride, two decyl alkyl dimethyl ammonium chloride, remaining deionized water according to said ratio, stir, obtain solution B;
When the temperature of C, described solution B is down to 35～40 degrees centigrade, add pH value to 6.0～8.0 that described hydrochloric acid soln is regulated described solution B according to said ratio, the essence described in adding according to said ratio again obtains solution C;
D, carry out filtration treatment after described solution C stirred, obtain described disinfecting washing liquid.
9. the preparation method of the compound disinfecting washing liquid of cationic and anionic surfactant according to claim 8, it is characterized in that: the filtration treatment of step D adopts 200 order nylon screens.
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| CN114948774A (en) * | 2022-07-29 | 2022-08-30 | 山东新华莎罗雅生物技术有限公司 | Disinfecting hand sanitizer with coexistence of anions and cations and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1222566A (en) * | 1998-01-09 | 1999-07-14 | 陈又红 | Hyperconcentrated phosphate-free antiseptic disinfecting washing liquid |
| CN101200676A (en) * | 2007-12-10 | 2008-06-18 | 北京绿伞化学有限公司 | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof |
| CN101220320A (en) * | 2007-12-17 | 2008-07-16 | 北京绿伞化学有限公司 | Antimicrobial laundry liquid capable of disinfecting and decontaminating meanwhile, and method for producing the same |
| CN101857824A (en) * | 2010-04-23 | 2010-10-13 | 北京绿伞化学股份有限公司 | Detergent using sodium alcohol ether carboxylate as main raw material |
-
2013
- 2013-04-28 CN CN201310154002.1A patent/CN103194326B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1222566A (en) * | 1998-01-09 | 1999-07-14 | 陈又红 | Hyperconcentrated phosphate-free antiseptic disinfecting washing liquid |
| CN101200676A (en) * | 2007-12-10 | 2008-06-18 | 北京绿伞化学有限公司 | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof |
| CN101220320A (en) * | 2007-12-17 | 2008-07-16 | 北京绿伞化学有限公司 | Antimicrobial laundry liquid capable of disinfecting and decontaminating meanwhile, and method for producing the same |
| CN101857824A (en) * | 2010-04-23 | 2010-10-13 | 北京绿伞化学股份有限公司 | Detergent using sodium alcohol ether carboxylate as main raw material |
Cited By (8)
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|---|---|---|---|---|
| CN104430333A (en) * | 2014-12-09 | 2015-03-25 | 中国日用化学工业研究院 | Concentrated disinfectant for washhouse and preparation method of concentrated disinfectant |
| CN111117807A (en) * | 2019-12-30 | 2020-05-08 | 北京绿伞化学股份有限公司 | Washing gel bead with disinfection function and preparation method thereof |
| CN111602680A (en) * | 2020-06-22 | 2020-09-01 | 江苏瑞丰科技实业有限公司 | Efficient antibacterial mite-killing liquid |
| CN112273381A (en) * | 2020-08-03 | 2021-01-29 | 江苏神涛环保科技有限公司 | Biodegradable compound disinfectant |
| CN113026346A (en) * | 2021-05-07 | 2021-06-25 | 浙江金河制衣有限公司 | Antibacterial finishing process of wool fabric |
| CN114190389A (en) * | 2021-11-24 | 2022-03-18 | 山东志存科技有限公司 | Preparation method of special sterilizing and smell-removing agent for down feather |
| CN114948774A (en) * | 2022-07-29 | 2022-08-30 | 山东新华莎罗雅生物技术有限公司 | Disinfecting hand sanitizer with coexistence of anions and cations and preparation method thereof |
| CN114948774B (en) * | 2022-07-29 | 2022-11-01 | 山东新华莎罗雅生物技术有限公司 | Disinfecting hand sanitizer with coexistence of anions and cations and preparation method thereof |
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