CN100554393C - Antimicrobial laundry liquid of a kind of disinfecting and decontaminating simultaneously and preparation method thereof - Google Patents
Antimicrobial laundry liquid of a kind of disinfecting and decontaminating simultaneously and preparation method thereof Download PDFInfo
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- CN100554393C CN100554393C CNB2007101796704A CN200710179670A CN100554393C CN 100554393 C CN100554393 C CN 100554393C CN B2007101796704 A CNB2007101796704 A CN B2007101796704A CN 200710179670 A CN200710179670 A CN 200710179670A CN 100554393 C CN100554393 C CN 100554393C
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- aliphatic alcohol
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Abstract
The purpose of this invention is to provide antimicrobial laundry liquid of a kind of disinfecting and decontaminating simultaneously and preparation method thereof, the this simultaneously antimicrobial laundry liquid of disinfecting and decontaminating is compound biguanides sterilant and permeate agent, emulsifying agent and nonionogenic tenside, sterilization and cleaning function are combined together, and the laundry sterilization is finished simultaneously.The present invention is formulated by aliphatic alcohol polyethenoxy (7) ether AEO-7, aliphatic alcohol polyethenoxy (9) ether AEO-9, poly hexamethylene biguanide PHMB, dodecyl benzyl dimethyl ammonium chloride 1227, short-chain branch type aliphatic alcohol polyethenoxy (8) ether XL-80, aliphatic alcohol polyethenoxy (5) ether AEO-5, lemon flavour, deionized water.The preparation method adds deionized water and described raw material material in changing the material still, detect, can, decals, detection vanning again.The present invention adopts biguanides, diquaternary amine class component compound, by special penetration enhancer effect, makes it useful effect in germ, improves sterilizing power, and can stablize storage; And low-consuming, the cost performance height.
Description
Technical field
The present invention relates to detergent applications, antimicrobial laundry liquid of specifically a kind of disinfecting and decontaminating simultaneously and preparation method thereof.
Background technology
Clothing, textiles cleaning is one of human lives's problem from start to finish, and cleaning is not only to remove visible dirt such as greasy dirt dust, also should remove even kill harmful germ.General cleaning can only decontamination, but can not sterilization, so people will carry out sterilization again with special sterilant, at present, sterilization mode mainly contains following a few class: chlorine-containing disinfectant: sterilization effect is good, but is difficult for preserving, and pungency is arranged, fugitive color; Oxygen-containing disinfectant: sterilization effect is good, and instability has corrosion to skin; Cresols class sterilizing agent: sterilization effect is general, and unpleasant flavor is arranged.Above sterilant all will use separately, and is very inconvenient, and not environmental protection, really can do washing, again can sterilization, and the good human consumer of cost performance can accept the antibiotic product of the antimicrobial laundry liquid of disinfecting and decontaminating simultaneously and not see as yet.
A kind of hyperconcentrated phosphate-free antiseptic disinfecting antimicrobial laundry liquid of disinfecting and decontaminating is simultaneously disclosed in the Chinese patent application 98113408.4.This simultaneously the antimicrobial laundry liquid of disinfecting and decontaminating it is characterized in that composition is C12-C15 fatty alcohol-polyoxyethylene ether, the basic sodium sulfonate of dodecane, trolamine, ethanol, Repone K, dodecyl dimethyl benzyl ammonium chloride and water.Only dodecyl dimethyl benzyl ammonium chloride is only arranged as sterilant in the prescription, sterilization effect is limited, and, not mentioned this quantized data of sterilization effect of the antimicrobial laundry liquid of disinfecting and decontaminating simultaneously in this patent application.The present invention adopts biguanides, diquaternary amine series bactericidal agent, improves sterilizing power by special penetration enhancer effect.The measured result of the antimicrobial laundry liquid sterilization effect of disinfecting and decontaminating simultaneously described in the present invention is up to state standards.
Summary of the invention
The purpose of this invention is to provide antimicrobial laundry liquid of a kind of disinfecting and decontaminating simultaneously and preparation method thereof, the this simultaneously antimicrobial laundry liquid of disinfecting and decontaminating is compound biguanides sterilant and permeate agent, emulsifying agent and nonionogenic tenside, sterilization and cleaning function are combined together, and the laundry sterilization is finished simultaneously.
Technical scheme of the present invention is achieved in that
A kind of antimicrobial laundry liquid of disinfecting and decontaminating simultaneously is characterized in that, this simultaneously the antimicrobial laundry liquid of disinfecting and decontaminating be that proportioning is prepared from according to the following number of weight ratio:
The title ratio of weight and number
Aliphatic alcohol polyethenoxy (7) ether AEO-7 1～25
Aliphatic alcohol polyethenoxy (9) ether AEO-9 1～20
Poly hexamethylene biguanide PHMB (20%) 0.1～20
Dodecyl benzyl dimethyl ammonium chloride 1227 (45%) 0.3～15
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether-XL-80 0.1～10
Aliphatic alcohol polyethenoxy (5) ether AEO-5 0.15～16
Lemon flavour 0.2
Deionized water 40～75
Above-described various raw material is technical grade.
A kind of preparation technology of antimicrobial laundry liquid of disinfecting and decontaminating simultaneously is characterized in that, this simultaneously the antimicrobial laundry liquid of disinfecting and decontaminating by following step preparation:
1. change material
(1) with 65～75 ℃ of deionized water of 40～50%, in the addingization material still, add aliphatic alcohol polyethenoxy (7) ether AEO-7, aliphatic alcohol polyethenoxy (9) ether AEO-9, aliphatic alcohol polyethenoxy (5) ether AEO-5, short-chain branch type aliphatic alcohol polyethenoxy (8) the ether XL-80 described in the antimicrobial laundry liquid formula of above-mentioned disinfecting and decontaminating simultaneously then respectively and stir.
When (2) equitemperature dropped to 45～50 ℃ of left and right sides, it was even to add poly hexamethylene biguanide PHMB, dodecyl benzyl dimethyl ammonium chloride 1227 and the remaining deionized water and stirring of part described in the antimicrobial laundry liquid formula of above-mentioned disinfecting and decontaminating simultaneously.
(3) be cooled to 35～40 ℃, regulate stoste pH value to 6.0～8.0, add above-mentioned lemon flavour described in can the antimicrobial laundry liquid formula of while disinfecting and decontaminating.
(4) after-filtration that stirs, stand for standby use.
Antimicrobial laundry liquid with the disinfecting and decontaminating simultaneously behind the describedization material detect, can, decals, detection vanning.
Filtration in described (4) step is to adopt 200 order nylon screens to filter.
Technology controlling and process point of the present invention:
1. raw material takes by weighing: accurately take by weighing industrial chemicals and deionized water.
2. deionized water quality control: the entire operation process must guarantee the quality of deionized water, and Ca can not be arranged
2+, Mg
2+, Fe
2+Bring into and precipitate Deng metal ion.
3. entire operation clean environment health, dustproof.
4.pH value (stoste): 6.0～8.0.
Product performance of the present invention:
Detersive power reaches national sector standard QB1224-1991 requirement.
Sterilizing power reaches the Ministry of Health's " disinfection technology standard " requirement in 2002.
The present invention is nontoxic to human body.According to Ministry of Health's " theoretical standard of sterilizing " (version in 2002), submitted sample of the present invention is carried out chmice acute per os toxicity test (once test to greatest extent): female, male mice LD
50All greater than 5000mg/kgBW, true border is nontoxic.
The normal temperature quality guaranteed period is 24 months.
Compared with the prior art the present invention has following advantage:
1. to adopt biguanides, two quaternary amines to divide compound in the present invention, by special penetration enhancer effect, makes it useful effect in germ, improves sterilizing power, and can stably store.
2. short-chain branch type aliphatic alcohol polyethenoxy (8) the ether XL-80 of one of component of the present invention is an isocyanide acids linking agent, and very strong infiltration promoter action is arranged, and can promote active ingredient to move to bacterium surface and is penetrated into the inside, strengthens sterilization effect; Also can promote the decontamination component to be penetrated into and assist decontamination in the dirt.
3. the present invention is low-consuming, the cost performance height; The laundry cost only is 1/3rd of a market like product.
Description of drawings:
Fig. 1: be process flow sheet of the present invention
Embodiment
The present invention is described further below in conjunction with embodiment, and embodiment only means never that for indicative it limits the scope of the invention by any way.
Embodiment 1:
The prescription that the antimicrobial laundry liquid of the disinfecting and decontaminating simultaneously that present embodiment provides adopts is as follows:
Prepare the described antimicrobial laundry liquid 100kg of disinfecting and decontaminating simultaneously, proportioning comprises following component by weight:
Aliphatic alcohol polyethenoxy (7) ether AEO-7 8kg
Aliphatic alcohol polyethenoxy (9) ether AEO-9 15kg
Poly hexamethylene biguanide PHMB (20%) 2.5kg
Dodecyl benzyl dimethyl ammonium chloride 1227 (45%) 4kg
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether XL-80 4kg
Aliphatic alcohol polyethenoxy (5) ether AEO-5 3kg
Lemon flavour 0.2kg
Deionized water 63.3kg
Operation steps:
1. change material
(1) with 65～75 ℃ of deionized water of 40～50%, in the addingization material still, add aliphatic alcohol polyethenoxy (7) ether AEO-7, aliphatic alcohol polyethenoxy (9) ether AEO-9, aliphatic alcohol polyethenoxy (5) ether AEO-5, short-chain branch type aliphatic alcohol polyethenoxy (8) the ether XL-80 described in the antimicrobial laundry liquid formula of above-mentioned disinfecting and decontaminating simultaneously then respectively and stir.
When (2) equitemperature dropped to 45～50 ℃ of left and right sides, it was even to add poly hexamethylene biguanide PHMB, dodecyl benzyl dimethyl ammonium chloride 1227 and the remaining deionized water and stirring of part described in the antimicrobial laundry liquid formula of above-mentioned disinfecting and decontaminating simultaneously.
Regulate stoste pH value to 6.0～8.0 when (3) being cooled to 35～40 ℃, add above-mentioned lemon flavour described in can the antimicrobial laundry liquid formula of while disinfecting and decontaminating.
(4) stir after, filter stand for standby use with 200 order nylon screens.
Antimicrobial laundry liquid with the disinfecting and decontaminating simultaneously behind the describedization material detect, can, decals, detection vanning.
The present embodiment product performance:
Detect according to Ministry of Health's 2002 " disinfection technology standard " through Beijing Disease Prevention and Control Centre, the antimicrobial laundry liquid of disinfecting and decontaminating simultaneously of the present invention is got the consumption of weight percent 0.3%, and sterilization effect is as follows:
Detersive power reaches national sector standard QB1224-1991 requirement.
Embodiment 2:
The prescription that the antimicrobial laundry liquid of the disinfecting and decontaminating simultaneously that present embodiment provides adopts is as follows:
Prepare the described antimicrobial laundry liquid 100kg of disinfecting and decontaminating simultaneously, proportioning comprises following component by weight:
Aliphatic alcohol polyethenoxy (7) ether AEO-7 20kg
Aliphatic alcohol polyethenoxy (9) ether AEO-9 5kg
Poly hexamethylene biguanide PHMB (20%) 15kg
Dodecyl benzyl dimethyl ammonium chloride 1227 (45%) 5kg
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether XL-80 8kg
Aliphatic alcohol polyethenoxy (5) ether AEO-5 2kg
Lemon flavour 0.2kg
Deionized water 44.8kg
Above-described various raw material is technical grade.
Present embodiment preparation technology is with embodiment 1.
The present embodiment product performance:
Detersive power reaches national sector standard QB1224-1991 requirement.
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.3%): streptococcus aureus: 99.99%, intestinal bacteria: 99.99%, Candida albicans: 99.3%.
Embodiment 3:
The prescription that the antimicrobial laundry liquid of the disinfecting and decontaminating simultaneously that present embodiment provides adopts is as follows:
Prepare the described antimicrobial laundry liquid 100kg of disinfecting and decontaminating simultaneously, proportioning comprises following component by weight:
Aliphatic alcohol polyethenoxy (7) ether AEO-7 5kg
Aliphatic alcohol polyethenoxy (9) ether AEO-9 20kg
Poly hexamethylene biguanide PHMB (20%) 3kg
Dodecyl benzyl dimethyl ammonium chloride 1227 (45%) 12kg
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether XL-80 2kg
Aliphatic alcohol polyethenoxy (5) ether AEO-5 5kg
Lemon flavour 0.2kg
Deionized water 53.8kg
Above-described various raw material is technical grade.
Present embodiment preparation technology is with embodiment 1.
The present embodiment product performance:
Detersive power reaches national sector standard QB1224-1991 requirement.
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.3%): streptococcus aureus: 99.88%, intestinal bacteria: 99.98%, Candida albicans: 99.1%.
Embodiment 4:
The prescription that the antimicrobial laundry liquid of the disinfecting and decontaminating simultaneously that present embodiment provides adopts is as follows:
Prepare the described antimicrobial laundry liquid 100kg of disinfecting and decontaminating simultaneously, proportioning comprises following component by weight:
Aliphatic alcohol polyethenoxy (7) ether AEO-7 3kg
Aliphatic alcohol polyethenoxy (9) ether AEO-9 5kg
Poly hexamethylene biguanide PHMB (20%) 0.8kg
Dodecyl benzyl dimethyl ammonium chloride 1227 (45%) 1kg
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether XL-80 2kg
Aliphatic alcohol polyethenoxy (5) ether AEO-5 0.3kg
Lemon flavour 0.2kg
Deionized water 87.7kg
Above-described various raw material is technical grade.
Present embodiment preparation technology is with embodiment 1.
The present embodiment product performance:
Detersive power reaches national sector standard QB1224-1991 requirement.
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.3%): streptococcus aureus: 98.2%, intestinal bacteria: 99.2%, Candida albicans: 55%.
This shows that poly hexamethylene biguanide PHMB in the present embodiment, dodecyl benzyl dimethyl ammonium chloride 1227, short-chain branch type fatty alcohol-polyoxyethylene ether (8) XL-80 content are low, cause for the sterilizing power of Candida albicans low.Therefore, each component rational proportion is very important among the present invention.
Embodiment 5:
The prescription that the antimicrobial laundry liquid of the disinfecting and decontaminating simultaneously that present embodiment provides adopts is as follows:
Prepare the described antimicrobial laundry liquid 100kg of disinfecting and decontaminating simultaneously, proportioning comprises following component by weight:
Aliphatic alcohol polyethenoxy (7) ether AEO-7 8kg
Aliphatic alcohol polyethenoxy (9) ether AEO-9 15kg
Poly hexamethylene biguanide PHMB (20%) 0.5kg
Dodecyl benzyl dimethyl ammonium chloride 1227 (45%) 1kg
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether XL-80 0kg
Aliphatic alcohol polyethenoxy (5) ether AEO-5 2.5kg
Lemon flavour 0.2kg
Deionized water 72.8kg
Above-described various raw material is technical grade.
Operation steps:
1. change material
(1) with 65～75 ℃ of deionized water of 40～50%, in the addingization material still, add aliphatic alcohol polyethenoxy (7) ether AEO-7, aliphatic alcohol polyethenoxy (9) ether AEO-9, aliphatic alcohol polyethenoxy (5) the ether AEO-5 described in the antimicrobial laundry liquid formula of above-mentioned disinfecting and decontaminating simultaneously then respectively.
When (2) equitemperature dropped to 45～50 ℃ of left and right sides, it was even to add poly hexamethylene biguanide PHMB, dodecyl benzyl dimethyl ammonium chloride 1227 and the remaining deionized water and stirring of part described in the antimicrobial laundry liquid formula of above-mentioned disinfecting and decontaminating simultaneously.
Regulate stoste pH value to 6.0～8.0 when (3) being cooled to 35～40 ℃, add above-mentioned lemon flavour described in can the antimicrobial laundry liquid formula of while disinfecting and decontaminating.
(4) stir after, filter stand for standby use with 200 order nylon screens.
Antimicrobial laundry liquid with the disinfecting and decontaminating simultaneously behind the describedization material detect, can, decals, detection vanning.
The present embodiment product performance:
Detersive power reaches national sector standard QB1224-1991 requirement.
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.3%): streptococcus aureus: 20%.
This shows that poly hexamethylene biguanide PHMB in the present embodiment, dodecyl benzyl dimethyl ammonium chloride 1227 content are low, and do not add short-chain branch type aliphatic alcohol polyethenoxy (8) ether XL-80, cause for the streptococcus aureus sterilizing power low.Therefore, short-chain branch type aliphatic alcohol polyethenoxy (8) ether XL-80 is important component among the present invention, and each component rational proportion is very important among the present invention.
Claims (6)
1. antimicrobial laundry liquid of disinfecting and decontaminating simultaneously is characterized in that described antimicrobial laundry liquid proportioning by weight is made up of following component:
Aliphatic alcohol polyethenoxy (7) ether 1～25
Aliphatic alcohol polyethenoxy (9) ether 1～20
20% poly hexamethylene biguanide 0.1～20
45% dodecyl benzyl dimethyl ammonium chloride 0.3～15
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 0.1～10
Aliphatic alcohol polyethenoxy (5) ether 0.15～16
Lemon flavour 0.2
Deionized water 40～75.
2. a kind of antimicrobial laundry liquid of disinfecting and decontaminating simultaneously according to claim 1 is characterized in that described antimicrobial laundry liquid proportioning by weight is made up of following component:
Aliphatic alcohol polyethenoxy (7) ether 8
Aliphatic alcohol polyethenoxy (9) ether 15
20% poly hexamethylene biguanide 2.5
45% dodecyl benzyl dimethyl ammonium chloride 4
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 4
Aliphatic alcohol polyethenoxy (5) ether 3
Lemon flavour 0.2
Deionized water 63.3.
3. a kind of antimicrobial laundry liquid of disinfecting and decontaminating simultaneously according to claim 1 is characterized in that described antimicrobial laundry liquid proportioning by weight is made up of following component:
Aliphatic alcohol polyethenoxy (7) ether 20
Aliphatic alcohol polyethenoxy (9) ether 5
20% poly hexamethylene biguanide 15
45% dodecyl benzyl dimethyl ammonium chloride 5
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 8
Aliphatic alcohol polyethenoxy (5) ether 2
Lemon flavour 0.2
Deionized water 44.8.
4. a kind of antimicrobial laundry liquid of disinfecting and decontaminating simultaneously according to claim 1 is characterized in that described antimicrobial laundry liquid proportioning by weight is made up of following component:
Aliphatic alcohol polyethenoxy (7) ether 5
Aliphatic alcohol polyethenoxy (9) ether 20
20% poly hexamethylene biguanide 3
45% dodecyl benzyl dimethyl ammonium chloride 12
Short-chain branch type aliphatic alcohol polyethenoxy (8) ether 2
Aliphatic alcohol polyethenoxy (5) ether 5
Lemon flavour 0.2
Deionized water 53.8.
5. a kind of preparation method of the antimicrobial laundry liquid of disinfecting and decontaminating simultaneously as claimed in claim 1 is characterized in that described preparation method's processing step is:
A. with 65～75 ℃ of deionized waters of 40～50%, in the addingization material still, add aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (5) ether, short-chain branch type aliphatic alcohol polyethenoxy (8) ether described in the antimicrobial laundry liquid formula of above-mentioned disinfecting and decontaminating simultaneously then respectively and stir;
When b. equitemperature dropped to 45～50 ℃, it was even to add the remaining deionized water and stirring of poly hexamethylene biguanide, dodecyl benzyl dimethyl ammonium chloride and part described in the antimicrobial laundry liquid formula of above-mentioned disinfecting and decontaminating simultaneously;
Regulate stoste pH value to 6.0～8.0 when c. being cooled to 35～40 ℃, add above-mentioned lemon flavour described in can the antimicrobial laundry liquid formula of while disinfecting and decontaminating.
D. after stirring, filter, stand for standby use gets product.
6. the preparation method of antimicrobial laundry liquid according to claim 5 is characterized in that, the filtration in the described d step is to adopt 200 order nylon screens to filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007101796704A CN100554393C (en) | 2007-12-17 | 2007-12-17 | Antimicrobial laundry liquid of a kind of disinfecting and decontaminating simultaneously and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007101796704A CN100554393C (en) | 2007-12-17 | 2007-12-17 | Antimicrobial laundry liquid of a kind of disinfecting and decontaminating simultaneously and preparation method thereof |
Publications (2)
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| CN101220320A CN101220320A (en) | 2008-07-16 |
| CN100554393C true CN100554393C (en) | 2009-10-28 |
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|---|---|---|---|
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101513197B (en) * | 2008-12-31 | 2012-07-25 | 北京绿伞化学股份有限公司 | Sterilization and disinfection solution for cleaning tissues and method for preparing sterilization and disinfection cleaning tissues |
| CN101828884A (en) * | 2010-05-04 | 2010-09-15 | 江西生成卫生用品有限公司 | Pet cleaning pad |
| CN101851564B (en) * | 2010-06-28 | 2013-05-08 | 上海制皂(集团)如皋有限公司 | Laundry detergent used for washing underwear |
| CN101933512A (en) * | 2010-07-05 | 2011-01-05 | 高旭 | Disinfectant capable of being used with high dilution multiples, preparation method and application |
| CN102047886B (en) * | 2010-11-29 | 2013-05-29 | 陕西永泰生物工程有限责任公司 | Antibacterial composition for washing machines and preparation method thereof |
| CN102816646A (en) * | 2012-09-14 | 2012-12-12 | 苏州谷力生物科技有限公司 | Bacteriostatic bleaching laundry detergent for hospitals and preparation method thereof |
| CN103194326B (en) * | 2013-04-28 | 2015-06-17 | 北京绿伞化学股份有限公司 | Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent |
| CN104789383A (en) * | 2015-05-19 | 2015-07-22 | 胡洪梅 | Antibacterial washing liquid |
| CN105112174B (en) * | 2015-09-10 | 2018-01-23 | 辽宁石化职业技术学院 | A kind of fungus and mildew resistance liquid detergent |
| CN105820888A (en) * | 2016-04-21 | 2016-08-03 | 刘爱华 | Decontaminating bactericidal clothing detergent |
| CN108410593B (en) * | 2018-03-27 | 2020-03-10 | 台州中知英健机械自动化有限公司 | Multi-effect laundry detergent and preparation method thereof |
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2007
- 2007-12-17 CN CNB2007101796704A patent/CN100554393C/en active Active
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Denomination of invention: Antimicrobial laundry liquid capable of disinfecting and decontaminating meanwhile, and method for producing the same Effective date of registration: 20111220 Granted publication date: 20091028 Pledgee: Beijing Haidian science and technology enterprise risk Company Limited by Guarantee Pledgor: Beijing Lusan Chemical Co., Ltd. Registration number: 2011990000498 |
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