CN106906053A - A kind of liquid detergent containing polylysine and shitosan and preparation method and application - Google Patents
A kind of liquid detergent containing polylysine and shitosan and preparation method and application Download PDFInfo
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- CN106906053A CN106906053A CN201710051687.5A CN201710051687A CN106906053A CN 106906053 A CN106906053 A CN 106906053A CN 201710051687 A CN201710051687 A CN 201710051687A CN 106906053 A CN106906053 A CN 106906053A
- Authority
- CN
- China
- Prior art keywords
- liquid detergent
- shitosan
- polylysine
- parts
- citric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007788 liquid Substances 0.000 title claims abstract description 58
- 239000003599 detergent Substances 0.000 title claims abstract description 56
- 108010039918 Polylysine Proteins 0.000 title claims abstract description 42
- 229920000656 polylysine Polymers 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000002253 acid Substances 0.000 claims abstract description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 239000004744 fabric Substances 0.000 claims description 9
- 239000011780 sodium chloride Substances 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- 238000013329 compounding Methods 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims description 2
- -1 preferably nonionic Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 7
- 241000894006 Bacteria Species 0.000 abstract description 3
- 241000192125 Firmicutes Species 0.000 abstract description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 2
- 230000006641 stabilisation Effects 0.000 abstract description 2
- 238000011105 stabilization Methods 0.000 abstract description 2
- 230000001236 detergent effect Effects 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 8
- 230000001408 fungistatic effect Effects 0.000 description 4
- 230000003385 bacteriostatic effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000006101 laboratory sample Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C11D2111/12—
Abstract
The present invention relates to a kind of liquid detergent containing polylysine and shitosan, wherein comprising polylysine and shitosan, the weight ratio of the two is 1:5~35；Also liquid detergent pH value is set to be in faintly acid or neutrality comprising citric acid.The present invention shares polylysine with shitosan, and the amount ratio of the two is optimized, shitosan can be made to be acted on by amino and to strengthen bactericidal effect of the polylysine for gram-positive bacteria, Gram-negative bacteria and mould, especially improve the long-acting bactericidal effect of liquid detergent；Appropriate citric acid is further added in the liquid detergent, the faintly acid neutral system of stabilization can be formed by citric acid balanced action, while appropriate effect environment being provided for polylysine and shitosan, reduce infringement of the liquid detergent to clothing, and softness can be made good, and keep its script color and quality.The liquid detergent effect that the present invention is provided is comprehensive, with extremely strong market popularization value.
Description
Technical field
The present invention relates to filed of daily-use chemical industry, and in particular to a kind of liquid detergent containing polylysine and shitosan and its system
Preparation Method.
Background technology
Liquid detergent is a kind of new articles for washing, its operation principle and traditional washing powder, and soap kind is same, active ingredient
All it is surfactant, but is with alkyl sulfonic acid because traditional washing powder, soap use anionic surfactant
Based on sodium and odium stearate, alkalescence is relatively strong, and then stimulation when in use to skin and injures larger.And liquid detergent is when in use
It is gentle to skin, and after entering nature, degraded is fast compared with washing powder, so becoming the detergent of a new generation.
Although however, at present the bactericidal effect of existing liquid detergent short time still, long-acting bactericidal less effective, and right
The nocuity of clothing is stronger.
The content of the invention
In order to overcome the defect of prior art, polylysine and shitosan liquid detergent are contained the invention provides one kind, should
Liquid detergent clean result especially long-acting bactericidal excellent effect, and wash that rear softness is good, the retentivity of color and quality is good
It is good.
Specifically, polylysine and shitosan are included in the liquid detergent that the present invention is provided, the weight ratio of the two is 1:5~
35；Wherein also liquid detergent pH value is set to be in faintly acid or neutrality comprising citric acid.
In order to further for polylysine and shitosan provide the best use of environment, and improve the submissive effect and color of clothing
Pool, makes liquid detergent pH value be 4.5~7.0 in the liquid detergent comprising citric acid.
The weight ratio of the preferably polylysine and shitosan of the invention is 1:8~34, more preferably 1:8~10.
The present invention shares polylysine with shitosan, and the amount ratio of the two is optimized, and can lead to shitosan
Cross amino effect and strengthen bactericidal effect of the polylysine for gram-positive bacteria, Gram-negative bacteria and mould；Further exist
Appropriate citric acid is added in the liquid detergent, the faintly acid-neutral system of stabilization can be formed by citric acid balanced action, be
While polylysine and shitosan provide appropriate effect environment, it is possible to reduce infringement of the liquid detergent to clothing, and improve clothing
Compliance after washing, and keep its script color and quality.
In order to further improve the synergy of the two, the molecular weight of polylysine of the present invention is 3000~5000,
Preferably 3500~4500.The molecular weight of this hair preferably shitosan is 9000~100000, preferably 10000~80000.
In order to realize the abundant clean result of liquid detergent, surfactant is also contained in the liquid detergent.Live on the surface
The consumption of property agent ensures to realize its clean result.In order to adapt to the liquid detergent system of present invention offer, strengthen its cleaning effect
Really, the surfactant can select activating agent of nonionic, amphoteric surfactant or the two compounding, it is specific and
Speech, can select Cocoamidopropyl betaine, sodium sulfate of polyethenoxy ether of fatty alcohol in one or two.
Can also further contain sodium chloride and deionized water in liquid detergent of the present invention.
Appropriate amount of essence can also be contained in the liquid detergent, to meet demand of the client to smell.
As a kind of concrete scheme of the invention, the composition comprising following weight portion in the liquid detergent：Polylysine 0.3
~1 part, 5~10 parts of shitosan, 2~3 parts of sodium chloride, 15~30 parts of surfactant, 60~75 parts of deionized water；Also contain lemon
Lemon acid makes liquid detergent pH value be in 4.5~7.0.
As a kind of concrete scheme of the invention, the composition comprising following weight portion in the liquid detergent：Polylysine 0.3
~1 part, 5~10 parts of shitosan, 0.5~0.8 part of citric acid, 2~3 parts of sodium chloride, 18~25 parts of surfactant, deionized water
63~73 parts.
Surfactant described above is the one kind in nonionic, amphoteric surfactant, or by the two compounding
Into；One or two preferably in Cocoamidopropyl betaine, sodium sulfate of polyethenoxy ether of fatty alcohol.
The molecular weight of above-mentioned polylysine is 3000~5000, preferably 3500~4500；The molecular weight of above-mentioned shitosan
It is 9000~100000, preferably 10000~80000.
The present invention is by by polylysine, shitosan and appropriate sodium chloride, surfactant and containing citric acid
The aqueous solution is used cooperatively, and under conditions of faintly acid or neutrality, each component can be made to play synergy to greatest extent, it is ensured that
The washing of liquid detergent, bactericidal effect, and maintain the compliance and fresh colour of clothing.
The liquid detergent that the present invention is provided is prepared from after each component can be mixed according to the conventional method of this area.
As preferred scheme of the invention, aqueous citric acid solution can be dissolved the chitosan in, add polylysine abundant
Dissolving.After above-mentioned steps terminate, then other compositions comprising surfactant are added in solution, be sufficiently mixed i.e.
Can.
The preferred preparation method that the present invention is provided defines that shitosan and polylysine are dissolved in the suitable of aqueous citric acid solution
Sequence, so that it is guaranteed that shitosan and polylysine are sufficiently mixed and play a role under suitable environment.
The liquid detergent that the present invention is provided has extremely excellent clean result to string and/or animal origin fabric.This
Application of the liquid detergent in washing string and/or animal origin fabric is further protected in invention, preferably in washing cotton
Application in fabric, linen, wool fabric and/or silk fabric.
Compared with prior art, especially bactericidal effect is excellent for the liquid detergent clean result that the present invention is provided, and washes rear clothing
Thing compliance is good, and the retentivity of color and quality is good.
Specific embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
Embodiment 1
A kind of liquid detergent comprising polylysine and shitosan is present embodiments provided, consisting of：Polylysine 0.5g,
Shitosan 5g, Cocoamidopropyl betaine 18g, essence 0.2g, sodium chloride 3g, citric acid 0.5g, deionized water 72.8g；
The molecular weight of the polylysine is 3800, and the molecular weight of the shitosan is 50000.
Embodiment 2
Present embodiments provide a kind of liquid detergent comprising polylysine and shitosan, polylysine 1g, shitosan 8g, fat
Fat alcohol polyethenoxy ether sodium sulfate 25g, essence 0.2g, sodium chloride 2g, citric acid 0.8g, deionized water 63g；
The molecular weight difference of the polylysine and shitosan is same as Example 1.
Embodiment 3
Present embodiments provide a kind of liquid detergent comprising polylysine and shitosan, polylysine 0.3g, shitosan
10g, Cocoamidopropyl betaine 20g, essence 0.2g, sodium chloride 2g, citric acid 0.8g, deionized water 66.7g；
The molecular weight difference of the polylysine and shitosan is same as Example 1.
Comparative example 1
Compared with Example 1, differ only in, shitosan is not contained in the liquid detergent.
Comparative example 2
Compared with Example 1, differ only in, polylysine is not contained in the liquid detergent.
Comparative example 3
Compared with Example 1, differ only in, the consumption of the shitosan is 2g.
Comparative example 4
Compared with Example 1, differ only in, the consumption of the shitosan is 20g.
Experimental example 1：Clean result is tested；
Example 1~3, comparative example 1~4 and common commercially available liquid detergent, conventionally wash cotton clothes.
Clean result is as shown in table 1.
Table 1：Clean result
Experimental example 2：Bactericidal effect is tested
Example 1~3, comparative example 1~4 and common commercially available liquid detergent are used as laboratory sample.Each group is tested into sample
Product are according to mass ratio 2:100 ratio mixes with water, after the fabric of a diameter of 5mm is inoculated with into mould and Escherichia coli bacteria liquid respectively
Immersion is wherein, it is desirable to be totally submerged, and soaks 30min.40 DEG C of aseptic drying after being pressed from both sides out with clean tweezers, are subsequently placed in culture medium
Culture 30min, observes clump count, records short-acting fungistatic effect.Further, continue to extend observing time to 36h, record bacterium colony
Growing state, detects its long-acting bacteriostatic effect.By the total plate count on 500 times of electron microscope observation culture mediums, length is judged
Effect fungistatic effect, as a result as shown in table 2.
Table 2：Fungistatic effect
From result above, the liquid detergent that the present invention is provided is better than commonly washing for the long-acting bacteriostatic effect is significant of clothing
Clothing liquid and each comparative example.Although the short-acting fungistatic effect of comparative example 3 and 4 is close with each embodiment, long-acting bacteriostatic effect is obvious
It is worse than embodiment 1~3.
Although above having used general explanation, specific embodiment and experiment, the present invention is made to retouch in detail
State, but on the basis of the present invention, it can be made some modifications or improvements, this is to those skilled in the art apparent
's.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to claimed
Scope.
Claims (10)
1. a kind of liquid detergent containing polylysine and shitosan, it is characterised in that comprising polylysine and shitosan, the two
Weight ratio is 1:5~35；
Also make liquid detergent pH value in faintly acid or neutrality comprising citric acid, preferably make liquid detergent pH value be 4.5~7.0.
2. liquid detergent according to claim 1, it is characterised in that the weight ratio of the polylysine and shitosan is 1:8
~34, preferably 1:8~10.
3. liquid detergent according to claim 1 and 2, it is characterised in that the molecular weight of the polylysine is 3000~
5000, preferably 3500~4500；
And/or, the molecular weight of the shitosan is 9000~100000, preferably 10000~80000.
4. the liquid detergent according to claims 1 to 3 any one, it is characterised in that also contain surface in the liquid detergent
One kind in activating agent, preferably nonionic, amphoteric surfactant, or formed by the two compounding；
One or two more preferably in Cocoamidopropyl betaine, sodium sulfate of polyethenoxy ether of fatty alcohol.
5. the liquid detergent according to Claims 1 to 4 any one, it is characterised in that also contain chlorination in the liquid detergent
Sodium and deionized water.
6. it is a kind of to contain polylysine and shitosan liquid detergent, it is characterised in that the composition comprising following weight portion：Polylysine
0.3~1 part, 5~10 parts of shitosan, 2~3 parts of sodium chloride, 15~30 parts of surfactant, 60~75 parts of deionized water；Also contain
Having citric acid makes liquid detergent pH value be in 4.5~7.0；
Or, the composition comprising following weight portion：0.3~1 part of polylysine, 5~10 parts of shitosan, 0.5~0.8 part of citric acid,
2~3 parts of sodium chloride, 18~25 parts of surfactant, 63~73 parts of deionized water.
7. liquid detergent according to claim 6, it is characterised in that the molecular weight of the polylysine is 3000~5000,
Preferably 3500~4500；
And/or, the molecular weight of the shitosan is 9000~100000, preferably 10000~80000.
8. the liquid detergent according to claim 6 or 7, it is characterised in that the surfactant is nonionic, amphoteric
One kind in surfactant, or formed by the two compounding；Preferably Cocoamidopropyl betaine, AEO
One or two in sodium sulphate.
9. the preparation method of liquid detergent described in claim 1~8 any one, it is characterised in that comprise the following steps：Shell is gathered
Sugar is dissolved in aqueous citric acid solution, adds polylysine and fully dissolves.
10. application of the liquid detergent described in claim 1~8 any one in washing string and/or animal origin fabric,
It is preferred that the application in washing bafta, linen, wool fabric and/or silk fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710051687.5A CN106906053A (en) | 2017-01-20 | 2017-01-20 | A kind of liquid detergent containing polylysine and shitosan and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710051687.5A CN106906053A (en) | 2017-01-20 | 2017-01-20 | A kind of liquid detergent containing polylysine and shitosan and preparation method and application |
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|---|---|
| CN106906053A true CN106906053A (en) | 2017-06-30 |
Family
ID=59207323
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|---|---|---|---|
| CN201710051687.5A Pending CN106906053A (en) | 2017-01-20 | 2017-01-20 | A kind of liquid detergent containing polylysine and shitosan and preparation method and application |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107929232A (en) * | 2017-11-21 | 2018-04-20 | 北京德得创业科技有限公司 | A kind of multiple-effect restraining and sterilizing bacteria repairs gel and preparation method and application |
| CN112368349A (en) * | 2018-08-31 | 2021-02-12 | Cj第一制糖株式会社 | Adhesive composition for label, method for preparing the same, adhesive sheet comprising the same, and object comprising the adhesive sheet |
| CN112877149A (en) * | 2021-02-05 | 2021-06-01 | 杭州诗茵服饰有限公司 | Cleaning agent suitable for white jean fabric and preparation method thereof |
| US11624028B2 (en) | 2018-08-31 | 2023-04-11 | Cj Cheiljedang Corporation | Method of suppressing dust generation, soil stabilizing composition, and spray device including soil stabilizing composition |
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| CN112368349B (en) * | 2018-08-31 | 2023-01-10 | Cj第一制糖株式会社 | Adhesive composition, preparation method thereof, adhesive sheet body containing adhesive composition and product |
| US11624028B2 (en) | 2018-08-31 | 2023-04-11 | Cj Cheiljedang Corporation | Method of suppressing dust generation, soil stabilizing composition, and spray device including soil stabilizing composition |
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