CN106635500A - Down garment detergent and production method thereof - Google Patents
Down garment detergent and production method thereof Download PDFInfo
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- CN106635500A CN106635500A CN201611210573.2A CN201611210573A CN106635500A CN 106635500 A CN106635500 A CN 106635500A CN 201611210573 A CN201611210573 A CN 201611210573A CN 106635500 A CN106635500 A CN 106635500A
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- Prior art keywords
- feather
- cleaning agent
- agent
- clothing cleaning
- down clothing
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/16—Anti-static materials
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2037—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of daily chemical detergents, and in particular relates to a down garment detergent and a production method thereof. The down garment detergent is prepared from the following components by mass percent: 20-30% of a surface active agent, 8-12% of a bacteriostatic agent, 1-3% of a chelating agent, 0.5-2% of sodium citrate, 0.5-2% of citric acid, 1-3% of a preservative and 48-69% of water. The down garment detergent has the technical advantages that a mild buffer system is formed by compounding the sodium citrate and the citric acid, so that the pH value of the detergent system is close to that of the skin of a human body, the down garment detergent is mild in performance, and the damage to azelon can be reduced; furthermore, the down garment detergent has good effects of decontaminating, removing bacteria and resisting static electricity.
Description
Technical field
The invention belongs to daily use chemicals detergent technical field, and in particular to a kind of feather-down clothing cleaning agent and its manufacture method.
Background technology
Eider down is widely used in making down jackets, but because eider down comes from animal, generally with more bacterium, there is fishy smell,
For the articles for washing played the part of, foul can be washed away, but without sterilizing function, and eider down is easily damaged, and cause hardened, no longer have
Elasticity originally and fluffy sense, thermal property is reduced, therefore urgent need research has washing, nursing and sterilizing function concurrently to eider down and takes into account
Cleaning agent.
Chinese patent application CN104312762A discloses down detergent, by triethanolamine, octadecane alcohol radical polyoxy second
Alkene ether, polyoxylethylene abietate, polyglycerol monostearate, hydroxypropyl methyl cellulose, sodium laurate, dodecyl front three
Base ammonium sulfate, sodium peroxydisulfate, N- octylisothiazolinones, phenyl silicone oil, aminomethyl propanol, morpholine, sodium acid carbonate, Tea Polyphenols,
Vinyl trimethylsilane, polyisobutene, polyvinylpyrrolidone, dimeric dibasic acid, maleic anhydride modified polyethylene.But the eider down is clear
The complicated popularization and application more difficult in actual production of lotion formulation.
Chinese patent CN101985584B discloses a kind of silk sweater detergent composition and preparation method thereof, by water,
Aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (7) ether, Dodecyl Polyoxyethylene Ether sodium sulphate, amphoteric imidazoline, nonyl
Base phenol polyethenoxy (10) ether, coconut acid diethanolamide, essence, ethylenediamine tetra-acetic acid and sodium chloride composition, wherein nonyl
Phenol polyethenoxy (10) ether is poor because of its degradability, successively by many country's disablings.
Still lack at present it is a kind of can and meanwhile be used for silk, wool or silk hair knot close or feather-down clothing cleaning cleaning agent,
The destruction to azelon is reduced, while with excellent clean effect and protection opsonic action.
The content of the invention
To solve problems of the prior art, the present invention provides a kind of feather-down clothing cleaning agent and its manufacture method.
Feather-down clothing cleaning agent of the present invention, including following components and its mass percent：
Surfactant 20～30%, bacteriostatic agent 8～12%, chelating agent 1～3%, sodium citrate 0.5～2%, citric acid
0.5～2%, preservative 1～3% and water 48～69%.
Preferably, described feather-down clothing cleaning agent, is made up of following components and its mass percent：
Surfactant 25%, bacteriostatic agent 10%, chelating agent 2%, sodium citrate 1%, citric acid 1.5%, preservative 2%
With water 58.5%.
Preferably, described surfactant by ethoxylated dodecyl alcohol, alkylpolyoxyethylene sodium sulphate and
Cocamidopropyl betaine in mass ratio 2:3:5 compositions.
Preferably, described bacteriostatic agent is by terpinol and γ-terpinene in mass ratio 3:5 compositions.
Preferably, described chelating agent is disodium ethylene diamine tetraacetate.
Further preferably, described preservative is borax.
In addition, present invention also offers a kind of manufacture method of feather-down clothing cleaning agent, comprises the following steps：The side in water
Stirring side adds surfactant；Bacteriostatic agent, chelating agent and preservative are added, is stirred；Add sodium citrate and citric acid
Stir, obtain final product.
Ethoxylated dodecyl alcohol CAS：9002-92-0；Alkylpolyoxyethylene sodium sulphate CAS：68585-
34-2；Cocamidopropyl betaine CAS：86243-76-7；Terpinol CAS：8000-41-7；γ-terpinene CAS
Number：99-85-4；Disodium ethylene diamine tetraacetate CAS：139-33-3；Borax CAS：1303-96-4.
Ethoxylated dodecyl alcohol of the present invention is a kind of nonionic surfactant, alkylpolyoxyethylene sodium sulphate
A kind of anion surfactant, cocamidopropyl betaine is a kind of zwitterionic surfactant, acid and
Excellent stability is respectively provided with alkalescence condition, respectively presentation male and female is ionic, is often lived with anions and canons and non-ionic surface
Property agent be used in combination, its compatibility is good, and excitant is little, soluble in water, to ph stability, can significantly improve the soft of washing class product
Soft, conditioning and low-temperature stability, in washing process, ethoxylated dodecyl alcohol can quickly ooze as nonionic surfactant
Emulsification thoroughly, coordinates anion surfactant alkylpolyoxyethylene sodium sulphate rapidly and efficiently to remove various dirts；In addition
Nonionic surfactant cocamidopropyl betaine in formula can occur accordingly with the change of wash environment pH
Change, in the environment of slant acidity, shows as cationic surfactant, and electrostatic, submissive effect are gone in increase, and neutral or
In the environment of meta-alkalescence, then anion surfactant can be well coordinated to play cleaning performance, while can remove well quiet
The generation of electricity and minimizing electrostatic, brings submissive effect.
Terpinol and γ-terpinene have good fungistatic effect, prevent the excessive health risk of bacteria breed.
Disodium ethylene diamine tetraacetate is that chelating agent has widely with bit function, almost can be formed with all of metal ion
Stable chelate, for complexation of metal ions and separation metal.
Borax, also known as sodium tetraborate, is very important containing boron mineral and boron compound, be can be used as with widely purposes
Cleaning agent, insecticide can also be used for configuring cushioning liquid and produce other boron compounds etc..
Compatibility of the present invention is reasonable, science, and each component cooperates, acts synergistically, and makes the cleaning agent ensure feather-down clothing
There is good cleaning performance on the basis of texture.
Compared with prior art, it is of the invention it is a technical advantage that：Sodium citrate and citric acid compounding constitute gentle delaying
System is rushed, the pH value and human body skin for making cleaning agent system is close to, and moderate performance can reduce the destruction to azelon, while
With excellent decontamination, degerming and antistatic effect.
Specific embodiment
The present invention is described in further details below by specific embodiment, these embodiments are only used for the mesh of illustration
, it is in no way intended to limit protection scope of the present invention.
Embodiment 1-3, comparative example 1-2
Table 1 lists the component and mass percent of embodiment of the present invention 1-3 and comparative example 1-2 feather-down clothing cleaning agent.
The component and mass percent of the embodiment of table 1 and comparative example feather-down clothing cleaning agent
Comparative example 1 is with the difference of embodiment 2：Surfactant is by ethoxylated dodecyl alcohol, dodecanol polyoxy
Ethene ether sodium sulfate and cocamidopropyl betaine in mass ratio 1:1:1 composition.
Comparative example 2 is with the difference of embodiment 2：Bacteriostatic agent is by terpinol and γ-terpinene in mass ratio 1:1 composition.
The manufacture method of the feather-down clothing cleaning agent of embodiment 2：Xiang Shuizhong adds while stirring surfactant；Add antibacterial
Agent, chelating agent and preservative, stir；Add sodium citrate and citric acid to stir, obtain final product.
The manufacture method of embodiment 1, embodiment 3 and comparative example 1-2 feather-down clothing cleaning agent is similar to Example 2.
Properties of product evaluation test
Test example 1：The present invention is tested for the cleaning effect of feather-down clothing cleaning agent
According to GB/T13174-2008《Dress material detergent detergency and the measure of cycle performance》It is middle to determine the present invention in fact
Apply example and comparative example prepares the cleaning effect of cleaning agent, as shown in table 2.
The cleaning effect of the embodiment of table 2 and comparative example eider down cleaning agent
As shown in Table 2, the cleaning effect of embodiment of the present invention 1-3 feather-down clothing cleaning agent is good, illustrates poly- using laruyl alcohol
Oxygen vinethene, dodecanol polyethenoxy ether sodium sulfate and cocamidopropyl betaine in mass ratio 2:3:5 combine other
Raw material compounding use has good clean result to dirt, grease for being attached on eider down, silk etc., at the same do not injure silk,
The natural protein fiber such as wool and eider down, the wherein cleaning effect of embodiment 2 are optimal, and carbon black, albumen and sebum ratio highest are said
The synergy of each raw material of bright embodiment 2 and proportioning is best.
Test example 2：Antibacterial, the bacteriostatic test of feather-down clothing cleaning agent of the present invention.
According to QB/T2738-2012《The evaluation method of daily chemical products antibacterial bacteriostatic effect》In simulation determine the present invention
Antibacterial effect (action time 20min, the activity 1 of feather-down clothing cleaning agent prepared by embodiment and comparative example:100).
The antibacterial effect of the embodiment of table 3 and comparative example feather-down clothing cleaning agent
The fungistatic effect of the embodiment of table 4 and comparative example feather-down clothing cleaning agent
Can be seen that embodiment of the present invention 1-3 compared with comparative example 2 for ETEC and golden yellow Portugal by table 3 and table 4
The sterilizing rate and bacteriostasis rate of grape coccus is high compared with comparative example 2, illustrates bacteriostatic agent of the present invention by terpinol and γ-terpinene in mass ratio
3:5 compositions have more preferable bactericidal effect.
Test example 3：The antistatic property test of eider down cleaning agent of the present invention
According to GB/T16801-1997《The measure of fabric conditioner antistatic property》Determine the embodiment of the present invention and contrast
The antistatic effect of cleaning agent prepared by example, as a result as shown in table 5.
The antistatic effect (electrostatic potential range of decrease %) of the embodiment of table 5 and comparative example feather-down clothing cleaning agent
As can be seen from Table 5, embodiment of the present invention 1-3 antistatic effect is good, pure woolen fabric model and real silk fabric model
Electrostatic potential decreases by more than 45% Jing after the cleaning agent before processing of embodiment 2, pure woolen fabric model and real silk fabric model Jing realities
Apply electrostatic potential after example 1 and the cleaning agent before processing of embodiment 3 and decrease by more than 35%, hence it is evident that better than comparative example 1-2, illustrate this
Invention eider down cleaning agent has protection nursing, opsonic action well for silk, wool and eider down, wherein especially with embodiment 2
Electrostatic potential range of decrease highest after cleaning agent process, antistatic effect is best.Illustrate using ethoxylated dodecyl alcohol, dodecane
Alcohol polyethenoxy ether sodium sulfate and cocamidopropyl betaine in mass ratio 2:3:5 combine other raw material compounding uses for
The present invention has effect well for the nursing efficacy of silk, wool and eider down.
The above is only the preferred embodiment of the present invention, it is noted that it is right that above-mentioned preferred embodiment is not construed as
The restriction of the present invention, protection scope of the present invention should be defined by claim limited range.For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change
Enter and retouch also to should be regarded as protection scope of the present invention.
Claims (7)
1. a kind of feather-down clothing cleaning agent, it is characterised in that including following components and its mass percent：
Surfactant 20～30%, bacteriostatic agent 8～12%, chelating agent 1～3%, sodium citrate 0.5～2%, citric acid 0.5
～2%, preservative 1～3% and water 48～69%.
2. feather-down clothing cleaning agent according to claim 1, it is characterised in that by following components and its mass percent group
Into：Surfactant 25%, bacteriostatic agent 10%, chelating agent 2%, sodium citrate 1%, citric acid 1.5%, preservative 2% and water
58.5%.
3. feather-down clothing cleaning agent according to claim 1 and 2, it is characterised in that described surfactant is by bay
Alcohol APEO, alkylpolyoxyethylene sodium sulphate and cocamidopropyl betaine in mass ratio 2:3:5 compositions.
4. feather-down clothing cleaning agent according to claim 1 and 2, it is characterised in that described bacteriostatic agent by terpinol and
γ-terpinene in mass ratio 3:5 compositions.
5. feather-down clothing cleaning agent according to claim 1 and 2, it is characterised in that described chelating agent is ethylenediamine tetraacetic
Acetic acid disodium.
6. feather-down clothing cleaning agent according to claim 1 and 2, it is characterised in that described preservative is borax.
7. the manufacture method of the feather-down clothing cleaning agent according to any one of claim 1-6, it is characterised in that including following
Step：Xiang Shuizhong adds while stirring surfactant；Bacteriostatic agent, chelating agent and preservative are added, is stirred；Add lemon
Sour sodium and citric acid stir, and obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210573.2A CN106635500A (en) | 2016-12-24 | 2016-12-24 | Down garment detergent and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210573.2A CN106635500A (en) | 2016-12-24 | 2016-12-24 | Down garment detergent and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106635500A true CN106635500A (en) | 2017-05-10 |
Family
ID=58827673
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611210573.2A Pending CN106635500A (en) | 2016-12-24 | 2016-12-24 | Down garment detergent and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106635500A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974365A (en) * | 2017-11-30 | 2018-05-01 | 成都梓楠家具有限公司 | A kind of care agent for down cloth cleaning |
| CN110846142A (en) * | 2019-11-20 | 2020-02-28 | 安徽沃伦科技有限公司 | Efficient environment-friendly down jacket cleaning agent and cleaning method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104706540A (en) * | 2015-03-13 | 2015-06-17 | 江西农业大学 | Bacteriostatic agent for daily chemical products |
| CN104877802A (en) * | 2015-04-28 | 2015-09-02 | 威莱(广州)日用品有限公司 | Cleaning agent for silk-wool and/or down feather clothes and preparation method of cleaning agent |
-
2016
- 2016-12-24 CN CN201611210573.2A patent/CN106635500A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104706540A (en) * | 2015-03-13 | 2015-06-17 | 江西农业大学 | Bacteriostatic agent for daily chemical products |
| CN104877802A (en) * | 2015-04-28 | 2015-09-02 | 威莱(广州)日用品有限公司 | Cleaning agent for silk-wool and/or down feather clothes and preparation method of cleaning agent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107974365A (en) * | 2017-11-30 | 2018-05-01 | 成都梓楠家具有限公司 | A kind of care agent for down cloth cleaning |
| CN110846142A (en) * | 2019-11-20 | 2020-02-28 | 安徽沃伦科技有限公司 | Efficient environment-friendly down jacket cleaning agent and cleaning method |
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Application publication date: 20170510 |