CN106867711A - A kind of solidifying pearl of degerming laundry and preparation method and application - Google Patents

A kind of solidifying pearl of degerming laundry and preparation method and application Download PDF

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Publication number
CN106867711A
CN106867711A CN201710123782.1A CN201710123782A CN106867711A CN 106867711 A CN106867711 A CN 106867711A CN 201710123782 A CN201710123782 A CN 201710123782A CN 106867711 A CN106867711 A CN 106867711A
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CN
China
Prior art keywords
degerming
pearl
laundry
bactericide
solidifying pearl
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201710123782.1A
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Chinese (zh)
Inventor
杜桂彬
孙明
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GUANGZHOU NANDA INDUSTRIAL Co Ltd
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GUANGZHOU NANDA INDUSTRIAL Co Ltd
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Priority to CN201710123782.1A priority Critical patent/CN106867711A/en
Publication of CN106867711A publication Critical patent/CN106867711A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2041Dihydric alcohols
    • C11D3/2044Dihydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609Protease or amylase in solid compositions only
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38627Preparations containing enzymes, e.g. protease or amylase containing lipase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Abstract

The invention discloses one kind solidifying pearl of degerming laundry and preparation method and application, the formula of the degerming solidifying pearl of laundry includes Lao Ruitan FT1379 activating agents, sodium alkyl sulfate, the carbon alcohol APEO of isomery 13, polyalcohol, bactericide, enzyme, essence, preservative and deionized water;Bactericide is the mixture of the quality such as Ao Legang essential oils, pot marigold essential oil and cinnamaldehyde oil.The present invention is gentle using decontamination main body, low stimulation, degradable surface activator composition, and good cooperative effect can be produced between vegetalitas antiseptic, antibacterial effect is improved, while so that product has good detergency ability.The botanical fungicide performance safety contained in inventive formulation, excitant is low, to human body without potential hazard, degerming efficiency high.

Description

A kind of solidifying pearl of degerming laundry and preparation method and application
Technical field
The invention belongs to household chemicals field, and in particular to a kind of degerming solidifying pearl of laundry and preparation method and application.
Background technology
The solidifying pearl of laundry is a kind of new clothing and textile product cleaning product, and the country has just listed soon.Presently commercially available The solidifying pearl of laundry typically only has washing, submissive and arrangement function, seldom has antibiotic and sterilizing function, it is impossible to meet cleaning clothing comprehensively In the case of having patient in the requirement of thing, especially family.Additionally, in people's daily life, especially living in public places Clothing when dynamic also becomes easily infected by all kinds of germs, therefore, it is possible to clothing is comprehensively cleaned and sterilization processing the solidifying pearl of laundry With important application value.
Chinese patent (application number:201610712928.1) a kind of remarkable sterilized laundry solidifying pearl and its preparation side are disclosed Method, the bactericide for using is triclosan (triclosan), but U.S.'s food and Drug Administration prohibited selling with issue in 2016 Order, will prohibit selling containing 19 kinds of antimicrobial products of sterilization component comprehensively, and including triclosan, FDA thinks that triclosan can be to strong Kang Zaocheng potential hazards.
Chinese patent (application number:201510437124.0) solidifying pearl of a kind of multifunctional laundry and preparation method thereof is disclosed, The patent formulation also adds antibacterial components triclosan.
The content of the invention
In order to overcome the deficiencies in the prior art and shortcoming, primary and foremost purpose of the invention is to provide a kind of degerming laundry to coagulate Pearl.The solidifying pearl of the laundry has good detergency ability, can effectively remove spot.Meanwhile, the surface-active in the product formula Agent combination is selected by meticulous, with hypotoxicity, low irritant, good biological degradability and compatibility, can be with antibacterial group Divide and directly produce good collaboration mutual assistance effect.Additionally, formula in bactericide be plant-source antibacterial agent, with has a broad antifungal spectrum, The characteristics of antimicrobial efficiency is high, can effectively kill common bacteria such as Escherichia coli, staphylococcus aureus etc., and safety is to human body Non-hazardous.
Preparation method another object of the present invention is to provide the above-mentioned solidifying pearl of degerming laundry.
It is still another object of the present invention to provide the application of the above-mentioned degerming solidifying pearl of laundry.
The purpose of the present invention is achieved through the following technical solutions:
A kind of solidifying pearl of degerming laundry, comprising component as follows by mass percentage:
Described polyalcohol is the one kind in ethylene glycol, glycerine or sorbierite;
Described bactericide is plant source compound disinfectant, is Ao Legang essential oils, pot marigold essential oil and cinnamaldehyde oil etc. The mixture of quality;
Described enzyme is the mixture of the quality such as two or more in protease, amylase, lipase or cellulase;
The preferred Kathon CG of described preservative, further preferred Kathon CG K15.
The preparation method of the solidifying pearl of described degerming laundry, comprises the following steps:
By deionized water, sodium alkyl sulfate, polyalcohol, Lao Ruitan FT1379 surfactants and different at 40-60 DEG C The carbon alcohol APEO of structure 13 mixes, and stirs evenly;Enzyme, essence, preservative and bactericide are added after being cooled to room temperature, is stirred evenly;Will Above-mentioned feed liquid is added in packing machine, is packaged into the solidifying pearl product of laundry;
Solidifying pearl can be applied in household chemicals field for described degerming laundry.
The present invention has the following advantages and effect relative to prior art:
(1) present invention is gentle using decontamination main body, low stimulation, and degradable surface activator composition can be with plant Property antiseptic between produce good cooperative effect, antibacterial effect is improved, while so that product has good detergency ability.
(2) the botanical fungicide performance safety for containing in inventive formulation, excitant is low, to human body without potential hazard, Degerming efficiency high.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but embodiments of the present invention not limited to this.
Embodiment 1
A kind of solidifying pearl of degerming laundry, comprising component as follows by mass percentage:
Described enzyme is the mixture of the quality such as protease and lipase;
Described bactericide is composite plant source bactericide, is Ao Legang essential oils, pot marigold essential oil and cinnamaldehyde oil etc. The mixture of quality.
The preparation method of the solidifying pearl of described degerming laundry, comprises the following steps:
By deionized water at 40 DEG C, sodium alkyl sulfate, polyalcohol, Lao Ruitan FT1379 surfactants, isomery ten Three carbon alcohol APEOs mix, and stirring is until well mixed;Being cooled to room temperature adds enzyme, essence, Kathon CG K15, bactericide to stir Mix well mixed;Finally, by above-mentioned feed liquid addition automatic packaging machine, the solidifying pearl product of laundry is packaged into PVA film.
Embodiment 2
A kind of solidifying pearl of degerming laundry, comprising component as follows by mass percentage:
Described enzyme is protease, the mixture of the quality such as amylase;
Described bactericide is composite plant source bactericide, is Ao Legang essential oils, pot marigold essential oil and cinnamaldehyde oil etc. The mixture of quality;
Preparation method is with embodiment 1.
Embodiment 3
A kind of solidifying pearl of degerming laundry, comprising component as follows by mass percentage:
Described enzyme is protease, the mixture of the quality such as cellulase;
Described bactericide is composite plant source bactericide, is Ao Legang essential oils, pot marigold essential oil and cinnamaldehyde oil etc. The mixture of quality;
Preparation method is with embodiment 1.
Embodiment 4
A kind of solidifying pearl of degerming laundry, comprising component as follows by mass percentage:
Described enzyme is protease, the mixture of the quality such as amylase;
Described bactericide is composite plant source bactericide, is Ao Legang essential oils, pot marigold essential oil and cinnamaldehyde oil etc. The mixture of quality;
Preparation method is with embodiment 1.
Comparative example 1
The solidifying pearl of one kind laundry, with embodiment 4, difference is to be not added with composite plant source bactericide to its formula.
Comparative example 2
A kind of solidifying pearl of degerming laundry, with embodiment 4, difference is that added bactericide is Ao Legang essential oils to its formula.
Comparative example 3
A kind of solidifying pearl of degerming laundry, with embodiment 4, difference is that added bactericide is pot marigold essential oil to its formula.
Comparative example 4
A kind of solidifying pearl of degerming laundry, with embodiment 4, difference is that added bactericide is cinnamaldehyde oil to its formula.
Comparative example 5
A kind of solidifying pearl of degerming laundry, its formula with embodiment 4, difference be added bactericide be Ao Legang essential oils and The mixture of the quality such as pot marigold essential oil.
Comparative example 6
A kind of solidifying pearl of degerming laundry, its formula with embodiment 4, difference be added bactericide be cinnamaldehyde oil and The mixture of the quality such as pot marigold essential oil.
Comparative example 7
A kind of solidifying pearl of degerming laundry, with embodiment 4, difference is that the surfactant package in being formulated becomes to its formula Change, the Lao Ruitan FT1379 (25%) and carbon alcohol APEO (25%) of isomery 13 in embodiment 4 are by more common day Change scrubbed component AEO (9EO, 25%) and DBSA (25%) replaces, its content keeps respectively Unanimously.
Comparative example 8
A kind of solidifying pearl of degerming laundry, with embodiment 4, difference is that the surfactant package in being formulated becomes to its formula Change, the Lao Ruitan FT1379 (25%) and carbon alcohol APEO (25%) of isomery 13 in embodiment 4 are by more common day Change scrubbed component AEO (9EO, 10%), DBSA (10%) and C14-16 alkene sulfonic acid sodiums (30%) replace.
Effect example
According to QB/T 1224-2012《Dress material washes agent by liquid》The method of regulation, degerming the washing of detection present invention preparation The detergency of the solidifying pearl of clothing.The method and soiled cotton specified using QB/T 13174-2008, laundry solidifying pearl sample and standard are determined with machine The detergency of liquid detergent.
The results are shown in Table 1.Washing performance test Data Comparison with standard liquid detergent and comparative example 7-8 is visible, and the present invention is real The solidifying pearl of laundry for applying example has good dirt-removing power, and its clean result will be far superior to liquid detergent, at the same also superior to using compared with It is the formula (comparative example 7-8) of traditional surfactant package, this shows the superiority of this patent formula.
The sterilization result of table 2 shows that the composite sterilization agent that this patent formula is added has good bacteria-eliminating efficacy.
The washing performance test of table 1
Antibacterial ability is tested:
Using QB/T2738-2012《The evaluation method of daily chemical products antibacterial bacteriostatic effect》To embodiment 1~4 and comparative example The anti-microbial property of the degerming solidifying pearl of laundry is tested obtained in 1-8, and the bacterial strain of experiment is Escherichia coli (ATCC 25922) and gold Staphylococcus aureus (ATCC 6538).
From the result of table 2, without the comparative example 1 of any antimicrobial component, antibacterial effect is not almost shown.Individually add Plus a kind of comparative example 2-4 of antimicrobial component, its bacteria-eliminating efficacy is between 65%-75%;Two kinds of comparative examples of antimicrobial component of addition 5-6, its bacteria-eliminating efficacy brings up to 86%;And three kinds of embodiment 1-4 of antimicrobial component are added simultaneously, its antibacterial effect reaches 97% More than.This shows that three kinds of natural plant antimicrobial components show good synergistic action effect, so that this patent has Preferable novelty.
The anti-microbial property test as shown by data of comparative example 7-8, compared with using the product of conventional surfactant formula, this More preferably, this is as a result of Lao Ruitan FT1379, the carbon alcohol polyoxyethylene of isomery 13 to the antibiotic property of patent of invention formulation product The composition of ether and sodium alkyl sulfate, the host component Lao Ruitan FT1379 surfactants used in said composition are that have Easily biological-degradable, hypotoxicity and excellent wetting and scourability;The carbon alcohol APEO of isomery 13 has easily biological-degradable With excellent scourability.Due to its good biological environmental production and compatibility, between its composition and vegetalitas antibacterial components Good collaboration mutual assistance effect can be produced, the anti-microbial property of product is significantly improved.And the fatty alcohol polyoxy second in common formula Alkene ether and DBSA are although with low cost, but difficult degradation, and toxicity is larger, in its composition and this patent formula Cooperative effect between vegetalitas antibacterial components is not obvious.
The anti-microbial property test of table 2
Above-described embodiment is the present invention preferably implementation method, but embodiments of the present invention are not by above-described embodiment Limitation, it is other it is any without departing from Spirit Essence of the invention and the change, modification, replacement made under principle, combine, simplification, Equivalent substitute mode is should be, is included within protection scope of the present invention.

Claims (7)

1. pearl is coagulated in a kind of degerming laundry, it is characterised in that comprising component as follows by mass percentage:
Described bactericide is the mixture of the quality such as Ao Legang essential oils, pot marigold essential oil and cinnamaldehyde oil.
2. pearl is coagulated in degerming laundry according to claim 1, it is characterised in that:Described polyalcohol is ethylene glycol, glycerine Or the one kind in sorbierite.
3. pearl is coagulated in degerming laundry according to claim 1, it is characterised in that:Described enzyme is protease, amylase, fat The mixture of the quality such as two or more in enzyme or cellulase.
4. pearl is coagulated in degerming laundry according to claim 1, it is characterised in that:Described preservative is Kathon CG.
5. pearl is coagulated in degerming laundry according to claim 1, it is characterised in that:Described preservative is Kathon CG K15.
6. the preparation method of the solidifying pearl of degerming laundry described in any one of claim 1-5, it is characterised in that comprise the following steps:
By deionized water, sodium alkyl sulfate, polyalcohol, Lao Ruitan FT1379 surfactants and isomery ten at 40-60 DEG C Three carbon alcohol APEOs mix, and stir evenly;Enzyme, essence, preservative and bactericide are added after being cooled to room temperature, is stirred evenly;Will be above-mentioned Feed liquid is added in packing machine, is packaged into the solidifying pearl product of laundry.
7. solidifying application of the pearl in household chemicals field of degerming laundry described in any one of claim 1-5.
CN201710123782.1A 2017-03-03 2017-03-03 A kind of solidifying pearl of degerming laundry and preparation method and application Pending CN106867711A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710123782.1A CN106867711A (en) 2017-03-03 2017-03-03 A kind of solidifying pearl of degerming laundry and preparation method and application

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Application Number Priority Date Filing Date Title
CN201710123782.1A CN106867711A (en) 2017-03-03 2017-03-03 A kind of solidifying pearl of degerming laundry and preparation method and application

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109337764A (en) * 2018-10-09 2019-02-15 王思淇 A kind of solidifying pearl and preparation method thereof of doing washing
CN110574765A (en) * 2018-06-08 2019-12-17 中国医学科学院药用植物研究所 Clothes disinfectant rich in pure natural plant essential oil and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104974864A (en) * 2015-07-23 2015-10-14 广州柏俐臣化妆品有限公司 Multifunctional laundry gel bead and preparation method thereof
CN106281760A (en) * 2016-08-16 2017-01-04 中轻日化科技有限公司 Solidifying pearl liquid of a kind of laundry and preparation method thereof
CN106318667A (en) * 2016-08-23 2017-01-11 余姚市德派日用品有限公司 Excellent bactericidal washing laundry condensate bead and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104974864A (en) * 2015-07-23 2015-10-14 广州柏俐臣化妆品有限公司 Multifunctional laundry gel bead and preparation method thereof
CN106281760A (en) * 2016-08-16 2017-01-04 中轻日化科技有限公司 Solidifying pearl liquid of a kind of laundry and preparation method thereof
CN106318667A (en) * 2016-08-23 2017-01-11 余姚市德派日用品有限公司 Excellent bactericidal washing laundry condensate bead and preparing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110574765A (en) * 2018-06-08 2019-12-17 中国医学科学院药用植物研究所 Clothes disinfectant rich in pure natural plant essential oil and preparation method thereof
CN109337764A (en) * 2018-10-09 2019-02-15 王思淇 A kind of solidifying pearl and preparation method thereof of doing washing

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Application publication date: 20170620