CN106867727A - A kind of hyperconcetration sterilization laundry sheet - Google Patents
A kind of hyperconcetration sterilization laundry sheet Download PDFInfo
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- CN106867727A CN106867727A CN201710137758.3A CN201710137758A CN106867727A CN 106867727 A CN106867727 A CN 106867727A CN 201710137758 A CN201710137758 A CN 201710137758A CN 106867727 A CN106867727 A CN 106867727A
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- hyperconcetration
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
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Abstract
The invention discloses a kind of hyperconcetration sterilization laundry sheet, by weight percentage including following component：Film forming agent：5 10%；Bactericide：0.5 5%；PCMX：0.5 2.5%；Phytoremediation agent：1 5%；Neopelex：10 30%；Lauryl sodium sulfate：5 15%；Aliphatic alcohol polyethenoxy (9) ether：5 10%；Polyoxyethylene fatty alkyl ether sulfonate：1 5%；Sodium silicate：5 10%；Soda ash：10 20%；Metal ion chelation agent：0.1 1%；Essence：0.05 0.5%；Pigment：0.001 0.005%；Preservative：0.1 0.5%；Deionized water：1 50%.Laundry sheet of the invention realizes the paper of laundry detergents from physical aspect, and small volume is easy to carry and takes conveniently, and active matter content is high, maintains the clean result of traditional liquid detergent and washing powder, can be dissolved immediately in hot and cold water, does not lump, does not precipitate.Addition plant sterilization composition and Phytoremediation composition, compared to conventional laundry product, both with clean effect, and with bactericidal effect, safer environmental protection.
Description
Technical field
The present invention relates to daily washing field, more particularly to a kind of hyperconcetration sterilization laundry sheet.
Background technology
At present, the laundry detergents commonly used in life mainly have three kinds of washing powder, liquid detergent and laundry soap.Wherein washing powder is usual
For packed, packaging bag is cut off when using, take and again pressed from both sides packaging bag with the article of clip etc after a small amount of washing powder.
This kind of washing powder due to packaging bag open after poor sealing, be easily caused washing powder make moist, lump and influence its dissolubility and
Cleaning force, and washing powder is also very easy to be scattered near washstand during taking, it is difficult to clear up.
Liquid detergent is usually bottled, needs measuring cup to measure when taking；There are extrusion type bottled liquid detergent, Ci Zhongxi in addition
The liquid outlet of clothing liquid is easily caused liquid detergent usually automatic excessive after extruding due to multiple extruding or extrusion head encapsulation problem
Go out, increased the cleaning after washing.
Laundry soap meeting residual moisture during washing by rubbing with the hands, after soap box is put into, the long-term retention of moisture can soften laundry
Soap, causes unnecessary waste.
In sum, there are various shortcomings in existing articles for washing mostly, and not portable, take up room, and be not easy to out
Used during travel row.Accordingly, it would be desirable to be improved to articles for washing.
Also there are laundry flake products in the prior art, the laundry sheet that current city faces the mountain there are two kinds：One kind is to use non-woven fabrics conduct
Carrier, part liquid detergent is sticked on non-woven fabrics, needs to remove non-woven fabrics every time after washing, and there is also fiber in non-woven fabrics
The phenomenon for coming off, the fiber for coming off can be sticked on clothes；Another kind is as film forming agent, with kaolin, two with polyvinyl alcohol
, used as filler, the surfactant drying for adding vector is in blocks, has very bright after being dissolved during washing for silica, cornstarch etc.
Aobvious sediment, water are very muddy, and sediment can be adsorbed in garment fabric in washing process, to final residual.
The content of the invention
For weak point present in above-mentioned technology, the present invention provide a kind of small volume, dissolving is fast, do not precipitate, can
Decontamination and hyperconcetration sterilization laundry sheet that can be sterilized.
To achieve the above object, the present invention provides a kind of hyperconcetration sterilization laundry sheet, by weight percentage including such as the following group
Point：
Film forming agent：5-10%；
Bactericide：0.5-5%；
PCMX：0.5-2.5%；
Phytoremediation agent：1-5%；
Neopelex：10-30%；
Lauryl sodium sulfate：5-15%；
Aliphatic alcohol polyethenoxy (9) ether：5-10%；
Polyoxyethylene fatty alkyl ether sulfonate：1-5%；
Sodium silicate：5-10%；
Soda ash：10-20%；
Metal ion chelation agent：0.1-1%；
Essence：0.05-0.5%；
Pigment：0.001-0.005%；
Preservative：0.1-0.5%；
Deionized water：1-50%.
Wherein, the specific composition of hyperconcetration sterilization laundry sheet is as follows：
Film forming agent：8%；
Bactericide：5%；
PCMX：1.5%；
Phytoremediation agent：3%；
Neopelex：15%；
Lauryl sodium sulfate：10%；
Aliphatic alcohol polyethenoxy (9) ether：8%；
Polyoxyethylene fatty alkyl ether sulfonate：3%；
Sodium silicate：7%；
Soda ash：15%；
Metal ion chelation agent：0.5%；
Essence：0.3%；
Pigment：0.0002%；
Preservative：0.15%；
Deionized water：23.5498%.
Wherein, film forming agent is one or more in polyethylene glycol, polyvinyl alcohol or polyvinylpyrrolidone.
Wherein, the bactericide is camphorated oil, eucalyptus oil, extract solution from aloe, ginger extract, galic essential oil, Chinese mugwort
One or more in leaf oil, tea oil.
Wherein, the Phytoremediation agent is the one kind or many in soapberry extract, Chinese honey locust extract solution, oil tea seed extract
Kind.
Wherein, the metal ion chelation agent be tetrasodium ethylenediamine tetraacetate, sodium citrate, disodium ethylene diamine tetraacetate,
One or more in sodium gluconate.
Wherein, the preservative is in methylchloroisothiazandnone, methylisothiazolinone or DMDMH
Plant or various.
Wherein, hyperconcetration sterilization laundry sheet is the sheet of 0.2-1.2mm in thickness.
The beneficial effects of the invention are as follows：Compared with prior art, hyperconcetration sterilization laundry sheet of the invention, from physical aspect
On realize the paper of laundry detergents, small volume is easy to carry and takes conveniently.Active matter content be more than 60%, with liquid detergent, wash
Clothing powder is compared with laundry soap, and usage amount is substantially reduced, and the clean result of traditional liquid detergent and washing powder is maintained, in hot and cold water
Can immediately dissolve, not lump, do not precipitate.The present invention addition plant sterilization composition and Phytoremediation composition, 3.3% laundry sheet
The aqueous solution is all higher than 90% to the sterilizing rate of Escherichia coli, staphylococcus aureus and Candida albicans, meets health ministry
's《Disinfection technology standard》(2002 editions), can remove mould taste removal after clothes washing.Phytoremediation composition and conventional surfactant
Compounding use, enhances clean result.Dirt-removing power is strong, according to QB/T 1224-2012 (dress material washes agent by liquid), 3.3%
Compared with the detergency of standard liquid detergent, the detergency to sebum greasy dirt cloth is 1.6 to the aqueous solution of the laundry sheet, to albumen soiled cotton
Detergency be 1.5, be 1.2 to the detergency of carbon black greasy dirt cloth, be all higher than the detergency of standard liquid detergent.Compared to conventional laundry
With product, both with clean effect, and with bactericidal effect, safer environmental protection.The present invention it is not phosphorous, without fluorescent whitening agent,
PH value does not hurt hands close to neutrality, biodegradable, does not result in environmental pollution.
Specific embodiment
PCMX in hyperconcetration sterilization laundry sheet of the present invention is a kind of antimildew and antibacterial agent of wide spectrum, to many
Number gram-positive bacteria, Gram-negative bacteria, fungi, mould all has kills effect, can make the protein denaturation of microorganism, sink
Form sediment, inactivate the enzyme system of microorganism, can suppress and kill brood body and the lipophilic virus of part bacterium.
Common phenolic antiseptic includes phenol, cresols, parachlorometaxylenol and Triclosan, table on the market
1 for above-mentioned four kinds of phenolic antiseptics performance parameter contrast, during test select equivalent, etc. dilution factor phenolic antiseptic, on an equal basis
Test object.In antibacterial effect based on the antibacterial effect of phenol numerical value, other antibacterial effects are with the antibacterial effect of phenol
Based on carry out multiple contrast.It is bactericidal effect based on different phenolic antiseptics, the pollution to environment, equal to skin irritation
It is different, in hyperconcetration of the invention sterilization laundry sheet preferred PCMX as bactericide, between chlorine two
Methylphenol is compared for other phenolic antiseptics, and bactericidal effect is higher, small to skin irritation, and the pollution to environment is small,
Without excitant taste, mould taste removal can be removed after clothes cleaning.
The performance comparison of the phenolic antiseptic of table 1
| Phenolic antiseptic | Corrosivity | Smell | Toxicity | Antibacterial effect |
| Phenol | There is slight erosion to act on skin | Off-odor | Moderate toxicity | 1 |
| Cresols | Without obvious corrosiveness | Less malodor | Moderate toxicity | 3-10 |
| Parachlorometaxylenol | Without obvious corrosiveness | Basic odorless | Basic toxicity | 20-30 |
| Triclosan | To no skin irritation | Slight aromatic odor | Substantially it is nontoxic | 20-30 |
Bactericide of the invention selects the plant containing reactivity functional compounds and terpenoid very high
Thing bactericide, forms the very strong molecule of diameter very little activity after the dissolving of these compounds, the very strong natural plants molecule of activity with
The chemical bond that odor molecules in fabric collide and destroy in odor molecules promotes it to decompose, and similar compatibility physics occurs
Absorb and dissolve；There is soda acid in the acidic oxides such as carbon, nitrogen, the sulphur of alkaloid in bactericide also with stains on fabrics
Neutralization reaction；Active ingredient in bactericide, can rapidly be polymerized with the harmful of spot, odor molecules, replace, put
The chemical reaction such as change, adsorb, decomposing.Because the extraction cost of different bactericides, extraction process maturity, purification are pure
Degree has differences, the present invention preferably camphorated oil, eucalyptus oil, extract solution from aloe, ginger extract, galic essential oil, Blumea oil, tea tree
Oil.Above-mentioned plant is wide in the planting range of China, and extraction process is ripe, and extraction cost is low, and sterilizing deodoring effect is good.
The decontamination principle of Phytoremediation agent is that, containing surfactant component, can occur with the spot on silk wool fabric
Bubble, decontamination, emulsification etc. are reacted, and then by the greasiness removal of fabric face.Phytoremediation agent is free of compared to for chemical decontaminants
Alkalescence, to silk wool fabric not damaged.And also added DBSA in addition to adding Phytoremediation agent in the present invention
The chemical surfactants such as sodium, lauryl sodium sulfate, Phytoremediation composition and conventional surfactant compounding use, enhance
Clean result.Dirt-removing power is strong.Preferred soapberry extract, Chinese honey locust extract solution and oil tea seed extract in Phytoremediation agent.Nothing
Suffer from son, Chinese honey locust, tea seed and make that detergent use time is long, extraction process is ripe, and extraction cost is lower, suitable industrial production.
It is the preferred first in the present invention in order to suppress the growth of microorganism on clothes and breeding that preservative is added in laundry sheet
, used as preservative, above-mentioned three kinds of preservatives are a kind of efficient for base chloroisothiazole quinoline ketone, methylisothiazolinone, DMDMH
Bactericide, with hot water resistance, can suppress the growth of bacterium, fungi and mould, can be directly added into personal-care supplies, change
The fields such as cosmetic, coating.Laundry sheet of the invention with the addition of preservative, further enhancing bactericidal effect, while being also provided with
The effect of antimildew and antibacterial.
Film forming agent is a kind of auxiliary agent that active material in laundry sheet can be allowed to be bonded together, and the film forming agent in the present invention can be with
It is one or more in polyethylene glycol, polyvinyl alcohol or polyvinylpyrrolidone, because polyethylene glycol is nontoxic, non-stimulated, tool
There is good water solubility, there can be good compatibility with many organic constituentses, so film forming agent of the invention is preferably poly- second
Glycol.
Hyperconcetration of the present invention sterilization laundry sheet is further described with reference to specific embodiment.
Embodiment 1：
A kind of hyperconcetration sterilization laundry sheet, its composition of raw materials is as follows：Polyethylene glycol 6g, polyvinylpyrrolidone 3g, camphor
Oily 1g, Blumea oil 2g, ginger extract 1g, tea oil 1g, PCMX 1.5g, Chinese honey locust extract solution 3g, dodecane
Base benzene sulfonic acid sodium salt 15g, lauryl sodium sulfate 10g, aliphatic alcohol polyethenoxy (9) ether 8g, polyoxyethylene fatty alkyl ether sulfonate
3g, sodium silicate 7g, soda ash 13g, tetrasodium ethylenediamine tetraacetate 0.5g, essence 0.3g, pigment 0.0002g, methylisothiazolinone
0.15g, deionized water 24.5495g.
By above-mentioned raw materials press mass fraction it is well mixed after, sheet is turned into after being dried into film process through oily heating, drying, cylinder
Laundry detergents, then clipped, punching press and packaging and other steps are made laundry sheet.
Embodiment 2：
A kind of hyperconcetration sterilization laundry sheet, its composition of raw materials is as follows：Polyethylene glycol 3g, polyvinyl alcohol 4g, eucalyptus oil 2g, reed
Luxuriant growth extract solution 2g, galic essential oil 1g, PCMX 2.5g, soapberry extract 3g, oil tea seed extract 2g, 12
Sodium alkyl benzene sulfonate 13g, lauryl sodium sulfate 10g, aliphatic alcohol polyethenoxy (9) ether 10g, AEO sulfonic acid
Sodium 2g, sodium silicate 6g, soda ash 12g, sodium citrate 0.3g, sodium gluconate 0.2g, essence 0.1g, pigment 0.0001g, methyl are different
Thiazolinone 0.1g, methylchloroisothiazandnone 0.2g, deionized water 26.5999g.
By above-mentioned raw materials press mass fraction it is well mixed after, sheet is turned into after being dried into film process through oily heating, drying, cylinder
Laundry detergents, then clipped, punching press and packaging and other steps are made laundry sheet.
Embodiment 3：
A kind of hyperconcetration sterilization laundry sheet, its composition of raw materials is as follows：Polyethylene glycol 2g, polyvinyl alcohol 3g, camphorated oil 0.2g,
Extract solution from aloe 0.1g, ginger extract 0.1g, tea oil 0.1g, PCMX 0.5g, Chinese honey locust extract solution 1g, ten
Dialkyl benzene sulfonic acids sodium 10g, lauryl sodium sulfate 5g, aliphatic alcohol polyethenoxy (9) ether 5g, AEO sulfonic acid
Sodium 1g, sodium silicate 5g, soda ash 10g, sodium citrate 0.1g, sodium gluconate 0.3g, essence 0.05g, pigment 0.0002g, methyl
OIT 0.1g, deionized water 56.4498g.
By above-mentioned raw materials press mass fraction it is well mixed after, sheet is turned into after being dried into film process through oily heating, drying, cylinder
Laundry detergents, then clipped, punching press and packaging and other steps are made laundry sheet.
Embodiment 4：
A kind of hyperconcetration sterilization laundry sheet, its composition of raw materials is as follows：Polyethylene glycol 3g, polyvinyl alcohol 3g, camphorated oil 0.3g,
Extract solution from aloe 0.3g, ginger extract 0.2g, tea oil 0.2g, PCMX 1g, Chinese honey locust extract solution 2g, 12
Sodium alkyl benzene sulfonate 12g, lauryl sodium sulfate 8g, aliphatic alcohol polyethenoxy (9) ether 6.5g, AEO sulfonic acid
Sodium 2g, sodium silicate 6g, soda ash 12g, sodium citrate 0.1g, sodium gluconate 0.3g, essence 0.13g, pigment 0.0002g, methyl
OIT 0.1g, deionized water 42.3998g.
By above-mentioned raw materials press mass fraction it is well mixed after, sheet is turned into after being dried into film process through oily heating, drying, cylinder
Laundry detergents, then clipped, punching press and packaging and other steps are made laundry sheet.
Embodiment 5：
A kind of hyperconcetration sterilization laundry sheet, its composition of raw materials is as follows：Polyethylene glycol 4g, polyvinyl alcohol 4g, camphorated oil 1g, reed
Luxuriant growth extract solution 2g, ginger extract 1g, tea oil 1g, PCMX 1.5g, Chinese honey locust extract solution 3g, detergent alkylate
Sodium sulfonate 15g, lauryl sodium sulfate 10g, aliphatic alcohol polyethenoxy (9) ether 8g, polyoxyethylene fatty alkyl ether sulfonate 3g, bubble
Flower alkali 7g, soda ash 13g, sodium citrate 0.2g, sodium gluconate 0.2g, essence 0.3g, pigment 0.0002g, methylisothiozoline
Ketone 0.15g, deionized water 24.8495g.
By above-mentioned raw materials press mass fraction it is well mixed after, sheet is turned into after being dried into film process through oily heating, drying, cylinder
Laundry detergents, then clipped, punching press and packaging and other steps are made laundry sheet.
Embodiment 6：
A kind of hyperconcetration sterilization laundry sheet, its composition of raw materials is as follows：Polyethylene glycol 4.5g, polyvinyl alcohol 4.5g, camphorated oil
0.5g, extract solution from aloe 0.5g, ginger extract 0.5g, tea oil 0.5g, PCMX 2g, Chinese honey locust extract solution
4g, neopelex 20g, lauryl sodium sulfate 12g, aliphatic alcohol polyethenoxy (9) ether 9g, aliphatic alcohol polyethenoxy
Ether sulfonic acid sodium 4g, sodium silicate 8g, soda ash 17g, sodium citrate 0.2g, sodium gluconate 0.3g, essence 0.1g, pigment 0.0002g,
Methylisothiazolinone 0.3g, deionized water 12.0998g.
By above-mentioned raw materials press mass fraction it is well mixed after, sheet is turned into after being dried into film process through oily heating, drying, cylinder
Laundry detergents, then clipped, punching press and packaging and other steps are made laundry sheet.
Embodiment 7：
A kind of hyperconcetration sterilization laundry sheet, its composition of raw materials is as follows：Polyethylene glycol 5g, polyvinyl alcohol 5g, camphorated oil 0.8g,
Extract solution from aloe 0.8g, ginger extract 0.7g, tea oil 0.7g, PCMX 2.5g, Chinese honey locust extract solution 5g, ten
Dialkyl benzene sulfonic acids sodium 20g, lauryl sodium sulfate 12g, aliphatic alcohol polyethenoxy (9) ether 9g, AEO sulphur
Sour sodium 5g, sodium silicate 10g, soda ash 20g, sodium citrate 0.2g, sodium gluconate 0.3g, essence 0.5g, pigment 0.0002g, first
Base OIT 0.5g, deionized water 1.9998g.
By above-mentioned raw materials press mass fraction it is well mixed after, sheet is turned into after being dried into film process through oily heating, drying, cylinder
Laundry detergents, then clipped, punching press and packaging and other steps are made laundry sheet.
Here is the pH value testing experiment of embodiment 1-7 hyperconcetration sterilization laundry sheet：
With reference to the Ministry of Public Health《Disinfection technology standard》2.2.1.4 is carried out in (version in 2002) (defending method prison hair [2002] 282)
Test；22 degrees Celsius of test temperature, relative humidity 61%.
Can be drawn by table 2-1, the disinfection tablet pH value of embodiment of the present invention 1-7 is close neutral between 6.40-7.10,
It is difficult to cause human body skin corrosion to injure.
The pH value measurement result of table 2-1 embodiment 1-7 hyperconcetration sterilization laundry sheet
Here is an intact skin irritant test of embodiment 1-7：
New zealand rabbit left side will be applied to after 5 times of the laundry sheet dissolved dilution of embodiment of the present invention 1-7 and removes hair-fields skin, so
Covered with non-stimulated plastic foil afterwards, hair-fields skin is removed as blank in new zealand rabbit right side.Application time 4h.Then with temperature
Water also washes away residual liquid, respectively with 1h, 24h, 48h observation local skin reaction, carries out IR scoring.
Table 2-2 shows：Interior during observation, tested new zealand rabbit skin has no erythema, oedema abnormal response, does not find it
His poisoning symptom, highest SI is 0.
Table 2-2 embodiments 1-7 intact skin irritant tests successively
Consolidated statement 2-1 and table 2-2 draw to draw a conclusion：Hyperconcetration sterilization laundry sheet pH value of the invention is in 6.40-7.10
Between, especially the formula of laundry sheet is substantially nonirritant to human body skin substantially close to neutrality in embodiment 5,6,7, does not hinder
Hand.
Here is killing experiments of the embodiment 1-7 to Escherichia coli and staphylococcus aureus：
The preparation of bacteria suspension：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.3, bacteria containing amount be 1 ×
108cfu/mL-5×108cfu/mL。
Embodiment 1-7 nertralizer qualification tests：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.5.Examination
Bacterium is tested for Escherichia coli.Each embodiment experiment is grouped into：(1) laundry sheet solution+bacteria suspension, (2) (laundry sheet solution+bacterium is hanged
Liquid)+nertralizer, (3) nertralizer+bacteria suspension, (4) (laundry sheet solution+nertralizer)+bacteria suspension, (5) TPS+ bacteria suspensions, (6) examination
Test used with batch TPS, nertralizer, culture medium.The dilution of laundry sheet solution 3.3%, action time 10min, experiment repeats 3
It is secondary.19 DEG C -21 DEG C of test temperature.
Embodiment 1-7 nertralizer authentication test results：
As shown in table 3-1, (1st) group average production bacterium number of embodiment 1 is 0cfu/mL, (2nd) group average production bacterium number
It is 4.24 × 102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 2.51%.(6th)
Group asepsis growth.
(1st) group average production bacterium number of embodiment 2 is 0cfu/mL, (2nd) group average production bacterium number is 4.20 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 2.24%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 3 is 0cfu/mL, (2nd) group average production bacterium number is 4.37 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, error rate 2.52% between three groups.(6th) group asepsis growth.
(1st) group average production bacterium number of embodiment 4 is 0cfu/mL, (2nd) group average production bacterium number is 4.27 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 2.58%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 5 is 0cfu/mL, (2nd) group average production bacterium number is 4.18 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 3.01%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 6 is 0cfu/mL, (2nd) group average production bacterium number is 4.24 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 2.75%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 7 is 0cfu/mL, (2nd) group average production bacterium number is 4.38 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 2.54%.(6th) the aseptic life of group
It is long.
Table 3-1 embodiment 1-7 nertralizer authentication test results
Suspension quantitative bactericidal test：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.7.Embodiment 1-7
The dilution of laundry sheet solution 3.3%, action time 10min, 20min, 30min, experiment is repeated 3 times.19 DEG C -21 of test temperature
℃。
Embodiment 1-7 is to Escherichia coli and the killing effect of staphylococcus aureus：
As shown in table 3-2, embodiment 1-7 shows through 3 repetition experiments：The hyperconcetration sterilization laundry sheet of embodiment 1-7,
In 19 DEG C -21 DEG C of test temperature, the dilution of laundry sheet solution 3.3% acts on 20min, to Escherichia coli and golden yellow Portugal
The killing logarithm value of grape coccus is all higher than 5.00, wherein sterilizing rate point of the embodiment 1 to Escherichia coli and staphylococcus aureus
Not Wei 95.1%, 94.9%, embodiment 2 is respectively 95.8% to the sterilizing rate of Escherichia coli and staphylococcus aureus,
95.5%, embodiment 3 is respectively 92.0%, 92.6%, embodiment 4 pairs to the sterilizing rate of Escherichia coli and staphylococcus aureus
The sterilizing rate of Escherichia coli and staphylococcus aureus is respectively 92.2%, 92.5%, and embodiment 5 is to Escherichia coli and golden yellow
Staphylococcic sterilizing rate is respectively 97.8%, 96.3%, and embodiment 6 is to Escherichia coli and the sterilizing rate of staphylococcus aureus
Respectively 95.3%, 95.4%, embodiment 7 is respectively 95.2% to the sterilizing rate of Escherichia coli and staphylococcus aureus,
94.7%.Consolidated statement 3-1 and table 3-2 draw to draw a conclusion：Hyperconcetration of the invention sterilization laundry sheet is to Escherichia coli and golden yellow
The staphylococcic sterilizing rate of color is all higher than 90%, and wherein embodiment 5 is to staphylococcus aureus and the bactericidal effect of Escherichia coli
Most preferably.
Killings of the table 3-2 embodiments 1-7 to Escherichia coli and staphylococcus aureus is tested
Here is killing experiments of the embodiment 1-7 to Candida albicans：
The preparation of bacteria suspension：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.3, bacteria containing amount be 1 ×
107cfu/mL-5×107cfu/mL。
Nertralizer qualification test：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.5.Test organisms is white
Candida albicans.Experiment is grouped into：(1) laundry sheet solution+bacteria suspension, (2) (laundry sheet solution+bacteria suspension)+nertralizer, (3) neutralize
Agent+bacteria suspension, (4) (laundry sheet solution+nertralizer)+bacteria suspension, (5) TPS+ bacteria suspensions, (66) experiment it is used with batch TPS,
Nertralizer, culture medium.The dilution of laundry sheet solution 2%, action time 10min, experiment is repeated 3 times.19 DEG C -21 of test temperature
℃。
Embodiment 1-7 nertralizer authentication test results：
As shown in table 4-1, (1st) group average production bacterium number of embodiment 1 is 0cfu/mL, (2nd) group average production bacterium number
It is 2.04 × 102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 4.24%.(6th)
Group asepsis growth.
(1st) group average production bacterium number of embodiment 2 is 0cfu/mL, (2nd) group average production bacterium number is 2.09 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 4.72%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 3 is 0cfu/mL, (2nd) group average production bacterium number is 2.19 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 3.01%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 4 is 0cfu/mL, (2nd) group average production bacterium number is 2.08 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 2.30%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 5 is 0cfu/mL, (2nd) group average production bacterium number is 2.04 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 4.25%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 6 is 0cfu/mL, (2nd) group average production bacterium number is 2.09 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 4.13%.(6th) the aseptic life of group
It is long.
(1st) group average production bacterium number of embodiment 7 is 0cfu/mL, (2nd) group average production bacterium number is 2.15 ×
102Cfu/mL, (3rd), (4), (5) group average production bacterium number it is close, between three groups error rate be 3.57%.(6th) the aseptic life of group
It is long.
The nertralizer authentication test results of table 4-1 embodiments 1-7
Quantitative disinfecting test：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.7.Embodiment 1-7's washes
The dilution of garment piece solution 3.3%, action time 10min, 20min, 30min, experiment is repeated 3 times.19 DEG C -21 DEG C of test temperature.
Killing effects of the embodiment 1-7 to Candida albicans：As shown in table 4-2, show through 3 repetition experiments：Embodiment
1-7 hyperconcetration sterilization laundry sheet, in 19 DEG C -21 DEG C of test temperature, the dilution of laundry sheet solution 3.3% acts on 20min,
Killing logarithm value to Candida albicans is all higher than 6.00, and it is qualified to sterilize, and wherein embodiment 1 is to the sterilizing rate of Candida albicans
93.9%, embodiment 2 is 93.2% to the sterilizing rate of Candida albicans, and embodiment 3 is to the sterilizing rate of Candida albicans
91.4%, embodiment 4 is 91.1% to the sterilizing rate of Candida albicans, and embodiment 5 is to the sterilizing rate of Candida albicans
96.7%, embodiment 6 is 92.6% to the sterilizing rate of Candida albicans, and embodiment 7 is to the sterilizing rate of Candida albicans
92.3%.Consolidated statement 4-1 and table 4-2 can draw to draw a conclusion：The hyperconcetration sterilization laundry sheet dialogue of embodiment of the present invention 1-7
The sterilizing rate that color reads coccus is all higher than 90%, wherein, embodiment 5 is optimal to the sterilizing rate of Candida albicans.
Killings of the table 4-2 embodiments 1-7 to Candida albicans is tested
Below for embodiment of the present invention 1-7 to textile disinfecting field test：
Embodiment 1-7 is carried out into following experiment with its 3.3% dilution, the formula of sample solution includes：Containing 0.3% lecithin
Fat, 3.0% Tween 80,0.5% glycine, the PBS of 0.3% histidine.The formula of dilution is the TRS containing 0.1% Tween 80
Solution.According to the Ministry of Public Health《Disinfection technology standard》2.1.2.10 is tested in (version in 2002).Cut the fabric 5cm of pollution ×
5cm is put into 10ml sample solutions as a control group.The fabric of residual contamination dilutes immersion with the lysate 3.3% of embodiment 1-7
Bubble, acts on 20min, and taking-up is put into 10ml sample solutions as experimental group, and eluent is lived after above-mentioned tested fabrics are eluted
Bacterium culture technique.Experiment is repeated 5 times.20 DEG C of test temperature.
Sterilization field tests of the embodiment 1-7 of table 5 to fabric natural bacteria
Embodiment 1-7 shows textile disinfecting experiment：The hyperconcetration sterilization laundry sheet 3.3% of embodiment of the present invention 1-7 is dilute
Release liquid, act on 20min, be respectively 1.94 to the average killing logarithm value of fabric natural bacteria, 1.91,1.68,1.66,2.00,
1.84 and 1.74, the equal ＞ 1.50 of logarithm value is killed in each experiment, and it is qualified to sterilize, wherein the hyperconcetration sterilization laundry sheet of embodiment 5
3.3% dilution, acts on 20min, to the average killing logarithm value highest of fabric natural bacteria, the i.e. laundry sheet of the formula of embodiment 5
Killing effect to fabric natural bacteria is optimal.
Table 6 is contrasted for the detergency of embodiment of the present invention 1-7 with common commercial laundry powder, liquid detergent.Can be obtained by table 6
Go out：
The embodiment 1-7 of table 6 compares with the detergency of liquid detergent, washing powder
, closest to neutrality, the stimulation of opponent is minimum, and comparatively active matter content highest cleans identical for the pH value of laundry sheet
The usage amount of the clothing of weight is minimum, according to QB/T 1224-2012 (dress material washes agent by liquid), the water of 3.3% laundry sheet
Compared with the detergency of standard liquid detergent, the detergency to sebum greasy dirt cloth is 1.6 to solution, and the detergency to albumen soiled cotton is
1.5, the detergency to carbon black greasy dirt cloth is 1.2, is all higher than the detergency of standard liquid detergent, and phosphorus content is also minimum.3.3% this wash
The aqueous solution of garment piece is all higher than 90% to the sterilizing rate of Escherichia coli and staphylococcus aureus, can be effectively sterilized.
Table 7 be embodiment of the present invention 1-7 laundry sheets and commercial laundry powder under waiting quality condition under the equal aqueous solution
Dissolving situation contrast.As can be seen from Table 7：
The rate of dissolution contrast of the laundry sheet and commercial laundry powder of the embodiment 1-7 of table 7
As can be seen from Table 7, no matter the laundry sheet of embodiment of the present invention 1-7 is also dissolved in cold water in being dissolved in hot water, shape
Into the aqueous solution be it is as clear as crystal, without caking, in the absence of muddy thing；Laundry sheet of the invention in the hot water molten simultaneously
Solution time average out to 22 seconds, dissolution velocity is arranged in the hot water for the dissolution time average out in cold water 53 seconds, wherein embodiment 1-7
Sequence is：The ＞ embodiments 3 of 57 ＞ embodiments of ＞ embodiment 1=embodiment 6 ＞ embodiments, 2 ＞ embodiments of embodiment 4；Wherein embodiment
1-7 dissolution velocities in cold water are ordered as：The ＞ embodiments of 7 ＞ embodiments of embodiment 5 ＞ embodiments, 1 ＞ embodiments, 6 ＞ embodiments 2
4 ＞ embodiments 3.
Laundry sheet of the invention by raw material press mass fraction it is well mixed after, be dried into film process through oily heating, drying, cylinder
Turn into laundry detergent tablet afterwards, then clipped, punching press and packaging and other steps are made laundry sheet.The thickness of finished product laundry sheet can reach
0.5-1.0mm, outer shape is generally the rectangular patch of 11 × 15mm, and whole laundry sheet compact is easy to carry, a piece of to wash
Garment piece can clean 5-6 part clothes, and active material is high, and dirt-removing power is strong.
Advantage of the invention is that：
1st, the thickness of laundry sheet of the invention is 0.5-1.0mm, and small volume is easy to carry and takes conveniently.
2nd, sterilization component containing natural plants, the aqueous solution of 3.3% laundry sheet to Escherichia coli, staphylococcus aureus and
The sterilizing rate of Candida albicans is all higher than 90%, meets health ministry《Disinfection technology standard》(2002 editions).
3rd, Phytoremediation composition and conventional surfactant compounding use, enhance clean result.Dirt-removing power is strong, according to
QB/T 1224-2012 (dress material washes agent by liquid), the aqueous solution of 0.1% laundry sheet and the detergency phase of standard liquid detergent
Than the detergency to sebum greasy dirt cloth is 1.6, and the detergency to albumen soiled cotton is 1.5, and the detergency to carbon black greasy dirt cloth is
1.2, it is all higher than the detergency of standard liquid detergent.
4th, not phosphorous, without fluorescent whitening agent, pH value does not hurt hands close to neutrality.
5th, in the neutral i.e. dissolving of hot and cold water, dissolving rear solution is transparent.
Disclosed above is only several specific embodiments of the invention, but the present invention is not limited to this, any this area
Technical staff can think change should all fall into protection scope of the present invention.
Claims (8)
1. a kind of hyperconcetration sterilization laundry sheet, it is characterised in that by weight percentage including following component：
Film forming agent：5-10%；
Bactericide：0.5-5%；
PCMX：0.5-2.5%；
Phytoremediation agent：1-5%；
Neopelex：10-30%；
Lauryl sodium sulfate：5-15%；
Aliphatic alcohol polyethenoxy (9) ether：5-10%；
Polyoxyethylene fatty alkyl ether sulfonate：1-5%；
Sodium silicate：5-10%；
Soda ash：10-20%；
Metal ion chelation agent：0.1-1%；
Essence：0.05-0.5%；
Pigment：0.001-0.005%；
Preservative：0.1-0.5%；
Deionized water：1-50%.
2. a kind of hyperconcetration sterilization laundry sheet according to claim 1, it is characterised in that hyperconcetration sterilization laundry sheet
Concrete component is as follows：
Film forming agent：8%；
Bactericide：5%；
PCMX：1.5%；
Phytoremediation agent：3%；
Neopelex：15%；
Lauryl sodium sulfate：10%；
Aliphatic alcohol polyethenoxy (9) ether：8%；
Polyoxyethylene fatty alkyl ether sulfonate：3%；
Sodium silicate：7%；
Soda ash：15%；
Metal ion chelation agent：0.5%；
Essence：0.3%；
Pigment：0.0002%；
Preservative：0.15%；
Deionized water：23.5498%.
3. a kind of hyperconcetration sterilization laundry sheet according to claim 1 and 2, it is characterised in that film forming agent be polyethylene glycol,
One or more in polyvinyl alcohol or polyvinylpyrrolidone.
4. a kind of hyperconcetration sterilization laundry sheet according to claim 1 and 2, it is characterised in that the bactericide is
One or more in camphorated oil, eucalyptus oil, extract solution from aloe, ginger extract, galic essential oil, Blumea oil, tea oil.
5. a kind of hyperconcetration sterilization laundry sheet according to claim 1 and 2, it is characterised in that the Phytoremediation agent is
One or more in soapberry extract, Chinese honey locust extract solution, oil tea seed extract.
6. a kind of hyperconcetration sterilization laundry sheet according to claim 1 and 2, it is characterised in that the metal ion-chelant
Agent is one or more in tetrasodium ethylenediamine tetraacetate, sodium citrate, disodium ethylene diamine tetraacetate, sodium gluconate.
7. a kind of hyperconcetration sterilization laundry sheet according to claim 1 and 2, it is characterised in that the preservative is methyl
One or more in chloroisothiazole quinoline ketone, methylisothiazolinone or DMDMH.
8. a kind of hyperconcetration sterilization laundry sheet according to claim 1, it is characterised in that hyperconcetration sterilization laundry sheet is in thickness
Spend the sheet for 0.5-1.0mm.
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| CN107441001A (en) * | 2017-09-22 | 2017-12-08 | 汝城和思生物技术有限公司 | A kind of method that hand cleanser is prepared using ginger camellia seed |
| CN107828520A (en) * | 2017-10-30 | 2018-03-23 | 佛山科学技术学院 | A kind of Chinese herbal medicine water-soluble laundry washing piece and preparation method thereof |
| CN108004042A (en) * | 2017-12-25 | 2018-05-08 | 中盐东兴盐化股份有限公司 | A kind of white Antibacterial laundry detergent of salt |
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