JPH03501271A - Cleaning and disinfecting composition for textile products - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

[Detailed description of the invention] name of understanding Cleaning and disinfecting composition for textile products field of invention The present invention deals with allergens (allergens: substances that cause allergies), particularly with respect to - Compositions and methods for reducing and eradicating mites in pets.

Background of the invention wm, the present invention will be mainly described with reference to mites, but as will be apparent below. As shown, the present invention is by no means limited thereto.

Bacteria and insects in household fixtures and textiles Wall decorations, curtains, rugs, Bedding, sheets, pillowcases, and such textile products or articles are allergy-free. It is believed that there is a possibility that it may be hidden.

Such textile products and articles are easily soiled during daily use, and this soiling often Food and beverages that often serve as a food source and/or habitat for undesirable microorganisms and other organisms. Residues of food, cooking oil, dirt on the floor, human dirt, dirt and dust in the air, especially on flat surfaces. All of the human and animal dirt that an average adult produces between 2 and 4 grams per day. These substances become food for living organisms such as microorganisms.

It is undoubtedly the most troublesome microorganism found in environmental and industrial settings. The tick is It is widely associated with human allergies, especially those in the nasal and upper respiratory areas. However, the skin Allergies are also frequently reported. In addition, allergies caused by dust mites may occur in people who are sensitive to In many cases it is associated with asthma. In addition, allergies caused by dust mites are common in children and children. Both in adults are considered a source of immunological allergic reactions. It cannot be eradicated However, there are no practical ways to control dust mites in the average household. It belongs to a major research field in science and has the potential to improve the health of many people. It has the potential.

Dust mite allergies can be caused by both live and dead mites. Occur. The number one cause of allergies is the internal organs produced by living mites. and one or more glycoproteins found in appreciable concentrations in the excreta. Facilitated by physical movements such as walking on a carpet. alive da They defecate into their habitat up to 20 times a day. Therefore, a high density of mites , until the mites stop growing or the allergen is removed or shielded. or may come into contact with people and react with compositions that prevent allergic reactions. Many times, large amounts of allergens are produced.

Female mites lay their eggs in the fur of carpets or in shielded areas of textiles. The eggs develop into stems in 3 to 4 weeks. Infection with certain protozoan parasites Just as the synocyst cannot be killed by chemical means, the egg membrane can be killed by most household There is no known way to kill live mites that is impervious to chemical pesticides or detergents. However, in order to prevent repeated inhabitation, the surface of the mite eggs should be penetrated or soaked. Until now, there was no practical way to do this.

Additionally, eggs can be found well below the surface of carpets and textiles. Therefore, it is relatively difficult to reach with normal cleaning methods.

Australian Patent Application No. 44606/85 is a patent application for carpet and textile products. Discloses a method of spraying an alcohol solution of tannic acid complex with tannic acid are doing.

The specification states that the solution kills live mites and that the tannic acid in the formulation kills live mites. Allergies caused by the aforementioned allergens found in dead mites and dead mites. -We teach things that contribute to eliminating reactions. However, this solution has It has many serious drawbacks. First, it is highly flammable. e), secondly, it is difficult to apply uniformly, and thirdly, it is difficult to kill the eggs. Finally, it leaves additional chemical residues inside and outside the textile. Tan Nitric acid residues discolor over time, causing light-colored textiles to gradually discolor (color (by air oxidation of elementary molecules), especially when this is used repeatedly . And the highly polar tannic acid also contributes to certain types of Acts to bind to dirt. Furthermore, it has no cleaning action and therefore Once the benzyl alcohol has evaporated, remains on the sprayed area. Then, spraying other chemicals onto the surface of the textile product. It may become a chemical residue and itself become an allergen.

As described in patent application no. 44606/85, dust mite allergens are Oxidizing agents, reducing agents, divalent metal ions, trivalent metal ions, alkalis, mild acids, alkaline Not destroyed by dehydes or proteolytic enzymes; In experiments, mites were removed by ordinary petroleum-based solvents or by ordinary household detergents. Depending on the type of surfactant found in carpet cleaning treatments, I found out that there is no such thing. We know this because dust mites are present in ordinary household cleaning processes. I think this explains why they survive. In fact, there are two widely used High efficiency fluorocarbons FC120 and FC99 (3MCOMPAN Y, INC) both provide very low surface and interfacial tension, making it difficult for mites to It turned out that there was no need to get it wet.

Additionally, carpets in certain locations, such as hospitals and health care facilities, may contain bacteria. There are special problems with contaminated materials and other hospital waste. car Pet and textile products do not contain human blood, body fluids, exudates, urine, excrement, vomit, saliva, or air. contaminated accidentally by aerosols or by medical procedures. Sometimes. These include many pathogenic bacteria that can cause cross-infection between patients. It can also be contaminated by viruses. Dried bacteria in the form of spores cause disease. It may also pollute the air in the passageway of the building. Therefore, the method of cleaning textile products should be In addition, it can kill as much as possible in hospital textiles and surfaces. It is desirable to be able to eradicate many microbial residues.

Stubborn dirt and stains are instantly and effectively removed during the disinfection process. It is preferable that

Dust mite residue on regular household carpets can be removed by using a regular carpet cleaner with sufficient carpet cleaner. Industrial sprays remain even after cleaning, and this has been shown in recently published literature. "Domestic mites and fungi on cotton carpets" by D. J. J. Wassenaar. Effects of vacuum cleaning and wet cleaning to reduce dust mite allergens ”: Case Study Experimental and Applied Aniology, 4 (1988) 53-62” explained.

This study investigated the procedures used to eliminate household mites (vacuum and then wet Spraying (extraction cleaning) may have the opposite effect if used for a long period of time. I conclude that no. Allergen levels are now lower, but after cleaning Many mites and their eggs were found. Thorough spraying will remove dust mites and their eggs. It also survived wet cleaning with chemicals.

Other published studies have shown that common household insecticides have little effect on ticks and have no killing ability. It shows that there is no power.

The first successful report on controlling ticks was published in 1975 ( C1inical Allergy Vol, 5109-114), this is a solvent based on a combination of terpenes and fungicides. Unfortunately, the experimental results did not support the laboratory findings, and the acaricidal efficacy was not further tested.

The true hydrophobic properties of the mite, its hard skin and its egg epidermis are This remained a major barrier to the development of antibacterial detergents. The solution to moisture problems is the right amount for dust mites. This is the first important step in delivering a toxic substance. This is a volatile alcohol solution. terpenes and benzyl alcohol and some terpenes, but the product is against eggs that are harmful, lack cleaning properties, and later become silent and repopulate textiles. It has no effect.

The object of the invention is to provide a detergent composition capable of moistening dust mites, in particular litter mites. By this means, it is possible to kill mites either alone or in combination. The purpose is to provide a medium for containing chemical substances. Moreover, the composition of the present invention kills eggs and targets protein allergens found in dust mites and their excrement. The aim is to reduce allergies. The latter event may occur in the compositions of the present invention. of proteins that become hydrogen bound to one or both of surfactants and solvents contained in This invention is believed to be due to the component group. Provides useful new and major discoveries in controlling clumps. In addition, the main The purpose of this technology is to eradicate microorganisms, especially dust mites and their eggs, and to produce textile products, especially textiles. Easy and safe for cleaning household textiles such as sheets, pillowcases and curtains The aim is to provide detergents that are

According to the invention, (a) a glycol or an alkali glycol; (b) one or more glycols; Chain alcohols, cyclic alcohols and aromatic alcohols, (C) alkanoylamines Acaricide detergent compositions are provided that contain one or more surfactants such as surfactants or amines. Ru.

Detergent action required to remove stains and organic stains and highly polar glycols Ether or ketone solvents are preferred to achieve emulsification with Ethylene glycol, propylene glycol, diethylene glycol, dipropylene lene glycol, triethylene glycol, or each of these mono or di , methyl, ethyl, propyl or butyl ether, ethyl 3-ethoxypropyl ester, or 3-methylmethoxybutanol, and propylene glycol ether You can choose from ether-substituted alkalis. The preferred amount will be determined in the final table. Surface active, and dissolves other components that are difficult to dissolve in water into the micellar structure of the acaricide composition. depends on the need to do so.

Preferred glycols of the present invention are commonly ethylene glycol, diethylene glycol, alcohol, propylene glycol, dipropylene glycol, triethylene glycol mono- and diethers. However, 3-methylmethoxybutanol and Similar low molecular weight hydrogen solvents, including chill-3-ethoxypropinate, have similar effects. It may show efficacy or efficacy. The amount required is based on the requirement for solubility in aqueous solvents. It varies depending on the amount and ratio of wax and other ingredients.

The amount of glycol or similar solvent may range from 1.0 to 45% in ready-to-use products. ．． 0%, preferably in the range of 1.0 to 5.0%, diluted For products used in industrial applications, it may range from 3.5 to 40.0 percent.

Furthermore, it aids in cleaning as a co-solvent and at the same time is an additional toxic agent for litter mites. Addition of aromatic alcohols and cyclic alcohols is the most effective It turned out to be useful.

Preferred alcohols are benzyl alcohol, 2-phenol alcohol and phenolic alcohol. Aromatic alcohols such as phenoxy alcohol. But also 4-gross butanol, n-pentanol, n-hexanol, n-octatool, n- Certain aliphatic alcohols, such as decanol and n-dodecanol, are Certain alcohols listed above that may be included in part of the extermination system may be partially dissolved in water. It may or may not dissolve.

Therefore, in order to dissolve alcohol that hardly dissolves, ethanol and isopropyl alcohol are used. Tools such as lower alcohols, glycols, or urea, xylene, sodium sulfite Addition of known detergent hydrotropes such as toluene or toluene sulfite. It is necessary to prepare the composition of the invention by. xylene sodium sulfite The preferred percentage of Between 0.05% and 25% for use in anhydrous concentrations. Ru. More preferably, the percentage range is suitable for use in diluted concentrations with water. It is between 0.5 and 15.0.

The toxic effects of aromatic alcohols were found to be increased by the addition of terpenes . Preferred terpenes include pine, eucalyptus, peppermint, citrus, and tea leaf oils. Among them, dipentene, terpineol, etc. terbinone, eucalyptol, citral, quince, pinene, tel Most preferred are pin-4-ol and Y-terpine.

Similar cyclic molecules with strongly polar hydroxy groups are also suitable. Micellar type Both cleaning and acaricidal properties by adding aromatic nuclei to the is significantly improved. Combining aromatic alcohols with low molecular weight alcohols This gives the composition of the invention a synergistic cleaning effect, especially a practical cleaning effect. .

The choice of solvent and its compatibility with the surfactant system are important in promoting surface activity and improving the properties of the present invention. before glycol-type solvents to dissolve other chemical components that are difficult to dissolve in the composition. It turns out that it is important to mix the ingredients mentioned above. And the hydrophobicity of the tick skin Add small amounts of terpene solvents that enhance the potency of these ingredients to counteract their effects. It is also important to include Presumably, the terpene solvent It is also thought to weaken the normal impermeability of .

Provides alkalinity and protects detergents against hydrophobic surfaces and stains, especially anionic stains. Water-soluble anines or alkanolamines may be included to increase solubility , the amine can be a cyclic amine such as virorhodone, or a mono-, di- or triethyl amine. May be selected from either tanolamine or isopropanolamine; of fish is adjusted by the desired pH and surface activity of the ingredients. In a preferred embodiment, The amine is present at 0.5 to 5.0 weight percent and the preferred p II of the detergent is The concentration ranges from 9.0 to 12.5.

Also, monoethanolamine, isopropanolamine, jetanolamine, such as triethanolamine, diethylaminoethanol or other odorless amines. Adding a small amount of alkanolamines or hydroxyamines is effective against dust mites and It contributes to the process of reducing the resistance of the egg. And this means that the aqueous solution It increases the amount of droxy ion and also increases the solubility.

Moreover, these effects are caused by phenomena that can be easily understood by those skilled in the art. The surfactant properties of the product greatly improve its cleaning ability.

Furthermore, the formulation of glycols, aromatic alcohols and alkanolamines supplemented as a detergent and stain remover by incorporating small amounts of terpenes derived from It is known to those skilled in the art that the cleaning action of is publicly known to the public. The amount required to dissolve a terpene in a particular composition is base surfactant systems, cyclic, aromatic or aliphatic alcohols, dispersion systems, and 0 for ready-to-use products, which will vary according to the choice of ．． Preferably used at 0.05 to 0.25 percent, but used diluted. In case of concentrated products, the amount ranges from 0.25 to 10.0%. It is surrounded by

The compositions of the invention preferably have very low sensitivity to polar and non-polar oils and solvents. It has a surfactant system with surface tension. The surfactant system preferably has one It consists of 2 to 5 surfactants, which are more than paste type, and these are mixed. Sometimes spontaneously emulsified with edible oils such as paraffin oil, lubricating oil, and olive oil. and has considerable surface activity on its own.

Such surface-active systems are usually used for very specific industrial degreasing. asing) used only in materials, and the use of textile detergents in terms of total viscosity or It is not suitable for products made from protein such as leather or silk.

In a preferred embodiment, the total amount of surfactant required in the composition ranges from 0.05 to It is in the range of 30.0%, typically 0% for immediate use. ．． 0.5 to 0.5 percent, and 2.0 percent for concentrated products that require dilution before use. It ranges from 5 to 30.0 percent.

Surfactants may be anionic, nonionic, amphoteric or cationic, and are preferred. In addition to instantly separating stains from common textile products, it also provides effective disinfection and disinfection. Some detergents contain one or more chemical substances that act as insecticides. I like detergent or a non-ionic detergent system, which removes mineral oils, fats and cooking oils. Some contain one or more nonionic detergents that can be emulsified. This way Detergents are phenolic polyesters substituted with long chain alkyls (e.g. CMC1). Toxylate or a.

Ethoxylated alkyl chains having a length of 8 to 20 saturated carbon atoms The non-ionic surfactant, which may be called The zero surface tension, which is preferably 27.5 percent, is between 25 and 40 Da. Fatty acid alkanolamide is a non-ionic detergent, which may be in the range of These two substances are compatible and sometimes have a synergistic effect on cleaning action. bring about.

In a preferred embodiment, the surfactant is an alkyl, aryl, sodium, calcium magnesium, ammonium, potassium, mono-, di- or triethanol Lua.

Mine or isopropanolamide, sodium olefin sulfonate, sodium Thorium alkyl or dialkyl naphthalene sulfonate, alkyl (C1゜ -018), sodium, calcium, magnesium, ammonium, or Lithium sulfonate or sulfonated sulfosuccinate derivative , alkyl (C+.-CIl+) diphenyl oxide, sodium, calcium, alkyl Sulfonate substituted with ammonium or alkanolamide disulfonate esterified or half esterified sodium, potassium, calcium or or other neutralized diogtylsulfosuccinates, nonionic fluorocarbon interfaces. consisting of two or more anionic surfactants selected from the group consisting of surfactants. It's okay.

Surfactants can wet litter mites, but they alone cannot kill live mites. It cannot kill or render tick eggs infertile; instead, , expanded microorganisms that aid the cleaning process and kill microbial life, including litter mites. Cell sources are used in detergents, micellar solvents and other chemicals. moreover, Alkyl, dimethyl, and benzene for added broad-spectrum bacterial action. chloride, bromide or iodide of dill or ammonium, alkyl, dimethyl Chyl or ammonium bromide, chloride or iodide, alkyl, tri- Methyl or ammonium bromide, chloride or iodide, or such Preferably, one or more fungicides of a general group of molecules are added, among which Also, alkyldimethylbenzyl ammonium chloride is preferred. 71(5) Examples include those with a single or branched chain, and hydrophobic substances substituted with halogens. cations reacted with chloride, bromide or iodide, or nitrogen element is replaced by a phosphonous by an active cation Different cationic types, such as those with the strongest bactericidal active cationic surfactants The different surface tensions obtained by the cations may be properly prepared and used. The preferred amount of surfactant is 35.0 percent of the total surfactant content. up to 0.025 to 1.0 percent for ready-to-use compositions. For products that are diluted, it ranges from 1.0 to 10.0.

The cationic surfactant may be supplemented by a second fungicide, this fungicide is preferably of the micellar, poorly attractive, proton-donating type.

It is often used for certain industrial purposes, including use in the veterinary and agricultural industries.

Preferred commercially available disinfectants include formaldehyde, glyoxal, and glutaraldehyde. Hyde, succinic aldehyde, crotondialdehyde, or cyclic or semicyclic is an aldehyde or ketone. Dantogard and Glydant (Glico Inc, USA), Kat hon) CG/I CP (Rhom & tlaas Inc, USA) , DMDH Hydantoin; Gerg+ all) 115 (Sutton Laboratories Inc, USA) ; Givgard D XN (Givaudan USA) and There are many other fungicides that may be used, and the amount of the second fungicide may vary. For compositions used directly, the range is 0.01 to 0.25%; When used as a diluent, it may range from 0.5 to 7.5 percent.

As is clear from the foregoing description, some of the components may perform more than one function at the same time.

Therefore, it functions as a kind of surfactant agent. Alkanolamines are solvent-free. Enhances the cleaning action by increasing the pH value so that it reacts immediately with fatty acids It also contributes to dissolving allergenic proteins.

The main feature of the compositions according to the invention is that they contain the surface of mites, their eggs and allergens. Solvent/detergent systems that effectively wet proteins and therefore act as acaricidal compounds This means that the agent is brought into strong contact with the target. Generally, the micellar structure is Among the aqueous compositions used, various solvents, glycols, alcohols, alkaline Widely associated with amines and micelles and contributes very effectively to the surface activity of compositions. Mix with surfactant.

Furthermore, conventional solid dispersions that would soften hard water in the compositions of the present invention Most preferably, such systems include systems and suspension systems; Found in detergents. However, in this case, the system chosen is each of the systems disclosed herein. The composition must be compatible with acaricides and bactericidal agents.

The soil suspension system has a cleaning action. assists in water softening and re-deposition of stains when removed from textiles Preferably, those that help prevent lium, tetrasodium birophosphate, tetrapotassium birophosphate, hexameta Sodium phosphate, or neutralized ethylenediamine acetate tetranatriate such as chelating agents such as analogs of amine or substituted derivatives of ethylenediamine are added. preferably an inorganically neutralized polyester with effective soil suspension properties. Acrylates or polyacrylate copolymers may also be used.

Soil dispersing systems are currently used in detergents. It may be of the type common to, and known to those skilled in the art. But the choice Chemicals that have been used can re-contaminate with unwashed residue after use. Preferably, the system should not be Sodium salt, sodium bicarbonate and sodium tripolyphosphate, pyrophosphate Tetrapotassium phosphate, tetrasodium pyrophosphate or tet Polymerized phosphates such as sodium lafossuate and ethylenediaminetetate triacetate, sodium nidol triacetate, disodium aluminum silicate um, trisodium nitriloaryacetate, te1, lanium ethylene diacetate Groups of ethylenediamine derivatives substituted with amine acetate or equivalent Loop chelating agent and polyacrylate dispersion, polyvinylpyrrolidone, nato aluminum carboxymethylcellulose and zeolite or sodium aluminum silicate and an ammonium salt of styrene malic acid anhydride resin. Essential The amount required is proportional to the amount of surfactant in the tissue and preferably Therefore, it is in the range of 0.1 to 5.0%.

The pH of the formulation is controlled by polymerized phosphates, buffers such as sodium citrate, young or a combination thereof, or an alkanol alcohol selected from the aforementioned selections. should be regulated by min. The dilution level and pH suitable for use are 4. The pH should be in the range of 5 to 1000, but in certain cases the pH Laundry like ammonium silicate, magnesium fluorosilicate, zinc fluorosilicate may be made more acidic by the use of a specific acid, with a pH ranging from 3.0 to 5.0. Make it. requires 0.10 to 5.0 percent acid in the specific composition. Ru. The purpose of acidification is to act as a soil decomposition or release agent; These are the more widely known "pre-spray J" (pre-spray J) before use of the original composition. It acts as a spray.

Additionally, ancillary dyes may be included to impart a special color to the composition, and It is also conceivable to include an appropriate amount of fragrance. Add sodium to stabilize the solution. Hydrotropes such as muxylene sulfonate or ethanol or isopropyl A small amount of low molecular weight alcohol such as alcohol may be required as mentioned above. Ru. The amount of hydrotrope will vary depending on the composition, but preferably It ranges from 1.0 to 25.0 percent of the composition. Preferred hydroto The rope depends on the formulation of the preferred composition.

The method according to the invention comprises, firstly, a solution of the invention diluted in 1 part to 3 to 6 parts of water. Pre-spray the composition onto the surface and allow the formulation to remain on the surface for 1 to 2 hours. , secondly, a solution containing 1 part of the composition of the present invention to 15 to 40 parts of water or hot water; The solution can be sprayed under pressure or injected by dipping into the solution under vacuum. ion) cleaning and then using commercial or household carpet cleaning equipment. The surface is wet and the composition is removed by removing excess solution under high vacuum. Dry for 2 to 8 hours so that the activity remains and the mite-killing and bactericidal effects continue. I am made to do so.

Pre-spraying allows the cleaning solution to soak into the carpet at the same time. Due to the wet cleaning process, where the piles are removed after being removed through the pile. This can be omitted in the case of many domestic carpets, especially on very soiled carpets. If there are stains, spraying will remove stubborn, hardened, and strongly adhered stains before cleaning. Pre-spray with a weak acid ``sour type'' to bring it to the surface. It is effective to use

For purposes of illustration only, preferred embodiments of the invention are disclosed herein as Examples It will be done. The following examples demonstrate preferred ingredient ranges for compositions according to the invention.

Example work Surfactant: Teric X5 (1) 2.5% Teric ric) N15 (2) 1.0% Teric 12A8 (3) 0.65% Teric N50 (4) 2.5% coconut 3 Ethanolamide 0.8% Lauryl methylamine oxybi 0.35 % Power (Gardiquat) 1480 (5) 1.6% Recall: Ethylene glycol (noethyl ether 5.0% a Alcohol: Benzyl alcohol 7.0% Amine: Monoethanolamine 1 ．． 3% Other ingredients Odor Caributol 0.1% Ethanol 1O80% Urea 4.3% Tetrapotassium birophosphate 1.0% EDTA Na3 1.0% Citric acid 1.8% water residual (1) Terik x5 - octylphenol containing 5 moles of ethylene oxide Commercially available nonionic surfactants consisting of toxylates (1(J) (2) Terik IJ15-nonylphenol containing 15 moles of ethylene oxide Commercially available nonionic surfactants (ICI) consisting of ethoxylates (3) C12 alcohol ester containing 8 moles of teric 12A8-ethylene oxide Commercially available nonionic surfactants (ICI) consisting of toxylates (4) Nonylphenol ether containing 50 moles of teric N50-ethylene oxide Commercially available nonionic surfactants (ICI) consisting of toxylates (5) Guardiquat 1480 - 80% active alkyl dimer in ethanol Tylbenzyl ammonium chloride (Albright & Wilson Li m1ted) Example ■ Surfactant: Teric (Teric) X 10 (6) 0.5% Teric (T eric) 12A4 (7) 0.65% Terik N50 0.65% ・Power Tequat 1480 1.75% glycol: Link ° Recall 1,000 ethyl ether 7.5% Alcohol: Benzyl Alcohol 8.0% Amine: Isopropanolamine 2.0% Other ingredients: Limone 0.15% Urea 1.5% Citric acid 0.8% Sodium acrylic relay 1 dispersion 2.5% water remainder (6) Octylphenol containing 10 moles of teric Xl0-ethylene oxide Commercially available nonionic surfactants (ICI) consisting of ethoxylates (7) Synthetic linear chain containing 4.5 moles of teric 12A4-ethylene oxide (average Cl2) Commercially available nonionic surfactants consisting of alcohol ethoxylates Agent (ICI) Example ■ Surfactant: TELIX x100.9% Teric 9A5 (8) 1.25% Teric 850 1.3 % coconut jetanolamide Bardac 22 (9) 3.0% glycol : Diethylene glycol (noethyl ether 21.0% alcohol: base) Dyl alcohol 10.0% Amine: Monoethanolamine 2.5% Others Ingredients Odor Caributol 0.1% Ethanol 17.5% Urea 2.3% E D T A N a 3 1.75% Citric acid 0.8% Sodium hydroxide) dispersion i 2.5% water residual (8) Synthetic linear chain containing 5 moles of teric 9A5-ethylene oxide (average C9C ) Commercially available nonionic surfactants consisting of alcohol ethoxylates ( ICI) (9) Pardac 22 - Commercially available double chain alkyldimethylbenzi Ammonium chloride (Lonza Inc. USA) Example ■ Surfactant: Telik 12A8 4.　O%ampbote rge) 251 (10) 2.55% lauryl chloride methylamine oxide], 0% Power ° Te ° Equal 1480 3.0% Glycol: Shiechi Lenklicol 18.0% Alcohol: Benzyl Al Coal 9.0% Amine: Monoethanolamine 2.0% Other components: Eta Nord 7.5% Urea 3.0% Tetrapotassium birophosphate 1.25% Sodium 0 Reacrylate tlt. 1 & 2.5% water remainder (10) Amphotage 251 - a commercially available amphoteric surfactant (Lonza Inc. US) Example■ Surfactant: TELIX X5 2. 0% Telik N15 2.　5% Teritsuku N50 3.　O% Coconut ethanolamide 2.5% strength equal 1480 4.5% Glycol: Ethylene glycol 1,000 ethyl ether 40.0% Alcohol: Benzyl alcohol 20.0% n decanol 5 ．． 0 Amine: Monoethanolamine 3.0% Other ingredients Oodocaributol 1 ．． 0% ethanol 16.0% Citric acid 1.0% Nidolyl triacetate trisodium 1.0% (note: without water) Example■ Surfactant: Telik XIO 2. 0% Terric 12A4 2.　5% Coconut Sheet Ethanolamide 9 1.0% Ha9ter Fuku 22 4.0 % to”) 022 (11) 0.5% Glycol: Ethylene glycol king noethyl ether 16.0 % Alcohol: Benzyl Alcohol 8.5% Amine: Monoethanolamine 1.5%Other ingredients Niocaributol 0.25%Ethanol 12.0% Nidolyl triacetate trisodium 1.8% water remainder (11) Petro 22 - Sulfonated and substituted naphthalenes Derivative (Soneborn Oil Co. USA) Example ■ Surfactant: TELIX X5 3. 0% Teric 12AI2 (12) 1.5% TELIX 9A5 1.0% Teritsuku N50 1.　5% Coconut jetanolamide ° 0.5% lauryl dimethylamine oxide Power Tee Ik 7t 1480 3.0% Glycol: Ethylene ° Recall Dried Noethyl Ether 18.0% Alcohol: Benzyl Alcohol 7.0% Amine Nidiethylamine Ethanol 1.5% Other ingredients Squid Ributol 0.15% Ethanol 8.0% Urea 2.5% Citric acid 1.0% Nidryl triacetate trisodium 2.0% × sodium acrylate Um 2.0% water residual (12) Lauryl alcohol containing 12 moles of teric 12A12-ethylene oxide A commercially available nonionic surfactant (ICI) consisting of alcohol ethoxylate Example■ Terik N15 2. 0% Telik 12A4 1.　5% Eighth - Evening Fuku 22 4. 0% Glycol: Ethylene glycol Cole Sennoethyl Ether 15.0% Alcohol: Benzyl Alcohol 7 ．． 5% Amine: Monoethanolamine 2.3% Other ingredients Odoric caributoe Le 0.1% Glyoxal 0.25% Ethanol 8.0% Citric acid 1.0% Nidolyl triacetate trisodium 1.5% Nidril triacetate trisodium Um dispersion 2.5% water remainder Example■ Surfactant: Terik 12A4 1.8% Sarkosyl NL 30 (13) 3.0% power゛-teequat 1480　2.5%〇te B 22 1.0% Glycol: Ethylene glycol monoethyl ether 17.5 % Alcohol: Benzyl alcohol 8.0% Amine: Monoethanolamine 2.5%Other ingredients Niocaributol 0.1%Ethanol 1.80% Citric acid 1.0% Nidolyl triacetate trisodium 1.5% Um dispersion 2.5% water remainder (13) Circosyl NL30 - a commercially available amphoteric surfactant (Ciba-G eigy Inc) Example X Surfactant: TELIX X5 1.0% Telik 12A12 1.0% Teritsuku 9A5 1.5% Telitsuku N50], 5% Lauryl methylamine oxide (50%) 1.0% strength 1480 3.0% Glycol: Ethylene glycol monoethyl ether 13.5% alcohol: benzyl alcohol 7.5% amine : Monoethanolamine 1.5% Other ingredients: Ethanol 7.5% Urea 2.0% Sodium acrylate dispersion 2.0% Macnesicum fluorosilicate 1.5% water remainder In the above example, the glycol used throughout was diethylene glycol moiety. Noethyl ether, but other glycols mentioned may be substituted, as well The aromatic alcohol used throughout was benzyl alcohol. , others may be substituted, using long-chain alkyl alcohols in powdered compositions. You can also Aqueous (or liquid if concentrated for use as non-aqueous) udder formulation) by mixing the appropriate elements in the solvent, e.g. 0.5 to 0.5% of Example V to the adsorbent powder or powder mixture. By absorbing 10.0%, it is a mite-killing and sterilizing cleaning powder. Udah can be manufactured.

Such a mixture consists of equal weights of sodium bicarbonate and diatomaceous earth. Ru. such as sodium sulfate, sodium borate or sodium tripolyphosphate. Other inorganic chemicals may be used, such as grains and other inorganic chemicals. d) Natural materials can also be used. Also, crushed or sprayed with high solvent adsorption -Dried polymers are suitable for this purpose. By this method powder Products that have been treated as This type of preparation should be able to consist of a kind of textile like This is especially important when water is not available.

In order to produce the compositions shown in Examples T to X, first, a surfactant and a glycosylation agent were added. These are then diluted with water if necessary. and the other components are individually dissolved therein. Finally, the solution must be Tomei. If so, then hydrotropes, ethanol, or both are preferred. added until stability is achieved. Finally, the dye is added and the pH is properly adjusted. be done.

Any residue left on the fiber or after drying is removed from the preferred composition. without causing damage to textile fibers, degradation or partial loss of dye after application of the product; The basic interface is Surfactant systems can be formulated in a variety of different ways by those skilled in the art. Examples I to X describes various methods by which suitable surfactant systems may be formulated; It is not limited to these. In any one molecular species of the above-mentioned surfactants Also, the length, branching or substitution of the hydrophobic part of the molecule can be varied, making it possible to A mixture of ethylene and propylene oxide is added to form a surfactant. Alternatively, the degree of ethoxylation can be varied by using propylene oxide alone. or -○H group at the end of the molecule to form sulfate or phosphate. can react. The latter is then treated with alkali salts, ammonia or is neutralized by alkanolamines. Various types of zwitterionic surfactants The surfactants are utilized to provide each with special surface-active properties and behaviors. Ani On-based surfactant A olefin sulfonate, substituted alhernaphthalene sulfate The wood can be treated with monovalent or divalent cations or with ammonia or alkali. Can be neutralized by canolamine.

Textile detergents exhibiting the aforementioned interfacial behavior and are good when containing other ingredients in the aforementioned proportions. and which in certain uses would result in a product that is acaricidal and fungicidal. Those skilled in the art will be able to use these and other commercially available surfactants to provide surfactant systems. You will be able to choose from sex agents.

Overall, the composition is (a) Nonionic, cationic, slightly anionic for low foaming compositions: medium foaming Slightly anionic, alkanolamide, amphoteric for foam compositions: Slightly anionic, alkanolamide, amphoteric for foam compositions; amphoteric and sulfurized or sulfonated surfactants; (b) alkyl glycols; water-miscible solvents such as alcohols, ketones and ethers; (C) At least partially water-immiscible solvents such as aromatic solvents and terpenes. ; (d) Aromatic alcohols　Ce　mite control such as C20 alkyl alcohols agent; (e) phosphate, citrate, polyacrylate, substituted cellulose, Detergent builders like silicates, aluminosilicates, polyvinylpyrrolidone (f) Tetrasodium EDTA, trisodium nidolyl triacetate, etc. Una chelating agent; (g) If necessary, use absorbent materials such as sodium carbonate, diatomaceous earth, or crushed plastic. Adhesive; Consists of a combination of

The mite extermination efficacy of Example ① is shown in the table below.

This table was produced by Australian Patent Application No. 44604/85. Composition of commercially available acaricide ALLER-3EARCH DMS and Example ① Comparing the characteristics of things.

The day of your second birthday.

Dilution 1/2 1/4 1/8 1/16 1/32 Example TV 6 14 ．． 5 17 23 50 Allersearch 7 9.5 21 45 5 9NS Both products have balanced acaricidal action at high concentrations, but at low dilutions of 1/16 In terms of performance, Example 2 shows a much better effect. However, ALLER3 EARC) I Dj'lS cannot kill oocysts, and Example ■ is not recommended. will prevent fertilization if used in a controlled manner.

Aromatic alcohols and alkyl alcohols in aqueous detergent systems have quick mite-killing action. This is thought to be due to the combination of The particles in the micellar structure exert the necessary interfacial behavior to attach to the mite and its eggs. This is thought to be because it is incorporated to a certain extent (but not completely).

Aromatic alcohols and long chain aliphatic alcohols exert the main acaricidal activity.

Due to their low solubility in aqueous systems (for which the use of aromatic alcohols is preferred), Aliphatic alcohols can be used primarily in non-aqueous powder compositions.

Glycol promotes cleaning action and includes dissolving dust mite allergens, Helps provide the required interfacial behavior. In addition, alkanolamines pH of the system to help dissolve allergens and promote reaction with fatty acids and thus further improve the cleaning action.

Adding organic solvents is useful to improve the cleaning action. Special Aromatic solvents such as terpenes, which themselves have acaricidal properties, are useful. be.

The method according to the invention is as follows.

1. Carpet diluted the product of Example ■ with 1 part to 3 to 6 parts of tap water. pre-sprayed with water (just to evenly moisten, not wet), this is -Leave on pet for 1-2 hours. During this time, the carpet, i.e. fiber It soaks into the skin, pre-washes stains and dirt, and releases them.

2. The carpet is then sprayed with a machine that sprays detergent onto the carpet. is cleaned and then mixed with 1 part of Example ■ to 15 to 40 parts of water under vacuum. and collect it into a collection tank. Also, concentration, fiber type and Depending on the location of the carpet, many types of heavy industrial spray (steam) cleaners are used. cleaning equipment may be used, in some cases similar to ordinary domestic carpet cleaning. In some cases, it is practical to eliminate the pre-spray step. Instead, a strong solution Used to spot spot stains and stains just before wet cleaning.

After cleaning, the carpet remains damp as in Example ■, and should not be exposed to sunlight or machined. It is then gradually dried over a period of 2 to 8 hours. During drying, the product, e.g. Item (3) remains active and continues to have mite-killing and bactericidal effects.

As mentioned above, if you have particularly stubbornly soiled carpets, spray (steam) Before cleaning, use a mild acid to release stubborn hardened and strongly adhered stains. It is effective to use a "sour type" pre-spray.

The composition of Example It is of type.

The foregoing description may include specific embodiments or means for producing the disclosed effects, or features expressed as a method or process for obtaining a disclosed result. They can be divided or combined and used to carry out the present invention in various ways. Ru.

international search report ,,,,,,,,-,,,,,,POT/GB 89100691 International Search Report

Claims (1)

[Claims] (1) (a) glycol or alkyl glycol, (b) one or more long chain alkyl Alcohol, cyclic or aromatic alcohol, (c) alkanolamine or amine and (d) a miticide detergent composition comprising one or more surfactants. (2) The glycol or alkyl glycol is ethylene glycol, propylene glycol, Ren glycol, diethylene glycol, dipropylene glycol, triethylene glycol, or each of these mono- or di-methyl, ethyl, pro- Ethyl 3-ethoxypropionate or 3 of pill or butyl ether The set of claim 1 selected from the group consisting of methyl methoxybutanol. A product. (3) The glycol or alkyl quelicol is 1.0 to 4 3. The composition of claim 2, wherein the composition is in the range of 5.0 percent. (4) The alcohol is soluble, insoluble, or partially soluble in an aqueous solution. The composition of claim 1, which is degradable. (5) The alcohol is benzyl or phenylethyl alcohol, or 5. The composition of claim 4 selected from the group consisting of phenoxyethanol. (6) The alcohol is in the range of 0.05 to 25% based on the composition. 3. The composition of claim 2. (7) The composition according to claim 1, further comprising an organic solvent. (8) The composition according to claim 7, wherein the solvent is a terpene. (9) The terpenes include dipentene, terpinolenterpineol, eucalyp Tall, citral, oxtail, pinene, limonene, terpinene-4-o 9. The composition of claim 8, wherein the composition is selected from the group consisting of Y-terpinene. (10) The solvent is in a range of 0.25 to 10.0% based on the composition. 8. The composition of claim 7. (11) Alkanolamine or amine is monoethanolamine, isopropanol Nolamine, diethylaminoethanol, diethanolamine, or trieta 2. The composition of claim 1, wherein the composition is selected from the group consisting of nolamines. (12) The alkanolamine or amine is 0.25 to 5 ．． 8. The composition of claim 7 in an amount of 0 percent. (13) The surfactant may be anionic, nonionic, amphoteric, or cationic. The composition according to claim 1, which is based on the composition. (14) The surfactant may be present in an amount of 0.05 to 30.0% based on the composition. 14. The composition of claim 13 within the range. 15. The composition of claim 1 having an additional soil dispersing suspending compound. (16) The additional compound may be one or more of sodium carbonate, sodium citrate, um, sodium bicarbonate and sodium tripolyphosphate, pyrophosphate totetrapotassium, tetrasodium pyrophosphate, sodium tetraphosphate Thorium, trisodium nitrile triacetate, tetrasodium ethylene Ethylenediamine derivatives substituted with diamine acetate or equivalent, chelating agents from the group of polyacrylate dispersions, polyvinylpyrrolidone, Sodium carboxymethyl cellulose and zeolite or sodium aluminum silicate Claim 1 consisting of an ammonium salt of anhydride resin of styrene malic acid and styrene malic acid anhydride resin. 5. The composition according to 5. (17) The additional compound is 0.1 to 5.0% based on the total composition. 16. The composition of claim 15 within the range of. (18) In addition, the hydrochloride is added in a predetermined required amount to stabilize the composition. 2. The composition of claim 1, comprising a rope. (19) The hydrotrope is urea, ethanol, xylene sulfonate 19. Selected from the group of toluenes or sulfonate toluenes. composition. (20) The hydrotrope accounts for 0.5 to 25.0% of the total composition. 20. The composition of claim 19, wherein the composition is within the range of . (21) Up to 35% of the surfactant is a cationic disinfectant. chloride, bromide or iodide of alkyldimethylpendylammonium , chloride, bromide or iodide of dialkyldimethylbenzylammonium , alkyltrimethylammonium bromide, chloride or iodide, or The composition of claim 1, wherein the composition is a cationic fungicide of similar molecules. (22) Additional fungicides of the atom-donating type include formaldehyde, glyoxal glutaraldehyde, succinic dialdehyde, croton dialdehyde or selected from the group consisting of cyclic or semicyclic aldehydes or ketones; 22. The composition of claim 21, comprising: (23) The additional fungicide is 0.01 to 7.5 percent based on the composition. 22. The composition of claim 21, within the range of. (24) When dissolved at a concentration of 0.25 to 25.0% in water, Liquid or powder that has a pH of 4.5 to 10.0 at the desired dilution level A composition according to claim 1. (25) Addition of ammonia to form a product usable as a soil release agent. acidified with aluminum, magnesium or zinc fluorosilicate. The composition according to claim 1. (26) The fluorosilicate additive is present in an amount of 0.10 to 5.0% of the composition. 26. The composition of claim 25, wherein the composition is within the range of . (27) Stable when mixed, including sodium bicarbonate, sodium sulfate, and Sodium urate, sodium tripolyphosphate, diatomaceous earth, with high solvent absorption powder selected from the group consisting of crushed or sprayed polymers; 2. The composition of claim 1, wherein the composition is on a sorbent. (28) The surfactant is alkyl, aryl, sodium, calcium, Gnesium, ammonium, potassium, mono-, di- or triethanolamine or isopropanolamide, sodium olefin sulfonate, sodium alkyl or dialkyl naphthalene sulfonate, alkyl (C10-C 18), sodium, calcium, magnesium, ammonium, or lithium umsulfonate or sulfonated sulfosuccinate derivative, a Lucyl (C10-C18) diphenyl oxide, sodium, calcium, ammonia um or alkanolamide disulfonate and sulfonated. or half esterified sodium, potassium, calcium or others Neutralized dioctyl sulfosuccinate, a nonionic fluorocarbon surfactant A claim consisting of two or more anionic surfactants selected from the group consisting of Item 1. The composition according to item 1. (29) 5.0 to 50.0% of anionic surfactants are replaced by an amphoteric surfactant that acts as a non-hygroscopic powdery residue upon drying. 29. The composition of claim 28. (30) The composition according to claim 1, wherein the composition is in liquid or powder form. (31) Mites substantially identical to those described with reference to Examples I to X above. Disinfecting composition.