JP2005054124A - Detergent composition - Google Patents
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本発明は人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の洗浄剤組成物、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去方法、ダニ誘引緩和用洗浄剤組成物に関する。 The present invention relates to a human-derived mite attractant and a human-derived mite attractant precursor cleaning composition, a human-derived mite attractant and a human-derived mite attractant precursor removing method, and a tick-induced mitigation detergent composition Related to things.
近年の住宅の高密閉化による室内空間の高温多湿化に伴い、布団、ソファー及びマット等にダニやカビ等が繁殖し易い環境となり、その人体への影響が問題となってきている。そして住居内のダニは、気管支喘息、アレルギー鼻炎等のアレルギー性疾患や、皮膚炎の原因となるため種々の防除剤が開発されている。 Accompanying the recent increase in the temperature and humidity of indoor spaces due to the high sealing of houses, it has become an environment in which mites, molds, etc. tend to propagate on futons, sofas, mats, etc., and its influence on the human body has become a problem. Various mites have been developed for mites in the house because they cause allergic diseases such as bronchial asthma and allergic rhinitis and dermatitis.
ダニ防除剤としては、ピレスロイド系、カーバメイト系、有機リン系等の各種薬剤が使用されているが、これらの薬剤は毒性が高く、住居内、特に小児のいる家庭では安全性上好ましいものではなかった。またこれら従来のダニ防除剤は、揮散性が少ないので、直接塗布した場所では効果が得られたとしても、カーペットやソファー、布団の内部等の通気性の悪い場所では、特に効果が弱かった。 Various drugs such as pyrethroids, carbamates, and organophosphorus are used as mite control agents, but these drugs are highly toxic and are not preferred for safety in homes, especially in families with children. It was. In addition, these conventional mite control agents have low volatility, so even if the effect is obtained in a directly applied place, the effect is particularly weak in a place with poor air permeability such as the inside of a carpet, sofa, or futon.
また、ダニの死骸や糞もアレルゲン物質であることから、ダニを直接殺すだけでなく、忌避作用の強い防除剤が求められている。ダニ忌避剤として、安全性が比較的高いと考えられる植物精油成分のリナロールやカルボンを用いたダニ駆除剤（特許文献１、２）が提案されているが、これらの効果も充分ではなかった。 In addition, since mite carcasses and feces are allergenic substances, there is a demand for a control agent that not only kills mites directly but also has a strong repellent action. As a tick repellent, a tick control agent (Patent Documents 1 and 2) using linalool or carvone, a plant essential oil component that is considered to be relatively safe, has been proposed, but these effects are not sufficient.
また、防除剤を用いない防虫材料として、特許文献３には、１デニール以下の極細繊維からなる綿、或いは表面が綿状であるか又は表面が起毛ないし植毛されている織布又は不織布を含むダニ防除具が記載されている。また、特許文献４、５には、繊維集合体の外周部に所定の繊維間隔の極細繊維層を配してなる防虫性繊維構造物が記載されている。また、特許文献６には、所定の繊維間隙、所定の繊維径、及び所定の繊維充填率を有する不織布からなる畳床用防虫シートが記載されている。更に、特許文献７には、ポリプロピレン系重合体からなる極細繊維不織布層の両面にポリプロピレン系重合体からなる長繊維不織布層が積層一体化されてなる耐アレルゲン性寝具カバーが記載されている。 Further, as an insect repellent material that does not use a control agent, Patent Document 3 includes cotton made of ultrafine fibers of 1 denier or less, or a woven or non-woven fabric whose surface is cotton-like or whose surface is raised or planted. A tick control device is described. Patent Documents 4 and 5 describe insect-proof fiber structures in which ultrafine fiber layers having a predetermined fiber interval are arranged on the outer periphery of a fiber assembly. Patent Document 6 describes an insect-proof sheet for a tatami floor made of a nonwoven fabric having a predetermined fiber gap, a predetermined fiber diameter, and a predetermined fiber filling rate. Further, Patent Document 7 describes an allergen-resistant bedding cover in which a long fiber nonwoven fabric layer made of a polypropylene polymer is laminated and integrated on both surfaces of an ultrafine fiber nonwoven fabric layer made of a polypropylene polymer.
しかしながら、上記各公報に記載の防虫材料は、極細繊維を使用しているので、寝具や家具等のカバー材としては肌触りが良くなく、また繊維中にダニが残るという欠点があった。 However, since the insect repellent materials described in each of the above publications use ultrafine fibers, they have a drawback that they do not feel good as a cover material for bedding, furniture, etc., and mites remain in the fibers.
また、特許文献８、９、１０には、ダニ誘引物質を用い、誘引されてきたダニを駆除する方法が記載されている。しかし、駆除しきれなかった場合、かえってダニを集めるだけになり不都合が多かった。人の分泌物或いは人の分泌物の酸化物の中にはダニ誘引物質が多く存在するため、人と直接接する寝具類では、公知の方法によるダニ誘引駆除効果はあまり期待できなかった。 Patent Documents 8, 9, and 10 describe a method for combating attracted ticks using a tick attractant. However, if they could not be removed, there were many inconveniences because they only collected ticks. Since there are many mite-inducing substances in human secretions or in human secretions, bedding that is in direct contact with humans could not be expected to have a tick-inducing effect by a known method.
また、特許文献１１、１２には、ダニ忌避物質によるダニ駆除方法が記載されている。しかし、ダニ誘引物質の存在下におけるダニ忌避効果は多くを望めなかった。 Patent Documents 11 and 12 describe a tick control method using a tick repellent substance. However, the mite repellent effect in the presence of the mite attractant could not be expected.
一方、近年の洗濯機は、環境・エネルギー問題や経済性への対応から、高浴比（衣料／洗浄水）化、運転時間の短縮化、低動力撹拌化等の傾向にあり、従来知られている洗浄剤組成物では、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体を十分に洗浄できない傾向にある。このため、低機械力でも人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体に対する洗浄力の高い洗浄剤が求められている。特許文献１３には、脂質分解酵素を配合した、皮脂の蓄積汚れに優れる洗浄剤が記載されているが、脂質の分解によりかえって、ノナナール等の人由来のダニ誘引物質の増加となり、好ましくない。
本発明の課題は、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の洗浄剤組成物、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去方法、ダニ誘引緩和用洗浄剤組成物を提供することにある。 An object of the present invention is to provide a cleaning composition for a human-derived tick attractant and a human-derived tick attractant precursor, a method for removing a human-derived tick attractant and a human-derived tick attractant precursor, and mite attraction mitigation It is to provide a cleaning composition.
本発明は、
（ａ）陰イオン界面活性剤〔以下、（ａ）成分という〕１０〜３０質量％、
（ｂ）非イオン界面活性剤〔以下、（ｂ）成分という〕２〜１５質量％、
（ｃ）蛋白質分解酵素〔以下、（ｃ）成分という〕０．００１〜２質量％、
（ｄ）炭水化物及び／又は炭水化物誘導体〔以下、（ｄ）成分という〕０．００１〜１０質量％、
（ｅ）水溶性無機塩〔以下、（ｅ）成分という〕２５〜５０質量％、
を含有し、
（ａ）と（ｂ）の質量比が（ａ）／（ｂ）で１０／１〜１０／１２、
（ａ）と（ｂ）の合計量が１５〜４０質量％、
（ｃ）と（ｄ）の質量比が（ｃ）／（ｄ）で２／１以下、
（ａ）と（ｂ）の合計量と（ｅ）成分の質量比が〔（ａ）＋（ｂ）〕／（ｅ）で４／３〜１／３、
（ａ）、（ｂ）、（ｅ）の合計量が５０〜８０質量％、
組成物のカルシウム捕捉量３０〜２００ＣａＣＯ3ｍｇ／ｇ
である、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の洗浄剤組成物に関する。
The present invention
(A) anionic surfactant [hereinafter referred to as component (a)] 10 to 30% by mass,
(B) 2-15% by mass of a nonionic surfactant (hereinafter referred to as component (b)),
(C) Proteolytic enzyme [hereinafter referred to as component (c)] 0.001 to 2% by mass,
(D) Carbohydrate and / or carbohydrate derivative (hereinafter referred to as component (d)) 0.001 to 10% by mass,
(E) Water-soluble inorganic salt [hereinafter referred to as component (e)] 25-50% by mass,
Containing
The mass ratio of (a) and (b) is 10/1 to 10/12 in (a) / (b),
The total amount of (a) and (b) is 15-40% by mass,
The mass ratio of (c) and (d) is 2/1 or less in terms of (c) / (d),
The mass ratio of the total amount of (a) and (b) and the component (e) is [(a) + (b)] / (e) 4/3 to 1/3,
The total amount of (a), (b), (e) is 50-80% by mass,
Calcium trapping amount of the composition 30 to 200 CaCO 3 mg / g
It is related with the cleaning composition of a human-derived tick attractant and a human-derived tick attractant.
また、本発明は、
（ａ）成分１０〜３０質量％、
（ｂ）成分２〜１５質量％、
（ｃ）成分０．００１〜２質量％、
（ｄ）成分０．００１〜１０質量％、
（ｅ）成分２５〜５０質量％、
を含有し、
（ａ）成分と（ｂ）成分の質量比が（ａ）／（ｂ）で１０／１〜１０／１２、
（ａ）成分と（ｂ）成分の合計量が１５〜４０質量％、
（ｃ）成分と（ｄ）成分の質量比が（ｃ）／（ｄ）で２／１以下、
（ａ）成分と（ｂ）成分の合計量と（ｅ）成分の質量比が〔（ａ）＋（ｂ）〕／（ｅ）で４／３〜１／３、
（ａ）成分、（ｂ）成分、（ｅ）成分の合計量が５０〜８０質量％、
組成物のカルシウム捕捉量３０〜２００ＣａＣＯ3ｍｇ／ｇ
であるダニ誘引緩和用洗浄剤組成物に関する。
The present invention also provides:
(A) 10-30 mass% of component,
(B) 2-15 mass% of component,
(C) 0.001 to 2% by mass of component,
(D) 0.001-10 mass% of components,
(E) component 25-50 mass%,
Containing
The mass ratio of the component (a) and the component (b) is 10/1 to 10/12 in (a) / (b),
The total amount of the component (a) and the component (b) is 15 to 40% by mass,
The mass ratio of the component (c) and the component (d) is 2/1 or less in terms of (c) / (d),
The total amount of the component (a) and the component (b) and the mass ratio of the component (e) is [(a) + (b)] / (e) 4/3 to 1/3,
The total amount of the component (a), the component (b), and the component (e) is 50 to 80% by mass,
Calcium trapping amount of the composition 30 to 200 CaCO 3 mg / g
It is related with the cleaning composition for tick attraction relaxation which is.
また、本発明は、
（ａ）成分１０〜３０質量％、
（ｂ）成分２〜１５質量％、
（ｃ）成分０．００１〜２質量％、
（ｄ）成分０．００１〜１０質量％、
（ｅ）成分２５〜５０質量％、
を含有し、
（ａ）成分と（ｂ）成分の質量比が（ａ）／（ｂ）で１０／１〜１０／１２、
（ａ）成分と（ｂ）成分の合計量が１５〜４０質量％、
（ｃ）成分と（ｄ）成分の質量比が（ｃ）／（ｄ）で２／１以下、
（ａ）成分と（ｂ）成分の合計量と（ｅ）成分の質量比が〔（ａ）＋（ｂ）〕／（ｅ）で４／３〜１／３、
（ａ）成分、（ｂ）成分、（ｅ）成分の合計量が５０〜８０質量％、
組成物のカルシウム捕捉量３０〜２００ＣａＣＯ3ｍｇ／ｇ、
である洗浄剤組成物による、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去方法に関する。
The present invention also provides:
(A) 10-30 mass% of component,
(B) 2-15 mass% of component,
(C) 0.001 to 2% by mass of component,
(D) 0.001-10 mass% of components,
(E) component 25-50 mass%,
Containing
The mass ratio of the component (a) and the component (b) is 10/1 to 10/12 in (a) / (b),
The total amount of the component (a) and the component (b) is 15 to 40% by mass,
The mass ratio of the component (c) and the component (d) is 2/1 or less in terms of (c) / (d),
The total amount of the component (a) and the component (b) and the mass ratio of the component (e) is [(a) + (b)] / (e) 4/3 to 1/3,
The total amount of the component (a), the component (b), and the component (e) is 50 to 80% by mass,
Calcium capture amount of the composition 30-200 CaCO 3 mg / g,
It is related with the removal method of the tick attractant derived from a person and the tick attractant precursor derived from a person by the cleaning composition which is.
本発明によれば、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の洗浄効果に優れた洗浄剤組成物ないしダニ誘引緩和用洗浄剤組成物が得られる。 ADVANTAGE OF THE INVENTION According to this invention, the cleaning composition thru | or the cleaning composition for mite attraction reduction excellent in the cleaning effect of the human-derived tick attractant and the human-derived tick attractant precursor are obtained.
本発明の組成物は、いずれも組成物のカルシウム捕捉量が３０〜２００ＣａＣＯ3ｍｇ／ｇである。ここで、カルシウム捕捉量は次の方法で求められるものをいう。
（カルシウム捕捉量の測定方法）
カルシウム捕捉量（Ｃａ捕捉量）は、特開平3−277696号公報3頁右下欄6行目から4頁左上欄6行目記載の方法（但し、陰イオン性界面活性剤を洗浄剤組成物と読み替える）により求める。
In any of the compositions of the present invention, the calcium capture amount of the composition is 30 to 200 CaCO 3 mg / g. Here, the calcium capture amount refers to that obtained by the following method.
(Measurement method of calcium capture amount)
The calcium capture amount (Ca capture amount) is the method described in JP-A-3-277696, page 3, lower right column, line 6 to page 4, upper left column, line 6 (however, an anionic surfactant is used as a detergent composition). To read).
人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、カルシウム捕捉量は、４０〜１５０ＣａＣＯ3ｍｇ／ｇが好ましく、５０〜１００ＣａＣＯ3ｍｇ／ｇがより好ましい。 In terms of removal of mite attractant and human origin mite attractant precursor of human origin, calcium uptake amounts, 40~150CaCO 3 mg / g are preferred, 50~100CaCO 3 mg / g is more preferable.
本発明の組成物のＪＩＳ Ｋ ３３６２：１９９８により規定された方法で測定する見掛け密度は、利便性や廃棄物（例えば、箱等）を低減する観点から、６００ｇ／Ｌ以上が好ましく、７００ｇ／Ｌ以上がより好ましく、８００ｇ／Ｌ以上が更に好ましい。また、溶解性の点で、見掛け密度は１６００ｇ／Ｌ以下が好ましく、１３００ｇ／Ｌ以下がより好ましく、１０００ｇ／Ｌ以下が更に好ましい。 The apparent density measured by the method defined by JIS K 3362: 1998 of the composition of the present invention is preferably 600 g / L or more, from the viewpoint of reducing convenience and waste (for example, boxes), and is preferably 700 g / L. The above is more preferable, and 800 g / L or more is still more preferable. In terms of solubility, the apparent density is preferably 1600 g / L or less, more preferably 1300 g / L or less, and still more preferably 1000 g / L or less.
ＪＩＳ Ｚ ８８０１の標準篩を用いて５分間振動させた後、篩目のサイズによる質量分率から求める本発明の洗浄剤組成物の平均粒径は、溶解性に優れる観点から、１５０〜７００μｍが好ましく、より好ましくは１５０〜６００μｍ、更に好ましくは１８０〜４００μｍである。 After vibrating for 5 minutes using a standard sieve of JIS Z 8801, the average particle size of the cleaning composition of the present invention obtained from the mass fraction depending on the size of the sieve mesh is 150 to 700 μm from the viewpoint of excellent solubility. More preferably, it is 150-600 micrometers, More preferably, it is 180-400 micrometers.
洗浄剤組成物は、携帯性や簡便性の点で、一回の使用量を分包包装しても良く、また、圧縮成型して錠剤型にして包装しても良い。この時包装材料が水溶性であることが好ましい。 The cleaning composition may be packaged and packaged in a single use amount from the viewpoint of portability and simplicity, or may be compressed and molded into a tablet. At this time, the packaging material is preferably water-soluble.
人由来のダニ誘引物質としては、デカン酸、パルミチン酸、オレイン酸、酢酸、４−メチル−３−ペンテン−２−オン、６−メチル−５−ヘプテン−２−オン、ペプタナール、オクタナール、ノナナール、デカナール、リモネン等が挙げられる。人由来のダニ誘引物質前駆体としては、酸化等により前記ダニ誘引物質になる化合物が挙げられる。特に除去すべき人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体としては、酢酸、４−メチル−３−ペンテン−２−オン、ペプタナール、ノナナール、リモネン及びこれらの前駆体が挙げられる。最も除去すべき人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体としては、ノナナール及びこの前駆体であるオレイン酸、トリオレイン、ジオレインである。
＜（ａ）成分＞
本発明の組成物は（ａ）成分として陰イオン界面活性剤を１０〜３０質量％含有する。人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、１２〜２８質量％が好ましく、１５〜２５質量％がより好ましい。
As human-derived tick attractants, decanoic acid, palmitic acid, oleic acid, acetic acid, 4-methyl-3-penten-2-one, 6-methyl-5-hepten-2-one, peptanal, octanal, nonanal, Examples include decanal and limonene. Examples of human-derived tick attractant precursors include compounds that become the mite attractant by oxidation or the like. In particular, examples of the human-derived tick attractant and human-derived tick attractant to be removed include acetic acid, 4-methyl-3-penten-2-one, peptanal, nonanal, limonene, and precursors thereof. Nonanal and its precursors, oleic acid, triolein, and diolein, are human-derived mite attractants and human-derived mite attractants that should be removed most.
<(A) component>
The composition of this invention contains 10-30 mass% of anionic surfactant as (a) component. In terms of removability of the human-derived tick attractant and human-derived tick attractant precursor, 12 to 28% by mass is preferable, and 15 to 25% by mass is more preferable.
（ａ）成分として、アルキルベンゼンスルホン酸塩、アルキル又はアルケニルエーテル硫酸エステル塩、アルキル又はアルケニル硫酸エステル塩、α−オレフィンスルホン酸塩、α−スルホ脂肪酸塩若しくはそのエステル、アルキル又はアルケニルエーテルカルボン酸塩、脂肪酸塩等が挙げられる。中でも、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、α−スルホ脂肪酸塩若しくはそのエステルを含有することが好ましい。対イオンとしてアルカリ金属イオンが洗浄力向上の点で好適である。特に、溶解速度向上の観点から、カリウムイオンが好ましく、全対イオン中カリウムイオンは５質量％以上が好ましく、２０質量％以上がより好ましく、４０質量％以上が特に好ましい。
＜（ｂ）成分＞
本発明の組成物は（ｂ）成分として非イオン界面活性剤を２〜１５質量％含有する。人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、３〜１５質量％が好ましく、５〜１２質量％がより好ましい。
As component (a), alkylbenzene sulfonate, alkyl or alkenyl ether sulfate, alkyl or alkenyl sulfate, α-olefin sulfonate, α-sulfo fatty acid salt or ester, alkyl or alkenyl ether carboxylate, Examples include fatty acid salts. Especially, it is preferable to contain (alpha) -sulfo fatty acid salt or its ester at the point of the removal property of a human-derived tick attractant and a human-derived tick attractant precursor. Alkali metal ions are preferred as counter ions in terms of improving detergency. In particular, from the viewpoint of improving the dissolution rate, potassium ions are preferable, and the potassium ions in all counter ions are preferably 5% by mass or more, more preferably 20% by mass or more, and particularly preferably 40% by mass or more.
<(B) component>
The composition of this invention contains 2-15 mass% of nonionic surfactant as (b) component. 3-15 mass% is preferable and 5-12 mass% is more preferable at the point of the removal property of a human-derived tick attractant and a human-derived tick attractant precursor.
（ｂ）成分として、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、融点が４０℃以下のものが好ましく、より好ましくは３０℃以下、特に好ましくは２５℃以下である。融点は、ＦＰ８００サーモシステムのメトラーＦＰ８１（Ｍｅｔｔｌｅｒ Ｉｎｓｔｒｕｍｅｎｔｅ ＡＧ製）を用い、昇温速度０．２℃／ｍｉｎで測定される。例えば洗浄力の点から、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルキルフェニルエーテル、ポリオキシアルキレンソルビタン脂肪酸エステル、ポリオキシアルキレングリコール脂肪酸エステル、ポリオキシエチレンポリオキシプロピレンブロックポリマーが好ましい。特に炭素数１０〜１８のアルコールにエチレンオキシド（以下、ＥＯと表記する）を平均で４〜２０モル付加したポリオキシエチレンアルキルエーテルや、前記アルコールにＥＯを平均で４〜２０モル、プロピレンオキシド（以下、ＰＯと表記する）を平均で０．３〜４モル付加したもの、その中でもＥＯ・ＰＯ・ＥＯの順にブロック付加したものが好ましい。また、（ｂ）成分は、グリフィン（Ｇｒｉｆｆｉｎ）法に基づくＨＬＢが６．５〜１４．０のものが好ましい。 The component (b) preferably has a melting point of 40 ° C. or lower, more preferably 30 ° C. or lower, particularly preferably 25 ° C. in terms of removability of the human-derived tick attractant and human-derived tick attractant precursor. It is as follows. The melting point is measured using a Mettler FP81 (manufactured by Mettler Instrument AG) of an FP800 thermosystem at a heating rate of 0.2 ° C./min. For example, from the viewpoint of detergency, polyoxyalkylene alkyl ether, polyoxyalkylene alkylphenyl ether, polyoxyalkylene sorbitan fatty acid ester, polyoxyalkylene glycol fatty acid ester, and polyoxyethylene polyoxypropylene block polymer are preferable. In particular, polyoxyethylene alkyl ether obtained by adding 4 to 20 moles of ethylene oxide (hereinafter referred to as EO) on average to an alcohol having 10 to 18 carbon atoms, or 4 to 20 moles of EO on average, propylene oxide (hereinafter referred to as EO). , PO)) and an average of 0.3 to 4 moles added, and among them, those added in the order of EO, PO, and EO are preferable. The component (b) preferably has an HLB of 6.5 to 14.0 based on the Griffin method.
本発明の組成物において、（ａ）成分と（ｂ）成分の合計量は１５〜４０質量％であり、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、２０〜３５質量％が好ましく、２５〜３３質量％がより好ましい。 In the composition of the present invention, the total amount of the component (a) and the component (b) is 15 to 40% by mass, and in terms of removability of the human-derived mite attractant and the human-derived mite attractant precursor, 20-35 mass% is preferable and 25-33 mass% is more preferable.
本発明の組成物において、（ａ）成分と（ｂ）成分の質量比は、（ａ）／（ｂ）で１０／１〜１０／１２であり、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、１０／８〜１０／１．５が好ましく、１０／７〜１０／３がより好ましい。
＜（ｃ）成分＞
本発明の組成物は（ｃ）成分として蛋白分解酵素を０．００１〜２質量％含有する。人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、０．００５〜２質量％が好ましく、０．０１〜２質量％がより好ましい。（ｃ）成分は安定性等のために個別に造粒物で添加するのが好ましく、酵素原末は酵素造粒物中に０．５〜１５質量％含有されることが好ましい。
In the composition of the present invention, the mass ratio of the component (a) to the component (b) is 10/1 to 10/12 in (a) / (b). In terms of the removability of the attractant precursor, 10/8 to 10 / 1.5 is preferable, and 10/7 to 10/3 is more preferable.
<(C) component>
The composition of the present invention contains 0.001 to 2% by mass of a proteolytic enzyme as the component (c). In terms of removability of the human-derived tick attractant and the human-derived tick attractant precursor, 0.005 to 2% by mass is preferable, and 0.01 to 2% by mass is more preferable. The component (c) is preferably added individually as a granulated product for stability and the like, and the enzyme bulk powder is preferably contained in an amount of 0.5 to 15% by mass in the enzyme granulated product.
（ｃ）成分として、パパイン、ブロメライン、グラヂン、フィシン等の植物由来のプロテアーゼ、トリプシン、キモトリプシン、パンクレアチン等の動物由来のプロテアーゼ、バチルス属等の細菌が生産する細菌プロテアーゼ等の微生物由来のプロテアーゼ等の何れも使用することができる。
＜（ｄ）成分＞
本発明の組成物は（ｄ）成分として炭水化物及び／又は炭水化物誘導体を０．００１〜１０質量％含有する。人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、０．００５〜８質量％が好ましく、０．０１〜６質量％がより好ましい。
(C) As components, proteases derived from plants such as papain, bromelain, gradient, ficin, proteases derived from animals such as trypsin, chymotrypsin, pancreatin, proteases derived from microorganisms such as bacterial proteases produced by bacteria such as Bacillus, etc. Any of these can be used.
<(D) component>
The composition of the present invention contains 0.001 to 10% by mass of a carbohydrate and / or a carbohydrate derivative as the component (d). In terms of removability of the human-derived tick attractant and the human-derived tick attractant precursor, 0.005 to 8% by mass is preferable, and 0.01 to 6% by mass is more preferable.
（ｄ）成分として、グルコース、ガラクトース、フコース、キシロース、マルトース、ラクトース、フルクトース、β−シクロデキストリン、スクロース、トレハロース、ラフィノース、スタキオース、α−メチル−Ｄ−グルコシド、ソルビトール、マンニトール、マンノース、２−デスオキシ−Ｄ−リボース、Ｄ−グルコサミン、アセチルガラクトサミン、アセチルグルコサミン、等が挙げられる。人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、単糖〜六糖類が好ましく、単糖〜三糖類がより好ましく、二糖類が更に好ましい。 (D) As components, glucose, galactose, fucose, xylose, maltose, lactose, fructose, β-cyclodextrin, sucrose, trehalose, raffinose, stachyose, α-methyl-D-glucoside, sorbitol, mannitol, mannose, 2-desoxy -D-ribose, D-glucosamine, acetylgalactosamine, acetylglucosamine, etc. are mentioned. Monosaccharide to hexasaccharide are preferable, monosaccharide to trisaccharide are more preferable, and disaccharide is still more preferable in terms of removability of the human-derived mite attractant and human-derived mite attractant precursor.
本発明の組成物は、（ｃ）成分と（ｄ）成分の質量比は２／１以下であり、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、１／１以下が好ましく、１／２以下が更に好ましく、１／５以下が特に好ましい。
＜（ｅ）成分＞
本発明の組成物は（ｅ）成分として水溶性無機塩を２５〜５０質量％含有する。人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、２８〜４５質量％が好ましく、３０〜４０質量％がより好ましい。ここで、水溶性無機塩とは、蒸留水に対する溶解度が０．５ｇ／１５ｇ（２５℃、蒸留水）以上の無機塩をいうものとする。
In the composition of the present invention, the mass ratio of the component (c) and the component (d) is 2/1 or less, and in terms of removability of the human-derived mite attractant and the human-derived mite attractant precursor, / 1 or less is preferable, 1/2 or less is more preferable, and 1/5 or less is particularly preferable.
<(E) component>
The composition of this invention contains 25-50 mass% of water-soluble inorganic salts as (e) component. 28-45 mass% is preferable and 30-40 mass% is more preferable at the point of the removal property of a human-derived mite attractant and a human-derived mite attractant precursor. Here, the water-soluble inorganic salt refers to an inorganic salt having a solubility in distilled water of 0.5 g / 15 g (25 ° C., distilled water) or more.
（ｅ）成分として、塩化ナトリウム、塩化カリウム、硫酸ナトリウム、硫酸カリウム、亜硫酸ナトリウム、亜硫酸カリウム、亜硫酸水素ナトリウム、塩化アンモニウム、硫酸アンモニウム、炭酸ナトリウム、炭酸カリウム、炭酸水素ナトリウム、１号ケイ酸ナトリウム、２号ケイ酸ナトリウム、３号ケイ酸ナトリウム、四ホウ酸ナトリウム、ピロリン酸ナトリウム、トリポリリン酸ナトリウム、水酸化ナトリウム、水酸化カリウムなどの一種以上が挙げられる。この中でも亜硫酸ナトリウム、亜硫酸カリウム、炭酸ナトリウム、炭酸カリウム、炭酸水素ナトリウム、１号ケイ酸ナトリウム、２号ケイ酸ナトリウム、３号ケイ酸ナトリウム、四ホウ酸ナトリウム、ピロリン酸ナトリウム、トリポリリン酸ナトリウム、水酸化ナトリウム、水酸化カリウムなどの一種以上が人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で好ましい。このうち、無水物として０．５ｇを蒸留水１５ｇに溶解させた水溶液のｐＨ（２５℃、電極法）が１０以上を示す水溶性無機塩、すなわち、炭酸ナトリウム、炭酸カリウム、ピロリン酸ナトリウム、トリポリリン酸ナトリウム、１号ケイ酸ナトリウム、２号ケイ酸ナトリウム、３号ケイ酸ナトリウム、水酸化ナトリウム、水酸化カリウムが人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点でより好ましい。更に、ｐＨ８〜１２の範囲において単位質量当たりのアルカリ緩衝能に優れる化合物、即ち、その化合物の０．０２５質量％水溶液（蒸留水）のｐＨ値（２５℃、電極法）をＰｉとした場合、Ｐｉが９以上であり、かつその水溶液に０．１規定の塩酸を滴下し、水溶液のｐＨ値が（Ｐｉ−１）となるのに要した塩酸の滴下量が３ｍＬを上回る化合物が好ましく、そのような緩衝能を有する化合物としては、炭酸ナトリウム、炭酸カリウム、１号ケイ酸ナトリウム、ピロリン酸ナトリウム、トリポリリン酸ナトリウムから選ばれる一種以上が、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で更に好ましい。更に、炭酸ナトリウムが経済性の点から最も好ましい。 (E) As a component, sodium chloride, potassium chloride, sodium sulfate, potassium sulfate, sodium sulfite, potassium sulfite, sodium hydrogen sulfite, ammonium chloride, ammonium sulfate, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, No. 1 sodium silicate, 2 One or more of No. sodium silicate, No. 3 sodium silicate, sodium tetraborate, sodium pyrophosphate, sodium tripolyphosphate, sodium hydroxide, potassium hydroxide and the like can be mentioned. Among these, sodium sulfite, potassium sulfite, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, No. 1 sodium silicate, No. 2 sodium silicate, No. 3 sodium silicate, sodium tetraborate, sodium pyrophosphate, sodium tripolyphosphate, water One or more of sodium oxide, potassium hydroxide, and the like are preferable in terms of removability of a human-derived tick attractant and a human-derived tick attractant precursor. Among them, a water-soluble inorganic salt having an aqueous solution in which 0.5 g as an anhydride is dissolved in 15 g of distilled water has a pH (25 ° C., electrode method) of 10 or more, that is, sodium carbonate, potassium carbonate, sodium pyrophosphate, tripolylin Sodium silicate, No. 1 sodium silicate, No. 2 sodium silicate, No. 3 sodium silicate, Sodium hydroxide, Potassium hydroxide are human mite attractant and human mite attractant precursor in terms of removability More preferred. Furthermore, when the pH value (25 ° C., electrode method) of a compound having excellent alkali buffering capacity per unit mass in a pH range of 8 to 12, that is, a 0.025 mass% aqueous solution (distilled water) of the compound is Pi, A compound in which Pi is 9 or more and 0.1 N hydrochloric acid is dropped into the aqueous solution, and the dropping amount of hydrochloric acid required for the pH value of the aqueous solution to be (Pi-1) is more than 3 mL is preferable. As the compound having such a buffering capacity, one or more selected from sodium carbonate, potassium carbonate, No. 1 sodium silicate, sodium pyrophosphate, and sodium tripolyphosphate are human mite attractant and human mite attractant precursor. More preferable in terms of body removability. Further, sodium carbonate is most preferable from the viewpoint of economy.
本発明の組成物において、（ａ）成分と（ｂ）成分と（ｅ）成分の合計量は５０〜８０質量％であり、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、５５〜７５質量％が好ましく、６０〜７０質量％がより好ましい。 In the composition of the present invention, the total amount of the component (a), the component (b), and the component (e) is 50 to 80% by mass, and removal of a human-derived tick attractant and a human-derived tick attractant precursor From the viewpoint of properties, 55 to 75 mass% is preferable, and 60 to 70 mass% is more preferable.
本発明の組成物において、（ａ）成分と（ｂ）成分の合計量と、（ｅ）成分の質量比は〔（ａ）＋（ｂ）〕／（ｅ）で４／３〜１／３であり、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、４／３．５〜１／２．５が好ましく、１／１〜１／２がより好ましい。
＜（ｆ）成分＞
本発明の組成物は（ｆ）成分としてホウ酸及び／又はホウ酸塩を含有することが、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で好ましく、含有量は０．０１〜１０質量％がより好ましく、０．０５〜５質量％が更に好ましい。
In the composition of the present invention, the total amount of the component (a) and the component (b) and the mass ratio of the component (e) are 4/3 to 1/3 as [(a) + (b)] / (e). 4 / 3.5 to 1 / 2.5 is preferable, and 1/1 to 1/2 is more preferable in terms of removability of the human-derived tick attractant and the human-derived tick attractant precursor.
<Component (f)>
It is preferable that the composition of the present invention contains boric acid and / or borate as the component (f) in terms of removability of the human-derived tick attracting substance and the human-derived tick attracting substance precursor. Is more preferably 0.01 to 10% by mass, and still more preferably 0.05 to 5% by mass.
人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、（ｃ）成分と（ｆ）成分の質量比は、（ｃ）／（ｆ）で１／１以下が好ましく、１／２以下がより好ましく、１／５以下が更に好ましく、１／１０以下が特に好ましい。
＜（ｇ）成分＞
本発明の組成物は（ｇ）成分として、セドレン、セドロール、ツヨプセン、セドリルアセテート、セドリルフォルメート、セドリルメチルエーテル、アセチルセドレン、β−カリオフィレン、α，β−サンタロール、２−メチル−４−（２，２，３−トリメチル−３−シクロペンテン−１−イル）−２−ブテン−１−オール、ベチベロール、ベチベリルアセテート、パチョリアルコール、セダーウッドオイル、セダーリーフオイル、ヒノキオイル、ヒバオイル、コパイババルサムオイル、サンダルウッドオイル、ベチバーオイル、パチョリオイル、４−（４−ヒドロキシ−４−メチルペンチル）−３−シクロヘキセン−１−カルボキシアルデヒド、ｉｓｏ−ボロニルシクロヘキサノール、ｉｓｏ−カンフィルシクロヘキサノール、ｉｓｏ−フェンシルシクロヘキサノール、フェニルアセトアルデヒドグリセリルアセタール、α−メチル−３，４−メチレンジオキシヒドロシンナミックアルデヒド、α−メチル−３，４−メチレンジオキシヒドロシンナミックアルデヒドのシッフ塩基、２−メチル−３−（ｐ−メトキシフェニル）プロパナール、エチルシンナメート、メチルシンナメート、シンナミルアセテート、シンナミックアルコール、ヘキシルシンナミックアルデヒド、α−アミルシンナミックアルデヒド、エチルオイゲノール、メチルオイゲノール、ｐ−ｔ−ブチル−α−メチルヒドロシンナミックアルデヒド、ｃｉｓ−３−ヘキセニルサリチレート、β−ナフトールエチルエーテル、β−ナフトールメチルエーテル、ジャスモン、ジヒドロジャスモン、ジャスモン酸低級アルキルエステル、ジヒドロジャスモン酸低級アルキルエステル、ファルネソール、ネロリドール、フィトール、イソフィトール、ゲラニルゲラニオール、ゲラニルリナロールから選ばれる１種以上を含有する香料を含有することがダニ再付着防止の点で好ましい。
＜その他成分＞
本発明の組成物には、衣料用洗剤の分野で公知のビルダー、漂白剤（過炭酸塩、過ホウ酸塩、漂白活性化剤等）、再汚染防止剤（カルボキシメチルセルロース等）、柔軟化剤、還元剤（亜硫酸塩等）、蛍光増白剤、抑泡剤（シリコーン等）、香料、両性界面活性剤、陽イオン性界面活性剤、その他の酵素（セルラーゼ、ペクチナーゼ、アミラーゼ、リパーゼ（好ましくは添加しない）等）等の添加剤を含有させることができる。
In terms of removability of the human-derived mite attractant and human-derived mite attractant, the mass ratio of the component (c) to the component (f) is preferably 1/1 or less in terms of (c) / (f). 1/2 or less, more preferably 1/5 or less, and particularly preferably 1/10 or less.
<(G) component>
The composition of the present invention comprises, as component (g), cedrene, cedrol, tyuopsen, cedryl acetate, cedryl formate, cedryl methyl ether, acetyl cedrene, β-caryophyllene, α, β-santalol, 2-methyl. -4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol, vetiverol, vetiberyl acetate, patchouli alcohol, cedarwood oil, cedar leaf oil, hinoki oil, hiba oil , Copaiba balsam oil, sandalwood oil, vetiver oil, patchouli oil, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, iso-boronylcyclohexanol, iso-camphylcyclohexanol , Iso-fe Silcyclohexanol, phenylacetaldehyde glyceryl acetal, α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde, α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde Schiff base, 2-methyl-3- (P-methoxyphenyl) propanal, ethyl cinnamate, methyl cinnamate, cinnamyl acetate, cinnamic alcohol, hexyl cinnamic aldehyde, α-amyl cinnamic aldehyde, ethyl eugenol, methyl eugenol, pt-butyl-α -Methylhydrocinnamic aldehyde, cis-3-hexenyl salicylate, β-naphthol ethyl ether, β-naphthol methyl ether, jasmon, dihydrojasmon, lower alkyl jasmonate Ester, dihydrojasmonate lower alkyl esters, farnesol, nerolidol, phytol, isophytol, geranylgeraniol, it is preferred in terms of mite antiredeposition containing perfume containing one or more selected from geranyl linalool.
<Other ingredients>
The composition of the present invention includes a builder, a bleaching agent (percarbonate, perborate, bleach activator, etc.), a recontamination inhibitor (carboxymethylcellulose, etc.), a softening agent known in the field of garment detergents. , Reducing agents (sulfites, etc.), fluorescent brighteners, foam inhibitors (silicones, etc.), fragrances, amphoteric surfactants, cationic surfactants, other enzymes (cellulase, pectinase, amylase, lipase (preferably Additives such as not added) etc. can be contained.
洗浄性能の点で、更に（ｈ）水溶性ポリマーを０．５〜２０質量％含有することが好ましく、１〜１５質量％がより好ましく、３〜１０質量％が更に好ましい。 In terms of cleaning performance, it is preferable that (h) the water-soluble polymer is further contained in an amount of 0.5 to 20% by mass, more preferably 1 to 15% by mass, and further preferably 3 to 10% by mass.
（ｈ）水溶性ポリマーとしては、２５℃の水１００ｇに対する溶解度が０．５ｇ以上且つ分子量１千以上の有機性重合体であり、例えばポリアルキレングリコール、カルボン酸系ポリマー、カルボキシメチルセルロース、可溶性澱粉、糖類等が挙げられる。中でも金属イオン封鎖能、固体汚れ・粒子汚れの分散能及び再汚染防止能の点で分子量が数千〜１０万のカルボン酸系ポリマー及びポリエチレングリコールが好ましい。特に、アクリル酸−マレイン酸コポリマーの塩、ポリアクリル酸塩及びポリエチレングリコールが好ましい。ここで、塩としてはナトリウム塩、カリウム塩、アンモニウム塩が挙げられる。 (H) The water-soluble polymer is an organic polymer having a solubility in 100 g of water at 25 ° C. of 0.5 g or more and a molecular weight of 1,000 or more, such as polyalkylene glycol, carboxylic acid polymer, carboxymethyl cellulose, soluble starch, Examples include saccharides. Of these, carboxylic acid polymers having a molecular weight of several thousand to 100,000 and polyethylene glycol are preferable in terms of sequestering ability, dispersibility of solid dirt / particle dirt, and ability to prevent recontamination. Particularly preferred are salts of acrylic acid-maleic acid copolymers, polyacrylates and polyethylene glycols. Here, examples of the salt include sodium salt, potassium salt, and ammonium salt.
本発明の組成物は、流動性及び非ケーキング性の点で、表面被覆剤により表面改質を行うことが好ましい。表面被覆剤は組成物中１〜３０質量％が好ましく、２〜２５質量％がより好ましく、５〜２５質量％が更に好ましい。表面被覆剤としては、例えば、アルミノケイ酸塩、ケイ酸カルシウム、二酸化ケイ素、ベントナイト、タルク、クレイ、非晶質シリカ誘導体、結晶性シリケート化合物等のシリケート化合物、金属石鹸、粉末の界面活性剤等の微粉体、カルボキシメチルセルロース、ポリエチレングリコール、ポリアクリル酸ソーダ、アクリル酸とマレイン酸のコポリマー又はその塩等のポリカルボン酸塩等の水溶性ポリマー；脂肪酸が挙げられる。中でもシリケート化合物が好ましく、特に結晶性アルミノケイ酸塩、非晶質アルミノケイ酸塩、結晶性シリケート化合物が好ましい。 The composition of the present invention is preferably surface-modified with a surface coating agent in terms of fluidity and non-caking property. 1-30 mass% is preferable in a composition in a surface coating agent, 2-25 mass% is more preferable, and 5-25 mass% is still more preferable. Examples of the surface coating agent include aluminosilicates, calcium silicates, silicon dioxide, bentonite, talc, clay, amorphous silica derivatives, crystalline silicate compounds such as silicate compounds, metal soaps, powder surfactants, etc. Water-soluble polymers such as fine powders, carboxymethylcellulose, polyethylene glycol, sodium polyacrylate, polycarboxylic acid salts such as copolymers of acrylic acid and maleic acid or salts thereof; and fatty acids. Of these, silicate compounds are preferred, and crystalline aluminosilicates, amorphous aluminosilicates, and crystalline silicate compounds are particularly preferred.
本発明の洗浄剤組成物は、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、ＪＩＳ Ｋ ３３６２：１９９８による２５℃、０．１質量％水溶液のｐＨが７〜１２であることが好ましく、８〜１２がより好ましく、１０〜１１が更に好ましい。 The cleaning composition of the present invention has a pH of a 0.1% by mass aqueous solution of 25 ° C. according to JIS K 3362: 1998 in terms of removability of human-derived mite attractant and human-derived mite attractant. It is preferable that it is -12, 8-12 are more preferable, and 10-11 are still more preferable.
本発明の洗浄剤組成物は、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去性の点で、水中で過酸化水素を放出する化合物及び水中で過酸化水素と反応し有機過酸を発生する化合物を含有することが好ましい。洗浄性能、洗浄効率の点で水中で過酸化水素を放出する化合物は０．１〜８質量％が好ましく、０．５〜５質量％がより好ましく、１〜３．５質量％が更に好ましく、１．５〜２．８質量％が更に好ましく、水中で過酸化水素と反応し有機過酸を発生する化合物は０．１〜５質量％が好ましく、０．５〜３質量％がより好ましく、０．８〜２質量％が更に好ましい。水中で過酸化水素を放出する化合物としては、炭酸塩・過酸化水素付加物、硼酸塩・過酸化水素付加物、トリポリリン酸塩・過酸化水素付加物、ピロリン酸塩・過酸化水素付加物、尿素・過酸化水素付加物等が挙げられる。この中でも、炭酸塩・過酸化水素付加物、硼酸塩・過酸化水素付加物が好ましく、炭酸ナトリウム・過酸化水素付加物、硼酸ナトリウム・過酸化水素付加物がより好ましく、洗浄性能の点で炭酸ナトリウム・過酸化水素付加物が更に好ましい。水中で過酸化水素と反応し有機過酸を発生する化合物としては、酸素系漂白剤含有洗剤に一般的に用いられる、グルコースペンタアセテート、トリアセチン、Ｎ，Ｎ，Ｎ’，Ｎ’−テトラアセチルエチレンジアミン、テトラアセチルグリコリルウリル等の漂白活性化剤を使用することができるが、効果の点で、下記一般式（１）〜（４）で表される化合物の一種以上が好ましく、（１）又は（２）で表される化合物の一種以上がより好ましい。 The cleaning composition of the present invention is a compound that releases hydrogen peroxide in water and an organic compound that reacts with hydrogen peroxide in water in terms of removability of a human-derived tick attractant and a human-derived tick attractant precursor. It is preferable to contain a compound that generates a peracid. The compound that releases hydrogen peroxide in water in terms of washing performance and washing efficiency is preferably 0.1 to 8% by mass, more preferably 0.5 to 5% by mass, still more preferably 1 to 3.5% by mass, The compound that reacts with hydrogen peroxide in water to generate an organic peracid is preferably 0.1 to 5% by mass, more preferably 0.5 to 3% by mass, 0.8-2 mass% is still more preferable. Compounds that release hydrogen peroxide in water include carbonate / hydrogen peroxide adduct, borate / hydrogen peroxide adduct, tripolyphosphate / hydrogen peroxide adduct, pyrophosphate / hydrogen peroxide adduct, Examples include urea / hydrogen peroxide adducts. Of these, carbonate / hydrogen peroxide adduct and borate / hydrogen peroxide adduct are preferable, sodium carbonate / hydrogen peroxide adduct and sodium borate / hydrogen peroxide adduct are more preferable. Sodium / hydrogen peroxide adduct is more preferred. Compounds that react with hydrogen peroxide in water to generate organic peracids include glucose pentaacetate, triacetin, N, N, N ′, N′-tetraacetylethylenediamine, which are commonly used in oxygen-based bleach-containing detergents. Bleach activators such as tetraacetylglycolyluril can be used, but in terms of effects, one or more compounds represented by the following general formulas (1) to (4) are preferable, (1) or One or more of the compounds represented by (2) are more preferred.
〔式中、Ｒ1は炭素数４〜１３、好ましくは１０〜１３のアルキル基、Ｒ2は炭素数５〜１３、好ましくは７〜１１のアルキル基、Ｍは水素原子又はアルカリ金属、アルカリ土類金属、アンモニウム若しくはアルカノールアミンを示す。〕 [Wherein, R 1 is an alkyl group having 4 to 13 carbon atoms, preferably 10 to 13 carbon atoms, R 2 is an alkyl group having 5 to 13 carbon atoms, preferably 7 to 11 carbon atoms, M is a hydrogen atom or an alkali metal, alkaline earth It represents a similar metal, ammonium or alkanolamine. ]
〔式中、Ｒ3、Ｒ4、Ｒ5、Ｒ6、Ｒ7、Ｒ9、Ｒ10はそれぞれ独立してメチル基、エチル基又はヒドロキシエチル基であり、Ｒ8は炭素数２〜１０のアルキレン基であり、Ｘ-は陰イオン、好ましくはハロゲンイオン、炭素数１〜３のアルキル硫酸イオン、炭素数１〜１２の脂肪酸イオン、リン酸イオン、硫酸イオンを示す。〕
本発明の組成物を用いて通常の洗濯を行うことで、処理後の繊維製品においてダニ誘引が緩和されるので、本発明の組成物は、ダニ誘引緩和用洗浄剤組成物として用いることもできる。本発明の組成物を用いて、衣類や寝具などの繊維製品を処理（洗濯等）することで、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去方法が提供される。
[Wherein, R 3 , R 4 , R 5 , R 6 , R 7 , R 9 , R 10 are each independently a methyl group, an ethyl group or a hydroxyethyl group, and R 8 has 2 to 10 carbon atoms. An alkylene group, and X − represents an anion, preferably a halogen ion, an alkyl sulfate ion having 1 to 3 carbon atoms, a fatty acid ion having 1 to 12 carbon atoms, a phosphate ion, or a sulfate ion. ]
By performing normal washing using the composition of the present invention, tick attraction is alleviated in the treated textile, so the composition of the present invention can also be used as a cleaning composition for mite attraction mitigation. . By treating (washing etc.) textile products such as clothes and bedding using the composition of the present invention, a method for removing a human-derived tick attractant and a human-derived tick attractant precursor is provided.
実施例１〜５、比較例１〜９
表１、２に示す成分のうち、（ａ）成分、（ｄ）成分、（ｅ）成分、（ｆ）成分、（ｈ）成分、ゼオライトの一部、蛍光染料を用いて、固形分４０質量％の水性スラリーを調製し、これを乾燥塔を用いてスプレー乾燥し、水分量３質量％の乾燥生地を得た。これを（ｂ）成分、結晶性シリケート、ゼオライトの一部、及び水分調整用の水と共に攪拌造粒し、ゼオライトの一部で表面被覆し、平均粒径４７０μｍ、見掛け密度８４０ｇ／Ｌの粒子を得た。更に得られた造粒物と（ｃ）成分、及び必要に応じて（ｇ）成分、過炭酸ナトリウム、ＬＯＢＳ、ＤＯＢＡを混合して、平均粒径４８０〜５２０μｍ、見掛け密度８２０ｇ／Ｌの洗浄剤組成物を得た。
Examples 1-5, Comparative Examples 1-9
Among the components shown in Tables 1 and 2, (a) component, (d) component, (e) component, (f) component, (h) component, a part of zeolite, a fluorescent dye, solid content 40 mass % Aqueous slurry was prepared and spray-dried using a drying tower to obtain a dry dough with a moisture content of 3 mass%. This is stirred and granulated with the component (b), a crystalline silicate, a part of zeolite, and water for adjusting moisture, and the surface is coated with a part of the zeolite to obtain particles having an average particle diameter of 470 μm and an apparent density of 840 g / L. Obtained. Further, the resulting granulated product, the component (c), and the component (g), sodium percarbonate, LOBS, and DOBA, if necessary, are mixed to obtain a detergent having an average particle size of 480 to 520 μm and an apparent density of 820 g / L. A composition was obtained.
表１、２に示す成分は以下のものを使用した。
・ＬＡＳ−Ｎａ：アルキル基の炭素数１２〜１４の直鎖アルキルベンゼンスルホン酸ナトリウム
・ＡＳ−Ｎａ：アルキル基の炭素数１２〜１６のアルキル硫酸エステルナトリウム
・ＡＯＳ−Ｎａ：アルキル基の炭素数１４〜１８のα−オレフィンスルホン酸ナトリウム
・α−ＳＦ：アルキル基の炭素数が１２〜１４のα−スルホ脂肪酸メチルエステルナトリウム
・石鹸：アルキル基の炭素数１４〜１８の脂肪酸ナトリウム
・ＡＥ１：アルキル基の炭素数が１２〜１４でＥＯ平均付加モル数が７であるポリオキシエチレンアルキルエーテル
・ＡＥ２：アルキル基の炭素数が１２〜１４でＥＯ平均付加モル数が１３であるポリオキシエチレンアルキルエーテル
・酵素：セルラーゼＫ（特開昭６３−２６４６９９号公報記載）、カンナーゼ２４ＴＫ（ノボ社製）、サビナーゼ６．０Ｔ（ノボ社製）を３：１：２の質量比で使用
・香料１：セドロール含有香料
・香料２：ツヨプセン含有香料
・ＡＡ／ＭＡコポリマー：アクリル酸マレイン酸コポリマー、ソカランＣＰ−５（ＢＡＳＦ製）
・ＣＭＣ：カルボキシメチルセルロース
・結晶性シリケート：プリフィード（トクヤマシルテック（株）製）
・過炭酸ナトリウム：炭酸ナトリウム過酸化水素付加物（特開２０００−２５６６９９号公報の段落００１９に記載の漂白剤粒子）
・ＬＯＢＳ：ラウロイルオキシベンゼンスルホン酸ナトリウム造粒物（特開２０００−２５６６９９号公報の段落００１８記載の漂白剤粒子）
・ＤＯＢＡ：デカノイルオキシ安息香酸ナトリウム造粒物（ＬＯＢＳと同様にして製造した。）
・蛍光染料：チノパールＣＢＳ−Ｘ（チバスペシャリティーケミカルス製）
ダニ誘引抑制効果は以下のようにして評価を行った。
１．供試ダニ
ヤケヒョウヒダニ（Dermatophagoides pteronyssinus)
２．試験方法
（２−１）
２２ｃｍ×１１ｃｍのガラス製皿の長手方向の一端に未洗浄の新品枕カバーを４ｃｍ角に裁断したものを２枚重ねて置き、他端に４ｃｍ角に裁断したろ紙を２枚重ねて置き、中心部に供試ダニ５００〜６００匹を置いた。これを飽和食塩水で相対湿度８５％以上に調整したプラスチック製密閉容器の中に置き、全暗状態で２５℃で保存した。２４時間後に枕カバー又はろ紙の表裏両面及び下の供試ダニの合計数を数えたところ、新品枕カバー及びろ紙に付着したダニ数は、それぞれ２６匹と２９匹であり、有意な差は認められず、枕カバー自体にはダニ誘引作用がないことを確認した。
（２−２）
中古枕カバーにダニ誘引物質が付着していることの確認を行うために、未洗浄の中古枕カバー〔（２−１）で用いたものを使用したもの〕とろ紙〔（２−１）で用いたものと同じもの〕を用いて上記（２−１）と同様の試験を行ったところ、中古枕カバーに付着したダニ数は４０３匹、ろ紙に付着したダニ数は３６匹であり、中古枕カバーにダニ誘引物質が付着していることを確認した。
（２−３）
ダニ誘引物質が付着していることを確認した中古枕カバーを４ｃｍ角に裁断したもの２枚を、表１に示す粉末の洗浄剤組成物を０．０８３３質量％、２０℃、１Ｌとなるように溶解した洗浄液を用いて、ターゴトメーターにて普通洗浄した（８０ｒｐｍ×１０分）。その後、水道水ですすぎ、乾燥させ、ダニ誘引試験のサンプルとした。このサンプルとろ紙〔（２−１）で用いたものと同じもの〕とを用いて上記（２−１）と同様の試験を行い、それぞれに付着したダニの合計数を数えた。結果を表１、２に示す。
The components shown in Tables 1 and 2 were as follows.
LAS-Na: linear alkylbenzene sulfonate sodium having 12 to 14 carbon atoms in the alkyl group AS-Na: sodium alkyl sulfate ester having 12 to 16 carbon atoms in the alkyl group AOS-Na: 14 to 14 carbon atoms in the alkyl group 18 sodium α-olefin sulfonate, α-SF: sodium α-sulfo fatty acid methyl ester having 12 to 14 carbon atoms in the alkyl group, soap: sodium fatty acid having 14 to 18 carbon atoms in the alkyl group, AE1: alkyl group Polyoxyethylene alkyl ether / enzyme having 12 to 14 carbon atoms and EO average addition mole number 7 AE2: Polyoxyethylene alkyl ether / enzyme having 12 to 14 carbon atoms in the alkyl group and 13 EO average addition mole number : Cellulase K (described in JP-A 63-264699), Cannase 24TK ( Bob), sabinase 6.0T (Novo) manufactured at a mass ratio of 3: 1: 2; Fragrance 1: Cedrol-containing fragrance; Fragrance 2: Thuopsen-containing fragrance; AA / MA copolymer: acrylic acid maleic acid copolymer , Socaran CP-5 (manufactured by BASF)
・ CMC: Carboxymethylcellulose ・ Crystalline silicate: Prefeed (manufactured by Tokuyama Siltech Co., Ltd.)
Sodium percarbonate: Sodium carbonate hydrogen peroxide adduct (bleaching agent particles described in paragraph 0019 of JP-A No. 2000-256699)
LOBS: sodium lauroyloxybenzenesulfonate granulated product (bleaching agent particles described in paragraph 0018 of JP-A No. 2000-256699)
DOBA: Sodium decanoyloxybenzoate granulated product (produced in the same manner as LOBS)
・ Fluorescent dye: Chino Pearl CBS-X (manufactured by Ciba Specialty Chemicals)
The tick attracting inhibitory effect was evaluated as follows.
1. Test mite Dermatophagoides pteronyssinus
2. Test method (2-1)
Place two unwashed new pillow covers cut into 4 cm squares on one end in the longitudinal direction of a 22 cm x 11 cm glass dish, and put two filter papers cut into 4 cm squares on the other end. 500 to 600 test mites were placed in the section. This was placed in a plastic sealed container adjusted to a relative humidity of 85% or higher with saturated saline and stored at 25 ° C. in a completely dark state. After 24 hours, the total number of mites on both the front and back sides of the pillow cover or filter paper and the lower test mites was counted, and the number of ticks adhering to the new pillow cover and filter paper was 26 and 29, respectively. It was confirmed that the pillow cover itself has no tick-inducing action.
(2-2)
In order to confirm that tick attracting substances are attached to the used pillow cover, unwashed used pillow cover [used in (2-1)] and filter paper [(2-1) Using the same test as in (2-1) above, the number of ticks adhering to the used pillow cover was 403 and the number of ticks adhering to the filter paper was 36. It was confirmed that a tick attracting substance adhered to the pillow cover.
(2-3)
Two pieces of used pillow covers that have been confirmed to have a tick attracting substance cut into 4 cm squares have a powder detergent composition shown in Table 1 at 0.0833 mass%, 20 ° C., and 1 L. Using the washing solution dissolved in the solution, it was usually washed with a targotometer (80 rpm × 10 minutes). Thereafter, it was rinsed with tap water, dried, and used as a sample for a tick attraction test. Using this sample and filter paper [same as that used in (2-1)], the same test as in (2-1) was performed, and the total number of mites adhering to each was counted. The results are shown in Tables 1 and 2.
Claims (5)
（ｂ）非イオン界面活性剤２〜１５質量％、
（ｃ）蛋白質分解酵素０．００１〜２質量％、
（ｄ）炭水化物及び／又は炭水化物誘導体０．００１〜１０質量％、
（ｅ）水溶性無機塩２５〜５０質量％、
を含有し、
（ａ）と（ｂ）の質量比が（ａ）／（ｂ）で１０／１〜１０／１２、
（ａ）と（ｂ）の合計量が１５〜４０質量％、
（ｃ）と（ｄ）の質量比が（ｃ）／（ｄ）で２／１以下、
（ａ）と（ｂ）の合計量と（ｅ）成分の質量比が〔（ａ）＋（ｂ）〕／（ｅ）で４／３〜１／３、
（ａ）、（ｂ）、（ｅ）の合計量が５０〜８０質量％、
組成物のカルシウム捕捉量３０〜２００ＣａＣＯ3ｍｇ／ｇ
である、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の洗浄剤組成物。 (A) 10-30% by mass of an anionic surfactant,
(B) 2 to 15% by mass of a nonionic surfactant,
(C) 0.001 to 2% by mass of proteolytic enzyme,
(D) 0.001-10% by weight of carbohydrates and / or carbohydrate derivatives,
(E) 25-50 mass% of water-soluble inorganic salt,
Containing
The mass ratio of (a) and (b) is 10/1 to 10/12 in (a) / (b),
The total amount of (a) and (b) is 15-40% by mass,
The mass ratio of (c) and (d) is 2/1 or less in terms of (c) / (d),
The mass ratio of the total amount of (a) and (b) and the component (e) is [(a) + (b)] / (e) 4/3 to 1/3,
The total amount of (a), (b), (e) is 50-80% by mass,
Calcium trapping amount of the composition 30 to 200 CaCO 3 mg / g
A cleaning composition for a human-derived tick attractant and a human-derived tick attractant precursor.
（ｂ）非イオン界面活性剤２〜１５質量％、
（ｃ）蛋白質分解酵素０．００１〜２質量％、
（ｄ）炭水化物及び／又は炭水化物誘導体０．００１〜１０質量％、
（ｅ）水溶性無機塩２５〜５０質量％、
を含有し、
（ａ）と（ｂ）の質量比が（ａ）／（ｂ）で１０／１〜１０／１２、
（ａ）と（ｂ）の合計量が１５〜４０質量％、
（ｃ）と（ｄ）の質量比が（ｃ）／（ｄ）で２／１以下、
（ａ）と（ｂ）成分の合計量と（ｅ）成分の質量比が〔（ａ）＋（ｂ）〕／（ｅ）で４／３〜１／３、
（ａ）、（ｂ）、（ｅ）の合計量が５０〜８０質量％、
組成物のカルシウム捕捉量３０〜２００ＣａＣＯ3ｍｇ／ｇ
であるダニ誘引緩和用洗浄剤組成物。 (A) 10-30% by mass of an anionic surfactant,
(B) 2 to 15% by mass of a nonionic surfactant,
(C) 0.001 to 2% by mass of proteolytic enzyme,
(D) 0.001-10% by weight of carbohydrates and / or carbohydrate derivatives,
(E) 25-50 mass% of water-soluble inorganic salt,
Containing
The mass ratio of (a) and (b) is 10/1 to 10/12 in (a) / (b),
The total amount of (a) and (b) is 15-40% by mass,
The mass ratio of (c) and (d) is 2/1 or less in terms of (c) / (d),
The total amount of the components (a) and (b) and the mass ratio of the component (e) are [(a) + (b)] / (e) 4/3 to 1/3,
The total amount of (a), (b), (e) is 50-80% by mass,
Calcium trapping amount of the composition 30 to 200 CaCO 3 mg / g
A cleaning composition for mitigation of mite attraction.
（ｂ）非イオン界面活性剤２〜１５質量％、
（ｃ）蛋白質分解酵素０．００１〜２質量％、
（ｄ）炭水化物及び／又は炭水化物誘導体０．００１〜１０質量％、
（ｅ）水溶性無機塩２５〜５０質量％、
を含有し、
（ａ）と（ｂ）の質量比が（ａ）／（ｂ）で１０／１〜１０／１２、
（ａ）と（ｂ）の合計量が１５〜４０質量％、
（ｃ）と（ｄ）の質量比が（ｃ）／（ｄ）で２／１以下、
（ａ）と（ｂ）成分の合計量と（ｅ）成分の質量比が〔（ａ）＋（ｂ）〕／（ｅ）で４／３〜１／３、
（ａ）、（ｂ）、（ｅ）の合計量が５０〜８０質量％、
組成物のカルシウム捕捉量３０〜２００ＣａＣＯ3ｍｇ／ｇ
である洗浄剤組成物による、人由来のダニ誘引物質及び人由来のダニ誘引物質前駆体の除去方法。 (A) 10-30% by mass of an anionic surfactant,
(B) 2 to 15% by mass of a nonionic surfactant,
(C) 0.001 to 2% by mass of proteolytic enzyme,
(D) 0.001-10% by weight of carbohydrates and / or carbohydrate derivatives,
(E) 25-50 mass% of water-soluble inorganic salt,
Containing
The mass ratio of (a) and (b) is 10/1 to 10/12 in (a) / (b),
The total amount of (a) and (b) is 15-40% by mass,
The mass ratio of (c) and (d) is 2/1 or less in terms of (c) / (d),
The total amount of the components (a) and (b) and the mass ratio of the component (e) are [(a) + (b)] / (e) 4/3 to 1/3,
The total amount of (a), (b), (e) is 50-80% by mass,
Calcium trapping amount of the composition 30 to 200 CaCO 3 mg / g
A method for removing a human-derived tick-inducing substance and a human-derived tick-inducing substance precursor using the cleaning composition.
Priority Applications (1)
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|---|---|---|---|
| JP2003288367A JP4246011B2 (en) | 2003-08-07 | 2003-08-07 | Cleaning composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003288367A JP4246011B2 (en) | 2003-08-07 | 2003-08-07 | Cleaning composition |
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| Publication Number | Publication Date |
|---|---|
| JP2005054124A true JP2005054124A (en) | 2005-03-03 |
| JP4246011B2 JP4246011B2 (en) | 2009-04-02 |
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Cited By (9)
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| JP2008101165A (en) * | 2006-10-20 | 2008-05-01 | Kao Corp | Odor-suppressing detergent composition |
| DE102009034461A1 (en) * | 2009-07-22 | 2011-02-03 | Azur Fragrances S.A.R.L. | Textile treatment agent e.g. softening agent, useful for cleaning, maintaining, dyeing and/or strengthening of fibers or yarns and/or textile end products, comprises additives that are herbal extracts such as bamboo and/or Calendula |
| JP2012100639A (en) * | 2010-11-09 | 2012-05-31 | Kai:Kk | Method of washing, application and antibacterial treatment using enzyme treatment solution |
| JP2013176313A (en) * | 2012-02-28 | 2013-09-09 | Kao Corp | Insect attractant |
| JP2013234206A (en) * | 2013-08-29 | 2013-11-21 | Earth Chemical Co Ltd | House dust acarid repellent |
| KR20160059120A (en) * | 2014-11-18 | 2016-05-26 | 윤정호 | Stain remover for protable and manufacture method |
| JPWO2015012235A1 (en) * | 2013-07-22 | 2017-03-02 | ライオン株式会社 | Granular detergent composition and method for producing the same |
| CN111440674A (en) * | 2020-05-13 | 2020-07-24 | 杭州炫墨生物科技有限公司 | Liquid detergent with mite removing effect |
| KR102214171B1 (en) * | 2020-09-07 | 2021-02-10 | 주식회사 서일 | Non-flammable and biodegradable eco-friendly liquid detergent composition |
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| DE102009034461A1 (en) * | 2009-07-22 | 2011-02-03 | Azur Fragrances S.A.R.L. | Textile treatment agent e.g. softening agent, useful for cleaning, maintaining, dyeing and/or strengthening of fibers or yarns and/or textile end products, comprises additives that are herbal extracts such as bamboo and/or Calendula |
| JP2012100639A (en) * | 2010-11-09 | 2012-05-31 | Kai:Kk | Method of washing, application and antibacterial treatment using enzyme treatment solution |
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| JPWO2015012235A1 (en) * | 2013-07-22 | 2017-03-02 | ライオン株式会社 | Granular detergent composition and method for producing the same |
| JP2013234206A (en) * | 2013-08-29 | 2013-11-21 | Earth Chemical Co Ltd | House dust acarid repellent |
| KR20160059120A (en) * | 2014-11-18 | 2016-05-26 | 윤정호 | Stain remover for protable and manufacture method |
| KR101647204B1 (en) | 2014-11-18 | 2016-08-09 | 윤정호 | Stain remover for protable and manufacture method |
| CN111440674A (en) * | 2020-05-13 | 2020-07-24 | 杭州炫墨生物科技有限公司 | Liquid detergent with mite removing effect |
| KR102214171B1 (en) * | 2020-09-07 | 2021-02-10 | 주식회사 서일 | Non-flammable and biodegradable eco-friendly liquid detergent composition |
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