ES2891361A1 - LIQUID POTASSIUM SOAP AND PRODUCTION PROCEDURE (Machine-translation by Google Translate, not legally binding) - Google Patents

LIQUID POTASSIUM SOAP AND PRODUCTION PROCEDURE (Machine-translation by Google Translate, not legally binding) Download PDF

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Publication number
ES2891361A1
ES2891361A1 ES202030730A ES202030730A ES2891361A1 ES 2891361 A1 ES2891361 A1 ES 2891361A1 ES 202030730 A ES202030730 A ES 202030730A ES 202030730 A ES202030730 A ES 202030730A ES 2891361 A1 ES2891361 A1 ES 2891361A1
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Prior art keywords
mixture
potassium soap
liquid potassium
koh
glycol
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ES202030730A
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Spanish (es)
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Mestre Jaime Nacher
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Beltran Hermanos SL
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Beltran Hermanos SL
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Priority to ES202030730A priority Critical patent/ES2891361A1/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D13/00Making of soap or soap solutions in general; Apparatus therefor
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

Liquid potassium soap and production process comprising, in its composition: avocado/olive oleins, 8.5%, high oleic sunflower oil, 35.7%, KOH 50% in water, 16.57%, K2CO3], 0.43%, ethyldiglycol, 8.5%, ethanol denatured with natural linalool, 22.8%, C8-C10 non-ionic surfactant, 5.25%, non- ionic C5, 2.25%, and whose production steps include: mix the fat together with the glycol and heat to a minimum of 40-50ºC; prepare the KOH + K{sub,2]CO{sub,3 solution slowly add the above alkali solution to the hot fat/glycol mixture; increase the temperature without reaching more than 80ºC; before the mixture begins to thicken abruptly, add the ethanol slowly to decrease the viscosity; add the surfactants when the mixture cools below 50-60°C. (Machine-translation by Google Translate, not legally binding)

Description

DESCRIPCIÓNDESCRIPTION

JABÓN POTÁSICO LÍQUIDO Y PROCEDIMIENTO DE ELABORACIÓNLIQUID POTASSIUM SOAP AND PRODUCTION PROCEDURE

OBJETO DE LA INVENCIÓNOBJECT OF THE INVENTION

La invención, tal como expresa el enunciado de la presente memoria descriptiva, se refiere a un jabón potásico líquido y al procedimiento de elaboración aportando, a la función a que se destina, ventajas y características, que se describen en detalle más adelante, que suponen una mejora del estado actual de la técnica.The invention, as expressed in the title of this descriptive report, refers to a liquid potassium soap and the production process, providing, to the function for which it is intended, advantages and characteristics, which are described in detail below, which involve an improvement on the current state of the art.

Más concretamente, el objeto de la invención se centra en un jabón de fabricación artesanal en forma de líquido-gel que, con múltiples aplicaciones, presenta la particularidad de comprender en su composición únicamente ingredientes de origen 100% natural donde las sales proceden de aceites vegetales, y los excipientes/vehículos son 100% de origen vegetal, ningún origen sintético ni animal, en particular a base de oleínas de aguacate y oliva junto a aceite de girasol, siendo un segundo aspecto de la invención el procedimiento de elaboración de dicho jabón.More specifically, the object of the invention focuses on a handmade soap in the form of a liquid-gel that, with multiple applications, has the particularity of comprising in its composition only ingredients of 100% natural origin where the salts come from vegetable oils , and the excipients/vehicles are 100% of plant origin, no synthetic or animal origin, in particular based on avocado and olive oleins together with sunflower oil, a second aspect of the invention being the process for making said soap.

CAMPO DE APLICACIÓN DE LA INVENCIÓNFIELD OF APPLICATION OF THE INVENTION

El campo de aplicación de la presente invención se enmarca dentro del sector de la industria química, centrándose particularmente en el ámbito de la fabricación de jabones.The field of application of the present invention falls within the chemical industry sector, focusing particularly on the field of soap manufacturing.

ANTECEDENTES DE LA INVENCIÓNBACKGROUND OF THE INVENTION

Como referencia al estado actual de la técnica, aunque son conocidos muchos tipos de jabones, al menos por parte del solicitante, se desconoce la existencia de ninguno que presente unas características técnicas y estructurales iguales o semejantes a las que presenta el que aquí se reivindica.As a reference to the current state of the art, although many types of soaps are known, at least by the applicant, the existence of none that has technical and structural characteristics equal to or similar to those of the one claimed here is unknown.

EXPLICACIÓN DE LA INVENCIÓNEXPLANATION OF THE INVENTION

El jabón que la invención propone, como se ha comentado anteriormente, es un producto de jabón potásico de fabricación artesanal en forma de líquido-gel que, aplicable para múltiples usos, presenta la particularidad de comprender en su composición únicamente ingredientes de origen 100% natural, donde las sales proceden de aceites vegetales, y los excipientes/vehículos son 100% de origen vegetal, sin ningún origen sintético ni animal. En particular a base de oleínas de aguacate y oliva junto a aceite de girasol, siendo un segundo aspecto de la invención el procedimiento de elaboración de dicho jabón.The soap that the invention proposes, as mentioned above, is a handmade potassium soap product in liquid-gel form that, applicable for multiple uses, has the peculiarity of comprising only ingredients of 100% natural origin in its composition, where the salts come from vegetable oils, and the excipients/vehicles are 100% of vegetable origin, without any synthetic or animal origin. In particular based on avocado and olive oleins together with sunflower oil, a second aspect of the invention being the process for making said soap.

Más específicamente, el jabón objeto de la invención comprende en su composición los ingredientes que se indican a continuación:More specifically, the soap object of the invention comprises in its composition the ingredients indicated below:

- oleínas de aguacate y oliva,- avocado and olive oleins,

- aceite de girasol alto oleico,- oleic high sunflower oil,

- KOH,- KOH,

- K2CO3,- K2CO3,

- etildiglicol,- ethyldiglycol,

- etanol desnaturalizado con linalol natural,- denatured ethanol with natural linalool,

- tensioactivo no iónico C8-C10,- C8-C10 non-ionic surfactant,

- tensioactivo no iónico C5.- nonionic surfactant C5.

Más concretamente, dichos ingredientes, preferentemente, se encuentran en las siguientes proporciones:More specifically, said ingredients are preferably in the following proportions:

- oleínas de aguacate/oliva, 8,5%,- avocado/olive oleins, 8.5%,

- aceite de girasol alto oleico, 35,7%,- high oleic sunflower oil, 35.7%,

- KOH 50% en agua, 16,57%,- KOH 50% in water, 16.57%,

- K2CO3, 0,43%,- K2CO3, 0.43%,

- etildiglicol, 8,5%,- ethyldiglycol, 8.5%,

- etanol desnaturalizado con linalol natural, calidad ECOCERT, 22,8%,- denatured ethanol with natural linalool, ECOCERT quality, 22.8%,

- tensioactivo no iónico C8-C10, 5,25%,- nonionic surfactant C8-C10, 5.25%,

- tensioactivo no iónico C5, 2,25%.- nonionic surfactant C5, 2.25%.

Por su parte, el procedimiento de elaboración del jabón comprende los siguientes pasos:For its part, the soap making procedure includes the following steps:

- Se mezcla la materia grasa junto al glicol y se calienta a un mínimo de 40-50°C;- The fat is mixed with the glycol and heated to a minimum of 40-50°C;

- mientras se mezcla y calienta, se prepara la disolución de KOH K2CO3;- while mixing and heating, the KOH K2CO3 solution is prepared;

- sobre la mezcla grasa/glicol caliente, se añade lentamente la disolución de álcali anterior. El tiempo aproximado depende de la cantidad de fabricación, pudiendo ir de entre 1-2 horas con calentamiento y agitación, a entre 6-8 horas únicamente con calentamiento; - slowly add the previous alkali solution to the hot fat/glycol mixture. The approximate time depends on the amount of manufacturing, and can range from 1-2 hours with heating and stirring, to between 6-8 hours with heating only;

- se aumenta la temperatura sin llegar a alcanzar más de 80°C;- the temperature is increased without reaching more than 80°C;

- antes de que la mezcla comience a espesar bruscamente (situación que ocurre tras la consecución de la reacción del álcali con los grupos carboxílicos de los ácidos grasos), se añade el etanol lentamente, con lo cual la viscosidad disminuye considerablemente;- before the mixture begins to thicken abruptly (a situation that occurs after the reaction of the alkali with the carboxylic groups of the fatty acids is achieved), the ethanol is added slowly, with which the viscosity decreases considerably;

- una vez homogénea la mezcla anterior con el alcohol, se añaden los tensioactivos cuando la mezcla se enfría por debajo de los 50-60sC.- Once the previous mixture is homogeneous with the alcohol, the surfactants are added when the mixture cools below 50-60sC.

Tras la homogeneización, el producto está listo para envasar.After homogenization, the product is ready for packaging.

Con ello, el jabón presenta una coloración oscura (negro-verdoso) procedente de las oleínas de aceite de oliva y aguacate que, preferentemente, son de origen español.With this, the soap has a dark coloration (greenish-black) from the oleins of olive oil and avocado that, preferably, are of Spanish origin.

Conviene destacar que la descrita composición de ácidos grasos de la oleína está siempre ajustada y se genera a partir de la mezcla de aguacate y oliva. Esta oleína es esencial para conseguir el aspecto particular del jabón objeto de la invención. Paralelamente, tiene una acidez específica que influye favorablemente en el proceso de saponificación, a diferencia de otras oleínas menos ácidas. La composición de ácidos grasos saturados no es elevada y también es un factor clave para el aspecto líquido del formulado, a diferencia de otras con mayor contenido en ácidos grasos saturados que son las más utilizadas por otros jabones existentes en el mercado.It should be noted that the described composition of olein fatty acids is always adjusted and is generated from the mixture of avocado and olive. This olein is essential to achieve the particular aspect of the soap object of the invention. At the same time, it has a specific acidity that favorably influences the saponification process, unlike other less acidic oleins. The composition of saturated fatty acids is not high and is also a key factor for the liquid aspect of the formulation, unlike others with a higher content of saturated fatty acids that are the most used by other soaps on the market.

Además, también de modo preferido se emplea aceite de girasol de la variedad alto oleico, ya que es de más específico y de mayor calidad que el aceite de girasol convencional, con menor % ácido oleico.In addition, sunflower oil of the high oleic variety is also preferably used, since it is more specific and of higher quality than conventional sunflower oil, with a lower % oleic acid.

Por su parte, los tensioactivos empleados, preferentemente, proceden de partes no comestibles de cereales, lo que da sentido al concepto de sostenibilidad, pues el origen es un residuo que se convierte en producto de valor dentro de un proceso de economía circular. Al no ser de grado alimentario no compite en mercado con los ingredientes útiles en alimentación. Son 100% biodegradables y con certificación ECOCERT como producto natural para su uso como detergente o producto de limpieza multiusos.On the other hand, the surfactants used, preferably, come from inedible parts of cereals, which gives meaning to the concept of sustainability, since the origin is a residue that becomes a value product within a circular economy process. As it is not food grade, it does not compete in the market with useful ingredients in food. They are 100% biodegradable and ECOCERT certified as a natural product for use as a detergent or multipurpose cleaning product.

Además, como producto para la limpieza de la ropa no precisa suavizante pues su contenido alto en glicoles y glicerina aporta suavidad a los tejidos.In addition, as a product for cleaning clothes, it does not require a softener because its high content of glycols and glycerin provides softness to the fabrics.

El producto es, pues certificable como ecológico dentro de ECOLABEL.The product is therefore certifiable as organic within ECOLABEL.

Asimismo presenta un olor característico vegetal amargo. It also has a characteristic bitter vegetable odor.

Por último, cabe destacar que el jabón presenta un estado líquido-gel a temperaturas > 4°C, lo cual constituye una de sus principales ventajas, ya que otros jabones semejantes existentes en el mercado suelen ser gelatina a estas temperaturas frías y suponen mayor dificultad en la manipulación/utilización.Finally, it should be noted that the soap is in a liquid-gel state at temperatures > 4°C, which is one of its main advantages, since other similar soaps on the market tend to be gelatin at these cold temperatures and are more difficult to process. in handling/use.

Por su parte, las especificaciones técnicas del jabón objeto de la invención son las siguientes:For its part, the technical specifications of the soap object of the invention are the following:

- Contenido en sales potásicas procedentes de ácidos grasos C7-C18 y C18 insaturados, >50%- Content of potassium salts from C7-C18 and C18 unsaturated fatty acids, >50%

- Aspecto: líquido a T>4°C- Appearance: liquid at T>4°C

- Olor vegetal- Vegetable smell

- Color: marrón-verde oscuro- Colour: dark brown-green

- pH (1%) = 10.5 ± 0.5- pH (1%) = 10.5 ± 0.5

- Densidad (g/ml, 20°C)= 0.985 - 1.007- Density (g/ml, 20°C)= 0.985 - 1.007

- Humedad (100°C)= 35.9 ± 5- Humidity (100°C)= 35.9 ± 5

- Glicerina generada durante la saponificación, 4.5%- Glycerin generated during saponification, 4.5%

Por último, cabe destacar que, además del mencionado uso como jabón para la limpieza de la ropa, el jabón de la invención es apto para los siguientes usos:Finally, it should be noted that, in addition to the aforementioned use as soap for cleaning clothes, the soap of the invention is suitable for the following uses:

- En limpieza del hogar:- In household cleaning:

Limpieza general de ropa (detergente lavadora)General laundry cleaning (washing detergent)

Quitamanchas para ropastain remover for clothes

Limpieza, cuidado y renovación del cueroCleaning, care and renewal of leather

Limpieza de vajilla (lavavajillas)Dish cleaning (dishwasher)

Limpieza de suelos (fregasuelos)Floor cleaning (floor cleaner)

Limpieza y renovación de suelos hidráulicosCleaning and renovation of hydraulic floors

Limpieza general de superficies lavables (baldosas, madera, esmalte, WC, superficies plásticas...)General cleaning of washable surfaces (tiles, wood, enamel, WC, plastic surfaces...)

Quitamanchas de todo tipo de superficiesStain remover for all types of surfaces

Limpieza de hornos y campanas (desengrasante)Cleaning of ovens and hoods (degreasing)

Limpieza de acero inoxidablestainless steel cleaning

Limpieza ventanas y vidrios (limpiacristales) Window and glass cleaning (glass cleaner)

Limpieza de pincelesbrush cleaning

Limpieza de brochas maquillajemakeup brush cleaning

- En limpieza e higiene personal:- In cleaning and personal hygiene:

Lavar manosWash hands

Lavar cuerpo (gel ducha)Body wash (shower gel)

Baño espumantefoaming bath

Lavar pelo (champú)Wash hair (shampoo)

Limpiador facial (desmaquillante)Facial cleanser (makeup remover)

Lavar mascotaswash pets

Base cosmética sobre la que dispersar principios activos.Cosmetic base on which to disperse active ingredients.

- En el ámbito agrícola y de jardinería:- In the field of agriculture and gardening:

Limpieza de plantas (negrilla, melaza...)Plant cleaning (bold, molasses...)

Jabón postcosecha para lavado de cítricosPostharvest soap for citrus washing

Limpieza de fruta y verdura en casa antes de consumirCleaning fruit and vegetables at home before consuming

Limpieza de utensilios jardinería y agriculturaCleaning of gardening and agricultural tools

Limpieza de instalaciones y maquinaria agrícolasCleaning of agricultural facilities and machinery

Fitosanitario insecticidaPhytosanitary insecticide

Fertilizante AbonoFertilizer Manure

- En el ámbito industrial:- In the industrial field:

Desmoldeante para escayolaRelease agent for plaster

Lubricante para encajar tuberíasPipe Fitting Lubricant

Lubricante para engranajesgear lubricant

Descrita suficientemente la naturaleza de la presente invención, así como la manera de ponerla en práctica, no se considera necesario hacer más extensa su explicación para que cualquier experto en la materia comprenda su alcance y las ventajas que de ella se derivan, haciéndose constar que, dentro de su esencialidad, podrá ser llevada a la práctica en otras formas de realización que difieran en detalle de la indicada a título de ejemplo, y a las cuales alcanzará igualmente la protección que se recaba siempre que no se altere, cambie o modifique su principio fundamental. Having sufficiently described the nature of the present invention, as well as the way of putting it into practice, it is not considered necessary to make its explanation more extensive so that any person skilled in the art understands its scope and the advantages derived from it, stating that, within its essentiality, it may be put into practice in other forms of embodiment that differ in detail from the one indicated by way of example, and to which it will also achieve the protection that is sought as long as its fundamental principle is not altered, changed or modified. .

Claims (5)

r e iv in d ic a c io n e s re iv in d ic a tio ns 1. - JABÓN POTÁSICO LÍQUIDO que, consistente en un producto artesanal en forma de líquido-gel, aplicable para múltiples usos, comprende, como ingredientes en su composición: oleínas de aguacate y oliva, aceite de girasol alto oleico, KOH, K2CO3 y está caracterizado porque como ingredientes de su composición, también, comprende:1. - LIQUID POTASSIUM SOAP which, consisting of an artisan product in liquid-gel form, applicable for multiple uses, includes, as ingredients in its composition: avocado and olive oleins, high oleic sunflower oil, KOH, K2CO3 and is characterized in that as ingredients of its composition, it also includes: - etildiglicol,- ethyldiglycol, - etanol desnaturalizado con linalol natural,- denatured ethanol with natural linalool, - tensioactivo no iónico C8-C10,- C8-C10 non-ionic surfactant, - tensioactivo no iónico C5.- nonionic surfactant C5. 2. - JABÓN POTÁSICO LÍQUIDO, según la reivindicación 1, caracterizado porque dichos ingredientes se encuentran en las siguientes proporciones:2. - LIQUID POTASSIUM SOAP, according to claim 1, characterized in that said ingredients are in the following proportions: - oleínas de aguacate/oliva, 8,5%,- avocado/olive oleins, 8.5%, - aceite de girasol alto oleico, 35,7%,- high oleic sunflower oil, 35.7%, - KOH 50% en agua, 16,57%,- KOH 50% in water, 16.57%, - K2CO3, 0,43%,- K2CO3, 0.43%, - etildiglicol, 8,5%- ethyldiglycol, 8.5% - etanol desnaturalizado con linalol natural, 22,8%,- ethanol denatured with natural linalool, 22.8%, - tensioactivo no iónico C8-C10, 5,25%,- nonionic surfactant C8-C10, 5.25%, - tensioactivo no iónico C5, 2,25%.- nonionic surfactant C5, 2.25%. 3. - PROCEDIMIENTO DE ELABORACIÓN DE UN JABÓN POTÁSICO LÍQUIDO, según el descrito en las reivindicaciones 1 y 2, caracterizado porque comprende los siguientes pasos:3. - PROCEDURE FOR PREPARING A LIQUID POTASSIUM SOAP, according to that described in claims 1 and 2, characterized in that it comprises the following steps: - se mezcla la materia grasa junto al glicol y se calienta a un mínimo de 40-50°C;- the fat is mixed with the glycol and heated to a minimum of 40-50°C; - mientras se mezcla y calienta, se prepara la disolución de KOH K2CO3;- while mixing and heating, the KOH K2CO3 solution is prepared; - sobre la mezcla grasa/glicol caliente, se añade lentamente la disolución de álcali anterior;- slowly add the previous alkali solution to the hot fat/glycol mixture; - se aumenta la temperatura sin llegar a alcanzar más de 80°C;- the temperature is increased without reaching more than 80°C; - antes de que la mezcla comience a espesar bruscamente (situación que ocurre tras la consecución de la reacción del álcali con los grupos carboxílicos de los ácidos grasos), se añade el etanol lentamente, con lo cual la viscosidad disminuye considerablemente;- before the mixture begins to thicken abruptly (a situation that occurs after the reaction of the alkali with the carboxylic groups of the fatty acids is achieved), the ethanol is added slowly, with which the viscosity decreases considerably; - una vez homogénea la mezcla anterior con el alcohol, se añaden los tensioactivos cuando la mezcla se enfría por debajo de los 50-60°C.- Once the previous mixture is homogeneous with the alcohol, the surfactants are added when the mixture cools below 50-60°C. 4. - PROCEDIMIENTO DE ELABORACIÓN DE UN JABÓN POTÁSICO LÍQUIDO, según la reivindicación 3, caracterizado porque la disolución de álcali se añade lentamente sobre la mezcla grasa/glicol caliente, durante un tiempo aproximado de entre 1-2 horas con calentamiento y agitación.4. - PROCEDURE FOR PREPARING A LIQUID POTASSIUM SOAP, according to claim 3, characterized in that the alkali solution is added slowly on the hot fat/glycol mixture, for approximately 1-2 hours with heating and stirring. 5.- PROCEDIMIENTO DE ELABORACIÓN DE UN JABÓN POTÁSICO LÍQUIDO, según la reivindicación 3, caracterizado porque la disolución de álcali se añade lentamente sobre la mezcla grasa/glicol caliente, durante un tiempo aproximado de entre 6-8 horas únicamente con calentamiento. 5. PROCEDURE FOR PREPARING A LIQUID POTASSIUM SOAP, according to claim 3, characterized in that the alkali solution is added slowly to the hot fat/glycol mixture, for an approximate time of between 6-8 hours with heating only.
ES202030730A 2020-07-15 2020-07-15 LIQUID POTASSIUM SOAP AND PRODUCTION PROCEDURE (Machine-translation by Google Translate, not legally binding) Withdrawn ES2891361A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989012673A1 (en) * 1988-06-21 1989-12-28 Vax Appliances Limited Fabric cleaning and sanitizing compositions
CN102423292A (en) * 2011-12-18 2012-04-25 骆志明 Pure traditional Chinese medicine freckle-removing and cleansing soap liquid
CN102488639A (en) * 2011-12-18 2012-06-13 骆志明 Pure Chinese traditional medicine moisturizing and cleansing liquid soap
CN103589536A (en) * 2013-11-27 2014-02-19 骆志明 Licorice-containing skin moistening liquid soap
CN107904050A (en) * 2017-11-08 2018-04-13 骆志明 Moisturizing whitening ferment face cleaning craft liquid soap

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989012673A1 (en) * 1988-06-21 1989-12-28 Vax Appliances Limited Fabric cleaning and sanitizing compositions
CN102423292A (en) * 2011-12-18 2012-04-25 骆志明 Pure traditional Chinese medicine freckle-removing and cleansing soap liquid
CN102488639A (en) * 2011-12-18 2012-06-13 骆志明 Pure Chinese traditional medicine moisturizing and cleansing liquid soap
CN103589536A (en) * 2013-11-27 2014-02-19 骆志明 Licorice-containing skin moistening liquid soap
CN107904050A (en) * 2017-11-08 2018-04-13 骆志明 Moisturizing whitening ferment face cleaning craft liquid soap

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