CN106867727B - Laundry sheet is sterilized in a kind of hyperconcetration - Google Patents
Laundry sheet is sterilized in a kind of hyperconcetration Download PDFInfo
- Publication number
- CN106867727B CN106867727B CN201710137758.3A CN201710137758A CN106867727B CN 106867727 B CN106867727 B CN 106867727B CN 201710137758 A CN201710137758 A CN 201710137758A CN 106867727 B CN106867727 B CN 106867727B
- Authority
- CN
- China
- Prior art keywords
- laundry sheet
- hyperconcetration
- laundry
- sheet
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of hyperconcetration to sterilize laundry sheet, by weight percentage including following component：Film forming agent：5 10%；Bactericide：0.5 5%；PCMX：0.5 2.5%；Phytoremediation agent：1 5%；Neopelex：10 30%；Lauryl sodium sulfate：5 15%；Aliphatic alcohol polyethenoxy (9) ether：5 10%；Polyoxyethylene fatty alkyl ether sulfonate：1 5%；Sodium silicate：5 10%；Soda ash：10 20%；Metal ion chelation agent：0.1 1%；Essence：0.05 0.5%；Pigment：0.001 0.005%；Preservative：0.1 0.5%；Deionized water：1 50%.The laundry sheet of the present invention realizes the paper of laundry detergents from physical aspect, small volume, is easy to carry and takes conveniently, active matter content is high, maintains the clean result of traditional liquid detergent and washing powder, can be dissolved immediately in hot and cold water, does not lump, do not precipitate.Plant sterilization composition and Phytoremediation composition are added, compared to conventional laundry product, both with clean effect, there is bactericidal effect, safer environmental protection again.
Description
Technical field
The present invention relates to daily washing field, more particularly to a kind of hyperconcetration sterilization laundry sheet.
Background technology
At present, the laundry detergents commonly used in life mainly have three kinds of washing powder, liquid detergent and laundry soap.Wherein washing powder is usual
Packaging bag is cut off to be packed, during use, takes and is again pressed from both sides packaging bag with the article of clip etc after a small amount of washing powder.
Such a washing powder due to packaging bag open after poor sealing, easily cause washing powder to make moist, lump and influence its dissolubility and
Cleaning force, and washing powder is also very easy to be scattered near washstand during taking, it is difficult to clear up.
Liquid detergent is usually bottled, needs measuring cup to measure when taking；There are extrusion type bottled liquid detergent, Ci Zhongxi in addition
The liquid outlet of clothing liquid easily causes liquid detergent usually to be overflow automatically later in extruding due to multiple extruding or extrusion head encapsulation problem
Go out, add the cleaning after washing.
Laundry soap meeting residual moisture during washing by rubbing with the hands, after soap box is put into, the long-term retention of moisture can soften laundry
Soap, cause unnecessary waste.
In summary, there are various shortcomings in existing articles for washing mostly, and not portable, space-consuming, be not easy to out
Used during travel row.Therefore, it is necessary to be improved to articles for washing.
Also there are laundry flake products in the prior art, the laundry sheet that city faces the mountain at present there are two kinds：One kind be by the use of non-woven fabrics as
Carrier, part liquid detergent are adhered on non-woven fabrics, need to remove non-woven fabrics every time after washing, and there is also fiber in non-woven fabrics
The phenomenon to come off, the fiber to come off can be adhered on clothes；Another kind is by the use of polyvinyl alcohol as film forming agent, with kaolin, two
Silica, cornstarch etc. are used as filler, and it is in blocks to add the surfactant drying of vector, have after dissolving during washing very bright
Aobvious sediment, water are very muddy, and sediment can be adsorbed in garment fabric in washing process, remained to the end.
The content of the invention
For weak point present in above-mentioned technology, the present invention provides a kind of small volume, dissolving is fast, do not precipitate, can
Decontamination, the hyperconcetration sterilization laundry sheet of and can sterilization.
To achieve the above object, the present invention provides a kind of hyperconcetration sterilization laundry sheet, by weight percentage by following component
Composition：
Film forming agent：5-10%；
Bactericide is camphorated oil, eucalyptus oil, extract solution from aloe, ginger extract, galic essential oil, Blumea oil, tea tree
One or more in oil：0.5-5%；
PCMX：1-2.5%；
Phytoremediation agent is the one or more in soapberry extract, Chinese honey locust extract solution, oil tea seed extract：1-5%；
Neopelex：10-30%；
Lauryl sodium sulfate：5-15%；
Aliphatic alcohol polyethenoxy (9) ether：5-10%；
Polyoxyethylene fatty alkyl ether sulfonate：1-5%；
Sodium silicate：5-10%；
Soda ash：10-20%；
Metal ion chelation agent：0.1-1%；
Essence：0.05-0.5%；
Pigment：0.001-0.005%；
Preservative：0.1-0.5%；
Deionized water：1-50%.
Wherein, film forming agent is the one or more in polyethylene glycol, polyvinyl alcohol or polyvinylpyrrolidone.
Wherein, the metal ion chelation agent be tetrasodium ethylenediamine tetraacetate, sodium citrate, disodium ethylene diamine tetraacetate,
One or more in sodium gluconate.
Wherein, the preservative is one in methylchloroisothiazandnone, methylisothiazolinone or DMDMH
Kind is a variety of.
Wherein, hyperconcetration sterilization laundry sheet is in the sheet that thickness is 0.2-1.2mm.
The beneficial effects of the invention are as follows：Compared with prior art, hyperconcetration of the invention sterilization laundry sheet, from physical aspect
On realize the paper of laundry detergents, small volume, be easy to carry and take conveniently.Active matter content be more than 60%, with liquid detergent, wash
Clothing powder is compared with laundry soap, and usage amount substantially reduces, and the clean result of traditional liquid detergent and washing powder is maintained, in hot and cold water
It can immediately dissolve, not lump, do not precipitate.Present invention addition plant sterilization composition and Phytoremediation composition, 3.3% laundry sheet
The aqueous solution is all higher than 90% to the sterilizing rate of Escherichia coli, staphylococcus aureus and Candida albicans, meets health ministry
's《Disinfection technology standard》(2002 editions), mould taste removal can be removed after clothes washing.Phytoremediation composition and conventional surfactant
Compounding use, enhance clean result.Dirt-removing power is strong, according to QB/T 1224-2012 (dress material washes agent by liquid), 3.3%
The aqueous solution of the laundry sheet is compared with the detergency of standard liquid detergent, and the detergency to sebum greasy dirt cloth is 1.6, to albumen soiled cotton
Detergency be 1.5, be 1.2 to the detergency of carbon black greasy dirt cloth, be all higher than the detergency of standard liquid detergent.Compared to conventional laundry
With product, both with clean effect, there is bactericidal effect, safer environmental protection again.The present invention is phosphorous, without fluorescent whitening agent,
The close neutrality of pH value, does not hurt hands, biodegradable, will not cause environmental pollution.
Embodiment
PCMX in hyperconcetration sterilization laundry sheet of the present invention is a kind of antimildew and antibacterial agent of wide spectrum, to more
Number gram-positive bacteria, Gram-negative bacteria, fungi, mould, which all has, kills effect, can make the protein denaturation of microorganism, sink
Form sediment, inactivate the enzyme system of microorganism, can suppress and kill brood body and the lipophilic virus of part bacterium.
Common phenolic antiseptic includes phenol, cresols, parachlorometaxylenol and Triclosan, table on the market
1 contrasts for the performance parameter of above-mentioned four kinds of phenolic antiseptics, select during test equivalent, etc. dilution factor phenolic antiseptic, on an equal basis
Test object.In antibacterial effect based on the antibacterial effect of phenol numerical value, other antibacterial effects are with the antibacterial effect of phenol
Based on carry out multiple contrast.It is bactericidal effect based on different phenolic antiseptics, the pollution to environment, equal to skin irritation
Different, preferred PCMX is as bactericide in hyperconcetration sterilization laundry sheet of the invention, chlorine two
For methylphenol compares other phenolic antiseptics, bactericidal effect is higher, small to skin irritation, and the pollution to environment is small,
Without excitant taste, mould taste removal can be removed after clothes cleaning.
The performance comparison of the phenolic antiseptic of table 1
| Phenolic antiseptic | Corrosivity | Smell | Toxicity | Antibacterial effect |
| Phenol | There is slight erosion effect to skin | Off-odor | Moderate toxicity | 1 |
| Cresols | Without obvious corrosiveness | Less malodor | Moderate toxicity | 3-10 |
| Parachlorometaxylenol | Without obvious corrosiveness | Basic odorless | Basic toxicity | 20-30 |
| Triclosan | To no skin irritation | Slight aromatic odor | Substantially it is nontoxic | 20-30 |
The bactericide of the present invention selects the plant containing the very high functional compounds of reactivity and terpenoid
Thing bactericide, forms the very strong molecule of diameter very little activity after the dissolving of these compounds, the very strong natural plants molecule of activity with
The chemical bond that odor molecules in fabric collide and destroyed in odor molecules promotes its decomposition, and similar compatibility physics occurs
Absorb and dissolve；Also with acidic oxides such as the carbon, nitrogen, sulphur of stains on fabrics soda acid occurs for the alkaloid in bactericide
Neutralization reaction；Active ingredient in bactericide, it can rapidly polymerize with the harmful of spot, odor molecules, substitute, put
The chemical reaction such as change, adsorb, decomposing.Because the extraction cost of different bactericides, extraction process maturity, purification are pure
Degree has differences, the present invention preferably camphorated oil, eucalyptus oil, extract solution from aloe, ginger extract, galic essential oil, Blumea oil, tea tree
Oil.Planting range of the above-mentioned plant in China is wide, and extraction process is ripe, and extraction cost is low, and sterilizing deodoring effect is good.
The decontamination principle of Phytoremediation agent is containing surfactant component, can be occurred with the spot on silk wool fabric
Bubble, decontamination, emulsification etc. are reacted, and then by the greasiness removal of fabric face.For chemical decontaminants are compared in Phytoremediation agent, be free of
Alkalescence, to silk wool fabric not damaged.And it also added DBSA in addition to adding Phytoremediation agent in the present invention
The chemical surfactants such as sodium, lauryl sodium sulfate, Phytoremediation composition and conventional surfactant compounding use, are enhanced
Clean result.Dirt-removing power is strong.Preferred soapberry extract, Chinese honey locust extract solution and oil tea seed extract in Phytoremediation agent.Nothing
Suffer from son, Chinese honey locust, tea seed and make detergent usage time length, extraction process is ripe, and extraction cost is lower, is adapted to industrial production.
It is to suppress the growth of the microorganism on clothes and breed, preferred first in the present invention that preservative is added in laundry sheet
As preservative, above-mentioned three kinds of preservatives are a kind of efficient for base chloroisothiazole quinoline ketone, methylisothiazolinone, DMDMH
Bactericide, there is hot water resistance, the growth of bacterium, fungi and mould can be suppressed, personal-care supplies can be directly added into, change
The fields such as cosmetic, coating.The laundry sheet of the present invention with the addition of preservative, further enhancing bactericidal effect, while be also provided with
The effect of antimildew and antibacterial.
Film forming agent be it is a kind of can allow the auxiliary agent that active material is bonded together in laundry sheet, the film forming agent in the present invention can be with
For the one or more in polyethylene glycol, polyvinyl alcohol or polyvinylpyrrolidone, because polyethylene glycol is nontoxic, non-stimulated, tool
There is good water solubility, there can be good compatibility with many organic constituentses, so the film forming agent of the present invention is preferably poly- second
Glycol.
Hyperconcetration of the present invention sterilization laundry sheet is further described with reference to specific embodiment.
Embodiment 1：
Laundry sheet is sterilized in a kind of hyperconcetration, and its composition of raw materials is as follows：Polyethylene glycol 6g, polyvinylpyrrolidone 3g, camphor
Oily 1g, Blumea oil 2g, ginger extract 1g, tea oil 1g, PCMX 1.5g, Chinese honey locust extract solution 3g, dodecane
Base benzene sulfonic acid sodium salt 15g, lauryl sodium sulfate 10g, aliphatic alcohol polyethenoxy (9) ether 8g, polyoxyethylene fatty alkyl ether sulfonate
3g, sodium silicate 7g, soda ash 13g, tetrasodium ethylenediamine tetraacetate 0.5g, essence 0.3g, pigment 0.0002g, methylisothiazolinone
0.15g, deionized water 24.5495g.
After above-mentioned raw materials are well mixed by mass fraction, turn into sheet after oily heating, drying, cylinder drying film process
Laundry sheet is made in laundry detergents, then clipped, punching press and packaging and other steps.
Embodiment 2：
Laundry sheet is sterilized in a kind of hyperconcetration, and its composition of raw materials is as follows：Polyethylene glycol 3g, polyvinyl alcohol 4g, eucalyptus oil 2g, reed
Luxuriant growth extract solution 2g, galic essential oil 1g, PCMX 2.5g, soapberry extract 3g, oil tea seed extract 2g, 12
Sodium alkyl benzene sulfonate 13g, lauryl sodium sulfate 10g, aliphatic alcohol polyethenoxy (9) ether 10g, AEO sulfonic acid
Sodium 2g, sodium silicate 6g, soda ash 12g, sodium citrate 0.3g, sodium gluconate 0.2g, essence 0.1g, pigment 0.0001g, methyl are different
Thiazolinone 0.1g, methylchloroisothiazandnone 0.2g, deionized water 26.5999g.
After above-mentioned raw materials are well mixed by mass fraction, turn into sheet after oily heating, drying, cylinder drying film process
Laundry sheet is made in laundry detergents, then clipped, punching press and packaging and other steps.
Embodiment 3：
Laundry sheet is sterilized in a kind of hyperconcetration, and its composition of raw materials is as follows：Polyethylene glycol 2g, polyvinyl alcohol 3g, camphorated oil 0.2g,
Extract solution from aloe 0.1g, ginger extract 0.1g, tea oil 0.1g, PCMX 0.5g, Chinese honey locust extract solution 1g, ten
Dialkyl benzene sulfonic acids sodium 10g, lauryl sodium sulfate 5g, aliphatic alcohol polyethenoxy (9) ether 5g, AEO sulfonic acid
Sodium 1g, sodium silicate 5g, soda ash 10g, sodium citrate 0.1g, sodium gluconate 0.3g, essence 0.05g, pigment 0.0002g, methyl
OIT 0.1g, deionized water 56.4498g.
After above-mentioned raw materials are well mixed by mass fraction, turn into sheet after oily heating, drying, cylinder drying film process
Laundry sheet is made in laundry detergents, then clipped, punching press and packaging and other steps.
Embodiment 4：
Laundry sheet is sterilized in a kind of hyperconcetration, and its composition of raw materials is as follows：Polyethylene glycol 3g, polyvinyl alcohol 3g, camphorated oil 0.3g,
Extract solution from aloe 0.3g, ginger extract 0.2g, tea oil 0.2g, PCMX 1g, Chinese honey locust extract solution 2g, 12
Sodium alkyl benzene sulfonate 12g, lauryl sodium sulfate 8g, aliphatic alcohol polyethenoxy (9) ether 6.5g, AEO sulfonic acid
Sodium 2g, sodium silicate 6g, soda ash 12g, sodium citrate 0.1g, sodium gluconate 0.3g, essence 0.13g, pigment 0.0002g, methyl
OIT 0.1g, deionized water 42.3998g.
After above-mentioned raw materials are well mixed by mass fraction, turn into sheet after oily heating, drying, cylinder drying film process
Laundry sheet is made in laundry detergents, then clipped, punching press and packaging and other steps.
Embodiment 5：
Laundry sheet is sterilized in a kind of hyperconcetration, and its composition of raw materials is as follows：Polyethylene glycol 4g, polyvinyl alcohol 4g, camphorated oil 1g, reed
Luxuriant growth extract solution 2g, ginger extract 1g, tea oil 1g, PCMX 1.5g, Chinese honey locust extract solution 3g, detergent alkylate
Sodium sulfonate 15g, lauryl sodium sulfate 10g, aliphatic alcohol polyethenoxy (9) ether 8g, polyoxyethylene fatty alkyl ether sulfonate 3g, bubble
Colored alkali 7g, soda ash 13g, sodium citrate 0.2g, sodium gluconate 0.2g, essence 0.3g, pigment 0.0002g, methylisothiozoline
Ketone 0.15g, deionized water 24.8495g.
After above-mentioned raw materials are well mixed by mass fraction, turn into sheet after oily heating, drying, cylinder drying film process
Laundry sheet is made in laundry detergents, then clipped, punching press and packaging and other steps.
Embodiment 6：
Laundry sheet is sterilized in a kind of hyperconcetration, and its composition of raw materials is as follows：Polyethylene glycol 4.5g, polyvinyl alcohol 4.5g, camphorated oil
0.5g, extract solution from aloe 0.5g, ginger extract 0.5g, tea oil 0.5g, PCMX 2g, Chinese honey locust extract solution
4g, neopelex 20g, lauryl sodium sulfate 12g, aliphatic alcohol polyethenoxy (9) ether 9g, aliphatic alcohol polyethenoxy
Ether sulfonic acid sodium 4g, sodium silicate 8g, soda ash 17g, sodium citrate 0.2g, sodium gluconate 0.3g, essence 0.1g, pigment 0.0002g,
Methylisothiazolinone 0.3g, deionized water 12.0998g.
After above-mentioned raw materials are well mixed by mass fraction, turn into sheet after oily heating, drying, cylinder drying film process
Laundry sheet is made in laundry detergents, then clipped, punching press and packaging and other steps.
Embodiment 7：
Laundry sheet is sterilized in a kind of hyperconcetration, and its composition of raw materials is as follows：Polyethylene glycol 5g, polyvinyl alcohol 5g, camphorated oil 0.8g,
Extract solution from aloe 0.8g, ginger extract 0.7g, tea oil 0.7g, PCMX 2.5g, Chinese honey locust extract solution 5g, ten
Dialkyl benzene sulfonic acids sodium 20g, lauryl sodium sulfate 12g, aliphatic alcohol polyethenoxy (9) ether 9g, AEO sulphur
Sour sodium 5g, sodium silicate 10g, soda ash 20g, sodium citrate 0.2g, sodium gluconate 0.3g, essence 0.5g, pigment 0.0002g, first
Base OIT 0.5g, deionized water 1.9998g.
After above-mentioned raw materials are well mixed by mass fraction, turn into sheet after oily heating, drying, cylinder drying film process
Laundry sheet is made in laundry detergents, then clipped, punching press and packaging and other steps.
Here is the pH value testing experiment of embodiment 1-7 hyperconcetration sterilization laundry sheet：
With reference to the Ministry of Public Health《Disinfection technology standard》2.2.1.4 is carried out in (version in 2002) (defending method prison hair [2002] 282)
Test；22 degrees Celsius of test temperature, relative humidity 61%.
It can be drawn by table 2-1,1-7 of embodiment of the present invention disinfection tablet pH value is between 6.40-7.10, close neutrality,
It is not easy to cause corrosion to injure human body skin.
The pH value measurement result of laundry sheet is sterilized in table 2-1 embodiment 1-7 hyperconcetration
Here is an embodiment 1-7 intact skin irritant test：
It will be applied to after 1-7 of the embodiment of the present invention 5 times of laundry sheet dissolved dilution on the left of new zealand rabbit and remove hair-fields skin, so
Covered afterwards with non-stimulated plastic foil, hair-fields skin is removed as blank control on the right side of new zealand rabbit.Apply time 4h.Then with temperature
Water also washes away residual liquid, respectively with 1h, 24h, 48h observation local skin reaction, carries out stimulate the reaction scoring.
Table 2-2 is shown：During observation, tested new zealand rabbit skin has no erythema, oedema abnormal response, does not find it
His poisoning symptom, highest stimulus index are 0.
Table 2-2 embodiments 1-7 intact skin irritant tests successively
Consolidated statement 2-1 and table 2-2 are drawn to draw a conclusion：The hyperconcetration of the present invention sterilizes laundry sheet pH value in 6.40-7.10
Between, the formula of laundry sheet is substantially nonirritant to human body skin substantially close to neutrality especially in embodiment 5,6,7, does not hinder
Hand.
Here is killing experiments of the embodiment 1-7 to Escherichia coli and staphylococcus aureus：
The preparation of bacteria suspension：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.3, bacteria containing amount be 1 ×
108cfu/mL-5×108cfu/mL。
Embodiment 1-7 nertralizer qualification tests：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.5.Examination
It is Escherichia coli to test bacterium.Each embodiment experiment is grouped into：(1) laundry sheet solution+bacteria suspension, (2) (laundry sheet solution+bacterium is hanged
Liquid)+nertralizer, (3) nertralizer+bacteria suspension, (4) (laundry sheet solution+nertralizer)+bacteria suspension, (5) TPS+ bacteria suspensions, (6) examination
Test used with batch TPS, nertralizer, culture medium.The dilution of laundry sheet solution 3.3%, action time 10min, experiment repeat 3
It is secondary.19 DEG C -21 DEG C of test temperature.
Embodiment 1-7 nertralizer authentication test results：
As shown in table 3-1, (1) group average production bacterium number of embodiment 1 is 0cfu/mL, and (2) organize average production bacterium number
For 4.24 × 102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 2.51% between three groups.(6)
Group asepsis growth.
(1) group average production bacterium number of embodiment 2 be 0cfu/mL, (2) group average production bacterium number for 4.20 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 2.24% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 3 be 0cfu/mL, (2) group average production bacterium number for 4.37 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, error rate 2.52% between three groups.(6) organize asepsis growth.
(1) group average production bacterium number of embodiment 4 be 0cfu/mL, (2) group average production bacterium number for 4.27 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 2.58% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 5 be 0cfu/mL, (2) group average production bacterium number for 4.18 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 3.01% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 6 be 0cfu/mL, (2) group average production bacterium number for 4.24 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 2.75% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 7 be 0cfu/mL, (2) group average production bacterium number for 4.38 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 2.54% between three groups.(6) organize sterile life
It is long.
Table 3-1 embodiment 1-7 nertralizer authentication test results
Suspension quantitative bactericidal test：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.7.Embodiment 1-7
The dilution of laundry sheet solution 3.3%, action time 10min, 20min, 30min, experiment is repeated 3 times.19 DEG C -21 of test temperature
℃。
Killing effects of the embodiment 1-7 to Escherichia coli and staphylococcus aureus：
As shown in table 3-2, embodiment 1-7 shows through 3 repetition experiments：Embodiment 1-7 hyperconcetration sterilization laundry sheet,
In 19 DEG C -21 DEG C of test temperature, the dilution of laundry sheet solution 3.3%, 20min is acted on, to Escherichia coli and golden yellow Portugal
The killing logarithm value of grape coccus is all higher than 5.00, and wherein embodiment 1 is to the sterilizing rate of Escherichia coli and staphylococcus aureus point
Not Wei 95.1%, 94.9%, embodiment 2 is respectively 95.8% to the sterilizing rate of Escherichia coli and staphylococcus aureus,
95.5%, embodiment 3 is respectively 92.0%, 92.6% to the sterilizing rate of Escherichia coli and staphylococcus aureus, and embodiment 4 is right
The sterilizing rate of Escherichia coli and staphylococcus aureus is respectively 92.2%, 92.5%, and embodiment 5 is to Escherichia coli and golden yellow
Staphylococcic sterilizing rate is respectively 97.8%, 96.3%, sterilizing rate of the embodiment 6 to Escherichia coli and staphylococcus aureus
Respectively 95.3%, 95.4%, embodiment 7 is respectively 95.2% to the sterilizing rate of Escherichia coli and staphylococcus aureus,
94.7%.Consolidated statement 3-1 and table 3-2 are drawn to draw a conclusion：The hyperconcetration sterilization laundry sheet of the present invention is to Escherichia coli and golden yellow
The staphylococcic sterilizing rate of color is all higher than 90%, wherein bactericidal effect of the embodiment 5 to staphylococcus aureus and Escherichia coli
Most preferably.
Killing experiments of the table 3-2 embodiments 1-7 to Escherichia coli and staphylococcus aureus
Here is killing experiments of the embodiment 1-7 to Candida albicans：
The preparation of bacteria suspension：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.3, bacteria containing amount be 1 ×
107cfu/mL-5×107cfu/mL。
Nertralizer qualification test：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.5.Test organisms is white
Candida albicans.Experiment is grouped into：(1) laundry sheet solution+bacteria suspension, (2) (laundry sheet solution+bacteria suspension)+nertralizer, (3) neutralize
Agent+bacteria suspension, (4) (laundry sheet solution+nertralizer)+bacteria suspension, (5) TPS+ bacteria suspensions, (66) experiment it is used with batch TPS,
Nertralizer, culture medium.The dilution of laundry sheet solution 2%, action time 10min, experiment are repeated 3 times.19 DEG C -21 of test temperature
℃。
Embodiment 1-7 nertralizer authentication test results：
As shown in table 4-1, (1) group average production bacterium number of embodiment 1 is 0cfu/mL, and (2) organize average production bacterium number
For 2.04 × 102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 4.24% between three groups.(6)
Group asepsis growth.
(1) group average production bacterium number of embodiment 2 be 0cfu/mL, (2) group average production bacterium number for 2.09 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 4.72% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 3 be 0cfu/mL, (2) group average production bacterium number for 2.19 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 3.01% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 4 be 0cfu/mL, (2) group average production bacterium number for 2.08 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 2.30% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 5 be 0cfu/mL, (2) group average production bacterium number for 2.04 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 4.25% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 6 be 0cfu/mL, (2) group average production bacterium number for 2.09 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 4.13% between three groups.(6) organize sterile life
It is long.
(1) group average production bacterium number of embodiment 7 be 0cfu/mL, (2) group average production bacterium number for 2.15 ×
102Cfu/mL, (3), (4), (5) group average production bacterium number are close, and error rate is 3.57% between three groups.(6) organize sterile life
It is long.
Table 4-1 embodiments 1-7 nertralizer authentication test results
Quantitative disinfecting test：According to the Ministry of Public Health《Disinfection technology standard》(version in 2002) 2.1.1.7.Embodiment 1-7's washes
The dilution of garment piece solution 3.3%, action time 10min, 20min, 30min, experiment are repeated 3 times.19 DEG C -21 DEG C of test temperature.
Killing effects of the embodiment 1-7 to Candida albicans：As shown in table 4-2, show through 3 repetition experiments：Embodiment
Laundry sheet is sterilized in 1-7 hyperconcetration, in 19 DEG C -21 DEG C of test temperature, the dilution of laundry sheet solution 3.3%, acts on 20min,
Killing logarithm value to Candida albicans is all higher than 6.00, and sterilization is qualified, and wherein embodiment 1 is to the sterilizing rate of Candida albicans
93.9%, embodiment 2 is 93.2% to the sterilizing rate of Candida albicans, and embodiment 3 is to the sterilizing rate of Candida albicans
91.4%, embodiment 4 is 91.1% to the sterilizing rate of Candida albicans, and embodiment 5 is to the sterilizing rate of Candida albicans
96.7%, embodiment 6 is 92.6% to the sterilizing rate of Candida albicans, and embodiment 7 is to the sterilizing rate of Candida albicans
92.3%.Consolidated statement 4-1 and table 4-2 can be drawn to draw a conclusion：1-7 of embodiment of the present invention hyperconcetration sterilization laundry sheet dialogue
The sterilizing rate that color reads coccus is all higher than 90%, wherein, embodiment 5 is optimal to the sterilizing rate of Candida albicans.
Killing experiments of the table 4-2 embodiments 1-7 to Candida albicans
Below for 1-7 of the embodiment of the present invention to textile disinfecting field test：
Embodiment 1-7 is subjected to following experiment with its 3.3% dilution, the formula of sample solution includes：Containing 0.3% lecithin
Fat, 3.0% Tween 80,0.5% glycine, the PBS of 0.3% histidine.The formula of dilution is the TRS containing 0.1% Tween 80
Solution.According to the Ministry of Public Health《Disinfection technology standard》2.1.2.10 is tested in (version in 2002).Cut the fabric 5cm of pollution ×
5cm is put into 10ml sample solutions as a control group.The fabric of residual contamination is soaked with the embodiment 1-7 dilution of lysate 3.3%
Bubble, 20min is acted on, taking-up, which is put into 10ml sample solutions, is used as experimental group, and eluent is lived after above-mentioned tested fabrics are eluted
Bacterium culture technique.Experiment is repeated 5 times.20 DEG C of test temperature.
Sterilization field tests of the embodiment 1-7 of table 5 to fabric natural bacteria
Embodiment 1-7 shows textile disinfecting experiment：1-7 of embodiment of the present invention hyperconcetration sterilization laundry sheet 3.3% is dilute
Release liquid, act on 20min, the average killing logarithm value to fabric natural bacteria is respectively 1.94,1.91,1.68,1.66,2.00,
1.84 and 1.74, the equal ＞ 1.50 of logarithm value is killed in each experiment, and sterilization is qualified, wherein the hyperconcetration sterilization laundry sheet of embodiment 5
3.3% dilution, 20min is acted on, to the average killing logarithm value highest of fabric natural bacteria, i.e., the laundry sheet that embodiment 5 is formulated
It is optimal to the killing effect of fabric natural bacteria.
The detergency that table 6 is 1-7 of the embodiment of the present invention contrasts with common commercial laundry powder, liquid detergent.It can be obtained by table 6
Go out：
The embodiment 1-7 of table 6 and liquid detergent, washing powder detergency compared with
For the pH value of laundry sheet closest to neutrality, the stimulation of opponent is minimum, active matter content highest, comparatively cleans identical
The usage amount of the clothing of weight is minimum, according to QB/T 1224-2012 (dress material washes agent by liquid), the water of 3.3% laundry sheet
Solution is compared with the detergency of standard liquid detergent, and the detergency to sebum greasy dirt cloth is 1.6, and the detergency to albumen soiled cotton is
1.5, the detergency to carbon black greasy dirt cloth is 1.2, is all higher than the detergency of standard liquid detergent, and phosphorus content is also minimum.3.3% this wash
The aqueous solution of garment piece is all higher than 90% to the sterilizing rate of Escherichia coli and staphylococcus aureus, can effectively sterilize.
Table 7 be 1-7 of embodiment of the present invention laundry sheets and commercial laundry powder under waiting quality condition under the equal aqueous solution
Dissolving situation contrast.As can be seen from Table 7：
The rate of dissolution contrast of the embodiment 1-7 of table 7 laundry sheet and commercial laundry powder
As can be seen from Table 7, also it is dissolved in no matter 1-7 of embodiment of the present invention laundry sheet is dissolved in hot water in cold water, shape
Into the aqueous solution be as clear as crystal, do not lump, in the absence of muddy thing；Laundry sheet in the hot water molten of the present invention simultaneously
Solve time average out to 22 seconds, dissolution velocity is arranged in the hot water for the dissolution time average out in cold water 53 seconds, wherein embodiment 1-7
Sequence is：The ＞ embodiments 3 of 57 ＞ embodiments of ＞ embodiment 1=embodiment 6 ＞ embodiments, 2 ＞ embodiments of embodiment 4；Wherein embodiment
1-7 dissolution velocities in cold water are ordered as：The ＞ embodiments of 7 ＞ embodiments of embodiment 5 ＞ embodiments, 1 ＞ embodiments, 6 ＞ embodiments 2
4 ＞ embodiments 3.
After raw material is well mixed by the laundry sheet of the present invention by mass fraction, film process are dried through oily heating, drying, cylinder
Turn into laundry detergent tablet afterwards, then laundry sheet is made in clipped, punching press and packaging and other steps.The thickness of finished product laundry sheet can reach
0.5-1.0mm, outer shape is generally 11 × 15mm rectangular patch, whole laundry sheet compact, is easy to carry, a piece of to wash
Garment piece can clean 5-6 part clothes, and active material is high, and dirt-removing power is strong.
Advantage of the invention is that：
1st, the thickness of laundry sheet of the invention is 0.5-1.0mm, small volume, is easy to carry and takes conveniently.
2nd, sterilization component containing natural plants, the aqueous solution of 3.3% laundry sheet to Escherichia coli, staphylococcus aureus and
The sterilizing rate of Candida albicans is all higher than 90%, meets health ministry《Disinfection technology standard》(2002 editions).
3rd, Phytoremediation composition and conventional surfactant compounding use, enhance clean result.Dirt-removing power is strong, according to
QB/T 1224-2012 (dress material washes agent by liquid), the aqueous solution of 0.1% laundry sheet and the detergency phase of standard liquid detergent
Than the detergency to sebum greasy dirt cloth is 1.6, and the detergency to albumen soiled cotton is 1.5, and the detergency to carbon black greasy dirt cloth is
1.2, it is all higher than the detergency of standard liquid detergent.
4th, not phosphorous, without fluorescent whitening agent, pH value is not hurt hands close to neutrality.
5th, it is transparent in the neutral i.e. dissolving of hot and cold water, dissolving rear solution.
Disclosed above is only several specific embodiments of the present invention, but the present invention is not limited to this, any this area
Technical staff can think change should all fall into protection scope of the present invention.
Claims (5)
1. laundry sheet is sterilized in a kind of hyperconcetration, it is characterised in that is made up of by weight percentage following component：
Film forming agent：5-10%；
Bactericide is in camphorated oil, eucalyptus oil, extract solution from aloe, ginger extract, galic essential oil, Blumea oil, tea oil
One or more：0.5-5%；
PCMX：1-2.5%；
Phytoremediation agent is the one or more in soapberry extract, Chinese honey locust extract solution, oil tea seed extract：1-5%；
Neopelex：10-30%；
Lauryl sodium sulfate：5-15%；
Aliphatic alcohol polyethenoxy (9) ether：5-10%；
Polyoxyethylene fatty alkyl ether sulfonate：1-5%；
Sodium silicate：5-10%；
Soda ash：10-20%；
Metal ion chelation agent：0.1-1%；
Essence：0.05-0.5%；
Pigment：0.001-0.005%；
Preservative：0.1-0.5%；
Deionized water：1-50%.
2. laundry sheet is sterilized in hyperconcetration according to claim 1, it is characterised in that film forming agent is polyethylene glycol, polyethylene
One or more in alcohol or polyvinylpyrrolidone.
3. laundry sheet is sterilized in hyperconcetration according to claim 1, it is characterised in that the metal ion chelation agent is second two
One or more in the sodium of amine tetraacethyl four, sodium citrate, disodium ethylene diamine tetraacetate, sodium gluconate.
4. laundry sheet is sterilized in hyperconcetration according to claim 1, it is characterised in that the preservative is methyl chloroisothiazole
One or more in quinoline ketone, methylisothiazolinone or DMDMH.
5. laundry sheet is sterilized in hyperconcetration according to claim 1, it is characterised in that hyperconcetration sterilizes laundry sheet and is in thickness
0.5-1.0mm sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710137758.3A CN106867727B (en) | 2017-03-09 | 2017-03-09 | Laundry sheet is sterilized in a kind of hyperconcetration |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710137758.3A CN106867727B (en) | 2017-03-09 | 2017-03-09 | Laundry sheet is sterilized in a kind of hyperconcetration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106867727A CN106867727A (en) | 2017-06-20 |
| CN106867727B true CN106867727B (en) | 2018-03-27 |
Family
ID=59170147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710137758.3A Active CN106867727B (en) | 2017-03-09 | 2017-03-09 | Laundry sheet is sterilized in a kind of hyperconcetration |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106867727B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674791A (en) * | 2017-09-15 | 2018-02-09 | 安徽科技学院 | A kind of solid-state sustained release Bactericidal cleaner and preparation method thereof |
| CN107441001B (en) * | 2017-09-22 | 2019-01-15 | 湖南和思生物科技有限公司 | A method of hand cleanser is prepared using ginger and camellia seed |
| CN107828520A (en) * | 2017-10-30 | 2018-03-23 | 佛山科学技术学院 | A kind of Chinese herbal medicine water-soluble laundry washing piece and preparation method thereof |
| CN108004042A (en) * | 2017-12-25 | 2018-05-08 | 中盐东兴盐化股份有限公司 | A kind of white Antibacterial laundry detergent of salt |
| CN108531309A (en) * | 2018-05-21 | 2018-09-14 | 李均辉 | A kind of color protection eliminates the unusual smell liquid detergent and its preparation method and application |
| CN109234043B (en) * | 2018-09-13 | 2020-10-16 | 威莱(广州)日用品有限公司 | Washing fragrance retaining bead and preparation method thereof |
| CN109468179A (en) * | 2018-11-05 | 2019-03-15 | 青岛美洁尔智能科技有限公司 | A kind of solidifying pearl of doing washing |
| CN110144268A (en) * | 2019-06-10 | 2019-08-20 | 刘小珍 | A kind of underwear laundry sheet containing potato ferment |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999028432A1 (en) * | 1997-12-01 | 1999-06-10 | Precision Fabrics Group, Inc. | Laundry compositions having antistatic and fabric softening properties, and laundry detergent sheets containing the same |
| CN105886145A (en) * | 2016-06-01 | 2016-08-24 | 茗燕生物科技(上海)有限公司 | Super-concentrated washing piece and preparation method thereof |
| CN106236625A (en) * | 2016-08-03 | 2016-12-21 | 阿布都 | A kind of cleanser compositions |
-
2017
- 2017-03-09 CN CN201710137758.3A patent/CN106867727B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999028432A1 (en) * | 1997-12-01 | 1999-06-10 | Precision Fabrics Group, Inc. | Laundry compositions having antistatic and fabric softening properties, and laundry detergent sheets containing the same |
| CN105886145A (en) * | 2016-06-01 | 2016-08-24 | 茗燕生物科技(上海)有限公司 | Super-concentrated washing piece and preparation method thereof |
| CN106236625A (en) * | 2016-08-03 | 2016-12-21 | 阿布都 | A kind of cleanser compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106867727A (en) | 2017-06-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106867727B (en) | Laundry sheet is sterilized in a kind of hyperconcetration | |
| CN101787334B (en) | Pesticide residue removing and sterilizing detergent | |
| Pankey et al. | Uptake on postmilking teat antisepsis | |
| US6375976B1 (en) | Multi-purpose acid compositions | |
| DE60111725T2 (en) | PERCARBONIC ACID COMPOSITIONS AND USES AGAINST MICROBIAL SPORTS | |
| CN109169653B (en) | Cation composite disinfectant and application thereof | |
| CN101160054B (en) | Acidified chlorite disinfectant compositions with olefin stabilizers | |
| US7439218B2 (en) | Disinfectant compositions comprising an orange oil mixture and methods of use thereof | |
| US6951833B2 (en) | Anti-microbial compositions | |
| CN111518635A (en) | Composite long-acting disinfection and bacteriostasis cleaning agent for medical textiles and preparation method thereof | |
| WO2011044916A1 (en) | Multipurpose eco-friendly disinfecting composition comprising nano size antibacterial agent | |
| CN106190639A (en) | A kind of cleaning agent | |
| CN102894001A (en) | Antiseptic and mildew inhibitor composition for wet tissues and production method thereof | |
| EP3015538A1 (en) | Disinfectant and/or cleaning article, use thereof and method for disinfecting and/or cleaning surfaces, tools and/or instruments | |
| CN108359543A (en) | The aerobic foam washing compound powder of environment-friendly highly efficient decontamination that safe pro-skin, profession are sterilized | |
| CN106520400A (en) | Quick dissolving low-irritation laundry sheet | |
| CH703870A2 (en) | Disinfecting cleaning composition. | |
| CN111575128A (en) | Antibacterial laundry detergent and preparation method thereof | |
| CN103215146A (en) | Liquid clothes detergent added with natural citrus extract | |
| CN101006790A (en) | Refined iodine disinfectant liquor | |
| CN107699377A (en) | A kind of non-toxic, multifunctional cleaning agent non-stimulated to skin and eyes, environmentally safe safe to the human body | |
| CN106675893A (en) | Underwear soap and preparation method thereof | |
| CN113073015B (en) | Sterilization and deodorization laundry detergent for pets and preparation method thereof | |
| WO2023144400A1 (en) | Antimicrobial indicator composition | |
| CN110982629A (en) | Antibacterial fabric detergent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |