CN104974864A - Multifunctional laundry gel bead and preparation method thereof - Google Patents
Multifunctional laundry gel bead and preparation method thereof Download PDFInfo
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- CN104974864A CN104974864A CN201510437124.0A CN201510437124A CN104974864A CN 104974864 A CN104974864 A CN 104974864A CN 201510437124 A CN201510437124 A CN 201510437124A CN 104974864 A CN104974864 A CN 104974864A
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- pearl
- triclosan
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Abstract
The invention provides a multifunctional laundry gel bead which comprises the following components in percentage by weight: 30-35% of sodium C14-16 olefinsulfonate, 15-20% of fatty alcohol polyethenoxy ether (9EO), 10-12% of dodecylbenzene sulfonic acid, 5-8% of cationic alkyl polyglycoside, 0.01-0.03% of disodium edetate, 1-2% of D-panthenol, 0.3-0.7% of phenoxyethanol, 0.1-0.3% of essence, 0.05-0.1% of triclosan, 0.01-0.03% of proteinase and the balance of deionized water. The invention also provides a preparation method of the multifunctional laundry gel bead. The product has the multiple effects of laundering, caring, sterilization, deodorization and delighting, has the advantages of energy saving and emission reduction, and is convenient to use.
Description
Technical field
The present invention relates to detergent applications, particularly relate to a kind of multifunctional laundry and coagulate pearl, the invention still further relates to the preparation method that above-mentioned multifunctional laundry coagulates pearl.
Background technology
Traditional washing liquid main active substances is linear dodecylbenzene sulfonate and other washing assistants; Linear dodecylbenzene sulfonate derives from petroleum chemicals, belongs to non-renewable raw material, and the not resistance to hard water of this raw material, under tap water environment, detersive power reduces greatly, is unfavorable for washing; Other auxiliary agents, 4A zeolite, to contain phosphorus, are unfavorable for environment protection as tripoly phosphate sodium STPP; Aluminium, soda ash, caustic soda alkalescence are higher, easily make clothing fade, damaging laundry; Saltcake belongs to weighting material, and inefficient cycle utilizes, and can bring unnecessary waste to operation.In addition, conventional liquid detergent utilizes conventional surfactants and alkaline assistant, only has washing cleaning action, submissive less effective.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of multifunctional laundry to coagulate pearl, there is washing, nursing, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, energy-saving and emission-reduction, easy to use, there is the superstrong pollution-removing of washing clothes and clean function, successful.
The invention allows for the preparation method that above-mentioned multifunctional laundry coagulates pearl.
For solving the problems of the technologies described above, technology of the present invention by the following technical solutions:
A kind of multifunctional laundry coagulates pearl, and its weight percent composition comprises: C14-16 alkene sulfonic acid sodium 30-35%, fatty alcohol-polyoxyethylene ether (9EO) 15-20%, Witco 1298 Soft Acid 10-12%, kation alkyl polysaccharide glycosides 5-8%, disodium ethylene diamine tetraacetate 0.01-0.03%, D-panthenol 1-2%, Phenoxyethanol 0.3-0.7%, essence 0.1-0.3%, triclosan 0.05-0.1%, proteinase-10 .01-0. 03%, surplus are deionized water.
Multifunctional laundry coagulates a preparation method for pearl, comprises the steps:
(1) deionized water, disodium ethylene diamine tetraacetate, C14-16 alkene sulfonic acid sodium, fatty alcohol-polyoxyethylene ether (9EO), Witco 1298 Soft Acid, kation alkyl polysaccharide glycosides are added in reactor be according to the above ratio successively heated with stirring to 75-85 DEG C, and stirring and dissolving is to transparent in particle, is incubated and carries out froth breaking in 30 minutes;
(2) after being cooled to 40 DEG C, in reactor, add D-panthenol, Phenoxyethanol, essence, triclosan, proteolytic enzyme successively, stir to transparent without particle;
(3a) sample censorship, recording pH value is that 7-8 is qualified discharging;
(4) the solidifying pearl product of laundry is made with polyvinyl alcohol water soluble film parcel.
As preferably, also comprise step (3b) stability test, 48 DEG C, 45 DEG C, 40 DEG C, illumination ,-15 DEG C, 0 DEG C, 5 DEG C, test one month under normal temperature condition.
The beneficial effect that the present invention compared with prior art has is: the present invention adopts Novel Cationic Surfactants APG, composite other conventional anion surfactant, nonionogenic tenside and amphotericses, liquid protease, triclosan, volatile oil, product of the present invention is made to have washing, nursing, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, energy-saving and emission-reduction, easy to use, there is the superstrong pollution-removing of washing clothes and clean function, successful.
Embodiment
For the understanding the present invention making those skilled in the art more clear and intuitive, below the present invention is further illustrated.
alkene sulfonic acid sodium(English name Sodium C14-16 Olefin Sulfonate) is a kind of anion surfactant-sulfonate.
Character: outward appearance: (1), liquid; (2), white or pale yellow powder.
Solvability: water-soluble.
Stability: stable.
Dangerous: there is pungency.Skin, eyes are had to the pungency of medium tenacity.Pungency is lower than alkylbenzene sulfonate.
Ecological: may harm to be had to environment, should pay special attention to water body.
Biological degradability: degradable.
Characteristic: have good decontamination, foaming, wetting, dispersion, emulsifying property, acid resistance is strong.
fatty alcohol-polyoxyethylene ether (9EO):nonionogenic tenside.
Product performance:
(1) there is excellent wetting, emulsification, penetrating quality,
(2) biological degradability is good,
(3) good scourability is had,
(4) can with negatively charged ion, amphoterics compatibility.
witco 1298 Soft Acid: Witco 1298 Soft Acid (C
18h
30o
3s), linear alkylbenzene, ten DAADBSA are also called; Be a kind of anion surfactant, be commonly used for the raw material of various washing composition or be used for producing linear alkylbenzene sulphonic acid salt, ammonium salt and ethanolamine salt, also can be used as the curing catalysts of amine baking varnish.
Molten point: 10 DEG C
Boiling point: 315 DEG C
Brown viscous liquid.Generate kelene by dewaxing by molecular sieve oil with chlorine reaction, then synthesize dodecylbenzene with benzene condensation, alkylbenzene oleum is sulphur vulcanization obtains dodecyl phenyl-hydrogen-sulfate, can be used as the curing catalysts of amine baking varnish.
kation alkyl polysaccharide glycosides: alkyl glycoside, APG for short, synthesized by renewable resources natural fat alcohol and glucose, it is the more comprehensive new non-ionic surfactants of a kind of performance, have the characteristic of conventional nonionic and anion surfactant concurrently, having high surface, good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surfactant.
Performance characteristics:
Compatibility is good, can with various ionic, the composite generation synergism of nonionic surface active agent;
Whipability is good, and foaming abundancy is fine and smooth;
Solvability is good, resistance to highly basic and ionogen, has good thickening capabilities;
Good with skin intermiscibility, significantly improve the mildness of formula, nontoxic, non-stimulated, readily biodegradable.
disodium ethylene diamine tetraacetate: disodium ethylene diamine tetraacetate is called EDTA-2Na again, and be a kind of good Synergist S-421 95 in chemistry, it has six ligating atoms, and the title complex of formation is called huge legendary turtle compound, and EDTA often uses in complexometric titration, is generally the content measuring metal ion.EDTA has important use dyestuff, food, medicine etc. are industrial.
Feature:
1. EDTA has ligancy widely, almost can form stable inner complex with all metal ions.
Favourable part: provide the possibility (being better than soda acid, the precipitator method) extensively measuring element.
2. the M-EDTA coordination ratio overwhelming majority of EDTA and formation is 1:1.
3. inner complex is most of electrically charged, therefore can be water-soluble, and be swift in response CASNo.:6381-92-6.
panthenol: the precursor being vitamin B5, therefore also known as dexpanthenol, it contains the D-panthenol being no less than 98% content, it is a kind of colourless liquid to micro-yellow transparent thickness, the special odor that tool is slight.
D-panthenol (99%) should be stored in shady and cool dry storehouse, all insensitive to light, oxygen and heavy metal, is stable water-soluble additive
phenoxyethanol: Phenoxyethanol, be medicine name, English name is: Phenoxyethanol, and Chinese name is again two phenoxyethyl alcohols, phenoxyethyl alcohol etc., and molecular formula is: C
8h
10o
2, Phenoxyethanol belongs to organic synthesis thing, is slightly with viscous liquid for colourless, micro-perfume (or spice), puckery.
Phenoxyethanol can be formed by ethylene glycol and menthylphenoxypolyethoxy ethanol, is common in protective skin cream and sunscreen.Phenoxyethanol is a kind of colourless oily liquids, has antibiotic effect, is used as having the substitute of the sodiumazide of severe toxicity in biological buffered soln of being everlasting, because the toxicity of 2-Phenoxyethanol is lower, and chemically to copper and plumbous and inactive.Usually the function of sanitas is played in makeup, vaccine and medicine.
triclosan: triclosan, formal name used at school " triclosan ", chemical molecular formula is C
12h
7c
l3o
2, have another name called " triclosan ", " Triclosan " etc., triclosan normality is white or canescence crystalline powder, slightly phenol stink.Water insoluble, be soluble in alkali lye and organic solvent, triclosan is a kind of broad spectrum antimicrobicide.
Solubleness: be slightly soluble in water, in diluted alkaline, solubleness is moderate, in a lot of organic solvent, have higher solubleness, can be made into transparent concentrated liquid product after dissolving in water-soluble solvent or tensio-active agent;
Stability: there is excellent package stability: less than 280-290 DEG C can not be decomposed rapidly; 200 DEG C are heated 14 hours, only have 2% active substance to decompose, even under long-time UV-irradiation, only have slight decomposition.Its solution is to acid, alkali tool stability.
Volatility: the volatility that tool is very low, micro-tool aromatising flavour.
Fundamental characteristics:
The first, the high purity white powder of fragrant, is not infected with product and skin.
The second, be dissolved in multiple organic solvent and tensio-active agent.
3rd, to strong acid and strong base and heat, there is high stability.
4th, kill widely and restraining effect causing infection or pathogenicity bo Gram positive mattress, true mattress, yeast and virus (as first, hepatitis B, rabies virus, virus of AIDS HTV) etc. all to have.
5th, to no skin irritation.
6th, antagonism antibiotic bacterium and non-anti-antibiotic bacterium effective equally.
proteolytic enzyme: the bloodstain on clothing and albumen dirt can be removed, strengthen clothes cleaning speed and efficiency.
The present invention not only has ordinary liquid laundry detergent a little, and surfactant content is more than 55%, adds again kation alkyl polysaccharide glycosides, better effects if.Triclosan, proteolytic enzyme, make that product has highly enriched, low cost, use is easy to clean, cleaning capacity is strong, gentleness does not hinder hand and clothing and adopt Japanese import polyvinyl alcohol water soluble film to make the solidifying pearl of laundry, convenient to use, noresidue, one time one, therefore the present invention has washing, smelly eliminating, sterilization, pleasant mental and body, the multi-efficiency such as easy to use concurrently.
Embodiment 1
A kind of multifunctional laundry coagulates pearl, and its weight percent composition comprises: C14-16 alkene sulfonic acid sodium 32%, fatty alcohol-polyoxyethylene ether (9EO) 17%, Witco 1298 Soft Acid 11%, kation alkyl polysaccharide glycosides 6.5%, disodium ethylene diamine tetraacetate 0.02%, D-panthenol 1.5%, Phenoxyethanol 0.5%, essence 0.2%, triclosan 0.07%, proteinase-10 .02%, surplus are deionized water.
Embodiment 2
A kind of multifunctional laundry coagulates pearl, and its weight percent composition comprises: C14-16 alkene sulfonic acid sodium 30%, fatty alcohol-polyoxyethylene ether (9EO) 15%, Witco 1298 Soft Acid 10%, kation alkyl polysaccharide glycosides 5%, disodium ethylene diamine tetraacetate 0.01%, D-panthenol 1%, Phenoxyethanol 0.3%, essence 0.1%, triclosan 0.05%, proteinase-10 .01%, surplus are deionized water.
Embodiment 3
A kind of multifunctional laundry coagulates pearl, and its weight percent composition comprises: C14-16 alkene sulfonic acid sodium 35%, fatty alcohol-polyoxyethylene ether (9EO) 20%, Witco 1298 Soft Acid 12%, kation alkyl polysaccharide glycosides 8%, disodium ethylene diamine tetraacetate 0.03%, D-panthenol 2%, Phenoxyethanol 0.7%, essence 0.3%, triclosan 0.1%, proteinase-10. and 03%, surplus is deionized water.
Embodiment 4
A kind of multifunctional laundry coagulates pearl preparation method, comprises the steps:
(1) deionized water, disodium ethylene diamine tetraacetate, C14-16 alkene sulfonic acid sodium, fatty alcohol-polyoxyethylene ether (9EO), Witco 1298 Soft Acid, kation alkyl polysaccharide glycosides are added in reactor successively in the ratio in embodiment 1 ~ 3 be heated with stirring to 75-85 DEG C, and stirring and dissolving is to transparent in particle, is incubated and carries out froth breaking in 30 minutes;
(2) after being cooled to 40 DEG C, in reactor, add D-panthenol, Phenoxyethanol, essence, triclosan, proteolytic enzyme successively, stir to transparent without particle;
(3a) sample censorship, recording pH value is that 7-8 is qualified discharging;
(3b) stability test, 48 DEG C, 45 DEG C, 40 DEG C, illumination ,-15 DEG C, 0 DEG C, 5 DEG C, test one month under normal temperature condition.
(4) the solidifying pearl product of laundry is made with polyvinyl alcohol water soluble film parcel.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (3)
1. a multifunctional laundry coagulates pearl, it is characterized in that, its weight percent composition comprises: C14-16 alkene sulfonic acid sodium 30-35%, fatty alcohol-polyoxyethylene ether (9EO) 15-20%, Witco 1298 Soft Acid 10-12%, kation alkyl polysaccharide glycosides 5-8%, disodium ethylene diamine tetraacetate 0.01-0.03%, D-panthenol 1-2%, Phenoxyethanol 0.3-0.7%, essence 0.1-0.3%, triclosan 0.05-0.1%, proteinase-10 .01-0. 03%, surplus is deionized water.
2. multifunctional laundry according to claim 1 coagulates the preparation method of pearl, it is characterized in that: comprise the steps:
(1) deionized water, disodium ethylene diamine tetraacetate, C14-16 alkene sulfonic acid sodium, fatty alcohol-polyoxyethylene ether (9EO), Witco 1298 Soft Acid, kation alkyl polysaccharide glycosides are added in reactor be according to the above ratio successively heated with stirring to 75-85 DEG C, and stirring and dissolving is to transparent in particle, is incubated and carries out froth breaking in 30 minutes;
(2) after being cooled to 40 DEG C, in reactor, add D-panthenol, Phenoxyethanol, essence, triclosan, proteolytic enzyme successively, stir to transparent without particle;
(3a) sample censorship, recording pH value is that 7-8 is qualified discharging;
(4) the solidifying pearl product of laundry is made with polyvinyl alcohol water soluble film parcel.
3. multifunctional laundry according to claim 2 coagulates the preparation method of pearl, it is characterized in that: also comprise step (3b) stability test, 48 DEG C, 45 DEG C, 40 DEG C, illumination ,-15 DEG C, 0 DEG C, 5 DEG C, test one month under normal temperature condition.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318666A (en) * | 2016-08-23 | 2017-01-11 | 余姚市德派日用品有限公司 | Infant clothing laundry condensate bead and preparing method thereof |
| CN106318667A (en) * | 2016-08-23 | 2017-01-11 | 余姚市德派日用品有限公司 | Excellent bactericidal washing laundry condensate bead and preparing method thereof |
| CN106350244A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Domestic cleaner and preparation method thereof |
| CN106436295A (en) * | 2016-08-23 | 2017-02-22 | 余姚市德派日用品有限公司 | Fabric softener and preparation method thereof |
| CN106833996A (en) * | 2017-01-05 | 2017-06-13 | 广州品圣洗涤用品有限公司 | A kind of single-chamber of chamber film stabilization or the liquid detergent of multi-cavity packaging |
| CN106867711A (en) * | 2017-03-03 | 2017-06-20 | 广州市南大实业有限公司 | A kind of solidifying pearl of degerming laundry and preparation method and application |
| JP2018039864A (en) * | 2016-09-05 | 2018-03-15 | ライオン株式会社 | Detergent composition for clothing |
| CN108192778A (en) * | 2017-10-19 | 2018-06-22 | 成都孚吉科技有限责任公司 | Pearl and preparation method are coagulated in a kind of nontoxic, non-stimulated laundry |
| CN109481133A (en) * | 2018-09-21 | 2019-03-19 | 珠海国佳新材股份有限公司 | A kind of shield brain temperature-sensitive coagulates pearl medical gel patch and preparation method |
| CN111040894A (en) * | 2019-12-31 | 2020-04-21 | 杨姗 | Mini laundry gel bead and preparation method thereof |
| CN111088129A (en) * | 2018-10-23 | 2020-05-01 | 中国石油化工股份有限公司 | Detergent coagulated bead containing thermoplastic polyvinyl alcohol film and preparation method thereof |
| US11312922B2 (en) | 2019-04-12 | 2022-04-26 | Ecolab Usa Inc. | Antimicrobial multi-purpose cleaner comprising a sulfonic acid-containing surfactant and methods of making and using the same |
| CN115404137A (en) * | 2022-09-23 | 2022-11-29 | 深圳市减化生物科技有限公司 | Washing gel bead and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1426454A (en) * | 2000-04-28 | 2003-06-25 | 宝洁公司 | Pouched compositions |
| CN1426456A (en) * | 2000-04-28 | 2003-06-25 | 宝洁公司 | Pouched compositions |
| CN1444644A (en) * | 2000-07-24 | 2003-09-24 | 宝洁公司 | Articles containing enclosed compositions |
| CN103275829A (en) * | 2013-06-17 | 2013-09-04 | 纳爱斯集团有限公司 | Solvent-free super-concentrated liquid detergent and preparation method thereof |
-
2015
- 2015-07-23 CN CN201510437124.0A patent/CN104974864A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1426454A (en) * | 2000-04-28 | 2003-06-25 | 宝洁公司 | Pouched compositions |
| CN1426456A (en) * | 2000-04-28 | 2003-06-25 | 宝洁公司 | Pouched compositions |
| CN1444644A (en) * | 2000-07-24 | 2003-09-24 | 宝洁公司 | Articles containing enclosed compositions |
| CN103275829A (en) * | 2013-06-17 | 2013-09-04 | 纳爱斯集团有限公司 | Solvent-free super-concentrated liquid detergent and preparation method thereof |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318667A (en) * | 2016-08-23 | 2017-01-11 | 余姚市德派日用品有限公司 | Excellent bactericidal washing laundry condensate bead and preparing method thereof |
| CN106350244A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Domestic cleaner and preparation method thereof |
| CN106436295A (en) * | 2016-08-23 | 2017-02-22 | 余姚市德派日用品有限公司 | Fabric softener and preparation method thereof |
| CN106318666A (en) * | 2016-08-23 | 2017-01-11 | 余姚市德派日用品有限公司 | Infant clothing laundry condensate bead and preparing method thereof |
| JP2018039864A (en) * | 2016-09-05 | 2018-03-15 | ライオン株式会社 | Detergent composition for clothing |
| CN106833996B (en) * | 2017-01-05 | 2020-04-21 | 广东优凯科技有限公司 | Single-cavity or multi-cavity packaged liquid detergent with stable cavity film |
| CN106833996A (en) * | 2017-01-05 | 2017-06-13 | 广州品圣洗涤用品有限公司 | A kind of single-chamber of chamber film stabilization or the liquid detergent of multi-cavity packaging |
| CN106867711A (en) * | 2017-03-03 | 2017-06-20 | 广州市南大实业有限公司 | A kind of solidifying pearl of degerming laundry and preparation method and application |
| CN108192778B (en) * | 2017-10-19 | 2020-06-30 | 成都孚吉科技有限责任公司 | Non-toxic and non-irritant washing gel bead and preparation method thereof |
| CN108192778A (en) * | 2017-10-19 | 2018-06-22 | 成都孚吉科技有限责任公司 | Pearl and preparation method are coagulated in a kind of nontoxic, non-stimulated laundry |
| CN109481133A (en) * | 2018-09-21 | 2019-03-19 | 珠海国佳新材股份有限公司 | A kind of shield brain temperature-sensitive coagulates pearl medical gel patch and preparation method |
| CN111088129A (en) * | 2018-10-23 | 2020-05-01 | 中国石油化工股份有限公司 | Detergent coagulated bead containing thermoplastic polyvinyl alcohol film and preparation method thereof |
| US11312922B2 (en) | 2019-04-12 | 2022-04-26 | Ecolab Usa Inc. | Antimicrobial multi-purpose cleaner comprising a sulfonic acid-containing surfactant and methods of making and using the same |
| US11891586B2 (en) | 2019-04-12 | 2024-02-06 | Ecolab Usa Inc. | Highly acidic antimicrobial multi-purpose cleaner and methods of making and using the same |
| CN111040894A (en) * | 2019-12-31 | 2020-04-21 | 杨姗 | Mini laundry gel bead and preparation method thereof |
| CN115404137A (en) * | 2022-09-23 | 2022-11-29 | 深圳市减化生物科技有限公司 | Washing gel bead and preparation method thereof |
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Application publication date: 20151014 |