CN101368147B - Neat soap washing powder and preparing technique thereof - Google Patents
Neat soap washing powder and preparing technique thereof Download PDFInfo
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- CN101368147B CN101368147B CN200810079337A CN200810079337A CN101368147B CN 101368147 B CN101368147 B CN 101368147B CN 200810079337 A CN200810079337 A CN 200810079337A CN 200810079337 A CN200810079337 A CN 200810079337A CN 101368147 B CN101368147 B CN 101368147B
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Abstract
The invention relates to a household chemicals manufacturing technique, in particular to a genuine soap washing-powder manufacturing technique, which solves the problems of no hard water tolerance, low solubility and weak detergency caused by sodium stearate added into the powder in the genuine soap washing-powder of the prior art. The weight percentages of integrants comprised in the genuine soap washing-powder are 5-30 portions of surface active agent, 2-40 portions of eunatrol, 20-70 portions of washing auxiliary detergent, 0.1-10 portions of auxiliary material and 5-50 portions of sodium sulfate used as plugging compound. Different manufacturing techniques are applied for adding the oleic acid or eunatrol into the washing-powder. The invention has the advantages of strong detergency, no skin irritation, no environment pollution, simple application, easy manufacturing, environment protection, high efficiency and low production cost.
Description
Technical field
The present invention relates to a kind of production technology of household chemicals, be specially a kind of Neat soap washing powder and production technique thereof.
Background technology
Prescription characteristics, technical requirements, production cost and washing habits according to washing powder; The tensio-active agent that adopts in the existing washing powder is the derived product of petrochemical complex mostly; Along with riseing of oil price, the price of this type of tensio-active agent also rises steadily, and makes the cost of washing powder skyrocketing; Domestic people adopt the custom of cold water washing mostly simultaneously, and the effect of this type of tensio-active agent is loss to some extent under the cold water condition.Domestic a lot of soap base class washing powder adopts in the StNa adding system mostly; There is not anti-hard water; The characteristics of poorly soluble, detersive power difference, simultaneously to the having relatively high expectations of equipment, but Neat soap washing powder is the cleaning product of one type of natural, green, environmental protection; The human consumer makes once downhearted soap powder to the pursuit of safety and environmental protection, become the focus of chasing on the daily necessities market in recent years.The decontamination principle of soap powder is with the soap basically identical, its physical property pure natural, and low irritant has also kept the good detersive power of soap simultaneously, makes fabric keep fluffy softness after the washing, and foam is lower when washing simultaneously, is fit to the trend of environmental protection and energy saving.What remember Chinese honey locust in fact the earliest is the flourishing Germany of science and technology unexpectedly, and according to the sound of Germany, one Chinese honey locust heat is just being risen in Germany now.Because in fact as ancient washing composition, be its nontoxic pollution-free pure natural on the one hand, factor is raw-material rise in price on the other hand, makes us seek the product of more economical material benefit.Along with the enhancing of human consumer's environmental consciousness, will further promote the development of soap powder to the pursuit of green product, simultaneously along with the international petroleum price increase, the competitive power of soap powder will progressively embody, and produce soap base type washing powder and progressively replace present petroleum base washing powder.
Summary of the invention
The present invention adopts mostly and causes not anti-hard water in the StNa adding system in order to solve the soap base class washing powder that exists in the prior art, problem such as poorly soluble, detersive power difference and a kind of Neat soap washing powder and production technique thereof are provided.
The present invention is a kind of Neat soap washing powder of being realized by following technical scheme, forms by the raw material of following weight ratio example,
5～30 parts in tensio-active agent, 2～40 parts of sodium oleates, 20～70 parts of washing auxiliary detergents, 0.1～10 part of auxiliary material, 5～50 parts in stopping composition sodium sulfate, all raw materials mix powder process get final product.
Tensio-active agent is AS or nonionogenic tenside or the mixing of the two.
AS is: any one in X 2073 LAS or α-sodium olefin sulfonate AOS or ethoxylated alkyl sulfate AES or the C10-24 fatty acid soaps or two kinds and two or more combinations.
Nonionogenic tenside is: any one of AEO AE0-9 or AEO AE0-7 or two kinds and two or more combinations.
The conventional sodium oleate product in sodium oleate existing market or undertaken by oleic acid and sodium hydroxide in back gained.
Auxiliary agent is any one perhaps two kinds and the two or more combination in yellow soda ash, tripoly phosphate sodium STPP, laminated crystal of sodium disilicate, zeolite, Trisodium Citrate, water glass, Starso, paratoluenesulfonic acid sodium salt, Sodium peroxoborate, the SPC-D.
Auxiliary material is any one perhaps two kinds and the two or more combination in CMC 99.5, high molecular polymer, whitening agent, essence, the proteolytic enzyme.
Production technique is three kinds:
1) conventional high tower powder injection process: AS and oleic acid and sodium hydroxide or sodium oleate, washing auxiliary detergent and partial supplementary material (CMC 99.5, high molecular polymer, whitening agent) and sodium sulfate are processed slip by prescription; Spraying drying then; And cool aging, again thermo-sensitivity auxiliary material (essence, proteolytic enzyme) and nonionogenic tenside are promptly got the finished product by the prescription adding.
2) the attached polymer molding production technique: AS (LAS, AOS, AES, C10-24 fatty acid soaps), nonionogenic tenside (AEO-9, AEO-7), sodium oleate, washing auxiliary detergent, partial supplementary material (CMC 99.5, high molecular polymer, whitening agent) and sodium sulfate are directly mixed by the Recipe requirement, and thorough mixing evenly back adding thermo-sensitivity auxiliary material (essence and proteolytic enzyme) gets final product.
3) Combex technology (high tower dusts and the attached polymer molding combines): at first according to the prescription requirement; AS (LAS, AOS, AES, C10-24 fatty acid soaps) and oleic acid and sodium hydroxide or sodium oleate, washing auxiliary detergent and partial supplementary material (CMC 99.5, high molecular polymer, whitening agent) and stopping composition sodium sulfate are processed slip by prescription; Spraying drying, and cool aging then.Next gets the umber that prescription requires with the original washing powder of the washing powder of gained; Require to take by weighing nonionogenic tenside (AEO-9, AEO-7), sodium oleate, washing auxiliary detergent, stopping composition sodium sulfate by directly mixing of Recipe requirement according to prescription again, the even back of thorough mixing adds thermo-sensitivity auxiliary material (essence, proteolytic enzyme) and gets final product.
Method for testing performance is:
Detersive power, anti-performance of hard water and solubility property are mainly investigated in the over-all properties contrast, and concrete working method is following: 1, detergency ability
Concrete grammar: carry out with the step in the mensuration of washing composition detersive power and anti-soil stain deposition capability with reference to the GB/T13174-2003 dress material.
2, anti-performance of hard water
Working method: accurately prepare 0.5% Neat soap washing powder solution 100mL, pipette 10mL and zero(ppm) water 50mL and place 100mL tool plug graduated cylinder, in 40 ± 1 ℃ water bath with thermostatic control, place 10min; Take out adding 2500ppm hard water 0.5mL, spin upside down 20 times, leave standstill 30 seconds observation liquid and have or not cotton-shaped suspended substance; When if solution system is translucent homogeneous system, continue to add 2500ppm hard water, add 0.5mL at every turn; Repeat above operation, flocculent suspended in system, record 2500ppm hard water add-on; Add-on is big more, and the resistance to hard water of expression Neat soap washing powder is strong more.
3, solubility property
Deliquescent mensuration mainly is to judge through the full particle in the mensuration system, and concrete grammar is: with adding the 1000ml tap water in the 2L beaker, take by weighing 2.5g washing powder sample, pour in the beaker, on magnetic agitation, stirred 2.5 minutes.Solution is crossed 18 mesh sieves, and the macrobead on the sieve is full particle.
Adopt safety, environmental protection in the washing powder, the plant soap base is as the tensio-active agent of novel renewable resources efficiently; The washing powder detersive power is strengthened; Become the daily use chemicals cleaning product of more natural and safe environmental protection, human body skin is not produced stimulation, environment is not produced pollution.Product uses simple, and is easily manufactured, environment-friendly high-efficiency, and production cost is low, is fit to multiple washing powder explained hereafter.
Embodiment
Embodiment 1, a kind of Neat soap washing powder is characterized in that: the raw material by the following weight ratio example is formed,
5 parts in tensio-active agent, 40 parts of sodium oleates, 20 parts of washing auxiliary detergents, 10 parts of auxiliary materials, 5 parts in stopping composition sodium sulfate.
Used tensio-active agent is anionic surfactant sodium dodecylbenzene sulfonate LAS, α-sodium olefin sulfonate AOS, ethoxylated alkyl sulfate AES, C10-24 fatty acid soaps and nonionogenic tenside AEO AEO-9, AEO AEO-7 any one perhaps two kinds and two or more combination wherein.
Used sodium oleate is back gained in being undertaken by oleic acid and sodium hydroxide.
Washing auxiliary detergent is any one perhaps two kinds and the two or more combination in yellow soda ash, tripoly phosphate sodium STPP, laminated crystal of sodium disilicate, zeolite, Trisodium Citrate, water glass, Starso, paratoluenesulfonic acid sodium salt, Sodium peroxoborate, the SPC-D.
Auxiliary material is any one perhaps two kinds and the two or more combination in CMC 99.5, high molecular polymer, whitening agent, essence, the proteolytic enzyme.
Working method is conventional high tower powder injection process, the attached polymer molding production technique, any in Combex technology (high tower dust with the attached polymer molding combine) technology.
Embodiment 2, a kind of Neat soap washing powder is characterized in that: the raw material by the following weight ratio example is formed, and umber is represented
30 parts in tensio-active agent, 2 parts of sodium oleates, 70 parts of washing auxiliary detergents, 0.1 part of auxiliary material, 50 parts in stopping composition sodium sulfate
Used tensio-active agent is anionic surfactant sodium dodecylbenzene sulfonate LAS, α-sodium olefin sulfonate AOS, ethoxylated alkyl sulfate AES, C10-24 fatty acid soaps and nonionogenic tenside AEO AEO-9, AEO AEO-7 any one perhaps two kinds and two or more combination wherein.
Used sodium oleate is back gained in being undertaken by oleic acid and sodium hydroxide.
Washing auxiliary detergent is any one perhaps two kinds and the two or more combination in yellow soda ash, tripoly phosphate sodium STPP, laminated crystal of sodium disilicate, zeolite, Trisodium Citrate, water glass, Starso, paratoluenesulfonic acid sodium salt, Sodium peroxoborate, the SPC-D.
Auxiliary material is any one perhaps two kinds and the two or more combination in CMC 99.5, high molecular polymer, whitening agent, essence, the proteolytic enzyme.
Working method is conventional high tower powder injection process, the attached polymer molding production technique, any in Combex technology (high tower dust with the attached polymer molding combine) technology.
Embodiment 3, a kind of Neat soap washing powder is characterized in that: the raw material by the following weight ratio example is formed, and umber is represented
20 parts in tensio-active agent, 25 parts of sodium oleates, 45 parts of washing auxiliary detergents, 5 parts of auxiliary materials, 30 parts in stopping composition sodium sulfate,
Used tensio-active agent is anionic surfactant sodium dodecylbenzene sulfonate LAS, α-sodium olefin sulfonate AOS, ethoxylated alkyl sulfate AES, C10-24 fatty acid soaps and nonionogenic tenside AEO AEO-9, AEO AEO-7 any one perhaps two kinds and two or more combination wherein.
Used sodium oleate is back gained in being undertaken by oleic acid and sodium hydroxide.
Washing auxiliary detergent is any one perhaps two kinds and the two or more combination in yellow soda ash, tripoly phosphate sodium STPP, laminated crystal of sodium disilicate, zeolite, Trisodium Citrate, water glass, Starso, paratoluenesulfonic acid sodium salt, Sodium peroxoborate, the SPC-D.
Auxiliary material is any one perhaps two kinds and the two or more combination in CMC 99.5, high molecular polymer, whitening agent, essence, the proteolytic enzyme.
Working method is conventional high tower powder injection process, the attached polymer molding production technique, any in Combex technology (high tower dust with the attached polymer molding combine) technology.
Embodiment 4, a kind of Neat soap washing powder; Raw material by the following weight ratio example is formed, 3 parts in 1.5 parts in 10 parts of sodium oleates, whitening agent, essence, 33.5 parts in sodium sulfate that 15 parts of Witco 1298 Soft Acids (LAS), 12 parts of soda ash, 20 parts in 4A zeolite, 2 parts of water glass, 3 parts of paratoluenesulfonic acid sodium salts, oleic acid and sodium hydroxide neutralization obtain.Working method is a high tower spraying production technique.
The performance comparison of table 1 instance 1 Neat soap washing powder and same dosage resin acid sodium washing powder
Embodiment 5; A kind of Neat soap washing powder; Raw material by following weight ratio example is formed, 11.5 parts of alkyl ethoxy compound AES12 parts, 5 parts of AEOs (AEO-9), 10 parts of soda ash, 18 parts of tripoly phosphate sodium STPPs, 2 parts of Starsos, 5 parts of Trisodium Citrates, 20 parts of sodium oleates, 2 parts of CMC 99.5s, 1.0 parts in whitening agent, 3 parts in essence, proteinase-10 .5 part, sodium sulfate.Production technique is the attached polymer molding working method.
The performance comparison of table 2 instance 2 Neat soap washing powders and same dosage resin acid sodium washing powder
Embodiment 6, a kind of Neat soap washing powder; Raw material by following weight ratio example is formed, 15.5 parts of 12 parts of AEOs (AEO-9), 30 parts of sodium oleates, 10 parts of soda ash, 15 parts of laminated crystal of sodium disilicate, 5 parts of Trisodium Citrates, 7 parts of SPC-Ds, 1 part of high molecular polymer, 1.0 parts in whitening agent, 3 parts in essence, proteinase-10 .5 part, sodium sulfate.Production technique is Combex technology (high tower dusts and the attached polymer molding combines).
The performance comparison of table 3 instance 3 Neat soap washing powders and same dosage resin acid sodium washing powder
Claims (2)
1. Neat soap washing powder is characterized in that:
Raw material by the following weight ratio example is formed tensio-active agent 5-30 part, sodium oleate 2-40 part, washing auxiliary detergent 20-70 part, auxiliary material 0.1-10 part, stopping composition sodium sulfate 5-50 part; Used tensio-active agent is anionic surfactant sodium dodecylbenzene sulfonate LAS, α-sodium olefin sulfonate AOS, ethoxylated alkyl sulfate AES, C10-24 fatty acid soaps and nonionogenic tenside AEO AEO-9, AEO AEO-7 any one perhaps two kinds and two or more combination wherein; Washing auxiliary detergent is any one perhaps two kinds and the two or more combination in yellow soda ash, tripoly phosphate sodium STPP, laminated crystal of sodium disilicate, zeolite, Trisodium Citrate, water glass, Starso, paratoluenesulfonic acid sodium salt, Sodium peroxoborate, the SPC-D; Auxiliary material is any one perhaps two kinds and the two or more combination in CMC 99.5, whitening agent, essence, the proteolytic enzyme; Its preparation method is one of following three kinds:
AS and sodium oleate, washing auxiliary detergent and partial supplementary material and stopping composition sodium sulfate are mixed and made into slip by formula ratio; Spraying drying then; And cool aging, again thermo-sensitivity auxiliary material and nonionogenic tenside AEO are pressed formula rate and add and promptly get the finished product;
AS, nonionogenic tenside, sodium oleate, washing auxiliary detergent and partial supplementary material and stopping composition sodium sulfate are directly mixed by the Recipe requirement, and thorough mixing evenly back adding thermo-sensitivity auxiliary material gets final product;
AS and sodium oleate, washing auxiliary detergent and partial supplementary material are processed slip by prescription, spraying drying then, and cool aging obtains washing powder; Secondly the original washing powder of the washing powder of gained is got the umber that prescription requires, require to take by weighing AEO, sodium oleate, washing auxiliary detergent, stopping composition sodium sulfate according to prescription again and directly mix, thorough mixing evenly back adds the thermo-sensitivity auxiliary material and gets final product.
2. Neat soap washing powder according to claim 1 is characterized in that: used sodium oleate is the back gained that neutralized by oleic acid and sodium hydroxide.
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Effective date of registration: 20181113 Address after: No. 376 Hongqi East Street, Yuncheng City, Shanxi Province Patentee after: Shanxi Coking Coal Yuncheng Salinization Group Co., Ltd. Address before: 044000 No. 294 Jiefang Road, Yuncheng, Shanxi Province Patentee before: Nanfeng Chemical Group Co., Ltd. |
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